Abstract: A means for enhancing capacity performance and charge-discharge rate capability of an electric device uses a positive electrode active material containing sulfur. In the positive electrode material for an electric device, which contains a conductive material having pores, solid electrolyte, and a positive electrode active material containing sulfur, at least a part of the solid electrolyte and at least a part of the positive electrode active material are to be placed on the inner surface of the pores.

Abstract: A secondary battery has a battery body and a restraint. The battery body has a plurality of stacked power generation elements. The restraint restrains the battery body. The restraint has a first contact section (for applying a restraining force to an outermost layer surface (e.g., a negative electrode collector) of the battery body. The restraint is configured so that a stress occurring at a boundary of a non-contact region and a contact region of the first contact section is less than a breaking strength of the negative electrode collector, and the stress is based on the restraining force and on expansion and contraction of a negative electrode due to a change in volume of a negative electrode active material layer caused by charging and discharging.

Abstract: A secondary battery provides a means for inhibiting the growth of dendrite in a solid electrolyte layer while suppressing the decrease in ion conductivity in the solid electrolyte layer. In the secondary battery, which includes a power-generating element formed by laminating a positive electrode which contains a positive electrode active material, a solid electrolyte layer which contains a solid electrolyte, and a negative electrode which contains a negative electrode active material, a binder having a Young’s modulus of 200 [MPa] or lower is further contained in the solid electrolyte layer.

Abstract: A secondary battery has a battery body and a restraint. The battery body has a plurality of stacked power generation elements. The restraint restrains the battery body. The restraint has a first contact section (for applying a restraining force to an outermost layer surface (e.g., a negative electrode collector) of the battery body. The restraint is configured so that a stress occurring at a boundary of a non-contact region and a contact region of the first contact section is less than a breaking strength of the negative electrode collector, and the stress is based on the restraining force and on expansion and contraction of a negative electrode due to a change in volume of a negative electrode active material layer caused by charging and discharging.

Abstract: A secondary battery has a battery body and a restraint. The battery body has a plurality of stacked power generation elements. The restraint restrains the battery body. The restraint has a first contact section (for applying a restraining force to an outermost layer surface (e.g., a negative electrode collector) of the battery body. The restraint is configured so that a stress occurring at a boundary of a non-contact region and a contact region of the first contact section is less than a breaking strength of the negative electrode collector, and the stress is based on the restraining force and on expansion and contraction of a negative electrode due to a change in volume of a negative electrode active material layer caused by charging and discharging.

Abstract: Provided is a technique capable of further improving the cycle characteristics in a negative electrode for a non-aqueous electrolyte secondary battery in which a silicon-based negative electrode active material and a carbon-based negative electrode active material are used in combination as a negative electrode active material, and constituent components of the electrode are not bound to each other via a binder. The negative electrode for a non-aqueous electrolyte secondary battery according to the present invention has a configuration in which a negative electrode active material layer containing a negative electrode active material is formed on a surface of a current collector. The negative electrode active material contains composite secondary particles in which silicon-based negative electrode active material particles and carbon-based negative electrode active material particles are bound to each other via a binder.

Abstract: A method for producing a non-aqueous electrolyte secondary battery in which the internal resistance of the battery is decreased, and which has a high capacity and high cycle durability, is provided. A method for producing a non-aqueous electrolyte secondary battery that comprises a current collector and an electrode active material layer disposed on a surface of the current collector, the electrode active material layer comprising a non-bound body including an electrode active material, the method comprising a step of applying an electrode active material slurry including an electrode active material, a lithium salt, and a non-aqueous solvent on the surface of the current collector and thereby forming a coating film, wherein a water content of the electrode active material slurry is less than 500 ppm by mass.

Abstract: A secondary battery has a battery body and a restraint. The battery body has a plurality of stacked power generation elements. The restraint restrains the battery body. The restraint has a first contact section (for applying a restraining force to an outermost layer surface (e.g., a negative electrode collector) of the battery body. The restraint is configured so that a stress occurring at a boundary of a non-contact region and a contact region of the first contact section is less than a breaking strength of the negative electrode collector, and the stress is based on the restraining force and on expansion and contraction of a negative electrode due to a change in volume of a negative electrode active material layer caused by charging and discharging.

Abstract: To improve cycle durability in an electrical device such as a lithium ion secondary battery including a negative electrode containing a silicon-containing negative electrode active material, an electrical device includes a power generating element containing a unit cell layer. The unit cell contains a positive electrode in which a positive electrode active material layer containing a positive electrode active material is formed on a surface of a positive electrode current collector, a negative electrode in which a negative electrode active material layer containing a silicon-containing negative electrode active material is formed on a surface of a negative electrode current collector, and a separator. In the unit cell layer, the electrical device satisfies formula (1): 0.91?C/A<0.99 where the area of the negative electrode active material layer is A [m2] and the area of the positive electrode active material layer is C [m2].

Abstract: A method for producing a lithium ion secondary battery comprising the positive electrode active material of formula (1), Li(2-0.5x)Mn1-xM1.5xO3 (x satisfies 0<x<1) . . . (1) (M in the formula is a lithium-containing transition metal oxide expressed by NiaCobMncM1d (in which 0<a?0.5, 0?b?0.33, 0<c?0.5, and 0?d?0.1 are satisfied, the sum of a, b, c, and d becomes 1, and M1 in the formula is an element selected from Li, V, Al, Zr, Ti, Nb, Fe, Cu, Cr, Mg, and Zn)). The method comprises a step to repeat charge-discharge multiple times (charge-discharge interval), and comprises a step to discharge a at a lower current density than the current density during charge a, during the discharge of the multiple charges-discharges, or, a step to discharge b at a lower current density than the current density during charge a after the electromotive force is naturally recovered by idle b after each charge-discharge.

Abstract: A non-aqueous electrolyte secondary battery includes: a negative electrode active material represented by the Formula (1)=? (Si material)+? (carbon material), wherein the Si material is one or more kinds selected from the group consisting of SiOx that is a mixture of amorphous SiO2 particles and Si particles and a Si-containing alloy; ? and ? represent % by mass of each component in the layer; and 80??+??98, 0.1???40, and 58???97.9 are satisfied, and a difference between the maximum value and the minimum value of an area proportion (%) of a binder in an area of the field of view of each image of cross-sections of the layer in a case where a plurality of arbitrary places is selected in a plane of the negative electrode active material layer is within 10%.

Abstract: A non-aqueous electrolyte secondary battery includes a negative electrode active material represented by: ?(Si material)+?(carbon material), the Si material is one or more kinds selected from the group consisting of SiOx that is a mixture of amorphous SiO2 particles and Si particles and a Si-containing alloy; ? and ? represent % by mass; and 80??+??98, 0.1???40, and 58???97.9 are satisfied), and when area proportions (%) of the Si material and the carbon material in an area of a field of view of each image of cross-sections of the layer in a case where a plurality of arbitrary places is selected in a plane of the layer are designated as S (%) and (100?S) (%), respectively, a difference between a maximum value and a minimum value of S is within 5%.

Abstract: A non-aqueous electrolyte secondary battery includes: a negative electrode active material represented by the Formula (1)=? (Si material)+? (carbon material), wherein the Si material is one or more kinds selected from the group consisting of SiOx that is a mixture of amorphous SiO2 particles and Si particles and a Si-containing alloy; ? and ? represent % by mass of each component in the layer; and 80??+??98, 0.1???40, and 58???97.9 are satisfied, and a difference between the maximum value and the minimum value of an area proportion (%) of a binder in an area of the field of view of each image of cross-sections of the layer in a case where a plurality of arbitrary places is selected in a plane of the negative electrode active material layer is within 10%.

Abstract: A negative electrode active material for an electric device according to the present invention includes crystalline metal having a structure in which a size in a perpendicular direction to a crystal slip plane is 500 nm or less. More preferably, the size in the perpendicular direction to the crystal slip plane is controlled to become 100 nm or less. As described above, a thickness in an orientation of the slip plane is controlled to become sufficiently small, and accordingly, micronization of the crystalline metal is suppressed even if breakage occurs from the slip plane taken as a starting point. Hence, a deterioration of a cycle lifetime can be prevented by applying the negative electrode active material for an electric device, which is as described above, or a negative electrode using the same, to an electric device, for example, such as a lithium ion secondary battery.

Abstract: To provide a means capable of further improving cycle durability in an electrical device such as a lithium ion secondary battery containing a positive electrode using a solid solution positive electrode active material. An electrical device has a power generating element containing a positive electrode in which a positive electrode active material layer containing a positive electrode active material is formed on a surface of a positive electrode current collector, a negative electrode in which a negative electrode active material layer containing a negative electrode active material is formed on a surface of a negative electrode current collector, and a separator impregnated with an electrolytic solution. The negative electrode active material layer contains a negative electrode active material represented by formula (1). The positive electrode active material layer contains a positive electrode active material (solid solution positive electrode active material) represented by formula (2).

Abstract: A control device for a secondary battery using positive electrode active material made of solid solution material, comprising: a voltage detecting unit configured to detect an actual open circuit voltage value; an SOC detecting unit configured to detect an actual state of charge value on a basis of the actual open circuit voltage value and/or an actual current value; a memory unit configured to store a voltage-SOC standard control curve which shows a relation between an open circuit voltage value and a state of charge value; a presumed voltage calculating unit configured to calculate a presumed voltage value on the basis of the actual state of charge value and the voltage-SOC standard control curve stored in the memory unit; a determining unit configured to determine sameness between the actual voltage value detected by the voltage detecting unit and the presumed voltage value calculated by the presumed voltage calculating unit.

Abstract: A non-aqueous electrolyte secondary cell has reduced degradation of the electrolytic solution or the anode active material and high cycle durability. The non-aqueous electrolyte secondary cell includes: a cathode capable of doping and de-doping lithium ions; an anode capable of occluding and releasing lithium ions, lithium or a lithium alloy; and an electrolytic solution containing an organic solvent, a lithium salt electrolyte and an additive. The cathode active material of the cathode contains a layered lithium-containing transition metal oxide of formula Li1.5[NiaCobMnc[Li]d]O3, where a, b, c, and d satisfy 0<a<1.4, 0?b<1.4, 0<c<1.4, 0<d?0.5, a+b+c+d=1.5, and 1.0?a+b+c<1.5. The anode active material contains a carbon-based material with the surface fully or partly covered with a coating derived from the additive.

Abstract: An electrolytic solution for lithium ion secondary batteries contains: a lithium salt electrolyte; an organic solvent; and an aliphatic compound having three or more carboxylic acid groups in a molecule. A lithium ion secondary battery includes: a cathode including a cathode active material that is capable of absorbing and releasing lithium and contains manganese (Mn) as a major transit metal species; an anode; and a non-aqueous electrolytic solution. The electrolytic solution is the above-described solution. The aliphatic compound has a molecular weight within the range from 50,000 to 500,000.

Abstract: To provide a means capable of further improving cycle durability in an electrical device such as a lithium ion secondary battery containing a positive electrode using a solid solution positive electrode active material. An electrical device has a power generating element containing a positive electrode in which a positive electrode active material layer containing a positive electrode active material is formed on a surface of a positive electrode current collector, a negative electrode in which a negative electrode active material layer containing a negative electrode active material is formed on a surface of a negative electrode current collector, and a separator impregnated with an electrolytic solution. The negative electrode active material layer contains a negative electrode active material represented by formula (1). The positive electrode active material layer contains a positive electrode active material (solid solution positive electrode active material) represented by formula (2).

Abstract: To provide a means for further improving cycle durability in an electrical device such as a lithium ion secondary battery including a negative electrode containing a silicon-containing negative electrode active material. An electrical device has a power generating element including a unit cell layer containing a positive electrode in which a positive electrode active material layer containing a positive electrode active material is formed on the surface of a positive electrode current collector, a negative electrode in which a negative electrode active material layer containing a silicon-containing negative electrode active material is formed on the surface of a negative electrode current collector, and a separator. The electrical device is configured such that the one or more unit cell layers constituting the power generating element satisfy formula (1): 0.