Patents by Inventor Toshikazu Sakamaki
Toshikazu Sakamaki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11866527Abstract: A photocurable composition includes a photopolymerizable component and a photopolymerization initiator. When a test piece with 39 mm length, 8 mm width, and 4 mm thickness, is produced by photofabrication under conditions in which the photocurable composition is irradiated with visible light having 405 nm wavelength at 12 mJ/cm2 irradiation dose to form a cured layer with 100 m thickness, the cured layer is stacked in a thickness direction thereof to form a rectangular fabrication product with 39 mm length, 8 mm width, and 4 mm thickness, and the fabrication product is irradiated with ultraviolet rays having 365 nm wavelength at 10 J/cm2 irradiation dose to produce the test piece, a total fracture work of the test piece measured in compliance with ISO20795-1:2008 is 1100 J/m2 or more.Type: GrantFiled: March 22, 2021Date of Patent: January 9, 2024Assignee: MITSUI CHEMICALS, INC.Inventors: Toshikazu Sakamaki, Mai Kimura, Hiroki Murai, Takaaki Hayashi, Suguru Endo
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Patent number: 11780947Abstract: The present invention provides a photocurable composition for use in stereolithography, the photocurable composition including: a (meth)acrylic monomer (X) that is at least one selected from the group consisting of di(meth)acrylic monomers containing, within one molecule, two aromatic rings and two (meth)acryloyloxy groups, and that has a weight average molecular weight of from 400 to 580; a (meth)acrylic monomer (D) that is at least one selected from the group consisting of (meth)acrylic monomers containing, within one molecule, at least one aromatic ring and one (meth)acryloyloxy group, and that has a weight average molecular weight of from 140 to 350; and a photopolymerization initiator.Type: GrantFiled: March 29, 2018Date of Patent: October 10, 2023Assignee: MITSUI CHEMICALS, INC.Inventor: Toshikazu Sakamaki
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Publication number: 20230303746Abstract: The present invention provides a photocurable composition for use in stereolithography, the photocurable composition including: a (meth)acrylic monomer (X) that is at least one selected from the group consisting of di(meth)acrylic monomers containing, within one molecule, two aromatic rings and two (meth)acryloyloxy groups, and that has a weight average molecular weight of from 400 to 580; a (meth)acrylic monomer (D) that is at least one selected from the group consisting of (meth)acrylic monomers containing, within one molecule, at least one aromatic ring and one (meth)acryloyloxy group, and that has a weight average molecular weight of from 140 to 350; and a photopolymerization initiator.Type: ApplicationFiled: May 12, 2023Publication date: September 28, 2023Applicant: MITSUI CHEMICALS, INC.Inventor: Toshikazu Sakamaki
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Publication number: 20230242785Abstract: A photocurable composition, wherein: in a case in which a rectangular sheet-like test piece P1 is produced by photomodeling under conditions in which the photocurable composition is irradiated with visible light having a wavelength of 405 nm at an irradiation dose of 11 mJ/cm2 to form a cured layer P1 with a thickness of 50 ?m, the cured layer P1 is stacked in a thickness direction thereof to form the rectangular sheet-like modeling product P1 with a length of 40 mm, a width of 10 mm, and a thickness of 0.5 mm, and the modeling product P1 is irradiated with ultraviolet rays having a wavelength of 365 nm at an irradiation dose of 3 J/cm2 to produce the test piece P1, the storage modulus at 135° C. of the test piece P1 is 3.0×108 Pa or more.Type: ApplicationFiled: July 6, 2021Publication date: August 3, 2023Applicant: MITSUI CHEMICALS, INC.Inventors: Takaaki HAYASHI, Toshikazu SAKAMAKI, Mai KIMURA, Hiroki MURAI, Suguru ENDO, Eiji KOBAYASHI
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Publication number: 20230137212Abstract: A photocurable composition includes a photopolymerizable component and a photopolymerization initiator. When a test piece with a length of 39 mm, a width of 8 mm, and a thickness of 4 mm, is produced by photofabrication under conditions in which the photocurable composition is irradiated with visible light having a wavelength of 405 nm at an irradiation dose of 12 mJ/cm2 to form a cured layer with a thickness of 100 µm, the cured layer is stacked in a thickness direction thereof to form a rectangular fabrication product with a length of 39 mm, a width of 8 mm, and a thickness of 4 mm, and the fabrication product is irradiated with ultraviolet rays having a wavelength of 365 nm at an irradiation dose of 10 J/cm2 to produce the test piece, a total fracture work of the test piece measured in compliance with ISO20795-1:2008 is 1100 J/m2 or more.Type: ApplicationFiled: March 22, 2021Publication date: May 4, 2023Applicant: MITSUI CHEMICALS, INC.Inventors: Toshikazu SAKAMAKI, Mai KIMURA, Hiroki MURAI, Takaaki HAYASHI, Suguru ENDO
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Publication number: 20230131633Abstract: A photocurable composition includes a photopolymerizable component and a photopolymerization initiator. In a case in which a rectangular sheet-like test piece is produced by photomodeling under conditions in which the photocurable composition is irradiated with visible light having a wavelength of 405 nm at an irradiation dose of 12 mJ/cm2 to form a cured layer with a thickness of 50 µm, the cured layer is stacked in a thickness direction thereof to form a rectangular sheet-like modeling product with a length of 40 mm, a width of 10 mm, and a thickness of 1 mm, and the modeling product is irradiated with ultraviolet rays having a wavelength of 365 nm at an irradiation dose of 10 J/cm2 to produce the test piece, the test piece has an X-ray absorption coefficient of from 9.0 cm-1 to 34.0 cm-1.Type: ApplicationFiled: March 26, 2021Publication date: April 27, 2023Applicant: MITSUI CHEMICALS, INC.Inventors: Mai KIMURA, Toshikazu SAKAMAKI
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Publication number: 20220339077Abstract: A photocurable composition includes a (meth)acrylic monomer component and a photopolymerization initiator, wherein an adhesive force of a cured product is less than or equal to 1.5 N, and a rupture elongation of the cured product is greater than or equal to 20%.Type: ApplicationFiled: October 28, 2020Publication date: October 27, 2022Applicant: MITSUI CHEMICALS, INC.Inventors: Suguru ENDO, Toshikazu SAKAMAKI, Mai KIMURA, Hiroki MURAI, Takaaki HAYASHI
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Publication number: 20220153894Abstract: A photo-curable composition including a di-(meth)acrylic monomer (A) having two (meth)acryloyloxy groups and two urethane bonds, an acrylic monomer (B) having one acryloyl group, and a photopolymerization initiator, as well as a cured product of the photo-curable composition, and a dental product including the cured product.Type: ApplicationFiled: March 30, 2020Publication date: May 19, 2022Applicant: MITSUI CHEMICALS, INC.Inventors: Toshikazu SAKAMAKI, Hirohisa SHIODE, Mai KIMURA
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Publication number: 20210178698Abstract: A measuring section of a stereolithography device measures a temperature of a photocurable resin liquid by a temperature sensor. A setting section sets an integrated light amount on the basis of temperature information obtained from a measured temperature and curing information stored in a storage section. An illuminating section controls a projector such that light, by which the set integrated light amount is obtained, is illuminated onto the photocurable resin liquid. Due thereto, light, which is such that there becomes an integrated light amount corresponding to the temperature of the photocurable resin liquid, is illuminated onto the photocurable resin liquid, and therefore, a molded object can be molded with high accuracy.Type: ApplicationFiled: December 20, 2018Publication date: June 17, 2021Applicant: MITSUI CHEMICALS, INC.Inventors: Toshikazu SAKAMAKI, Hirohisa SHIODE, Takaaki HAYASHI
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Patent number: 10973742Abstract: A photocurable composition for manufacturing a dental prosthesis by stereolithography, including: a photopolymerization initiator; and a (meth)acrylic monomer component including an acrylic monomer (X) having no aromatic rings and having a ring structure other than an aromatic ring and two or more acryloyloxy groups in one molecule and having an Mw of from 200 to 800, and at least one of a (meth)acrylic monomer (A) having one or more ether bonds and two (meth)acryloyloxy groups in one molecule and having a defined Mw, a (meth)acrylic monomer (B) having a ring structure other than an aromatic ring and one (meth)acryloyloxy group in one molecule and having a defined Mw, a (meth)acrylic monomer (C) having a hydrocarbon skeleton and two (meth)acryloyloxy groups in one molecule and having a defined Mw, and a (meth)acrylic monomer (D) having one or more aromatic rings and one (meth)acryloyloxy group in one molecule and having a Mw.Type: GrantFiled: August 2, 2017Date of Patent: April 13, 2021Assignee: MITSUI CHEMICALS, INC.Inventors: Toshikazu Sakamaki, Kouya Kojima, Hirohisa Shiode, Mai Kimura
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Publication number: 20210038353Abstract: The present invention provides a photocurable composition for use in stereolithography, the photocurable composition including: a (meth)acrylic monomer (X) that is at least one selected from the group consisting of di(meth)acrylic monomers containing, within one molecule, two aromatic rings and two (meth)acryloyloxy groups, and that has a weight average molecular weight of from 400 to 580; a (meth)acrylic monomer (D) that is at least one selected from the group consisting of (meth)acrylic monomers containing, within one molecule, at least one aromatic ring and one (meth)acryloyloxy group, and that has a weight average molecular weight of from 140 to 350; and a photopolymerization initiator.Type: ApplicationFiled: March 29, 2018Publication date: February 11, 2021Applicant: Mitsui Chemicals, Inc.Inventor: Toshikazu SAKAMAKI
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Publication number: 20200377637Abstract: A curable composition for stereolithography, comprising a photopolymerizable component and a photopolymerization initiator, wherein a cured product of the curable composition has a minimum value of a storage elastic modulus, in a range of from 25° C. to 300° C., of not greater than 1.20×107 Pa.Type: ApplicationFiled: March 28, 2019Publication date: December 3, 2020Applicant: MITSUI CHEMICALS, INC.Inventors: Takaaki HAYASHI, Toshikazu SAKAMAKI
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Patent number: 10562995Abstract: Provided is a photocurable composition including a monomer component including: a monomer (X) containing, within one molecule, two aromatic rings and two (meth)acryloyloxy groups, and having an Mw of from 400 to 580, and a monomer (H) containing, within one molecule, at least one of a hydroxyl group or a carboxy group, and a (meth)acryloyloxy group, and having an Mw of from 100 to 700; and a photopolymerization initiator. The composition has a functional group value (a) of from 0.5×10?3 to 2.0×10?3 mol/g. Functional group value (a)=(nH/MH)×PH??Formula (a) wherein nH represents the total number of hydroxyl groups and carboxy groups contained in one molecule of the (meth)acrylic monomer (H); MH represents the Mw of the (meth)acrylic monomer (H); and PH represents the mass ratio of the (meth)acrylic monomer (H) with respect to the total amount of the (meth)acrylic monomer component.Type: GrantFiled: October 4, 2016Date of Patent: February 18, 2020Assignee: MITSUI CHEMICALS, INC.Inventors: Toshikazu Sakamaki, Takashi Koura, Kouya Kojima, Hirohisa Shiode, Mai Kimura
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Publication number: 20190175455Abstract: A photocurable composition for manufacturing a dental prosthesis by stereolithography, including: a photopolymerization initiator; and a (meth)acrylic monomer component including an acrylic monomer (X) having no aromatic rings and having a ring structure other than an aromatic ring and two or more acryloyloxy groups in one molecule and having an Mw of from 200 to 800, and at least one of a (meth)acrylic monomer (A) having one or more ether bonds and two (meth)acryloyloxy groups in one molecule and having a defined Mw, a (meth)acrylic monomer (B) having a ring structure other than an aromatic ring and one (meth)acryloyloxy group in one molecule and having a defined Mw, a (meth)acrylic monomer (C) having a hydrocarbon skeleton and two (meth)acryloyloxy groups in one molecule and having a defined Mw, and a (meth)acrylic monomer (D) having one or more aromatic rings and one (meth)acryloyloxy group in one molecule and having a Mw.Type: ApplicationFiled: August 2, 2017Publication date: June 13, 2019Applicant: Mitsui Chemicals, Inc.Inventors: Toshikazu SAKAMAKI, Kouya KOJIMA, Hirohisa SHIODE, Mai KIMURA
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Publication number: 20180282455Abstract: Provided is a photocurable composition including a monomer component including: a monomer (X) containing, within one molecule, two aromatic rings and two (meth)acryloyloxy groups, and having an Mw of from 400 to 580, and a monomer (H) containing, within one molecule, at least one of a hydroxyl group or a carboxy group, and a (meth)acryloyloxy group, and having an Mw of from 100 to 700; and a photopolymerization initiator. The composition has a functional group value (a) of from 0.5×10?3 to 2.0×10?3 mol/g. Functional group value (a)=(nH/MH)×PH??Formula (a) wherein nH represents the total number of hydroxyl groups and carboxy groups contained in one molecule of the (meth)acrylic monomer (H); MH represents the Mw of the (meth)acrylic monomer (H); and PH represents the mass ratio of the (meth)acrylic monomer (H) with respect to the total amount of the (meth)acrylic monomer component.Type: ApplicationFiled: October 4, 2016Publication date: October 4, 2018Applicant: MITSUI CHEMICALS, INC.Inventors: Toshikazu Sakamaki, Takashi Koura, Kouya Kojima, Hirohisa Shiode, Mai Kimura