Abstract: The invention relates to rubber compositions that are provided with polyorganosiloxanes as plasticizers. The rubber compositions can be vulcanized by means of a cross-linking resin and they are particularly suitable for use as curing bladders in the production of tires. The invention further relates to the use of polyorganosiloxanes as corresponding plasticizers.

Abstract: The present invention relates to aqueous binder compositions obtainable by emulsion polymerization of (A) at least one C1-C10 alkyl (meth)acrylate, and/or a vinylaromatic compound having up to 20 C atoms, or mixtures thereof (monomers A), (B) and also, if appropriate, further monomers B, and (C) at least one water-soluble alkyd resin having a weight-average molecular weight between 5000 and 40 000 Da, wherein the polymerization of the monomers A and also, if appropriate, B and the alkyds C is carried out in the form of a parallel feed process, and also to their preparation and use in coating materials.

Abstract: Coating compositions containing an aqueous polymer dispersion having improved resistance toward chemicals. The aqueous polymer dispersion is prepared by polymerizing a first composition containing at least one ethylenically unsaturated group (monomers) by radical aqueous emulsion polymerization and then, in the presence of a product mixture from the previous polymerization, polymerizing a second composition containing at least one ethylenically unsaturated group (monomers) by radical aqueous emulsion polymerization. The coating compositions are such that the difference between a glass transition temperature of a polymer prepared from the first polymerization and a glass transition temperature of a polymer prepared from the second polymerization is at least 50° C.

Abstract: The present invention relates to an aqueous binder composition comprising (a) at least one emulsion polymer comprising as monomer units a C1-C8 alkyl (meth)acrylate, a vinylaromatic compound having up to 20 carbon atoms or mixtures thereof, (b) at least one water-soluble alkyd resin having a weight-average molecular weight of between 5000 and 40 000 Da, and (c) at least one alkyd resin having a weight-average molecular weight of more than 100 000 Da in the form of an aqueous emulsion, wherein the solids content of the mixture of (a), (b), and (c) is less than 60% by weight, and also to their use and preparation.

Abstract: The invention relates to the use of polyorganosiloxanes having 3 or more siloxane units, which have one or more organic fractions R1, where R1 has one or more carbon-carbon multiple bonds and at least 4 carbon atoms, and wherein the presence of hydrocarbon fractions having a chain length of 5 to 50 carbon atoms is excluded, as additives in the processing of rubber. The polyorganosiloxanes are used in the processing and vulcanization of rubber in a quantity of 0.1 to 10 phr and incorporated by reaction in same. Said polyorganosiloxanes produce a reduction in the viscosity of the rubber during processing and optionally an improvement in the mechanical properties of the vulcanized rubber.

Abstract: Coating compositions containing an aqueous polymer dispersion having improved resistance toward chemicals. The aqueous polymer dispersion is prepared by polymerizing a first composition containing at least one ethylenically unsaturated group (monomers) by radical aqueous emulsion polymerization and then, in the presence of a product mixture from the previous polymerization, polymerizing a second composition containing at least one ethylenically unsaturated group (monomers) by radical aqueous emulsion polymerization. The coating compositions are such that the difference between a glass transition temperature of a polymer prepared from the first polymerization and a glass transition temperature of a polymer prepared from the second polymerization is at least 50° C.

Abstract: The invention relates to the use of polyorganosiloxanes having 3 or more siloxane units, which has (i) at least one organic component R1, where R1 has at least one carbon-carbon multiple bond, and (ii) at least one hydrocarbon component R2, where R2 has a chain length of 5 to 50 carbon atoms. The polyorganosiloxanes are used in the processing and vulcanization of rubber and are incorporated reactively into it. They give rise to a lowering in the viscosity of the rubber in the course of processing and in some cases to an improvement in the mechanical properties of the vulcanized rubber.

Abstract: The invention relates to the use of polyorganosiloxanes having 3 or more siloxane units, which have one or more organic fractions R1, where R1 has one or more carbon-carbon multiple bonds and at least 4 carbon atoms, and wherein the presence of hydrocarbon fractions having a chain length of 5 to 50 carbon atoms is excluded, as additives in the processing of rubber. The polyorganosiloxanes are used in the processing and vulcanisation of rubber in a quantity of 0.1 to 10 phr and incorporated by reaction in same. Said polyorganosiloxanes produce a reduction in the viscosity of the rubber during processing and optionally an improvement in the mechanical properties of the vulcanised rubber.

Abstract: Nitrous bridged derivatives of 6H-dibenz[c,e][1,2]-oxaphosphorine-6-oxides, process for the preparation and use thereof. The invention refers to nitrous bridged derivatives of 6H-dibenz[c,e][1,2]-oxaphosphorine-6-oxides, a process for the preparation thereof and their use as flameproofing agents for polymers such as polyesters, polyamides, polycarbonates, polystyrenes, polyethylene, polypropylene, phenolic and epoxy resins.

Abstract: The invention relates to the use of polyorganosiloxanes having 3 or more siloxane units, which has (i) at least one organic component R1, where R1 has at least one carbon-carbon multiple bond, and (ii) at least one hydrocarbon component R2, where R2 has a chain length of 5 to 50 carbon atoms. The polyorganosiloxanes are used in the processing and vulcanization of rubber and are incorporated reactively into it. They give rise to a lowering in the viscosity of the rubber in the course of processing and in some cases to an improvement in the mechanical properties of the vulcanized rubber.

Abstract: The present invention relates to aqueous binder compositions obtainable by emulsion polymerization of (A) at least one C1-C10 alkyl (meth)acrylate, and/or a vinylaromatic compound having up to 20 C atoms, or mixtures thereof (monomers A), (B) and also, if appropriate, further monomers B, and (C) at least one water-soluble alkyd resin having a weight-average molecular weight between 5000 and 40 000 Da, wherein the polymerization of the monomers A and also, if appropriate, B and the alkyds C is carried out in the form of a parallel feed process, and also to their preparation and use in coating materials.

Abstract: The invention refers to nitrous bridged derivatives of 6H-dibenz[c,e][1,2]-oxaphosphorine-6-oxides, a process for the preparation thereof and their use as flameproofing agents for polymers such as polyesters, polyamides, polycarbonates, polystyrenes, polyethylene, polypropylene, phenolic and epoxy resins.

Abstract: The present invention relates to an aqueous binder composition comprising (a) at least one emulsion polymer comprising as monomer units a C1-C8 alkyl (meth)acrylate, a vinylaromatic compound having up to 20 carbon atoms or mixtures thereof, (b) at least one water-soluble alkyd resin having a weight-average molecular weight of between 5000 and 40 000 Da, and (c) at least one alkyd resin having a weight-average molecular weight of more than 100 000 Da in the form of an aqueous emulsion, wherein the solids content of the mixture of (a), (b), and (c) is less than 60% by weight, and also to their use and preparation.

Abstract: Nitrous bridged derivatives of 6H-dibenz[c,e][1,2]-oxaphosphorine-6-oxides, process for the preparation and use thereof. The invention refers to nitrous bridged derivatives of 6H-dibenz[c,e][1,2]-oxaphosphorine-6-oxides, a process for the preparation thereof and their use as flameproofing agents for polymers such as polyesters, polyamides, polycarbonates, polystyrenes, polyethylene, polypropylene, phenolic and epoxy resins.

Abstract: A process is provided for the preparation of 9,10-dihydro-9-oxa-10-organyloxyphosphaphenanthrene-10-oxide or -thione and derivatives of same substituted on the phenyl groups, in which: (a) 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOP) or a derivative of same is reacted in the presence of at least one mono- or polyhydric alcohol with at least one ortho ester with formation of a first intermediate product, (b) the intermediate product from step (a) is optionally reacted with at least one further mono- or polyhydric alcohol with formation of a further intermediate product and (c) the intermediate product from steps (a) or (b) is transformed by addition of oxidation agent into 9,10-dihydro-9-oxa-10-organyloxyphosphaphenanthrene-10-oxide or -thione or a derivative of same substituted on the phenyl groups.

Abstract: A process is provided for the preparation of 9,10-dihydro-9-oxa-10-organylphosphaphenanthrene-10-oxide and derivatives of same substituted on the phenyl groups, in which: (a) 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOP) or a derivative of same is reacted in the presence of at least one mono- or polyhydric alcohol with at least one ortho ester with formation of a first intermediate product, (b) the intermediate product from step (a) is optionally reacted with at least one further mono- or polyhydric alcohol with formation of a further intermediate product and (c) the intermediate product from steps (a) or (b) is transformed by addition of catalytic quantities of alkylation agent into 9,10-dihydro-9-oxa-10-organylphosphaphenanthrene-10-oxide or a derivative of same substituted on the phenyl groups.

Abstract: A process is provided for the preparation of 9,10-dihydro-9-oxa-10-organylphosphaphenanthrene-10-oxide and derivatives of same substituted on the phenyl groups, in which: (a) 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOP) or a derivative of same is reacted in the presence of at least one mono- or polyhydric alcohol with at least one ortho ester with formation of a first intermediate product, (b) the intermediate product from step (a) is optionally reacted with at least one further mono- or polyhydric alcohol with formation of a further intermediate product and (c) the intermediate product from steps (a) or (b) is transformed by addition of catalytic quantities of alkylation agent into 9,10-dihydro-9-oxa-10-organylphosphaphenanthrene-10-oxide or a derivative of same substituted on the phenyl groups.

Abstract: A process is provided for the preparation of 9,10-dihydro-9-oxa-10-organyloxyphosphaphenanthrene-10-oxide or -thione and derivatives of same substituted on the phenyl groups, in which: (a) 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOP) or a derivative of same is reacted in the presence of at least one mono- or polyhydric alcohol with at least one ortho ester with formation of a first intermediate product, (b) the intermediate product from step (a) is optionally reacted with at least one further mono- or polyhydric alcohol with formation of a further intermediate product and (c) the intermediate product from steps (a) or (b) is transformed by addition of oxidation agent into 9,10-dihydro-9-oxa-10-organyloxyphosphaphenanthrene-10-oxide or -thione or a derivative of same substituted on the phenyl groups.

Abstract: Novel derivatives of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, processes for their preparation and the use of the derivatives for flame protection of natural products and plastics are disclosed.

Abstract: An aqueous polymer dispersion having a minimum film-forming temperature of below +65° C.