Abstract: This nonaqueous electrolyte secondary battery has a non-aqueous electrolyte and an electrode assembly formed by layering a positive electrode and a negative electrode layered via a separator. The positive electrode has a positive electrode core and a positive electrode mix layer containing a positive electrode active substance. The median diameter (D50) of the positive electrode active substance in terms of volume is 5.0 to 7.0 ?m, the BET specific surface area of the positive electrode active substance is 2.00 to 3.00 m2/g, the TAP density of the positive electrode active substance is 1.30 to 1.70 g/cm3, and the density of the positive electrode mix layer is 2.3 to 2.5 g/cm3.

Abstract: The present nonaqueous electrolyte secondary battery positive electrode comprises a positive electrode core, and a positive electrode composite material layer formed on the surface of the positive electrode core. The positive electrode composite material layer includes at least a positive electrode active material, and lithium phosphate. The positive electrode active material includes a first positive electrode active material wherein the Ni content relative to the total molar amount of metal elements other than Li is 50-65 mol%, and a second positive electrode active material wherein the Ni content relative to the total molar amount of metal elements other than Li is 45 mol% or less. The ratio of the first positive electrode active material to the second positive electrode active material in the positive electrode composite material layer is, by mass ratio, from 80:20 to 50:50.

Abstract: A nonaqueous electrolyte secondary battery includes an electrode assembly including a negative plate and a positive plate including a positive electrode active material mix layer, a nonaqueous electrolyte, a battery case that houses the electrode assembly and the nonaqueous electrolyte, and a pressure-sensitive safety system that operates when the pressure in the battery case reaches a value greater than or equal to a predetermined value. The positive electrode active material mix layer contains lithium carbonate and lithium phosphate. The average particle size of lithium carbonate contained in the positive electrode active material mix layer is greater than the average particle size of lithium phosphate contained in the positive electrode active material mix layer. The number of particles of lithium carbonate contained in the positive electrode active material mix layer is less than the number of particles of lithium phosphate contained in the positive electrode active material mix layer.

Abstract: A secondary battery includes a positive electrode including a positive electrode core; and a positive electrode mixture layer formed on at least one of the surfaces of the positive electrode core. The positive electrode mixture layer has a first positive electrode mixture layer and a second positive electrode mixture layer formed om the surface of the first positive electrode mixture layer. The first positive electrode mixture layer contains a first positive electrode active material having a BET specific surface area of 1.6 m2/g to 2.8 m2/g, and the second positive electrode mixture layer contains a second positive electrode active material having a BET specific surface area of 0.8 m2/g to 1.3 m2/g. The thickness of the second positive electrode mixture layer is 5 ?m to 15 ?m.

Abstract: A non-aqueous electrolyte secondary battery positive electrode capable of suppressing a decomposition reaction of an electrolyte solution in an overcharged state is provided. A non-aqueous electrolyte secondary battery positive electrode according to this embodiment includes a positive electrode active material layer which includes a positive electrode active material (54) containing a lithium transition metal oxide, a tungsten compound (56), a phosphoric acid compound (58) not in contact with the positive electrode active material (54), and an electrically conductive agent (52) in contact with the tungsten compound (56) and the phosphoric acid compound (58).

Abstract: A nonaqueous electrolyte secondary battery includes an electrode assembly including a negative plate and a positive plate including a positive electrode active material mix layer, a nonaqueous electrolyte, a battery case that houses the electrode assembly and the nonaqueous electrolyte, and a pressure-sensitive safety system that operates when the pressure in the battery case reaches a value greater than or equal to a predetermined value. The positive electrode active material mix layer contains lithium carbonate and lithium phosphate. The average particle size of lithium carbonate contained in the positive electrode active material mix layer is greater than the average particle size of lithium phosphate contained in the positive electrode active material mix layer. The number of particles of lithium carbonate contained in the positive electrode active material mix layer is less than the number of particles of lithium phosphate contained in the positive electrode active material mix layer.

Abstract: Provided is a nonaqueous electrolyte secondary battery in which the structural change of a positive electrode active material is suppressed at high voltage and which can achieve high capacity and long life. The nonaqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material storing and releasing lithium ions, a negative electrode containing a negative electrode active material storing and releasing lithium ions, and a nonaqueous electrolyte. The positive electrode active material is a cobalt composite oxide which has a layered rock salt structure and which includes a lithium layer containing magnesium, magnesium is present in the lithium layer after charge is performed at a potential of 4.53 V or more versus lithium, and 4.5 mole percent to 10 mole percent of a magnesium-containing compound is present on the negative electrode with respect to magnesium in the positive electrode.

Abstract: A nonaqueous electrolyte secondary battery which can suppress the change in structure of a positive electrode active material at a high voltage is provided. The nonaqueous electrolyte secondary battery has a positive electrode including a positive electrode active material which absorbs and releases lithium ions; a negative electrode including a negative electrode active material which absorbs and releases lithium ions; and a nonaqueous electrolyte. The positive electrode active material has a surface to which a rare earth compound is adhered and includes a lithium cobalt composite oxide containing at least one type selected from the group consisting of Ni, Mn, Ca, Cu, Zn, Sr, Ge, Sn, Si, P, Nb, Mo, S, and W, and charge is performed so that the potential of the positive electrode is 4.53 V or more with reference to lithium.

Abstract: A non-aqueous electrolyte secondary battery positive electrode capable of suppressing a decomposition reaction of an electrolyte solution in an overcharged state is provided. A non-aqueous electrolyte secondary battery positive electrode according to this embodiment includes a positive electrode active material layer which includes a positive electrode active material (54) containing a lithium transition metal oxide, a tungsten compound (56), a phosphoric acid compound (58) not in contact with the positive electrode active material (54), and an electrically conductive agent (52) in contact with the tungsten compound (56) and the phosphoric acid compound (58).

Abstract: A non-aqueous electrolyte secondary battery having a high capacity and a long life is provided by eliminating or reducing the structural change of a positive electrode active material at high voltages. The non-aqueous electrolyte secondary battery includes a positive electrode having a positive electrode active material that intercalates and deintercalates lithium ions, a negative electrode having a negative electrode active material that intercalates and deintercalates lithium ions, and a non-aqueous electrolyte. The positive electrode active material includes a lithium-cobalt composite oxide containing nickel, manganese, aluminum, and germanium. The percentage of cobalt in the lithium-cobalt composite oxide is 80 mol % or more with respect the total molar amount of metal elements except lithium.

Abstract: Provided is a nonaqueous electrolyte secondary battery in which the structural change of a positive electrode active material is suppressed at high voltage and which can achieve high capacity and long life. The nonaqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material storing and releasing lithium ions, a negative electrode containing a negative electrode active material storing and releasing lithium ions, and a nonaqueous electrolyte. The positive electrode active material is a cobalt composite oxide which has a layered rock salt structure and which includes a lithium layer containing magnesium, magnesium is present in the lithium layer after charge is performed at a potential of 4.53 V or more versus lithium, and 4.5 mole percent to 10 mole percent of a magnesium-containing compound is present on the negative electrode with respect to magnesium in the positive electrode.

Abstract: Provided is a nonaqueous electrolyte secondary battery which is capable of achieving high capacity and long life by suppressing the structural change of a positive electrode active material at high voltage. The nonaqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material storing and releasing lithium ions, a negative electrode containing a negative electrode active material storing and releasing lithium ions, and a nonaqueous electrolyte. The positive electrode active material is a lithium-cobalt composite oxide containing nickel, manganese, and aluminium and has a rare-earth compound or oxide deposited to a portion of the surface thereof.

Abstract: A nonaqueous electrolyte secondary battery which can suppress the change in structure of a positive electrode active material at a high voltage is provided. The nonaqueous electrolyte secondary battery has a positive electrode including a positive electrode active material which absorbs and releases lithium ions; a negative electrode including a negative electrode active material which absorbs and releases lithium ions; and a nonaqueous electrolyte. The positive electrode active material has a surface to which a rare earth compound is adhered and includes a lithium cobalt composite oxide containing at least one type selected from the group consisting of Ni, Mn, Ca, Cu, Zn, Sr, Ge, Sn, Si, P, Nb, Mo, S, and W, and charge is performed so that the potential of the positive electrode is 4.53 V or more with reference to lithium.

Abstract: A method of manufacturing an active material for a non-aqueous electrolyte battery, the active material containing a lithium-containing vanadium oxide, is provided. The active material for a non-aqueous electrolyte battery is washed with water or an acidic aqueous solution. By dissolving pentavalent vanadium, which is toxic, in water or an acidic aqueous solution, the pentavalent vanadium can be removed from the active material.