Patents by Inventor Thierry Le Mercier

Thierry Le Mercier has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 12294049
    Abstract: The present invention relates to a method of preparation of a garnet-type inorganic material. It also relates to the garnet-type inorganic material itself. The process comprises the following steps: (1) bringing an aqueous solution S comprising (i) a salt of zirconium, (ii) a salt of lanthanum and (iii) a salt of the element A or a precursor of an oxide of element A into contact with an aqueous solution of a basic compound, as a result of which a precipitate suspended in the reaction medium is obtained; (2) stirring the reaction medium obtained at the end of step (1) for at least 30 min; (3) bringing the precipitate obtained at the end of step (2) into contact with an additive selected in the group consisting of: anionic surfactants; nonionic surfactants; polyethylene glycols; carboxylic acids and their salts; and surfactants of the carboxymethylated fatty alcohol ethoxylate type; (4) calcining in air the precipitate recovered at the end of the previous step at a temperature which is at least 400° C.
    Type: Grant
    Filed: July 29, 2020
    Date of Patent: May 6, 2025
    Assignee: SPECIALTY OPERATIONS FRANCE
    Inventors: Réka Toth, Laure Bertry, Valérie Buissette, Thierry Le Mercier, Marc-David Braida, Robin Amisse
  • Patent number: 12288843
    Abstract: The present invention concerns a new method for the preparation of a Li—P—S product, as well as the products obtainable by said methods, and uses thereof especially as solid electrolytes.
    Type: Grant
    Filed: September 4, 2020
    Date of Patent: April 29, 2025
    Assignees: SPECIALTY OPERATIONS FRANCE, LE CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE DE PICARDIE JULES VERNE
    Inventors: Marc-David Braida, Ömer Ulas Kudu, Christian Masquelier, Thierry Le Mercier, Benoit Fleutot
  • Patent number: 12241009
    Abstract: A modified phosphor is described comprising phosphor particles and at least one amphiphilic agent. Compositions comprising the modified phosphor and at least one polymer are also described.
    Type: Grant
    Filed: October 5, 2021
    Date of Patent: March 4, 2025
    Assignee: RHODIA OPERATIONS
    Inventors: Valérie Buissette, Franck Aurissergues, Thierry Le Mercier
  • Publication number: 20250059040
    Abstract: The present invention pertains to a solid material according to general formula (I) as follows having high calculated ionic conductivity and to a method for producing said solid material: Li7-2x-yMgxPS6-yXy??(I) wherein: X is a halogen selected from the group consisting of F, Cl, I and Br or a combination thereof; x is a number such as 0.01?x?0.4 and y is a number such as 0.5?y<1. The present disclosure also refers to the use of this solid material as solid electrolyte notably for electrochemical devices such as batteries.
    Type: Application
    Filed: December 12, 2022
    Publication date: February 20, 2025
    Applicant: SPECIALTY OPERATIONS FRANCE
    Inventors: Antoine Emery, Marc-David Braida, Thierry Le Mercier, Nicola Marzari, Sokseiha Muy, Loris Ercole
  • Publication number: 20250055025
    Abstract: The present invention pertains to a solid material according to general formula (I) as follows and to a method for producing said solid material: Li7-2x-yMgxPS6-yXy??(I) wherein: X is a halogen selected from the group consisting of F, Cl, I and Br or a combination thereof; x is a number such as 0.01?x?0.35 and y is a number such as 1.3?y?1.6. The present disclosure also refers to the use of this solid material as solid electrolyte notably for electrochemical devices such as batteries.
    Type: Application
    Filed: December 14, 2022
    Publication date: February 13, 2025
    Applicant: SPECIALTY OPERATIONS FRANCE
    Inventors: Antoine Emery, Marc-David Braida, Thierry Le Mercier, Nicola Marzari, Sokseiha Muy, Loris Ercole
  • Publication number: 20250002342
    Abstract: The present disclosure relates to a process of obtaining a powder of lithium sulfide (Li2S powder) having a d50-value of less than 10 ?m, a specific surface area of more than 5 m2/g, a total pore volume of more than 0.035 cm3/g and a percentage of total pore volume constituted of pore with diameter below 20 nm of more than 20%, comprising the steps of: a) providing a powder of lithium hydroxide having a d50-value of less than 10 ?m and presenting a residual water content below 5 wt. % (LiOH powder A), and b) reacting such LiOH powder A with a sulfide reactant, in order to obtain the Li2S powder. The present disclosure also relates to the powder of lithium sulfide obtained from such process and the use of such Li2S powder to prepare a solid compound of formula (I): LiaPSbXc wherein —X represents at least one halogen element; —a represents a number from 3.0 to 6.0; —b represents a number from 3.5 to 5.0; and —c represents a number from 0 to 3.0.
    Type: Application
    Filed: July 5, 2022
    Publication date: January 2, 2025
    Applicant: SPECIALTY OPERATIONS FRANCE
    Inventors: Sébastien Jus, Lauriane D'Alencon, Thierry Le Mercier
  • Publication number: 20240413387
    Abstract: The present disclosure relates to a powder of solid material particles of formula (I): LiaPSbXc wherein—X represents at least one halogen element; —a represents a number from 2.0 to 7.0; —b represents a number from 3.0 to 6.0; and —c represents a number from 0 to 3.0, wherein the powder has a d50-value of less than 50 ?m, characterised in that its L* value in the L*a*b* color system is less than 60.0. The present disclosure also relates to a process for preparing such powder, as well as to the use of such powder for notably manufacturing solid electrolytes or battery articles.
    Type: Application
    Filed: October 11, 2022
    Publication date: December 12, 2024
    Applicant: SPECIALTY OPERATIONS FRANCE
    Inventors: Lauriane D'Alencon, Jules Valente, Thierry Le Mercier
  • Patent number: 12139416
    Abstract: The present invention relates to the new process of preparation of a Li-rich layered oxide based on Mn and optionally on Ni and/or Co in which F is incorporated within the crystal of the oxide (or “fluorinated oxide”). It also relates to the new fluorinated oxide its use as a component in a cathode of a battery.
    Type: Grant
    Filed: April 25, 2019
    Date of Patent: November 12, 2024
    Assignees: LE CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, COLLEGE DE FRANCE, SPECIALTY OPERATIONS FRANCE
    Inventors: Jean-Marie Tarascon, Jiwei Ma, Laure Bertry, Robin Amisse, Marc-David Braida, Thierry Le Mercier, Valérie Buissette
  • Publication number: 20240343579
    Abstract: The present disclosure relates to The present disclosure relates to a powder of solid material particles comprising at least Li, P and S elements, characterized in that the thiol to carbonate surface groups ratio of the particle surface is less than 2, as measured by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) on a Bruker FTIR (MIR) Vertex 70 spectrometer. The present disclosure also relates to a process for preparing such powder, as well as to the use of such powder for notably manufacturing solid electrolytes or battery articles.
    Type: Application
    Filed: August 1, 2022
    Publication date: October 17, 2024
    Applicant: SPECIALTY OPERATIONS FRANCE
    Inventors: Lauriane D'Alencon, Diego Lopez Gonzalez, Jules Valente, Thierry Le Mercier
  • Publication number: 20240294828
    Abstract: The present invention relates to the use of silicates in a greenhouse film for increasing the fruit development of a plant, wherein the film comprises at least a matrix and a silicate. Said invention also refers to a film comprising at least a matrix and said silicate to increase the fruit development of a plant, and the use of a film comprising at least a matrix and said silicate in a greenhouse to increase the fruit development of a plant.
    Type: Application
    Filed: October 12, 2020
    Publication date: September 5, 2024
    Applicant: Solvay SA
    Inventors: Morgane Pellerin, Denis Belekian, Franck Aurissergues, Lauriane D'Alencon, Thierry Le Mercier
  • Publication number: 20240247169
    Abstract: The invention relates to cerium based core-shell particles having a core of cerium oxide optionally doped with at least one metal (M) and a shell consisting of a plurality of nanoparticles of cerium oxide optionally doped with at least one metal (M?), which can be the same or different from metal (M), formed on the surface of the core particle. The invention also relates to dispersions thereof in a liquid medium, to a process for producing the same and to the use of these particles and dispersions in polishing applications such as chemical mechanical polishing.
    Type: Application
    Filed: May 17, 2022
    Publication date: July 25, 2024
    Applicant: RHODIA OPERATIONS
    Inventors: Marie Plissonneau, Réka Toth, Thierry Le Mercier, Valérie Buissette, Lauriane D'Alencon
  • Publication number: 20240234804
    Abstract: The present invention concerns a new method for the preparation of a Li—P—S—O product, as well as the products obtainable by said methods, and uses thereof especially as solid electrolytes.
    Type: Application
    Filed: July 4, 2022
    Publication date: July 11, 2024
    Applicants: Solvay SA, Centre National de la Recherche Scientifique, UNIVERSITE DE PICARDIE JULES VERNE
    Inventors: Marc-David Braida, Thierry Le Mercier, Omer Kudu, Christian Masquelier
  • Publication number: 20240105986
    Abstract: The invention relates to a Composition comprising or consisting essentially of a product according to formula (I): LiaPSbXc (I) wherein—X represents at least one halogen element; —a represents a number from 2.0 to 7.0; —b represents a number from 3.5 to 6.0; and—c represents a number from 0 to 3.0; in the form of particles or articles the size of which being such that less than 10 wt % of the composition pass through a sieve of 200 ?m.
    Type: Application
    Filed: January 27, 2022
    Publication date: March 28, 2024
    Applicant: RHODIA OPERATIONS
    Inventors: Diego Lopez Gonzalez, Thierry Le Mercier, Lauriane D'Alencon, Laure Bertry, Marc-David Braida, Vincent Finsy
  • Publication number: 20240081198
    Abstract: The present invention relates to the use of silicates in a greenhouse film for increasing the flower development of a plant, wherein the film comprises at least a matrix and a silicate. Said invention also refers to a film comprising at least a matrix and said silicate to increase the flower development of a plant, and the use of a film comprising at least a matrix and said silicate in a greenhouse to increase the flower development of a plant.
    Type: Application
    Filed: October 12, 2020
    Publication date: March 14, 2024
    Applicant: Solvay SA
    Inventors: Morgane Pellerin, Denis Belekian, Franck Aurissergues, Lauriane D'Alencon, Thierry Le Mercier
  • Publication number: 20230352727
    Abstract: The present disclosure concerns a method for the preparation of lithium thiophosphate, as well as the products obtainable by said methods, and uses thereof especially as solid electrolytes. The method includes preparing a lithium thiophosphate including at least one step for the preparation of a solution S1 at a temperature T1 from ?200° C. to 10° C. followed by a step for removing at least a portion of the solvent from solution S1 to obtain lithium thiophosphate. The solution S1 includes a solvent and at least P species under the form of (PS4)3?, Li species under the form of Li+, and remaining sulfur under the form of polysulfide. followed by a step for removing at least a portion of the solvent from said solution S1 to obtain lithium thiophosphate.
    Type: Application
    Filed: November 20, 2020
    Publication date: November 2, 2023
    Applicant: Solvay SA
    Inventors: Marc-David Braida, Lauriane D'Alencon, Jean-Daniel Compain, Thierry Le Mercier
  • Publication number: 20230335787
    Abstract: The present disclosure concerns a method for the preparation of lithium argyrodite, as well as the products obtainable by said methods, and uses thereof especially as solid electrolytes. The method includes at least one step for the preparation of a solution S1 at a temperature T1 from ?200° C. to 10° C. followed by a step for removing at least a portion of the solvent from said solution S1 to obtain Li6PS5X. The solution S1 includes a solvent and at least P species in the form of (PS4)3-, Li species in the form of Li+, X species in the form of X? and remaining sulfur in the form of polysulfide.
    Type: Application
    Filed: November 20, 2020
    Publication date: October 19, 2023
    Applicant: Solvay SA
    Inventors: Marc-David Braida, Lauriane D'Alencon, Jean-Daniel Compain, Thierry Le Mercier
  • Publication number: 20230238572
    Abstract: The present invention concerns a new solid material according to general formula (I) as follows: Li4?2xZnxP2S6 (I) wherein 0<x?1. The invention also refers to a method for producing a solid material comprising at least bringing at least lithium sulfide, phosphorous sulfide, and a zinc compound, optionally in one or more solvents. The invention also refers to said solid materials and their use as solid electrolytes notably for electrochemical devices.
    Type: Application
    Filed: May 25, 2021
    Publication date: July 27, 2023
    Applicants: Solvay SA, Centre National de la Recherche Scientifique, UNIVERSITE DE PICARDIE JULES VERNE
    Inventors: Marc-David Braida, Thierry Le Mercier, Christian Masquelier, Omer Kudu
  • Publication number: 20230187687
    Abstract: The invention relates to a fluorination process consisting in bringing an inorganic compound M into contact with an atmosphere comprising difluorine gas, the inorganic compound M being a garnet based on the elements Li, La, Zr, A and O and for which the relative composition of the Li, La, Zr and A cations corresponds to the formula (I): LixLa3ZrzAw.
    Type: Application
    Filed: April 29, 2021
    Publication date: June 15, 2023
    Applicants: Solvay SA, Centre National de la Recherche Scientifique, Clermont Auvergne INP, Universite Clermont Auvergne
    Inventors: Laure Bertry, Réka Toth, Thierry Le Mercier, Valérie Buissette, Katia Guerin, Marc Dubois, Michaël Herraiz
  • Patent number: 11658288
    Abstract: The invention relates to an NVPF-based composition and the use thereof in the field of batteries as an electrochemically active material. The invention also relates to a conductive composition comprising said composition as well as to a method for obtaining said composition.
    Type: Grant
    Filed: July 30, 2019
    Date of Patent: May 23, 2023
    Assignee: RHODIA OPERATIONS
    Inventors: Laure Bertry, Robin Amisse, Valérie Buissette, Marc-David Braida, Stéphanie Lesturgez, Thierry Le Mercier
  • Patent number: 11655151
    Abstract: The present invention relates to a process for preparing an ammonium vanadium phosphate of formula (NH4)(VO2)(HPO4). It also relates to a process for preparing a vanadium orthophosphate VPO4.
    Type: Grant
    Filed: June 14, 2018
    Date of Patent: May 23, 2023
    Assignee: RHODIA OPERATIONS
    Inventors: Cyril Chomette, Valérie Buissette, Marc-David Braida, Thierry Le Mercier