Mechanical Memory Patents (Class 148/402)
  • Patent number: 5419788
    Abstract: The present invention relates to a method for increasing the useful life of a shape memory alloy (SMA) actuator, wherein the SMA element contracts on heating and elongates on cooling under an applied stress and that property is used as an actuating technique. More specifically, the present invention relates to the cooling aspect of the cycle and maintaining a martensite strain on the actuator SMA element at less than about 3% by limiting the upper stress on the element. In the most preferred embodiment, the element is a ribbon actuator prepared from a nickel-titanium SMA alloy.
    Type: Grant
    Filed: December 10, 1993
    Date of Patent: May 30, 1995
    Assignee: Johnson Service Company
    Inventors: Paul E. Thoma, Ming-Yuan Kao, Dwight M. Schmitz
  • Patent number: 5398916
    Abstract: A metallic damping body for damping shock-type and/or periodically changing stresses, consists of a shape-memory alloy material for effecting the damping. In order to be able to achieve a high damping effect even under a high mechanical stress on the damping body, the shape-memory alloy is selected such that it is in a state of austenitic microstructure at the operating temperature of the damping body. A sufficiently high mechanical prestress is applied to the damping body so that the damping working range is within the range of the pseudoelastic strain which starts below the proportionality limit in the stress/strain diagram of the shape-memory alloy. When the damping body is compressively stressed, a multiplicity of closely adjacent, small, uniformly distributed voids are present in the interior thereof, which together make up at least about 5%, preferably about 15 to 40%, of the total volume of the damping body.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: March 21, 1995
    Assignee: Mercedes-Benz AG
    Inventors: Johann Kramer, Rainer Renz, Martin Schlegl
  • Patent number: 5358796
    Abstract: Composite parts of Ni-Ti alloys joined to a different metal have a melt forged structure obtained through the reactive fusion of both metals, initiated by the fusion of at least one metal bordering on the joint interface and the application of pressure; a hot forged structure of Ni-Ti alloy obtained through softening the alloy at high temperature and applying pressure on the Ni-Ti alloy side of the joint; and a hot forged structure of the different metal obtained by softening the metal at high temperature and applying pressure on the different metal side of the joint.
    Type: Grant
    Filed: June 15, 1993
    Date of Patent: October 25, 1994
    Assignees: The Furukawa Electric Co., Ltd., Masunaga Menlo Park Co., Ltd.
    Inventors: Masayuki Nakamura, Kaisuke Shiroyama, Satoru Masunaga, Kazuo Murata
  • Patent number: 5344506
    Abstract: A shape memory alloy (SMA) actuator predeformed in compression actuates a cable cutter mechanism. A cable or other item to be cut is placed between an anvil and a movable blade affixed to the SMA element. The SMA element is heated by an electrical resistance heater to cause it to return to its undeformed elongated state, thereby moving the blade against the anvil to compress and sever the cable or other item. Ones of the shape memory alloy actuator have a plurality of parallelly arranged SMA elements, every other one of which is predeformed in compression and intermediate ones of which are predeformed in tension. The elements are coupled end-to-end so that, when they are heated to cause them to return to their undeformed states, their respective elongations and shrinkages combine at the output to produce an actuation that is the cumulation in the same direction of the changes of all the elements. The plurality of elements may be in a side-by-side or concentric arrangement.
    Type: Grant
    Filed: October 23, 1991
    Date of Patent: September 6, 1994
    Assignee: Martin Marietta Corporation
    Inventor: Dominick A. DeAngelis
  • Patent number: 5244513
    Abstract: Ferrous group shape memory alloys consisting essentially of Cr: 16.0-21.0 wt %, Si: 3.0-7.0 wt % and Ni: 11.0-21.0 wt % and satisfying Ni wt %.gtoreq.[0.67.times.{Cr+1.2.times.(Si+Ti+Zr+Hf+V+Nb+Ta)}-] wt % and (Cr+Si) wt %.gtoreq.20 wt %, these ferrous-group shape-memory alloys having a corrosion resistance, a shape-memorizing properties, an intergranular corrosion resistance and a stress corrosion cracking resistance in nitric acid for nuclear fuel reprocessing plants and high-temperature, high-pressure water for light-water reactors.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: September 14, 1993
    Assignees: Mitsubishi Jukogyo Kabushiki Kaisha, NKK Corporation
    Inventors: Yoshikuni Kadoya, Toshio Yonezawa, Naotake Ito, Toru Inazumi, Yutaka Moriya, Haruo Suzuki, Katsumi Masamura, Takemi Yamada
  • Patent number: 5242002
    Abstract: A pneumatic radial tire is disclosed, including an annular tread having a belt incorporated therein, a pair of sidewalls which extend radially inward from both ends of the annular tread and a bead portion, provided at the inner end of each sidewall, wherein the belt includes a belt ply having a plurality of belt cords in parallel arrangement, the belt cords being formed by twisting a plurality of steel filaments or two or more strands each consisting of a plurality of steel. filaments, and at least one of said steel filaments being replaced by a filament of a shape-memory alloy which, before it is twisted either as a belt cord or as a strand which forms a belt cord, has been heat set at a predetermined heat set temperature whereby the filament has a linear shape at a temperature below the heat set temperature and has a wavy shape at a temperature at or above the heat set temperature.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: September 7, 1993
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Masahiro Oku
  • Patent number: 5226979
    Abstract: The present invention relates to hollow elements prepared from alloys having shape memory characteristics and techniques for heating the elements to effect the martensite (or R-phase) to austenite transformation. In its most preferred embodiment, the invention relates to the use of shape memory alloys to prepare hollow springs or tubular beams, bending and torsional, and the preferred methods of heating the elements include passing an insulated resistance heating wire through the core thereof and applying a current, or applying two layers of coating to the inside or outside of the tube, one of which is insulating and the other of which is electrically conductive. In the latter example, application of current to the conductive coating will heat the element. It is also envisioned that hot fluid may be passed through the element as the heating technique.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: July 13, 1993
    Assignee: Johnson Service Company
    Inventor: Paul E. Thoma
  • Patent number: 5199497
    Abstract: The present invention is a wellbore tool which includes as a component an actuator which is composed at least in-part of a shape-memory material characterized by having a property of switching between a deformed shape and a pre-deformed shape upon receipt of thermal energy of a preselected amount. The wellbore tool further includes a component which is movable in position relative to a wellbore tubular conduit into a selected one of a plurality of configurations. The plurality of configurations include a first configuration with the first component in a first position relative to the wellbore tubular conduit, and corresponding to a first mode of operation of the wellbore tool. The plurality of configurations also includes a second configuration with the first component in a second position relative to the wellbore tubular conduit, and corresponding to a second mode of operation in the wellbore tool.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: April 6, 1993
    Assignee: Baker Hughes Incorporated
    Inventor: Richard J. Ross
  • Patent number: 5198041
    Abstract: A shape memory stainless steel containing more than 10% by weight of Cr excellent in resistance to stress corrosion cracking and having sufficient function as a shape memory alloy, which comprises, by weight, up to 0.10% of C, 3.0 to 6.0% of Si, 6.0 to 25.0% of Mn, up to 7.0% of Ni, more than 10.0% and not more than 17.0% of Cr, 0.02 to 0.3% of N, 2.0 to 10.0% of Co and more than 0.2% and not more than 3.5% of Cu, and at least one selected from up to 2.0% of Mo, 0.05 to 0.8% of Nb, 0.05 to 0.8% of V, 0.05 to 0.8% of Zr, 0.05 or 0.8% of Ti, the balance being Fe and unavoidable impurities, the alloying components being adjusted so that a D value is not less than-26.0, wherein the D value is defined by the following equation:D=Ni+0.30.times.Mn+56.8.times.C+19.0.times.N+0.73.times.Co+Cu -1.85.times.[Cr+1.6.times.Si+Mo+1.5.times.(Nb+V+Zr+Ti)].
    Type: Grant
    Filed: February 25, 1992
    Date of Patent: March 30, 1993
    Assignee: Nisshin Steel Co., Ltd.
    Inventors: Toshihiko Takemoto, Masayuki Kinugasa, Teruo Tanaka, Takashi Igawa
  • Patent number: 5173131
    Abstract: Stainless iron-base alloy having a total shape memory effect consisting, after a given cold mechanical deformation, in a recovery of the initial shape by heating, characterized in that its composition by weight is the following:9 to 13% chromium,15 to 25% manganese,3 to 6% silicon,the remainder being iron and residual impurities resulting from the fusion of substances necessasry for producing the alloy, the proportions of the elements satisfying the relation:1.43(%Si)+1 (%Cr) .ltoreq.17.The invention also provides a method for producing this alloy.
    Type: Grant
    Filed: November 21, 1990
    Date of Patent: December 22, 1992
    Assignee: Ugine, Aciers De Chatillon Et Gueugnon
    Inventor: Mantel Marc
  • Patent number: 5133721
    Abstract: A device for removing foreign objects from anatomic organs such as the ear canal or throat having a housing shaped like a flashlight, an electrical power source such as a battery or AC power from a wall socket, and a tip extending from the housing, the tip having at least one wire loop made from a shape-memory-effect alloy such as Nitinol switchably connected to the electrical power source such that when electric current flows through the wire loop the wire loop heats up and returns to a previously programmed shape such as a curet or tweezers so as to facilitate removal of the foreign object.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: July 28, 1992
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventor: Earl D. Angulo
  • Patent number: 5114504
    Abstract: A high temperature titanium-based shaped memory alloy contains from at least 0.1 at. % hafnium. Articles formed from the disclosed alloy have high transformation temperatures. The alloy of the invention can be successfully hot and cold worked to make articles such as springs and wires.
    Type: Grant
    Filed: November 5, 1990
    Date of Patent: May 19, 1992
    Assignee: Johnson Service Company
    Inventors: David N. AbuJudom, II, Paul E. Thoma, Ming-Yuan Kao, David R. Angst
  • Patent number: 5108523
    Abstract: A shape memory alloy for repeated use, containing no noble metals. NiTiZr and NiTiZrCu shape memory alloys having A.sub.s temperature which lies above 100.degree. C. are disclosed. These shape memory alloys have the following composition: 41.5 to 54 atomic % Ni; 24 to 42.5 atomic % Ti and 7.5 to 22 atomic % Zr.
    Type: Grant
    Filed: July 24, 1990
    Date of Patent: April 28, 1992
    Assignee: Fried. Krupp GmbH
    Inventors: Jurgen Peterseim, Wolfgang Schlump
  • Patent number: 5092941
    Abstract: A method of imparting a particular shape to a wire made of a shape memory alloy, such as a Ni-Ti alloy, which includes the steps of bending the wire inside a tubular body into the particular shape; heating the wire within the tubular body to a temperature sufficient to cause the wire to retain the particular shape; and removing the wire from the tubular body. The tubular body is made of a deformable metal, such as stainless steel or nickel-chrome alloy tubing, and includes a slit therethrough extending in its axial direction. The slit is provided to facilitate bending the tubular body and removing the wire from the tubular body.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: March 3, 1992
    Assignee: GAC International, Inc.
    Inventor: Fujio Miura
  • Patent number: 5066341
    Abstract: The method of conditioning an article of shape memory metallic alloy having a double-action shape memory in accordance with the invention comprises the operations offorming at ambient temperature the article to the shape constituting a first shape memory state,mechanically maintaining the article in its first shape memory state and heating the mechanically held article to a temperature to transform it into a state of the austenitic crystallographic phase,suddenly lowering the mechanically held article to a selected temperature and subjecting it to thermal stabilization treatment while still preserving its austenitic state, andsubjecting the article to an education process in order to shape it into the second shape memory state.
    Type: Grant
    Filed: January 26, 1990
    Date of Patent: November 19, 1991
    Assignee: Nivarox-FAR S. A.
    Inventor: Guy Grenouillet
  • Patent number: 5032195
    Abstract: A Fe-base shape memory alloy consisting of 15-20 wt. % of Mn, not more than 3 wt. % of Si, not more than 10 wt. % of Cr, and the balance being Fe and inevitable impurities is cold worked and heated to 400.degree.-700.degree. C. The Fe-base shape memory alloy of the present invention can be manufactured at low prices by reducing or avoiding the use of high priced elements compared to existing Ti-Ni alloy, and is superior to existing Fe-base shape memory alloy in the shape memory capacity and cold workability.
    Type: Grant
    Filed: December 29, 1989
    Date of Patent: July 16, 1991
    Assignee: Korea Institute of Science and Technology
    Inventors: Myung Chul Shin, Kwang Koo Jee
  • Patent number: 5026441
    Abstract: This invention is concerned with the development of a Cu-base shape memory alloy and it's manufacturing process. The alloy is a Cu-Al-Ni-Zr-Si shape memory alloy exhibiting high strength(830Mpa, 85kg/mml) and good ductility(7.5 - 8%) due to grain size refinement by the addition of microalloying elements (Zr, Si). Also, the invented alloy has good thermal stability and is useful for temperatures of up to about 300.degree. C.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: June 25, 1991
    Assignee: Korea Advanced Institute of Science & Technology
    Inventors: Young-gil Kim, Jin-woong Kim, Dong-wan Nho
  • Patent number: 5001446
    Abstract: A shape memory alloy consists of a three element alloy of nickel-titanium-copper which is formed as being subjected to a cold working and to a heat treatment at a temperature below recrystallization point of the alloy for storing the shape, the alloy being thereby improved in operation stability and reliability even after repetitive operation and made wider in environmental temperature range for use therein of the alloy.
    Type: Grant
    Filed: July 21, 1989
    Date of Patent: March 19, 1991
    Assignee: Matsushita Electric Works, Ltd.
    Inventors: Koji Tsuji, Yoshinobu Takegawa
  • Patent number: 4965045
    Abstract: A new copper-based metallic alloy is described containing principally Zn and Al in quantities such as to render it capable, after solution heat treatment at high temperature, and tempering, of assuming a crystalline structure of Beta type; its principal characteristics lies in the fact that it simultaneously contains, as grain size reducing additives, Nb and Ti in an overall quantity lying between 0.01 and 0.2% by weight.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: October 23, 1990
    Assignee: Europe Metalli - LMI S.p.A.
    Inventors: Andrea Giarda, Sergio Ceresara
  • Patent number: 4950340
    Abstract: An intermetallic compound type alloy consisting essentially of:Ni or Co or both 45-60%;Si 0.01-1%;Re 0-2%;Hf 0-2%;C 0-2%;one or more elements selected from a group consisting of Zr, Fe, V, Nb, Ta, Cr, Mo, W and Mn 0-5%;one or more elements selected from a group consisting of P, Cu, Zn, Ga, Ge, Cd, In, Sn, Sb, Pb and Bi 0-2%; andthe balance Ti and incidental impurities, andhaving excellent toughness, machinability and wear resistance, the % being atomic %.
    Type: Grant
    Filed: August 5, 1988
    Date of Patent: August 21, 1990
    Assignee: Mitsubishi Kinzoku Kabushiki Kaisha
    Inventors: Saburo Wakita, Junji Hoshi
  • Patent number: 4943326
    Abstract: An ornament is disclosed, which is characterized in that a metallic alloy wire provided with a characteristic to show the superelastic effect at room temperature by making the metallic texture Austenite phase is overlapped on both ends and formed into an approximately circular ring shape to form a wound ring. A method of manufacturing the same claimed is that a prime wire of Ni--Ti type alloy is submitted to the cold processing rating from 20 to 50% to form a round or angular wire rod, said wire rod is wound up around a stick or pipe with a fixed outer diameter and submitted to the heat treatment at 300.degree. to 600.degree. C. under restraint of both ends of wire rod to form a wound ring of approximately circular ring shape and simultaneously the superelastic effect is given to said ring at room temperature by making the metallic texture thereof Austenite phase.
    Type: Grant
    Filed: October 20, 1988
    Date of Patent: July 24, 1990
    Assignees: The Furukawa Electric Co., Ltd., Yamaguchi Pearl, Co., Ltd.
    Inventors: Kazuhiro Ozawa, Etsuo Nakajima, Isao Yamaguchi
  • Patent number: 4935068
    Abstract: A method of treating a sample of an alloy which is capable of transforming between martensitic and austenitic phases, to render the alloy pseudoelastic, the method comprising:(a) annealing the alloy at a temperature which is greater than the stress relaxation temperature (T.sub.SR) of the alloy and less than the temperature at which the alloy is fully recrystallized (T.sub.x); and(b) deforming the sample at a temperature which is greater than about the maximum temperature at which the alloy can be made to transform from its austenitic phase to its martensitic phase by the application of stress (M.sub.d), and less than the stress relaxation temperature.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: June 19, 1990
    Assignee: Raychem Corporation
    Inventor: Thomas W. Duerig
  • Patent number: 4933027
    Abstract: An iron-based shape-memory alloy excellent in a shape-memory property, a corrosion resistance and a high-temperature oxidation resistance, consisting essentially of:chromium: from 5.0 to 20.0 wt. %,silicon: from 2.0 to 8.0 wt. %,at least one element selected from the group consisting of:manganese: from 0.1 to 14.8 wt. %,nickel: from 0.1 to 20.0 wt. %,cobalt: from 0.1 to 30.0 wt. %,copper: from 0.1 to 3.0 wt. %, andnitrogen: from 0.001 to 0.400 wt. %,whereNi+0.5 Mn+0.4 Co+0.06 Cu+0.002 N.gtoreq.0.67 (Cr+1.2 Si)-3,and the balance being iron and incidental impurities.
    Type: Grant
    Filed: February 23, 1989
    Date of Patent: June 12, 1990
    Assignee: NKK Corporation
    Inventors: Yutaka Moriya, Tetsuya Sanpei, Hisatoshi Tagawa
  • Patent number: 4929289
    Abstract: An iron-based shape-memory alloy excellent in a shape-memory property and a corrosion resistance, consisting essentially of:______________________________________ chromium: from 0.1 to 5.0 wt. %, silicon: from 2.0 to 8.0 wt. %, manganese: from 1.0 to 14.8 wt. %, at least one element selected from the group consisting of: nickel: from 0.1 to 20.0 wt. %, cobalt: from 0.1 to 30.0 wt. %, copper: from 0.1 to 3.0 wt. %, and nitrogen: from 0.001 to 0.400 wt. %, where, Ni + 0.5 Mn + 0.4 Co + 0.06 Cu + 0.002 N .gtoreq. 0.67 (Cr + 1.2 Si), and the balance being iron and incidental impurities.
    Type: Grant
    Filed: February 23, 1989
    Date of Patent: May 29, 1990
    Assignee: NKK Corporation
    Inventors: Yutaka Moriya, Tetsuya Sanpei, Hisatoshi Tagawa
  • Patent number: 4919177
    Abstract: A method of treating a Ti-Ni shape memory alloy to improve their various characteristic properties. In a first step of the method, a wire of the shape memory alloy is held at a high temperature within a predetermined range to be turned into a solid solution, and thereafter, cooled, whereby plastic strain in it is removed and crystals of the alloy are grown. In a second step of the method, current pulse is passed through the wire to rapidly heat it to a temperature higher than its M.sub.f point to cause elongation due to transformation superplasticity to it. In a third step of the method, the application of the pulse is stopped, the wire is rapidly cooled to the temperature of its M.sub.f point or below, and tensile load is applied to the wire immediately after the stop of the application of the pulse to cause elongation to the wire again in a cooling process, and thereafter the load is removed or sufficiently decreases to stop the deformation when the value of m concerning the wire is sharply decreased.
    Type: Grant
    Filed: March 29, 1988
    Date of Patent: April 24, 1990
    Inventor: Dai Homma
  • Patent number: 4894100
    Abstract: A shape memory alloy consisting, by atomic ratio, of V 0.25-2.0% and the balance of Ni and Ti, an atomic ratio of Ni and Ti being 0.96-1.06. The shape memory alloy has a good workability and a reduced temperature difference between a martensitic transition start point and an austenitic transition finish point. When the atomic ration of Ni/Ti is 0.96-1.02, the martensitic transition start point is the room temperature or higher. When the atomic ratio of Ni/Ti is 1.02-1.06, the martensitic transition start point is the room temperature or lower. The shape memory alloy has a pseudo elasticity.
    Type: Grant
    Filed: January 7, 1988
    Date of Patent: January 16, 1990
    Assignee: Tokin Corporation
    Inventors: Kiyoshi Yamauchi, Shoichi Sato, Hideo Takaara
  • Patent number: 4884557
    Abstract: An endoscope includes a bending member having a shape memory alloy. A pair of heating current supplying wires and a pair of resistance detecting wires are connected at one end to the ends of the shape memory alloy. The other end of the heating current supplying wire is connected to a current supply circuit, and the other end of the resistance detecting wire is connected to a resistance detector. The resistance detector is constituted by a bridge circuit having a branch opened and the shape memory alloy is connected in the opened branch via the resistance detecting wires. A controller controls the current supply circuit according to the detected resistance. The current supply is effected by supplying a current pulse, and the amount of heating current and the bending degree can be controlled by controlling the pulse width of the current pulse.
    Type: Grant
    Filed: May 11, 1988
    Date of Patent: December 5, 1989
    Assignee: Olympus Optical Co., Ltd.
    Inventors: Sakae Takehana, Yasuhiro Ueda, Tomohisa Sakurai
  • Patent number: 4881981
    Abstract: A process for adjusting the physical and mechanical properties of a shape memory alloy member of a known chemical composition comprising the steps of increasing the internal stress level and forming said member to a desired configuration and heat treating said member at a selected memory imparting temperature.
    Type: Grant
    Filed: April 20, 1988
    Date of Patent: November 21, 1989
    Assignee: Johnson Service Company
    Inventors: Paul E. Thoma, David N. AbuJodom, II, Sepehr Fariabi
  • Patent number: 4878954
    Abstract: A process is disclosed for improving the ductility of shape-memory alloy products based on Ti-Ni involving martensitic transformation. The process comprises at least one thermal treatment cycle of alternating hot and cold treatment, wherein the first thermal treatment cycle comprises a cold treatment at a temperature both lower than -50.degree. C. and lower than M.sub.s -50.degree. C., where M.sub.s is the temperature at which martensitic transformation of the product begins, and a hot treatment of the product at a temperature of 700.degree. to 900.degree. C. Each optional subsequent thermal treatment cycle comprises a cold treatment of the product at a temperature both lower than -50.degree. C. and lower than M.sub.s -30.degree. C., and a hot treatment of the product at a temperature of 600.degree. to 900.degree. C.
    Type: Grant
    Filed: June 17, 1988
    Date of Patent: November 7, 1989
    Assignee: Compagnie Europeenne Du Zirconium Cezus
    Inventors: Alain Dubertret, Bernard Prandi
  • Patent number: 4865663
    Abstract: A nickel-titanium-palladium based alloy for converting heat energy into mechanical energy. The alloy exhibits shape memory. The alloy contains palladium to raise the temperature at which the alloy flexes between a deformed condition at a relatively colder temperature and a nondeformed condition at a relatively higher temperature. The alloy is characterized by including boron for increasing the fabricability of the alloy.
    Type: Grant
    Filed: March 18, 1988
    Date of Patent: September 12, 1989
    Assignee: Armada Corporation
    Inventors: Steven M. Tuominen, Robert J. Biermann
  • Patent number: 4849032
    Abstract: An orthodontic coil spring is made of a shape-memory alloy wire which is wound into a coil and heat treated into a superelastic state. The coil spring imparts a predetermined spring force within a superelastic zone of deflection.
    Type: Grant
    Filed: March 17, 1988
    Date of Patent: July 18, 1989
    Assignee: Tomy, Inc.
    Inventor: Kozo Kawaguchi
  • Patent number: 4808246
    Abstract: A composite material in rod, tube, strip, sheet or plate shape with reversible thermomechanical properties is produced by joining of at least two parts consisting of a total of at least one shape memory alloy having a two-way effect, whereby each part has a memory effect by itself. In the case of at least two shape memory alloys (1, 2) with different transition temperatures but the same mode of movement, the joining of the individual parts can take place prior to the deformation in the low temperature range necessary to inducing the two-way effect. In the case of differing types and degrees of movement of the individual parts (25, 26), their joining can first be accomplished only after the individual deformations of each part for itself in the low temperature range are accomplished regardless of how many shape memory alloys with different transition temperatures are used in the structure of the composite material.
    Type: Grant
    Filed: September 26, 1986
    Date of Patent: February 28, 1989
    Assignee: BBC Brown, Boveri & Company Limited
    Inventors: Joachim Albrecht, Thomas Duerig
  • Patent number: 4797085
    Abstract: An apparatus using a shape memory alloy such as nickel-titanium as a die material in one embodiment is used for performing pseudo-isostatic pressing by using a uniaxial mechanical press to densify a powder mixture, preform or presinter with or without the use of pressure transmitting powder. The apparatus can also be used to perform thermal mechanical work on any article to obtain near net shape. With controlled thermal mechanical processing and fabrication of the shape memory alloy into a die configuration, its shape can be changed from a low temperature configuration to a high temperature configuration after being heated. As a result, near net shape parts can be cold or hot pressed pseudo-isostatically without using an expensive and sophisticated press apparatus of the prior art. In a second embodiment, the shape memory alloy is employed as the expansion tooling for near net shape forming of composite materials.
    Type: Grant
    Filed: April 3, 1987
    Date of Patent: January 10, 1989
    Assignee: Aerojet-General Corporation
    Inventors: Tien-Hon Chiang, Donald N. Thatcher
  • Patent number: 4780154
    Abstract: A known Ti-Ni based and Cu-based shape memory alloy can be replaced by an Fe-based shape memory alloy. An excellent shape memory effect is attained by an Fe-based shape memory alloy with an Mn content of 20% to 40% and an Si content of 3.5% to 8%.
    Type: Grant
    Filed: March 17, 1987
    Date of Patent: October 25, 1988
    Assignee: Nippon Steel Corporation
    Inventors: Tsutomu Mori, Akikazu Sato, Hiroo Suzuki, Yasushi Nakamura, Masato Murakami
  • Patent number: 4770725
    Abstract: Disclosed are a group of nickel/titanium/niobium alloys wherein the niobium varies from about 2.5 to 30 atomic percent. Also disclosed is an aritcle made from these nickel/titanium/niobium alloys.
    Type: Grant
    Filed: June 5, 1987
    Date of Patent: September 13, 1988
    Assignee: Raychem Corporation
    Inventors: John A. Simpson, Keith Melton, Tom Duerig
  • Patent number: 4759906
    Abstract: A method of producing functional alloys by adding not more than 20 atomic percent Cr to a TiPd alloy with 40-60 atomic percent Ti which develops thermoelastic martensitic transformation, for adjusting the transformation point of the alloy. Such a functional alloy may comprise in addition to the Ti, 0.001-20 atomic percent Cr, the balance being Pd.
    Type: Grant
    Filed: February 4, 1987
    Date of Patent: July 26, 1988
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Soji Nenno, Kazuyuki Enami, Kazuhiko Hayashi
  • Patent number: 4753689
    Abstract: The invention relates to a method of conditioning an object in shape-memory material of metallic alloy type.The object formed to final shapes and dimensions constituting the first shape-memory state is submitted to a thermal treatment in order to bring this object to an austenitic crystallographic phase, then to cooling. The object is then submitted in at least one deformation zone to a process of education consisting of imposing on the object, in at least one cycle, a series of thermal and/or mechanical stresses. The stresses are such as to lead to deformation of the object for bringing it to a shape close to its second shape-memory state in a martensitic crystallographic state, then to permit the return of the object to its first shape-memory state, on a return of the object to the austenitic crystallographic state.Application to electric contact elements.
    Type: Grant
    Filed: March 13, 1986
    Date of Patent: June 28, 1988
    Assignee: Souriau & Cie
    Inventors: Gilles Rizzo, Alain Dubertret, Gerard Guenin
  • Patent number: 4750953
    Abstract: A copper-base shape-memory alloy consisting essentially of 15-35% Zn, 3.2-10% Al, 0.01-1% Si, at least one element selected from the group of 0.5-2% Ti, 0.01-1% Cr, 0.01-8% Mn, 0.01-2% Co and 2.1-4% Ni, the balance being Cu and incidental impurities, the percent being by weight is disclosed.This alloy has high resistance to intercrystalline cracking and thermal cycling as well as improved shape-memory properties.
    Type: Grant
    Filed: May 7, 1986
    Date of Patent: June 14, 1988
    Assignee: Mitsubishi Kinzoku Kabushiki Kaisha
    Inventor: Kazuhiko Tabei
  • Patent number: 4747887
    Abstract: A method for actuating a member made of shape memory alloy, including stressing the shape memory alloy member so that its Ms point becomes positioned between its As point and its Af point, and applying a pulsed supply of electricity to it to heat it up is disclosed. The voltage and the duty factor d of the pulsed supply of electricity ensure that the relations .theta.ha greater than -.theta.ca and "d" less than or equal to .theta..sub.cc /(.theta.cc -.theta.hb ) are satisfied, where .theta..sub.ha is the heating speed of the shape memory alloy member in the region below its As point, .theta.hb is the heating speed of the shape memory alloy member in the region between its As point and its Af point, .theta..sub.cc is the cooling speed of the shape memory alloy member in the region above its Ms point, and .theta.ca is the cooling speed of the shape memory alloy member in the region below its Mf point.
    Type: Grant
    Filed: April 13, 1987
    Date of Patent: May 31, 1988
    Assignee: Naomitsu Tokieda
    Inventor: Dai Honma
  • Patent number: 4740253
    Abstract: There is disclosed a method of preassembling a composite coupling. The coupling has at least one heat-recoverable driver member and at least one metallic insert. The driver member is made from a nickel/titanium-based shape memory alloy having a transformation hysteresis defined by M.sub.s, M.sub.f, A.sub.s and A.sub.f temperatures. The method includes the steps of overdeforming the driver member by applying a stress sufficient to cause nonrecoverable strain in the driver member so that the A.sub.s and A.sub.f temperatures are temporarily raised to A.sub.s' and A.sub.f', respectively; removing the stress; engaging the driver member and insert; and then warming the driver and insert to a temperature less than A.sub.s'. There is also disclosed a composite coupling processed by this method.
    Type: Grant
    Filed: October 7, 1985
    Date of Patent: April 26, 1988
    Assignee: Raychem Corporation
    Inventors: John A. Simpson, Keith Melton, Tom Duerig
  • Patent number: 4738610
    Abstract: An apparatus using a shape memory alloy such as nickel-titanium as a die material for performing pseudo-isostatic pressing by using a uniaxial mechanical press to densify a powder mixture, preform or presinter with or without the use of pressure transmitting powder. The process can also be used to perform thermal mechanical work on any article to obtain near net shape. With controlled thermal mechanical processing and fabrication of the shape memory alloy into a die configuration, its shape can be changed from a low temperature configuration to a high temperature configuration after being heated. The shape transformation temperature for nickel-titanium alloy in particular, ranges from about -200 degrees Centigrade to +100 degrees Centigrade depending primarily upon alloy composition.
    Type: Grant
    Filed: December 4, 1986
    Date of Patent: April 19, 1988
    Assignee: Aerojet-General Corporation
    Inventors: Tien-Hon Chiang, Donald N. Thatcher
  • Patent number: 4732556
    Abstract: An apparatus using a shape memory alloy such as nickel-titanium as a reaction vessel for self-sustaining combustion (SSC) reaction synthesis of ceramics, intermetallics, metal or ceramic matrix composites and the like and as a die material for pseudo-isostatic hot pressing by providing a uniaxial mechanical press to density the reaction products with or without the use of pressure transmitting powder. The process can also be used to perform thermal mechanical work on any article synthesized by the self-sustaining combustion reaction to obtain near net shape. With controlled thermal mechanical processing and fabrication of the shape memory alloy into a die configuration, its shape can be changed from a low temperature configuration to a high temperature configuration after being heated. The shape transformation temperature for nickel-titanium alloy in particular, ranges from about -200 degrees Centigrade to +100 degrees Centigrade depending primarily upon alloy composition.
    Type: Grant
    Filed: December 4, 1986
    Date of Patent: March 22, 1988
    Assignee: Aerojet-General Corporation
    Inventors: Tien-Hon Chiang, Donald N. Thatcher
  • Patent number: 4712969
    Abstract: An expandable and contractable arm is constituted by a plurality of expandable and contractable units and connecting devices including universal joints for serially interconnecting the units into the arm. Each unit includes at least three expandable and contractable operating members in the form of link mechanisms or double thread type expandable and contractable rods, and actuating devices for equally or unequally expanding and contracting the operating members so as to increase or decrease distances between the connecting members while maintaining them in parallel or inclined with respect to each other.
    Type: Grant
    Filed: August 24, 1984
    Date of Patent: December 15, 1987
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Motohiko Kimura
  • Patent number: 4707196
    Abstract: A reversible shape memory (R.S.M.) article of Ti-Ni alloy containing excess Ni over the stoichiometric composition, such as containing 50.3-53.0 at. % Ni which has a dual phase structure of a TiNi compound phase and a precipitated Ni rich compounds phase and the improved R.S.M. property wherein the different two shapes are recovered by thermal cycles between two temperatures sufficient higher and lower than the martensitic transformation temperature (Ms). The alloy prepared by the melting method is heat-treated at 600.degree. C. or more to be made into a single phase of TiNi compound after being worked into a strip plate, and the plate is fixedly wound on a pipe and aged at 300.degree. C.-600.degree. C. for one or more hours, whereby the article having the R.S.M. property with a large amount of shape change by thermal cycles can be obtained.
    Type: Grant
    Filed: September 6, 1985
    Date of Patent: November 17, 1987
    Assignee: Tohoku Metal Industries Ltd.
    Inventors: Toshio Honma, Minoru Nishida, Kiyoshi Yamauchi
  • Patent number: 4654092
    Abstract: Method of processing nickel-titanium-base shape-memory alloys to substantially suppress the two-way effect including the steps of cold working and low-temperature annealing without restraint. A composite structure is also provided including a nickel-titanium-base shape-memory alloy with the two-way effect substantially suppressed.
    Type: Grant
    Filed: August 5, 1985
    Date of Patent: March 31, 1987
    Assignee: Raychem Corporation
    Inventor: Keith N. Melton
  • Patent number: 4637846
    Abstract: A method of manufacturing a nickel-titanium-beryllium alloy wire, comprising the steps of preparing a nickel-titanium alloy consisting essentially of nickel (Ni) 50 to 40% by weight and titanium (Ti) 40 to 50% by weight, with a portion of either the Ni or Ti being replaced by from 0.005 to 0.5% beryllium (Be), brining the nickel-titanium-beryllium alloy to a molten state, and jetting a melt of the alloy into a liquid flow, formed as a laminar flow, on the internal surface of a rotating drum so as to cool and solidify the nickel-titanium-beryllium alloy from its molten state into a fine wire at an average cooling rate in the range of 10.sup.2 to 10.sup.4 C/sec.
    Type: Grant
    Filed: February 28, 1985
    Date of Patent: January 20, 1987
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventor: Kazuo Sawada
  • Patent number: 4634477
    Abstract: A workable high strength shape memory alloys comprising:Al: 11.5-13.5%,Ni: 2-6%,Mn: 1-5%,Ti: 0.1-5%,each on the weight basis, and the balance of Cu and inevitable impurities.In the modified alloy composition, the workability can be improved without increasing the martensitic transformation temperature.
    Type: Grant
    Filed: September 17, 1985
    Date of Patent: January 6, 1987
    Assignee: Kabushiki Kaisha Kobe Seiko Sho
    Inventors: Koichi Sugimoto, Kiyoshi Kamei, Yotaro Murakami, Takashi Sugimoto, Takashi Nishimura, Takahiro Takashima
  • Patent number: 4631094
    Abstract: There is disclosed a method of processing a nickel/titanium-based shape memory alloy. The method comprises overdeforming the alloy so as to cause at least some amount of nonrecoverable strain, temporarily expanding the transformation hysteresis by raising the austenite transformation temperature, removing the applied stress and then storing the alloy at a temperature less than the new austenite transition temperature. There is also disclosed an article produced from this method.
    Type: Grant
    Filed: November 6, 1984
    Date of Patent: December 23, 1986
    Assignee: Raychem Corporation
    Inventors: John A. Simpson, Keith Melton, Tom Duerig
  • Patent number: 4617448
    Abstract: A locking device for holding a movable member of an apparatus rigidly in place during shipment. A locking element is made from a material exhibiting a "shape memory", and is deformed at a temperature below its transition temperature and installed in the apparatus so as to lock the movable member firmly in place. When it is desired to be able to operate the apparatus in a normal mode, the locking element is heated electrically to a temperature above the transition temperature, so that it resumes the original shape and releases the movable member.
    Type: Grant
    Filed: December 18, 1984
    Date of Patent: October 14, 1986
    Assignee: North American Philips Corporation
    Inventor: Michael P. Goldowsky
  • Patent number: 4586969
    Abstract: The disclosed alloy with a shape memory effect and a pseudo-elasticity exhibits a thin-plate martensitic structure, which alloy is made by heating an alloy consisting of 32-34 wt. % of nickel, 3-6 wt. % of titanium, 10-15 wt. % of cobalt and the remainder of Fe to a temperature between 900.degree. C. to 1,200.degree. C. and effecting an aging treatment at a temperature between 500.degree. C. and 800.degree. C. so as to generate a thin-plate martensite.
    Type: Grant
    Filed: March 14, 1985
    Date of Patent: May 6, 1986
    Assignee: Kyoto University
    Inventors: Imao Tamura, Tadashi Maki