Invisible Patents (Class 106/31.14)
  • Patent number: 11244218
    Abstract: The present disclosure provides a polarized Raman spectrum-based nano barcode smart label, including: a substrate and a nanoparticle coding layer that is provided on the substrate and can be coded by polarized Raman spectrum coding, wherein the nanoparticle coding layer that can be coded by polarized Raman spectrum coding is a mixed layer including a plurality of nanomaterials having different Raman characteristic peaks; under different polarization detection states, the Raman characteristic peaks can exhibit coding characteristics that are totally different from those under a non-polarization detection state and are distinguished from those of a conventional Raman peak position, so as to achieve spectral characteristics for multiple coding. During use of the smart label of the present disclosure, a corresponding nano barcode detection system is used to detect a brand label provided with the encoded nanoparticles to obtain coding information of the brand label.
    Type: Grant
    Filed: June 1, 2021
    Date of Patent: February 8, 2022
    Assignee: Nanjing University
    Inventors: Xinglong Wu, Jiaqing Xu, Jiancang Shen
  • Patent number: 10828263
    Abstract: A layered body comprising: a core region; at least one intermediate layer disposed around the core region; and an outer layer disposed around the at least one intermediate layer, wherein at least one of the at least one intermediate layers comprises a gas, the layered body having at least one dimension, measured across the body and through the core region, of 100 ?m or less.
    Type: Grant
    Filed: December 6, 2017
    Date of Patent: November 10, 2020
    Assignee: UCL Business Ltd
    Inventors: Mohan Edirisinghe, Ming Wei Chang, Eleanor Stride
  • Patent number: 10780059
    Abstract: A layered body comprising: a core region; at least one intermediate layer disposed around the core region; and an outer layer disposed around the at least one intermediate layer, wherein at least one of the at least one intermediate layers comprises a gas, the layered body having at least one dimension, measured across the body and through the core region, of 100 ?m or less.
    Type: Grant
    Filed: December 6, 2017
    Date of Patent: September 22, 2020
    Assignee: UCL Business Ltd
    Inventors: Mohan Edirisinghe, Ming Wei Chang, Eleanor Stride
  • Patent number: 10620558
    Abstract: Described herein is a LEP ink composition comprising a luminescent component, a resin; and a carrier liquid security liquid electrostatic ink composition for printing a security image.
    Type: Grant
    Filed: March 10, 2016
    Date of Patent: April 14, 2020
    Assignee: HP Indigo B.V.
    Inventors: Haim Cohen, Yaron Grinwald, Julia Kornilov, Reut Avigdor, Gideon Amir
  • Patent number: 10184057
    Abstract: A fluid for ink jet printing characters on a substrate that become magnetized in the presence of a magnetic field, the fluid HAVING a suspension of nanoparticles dispersed in a solvent, wherein the fluid comprises a viscosity from 1 to 50 cps and a surface tension of 20-45 dynes/cm, further wherein each nanoparticle is sized between 10-180 nm and comprises M(III)2O3, M(II)O and M(II)M(III)2O4, wherein M(III) is a trivalent metal and M(II) is a divalent metal, or Fe2O3, MnO and M(II)O, wherein M is a divalent metal selected from the group consisting of Fe, Ni, Mn, Co, Cu, Pt, Au, Ag, Ba and a rare earth metal.
    Type: Grant
    Filed: June 8, 2016
    Date of Patent: January 22, 2019
    Inventor: Thomas Villwock
  • Patent number: 9303135
    Abstract: An aqueous ink for indirect printing applications including water; a co-solvent; a colorant; and a polymer latex comprising an aqueous dispersion of polymer particles wherein the polymer latex has a softening temperature of from about 60° C. to less than 105° C. and a glass transition temperature of from about 45° C. to about 100 C.
    Type: Grant
    Filed: October 30, 2013
    Date of Patent: April 5, 2016
    Assignee: Xerox Corporation
    Inventors: Jenny Eliyahu, Daryl W. Vanbesien, Michelle N. Chrétien, Marcel P. Breton, Barkev Keoshkerian
  • Patent number: 9034089
    Abstract: The disclosed invention relates to the use of molybdenum (VI) peroxo complex containing an amino acid, such as MoO(O2)2(GLY)(H2O), in marking applications, as well as to ink formulations comprising such complexes.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: May 19, 2015
    Assignee: Tetra Laval Holdings & Finance S.A.
    Inventors: Anthony Jarvis, Martin Walker, Adam O'Rourke, Richard Cook
  • Patent number: 8669536
    Abstract: An ink composition includes a colorant visible under visible light and a tagging composition, including a carrier and a detectable marker dispersed or dissolved in the carrier. The detectable marker is an isotope of an element, the isotope being present in the ink composition in a concentration ranging from about 1 parts per billion (ppb) to about 1000 ppb.
    Type: Grant
    Filed: February 12, 2013
    Date of Patent: March 11, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Zeying Ma, Gary William Larson, Lufei Lin
  • Patent number: 8663820
    Abstract: The invention relates to a printed document of value having at least one authenticity feature in the form of a luminescent substance based on doped host lattices. The host lattice has a strong crystal field and is doped with at least one chromophore with the electron configuration (3d)2.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: March 4, 2014
    Assignee: Giesecke & Devrient GmbH
    Inventors: Thomas Giering, Rainer Hoppe, Fritz Stahr
  • Patent number: 8642504
    Abstract: The present invention provides a composition, which comprises an aqueous solvent and forms a transparent colorless coating, which yields markings of high contrast on exposure to energy. It also provides a process for the preparation of these compositions, substrates coated with these compositions and a process for their preparation, a process for preparing marked substrates using these compositions and marked substrates obtainable by the latter process.
    Type: Grant
    Filed: July 17, 2006
    Date of Patent: February 4, 2014
    Assignee: Gill Jennings & Every LLP
    Inventors: Jonathan Campbell, William Walker, Alan Platt, John Whitworth, Karen O'Donoghue, Ann Hunt, Howard Roger Dungworth, John Mark Plonka
  • Patent number: 8632175
    Abstract: A high viscosity aqueous inkjet ink that is useful in ink jet printers. The ink having heat activated colorant solids that are not heat activated during the printing process, and are printed onto a substrate in the form of an image that can be transferred onto a subsequent or final substrate by applying heat and intimate contact between the two substrates. The ink can also be heat activated onto the substrate without further transfer by applying heat at the temperature that is suitable for the activation of the colorant.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: January 21, 2014
    Assignee: Sawgrass Technologies, Inc.
    Inventor: Ming Xu
  • Publication number: 20130255536
    Abstract: A document which may be a security document has a thermochromic coating which may be a thermochromic ink on the substrate of the document. The ink may include several thermochromic materials which transition from various different colors to substantially clear in appearance as the ink is warmed to various temperatures. The combination of the colors of the thermochromic materials can give the document a different color at a number of different temperatures, until the coating is warmed to the highest color change point. When at or above the highest color change temperature, the coating becomes substantially transparent and the printed area assumes the color of the underlying substrate. The coating may also include non-reactive materials of yet another color that mixes with the colors of the thermochromic materials.
    Type: Application
    Filed: May 31, 2013
    Publication date: October 3, 2013
    Inventors: Rajendra Mehta, Richard L. Shields
  • Patent number: 8540812
    Abstract: The present invention relates to a machine-readable security element for security products which comprises at least one particulate substance having electroluminescent properties and a transparent, electrically conductive pigment, to a priming ink for the production of a security element of this type, and to a security product which includes the security element.
    Type: Grant
    Filed: August 5, 2011
    Date of Patent: September 24, 2013
    Assignee: MERCK PATENT GmbH
    Inventors: Burkhard Krietsch, Matthias Kuntz, Oliver Muth, Manfred Paeschke, Jakob Kuen
  • Publication number: 20130127947
    Abstract: The invention relates to a treatment for printing a surface with an ink that comprises a compound that exhibits a change of electronic spin state as a function of temperature, imparting optical properties such that the ink is visible in a temperature range that includes an ambient temperature of around 20° C. and is transparent in the visible spectrum when the ink is brought to a temperature above said range and then brought back down to a temperature within the range.
    Type: Application
    Filed: July 21, 2011
    Publication date: May 23, 2013
    Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE-CNRS
    Inventor: Jean-Francois Letard
  • Patent number: 8216354
    Abstract: An inkjet ink composition, and in particular, invisible ink printable with an inkjet printing device. The present embodiments provide a water-based invisible ink that can be detected by using a long wavelength ultraviolet (UV) light and is easier and safer to use than other sources used to detect known invisible inks.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: July 10, 2012
    Assignee: Xerox Corporation
    Inventor: Gabriel Iftime
  • Publication number: 20120125228
    Abstract: An inkjet ink composition, and in particular, invisible ink printable with an inkjet printing device. The present embodiments provide a water-based invisible ink that can be detected by using a long wavelength ultraviolet (UV) light and is easier and safer to use than other sources used to detect known invisible inks.
    Type: Application
    Filed: November 19, 2010
    Publication date: May 24, 2012
    Applicant: XEROX CORPORATION
    Inventor: Gabriel Iftime
  • Publication number: 20120104743
    Abstract: A document which may be a security document has a thermochromic coating which may be a thermochromic ink on the substrate of the document. The ink may include several thermochromic materials which transition from various different colors to substantially clear in appearance as the ink is warmed to various temperatures. The combination of the colors of the thermochromic materials can give the document a different color at a number of different temperatures, until the coating is warmed to the highest color change point. When at or above the highest color change temperature, the coating becomes substantially transparent and the printed area assumes the color of the underlying substrate. The coating may also include non-reactive materials of yet another color that mixes with the colors of the thermochromic materials.
    Type: Application
    Filed: November 2, 2010
    Publication date: May 3, 2012
    Applicant: THE STANDARD REGISTER COMPANY
    Inventors: Rajendra Mehta, Richard L. Shields
  • Patent number: 8167989
    Abstract: The invention refers to new chemical compounds belonging to the known class of REE mixed ligand complexes, namely, to the compound of di-(nitrate)acetylacetonatobis (1,10-fenantrolin)lanthanide (III) of the general formula [Ln(NO3)2Acac(Phen)2]*H20, where Ln is TbxEr1-x, Acac is acetylacetonate-ion, Phen is 1,10-fenantrolin in the form suitable for application as a luminescent additive to ink for the hidden marking the valuables to provide protection against forgery. Such additive has three protective features suitable for automatic control independently of each other. The first protective feature is the ability to luminescence in green light under the impact of UV-radiation. The second protective feature is the ability to luminescence in green light under the impact of X-rays. The third protective feature is the Thermo-luminescence, which means the ability to accumulate for indefinite time span the energy of UV- and X-rays with subsequent green light emission at heating.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: May 1, 2012
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Anatoliy Grigor'evich Mirochnik, Vladimir Egorovich Karacev
  • Patent number: 8138252
    Abstract: It is an object of the present invention to provide a thermally disappearing resin particle and a thermally disappearing hollow resin particle which can be decomposed at a low temperature in a short time and do not cause deformation or cracking of a sintered body to be obtained in the case of using as a binder for a ceramic or a lightening material; a method of producing the thermally disappearing hollow resin particle; a ceramic composition which can be degreased and fired at a low temperature in a short time and gives a molded body with a high porosity without deformation or cracking even in the case a large quantity of a pore-forming material is used; and a method of producing a porous ceramic filter. The present invention is directed to a thermally disappearing resin particle, which contains a polyoxyalkylene resin, and 10% by weight or more of the whole particle disappearing within an hour by heating at a prescribed temperature in a range from 100 to 300° C.
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: March 20, 2012
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Takahiro Oomura, Naoyuki Nagatani, Miki Inaoka, Hiroshi Yamauchi
  • Patent number: 8128300
    Abstract: Disclosed is a hand-held photochromic marking implement including a photochromic colorant and solid phase colorant carrier which can be used in direct-to-media marking and a method of forming same.
    Type: Grant
    Filed: June 16, 2010
    Date of Patent: March 6, 2012
    Assignee: Xerox Corporation
    Inventors: Alexander Kugel, Jeffrey Banning
  • Patent number: 8114207
    Abstract: The invention relates to a marker solution which is to be applied by means of an inkjet printer and contains (i) at least one organic solvent that has a greater steam pressure than water at 20° C. and a water content of less than 50 percent (v/v), (ii) predefined first synthetically produced nucleic acids, and (iii) a nucleic acid-complexing, organic auxiliary agent as components.
    Type: Grant
    Filed: March 1, 2006
    Date of Patent: February 14, 2012
    Assignee: Secutech International Pte. Ltd.
    Inventor: Andre Josten
  • Patent number: 8080097
    Abstract: A method for labeling a UV-fluorescing substrate includes positioning a UV-fluorescing substrate adjacent to an inkjet material dispenser, and selectively jetting an edible, invisible, non-UV fluorescing ink onto the UV-fluorescing substrate with the inkjet material dispenser.
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: December 20, 2011
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Vanessa I. Chinea, Marcos A. Barreto
  • Patent number: 7926930
    Abstract: The invention relates to a method for manufacturing an inkjet ink including a polyamic acid (A), including a step of at least reacting one or more compounds selected from the group of a monoamine (a3) and a compound having one acid anhydride group (a4) with a compound having two or more acid anhydride groups (a1) and a diamine (a2).
    Type: Grant
    Filed: August 30, 2007
    Date of Patent: April 19, 2011
    Assignee: Chisso Corporation
    Inventors: Hiroyuki Satou, Setsuo Itami, Takayuki Hattori
  • Patent number: 7758268
    Abstract: Disclosed is a hand-held photochromic marking implement including a photochromic colorant and solid phase colorant carrier which can be used in direct-to-media marking and a method of forming same.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: July 20, 2010
    Assignee: Xerox Corporation
    Inventors: Alexander Kugel, Jeffrey Banning
  • Publication number: 20100112314
    Abstract: Methods of applying covert features using security inks comprise transparent chiral birefringent pigments or a mixture of transparent chiral birefringent pigments and reflective pigments are described. Hidden features appear to be bright and achromatic against dark background when overlaid with circular polarizer.
    Type: Application
    Filed: November 2, 2009
    Publication date: May 6, 2010
    Inventors: Yingqiu Jiang, Aharon Hochbaum
  • Publication number: 20100050901
    Abstract: Various complex structures (nano/micro particles) are incorporated into a taggant providing different optical, magnetic and spectroscopic identification codes. The size and shape of the taggant can be tailored for many different types of products ranging from pharmaceuticals, auto and airplane parts all the way to apparel goods. By integrating a number of different nano/micro structures with various optical, electrical and magnetic properties, significant barriers are introduced to the counterfeiters attempting to replicate the taggant. The latter is easily incorporated to different types of products and is detected with various types of handheld readers/detectors depending on the complexity of the security level. The taggant may detect environmental materials or conditions.
    Type: Application
    Filed: August 20, 2009
    Publication date: March 4, 2010
    Inventors: Alexandru S. Biris, Enkeleda Dervishi
  • Publication number: 20100005601
    Abstract: An ink, dye or paint containing inclusions which reflect incident light in a low ambient light environment, such as at night is provided and is transparent or invisible during the day or in high light environments.
    Type: Application
    Filed: July 14, 2009
    Publication date: January 14, 2010
    Inventor: Barbara C. Kantor
  • Publication number: 20090220749
    Abstract: The present invention provides a composition, which comprises a latent activator. It also provides a process for the preparation of these compositions, substrates coated with these compositions and a process for their preparation, a process for preparing marked substrates using these compositions and marked substrates obtainable by the latter process.
    Type: Application
    Filed: September 6, 2006
    Publication date: September 3, 2009
    Inventors: Karen O' Donoghue, Jonathan Campbell, Alan Platt, John Whitworth, Howard Roger Dungworth, Adolf Käser
  • Patent number: 7576149
    Abstract: A recording medium with an ink image thereon, wherein a varnish at least partially covers the ink image, and wherein the varnish composition prior to application comprises at least one latex emulsion, water, at least one base and at least one surfactant.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: August 18, 2009
    Assignee: Xerox Corporation
    Inventors: Christine D. Anderson, T. Brian McAneney
  • Publication number: 20090191420
    Abstract: Composition, which comprises a latent activator and a colour former, a process for the preparation of these compositions, substrates coated with these compositions and a process for their preparation, a process for preparing marked substrates using these compositions and marked substrates obtainable by the latter process.
    Type: Application
    Filed: January 17, 2007
    Publication date: July 30, 2009
    Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC.
    Inventors: Karen O'Donoghue, Jonathan Campbell, Ian Street
  • Publication number: 20080276817
    Abstract: Embodiments of a printed security mark and a process are disclosed.
    Type: Application
    Filed: May 9, 2007
    Publication date: November 13, 2008
    Inventors: Garry Dale Hinch, Herbert T. Etheridge, III, James William Stasiak, Timothy Dean Strecker
  • Publication number: 20080245267
    Abstract: The present invention relates to an red luminescent ink composition exhibiting adequate and stable emission intensity under irradiation of ultraviolet rays and high solubility for a resin and an organic solvent. The ink composition of the present invention contains a luminous compound represented by the following formula (1): wherein R is a perfluoroalkyl group having 2 to 20 carbons, L1 and L2 are the same or different and are sulfoxide having a substituted or unsubstituted aryl group or a substituted or unsubstituted an alkyl group.
    Type: Application
    Filed: April 6, 2007
    Publication date: October 9, 2008
    Applicant: Orient Chemical Industries, Ltd.
    Inventors: Fumio Furuya, Yasuhiro Yamasaki
  • Publication number: 20080145588
    Abstract: A coating composition for optical recording includes a uniform dispersion of polymer particles in a liquid, a quantity of dye particles uniformly dispersed in the liquid, the dye particles being soluble in the polymer but substantially insoluble in the liquid, and a quantity of radiation absorber material adapted to absorb radiation at a wavelength of a laser for optical recording of an image.
    Type: Application
    Filed: December 16, 2006
    Publication date: June 19, 2008
    Inventors: Vladek P. Kasperchik, Michael J. Day, Jayprakash C. Bhatt
  • Publication number: 20080022888
    Abstract: A ready to use skin marking stain/applicator for use in inhibiting voter fraud requiring only the addition of water, includes a open top container with a measured quantity of dry water soluble stain producing compound disposed therein. The compound, when dissolved in water, filling the container, is capable of reacting with the organic materials on the person's finger, to produce within a relatively short time, a semipermanent, highly visible, stain, on the finger. A substantially impermeable removable cover is secured over the open top of the container to inhibit the ingress of moisture into the container prior to its use.
    Type: Application
    Filed: July 27, 2006
    Publication date: January 31, 2008
    Inventor: Douglas C. Arndt
  • Patent number: 7297454
    Abstract: A colorless ink jet ink composition is provided for printers for printing on both porous and hybrid glossy or semi-glossy media. The ink composition comprises a water soluble polymer or dispersed latex. The ink formulation provides substantially air fast, stain resistant, and light fastness to the printed image. Further, the ink formulation evidences improved overall image quality.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: November 20, 2007
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Zeying Ma, John M Gardner, Gregg A Lane
  • Patent number: 7289103
    Abstract: A method and system for enabling user interaction with computer software running in a computer system. A user is provided with an interface surface containing information relating to the computer software and including coded data indicative of an identity of the interface surface and of at least one reference point of the interface surface. The user places a sensing device into an operative position relative to the interface surface. In this operative position, the sensing device senses indicating data indicative of: the identity of the interface surface; and a position of the sensing device relative to the interface surface, using at least some of the coded data. The computer system receives the indicating data from the sensing device, and uses the indicating data to identify at least one interactive element relating to the computer software. The computer software is then operated in accordance with instructions associated with the at least one interactive element.
    Type: Grant
    Filed: November 12, 2002
    Date of Patent: October 30, 2007
    Assignee: Silverbrook Research Pty Ltd
    Inventors: Paul Lapstun, Kia Silverbrook
  • Patent number: 6861012
    Abstract: A latent or “invisible ink” security marking formulation is provided using a phosphor with distinct emissions characteristics including visible emission due to excitation at a particular invisible wavelength. An insoluble inorganic phosphor with this or a similarly distinct emission characteristic is milled to a small particle size, preferably less than one micron particle diameter, and is combined with a carrier at very low pigment concentration, for example one percent by weight of the ink formulation. Preferably the pigment is cropped to resin particles in a binder. This ink formulation is diluted by a volatile solvent and applied using a conventional inkjet printer of the type used to mark codes on packages and labels. To test for security purposes the printing is irradiated and a response according to the predetermined characteristic is noted (or not noted) to detect security information.
    Type: Grant
    Filed: October 11, 2001
    Date of Patent: March 1, 2005
    Assignee: Laser Lock Technologies, Inc.
    Inventors: Norman A. Gardner, Terry Stovold
  • Patent number: 6846350
    Abstract: Disclosed is a red luminous ink composition comprising a europium complex represented by the formula: wherein R1 is a hydrogen atom or a substituent selected from the group consisting of an alkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms and a halogen atom, R is a group selected from the group consisting of a fluorine-comprising alkyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkyl group having from 1 to 6 carbon atoms, a substituted or unsubstituted aralkyl group having from 7 to 10 carbon atoms and a substituted or unsubstituted aryl group having from 6 to 12 carbon atoms. The red luminous ink composition exhibits satisfactory emission intensity under ultraviolet irradiation.
    Type: Grant
    Filed: July 16, 2002
    Date of Patent: January 25, 2005
    Assignee: Orient Chemical Industries, Ltd.
    Inventors: Keishi Imanishi, Yasuhiro Yamasaki
  • Publication number: 20040202838
    Abstract: The invention relates to an overcoat composition for an imaged image-recording element, the overcoat composition comprising an aqueous carrier, an optional humectant, an optional surfactant, and 0.05 to 20 weight percent, based on the total weight of the overcoat composition, of an addition polymer having an acid number greater than about 110. The invention also relates to a method of making an imaged image recording element having a transparent overcoat, which method comprises forming an image on the image recording element and applying over the image an overcoat composition of the present invention.
    Type: Application
    Filed: October 24, 2002
    Publication date: October 14, 2004
    Applicant: Eastman Kodak Company
    Inventors: David S. Uerz, Hwei-Ling Yau
  • Patent number: 6802992
    Abstract: Non-green anti-Stokes luminescent material, comprising the elements Ln, erbium (Er) and ytterbium (Yb), Ln representing at least one element which is selected from the group consisting of yttrium (Y), gadolinium (Gd), scandium (Sc) and lanthanum (La), a process for its production and its use.
    Type: Grant
    Filed: November 8, 1999
    Date of Patent: October 12, 2004
    Inventors: Jürgen Wieczoreck, Alfred Siggel, Uwe Fischbeck
  • Patent number: 6770687
    Abstract: A water-based security printing ink is provided with two means of security. The use of a variable light absorbing and/or transmitting pigment or dye is a first security and a water repelling agent is provided as a second security. Visible images can be generated from the printed ink upon exposure to UV or infrared light. The water repelling agent renders the image waterproof and differentiates the printed image from the substrate, which allows the image to be detected upon exposure to water or other aqueous mixture. Suitable inks can be used in conventional printing methods, such as jet printing, lithography, offset printing and impact printing. Also provided are substrates imaged with these security printing inks.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: August 3, 2004
    Assignee: NCR Corporation
    Inventors: Yaoping Tan, Maurice W. Lewis
  • Patent number: 6743283
    Abstract: Disclosed is a blue luminous ink composition comprising a luminous compound represented by the formula: wherein R1 is a group selected from the group consisting of a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, an alkoxyl group having from 1 to 4 carbon atoms and a halogen atom, R is a group selected from the group consisting of a fluorine-comprising alkyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkyl group having from 1 to 4 carbon atoms, a substituted or unsubstituted aralkyl group having from 7 to 10 carbon atoms and a substituted or unsubstituted aryl group having from 6 to 12 carbon atoms, M is a two-valent or three-valent metal, provided rare-earth metal and alkaline earth metal (IIa group) are eliminated, and n is an integer of 2 or 3. The blue luminous ink composition exhibits satisfactory emission intensity under ultraviolet irradiation.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: June 1, 2004
    Assignee: Orient Chemical Industries, Ltd.
    Inventors: Keishi Imanishi, Yasuhiro Yamasaki
  • Publication number: 20040094065
    Abstract: A pigment-based ink jet ink set and image-recording element combination is described, wherein the ink jet image-recording element has a gloss value of at least 5 when measured at 60°, and wherein each ink in the ink set has a normalized differential specular reflectance, N&Dgr;RS(X), of less than 1.25. N&Dgr;RS(X) is defined as the maximum value within a set of N&Dgr;RS(Xn) values in which each N&Dgr;RS(Xn) is the normalized specular reflectance for a density patch of a printed test image. The printed test image consists of a series of at least eleven density patches printed such that the ink laydown of the patches increases incrementally, from no ink laydown to a maximum level generating a density of at least 1.
    Type: Application
    Filed: November 19, 2002
    Publication date: May 20, 2004
    Applicant: Eastman Kodak Company
    Inventors: Richard C. Reem, Karen J. Klingman
  • Patent number: 6610351
    Abstract: An organic or organoelement, linear or branched, monomeric or polymeric composition of matter having a Raman-active component in the form of particles. The particles having a maximum dimension of 50 &mgr;m. The Raman-active compound is applied to a substrate. When the Raman-active compound is exposed to a laser light wavelength which is batochromically well beyond a spectral region of maximum absorbance of said Raman-active compound, Raman scattering can be detected.
    Type: Grant
    Filed: April 11, 2001
    Date of Patent: August 26, 2003
    Assignee: Quantag Systems, Inc.
    Inventors: Alexander Nikitovich Shchegolikhin, Olga Leonidovna Lazareva, Valery Pavlovich Mel'nikov, Vassili Yu Ozeretski, Lyle David Small
  • Publication number: 20030110979
    Abstract: Disclosed is a blue luminous ink composition comprising a luminous compound represented by the formula: 1
    Type: Application
    Filed: August 30, 2002
    Publication date: June 19, 2003
    Inventors: Keishi Imanishi, Yasuhiro Yamasaki
  • Publication number: 20030106460
    Abstract: Disclosed is a red luminous ink composition comprising a europium complex represented by the formula: 1
    Type: Application
    Filed: July 16, 2002
    Publication date: June 12, 2003
    Inventors: Keishi Imanishi, Yasuhiro Yamasaki
  • Publication number: 20030055156
    Abstract: The invention relates to water-dilutable binding agents and coating agents with particularly quick drying surfaces. The invention also relates to a method for the production and use thereof. The water-dilutable binding agents are based on polymer dispersions, which are characterized in that they contain at least one poly acid/polyvinylpyrrolidone complex and optionally one or several water-soluble zircon compounds. The inventive binding agents have a quick drying surface and are suitable for use in the production of primers, paints and plasters with quick drying surfaces or quick-acting wash-fastness.
    Type: Application
    Filed: June 19, 2002
    Publication date: March 20, 2003
    Inventor: Ivan Cabrera
  • Publication number: 20020170461
    Abstract: A thermochromic ink composition is provided for use on security documents such as checks which provides a reversible color change in response to heat. The ink composition includes a thermochromic aqueous slurry and an ink vehicle comprising either a phenolic modified rosin and a compatible oil, a styrene maleic anhydride resin and a glycol, or an acrylic resin varnish. The ink composition is printed on at least a portion of a substrate using letterpress printing methods and provides enhanced adhesion to toner when applied to areas of a substrate which are subsequently printed with a non-impact printing device such as a laser printer.
    Type: Application
    Filed: May 10, 2002
    Publication date: November 21, 2002
    Inventors: Rajendra Mehta, Richard L. Shields, Aurelia Gloria W. Kalman
  • Patent number: 6478861
    Abstract: The present invention provides a transparent or colorless coating comprising a heat responsive material that increases in opacity when exposed to heat. An example of a heat responsive material is an inorganic compound or an organic resin. The present invention further provides a coating composition comprising a carrier and a heat responsive material. The coating can further include additives such as an adhesion promoter, a defoamer, a crosslinking agent, a plasticizer, a humectant, a pH adjuster, a biocide, a co-solvent, a surface tension modifier, and/or a combination thereof. The present invention further provides a method for creating a mark on a substrate comprising providing to the substrate the transparent coating to obtain a coated substrate and exposing a selected area of the coated substrate to heat, e.g., a laser, to create the mark. The present invention further provides substrates suitable for laser marking.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: November 12, 2002
    Assignee: Videojet Technologies Inc.
    Inventors: Wing Sum Vincent Kwan, Yoshikazu Mizobuchi
  • Publication number: 20010051217
    Abstract: The present invention features processes and compositions for producing a metallic-looking image on a substrate having a reflective or luminescent surface. The process utilizes an opaque coating composition containing an opaque coating agent comprising a mixture of a polyacid and a polybase. When applied to a light-emitting, reflective or luminescent substrate, the opaque coating composition at least partially masks the light-emitting reflective or luminescent surface of the substrate, but becomes increasingly translucent or transparent when contacted with a recording liquid such as an ink, revealing the light-emitting, reflective or luminescent surface.
    Type: Application
    Filed: March 19, 2001
    Publication date: December 13, 2001
    Inventor: Asutosh Nigam