Patents by Inventor Volker Fraaije

Volker Fraaije has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20060160962
    Abstract: A process for polymerizing one or more alpha-olefins of formula CH2?CHT wherein T is a hydrogen atom or a C1-C20 alkyl radical comprising the following steps: a) contacting in a continuous way one or more of said alpha olefins with a metallocene based catalyst system in a loop reactor, wherein: (i) the reaction is carried out in a liquid medium; (ii) the average residence time of the metallocene-based catalyst system is not more than 30 minutes; (iii) the temperature of the loop ranges from 25° to 70° C.; in to obtain a polymerization degree ranging from 60 to 500 g per gram of catalyst system; b) feeding in continuous the prepolymerized metallocene-based catalyst system obtained in step a) into a polymerization reactor C) polymerizing one or more alpha-olefins, the same or different from the alpha olefins used in step a), in the presence of said prepolymerized metallocene-based catalyst system.
    Type: Application
    Filed: June 29, 2004
    Publication date: July 20, 2006
    Applicant: Basell Polyolefine GmbH
    Inventors: Maria Tonti, Markus Oberhoff, Volker Fraaije, Bernd Bachmann
  • Patent number: 7038070
    Abstract: A process for the preparation of indanones of the formula II from indanones of the formula I or of indanones of the formula IIa from indanones of the formula Ia comprises reacting an indanone of the formula I or Ia with a coupling component.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: May 2, 2006
    Assignee: Basell Polyolefine GmbH
    Inventors: Carsten Bingel, Markus Goeres, Volker Fraaije, Andreas Winter
  • Publication number: 20060058180
    Abstract: The present invention relates to a process for preparing a catalyst solid for olefin polymerization, comprising a finely divided support, an aluminoxane and a metallocene compound, which comprises a) firstly combining the finely divided support with the aluminoxane and subsequently b) adding the reaction product of a metallocene compound with at least one organometallic compound to the modified support, catalyst solids obtainable by this process, catalyst systems comprising these catalyst solids, their use for the polymerization of olefins and a process for the polymerization of olefins.
    Type: Application
    Filed: December 16, 2003
    Publication date: March 16, 2006
    Applicant: Basell Polyolefine GmbH
    Inventors: Heike Gregorius, Volker Fraaije, Manfred Lutringshauser
  • Publication number: 20060020096
    Abstract: A process for the polymerization of olefins, in particular a process for the copolymerization of propylene with further olefins, is carried out in the presence of highly active catalyst systems comprising specifically selected metallocenes, in particular ones which bear different substituents in position 2 position 4 on an indenyl ligand. Novel polypropylene copolymers can be obtained by this process.
    Type: Application
    Filed: May 18, 2005
    Publication date: January 26, 2006
    Inventors: Jorg Schottek, Markus Oberhoff, Carsten Bingel, David Fischer, Horst Weiss, Andreas Winter, Volker Fraaije, Ralph-Dieter Maier, Wolfgang Bidell, Nicola Paczkowski, Juergen Suhm, Roland Kratzer
  • Publication number: 20050272596
    Abstract: The present invention relates to a process for preparing a catalyst for olefin polymerization which is obtainable by bringing A) at least one organic transition metal compound, B) a mixture of at least two different organo metallic compounds and C) at least one cation-forming compound into contact with one another, wherein the organic transition metal compound A) is firstly brought into contact with the mixture of the organo metallic compounds B). In addition, the invention relates to the use of the catalyst for olefin polymerization, to catalysts obtainable by this process and to a process for the polymerization of olefins in which these catalysts are used.
    Type: Application
    Filed: July 14, 2003
    Publication date: December 8, 2005
    Applicant: BASELL POLYOLEFINE GMBH
    Inventors: Roland Kratzer, Volker Fraaije
  • Patent number: 6963017
    Abstract: A process for the preparation of indanones of the formula II from indanones of the formula I or of indanones of the formula IIa from indanones of the formula Ia comprises reacting an indanone of the formula I or Ia with a coupling component.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: November 8, 2005
    Assignee: Basell Polyolefine GmbH
    Inventors: Carsten Bingel, Markus Goeres, Volker Fraaije, Andreas Winter
  • Patent number: 6924248
    Abstract: Catalyst system for olefin polymerization comprising A) at least one calcined hydrotalcite, B) at least one organic transition metal compound, C) optionally one or more cation-forming compounds and D) at least one organic magnesium compound.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: August 2, 2005
    Assignee: Basell Polyolefine GmbH
    Inventors: Shahram Mihan, Markus Schopf, Joachim Wulff-Döring, Wolfgang Bidell, Volker Fraaije, Nicola Paczkowski, Markus Oberhoff
  • Publication number: 20050043170
    Abstract: A catalyst solid comprising: A) support particles having a mean particle diameter d50 of from 5 to 200 ?m and a specific surface area of from 30 to 1 000 m2/g and obtainable by agglomeration of primary particles of a pyrogenic silica having a mean particle diameter dm of from 1 to 50 nm, and B) at least one organic transition metal compound, can be used for the polymerization or copolymerization of olefins.
    Type: Application
    Filed: December 17, 2002
    Publication date: February 24, 2005
    Inventors: Volker Fraaije, Markus Oberhoff, Nicola Paczkowski, Heike Gregorius, Roland Kratzer, Wolfgang Bidell, Joachim Wulff-Doring
  • Publication number: 20050033076
    Abstract: A process for the preparation of indanones of the formula II from indanones of the formula I or of indanones of the formula IIa from indanones of the formula Ia comprises reacting an indanone of the formula I or Ia with a coupling component.
    Type: Application
    Filed: September 9, 2004
    Publication date: February 10, 2005
    Inventors: Carsten Bingel, Markus Goeres, Volker Fraaije, Andreas Winter
  • Patent number: 6759500
    Abstract: Propylene polymers containing from 0 to 2.5% by weight of C2-C10-olefin comonomers have an Mw of from 350,000 to 1,000,000 g/mol, an Mw/Mn of from 4 to 10, a proportion by weight of the polymer fraction having a viscosity number of from 500 to 1400 ml/g of from 20 to 80% of the total polymer and a proportion by weight of a polymer fraction having a viscosity number of from 200 to 400 ml/g of from 80 to 20% of the total polymer and an isotactic sequence length of from 50 to 100.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: July 6, 2004
    Assignee: Basell Polyolefine GmbH
    Inventors: Volker Dolle, Volker Fraaije, Herbert Terwyen, Thomas Boehm
  • Publication number: 20040033890
    Abstract: Catalyst system for olefin polymerization comprising
    Type: Application
    Filed: June 6, 2003
    Publication date: February 19, 2004
    Inventors: Shahram Mihan, Markus Schopf, Jiachim Wulff-Doring, Wolfgang Bidell, Volker Fraaije, Nicola Paczkowski, Markus Oberhoff
  • Publication number: 20030176275
    Abstract: Catalyst solid for olefin polymerization comprising
    Type: Application
    Filed: December 12, 2002
    Publication date: September 18, 2003
    Inventors: Volker Fraaije, Markus Oberhoff, Nicola (Hugsen) Paczkowski, Markus Schopf, Wolfgang Bidell, Joachim Wulff-Doring, Shahram Mihan
  • Publication number: 20030149199
    Abstract: A process for the polymerization of olefins, in particular a process for the copolymerization of propylene with further olefins, is carried out in the presence of highly active catalyst systems comprising specifically selected metallocenes, in particular ones which bear different substituents in position 2 and position 4 on an indenyl ligand. Novel polypropylene copolymers can be obtained by this process.
    Type: Application
    Filed: June 24, 2002
    Publication date: August 7, 2003
    Inventors: Jorg Schottek, Markus Oberhoff, Carsten Bingel, David Fischer, Horst Weiss, Andreas Winter, Volker Fraaije, Ralph-Dieter Maier, Wolfgang Bidell, Nicola Paczkowski, Jurgen Suhm, Roland Kratzer
  • Publication number: 20030009046
    Abstract: A process for the preparation of indanones of the formula II from indanones of the formula I or of indanones of the formula IIa from indanones of the formula Ia 1
    Type: Application
    Filed: July 22, 2002
    Publication date: January 9, 2003
    Inventors: Carsten Bingel, Markus Goeres, Volker Fraaije, Andreas Winter
  • Patent number: 6492539
    Abstract: a process for the preparation of indanones of the formula II from, indanones of the formula I or of indanones of the formula IIa from indanones of the formula Ia comprises reacting an indanone of the formula I or Ia with a coupling component.
    Type: Grant
    Filed: September 1, 1999
    Date of Patent: December 10, 2002
    Assignee: Basell Polypropylen GmbH
    Inventors: Carsten Bingel, Markus Goeres, Volker Fraaije, Andreas Winter
  • Patent number: 6469114
    Abstract: Disclosed are compounds of the following core structure, and their use as polymerization catalysts: wherein M1 is a group lVb transition metal, R5 is a substituted aryl group, and Ra forms a heteroatom-containing ring fused to the cyclopentadienyl ring.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: October 22, 2002
    Assignee: Basell Polyolefins GmbH
    Inventors: Jörg Schottek, Roland Kratzer, Andreas Winter, Volker Fraaije, Michael-Joachim Brekner, Markus Oberhoff
  • Patent number: 6444606
    Abstract: The invention relates to a catalyst system obtained by mixing at least one metallocene, at least one co-catalyst and at least one support which is rendered inert. The invention further relates to a method for producing a free flowing supported catalyst system wherein a) a metallocene/co-catalyst mixture is produced in a solvent or suspension agent, b) the metallocene/co-catalyst mixture is applied to a porous preferably inorganic dehydrated support, c) the solvent is removed from the resulting mixture, d) the supported catalyst system is isolated. The present invention also relates to homopolymers and/or copolymers having the preferred formula Rm—CH═CH—Rn for the monomer, wherein Rm and Rn are the same or different and mean a hydrogen atom or a group containing carbon with 1 to 10 C atoms, and Rm and Rn can form one or several rings with the binding atoms, which can be obtained with a catalyst system.
    Type: Grant
    Filed: February 10, 1999
    Date of Patent: September 3, 2002
    Assignee: Basell Polypropylen GmbH
    Inventors: Carsten Bingel, Markus Goeres, Volker Fraaije, Andreas Winter
  • Patent number: 6365763
    Abstract: The invention relates to a method for producing rac/meso metallocenes, the rac/meso metallocenes themselves, and their use in the production of polyolefins.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: April 2, 2002
    Assignee: Basell Polyolefin GmbH
    Inventors: Andreas Winter, Carsten Bingel, Volker Fraaije, Frank Kueber
  • Patent number: 6319874
    Abstract: A process for preparing rac/meso-metallocenes, the rac/meso-metallocenes themselves and the use of the rac/meso-metallocenes for preparing isotactic polyolefins are described.
    Type: Grant
    Filed: January 11, 2000
    Date of Patent: November 20, 2001
    Assignee: Basell Polyolefine GmbH
    Inventors: Andreas Winter, Carsten Bingel, Volker Fraaije, Frank Kueber
  • Patent number: 5990331
    Abstract: The present invention relates to a metallocene of the formula I, ##STR1## for preparing polyolefins, where M.sup.1 is preferably Zr, Hf or Ti, R.sup.1 and R.sup.2 are each a hydrogen atom, a C.sub.1 -C.sub.3 -alkyl group, a C.sub.1 -C.sub.3 -alkoxy group, a C.sub.6 -C.sub.8 -aryl group, a C.sub.6 -C.sub.8 -aryloxy group, a C.sub.2 -C.sub.4 -alkenyl group, a C.sub.7 -C.sub.10 -arylalkyl group, a C.sub.7 -C.sub.12 -alkylaryl group, a C.sub.8 -C.sub.12 -arylalkenyl group or chlorine, R.sup.3 is a chlorine atom, a C.sub.1 -C.sub.3 -alkyl group, a C.sub.2 -C.sub.4 -alkenyl group, a C.sub.6 -C.sub.8 -aryl group, an NR.sup.16.sub.2, SR.sup.16, OSiR.sup.16.sub.3, SiR.sup.16.sub.3 or PR.sup.16.sub.2 radical where R.sup.16 is chlorine, a C.sub.1 -C.sub.4 -alkyl group or a C.sub.6 -C.sub.8 -aryl group. R.sup.4 is a hydrogen atom, R.sup.13 is --(R.sup.14 M.sup.2 R.sup.15)--, --(R.sup.14 CR.sup.15)--(R.sup.14 CR.sup.15)--, --(R.sup.14 CR.sup.15)--(R.sup.14 M.sup.2 R.sup.15)-- or --(R.sup.14 CR.sup.15)--, where R.sup.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: November 23, 1999
    Assignee: Targor GmbH
    Inventors: Andreas Winter, Roland Zenk, Volker Fraaije, Frank Kuber