Abstract: The composition includes a polysiloxane having at least one of a phosphate or phosphonate group and an amino-functional compound having at least one silane group. The method includes treating the metal surface with a composition including a polysiloxane functionalized with at least one of a phosphate or phosphonate group. The method can include first treating the metal surface with a primer composition including an amino-functional compound having at least one silane group or including an amino-functional compound having at least one silane group in the composition with the polysiloxane. Certain polysiloxanes functionalized with at least one of a phosphate or phosphonate group are also described.

Abstract: The present disclosure relates to a protective coating composition for a hard surface, wherein the composition comprises an organic solvent and a polysiloxane having the general formula (I), wherein: R1, R2, R3, R4, R5, R6, R7 and R8 are independently an alkyl group having from 1 to 8 carbon atoms; Y and Z are independently a divalent linking group selected from the group consisting of urea, urethane, oxygen atom, sulfur atom and alkylene having from 1 to 8 carbon atoms; A, B, L and M are independently a divalent slinking group selected from the group consisting of alkylene having from 1 to 8 carbon atoms, with the proviso that if the combined linking groups formed by -A-Y-L- and -M-Z—B— are independently an alkylene, then the alkylene is independently different from ethylene; n is an integer from 5 to 1500; and m and p are independently an integer from 1 to 3. In another aspect, the present disclosure is directed to a method of reducing contamination from a hard surface.

Abstract: A method is disclosed that includes contacting a hydrocarbon-bearing formation with a treatment composition comprising solvent and a fluorinated polymer. The fluorinated polymer includes: a first divalent unit represented by formula (I): wherein Rf represents a fluoroalkyl group having from 1 to 8 carbon atoms; each R1 is independently hydrogen or methyl; Q is a bond or —SO2—N(R)—, wherein R is alkyl having from 1 to 4 carbon atoms; and m is an integer from 1 to 11, a second divalent unit comprising a poly(alkyleneoxy) group; and a third divalent unit comprising a pendant ionic group. The solvent includes not more than ten percent by weight methanol and not more than 25 percent by weight water, based on the total weight of the solvent, and/or the solvent solubilizes or displaces brine in the hydrocarbon-bearing formation. Treated hydrocarbon-bearing formations are also disclosed.

Abstract: A composition is disclosed that includes fluorinated polymer and a non-fluorinated polymer. The fluorinated polymer includes first divalent units independently represented by formula and second divalent unit independently comprising a pendent cationic, anionic, amphoteric, or amine-oxide group or a pendent poly(alkyleneoxy) segment. The non-fluorinated polymer is R2O-(EO)p—(R3O)q-(EO)p—R2 or R2O—(R3O)q-(EO)p—(R3O)q—R2. A method of making the composition and methods of reducing the surface tension of a liquid and a method of treating a hydrocarbon-bearing formation are also disclosed.

Abstract: A method is disclosed that includes contacting a hydrocarbon-bearing formation with a treatment composition comprising solvent and a fluorinated polymer. The fluorinated polymer includes: a first divalent unit represented by formula (I): wherein Rf represents a fluoroalkyl group having from 1 to 8 carbon atoms; each R1 is independently hydrogen or methyl; Q is a bond or —SO2—N(R)—, wherein R is alkyl having from 1 to 4 carbon atoms; and m is an integer from 1 to 11, a second divalent unit comprising a poly(alkyleneoxy) group; and a third divalent unit comprising a pendant ionic group. The solvent includes not more than ten percent by weight methanol and not more than 25 percent by weight water, based on the total weight of the solvent, and/or the solvent solubilizes or displaces brine in the hydrocarbon-bearing formation. Treated hydrocarbon-bearing formations are also disclosed.

Abstract: A polyurethane polymer, a synthetic leather including such polymer, and a method of making such polymer, wherein the polyurethane polymer includes the reaction product of components including: a fluorinated mono-functional alcohol comprising a perfluorinated (C4-C6)alkyl group, a perfluorinated (C4-C6)alkylene group, or both; a fluorinated aliphatic diol comprising a perfluorinated (C4-C6)alkyl group, a perfluorinated (C4-C6)alkylene group, or both; a hydrocarbon diol; and a diisocyanate; wherein at least one of the following conditions is met: the total of the fluorinated aliphatic diol and the mono-functional alcohol is less than 2 wt-% of the components forming the polyurethane polymer; or the total fluorine content is less than 1 wt-% of the polyurethane polymer.

Abstract: A surface having dust particles thereon and a coating on the surface comprising a coating polymer having a Tg less than ?20° C. A method of reducing dust, the method including providing a surface having dust particles thereon and coating the surface with a coating polymer with a Tg less than ?20° C.

Abstract: A composition and method of treating substrates, in particular substrates having a hard surface such as ceramics, metal or glass, to render them water, oil, stain, and dirt repellent is described.

Abstract: Particles, including proppants, comprising a fluorinated siloxane. The particles are useful as proppants in fractured a subterranean geological formation comprising hydrocarbons.

Abstract: A surface having dust particles thereon and a coating on the surface comprising a coating polymer having a Tg less than ?20° C. A method of reducing dust, the method including providing a surface having dust particles thereon and coating the surface with a coating polymer with a Tg less than ?20° C.

Abstract: A method of forming an easy-to-clean metal or metallized substrate, the method comprising forming a layer comprising silicon, oxygen, and hydrogen on at least a portion of a surface of the substrate by plasma deposition; and applying an at least partially fluorinated composition comprising at least one silane group to at least a portion of a surface of the layer comprising the silicon, oxygen, and hydrogen; and an easy-to-clean article made by the method are disclosed.

Abstract: A method of treating a hydrocarbon-bearing formation that includes receiving data comprising a temperature and a brine composition of the hydrocarbon-bearing formation; selecting a treatment composition for the hydrocarbon-bearing formation comprising a fluorinated compound and solvent, wherein, at the temperature, a mixture of an amount of the brine composition and the treatment composition separates into at least two separate transparent liquid layers, and wherein the mixture is free of precipitated solid; and contacting the hydrocarbon-bearing formation with the treatment composition. Compositions containing certain fluorinated polymers and solvents containing water, monohydroxy alcohols, and ketones are also disclosed.

Abstract: The present application is directed to an article comprising a dusty surface and a coating on the dusty surface comprising a coating polymer having a Tg less ?20° C. and a method of reducing dust. In some embodiments, the polymer has a Tg less than ?30° C., and in specific embodiments, the polymer has a Tg less than ?45° C. The dusty surface may be, for example, crushed stone, coal, iron ore, gravel, sand or other aggregates (e.g. a roofing granule,) or a soil surface. Generally, the coating polymer comprises a polyacrylate, polyurethane, synthetic and natural rubber, silicone and other organic polymers. In specific embodiments, the coating polymer comprises an acrylic emulsion polymer.

Abstract: A chemical composition comprises one or more urethane oligomers of at least two polymerized units selected from the group consisting of fluorine-containing urethane oligomers and long-chain hydrocarbon-containing urethane oligomers, wherein said oligomers comprise the reaction product of (a) one or more polyfunctional isocyanate compounds, (b) one or more polyols, (c) one or more monoalcohols selected from the group consisting of fluorocarbon monoalcohols, optionally substituted long-chain hydrocarbon monoalcohols, and mixtures thereof, (d) one or more silanes, and (e) one or more stabilizers comprising one or more reactive groups.

Abstract: A composition and method of treating substrates, in particular substrates having a hard surface such as ceramics, metal or glass, to render them water, oil, stain, and dirt repellent is described.

Abstract: A method of forming an easy-to-clean metal or metallized substrate, the method comprising forming a layer comprising silicon, oxygen, and hydrogen on at least a portion of a surface of the substrate by plasma deposition; and applying an at least partially fluorinated composition comprising at least one silane group to at least a portion of a surface of the layer comprising the silicon, oxygen, and hydrogen; and an easy-to-clean article made by the method are disclosed.

Abstract: Method of treating proppant particles present in a fractured subterranean geological formation comprising hydrocarbons in-situ with fluorinated silane.

Abstract: The present application is directed to an article comprising a dusty surface and a coating on the dusty surface comprising a coating polymer having a Tg less ?20° C. and a method of reducing dust. In some embodiments, the polymer has a Tg less than ?30° C., and in specific embodiments, the polymer has a Tg less than ?45° C. The dusty surface may be, for example, crushed stone, coal, iron ore, gravel, sand or other aggregates (e.g. a roofing granule,) or a soil surface. Generally, the coating polymer comprises a polyacrylate, polyurethane, synthetic and natural rubber, silicone and other organic polymers. In specific embodiments, the coating polymer comprises an acrylic emulsion polymer.

Abstract: Fluorochemical silane compounds and coating compositions derived therefrom are described. The compounds and compositions may be used in treating substrates, in particular substrates having a hard surface such as ceramics or glass, to render them water, oil, stain, and soil repellent.

Abstract: An easy-to-clean article with a stainless steel surface treated with a mixture of a fluorinated composition and a first compound. The fluorinated composition comprises a polyfluoropolyether group and a hydrolysable silane group. The first compound comprises an amino group, an epoxy group, or a mercapto group and a hydrolysable silane group. A method of treating a stainless steel surface with the mixture is also disclosed.