Patents by Inventor Tomio Yagihara

Tomio Yagihara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6756497
    Abstract: Benzoic acid derivatives useful as intermediates for the preparation of drugs and agricultural chemicals, particularly compounds having herbicidal activity; and easy and economical processes for the preparation of the same. The processes are specifically those represented by reaction formula for the preparation of compounds represented by general formulae (1) and (6).
    Type: Grant
    Filed: January 12, 2001
    Date of Patent: June 29, 2004
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Yuuki Nakagawa, Masao Yamaguchi, Hiroyuki Adachi, Hiroyuki Yamanaka, Tomio Yagihara, Masami Hatano
  • Publication number: 20040059122
    Abstract: A thioacetamide compound represented by the formula (1) which is useful as an intermediate for an acrylonitrile derivative serving as an active ingredient for medicines and agricultural chemicals, especially insecticides/acaricides; a process for producing the compound; and a process for producing a 3-oxo-2-(2-thiazolyl)propanenitrile compound, characterized by reacting the compound represented by the formula (1) with a phenacyl halide.
    Type: Application
    Filed: July 22, 2003
    Publication date: March 25, 2004
    Inventors: Tomio Yagihara, Tetsushi Ookuchi
  • Publication number: 20040019221
    Abstract: A process (1) for the preparation of 4-cyanoacetylpyrazoles of the general formula (I) wherein R1 is C1-6 alkyl, R2 is C1-6 alkyl or C1-6 haloalkyl, and X is hydrogen or C1-6 alkyl which comprises using a pyrazolecarboxylic acid halide and a cyanoacetate ester; a process (2) for the preparation of the same which comprises using a pyrazolecarboxylic acid and a cyanoacetate ester; a process (3) for the preparation of the same which comprises using a pyrazolecarbonitrile; and a process (4) for the preparation of the same which comprises using a haloacetylpyrazole. Furthermore, an industrially advantageous process for preparing pyrazolecarboxylic acids useful as intermediates in the above processes.
    Type: Application
    Filed: February 6, 2003
    Publication date: January 29, 2004
    Inventors: Tomio Yagihara, Tsutomu Imagawa, Shigemi Suga, Masami Hatano, Yasushi Shibata, Tetsushi Ookuchi, Isamu Kasahara
  • Patent number: 6541642
    Abstract: A process for the preparation of (E)-3-(1-propenyl)-2-isoxazoline, characterized by reacting crotonaldehyde with hydroxylamine to form an oxime, and then converting the oxime into a nitrile oxide while reacting the nitrile oxide with ethylene.
    Type: Grant
    Filed: September 26, 2001
    Date of Patent: April 1, 2003
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Tomio Yagihara, Michinori Takebayashi, Hiroyuki Yamanaka
  • Patent number: 6420612
    Abstract: Bicycloheptene compounds represented by general formula (1) and being useful as intermediates for the production of agricultural chemicals or drugs (wherein X is hydroxycarbonyl, hydroxymethyl, halogenomethyl, nitromethyl, or methylthiomethyl); and a process for the preparation of compounds of general formula (1), characterized by reacting 5,5-dimethoxy-1,2,3,4-tetrachlorocyclopentadiene with a compound represented by general formula (2) (wherein X is as defined above)
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: July 16, 2002
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Tomio Yagihara, Hiroyuki Yamanaka
  • Patent number: 5317102
    Abstract: This invention relates to 3,6-diamino-2,5-pyrazinedicarbonitrile which is a red crystal and yellowish green fluorenscent substance and the methods of preparation from compounds represented by formula [I], ##STR1## (wherein R are aryl, alkyl, aralkyl or alkenyl or may be substituted), as a starting material, under acidic condition in the presence of oxygen.
    Type: Grant
    Filed: August 7, 1992
    Date of Patent: May 31, 1994
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Seiji Tazaki, Tomio Yagihara, Nobuo Matsui, Atsushi Yanagisawa, Takakazu Kojima
  • Patent number: 5306443
    Abstract: By the selective use of a homogeneous stable precursor solution in which no polymerization reactions immediately occur and which contains aromatic compounds such as pyrrole, thiophene, aromatic amines or their derivatives, oxidizing agents, and solvents, as a precursor solution of conductive polymer film, a homogeneous and tough conductive polymer film can be obtained when the said precursor solution is cast on a substrate and the solvents are evaporated to remove.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: April 26, 1994
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Takehira Kaneko, Hirofumi Suzuki, Nobuo Matsui, Tomio Yagihara, Shiro Higashida, Akira Nakada, Hitoshi Matsumoto, Takeo Shimizu
  • Patent number: 5294711
    Abstract: This invention relates to 3,6-diamino-2,5-pyrazinedicarbonitrile which is a red crystal and yellowish green fluorescent substance and the methods of preparation from compounds represented by formula [I], ##STR1## (wherein R are aryl, alkyl, aralkyl or alkenyl or may be substituted), as a starting material, under acidic condition in the presence of oxygen.
    Type: Grant
    Filed: April 29, 1991
    Date of Patent: March 15, 1994
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Seiji Tazaki, Tomio Yagihara, Nobuo Matsui, Atsushi Yanagisawa, Takakazu Kojima
  • Patent number: 5185460
    Abstract: Aminoacetonitrile derivatives, where the 2-position of aminoacetonitrile is optionally substituted by alkylthio groups, arylthio groups and heterocyclicthio groups. The process for making such compounds comprises reacting hydrogen cyanide with the desired corresponding R-S-H and recovering the crystallized salt thereof. The aminoacetonitrile derivatives are useful as starting materials to produce pharmaceutical and agricultural intermediates such as benzomide derivatives with fungicidal and herbicidal activities.
    Type: Grant
    Filed: April 22, 1992
    Date of Patent: February 9, 1993
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Seiji Tazaki, Nobuhiro Umeda, Nobuo Matsui, Tomio Yagihara, Katsunori Mikuma
  • Patent number: 4990630
    Abstract: The present invention relates to a 2,3-diaminoacrylonitrile derivative or salts thereof, having the formula ##STR1## wherein R represents an alkyl group (which may be substituted by unsubstituted or substituted phenyl groups, halogen atoms, C.sub.1-6 alkoxycarbonyl groups, carboxy groups, C.sub.1-6 alkoxycarbonyl C.sub.1-6 alkylthio groups, hydroxy groups, mercapto groups, cycloalkyl groups or heterocyclic groups containing oxygen atoms); an alkenyl group; a cycloalkyl group; an aryl group (which may be substituted by halogen atoms, C.sub.1-6 alkyl groups, nitro-groups, unsubstituted or substituted phenyl or phenoxy groups or heterocyclic groups containing oxygen atoms or sulfur atoms).The 2,3-diaminoacrylonitrile derivative can be used as starting materials for the production of pharmaceutical and/or agricultural intermediates such as cyanoimidazoles, cyanopyrazines or other cyano-substituted heterocycles.
    Type: Grant
    Filed: August 28, 1989
    Date of Patent: February 5, 1991
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Katsunori Mikuma, Nobuhiro Umeda, Tomio Yagihara, Isami Hamamoto
  • Patent number: 3950534
    Abstract: Carbamic acid derivatives of the general formula: ##EQU1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of lower alkyl, cycloalkyl, phenyl and phenyl substituted with halogen,R.sub.3 is selected from the group consisting of hydrogen and lower alkyl,Each of X.sub.1, X.sub.2, Y.sub.1 and Y.sub.2 is selected from the group consisting of oxygen and sulfur,N is an integer from 1 to 2, are useful as fungicides.An exemplary specie is 2-(N-n-butylcarbomoylthio)ethyl N'-n-butylthiolcarbamate.
    Type: Grant
    Filed: July 24, 1974
    Date of Patent: April 13, 1976
    Assignee: Nippon Soda Company, Ltd.
    Inventors: Tomio Yagihara, Koshin Miyazaki, Sho Hashimoto, Akira Wakai