Abstract: A supported catalyst used for synthesizing a polyether amine, and a manufacturing method of the catalyst. The catalyst comprises: a porous oxide as a support; Ni, Cu, Pd, and Rh as active components; and one or more of any of Zr, Cr, Mo, Fe, Zn, Sn, Bi, Ce, La, Hf, Sr, Sb, Mg, Be, Re, Ta, Ti, Sc, Ge and related metals as an auxiliary agent. The catalyst can be used in an amination reaction for a large molecular weight polyether polyol, and is particularly active and selective for an amination reaction of a low molecular weight polyether polyol. The catalyst has a simple and economic manufacturing technique and good potential for future applications.

Abstract: A supported catalyst used for synthesizing a polyether amine, and a manufacturing method of the catalyst. The catalyst comprises: a porous oxide as a support; Ni, Cu, Pd, and Rh as active components; and one or more of any of Zr, Cr, Mo, Fe, Zn, Sn, Bi, Ce, La, Hf, Sr, Sb, Mg, Be, Re, Ta, Ti, Sc, Ge and related metals as an auxiliary agent. The catalyst can be used in an amination reaction for a large molecular weight polyether polyol, and is particularly active and selective for an amination reaction of a low molecular weight polyether polyol. The catalyst has a simple and economic manufacturing technique and good potential for future applications.

Abstract: The present invention has provided a welding forged steel single piece piston and its manufacturing methods. A semi-finished head and a semi-finished skirt are forged respectively; the semi-finished head and semi-finished skirt are heat-treated respectively; rough machining is carried out respectively to the semi-finished head and the semi-finished skirt, and a face of weld between the two adjacent ring grooves is higher than the one under the combustion chamber; the head and the skirt are welded together through friction welding; an annular groove, a combustion chamber, a ring groove, a pinhole, an outer annulus and oil inlet/outlet holes are manufactured respectively; and the surface of the piston is phosphorized and graphitized. Compared with one-piece forged piston, it has better processing technology, because the head and skirt are forged respectively and then welded together.