Patents by Inventor Tohru Haruna
Tohru Haruna has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7018570Abstract: The present invention is directed to an ultraviolet absorber composition which is formed by melt-mixing a compound (A) represented by formula (I): and a resin stabilizer (B) selected from the group consisting of a phenolic antioxidant (b-1), a phosphorus-containing antioxidant (b-2), a hindered amine stabilizer (b-3), and an ultraviolet absorber (b-4) other than the compound (A), at a mass ratio (A)/(B) of 95/5 to 50/50. The composition has excellent compatibility with synthetic resins and provides a stabilized synthetic resin molding.Type: GrantFiled: June 6, 2002Date of Patent: March 28, 2006Assignee: Asahi Denka Kogyo K.K.Inventors: Tohru Haruna, Shinichi Ishikawa
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Publication number: 20040122137Abstract: The present invention is directed to an ultraviolet absorber composition which is formed by melt-mixing a compound (A) represented by formula (I): 1Type: ApplicationFiled: February 12, 2004Publication date: June 24, 2004Inventors: Tohru Haruna, Shinichi Ishikawa
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Patent number: 6103828Abstract: A macromolecular material composition which comprises a macromolecular material and a modifier which comprises a polyvinyl cyclohexane compound having hydroindane structure. The modifier improves melt flow characteristics, flexibility at a low temperature, and mechanical characteristics, such as bending modulus and bending strength, of the material, and do not bleed or give bad smell.Type: GrantFiled: October 28, 1998Date of Patent: August 15, 2000Assignees: Hitachi Chemical Co. Ltd., Asahi Denka Kogyo K.K.Inventors: Yuji Kobayashi, Takayuki Saitoh, Atsushi Fujioka, Akihiro Kobayashi, Fumiaki Kanega, Kiyotaka Mashita, Tohru Haruna, Takashi Takeuchi
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Patent number: 5238979Abstract: Stabilizers for enhancing the resistance of synthetic resins to deterioration when exposed to elevated temperatures and/or ultraviolet light comprising from about 0.001 to about 10 parts by weight of a bisphenol phosphite having the formula ##STR1## wherein R.sub.1 is tertiary-butyl or tertiary-amyl, R.sub.2 is alkyl having from one to about nine carbon atoms, R.sub.3 is hydrogen or alkyl having from one to about four carbon atoms, and R.sub.4 is alkyl having from one to about thirty carbon atoms; and from about 0.001 to about 10 parts by weight of a phenol having the formula ##STR2## wherein R.sub.5 is alkyl having from one to about four carbon atoms; and R.sub.6 is hydrogen or alkyl having from one to about four carbon atoms; and stabilized synthetic resin compositions comprising such stabilizers.Type: GrantFiled: March 12, 1990Date of Patent: August 24, 1993Assignee: Asahi Denka Kogyo K.K.Inventors: Tohru Haruna, Kazunori Nishikawa
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Patent number: 5112891Abstract: A polycarbonate resin composition improved in heat resistance by the addition of an organic cyclic phosphite represented by the general formula: ##STR1## wherein R.sub.1 represents an alkyl group having 1 to 9 carbon atoms; R.sub.2 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and R.sub.3 represents an alkyl group having 1 to 30 carbon atoms.Type: GrantFiled: August 28, 1990Date of Patent: May 12, 1992Assignee: Asahi Denka Kogyo Kabushiki KaishaInventors: Tohru Haruna, Masayuki Takahashi, Toshinori Yukino
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Patent number: 5077328Abstract: A filler-containing polyolefin resin composition comprising a resin composition composed of a polyolefin resin and an inorganic filler exhibits an excellent thermal stability despite the presence of the inorganic filler by adding thereto a particular phenolic antioxidant, an amide or monoglyceride compound of a higher fatty acid and a particular metal inactivating agent.Type: GrantFiled: January 25, 1991Date of Patent: December 31, 1991Assignee: Asahi Denka Kogyo K.K.Inventors: Tohru Haruna, Takashi Takeuchi
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Patent number: 5055507Abstract: Stabilizers for enhancing the resistance of synthetic resins to deterioration when exposed to elevated temperatures and/or ultraviolet light comprising from about 0.001 to about 10 parts by weight of a bisphenol phosphite having the formula ##STR1## wherein R.sub.1 is tertiary-butyl or tertiary-amyl, R.sub.2 is alkyl having from one to about nine carbon atoms, R.sub.3 is hydrogen or alkyl having from one to about four carbon atoms, and R.sub.4 is alkyl having from one to about thirty carbon atoms; and from about 0.001 to about 10 parts by weight of a phenol having the formula ##STR2## wherein R.sub.5 is alkyl having from one to about four carbon atoms; and stabilized synthetic resin compositions comprising such stabilizers.Type: GrantFiled: March 1, 1990Date of Patent: October 8, 1991Assignee: Asahi Denka Kogyo K.K.Inventors: Tohru Haruna, Kazunori Nishikawa
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Patent number: 5039723Abstract: A synthetic resin composition stabilized particularly against the deterioration caused by the action of heat and light, which comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic phosphite compound represented by the following general formula (I) and 0.001 to 10 parts by weight of a hindered amine compound having a group represented by the following general formula (II) in its molecule: ##STR1## wherein R.sub.1 stands for a tert-butyl or tert-amyl group; R.sub.2 stands for a C.sub.1.about.9 alkyl group; R.sub.3 stands for a hydrogen atom or a C.sub.1.about.4 alkyl group and R.sub.4 stands for a C.sub.1.about.30 alkyl group.Type: GrantFiled: July 31, 1989Date of Patent: August 13, 1991Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Tohru Haruna, Kazunori Nishikawa
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Patent number: 4999393Abstract: A cyclic phosphonite compound having the following formula (I) is disclosed and useful as a stabilizer for a synthetic resin. ##STR1## in which R1 is an alkyl, phenyl or an alkylphenyl, R2 is hydrogen or an alkyl, R3 is an alkyl, R4 is hydrogen or methyl and R1 and R2 may form an alkylene by linking each other.Type: GrantFiled: February 6, 1989Date of Patent: March 12, 1991Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Tohru Haruna, Kazunori Nishikawa
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Patent number: 4912156Abstract: A polyolefin composition comprises 100 parts by weight of a polyolefine which has been produced with use of a Ziegler catalyst and has a part or residue of the catalyst left therein, 0.005 to 1 part by weight of a phenol compound having the formula (I) and 0.005 to 1 part by weight of an organic phosphite compound having the formula (II). ##STR1## in which R is a residue group of an alcohol being monohydric, dihydric, trihydric or terahydric, R1 is methyl or tert.-butyl, R2 is an alkyl, --CH2CH2COOR3 or --COOR3, R3 being an alkyl, an aryl or an alkylaryl, and n is a number of 1 to 4.Type: GrantFiled: July 27, 1988Date of Patent: March 27, 1990Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Masaki Yagi, Tohru Haruna, Takashi Takeuchi, Toshinori Yukino
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Patent number: 4894400Abstract: Synthetic polymer compositions comprise 100 parts by weight of a synthetic polymer and 0.001 to 5 parts by weight of a benzotriazol compound, and thus possesses improved stability.Type: GrantFiled: August 5, 1988Date of Patent: January 16, 1990Assignee: Adeka Argus Chemical Co. Ltd.Inventors: Tohru Haruna, Masayuki Takahashi, Kazunori Nishikawa
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Patent number: 4885326Abstract: A synthetic resin composition comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic alkylphosphite compound of 2,2'-alkylidene-bisphenol (I) and 0.001 to 10 parts by weight of beta-(3,5-dialkyl-4-hydroxyphenyl)-propionic acid ester (II) and is stabilized to light and heat.Type: GrantFiled: March 24, 1989Date of Patent: December 5, 1989Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Tohru Haruna, Kazunori Nishikawa, Mitsuhiro Hamajima
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Patent number: 4670492Abstract: Cyclic bis and tris phosphites are provided having the formula: ##STR1## wherein: A is selected from the group consisting of sulfur; oxygen; alkylidene having from one to about six carbon atoms; cycloalkylidene having from three to about eight carbon atoms; and phenyl and alkyl phenyl alkylidene having from seven to about fourteen carbon atoms;R is selected from the group consisting of alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about eight carbon atoms; and phenalkylidene and alkyl phenalkylidene having from seven to about twelve carbon atoms;R.sub.1 is selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about eight carbon atoms; and phenalkylidene and alkyl phenalkylidene having from seven to about twelve carbon atoms;n is 2 or 3;R.sub.2 is ##STR2## wherein: m=0 when n is 2; and 1 when n is 3;R.sub.3, R.sub.4, R.sub.5, R.sub.Type: GrantFiled: October 22, 1985Date of Patent: June 2, 1987Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Yutaka Nakahara, Tohru Haruna, Etsuo Tobita
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Patent number: 4663459Abstract: A process is provided for the preparation of 2,2,6,6-tetramethyl-4-oxopiperidine, reacting acetone with ammonia in the presence of a catalytically effective amount of an organic carboxylic acid halide.Type: GrantFiled: February 14, 1985Date of Patent: May 5, 1987Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Tohru Haruna, Atsushi Nishimura, Kazuo Sugibuchi
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Patent number: 4661597Abstract: A process is provided for the preparation of 2,2,6,6-tetramethyl-4-oxopiperidine, reacting acetone with 2,2,4,4,6-pentamethyl-2,3,4,5,-tetrahydropyrimidine in the presence of a catalytically effective amount of an organic carboxylic acid halide.Type: GrantFiled: February 14, 1985Date of Patent: April 28, 1987Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Tohru Haruna, Atsushi Nishimura, Kazuo Sugibuchi
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Patent number: 4619958Abstract: Mixed light stabilizers for synthetic polymers are provided having the formula ##STR1## wherein: R is a polyvalent group selected from the group consisting of aliphatic hydrocarbon groups having from one to about twenty carbon atoms, cycloaliphatic hydrocarbon groups having from three to about sixteen carbon atoms and aromatic hydrocarbon groups having from six to about thirty carbon atoms; such groups substituted with from one to about six groups selected from the group consisting of hydroxy, acyloxy, and halogen; and N(C.sub.n.sbsb.1 H.sub.2n.sbsb.1).sbsb.3 where n.sub.1 is a number from one to five;R.sub.1 is selected from the group consisting of hydrogen, oxyl, alkyl, epoxy alkyl and hydroxy alkyl having from one to about twelve carbon atoms, alkyl aryl having from six to about eighteen carbon atoms, and acyl having from two to about twelve carbon atoms;R.sub.2 is selected from the group consisting of alkyl and alkenyl having from eight to about thirty carbon atoms;R.sub.Type: GrantFiled: September 30, 1983Date of Patent: October 28, 1986Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Tohru Haruna, Atsushi Nishimura
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Patent number: 4529760Abstract: Oligomers of 2,2,6,6-tetramethylpiperidinol polycarboxylic acid esters are provided having the formula: ##STR1## wherein: Z is the residue of an aliphatic or aromatic or nitriloaliphatic or hydroxy aliphatic polycarboxylic acid having from three to six carboxylic acid groups and from one to thirty carbon atoms; ##STR2## wherein R.sub.3 is hydrogen, alkyl and hydroxyalkyl having from one to about twenty carbon atoms; cycloalkyl having from six to about twenty carbon atoms; aryl having from six to about twenty carbon atoms; or cycloalkylene with the N in the ring and having from two to five carbon atoms;R is alkylene having from two to about twelve carbon atoms; cycloalkylene having from three to about twelve carbon atoms; phenylene having from six to about twenty carbon atoms; mixed alkylenecycloalkylene or alkylene phenylene or oxyalkylene having from two to about twelve carbon atoms; ##STR3## wherein R.sub.4 is alkyl having from one to about six carbon atoms;R.sub.Type: GrantFiled: November 1, 1983Date of Patent: July 16, 1985Assignee: Adeka Argus Chemical Co., Ltd.Inventors: William E. Leistner, Motonobu Minagawa, Yutaka Nakahara, Tohru Haruna, Atsushi Nishimura
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Patent number: 4481317Abstract: Hindered bisphenol diphosphonites are provided having the structure: ##STR1## wherein: A is selected from the group consisting of thio sulfur --S--; oxy oxygen --O--; alkylidene having from one to about ten carbon atoms; cycloalkylidene having from about four to about eight carbon atoms; and phenylalkylidene having from seven to about twelve carbon atoms;R is selected from the group consisting of alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about twelve carbon atoms; and aralkyl having from seven to about twelve carbon atoms;R.sub.1 is selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about twelve carbon atoms; and aralkyl having from seven to about twelve carbon atoms;R.sub.2 is selected from the group consisting of ##STR2## as well as synthetic resin compositions having an enhanced resistance to deterioration by heat and light comprising a synthetic resin and such phosphonites.Type: GrantFiled: June 7, 1983Date of Patent: November 6, 1984Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Yutaka Nakahara, Tohru Haruna, Etsuo Tobita
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Patent number: 4469828Abstract: Alkylthiopropionyl hydrazino triazines are provided having the formula: ##STR1## wherein: R is alkyl having from one to about fifty carbon atoms;X is ##STR2## where R.sub.1 is selected from the group consisting of hydrogen, alkyl having from one to about fifty carbon atoms; and ##STR3## where R.sub.2 is selected from the group consisting of hydrogen, O and alkyl hydroxyalkyl, epoxy alkyl and acyloxy alkyl having from one or two to about eight carbon atoms;when X is O, A is selected from the group consisting of alkylene having from two to about twenty carbon atoms, cycloalkylene having from about five to about eight carbon atoms and phenylene;when X is ##STR4## A is selected from the group consisting of a direct linkage, alkylene having from one to about twenty carbon atoms, cycloalkylene having from five to about eight carbon atoms; phenylene; and ##STR5## where R.sub.Type: GrantFiled: November 22, 1982Date of Patent: September 4, 1984Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Motonobu Minagawa, Tohru Haruna, Masayuki Takahashi
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Patent number: 4463113Abstract: Bis-phenol phosphates, are provided, represented by the formula: ##STR1## wherein: R is selected from the group consisting of a carbon-to-carbon bond; thio sulfur --S--; and alkylidene ##STR2## in which R.sub.3 and R.sub.4 are selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms, and cycloalkyl, including cycloalkylidene in which R.sub.3 and R.sub.4 are taken together as part of a cycloalkylene ring, having from three to about twelve carbon atoms;R.sub.1 and R.sub.2 are each selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms; and cycloalkyl having from three to about twelve carbon atoms;m is 0 or 1;M is a metal atom which can be monovalent or polyvalent; and n is the valence of the metal atom M, ranging from one to about four;useful to improve clarity of polyolefin resin compositions in an amount within the range from 0.005 to 5 parts by weight per 100 parts of resin.Type: GrantFiled: May 20, 1982Date of Patent: July 31, 1984Inventors: Yutaka Nakahara, Mitsuo Akutsu, Tohru Haruna, Masayuki Takahashi