Patents by Inventor Yukio Tatsumi
Yukio Tatsumi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 9255237Abstract: The purpose of the present invention is to provide a thiodicarboxylic acid ester which has high long-term storage stability without inhibiting antioxidant properties and wear-resistant properties of the thiodicarboxylic acid ester. In order to achieve the above-mentioned purpose, the present invention provides a lubricating oil additive composition which is characterized by containing a compound (A) represented by general formula (1) and a compound (B) represented by general formula (2) and by having an acid value of 0.01-0.4 mgKOH/g. (in the formula, R1 and R4 each independently represent a hydrocarbon group having 6 to 18 carbon atoms and R2 and R3 each independently represent an alkylene group having 1 to 4 carbon atoms) (in the formula, R5 represents a hydrocarbon group having 6 to 18 carbon atoms and R6 and R7 each independently represent an alkylene group having 1 to 4 carbon atoms).Type: GrantFiled: April 24, 2012Date of Patent: February 9, 2016Assignee: ADEKA CORPORATIONInventors: Yukio Tatsumi, Yukiya Moriizumi, Shinji Iino
-
Patent number: 8722597Abstract: Provided is a lubricating oil composition for an internal combustion engine, including as essential components the following component (A), component (B), and component (C), in which a phosphorus content of the composition is 50 ppm by mass to 1,000 ppm by mass: Component (A): a base oil; Component (B): a compound represented by the following general formula (1); and Component (C): a metal-containing antioxidant: where R1 to R8 each independently represent a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, Z represents a hydrocarbon group having 2 to 20 carbon atoms, and n represents a number of 1 to 10.Type: GrantFiled: May 18, 2011Date of Patent: May 13, 2014Assignee: Adeka CorporationInventors: Yukio Tatsumi, Kenji Yamamoto
-
Publication number: 20140045738Abstract: The purpose of the present invention is to provide a thiodicarboxylic acid ester which has high long-term storage stability without inhibiting antioxidant properties and wear-resistant properties of the thiodicarboxylic acid ester. In order to achieve the above-mentioned purpose, the present invention provides a lubricating oil additive composition which is characterized by containing a compound (A) represented by general formula (1) and a compound (B) represented by general formula (2) and by having an acid value of 0.01-0.4 mgKOH/g. (in the formula, R1 and R4 each independently represent a hydrocarbon group having 6 to 18 carbon atoms and R2 and R3 each independently represent an alkylene group having 1 to 4 carbon atoms) (in the formula, R5 represents a hydrocarbon group having 6 to 18 carbon atoms and R6 and R7 each independently represent an alkylene group having 1 to 4 carbon atoms).Type: ApplicationFiled: April 24, 2012Publication date: February 13, 2014Applicant: ADEKA CORPORATIONInventors: Yukio Tatsumi, Yukiya Moriizumi, Shinji Iino
-
Publication number: 20130012418Abstract: Provided is a lubricating oil composition for an internal combustion engine, including as essential components the following component (A), component (B), and component (C), in which a phosphorus content of the composition is 50 ppm by mass to 1,000 ppm by mass: Component (A): a base oil; Component (B): a compound represented by the following general formula (1); and Component (C): a metal-containing antioxidant: where R1 to R8 each independently represent a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, Z represents a hydrocarbon group having 2 to 20 carbon atoms, and n represents a number of 1 to 10.Type: ApplicationFiled: May 18, 2011Publication date: January 10, 2013Inventors: Yukio Tatsumi, Kenji Yamamoto
-
Patent number: 8071801Abstract: Provided is a phosphorus molybdenum amine compound, represented by the following general formula (I). where R1 to R6 each independently represent a hydrogen atom or a hydrocarbon group and p represents a number of 1 to 5, provided that all of R1 to R6 are can not all be hydrogen atoms at the same time and the phosphorus molybdenum compound is obtained by reducing a hexavalent molybdenum compound with a reducing agent, and then reacting the resulting with an acidic phosphate after neutralization with a mineral acid.Type: GrantFiled: July 3, 2007Date of Patent: December 6, 2011Assignee: Adeka CorporationInventors: Yukio Tatsumi, Kazuhiro Umehara, Kenji Yamamoto
-
Patent number: 8012916Abstract: A lubricating oil additive capable of providing an antioxidant which enables a lubricating oil composition to have long drain intervals, while reducing specific components such as metals and phosphorus atoms, and a lubricating oil composition containing the lubricating oil additive are provided. A phosphorus molybdenum compound represented by the following general formula (1) where R1, R2, and R3 each independently represent a hydrocarbon group having 1 to 20 carbon atoms is also provided.Type: GrantFiled: October 26, 2007Date of Patent: September 6, 2011Assignee: Adeka CorporationInventors: Yukiya Moriizumi, Kazuhiro Umehara, Yukio Tatsumi
-
Publication number: 20090270289Abstract: A lubricating oil additive capable of providing an antioxidant which enables a lubricating oil composition to have long drain intervals, while reducing specific components such as metals and phosphorus atoms, and a lubricating oil composition containing the lubricating oil additive are provided. A phosphorus molybdenum compound represented by the following general formula (1) where R1, R2, and R3 each independently represent a hydrocarbon group having 1 to 20 carbon atoms is also provided.Type: ApplicationFiled: October 26, 2007Publication date: October 29, 2009Inventors: Yukiya Moriizumi, Kazuhiro Umehara, Yukio Tatsumi
-
Publication number: 20090192062Abstract: Provided is a phosphorus molybdenum amine compound, represented by the following general formula (1). where R1 to R6 each independently represent a hydrogen atom or a hydrocarbon group and p represents a number of 1 to 5, provided that all of R1 to R6 are can not all be hydrogen atoms at the same time and the phosphorus molybdenum compound is obtained by reducing a hexavalent molybdenum compound with a reducing agent, and then reacting the resulting with an acidic phosphate after neutralization with a mineral acid.Type: ApplicationFiled: July 3, 2007Publication date: July 30, 2009Inventors: Yukio Tatsumi, Kazuhiro Umehara, Kenji Yamamoto
-
Patent number: 6465399Abstract: The present invention is a lubricant composition, composed of a lubricant base oil containing: a (poly)glyceryl ether represented by the following general formula (1) (wherein R1 represents a hydrocarbon group and n represents a numeral being 1 or more.), as a (A) component; and an alkaline-earth metal salt of an organic acid as a (B) component. Furthermore, it is preferable to contain an antioxidant as a (C) component. As an alkaline-earth metal salt of an organic acid, sulfonate, phenate, or salicylate are preferable, and neutral, basic or overbased calcium salicylate or calcium sulfonate are particularly preferable.Type: GrantFiled: January 30, 2001Date of Patent: October 15, 2002Assignee: Asahi Denka Koygo Kabushiki KaishaInventors: Naomi Koishikawa, Yukio Tatsumi
-
Patent number: 6379581Abstract: A lubricant for use in a refrigerator which operates with a chlorine-free Flon (fluorocarbon)-type refrigerant whose molecules do not contain chlorine. The lubricant contains a synthetic oil, and molybdenumoxysulfide diorganophosphorodithioate given by the following formula (1) and/or molybdenumoxysulfide diorganodithiocarbamate given by the following formula (2), the content of the compounds of formulae (1) and (2) in total ranges from 0.1 to 10 wt % to the content of the synthetic oil: {(RO)2PS2}2Mo2SXOY (1) where R represents a hydrocarbon group having 3 to 20 carbon atoms, and X and Y are numbers which meet the conditions of O≦X≦4, 0≦Y≦4 and X+Y=4; and (R′2NCS2)2Mo2SX′OY′ (2) where R′ is a hydrocarbon group having 3 to 20 carbon atoms and X′ and Y′ are numbers which meet the conditions of )≦X′≦4, 0≦Y′≦4 and X′+Y′=4.Type: GrantFiled: February 28, 1995Date of Patent: April 30, 2002Assignee: Asahi Denka Kogyo, K.K.Inventors: Tamiji Kamakura, Noriyoshi Tanaka, Kimiyoshi Namiwa, Yukio Tatsumi, Masato Namiki
-
Publication number: 20010012821Abstract: The present invention is a lubricant composition, composed of a lubricant base oil containing: a (poly)glyceryl ether represented by the following general formula (1) 1Type: ApplicationFiled: January 30, 2001Publication date: August 9, 2001Inventors: Naomi Koishikawa, Yukio Tatsumi
-
Patent number: 6245725Abstract: There is provided a lubricating composition including a lubricating base containing an asymmetric sulfurized oxymolybdenum dithiocarbamate of the formula (1); a symmetric sulfurized oxymolybdenum dithiocarbamate of the formula (2); and a phenolic or aminic antioxidant. (wherein R1 to R5 are each a hydrocarbon group, provided that R1 to R4 are not concurrently the same group; and X1 to X8 are each a sulfur atom or an oxygen atom.) This lubricating composition meets both the required solubility of additives in base oils and long drain properties concurrently.Type: GrantFiled: December 20, 1999Date of Patent: June 12, 2001Assignee: Asahi Denka Kogyo K.K.Inventors: Noriyoshi Tanaka, Yukio Tatsumi, Yoko Saito, Atsuo Miyashita
-
Patent number: 6217791Abstract: The object of the present invention is to provide a lubricant for refrigerators having good compatibility with chlorine-free Flon-type coolants, good lubricity and resistant to hygroscopicity and a composition for refrigerators using this lubricant. This lubricant contains a monomethylether of polyoxyethyleneoxypropyleneglycol where the end group at the hydrogen terminal is an oxyethylene group, represented by the following general formula (1): CH3O(AO)m(CH2CH2O)nH wherein the AO group represents oxypropylene group, or copolymeric group of oxypropylene groups and oxyethylene groups wherein the copolymeric form may be a block type and/or a random type, m is a number of 1≦m≦50, n is a number of 1≦n≦10, and the content of the oxyethylene group in the compound ranges from 5 to 60 percent by weight. A composition for refrigerators using said lubricant is also provided.Type: GrantFiled: December 17, 1992Date of Patent: April 17, 2001Assignee: Asahi Denka Kogyo K.K.Inventors: Tamiji Kamakura, Noriyoshi Tanaka, Yuji Baba, Kimiyoshi Namiwa, Yukio Tatsumi, Masato Namiki
-
Patent number: 6041082Abstract: Since output voltage e of coupler CU2 is displaced in phase by -135 degrees from input signals c and d (by -270 degrees from signals a and b), a carrier which makes signal f is phase shifted by -270 degrees by phase shifter .phi.1 so that signal f may have the same phase as signal e. Signal f and signal e are power composed by first 3 dB coupler M1, and are further phase shift controlled by variable phase shifters PH11 and PH12 so that they may have the same phase. Further, an output signal of variable phase shifter PH11 is phase shifted by -90 degrees by phase shifter SH1 so that it has a phase difference by 90 degrees from an output signal of variable phase shifter PH2, and the two signals controlled in this manner are inputted to 3 dB coupler M2. Consequently, two signals e and f inputted to the amplifier are all outputted as output voltage EOUT.Type: GrantFiled: September 4, 1997Date of Patent: March 21, 2000Assignees: NEC Corporation, Nippon Hoso KyokaiInventors: Haruo Takeda, Yukio Tatsumi, Ikuji Fujitani, Takuya Shioda, Tomofumi Yoshimi, Tomohiko Sugimoto, Kazuhisa Haeiwa
-
Patent number: 5858931Abstract: A lubricating composition of the present invention comprises a base oil for lubricating oil or base grease; at least one molybdenum compound as component (A) selected from the group consisting of a selected sulfurized oxymolybdenum dithiocarbamate, a selected sulfurized oxymolybdenum dithiophosphate and a selected molybdenum amine compound; and a (poly)glycerol ether and/or a (poly)oxyalkylene glycol monoalkyl ether as component (B).Type: GrantFiled: August 5, 1996Date of Patent: January 12, 1999Assignee: Asahi Denka Kogyo K.KInventors: Noriyoshi Tanaka, Aritoshi Fukushima, Yukio Tatsumi, Kazuhisa Morita, Yoko Saito
-
Patent number: 5696065Abstract: The present invention is directed to provide an engine oil composition which fully exploits the performance of molybdenum dithiocarbamate (MoDTC), restricts degradation of MoDTC itself, and has a high MoDTC residual property even at the time of degradation, hence providing low friction and low wear for a long time, and which results in savings in fuel consumption. It is also directed to an engine oil composition having a high coefficient of friction and an extreme-pressure property under fluid lubricating conditions arising from extreme-pressures, in order to solve various problems encountered in friction. The engine oil compositions according to the present invention comprise a specific MoDTC, a specific zinc dithiophosphate and a base oil for engine oil as the essential components, and specific polyglycerin half esters may be further added.Type: GrantFiled: March 4, 1996Date of Patent: December 9, 1997Assignee: Asahi Denka Kogyo K. K.Inventors: Noriyoshi Tanaka, Aritoshi Fukushima, Yukio Tatsumi, Kazuhisa Morita, Yoko Saito
-
Patent number: 5631213Abstract: A process for producing molybdenum oxysulfide dithiocarbamate (MoDTC) by reacting [A] an aqueous solution or suspension prepared by reacting (a) a compound having hexavalent molybdenum, with (b) an alkali hydrogensulfide or an alkali sulfide, [B] a carbon disulfide, [C] a secondary amine and [D] a mineral acid, wherein [E] a reducing agent is added and reacted at any stage, and a lubricating oil composition containing the compound obtained according to said process. MoDTC can be efficiently produced in high yields by using a hexavalent molybdenum compound as a starting material, and the produced MoDTC has low corrosive action, excellent wear characteristics and excellent lubricating properties.Type: GrantFiled: February 6, 1996Date of Patent: May 20, 1997Assignee: Asahi Denka Kogyo K. K.Inventors: Noriyoshi Tanaka, Aritoshi Fukushima, Yukio Tatsumi, Kazuhisa Morita, Yoko Saito
-
Patent number: 5627146Abstract: The present invention is directed to providing a lubricating oil composition which contains an alkyl group asymmetric type molydbdenum dithiocarbamate (MoDTC) as an essential component thereof and which exhibits far more excellent lubrication performance than a conventional lubricating oil composition containing an alkyl group symmetric type MoDTC conventional used in the field of lubricating oils. The lubricating oil composition according to the present invention comprises a base oil for a lubricating oil consisting of a mineral oil and/or a synthetic oil and having a viscosity index of at least 115 and a viscosity at 100.degree. C. falling within the range of 2 to 50 cSt, and a specific alkyl group asymmetric type MoDTC as an essential component.Type: GrantFiled: December 27, 1995Date of Patent: May 6, 1997Assignee: Asahi Denka Kogyo K.K.Inventors: Noriyoshi Tanaka, Aritoshi Fukushima, Yukio Tatsumi, Yoko Saito
-
Patent number: 5620950Abstract: The objective of the present invention resides in providing a lubricant for refrigerators that reacts rapidly with free acids and contains a stabilizer that has good compatibility with a chlorine-free Flon-thpe coolant such as Flon 134a and the like whose molecules do not contain chlorine. The lubricant for refrigerators employing a chlorine-free Flon-type coolant in accordance with the present invention 100 parts by weight of a synthetic oil and is compounded with 0.05 to 15 parts by weight of an alicyclic epoxy compound having one or more functional groups represented by the following formula: ##STR1## (wherein R.sub.1 and R.sub.2 independently represent a hydrogen or methyl group, and may be the same or different).Type: GrantFiled: August 8, 1995Date of Patent: April 15, 1997Assignee: Asahi Denka Kogyo K.K.Inventors: Tamiji Kamakura, Noriyoshi Tanaka, Kimiyoshi Namiwa, Yukio Tatsumi, Masato Namiki
-
Patent number: 5612297Abstract: A grease composition comprising 0.1 to 10 parts by weight of a powdered molybdenum oxysulfide dithiocarbamate composition which comprises a compound represented by the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independent hydrocarbyl groups and may be the same or different groups, and the total number of carbon atoms contained in R.sup.1 to R.sup.4 is 4 to 36; and wherein X is sulfur or oxygen and the composition of the total of all Xs is given as S.sub.m and O.sub.n in which m and n satisfy the ranges of 1.7.ltoreq.m.ltoreq.3.5 and 0.5.ltoreq.n.ltoreq.2.3, respectively, in which the constituent particles have diameters of not larger than 50 .mu.m, based on 100 parts by weight of a base grease.Type: GrantFiled: November 21, 1995Date of Patent: March 18, 1997Assignee: Asahi Denka Kogyo K.K.Inventors: Tamiji Kamakura, Noriyoshi Tanaka, Aritoshi Fukushima, Yukio Tatsumi, Kazuhisa Morita