Abstract: A corrosion-inhibiting coating, process, and system that provides a tight, adherent zinc- or zinc-alloy coating that is directly deposited onto steel or cast iron surfaces for enhanced corrosion protection. A process for applying the coating is also provided. The process includes the application of two sequential aqueous baths. The first bath contains a precursor zinc compound while the second bath contains a reducing agent to deposit the zinc directly upon the steel or cast iron.
Abstract: A multipurpose treatment composition for metal surfaces comprises phosphate ions, fluorometallate ions, water soluble polymers containing substituted aminomethylene moieties bonded to benzene rings which also have an oxygen atom bonded to another carbon atom in the same ring, and a distinct kind of film-forming polymer. The compositions are free from chromium and other heavy metals that cause serious pollution problems in some prior art treatment compositions.
Abstract: The present invention relates generally to the field of metal conversion surfaces, in particular, the creation of a phosphate-metal chemisorbed layer for iron and aluminum parts as well as to other metal substrates capable of forming a conversion surface. A phosphorus-containing solution is brought into contact with the metal components such that a conversion surface is formed.
Abstract: A chemical conversion treatment liquid which can stably form a phosphate-type chemical conversion film on a steel material for a joint portion of an oil well steel pipe containing 0.5-13% Cr is developed.
Using a chemical conversion treatment liquid to which a prescribed amount of potassium is added, a chemical conversion film containing a prescribed amount of potassium compounds and having a prescribed thickness can be formed on the threaded surface of a joint portion of an oil well steel pipe.
Abstract: The aim of the present invention is to provide a phosphate treated zinc coated steel sheet with excellent workability. A steel sheet coated with a zinc based alloy has a phosphate treated coating on the surface thereof. The phosphate treated coating comprises mainly granulated crystals, specifically, crystals in which the average ratio of the major axis to the minor axis is not less than 1.00 and not more than 2.90. Moreover, the method for producing the phosphate treated coating uses a phosphate treatment solution in which the amount of Mg ions is ≧6 g/l and the amount of Zn ions is ≧0.5 g/l, or a phosphate treatment solution in which the amount of Mg ions is ≧10 g/l, the amount of Zn ions is 0≦ and <0.5 g/l, and the amount of nitric acid ions is ≧40 g/l.
Abstract: A method for coating zinc or zinc plated article with a polymerized molybdate protective coating by coating a cleaned zinc or zinc plated article with a chromium-free polymerized molybdate composition having a pH of about 1.0 to 5.0. A passified zinc or zinc plated article having coated thereon a polymerized molybdate composition that will allow the article to be painted with an appropriate paint.
Abstract: A chromium-free corrosion inhibiting coating composition, which does not utilize harmful chromium compounds and can be used for corrosion inhibition of a metal surface, comprising a slurry mixture in which coated aluminum fine powder treated with a hydrophilic coupling agent is suspended in an acidic phosphate bonding solution and which can be stored in a refrigerator, is disclosed. A titanium-coupling agent is preferable to use as the coupling agent, which treats a surface of the aluminum fine powder. In this aqueous chromium-free corrosion inhibiting coating composition, 25 to 40% by weight of the aluminum fine powder a surface of which is treated with the coupling agent is suspended in the acidic phosphate bonding solution.
Abstract: A metal surface on which a phosphate conversion coating is to be formed and which has been surface conditioned by contact with a liquid surface conditioner composition that contains dispersed fine particles of solid phosphate of at least one divalent or trivalent cations type and an adhesion promoting agent. After such conditioning, a very high quality conversion coating can be formed on the surface by contact with a nickel-free liquid phosphating composition that contains at least acid, zinc cations, and phosphate anions and optionally and preferably also contains other materials.
Abstract: In a process for the chemical pretreatment before painting of composite metal structures that contain aluminum or aluminum alloy portions together with steel, galvanized steel and/or alloy-galvanized steel portions, in a first step the metal structure is treated with a zinc phosphating solution that forms a surface-covering crystalline zinc phosphate layer on steel and on galvanized or alloy-galvanized steel, but without forming a zinc phosphate layer on the aluminum portions, and then in a second step the metal structure is brought into contact with a treatment solution that does not excessively dissolve the crystalline zinc phosphate layer on steel, galvanized and/or alloy-galvanized steel, but forms a conversion layer on the aluminum portions.
Type:
Grant
Filed:
March 10, 2000
Date of Patent:
April 13, 2004
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Peter Kuhm, Michael L. Sienkowski, Gerald J. Cormier, Matthias Hamacher, Jurgen Geke, Volkhard Enke, Jan-Willem Brouwer, Hubert Venschott
Abstract: A liquid iron phosphating concentrate is provided which contains dispersed aromatic carboxylic acid. The aromatic carboxylic acid remains dispersed in the concentrate by incorporation of a thickener in the composition.
Abstract: A method of coating aluminum and aluminum alloy substrates not only imparts a corrosion resistance comparable or even superior to that afforded by chromate treatment but also improves the adhesion to the coating film, while the luster of aluminum is fully retained, notwithstanding the use of a chromium-free treating solution, resulting in an improved coated article with the coated surface having a metallic luster. The method comprises treating an aluminum or aluminum alloy substrate with an acidic solution containing sulfuric acid and 0.2 to 0.4 g/L of a ferric ion and having a pH value of 0.6 to 2.0, subjecting the same to chemical conversion treatment with an acidic coat-forming agent containing 0.01 to 0.125 g/L of a zirconium or titanium ion, 0.01 to 1.0 g/L of a phosphate ion, and 0.01 to 0.5 g/L of a fluoride ion and having a pH value of 1.5 to 4.0, followed by coating.
Abstract: A surface-treated steel sheet includes a steel sheet, an Al—Zn-base alloy plating layer formed on the steel sheet, a chemical conversion film provided on the alloy plating layer, and a concentric layer of a Cr compound that is formed on the alloy plating layer of the chemical conversion film. The surface-treated steel sheet may include a steel sheet, an zinc-base plating layer formed on the steel sheet, and a film that contains chromium and calcium and that is formed on the zinc-base plating layer.
Abstract: A process for forming an improved anodizing film on the surface of an aluminum alloy material. The film is impregnated with an amorphous substance which fills pores formed in the film during its growth. If the film has a flaw reaching the aluminum alloy material, the amorphous substance and aluminum form a layer of passivity which restrains the corrosion of the aluminum alloy material.
Abstract: Rinsing or sealing solutions based on cobalt are described for barrier films such as anodic coatings, phosphate coatings, or “black oxide” coatings. The treated films contain a trivalent or tetravalent cobalt/valence stabilizer complex. The rinsing or sealing bath may also contain an optional preparative agent or an optional solubility control agent. The oxidized cobalt is present in the coating in a “sparingly soluble” form. The valence stabilizers can be either inorganic or organic in nature. Cobalt/valence stabilizer combinations are chosen based on the well-founded principles of cobalt coordination chemistry. A number of cobalt/valence stabilizer combinations that match the performance of conventional hexavalent chromium systems are presented.
Type:
Application
Filed:
January 4, 2002
Publication date:
December 18, 2003
Inventors:
Jeffrey Allen Sturgill, Andrew Wells Phelps, Joseph Thomas Swartzbaugh
Abstract: A process for post-passivation of a phosphated metal surface, characterized in that the phosphated metal surface is treated with an aqueous post-passivation solution which contains from 50 to 500 mg/l of nickel ions and from 200 to 1500 mg/l of phosphate ions. Rinsing water arising which contains constituents of the post-passivation solution may be processed by nanofiltration or reverse osmosis, the retentate being transferred into the phosphating bath, thereby closing the Ni circuit. The post-passivation solution preferably additionally contains a phosphating accelerator.
Abstract: The objects of the present invention are to provide a method of producing highly weather-resistant iron-based magnet powder containing a rare-earth element, particularly characterized by high coercive force in a practically important humid atmosphere, highly weather-resistant magnet powder produced by the same method, resin composition containing the same powder for bonded magnets, and bonded magnet containing the same powder. The present invention provides a method of producing a magnet powder by crushing an iron-based magnet powder containing a rare-earth element in an organic solvent, wherein phosphoric acid is added to the solvent in which the powder is crushed.
Abstract: By including nitric acid and hydroxylamine in a manganese phosphating composition and controlling the ratio of nitric to phosphoric acids and the ratio of Total Acid to Free Acid within a specified range, satisfactory manganese phosphate conversion coatings can be obtained within a reasonable time at temperatures much lower than has previously been thought necessary for operating a manganese phosphating composition with no other metal cations (except possibly for iron).
Abstract: An object of the present invention is to provide a nonchromate metallic surface-treating agent capable of achieving the corrosion resistance and adhesion with a coating film equal to a chromium phosphate surface-treating agent.
Abstract: Methods of making and using annealable insulated metal-based powder particles are provided. The insulated metal-based powder particles are formed from metal-based core particles that are coated with an annealable insulating material. The annealable insulating material has at least one inorganic compound and at least one organic polymeric resin. The inorganic compound in the insulating material forms a nonporous insulating layer surrounding the metal-based core particles upon heating. The organic polymeric resin preferably aids in dispersing or binding the inorganic compound to the metal-based core particles prior to annealing. The insulated metal-based powder particles produced can be formed into core components that can be annealed to improve the magnetic performance of the core component. The core components produced are particularly useful under AC operating conditions of 500 Hz or lower.
Abstract: A method for the immobilization of a radioactive anion on the surface of a metal substrate, said method comprising treating the substrate with an oxidizing agent in the presence of a solution of a radioactive anion which forms an insoluble salt with ions of said metal. Preferably, a binding agent will also be present. Preferably, the metal is silver, the radioactive anion is 125I− and the binding agent comprises bromide ions.
Type:
Grant
Filed:
May 24, 2000
Date of Patent:
July 22, 2003
Assignee:
Amersham, PLC
Inventors:
Robert Snow, Gregory McIntire, Edward Bacon, Evan Gustow
Abstract: There has been invented a chemically bonded phosphate corrosion protection material and process for application of the corrosion protection material for corrosion prevention. A slurry of iron oxide and phosphoric acid is used to contact a warm surface of iron, steel or other metal to be treated. In the presence of ferrous ions from the iron, steel or other metal, the slurry reacts to form iron phosphates which form grains chemically bonded onto the surface of the steel.
Type:
Grant
Filed:
May 29, 2001
Date of Patent:
May 27, 2003
Assignee:
The Regents of the University of California
Abstract: Fairly pure metallic nickel may be efficiently dissolved in non-oxidizing acid. If the nickel includes individual pieces longer than 0.5 mm in any linear dimension, oxidizing agent is preferably added from the beginning of dissolution, while if the nickel is powdered so that no single piece has a linear dimension longer than 0.35 mm, oxidizing agent is preferably added only after most of the originally supplied nickel has been dissolved. After oxidizing agent is added, most or all of the remaining undissolved nickeliferous solid will then dissolve. The temperature of the reaction mixture of acid liquid and solid nickel preferably is room temperature at the beginning of dissolution but is raised in steps to a final value of at least 65° C. and maintained at that temperature for several hours.
Abstract: Phosphate conversion coatings having very fine crystal size are obtained using liquid compositions containing phosphate, zinc cations and relatively low concentrations of Co, Ni and Mn.
Abstract: An adhesive bonding process for making vehicle structures wherein a surface portion of an aluminum alloy body is anodized in an aqueous solution of hypophosphorous acid (H3PO2) to form an anodic oxide coating. A layer of adhesive is applied onto the surface portion and the adhesive coated anodized surface portion is joined to an adjacent metal structure.
The phosphorous acid anodizing is preferably carried out for less than 1 minute at about 5-40 volts and a current density of about 1-50 mA/cm2 in a solution containing about 1-25 wt % hypophosphorous acid. Anodization time is more preferably about 10-30 seconds and is about 20 seconds in a particularly preferred embodiment.
Abstract: The present invention is drawn to a method of lowering the net resistivity of an interconnect by depositing a monomer layer upon an aluminum bonding pad, the treatment thereof to cross link the monomer to form an electrically conductive polymer, and simultaneously, the substantial reduction of alumina, Al2O3, to metallic aluminum. In the method of the present invention, deposition of a monomer layer in a solvent, volatilization of the solvent, and contact with a strong oxidizer such as a potassium permanganate allows for the use of the strong oxidizer without the hindrance of having to deal with a manganese oxide husk on the surface of the aluminum bonding pad. Preferably, the chemical qualities of the monomer will include the tendency to be a reducing agent to the native oxide film of the bonding pad. By selecting a monomer that tends to reduce rather than to oxidize, the problem of thickening the native oxide film is avoided.
Abstract: Disclosed is a process for the production of Zintl compounds by thermal decomposition of heterometallic phosphinidene complexes. The heterometallic phosphinidene complex typically comprises at least two metals, at least one of which is selected from a Group I metal, M1, and another being a metal M2, selected from Group 13, 14 or 15 of the Periodic Table. The heterometallic phosphinidene complex further comprises one or more phosphinidene ligands, [PR], wherein R is typically a substituted or unsubstituted hydrocarbyl group, and a Lewis base stabilizing ligand. Thermal decomposition of the heterometallic phosphinidene complexes in accordance with the invention forms a Zintl compound comprising metals M1 and M2 coordinated to Lewis base stabilizing ligands, Lg. The invention further provides a process for removal of the stabilizing ligand from the Zintl compounds to form an intermetallic compound.
Type:
Grant
Filed:
December 22, 2000
Date of Patent:
January 7, 2003
Inventors:
Dominic Wright, Alex Hopkins, Neil Stoodley
Abstract: An aqueous solution contains phosphate for producing layers of phosphate on metal surfaces selected from the group consisting of iron, steel, zinc, zinc alloys, aluminum and aluminum alloys. The solution contains 0.3 to 5 g Zn2+/1, 0.1 to 2 g nitroguanidine/1 and 0.05 to 0.5 g hydroxylamine/l, with an S-value amounting to 0.03 to 0.3 and the ratio of the weight of Zn2+ to P2O5=1:5 to 1.30.
Type:
Grant
Filed:
January 9, 2001
Date of Patent:
December 24, 2002
Assignee:
Metallgesellschaft Aktiengesellschaft
Inventors:
Peter Schubach, Joachim Heitbaum, Thomas Kolberg, Margit Fleischhacker-Jeworrek, Peter Jorns, Michael Deemer, Ralf Stickler, Jurgen Specht, Michael Lenhard
Abstract: A process of production of a compressor shoe superior in durability and reduced in manufacturing cost, wherein a process of quenching the shoe is performed in a vacuum, inert gas, or modified gas so as to prevent oxidation of the chrome and manganese of the surface of the material or the quenching process is performed after forming an antioxidation film on the surface of the material to prevent the oxidation of the chrome and manganese.
Abstract: An especially effective hydrophilicizing treatment for solid surfaces, particularly those of conversion coated aluminum, is a liquid mixture of water, organic polymer molecules that include sulfonyl/ate moieties, and preferably also a substance made by mixing with aqueous phosphoric acid at least one metal, metal oxide, or metal hydroxide so as to form a transparent liquid mixture. The treatment liquid preferably has a nearly neutral pH and is applied to a substrate and dried in place by exposure to heat.
Abstract: Sequentially applying two different coatings, in two steps, to metallic surfaces. Metallic surfaces are contacted at temperatures from 10-100° C.
Type:
Grant
Filed:
October 6, 2000
Date of Patent:
December 3, 2002
Assignee:
Chemetall GmbH
Inventors:
Sean M. Wetterer, Lars Sebralla, Manfred Walter
Abstract: When a phosphate ester or a dispersed wax is added to a conventional liquid phosphate conversion coating composition, the resulting phosphate coating formed on a metal substrate has a lower coefficient of friction after being oiled than it would have had if the additive had been omitted. The corrosion resistance and paint adhesion properties expected from the conversion coating are not substantially diminished by the additive. Particularly good results are achieved if the phosphate coating composition contains calcium and ferrous cations and the liquid phosphate conversion coating composition is dried into place on the substrate.
Abstract: An anticorrosion treatment of an aluminium/zinc alloy surface is disclosed. The treatment includes the steps of forming on the alloy surface a coating of a solution which contain 5-40 grams of molybdenum per litre of the solution, 2-19% by volume of a phosphoric acid, and a surface etchant. The treatment also includes drying the coating to form a dried coating having a loading of molybdenum of at least 10 mg/m2 of the dried coating and of phosphorus of at least 15 mg/m2 of the dried coating.
Abstract: A process for controlling the layer weight during the phosphating of steel strip zinc-coated on one or both sides, using a phosphating solution which contains 1 to 6 g/l zinc ions and 10 to 30 g/l phosphate ions, characterized in that a Fe(II) ion content within the range of 3 to 100 mg/l is established in the phosphating solution. The higher the Fe(II) content, the lower is the layer weight. An alteration in the Fe(II) content of 3 to 20 mg/l results in an alteration in the layer weight of about 0.1 g/m2.
Type:
Grant
Filed:
February 16, 2001
Date of Patent:
October 8, 2002
Assignees:
Henkel Kommanditgesellschaft fur Aktien, Thyssen Krupp Stahl AG
Inventors:
Joerg Riesop, Franz-Gerd Ricke, Frank Panter, Dieter Geruhn, Hubertus Peters, Manfred Wessel, Andreas Klare
Abstract: A process for the production of a rubber-to-metal bond on steel, galvanized steel, aluminum and/or magnesium is provided The process comprises at least the following steps:
a) chemical pretreatment of the metal parts,
b) intermediate rinsing, and
c) vulcanizing-on of natural or synthetic rubber using primers and/or binders.
The chemical pretreatment in step a) is carried out with an aqueous solution with a pH value of 3.5 to 5.5 which contains:
4 to 20 g/l of phosphate ions,
0.1 to 1 g/l of free or complexed fluoride, and
0.04 to 1 g/l of nitrate ions.
Type:
Grant
Filed:
July 19, 1996
Date of Patent:
August 27, 2002
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Wolf-Dieter Beiersdorf, Werner Gruber, Hans Scheer, Juergen Foell, Birgit Gies, Peter Kuhm, Franz-Josef Schueller
Abstract: There are provided a painted structure of a magnesium alloy molded product having an aesthetic appearance, a painting method of forming the patented structure of the magnesium alloy molded product having an aesthetic appearance, and a casing fabricated using the magnesium alloy molded product. The painted structure of the magnesium alloy molded product has flow marks of which maximum depth is 100 &mgr;m and maximum opening width is 0.5 mm. An anticorrosive film is formed on a surface of the magnesium alloy molded product, and a painted film having an average surface roughness of 10 &mgr;m or more and a thickness of 80 &mgr;m or more is formed on a surface of the anticorrosive film.
Type:
Application
Filed:
December 6, 2001
Publication date:
June 13, 2002
Applicant:
MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
Abstract: A process for phosphating metal surfaces in which a nitrite- and nickel-free zinc-containing phosphating solution is applied to the metal surfaces which, if desired, are then rinsed and subsequently after-rinsed with an aqueous solution with a pH value of 3 to 7 which contains 0.001 to 10 g/l of one or more of the cations of Li, Cu and Ag.
Abstract: Concentrates containing (a) an hydroxylamine sulfate accelerator, and (b) zinc, nickel, manganese, and phosphate ions are formulated into aqueous coating solutions for treating metal surfaces, such as ferrous, zinc, and aluminum surfaces. In the process of using this solution, hydroxylamine ions become depleted or reduced in concentration in the applied solution. A replenishing solution is added for reusing the solution until the replenished coating solution reaches a sulfate level of no more than 14 g/l.
Type:
Grant
Filed:
January 31, 2000
Date of Patent:
April 9, 2002
Assignee:
Henkel Corporation
Inventors:
Michael L. Sienkowski, Gerald J. Cormier
Abstract: An aqueous surface treatment bath that has a pH from 2.5 to 4.5 and contains at least 0.1 g/L of orthophosphate ions, from 0.1 to 3 g/L of condensed phosphate ions, from 0.1 to 0.5 g/L of free hydrofluonc acid, and at least 0.1 g/L of water-soluble polymer molecules that, except for short end groups as generally known in the art, conform to general formula (1) below:
in which n is the degree of polymerization and has an integral value or each molecule, the average value of n for all of the molecules present being from 2 to 50 and not necessarily integral, X is a hydrogen atom or a moiety Y conforming to general formula (II)
wherein each of R1 and R2 is an alkyl moiety or a hydroxy alkyl moiety having from 1 to 3 carbon atoms each,
the total number of moieties Y having a ratio to the total number of aromatic rings that is from 0.2:1.0 to 1.0:1.
Abstract: A method for inhibiting the formation of stains, especailly water stains, on the exterior surface of aluminum alloy products. The method entails contacting the exterior surfaces of these products, particularly sheet or plate products, extrusions and/or forgings made from 5000 or 6000 Series aluminum alloys, with an organophosphonic or organophosphinic acid-derived material. Preferably, liquid forms of this material are added to an alcohol or water-based carrier solution, then sprayed, dipped, painted or rolled onto the surfaces of flat sheet or plate products to enhance their brightness. Other more complex shapes may be dipped into material baths.
Type:
Application
Filed:
May 29, 2001
Publication date:
January 31, 2002
Inventors:
Gary A. Nitowski, Raymond J. Colbert, Karl Wefers, Daniel D. Roup, Larry F. Wieserman, Paul R. Ziman
Abstract: Fairly pure metallic nickel may be efficiently dissolved in non-oxidizing acid. If the nickel includes individual pieces longer than 0.5 mm in any linear dimension, oxidizing agent is preferably added from the beginning of dissolution, while if the nickel is powdered so that no single piece has a linear dimension longer than 0.35 mm, oxidizing agent is preferably added only after most of the originally supplied nickel has been dissolved. After oxidizing agent is added, most or all of the remaining undissolved nickeliferous solid will then dissolve. The temperature of the reaction mixture of acid liquid and solid nickel preferably is room temperature at the beginning of dissolution but is raised in steps to a final value of at least 65° C. and maintained at that temperature for several hours.
Abstract: A method of treating a metallic surface which comprises treating a metal-coated steel panel with a nonchromate metallic surface treating agent containing, in each liter thereof, (a-1) a silane coupling agent and/or a hydrolytic condensation product thereof, (a-2) water-dispersible silica in a proportion, and (a-3) a zirconium compound and/or a titanium compound, drying the treated steel panel and coating it with an anticorrosion coating agent containing, in each liter of an aqueous resin solution or dispersion, (b-1) a silane coupling agent and/or a hydrolytic condensation product thereof, (b-2) water-dispersible silica and (b-3) at least one phosphorus-containing ion selected from among phosphate ion, phosphite ion and hypophosphite ion.
Abstract: The coating structure having a corrosion resistance of the invention contains a formation film formed on the surface of an aluminum alloy material. The formation film is subjected to a zirconium phosphate treatment. Because the zirconium phosphate reacts with an oxide film on the surface of the aluminum alloy to form a zirconium boehmite layer and to increase the adhesion of the coating material, a corrosion resisting structure is obtained without need of a sealing treatment while restraining the increase of the product cost. Also, a primer layer is formed on the outer surface of the formation film and the primer layer is composed of phosphomolybdic acid.
Abstract: The present invention is relates to pretreatment chemicals metal materials to be painted containing at least one kind of sulfur-containing compounds and at least one of phosphorus ion-containing compounds, and an anticorrosive treatment of metal materials, by the pretreatment chemicals.
Abstract: This invention provides for metal surfaces which when derivatized with &agr;-&ohgr; bis-functionalized substantially linear aliphatic, including fluoroaliphatic acids and metal salts thereof exhibit changes in surface properties. In particular, composites formed from polymers and metallic surfaces derivatized according to a process of the present invention exhibit surprising durability.
Abstract: Disclosed is a composition and a process for anticorrosive treatment of the surface of non-ferrous metal. The composition is obtainable by treating an aqueous solution of CrO3 and an inorganic acid with phosphorous acid as a reducing agent until substantially 100% of hexavalent chromium contained in the starting solution is reduced.
Abstract: A phosphatizing system for phosphatizing an object including a closed-loop phosphatizing assembly is provided configured to pass a phosphatizing reagent solution over an object during a phosphatizing procedure. The phosphatizing assembly includes a collection compartment in fluid communication with a run-off portion of a subfloor assembly supporting the object for receipt of substantially all the reagent run-off fluids from the subfloor assembly. A storage assembly is configured to pass a rinsing solution over the object to wash the reagent solution therefrom during a finishing rinse procedure performed after the phosphatizing procedure. This storage assembly includes a storage compartment in fluid communication with the run-off portion for receipt of substantially all the rinsing/reagent run-off fluids from the subfloor assembly.
Type:
Grant
Filed:
November 25, 1998
Date of Patent:
May 22, 2001
Assignee:
EZ Environmental Solutions, Corporation
Inventors:
Scott A. Comiso, Vincent J. Ferrari, Neil J. Bailer, Michael D. Damron, Nhan Nguyen Thanh Lam
Abstract: A highly corrosion resistant and paint adherent surface coating on aluminiferous metals can be provided very rapidly, if desired in less than one second, by contacting the surface with an aqueous acid liquid treating composition containing as solutes specified proportions of phosphate ions, titanium containing materials, fluoride, and an accelerator, the accelerator is preferably at least one of nitrous acid, nitric acid, tungstic acid, molybdic acid, permanganic acid, water soluble salts of all of these acids, and water-soluble organoperoxides.
Abstract: Metal surfaces are contacted with a solution of a process bath (1), for example a phosphating or pickling solution, which comprises several components in aqueous solution, the composition of the process bath (1) being maintained within a given range by addition of solutions or gases, in particular air. The profitability is improved considerably if the solution of the process bath (1) is circulated via a first line (2) and a circulating pump (3) and the solution to be added and/or the gas to be added is fed to the process bath where, as a consequence of the ending of the line (2), vigorous thorough mixing prevails, or if the solution to be added or the gas to be added is fed to a suction pump (4), the solution to be added or the gas to be added mixing with the circulated solution.
Type:
Grant
Filed:
July 16, 1999
Date of Patent:
January 9, 2001
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Matthias Hamacher, Berhard Kotschy, Peter Kuhm
Abstract: An aqueous liquid surface treatment composition having a pH value not more than 6.5 and containing phosphoric acid ions, condensed phosphoric acid ions, an oxidizing agent, and a water-soluble polymer consisting, except for end groups, of polymer units expressed by formula (I), in a weight ratio of 0.1 to 30:0.1 to 10:0.1 to 10:0.1 to 20 respectively, when brought into contact with an aluminiferous metal surface, rapidly forms on the surface a conversion coating that has good corrosion resistance and adhesion to subsequently applied organic coatings such as paint and is less easily damaged by mechanical stresses than prior art conversion coatings.
Abstract: A metallic surface treating solution characterized in that it is an aqueous solution at pH 0.1 to 6.5 comprising a source of at least one selected from the group consisting of Mo, W, V, Nb, Ta, Ti, Zr, Ce, Sr, and trivalent chromium, an oxidizing substance source, and an oxyacid or oxyacid salt of phosphorus or its anhydride, a surface treating method using the treating solution, and metals thereby treated on the surface.