Patents by Inventor Wolfgang Grabarse
Wolfgang Grabarse has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 11912950Abstract: The invention relates to the use of quaternized nitrogen compounds as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems; the invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.Type: GrantFiled: August 4, 2021Date of Patent: February 27, 2024Assignee: BASF SEInventors: Markus Hansch, Harald Boehnke, Wolfgang Grabarse, Ludwig Voelkel, Maxim Peretolchin
-
Patent number: 11879108Abstract: The present invention relates to a middle-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer mix comprising the ethylene and the acrylate is polymerized at a pressure of 50 to 400 bar and in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to a liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.Type: GrantFiled: March 23, 2020Date of Patent: January 23, 2024Assignee: BASF SEInventors: Ivette Garcia Castro, Wolfgang Grabarse, Jan Strittmatter, Rene Koschabek, Robert Rupaner
-
Publication number: 20230406968Abstract: A process for the preparation of polyisobutene derivatives involves bringing an oxygen-containing gas in contact with polyisobutene, in the presence of a photosensitizer, and irradiating the reaction mixture. The polyisobutene derivatives are useful, for example, in hydrocarbon mixtures or hydrocarbon-containing oils.Type: ApplicationFiled: November 9, 2021Publication date: December 21, 2023Applicant: BASF SEInventors: Bernd Schaefer, Klaus Muehlbach, Paul Lederhose, Wolfgang Grabarse, Andreas Minke, Thorsten Schoeppe
-
Patent number: 11667864Abstract: Lubricants with a terpolymer made of diester, olefin and acrylate The invention relates to a lubricant comprising a terpolymer which comprises in polymerized forma diester selected from di(C4-C22 alkyl)ester of maleic acid, fumaric acid, 2-methylmaleic acid, 2,3-dimethylmaleic acid, 2-methylfumaric acid, 2,3-dimethylfumaric acid, or mixtures thereof, an olefin selected from C6-C40 alky-1-ene, and an acrylate selected from C4-C40 alkyl (meth)acrylate. The invention further relates to the terpolymer, a process for preparing the terpolymer comprising the step of polymerizing the diester, the olefin, and the acrylate; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the terpolymer.Type: GrantFiled: October 8, 2019Date of Patent: June 6, 2023Assignee: BASF SEInventors: Ivette Garcia Castro, Wolfgang Grabarse, Jan Strittmatter, Markus Scherer, Karolin Monz, Rene Koschabek
-
Patent number: 11634654Abstract: An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems; for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.Type: GrantFiled: March 25, 2021Date of Patent: April 25, 2023Assignee: BASF SEInventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
-
Patent number: 11608393Abstract: The present invention relates to a continuous high-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized for methylene; and a reactive acrylate which is selected from hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, and hydroxybutyl (meth)acrylate, where a monomer feed comprising the ethylene and the reactive acrylate is polymerized in the presence of at least 2 wt % of a chain transfer agent. The present invention also relates to the liquid ethylene copolymer, to a coating material comprising the liquid ethylene copolymer and to a use of the liquid ethylene copolymer to produce a coating material.Type: GrantFiled: July 17, 2019Date of Patent: March 21, 2023Assignee: BASF SEInventors: Ivette Garcia Castro, Wolfgang Grabarse, Werner-Alfons Jung
-
Patent number: 11498986Abstract: The present invention relates to a continuous high-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer feed comprising the ethylene and the acrylate is polymerized in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to the liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.Type: GrantFiled: March 14, 2019Date of Patent: November 15, 2022Assignee: BASF SEInventors: Martin Wendker, Ivette Garcia Castro, Jan Strittmatter, Karolin Geyer, Wolfgang Grabarse, Markus Scherer, Rene Koschabek
-
Patent number: 11453836Abstract: The present invention relates to a lubricant comprising a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate. It further relates to the liquid ethylene copolymer; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.Type: GrantFiled: March 14, 2019Date of Patent: September 27, 2022Assignee: BASF SEInventors: Martin Wendker, Ivette Garcia Castro, Jan Strittmatter, Karolin Geyer, Wolfgang Grabarse, Markus Scherer, Rene Koschabek
-
Publication number: 20220177799Abstract: The present invention relates to a middle-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer mix comprising the ethylene and the acrylate is polymerized at a pressure of 50 to 400 bar and in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to a liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.Type: ApplicationFiled: March 23, 2020Publication date: June 9, 2022Inventors: Ivette GARCIA CASTRO, Wolfgang GRABARSE, Jan STRITTMATTER, Rene KOSCHABEK, Robert RUPANER
-
Patent number: 11214752Abstract: The present invention is directed to the use of poly(polyisobutylenemethacrylate) as viscosity index improving component in lubricating oil compositions. The invention is further related to lubricating oil compositions comprising poly(polyisobutylenemethacrylate) with enhanced shear stability.Type: GrantFiled: July 19, 2018Date of Patent: January 4, 2022Assignee: BASF SEInventors: Szilard Csihony, Anja Thomas, Kevin J. Desantis, Philippe Rabbat, Andrea Misske, Johannes Barth, Meik Ranft, Peter Mueller, Wolfgang Grabarse, Christoph Fleckenstein
-
Publication number: 20210363451Abstract: The invention relates to the use of quaternized nitrogen compounds as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems; the invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.Type: ApplicationFiled: August 4, 2021Publication date: November 25, 2021Applicant: BASF SEInventors: Markus Hansch, Harald Boehnke, Wolfgang Grabarse, Ludwig Voelkel, Maxim Peretolchin
-
Publication number: 20210348079Abstract: Lubricants with a terpolymer made of diester, olefin and acrylate The invention relates to a lubricant comprising a terpolymer which comprises in polymerized forma diester selected from di(C4-C22 alkyl)ester of maleic acid, fumaric acid, 2-methylmaleic acid, 2,3-dimethylmaleic acid, 2-methylfumaric acid, 2,3-dimethylfumaric acid, or mixtures thereof, an olefin selected from C6-C40 alky-1-ene, and an acrylate selected from C4-C40 alkyl (meth)acrylate. The invention further relates to the terpolymer, a process for preparing the terpolymer comprising the step of polymerizing the diester, the olefin, and the acrylate; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the terpolymer.Type: ApplicationFiled: October 8, 2019Publication date: November 11, 2021Inventors: Ivette GARCIA CASTRO, Wolfgang GRABARSE, Jan STRITTMATTER, Markus SCHERER, Karolin MONZ, Rene KOSCHABEK
-
Patent number: 11168273Abstract: The present invention relates to the use of an olefin-carboxylic acid copolymer, wherein the copolymer comprises at least one free carboxylic acid side group, or of a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, wherein the copolymer comprises at least one free carboxylic acid side group, as a fuel additive or lubricant additive; to processes for preparing additives of this kind, and to fuels and lubricants additized therewith; such as, more particularly, as a detergent additive; for reduction or prevention of deposits in the injection systems of direct injection diesel engines, especially in common rail injection systems, for reduction of the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operationType: GrantFiled: December 4, 2014Date of Patent: November 9, 2021Assignee: BASF SEInventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
-
Publication number: 20210301047Abstract: The present invention relates to a continuous high-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized for methylene; and a reactive acrylate which is selected from hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, and hydroxybutyl (meth)acrylate, where a monomer feed comprising the ethylene and the reactive acrylate is polymerized in the presence of at least 2 wt % of a chain transfer agent. The present invention also relates to the liquid ethylene copolymer, to a coating material comprising the liquid ethylene copolymer and to a use of the liquid ethylene copolymer to produce a coating material.Type: ApplicationFiled: July 17, 2019Publication date: September 30, 2021Inventors: Ivette Garcia Castro, Wolfgang Grabarse, Werner-Alfons Jung
-
Patent number: 11111449Abstract: The invention relates to the use of quaternized nitrogen compounds as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems; the invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.Type: GrantFiled: April 28, 2020Date of Patent: September 7, 2021Assignee: BASF SEInventors: Markus Hansch, Harald Boehnke, Wolfgang Grabarse, Ludwig Voelkel, Maxim Peretolchin
-
Publication number: 20210246395Abstract: The present invention relates to a lubricant comprising a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate. It further relates to the liquid ethylene copolymer; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.Type: ApplicationFiled: March 14, 2019Publication date: August 12, 2021Inventors: Martin WENDKER, Ivette GARCIA CASTRO, Jan STRITTMATTER, Karolin GEYER, Wolfgang GRABARSE, Markus SCHERER, Rene KOSCHABEK
-
Publication number: 20210222080Abstract: An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems; for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.Type: ApplicationFiled: March 25, 2021Publication date: July 22, 2021Applicant: BASF SEInventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
-
Publication number: 20210214635Abstract: An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems: for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.Type: ApplicationFiled: March 25, 2021Publication date: July 15, 2021Applicant: BASF SEInventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
-
Publication number: 20210198590Abstract: A lubricant comprising 2,5-(bishydroxymethyl) tetryhydrofuran dialkanoates This invention relates to a lubricant comprising a THF ester of the formula (I) as defined below. This invention further relates to a use of the THF ester as lubricant; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the THF ester.Type: ApplicationFiled: May 13, 2019Publication date: July 1, 2021Inventors: Martin Alexander BOHN, Karolin GEYER, Wolfgang GRABARSE, Markus SCHERER, Muriel ECORMIER, Jan STRITTMATTER
-
Publication number: 20210147759Abstract: The present invention is directed to the use of poly(polyisobutylenemethacrylate) as viscosity index improving component in lubricating oil compositions. The invention is further related to lubricating oil compositions comprising poly(polyisobutylenemethacrylate) with enhanced shear stability.Type: ApplicationFiled: July 19, 2018Publication date: May 20, 2021Inventors: Szilard CSIHONY, Anja THOMAS, Kevin J. DESANTIS, Philippe RABBAT, Andrea MISSKE, Johannes BARTH, Meik RANFT, Peter MUELLER, Wolfgang GRABARSE, Christoph FLECKENSTEIN