Abstract: An improvement in a method of bonding copper and a resin together wherein a copper oxide layer is formed on the surface of copper by the oxidation of metallic copper, the copper oxide layer is reduced to metallic copper with an aqueous reducing solution containing at least one amine borane represented by the general formula: BH3NHRR′ (wherein R and R′ are each a member selected from the group consisting of H, CH3, and CH2CH3), and the metallic copper is bonded to a resin. According to the improvement, a reducing stabilizer is added to the reducing solution in an amount sufficient to decrease consumption of the amine borane during reduction to a level less than that consumed in the absence of the reducing stabilizer during the course of the copper oxide reduction process, wherein the stabilized reduction process is initiated in a reasonable time and the metallic copper layer resulting from the stabilized reduction process is resistant to acid attack.

Abstract: Metal surfaces, metal-oxide surfaces, metal-salt surfaces, silicon-comprising surfaces and/or high-molecular-weight aquoxide-comprising organic surfaces are coated. The coating is carried out with a reagent having a reactive group chosen from Si—H, Sn—H, and Ge—H. The reagent is applied in liquid, pasty, or solid form to the surface that is to be coated. Furthermore, the coating reaction requires the presence of an activator. A platinum metal in form of a compound or in metallic form is used as activator.

Abstract: The coating structure having a corrosion resistance of the invention contains a formation film formed on the surface of an aluminum alloy material. The formation film is subjected to a zirconium phosphate treatment. Because the zirconium phosphate reacts with an oxide film on the surface of the aluminum alloy to form a zirconium boehmite layer and to increase the adhesion of the coating material, a corrosion resisting structure is obtained without need of a sealing treatment while restraining the increase of the product cost. Also, a primer layer is formed on the outer surface of the formation film and the primer layer is composed of phosphomolybdic acid.

Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220° F.) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).

Abstract: A post-treatment method for copper on printed circuit boards is disclosed. The method comprises forming a cupric-based organometallic conversion coating on a copper surface of a printed circuit board, and then converting the cupric-based organometallic conversion coating to a cuprous-based organometallic conversion coating. The resulting cuprous-based organometallic conversion coating is desirable in that it improves copper to dielectric bond integrity.

Abstract: A process for sealing the surface coating formed by anodizing an aluminum or aluminum alloy substrate (for example, aerospace, commercial, and architectural products), the process including the steps of: (a) providing an aluminum or aluminum alloy substrate with a surface coating formed thereon by anodizing the aluminum or aluminum alloy substrate; (b) providing a sealing solution comprising a dilute solution of a rare earth metal salt selected from the group consisting of cerium salts and yttrium salts; and (c) contacting the substrate with the sealing solution for a sufficient amount of time to seal the surface coating on the substrate. Also disclosed is a chemical sealing solution for sealing the surface coating formed by anodizing an aluminum or aluminum alloy substrate, the solution being a dilute solution of a rare earth metal salt selected from the group consisting of cerium salts and yttrium salts.

Abstract: The present invention is drawn to a method of lowering the net resistivity of an interconnect by depositing a monomer layer upon an aluminum bonding pad, the treatment thereof to cross link the monomer to form an electrically conductive polymer, and simultaneously, the substantial reduction of alumina, Al.sub.2 O.sub.3, to metallic aluminum. In the method of the present invention, deposition of a monomer layer in a solvent, volatilization of the solvent, and contact with a strong oxidizer such as a potassium permanganate allows for the use of the strong oxidizer without the hindrance of having to deal with a manganese oxide husk on the surface of the aluminum bonding pad. Preferably, the chemical qualities of the monomer will include the tendency to be a reducing agent to the native oxide film of the bonding pad. By selecting a monomer that tends to reduce rather than to oxidize, the problem of thickening the native oxide film is avoided.

Abstract: A substrate for an electrophotographic photoconductor having an anodic oxidation film on the surface is subjected to two-step sealing treatment in which the substrate is sealing treated with nickel fluoride as a sealing agent, and then with nickel acetate as a sealing agent. Therefore, an electrophotographic photoconductor using the substrate for an electrophotographic photoconductor is small in charge potential difference between the first turn and the second turn and after, and does not generate a fogged image defect or the like even without preliminary charging before printing.

Abstract: Process for stainless steel pickling consisting in placing the material to be treated in a bath kept at a temperature ranging from 30.degree. C. to 70.degree. C. and containing:a) HClb) Fe.sup.3+c) HFd) emulsifiers, wetting agents, polishing agents, acid attack inhibitors;the bath being fed continuously with:an air flow equal to at least 3 m.sup.3 /h per m.sup.3 bath min. and an oxidizer quantity adjusted to the bath redox potential to be kept at 250 mV min.

Abstract: Process for post-sealing anodized metal surfaces, characterized in that the anodized metal is contacted with an aqueous solution for a period of between 0.5 and 2 minutes per micrometer of anodized coating thickness, which solution is at a temperature of between 75.degree. C. and its boiling point and has a pH of from 5.5 to 8.5 and which contains:(a) a total of 0.0004 to 0.05 g/l of one or more cationic, anionic or non-ionic surfactants; and(b) a total of 0.0005 to 0.5 g/l of one or more organic acids selected from cyclic polycarboxylic acids having 3 to 6 carboxyl groups and/or phosphonic acids.Non-ionic surfactants are preferred as the surfactants while polyphosphinocarboxylic acids are preferred as the acids. Alkali and/or alkaline earth metal cations, preferably Li and/or Mg ions, are optionally present in quantities of 0.0001 to 5 g/l.

Abstract: Substantially improved hydrophilicity can be provided to a metal substrate, particularly an aluminum alloy of the type used for heat exchanger fins, that has been previously provided with a conventional chromium oxide conversion coating, by drying into place on the surface of the chromium oxide conversion coating an aqueous liquid hydrophilicizing treatment composition containing at least one of: (i) aproduct or products of reaction between dissolved phosphoric acid and at least one of elemental metal, metal oxides, and metal hydroxides in contact therewith; (ii) tungstate ions; and (iii) at least one of sulfate or molybdate ions together with polyethyleneimine. Most preferably, a solution formed by dissolving MgO in aqueous H.sub.3 PO.sub.4 in the proper stoichiometric amount to form an aqueous solution of Mg(H.sub.2 PO.sub.4).sub.2 with a pH of 4.5-5.5 is used for the hydrophilicizing treatment.

Abstract: A method for reducing the corrosion potential of steel vessels and piping used in nuclear reactors, in particular steel vessels and piping carrying high temperature water and/or steam which has a concentration of oxygen therein. A metal hydride is added to the water, the hydrogen of such metal hydride combining with oxidizing agents, typically oxygen, present in the water to reduce the concentration of such oxidizing agents. In the preferred embodiment the metal of the metal hydride is a metal that is capable of reacting with oxygen to form a substantially non-water soluble and substantially electrically insulating compound on the surface of the steel, and in particular is one that may react with and become deposited or incorporated into a pre-existing thin oxide film layer on the surface of the steel to thereby render such thin oxide layer substantially non-electrically conducting.

Abstract: A process for forming a conversion coating on the surface of a metal, including: contacting the metal with an acidic solution containing an oxidant in order to initiate growth of a metal oxide cell structure on the metal surface; contacting the metal with water for a period of time sufficient to thicken the oxide and form a metal oxide containing layer of a desired thickness; and treating the metal with one or more rare earth elements in order to impregnate and substantially seal the metal oxide.

Abstract: A process for treating metal surfaces that includes first contacting the metal surface with a particular acidic peroxide adhesion promoting composition, followed by contacting that metal surface with an alkaline solution. This treatment is particularly suitable for treating metal surfaces used in printed circuit multilayer construction.

Abstract: An aqueous liquid chromate free primary composition for forming a protective coating on metals, particularly aluminum, is made by reacting cobalt(II) cations, carboxylate anions, at least one other type of coordinate complexing agent for cobalt(III) cations, and an oxidizing agent in an aqueous solution in which the molar ratio of carboxylate anions to cobalt(II) cations is from 0.10 to 6.8 and the aqueous solution contains no more than 1% of each of ammonia, ammonium ions, and nitrite ions. The primary layer formed by this or any other composition that forms a coating containing metal atoms and oxygen atoms on a metal substrate is advantageously sealed by further treatment with an aqueous solution of sodium ammonium decavanadate, optionally after an intermediate step of immersing in water for a few minutes between the primary treatment and the sealing treatment.

Abstract: A method for creating an oxide coating on the surface of a component formed from austenitic stainless steel or nickel alloy steel is set forth. The component has a naturally formed oxide film at the surface. The naturally formed oxide is enhanced through a process comprising at least two steps. In the first step, the component is heated in the presence of circulating dry air for a first period of time at a temperature of approximately 300 degrees centigrade. In the second step, the component is heated in the presence of static dry air at an elevated pressure for a second period of time at a temperature that is higher than the temperature during the first period. The exterior portion of the enhanced oxide coating is removed with an oxidizing treatment whereby an oxide coating having a high ratio of chromium to iron is exposed at the surface of the stainless steel.

Abstract: A process for improving the adherence of paint applied after thin-film anodization is characterized in that the anodized metal surfaces are brought into contact with an aqueous solution containing one or more of the following components: (a) 200 to 2000 ppm of a homopolymer or copolymer of acrylic acid, methacrylic acid, and/or their esters; (b) 200 to 3000 ppm of a poly(vinyl phenol) compound in which at part of the phenol rings carry an alkylamino substituent; (c) 200 to 3000 ppm of hexafluorotitanic acid, hexafluorozirconic acid, and/or their anions.

Abstract: A method for treating the surface or surfaces of an aluminium or aluminium alloy containing substrate to confer corrosion resistance in which a porous layer is created on the surface or surfaces and then the surface or surfaces are treated with a solution or gel comprising a metavanadate ion, and further treated with a solution comprising a metal ion selected to coprecipitate with the metavanadate ion to form a sparingly soluble compound within the pores of the porous layer. A corrosion resistant coating for aluminium or aluminium alloy comprising a porous surface layer containing within the pores a deposit of a sparingly soluble metal metavanadate. The porous layer may be an oxide layer produced for example by acid anodising.

Abstract: A process for sealing anodized metal surfaces is characterized by bringing the anodized metal into contact with an aqueous solution at a temperature from 75.degree. C. to the boiling point of the solution for a time equal to from 0.5 to 2 minutes per micrometer of anodized layer thickness. The solution contains: a) from 0.0001 to 5 g/l of one or more alkali metal and/or alkaline earth metal ions and b) from 0.0005 to 0.5 g/l of one or more organic acids selected from: polycarboxylic acids with from 3 to 6 carboxyl groups; phosphonic acids; and/or polyphosphinocarboxylic acids, the solution containing a greater amount of metal ions of group a) than is needed to insure complete neutralization of the acids of group b).

Abstract: Aluminium oxide sealant compositions, concentrates, and processes employing the same are described which comprise a combination of certain sulphonated aromatic compounds and condensates of aldehydes and certain other sulphonated aromatic compounds. Unexpected improvements in seal quality are obtained using the compositions of the invention, and in the substantial absence of smut formation.

Abstract: A process for sealing anodized metals without using any heavy metals comprises a first step in which the anodized metal is contacted for a period of between 3 and 30 minutes (for an anodized layer thickness of 20 .mu.m) with an aqueous solution which has a temperature from 15.degree. to 35.degree. C. and a pH between 5.0 and 6.5 and contains from 0.1 to 3 g/l of lithium ions and from 0.1 to 5 g/l of fluoride ions and a second step in which the anodized metal is contacted for a period from 5 to 30 minutes (for an anodized layer thickness of 20 .mu.m) with water or an aqueous solution of substances which prevent the formation of a sealing coating, the solution having a pH from 5.5 to 8.5 and a temperature from 80.degree. to 100.degree. C.

Abstract: In the method for stabilizing an artificial patina layer produced on a copper panel, a transparent cover layer consisting of water glass and hydroxycellulose is applied onto the patina layer immediately after it is produced. The cover layer can consist of sodium or potassium water glass and hydroxycellulose, and is applied onto an artificially patinated copper panel by either immersion or spraying. After immersion or spraying, the cover layer is dried. This occurs in an atmosphere with a temperature of approximately 20.degree. C. to 150.degree. C., within a time period of approximately one to one and a half hours.

Abstract: The present invention relates to a bond enhancement process for promoting strong, stable adhesive bonds between surfaces of copper foil and adjacent resin impregnated substrates or superimposed metallic sublayers. According to the process of the invention, a black oxide-coated copper surface is treated with an aqueous reducing solution containing sodium metabisulfite and sodium sulfide to convert the black oxide coating to a roughened metallic copper coating. The roughened metallic copper-coated surface is then passivated and laminated to a resin impregnated substrate. The bond enhancement process is especially useful in multilayer printed circuit fabrication and in the treatment of copper circuit lines and areas which are disconnected from each other, that is, which do not have electrically conductive continuity.

Abstract: An aqueous liquid chromate free primary composition for forming a protective coating on metals, particularly aluminum, is made by reacting cobalt(II) cations, carboxylate anions, at least one other type of coordinate complexing agent for cobalt(III) cations, and an oxidizing agent in an aqueous solution in which the molar ratio of carboxylate anions to cobalt(II) cations is from 0.10 to 6.8 and the aqueous solution contains no more than 1% of each of ammonia, ammonium ions, and nitrite ions. The primary layer formed by this or any other composition that forms a coating containing metal atoms and oxygen atoms on a metal substrate is advantageously sealed by further treatment with an aqueous solution of sodium ammonium decavanadate, optionally after an intermediate step of immersing in water for a few minutes between the primary treatment and the sealing treatment.

Abstract: Anodized aluminum coatings employed in semiconductor processing equipment are treated to reduce their sensitivity to halogenated species. The pores of the aluminum oxide surface can be filled either by a metal, such as magnesium or aluminum, forming the corresponding metal oxide that is resistant to reaction with halogens, or by filling the pores with a getter for halogens, such as hydrogen ions. The hydrogen ions adsorbed on the surface of the aluminum oxide react with halogens to form volatile hydrogen halides that can be pumped away in the exhaust system of the semiconductor processing chambers, thereby preventing or reducing reaction of the underlying aluminum oxide with the halogens.

Abstract: Surface preparation methods and materials that provide corrosion protection for aluminum and its alloys without the use of chromate and that protects aluminum surfaces against corrosion nearly as well as a chromate conversion coating. In accordance with the present methods, aluminum parts are degreased in a general purpose cleaner and rinsed in hot tap water. The parts are then cleaned using alkaline cleaner and then rinsed in cold tap water. The parts are then deoxidized using one of two alternative steps. The parts may be deoxidized using a 20-25 volume percent Smut-Go NC solution at room temperature for 15-25 minutes. The parts may alternatively be deoxidized using a solution of 10% HNO.sub.3 and 3% NaBrO.sub.4 dissolved in water at room temperature for 15-25 minutes. The deoxidized aluminum parts are then rinsed in cold tap water. The parts are then immersed in boiling deionized water and then sealed using a 1% LiNO.sub.3, 10% Al(NO.sub.3).sub.3 and 10% aluminum silicate solution.

Abstract: The present invention provides a method for preparing an aluminum foil comprising the steps of roughening and anodizing an aluminum foil, posttreating said roughened and anodized aluminum foil with an aqueous bicarbonate solution and subsequently rinsing said posttreated foil with water characterized in that the temperature of said water ranges from 30.degree. C. to 55.degree. C.

Abstract: Aluminum surfaces are protected with increased corrosion resistance by anodize, and sealing with a liquid fatty acid free of flammable solvents, suitably in the presence of a heterocyclic aromatic azole treating agent where the aluminum surface is of a copper containing aluminum alloy.

Abstract: A non-chromium aluminum conversion coating composition for coating aluminum or an aluminum alloy which has as the essential ingredients an alkaline metal permanganate and aluminum nitrate and a pH of about 2.5 to about 4.0. The composition is effective in protecting aluminum and aluminum alloys for more than 168 hours in salt fog at 95.degree. F. according to standard ASTM method B-117. The process, of coating the aluminum or aluminum alloy is generally carried out by cleaning the aluminum or aluminum alloy with sodium hydroxide, and nitric acid-hydrofluoric acid mixture, and then coating with the permanganate-nitrate composition. There is also provided an anodized aluminum or aluminum alloy coated with a non-chromium permanganate composition.

Abstract: This invention relates to a process and composition for sealing anodically oxidized aluminum surfaces, the composition having an effective amount of a source of alkali metal ions especially lithium ions. The process of the invention involves contacting an anodically oxidized aluminum surface with the aqueous sealing solution of the invention.

Abstract: An aluminum material is surface-treated with an aqueous solution containing 0.005 mol/lit. or more of a chelating agent and 5 g/lit. or more of an organic amine and having 100 ppm or less of phosphoric acid radical ion concentration and 500 ppm or less of sulfuric acid radical ion concentration, until its surface has a color tone (S) of:S=(X.sup.2 +(3.388Z-3Y.sup.2).sup.1/2.gtoreq.70wherein X, Y and Z represent the tristimulus values of color.The aluminum material can be surface-treated while setting the treating conditions on the basis of a specific color tone detectable by colorimetry, without relying on experience and intuition. The surface-treated aluminum material can have a good anticorrosion, have good color change preventive properties, a good adhesion of coatings and a beautiful surface appearance.

Abstract: An alloy has less stable oxides, e.g. nickel oxide, chromium oxide, and iron oxide on a surface (FIG. 1 ). The material has specific reaction elements such as titanium and aluminum in a relatively low concentration throughout the alloy. At an elevated temperature, the surface of the alloy is subject to a fluid which reduces the nickel, chromium, and iron oxides and the aluminum or titanium adjacent the surface reduces components of the fluid (FIG. 2 ). The alloy is maintained at the elevated temperature in the presence of the fluid until a barrier film of the specific reactive elements is formed. In one embodiment, the working fluid is a gaseous fluid of hydrogen or an inert gas with water vapor. The hydrogen of the water vapor reduces the less stable oxides and the oxygen oxidizes the specific reaction elements. In another embodiment, the working fluid is a liquid metal other than lithium which carries oxygen.

Abstract: This invention relates to a process and composition for sealing anodically oxidized aluminum surfaces, the composition having an effective amount of a source of alkali metal ions especially lithium ions. The process of the invention involves contacting an anodically oxidized aluminum surface with the aqueous sealing solution of the invention.

Abstract: An aluminum sheet for use in spot welding has an anodic oxide film with a thickness of 50 .mu.m or less on at least one surface thereof. The anodic oxide film is preferably overlaid with a plating layer predominantly comprising at least one metal selected from the group consisting of Zn, Cr, Co, Ni, Fe, and Mn. The aluminum sheet can be produced by subjecting an aluminum or aluminum alloy sheet to anodic oxidation in an acidic solution having a pH of 4 or less conditions of from 2 to 200 V in voltage and from 0.2 to 200 seconds in duration, optionally followed by electroplating in an acidic plating bath.

Abstract: Seal coating compositions and methods of applying them to metallic surfaces, particularly aluminum or alloys thereof, beating a previously formed protective coating, particularly a conversion coating, such as a chromate or phosphate coating or a chrome-free metal oxide conversion coating, or a coating formed by anodization, provide improved corrosion resistance beyond that provided by the previously formed protective coating. The seal coating compositions preferably contain at least one of benzotriazole, nickel and/or cobalt cations and borates, or aminated polymers of vinyl styrene.

Abstract: A method for forming a protective layer on a copper surface is set forth. The surface of degreased strips or sheets of copper are roughened by mechanical treatment in a controlled manner. The roughened surfaces of the strips or sheets are then chemically treated to bring about a green patination. After the chemical treatment, the strips or sheets are stored in a climate-controlled space.

Abstract: Copper alloys of aluminum are afforded extended protection against surface corrosion by anodizing the aluminum surface to be protected, treating the surface with a heterocyclic aromatic azole treating agent having up to 16 carbon atoms before, during or after the anodizing step, and coating the treated surface after anodize with a fatty acid of 5 to 24 carbon atoms.

Abstract: A method is provided by which a corrosion-resistant barrier layer composed of a rare earth oxide coating incorporated in an oxide film is developed on the surface of a metal for the purpose of improving the corrosion resistance of the metal. The method is particularly suitable for forming a corrosion-resistant barrier on an aluminum alloy, in which the corrosion-resistant barrier layer is composed of a cerium oxide coating incorporated with a uniform aluminum oxide film which has been formed on the aluminum alloy. The corrosion-resistant barrier layer exhibits a broader passivation range as compared to chromium conversion coatings typically used in the art. Simultaneously, the method of this invention avoids the environmental hazards associated with chromium conversion processes, making the method more suitable for manufacturing operations. Furthermore, the method of this invention does not employ hazardous compounds, making the process suitable for a manufacturing environment.

Abstract: A method of protecting a non-chromium anodized aluminum or aluminum alloy by rinsing the anodized aluminum or aluminum alloy with warm water to warm the anodized aluminum or aluminum alloy, coating the warm anodized aluminum or aluminum alloy with, a non-chromium alkali metal permanganate solution having a pH in the range of about 4.0 to about 8.0, and a temperature of from about 170.degree. F. to about 212.degree. F., and forming a non-chromium mixed metal oxide coating of aluminum and manganese oxides on the anodized aluminum or aluminum alloy.

Abstract: A method for inhibiting the corrosion of metals exposed to aqueous mixtures of sulfuric acid and hydrocyanic acid by the use of iron salts.

Abstract: Rust inhibiting compositions having improved elasticity properties are provided. The compositions contain oxime based rust converter compounds formulated with a latex based paint to provide a flexible film coating that acts as a barrier to oxygen and water vapor diffusion to the metal surface. Methods for applying the rust inhibiting compositions to metal surfaces are also provided.

Abstract: Seal coating compositions and method of applying same, to metallic surfaces, particularly aluminum or alloys thereof, containing a previously formed protective coating on the metal surface, to provide for improved corrosion resistance beyond that provided by the previously formed protective coating. Aqueous solutions of the seal coating components are applied to the metal surface containing the previously formed coating which is subsequently rinsed and dried to provide metal articles having improved resistance to corrosion.

Abstract: A method is described of compacting an anodically produced layer of oxide on parts of aluminum or aluminum alloy. In accordance with the invention, the oxide layer is compacted in two process stages, the parts being pretreated in the first process stage in a solution containing about 6% cobalt fluoride and about 30% nickel fluoride in completely desalinified water at about 30.degree. C. for about 10 minutes and then being treated in a second process stage in completely desalinified water with the addition of a coating inhibitor of about 2 ml/l of triazine derivative at an operating temperature of about 70.degree. C. to the boiling point for about 50 minutes.

Abstract: Metallic articles, and method for making same, having a thin, adherent, chemically formed coating on their surface which preserves the uncoated article appearance and provides a unique combination of functional properties including resistance to chipping and flaking during elevated temperature use, resistance to corrosion from chemicals in the form of gases or aqueous acidic or alkaline solutions including salt spray, organic solvents, oils and vehicle fuels and suitability as a base for paint for parts within the engine compartment of vehicles.

Abstract: An method of providing a protective coating on the surface of aluminum or aluminum alloys, comprising: removing contaminants from the surface; exposing the surface to water at 50.degree. to 100.degree. C. to form a porous boehmite coating on the surface; and exposing the boehmite-coated surface to an aqueous solution comprising a cerium salt and a metal nitrate at a temperature of 70.degree. to 100.degree. C. Oxides and hydroxides of cerium are formed within the pores of the boehmite to provide the protective coating, which provides corrosion resistance and improved paint adhesion.

Abstract: Corrosion resistance of anodized aluminum surfaces is improved by conditioning the surface with a low molecular weight (2-7 carbon atoms) alcohol, and sealing the surface with long chain (10-24 carbon atom) carboxylic acid at low temperatures below about 35-50 degrees centigrade, the alcohol being a solvent for the acid.

Abstract: A method of bonding copper and resin comprising the steps of:a) forming a layer of copper oxide on a surface of copper by oxidation of copper;b) reducing the layer of copper oxide thus formed to metallic copper with a reducing solution with the addition of an alkaline solution and a stabilizer at a controlled temperature under a circulated condition within a controlled period of time to modify its morphology; andc) forming a layer of copper oxide on a surface of the metallic copper by baking; andd) bonding the surface of the copper oxide formed by the baking and a resin together by heat-pressing.

Abstract: A method of making an electrical contact to a metal on which an electrically insulating native oxide is formed includes applying atoms or ions to the native oxide, heating the metal and oxide to a temperature and for a time effective to make the oxide, where the atoms and/or ions have been applied, electrically conducting and in electrical communication with the metal. The invention may be employed to establish electrical contacts with native oxides on aluminum, molybdenum, niobium, tantalum, titanium, tungsten, and zirconium. The atoms and ions include aluminum, antimony, arsenic, boron, gallium, indium, phosphorus, and silicon. An aqueous solution of boric acid and trisodium phosphate may be applied to establish electrically conductive regions in an oxide on niobium, tantalum, titanium, and stainless steel after heat treatment. Brushing with palladium wires mechanically applies palladium atoms to tantalum oxide to establish electrical contact to the tantalum after heat treatment.

Abstract: A process for producing a multilayer printed wiring board, characterized in that copper surface of internal layer(s) is chemically oxidized, thereby forming a brown or black, oxidized copper surface on the internal layer board; and said oxidized copper surface of said internal layer board is treated with an acidic aqueous solution of a reducing agent containing at least one material selected from the group consisting of zinc formaldehyde sulfoxylate and sodium hypophosphite.

Abstract: Disclosed is a method of producing a functionalized layer and an aluminum hydroxide layer on an aluminum substrate, the aluminum hydroxide layer located between the substrate and the functionalized layer. The method comprises the steps of subjecting an aluminum substrate to a hydrothermal treatment in an aqueous solution having a pH in the range of 2 to 14 to form a layer of aluminum hydroxide on said substrate and thereafter treating said aluminum substrate with a phosphorus-containing acid selected from phosphonic and phosphonic acid to form a functionalized layer on said aluminum hydroxide layer, the functionalized layer comprised of the reaction product of said acid and the layer of aluminum hydroxide.