Tin Containing Patents (Class 148/433)
  • Patent number: 8303737
    Abstract: A lead-free brass material exhibiting excellent forgeability and dezincification resistance is provided. The brass material includes 61.0 to 63.0 wt % of Cu, 0.5 to 2.5 wt % of Bi, 1.5 to 3.0 wt % of Sn, 0.02 to 0.10 wt % of Sb, and 0.04 to 0.15 wt % of P, with the balance being substantially Zn. The brass material is a lead-free, free-cutting alloy which can be suitably applied to forging and which exhibits excellent mechanical properties and dezincification resistance without substantially subjecting the brass material to a heat treatment after forging.
    Type: Grant
    Filed: September 5, 2006
    Date of Patent: November 6, 2012
    Assignee: San-Etsu Metals Co., Ltd.
    Inventors: Yoshiharu Kosaka, Masanori Okuyama
  • Patent number: 8293039
    Abstract: A method of manufacturing a sheet of a copper-based alloy containing controlled amounts of Ni, Sn, P, optionally Zn and Fe, Co, Mg, Ti, Cr, Zr, and Al with the remainder being Cu and unavoidable impurities, comprising the steps of cold rolling followed by annealing at least one time of an ingot of the copper-based alloy, thereafter performing intermediate cold rolling, which is a cold rolling process before final cold rolling process, performing annealing with controlled temperature and time to obtain sheet with a grain size of 20 ?m or less, performing final cold rolling at a percent reduction Z to meet the following Formula 0.8×(100?10X?Y)<Z<100?10X?Y, where Z is percent cold reduction, X is Sn content, and Y is the total content (wt.%) of all elements other than Sn and Cu, and performing low-temperature annealing at a temperature below the recrystallization temperature.
    Type: Grant
    Filed: August 29, 2008
    Date of Patent: October 23, 2012
    Assignee: Dowa Metaltech Co., Ltd.
    Inventor: Kouichi Hatakeyama
  • Patent number: 8287669
    Abstract: A copper alloy for electric and electronic equipments, containing from 0.5 to 4.0 mass % of Ni, from 0.5 to 2.0 mass % of Co, and from 0.3 to 1.5 mass % of Si, with the balance of copper and inevitable impurities, wherein R{200} is 0.3 or more, in which the R{200} is a proportion of a diffraction intensity from a {200} plane of the following diffraction intensities and is represented by R{200}=I{200}/(I{111}+I{200}+I{220}+I{311}), I{111} is a diffraction intensity from a {111} plane, I{200} is a diffraction intensity from a {200} plane, I{220} is a diffraction intensity from a {220} plane, and I{311} is a diffraction intensity from a {311} plane, each at the material surface.
    Type: Grant
    Filed: May 30, 2008
    Date of Patent: October 16, 2012
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Hiroshi Kaneko, Tatsuhiko Eguchi, Kuniteru Mihara, Kiyoshige Hirose
  • Patent number: 8273193
    Abstract: The present invention supplies a lead-free, bismuth-free free-cutting silicon brass alloy with high zinc which preferably comprises 35.0 to 42.0 wt % Zn, 0.1 to 1.5 wt % Si, 0.03 to 0.3 wt % Al, 0.01 to 0.36 wt % P, 0.01 to 0.1 wt % Ti, 0.001 to 0.05 wt % rare earth metals selected from the group consisting of La and Ce, 0.05 to 0.5 wt % Sn, and/or 0.05 to 0.2 wt % Ni, and the balance being Cu and unavoidable impurities. In yet another embodiment, the alloy may be boron-free. The invented alloy is excellent in castability, weldability, cuttability, electroplating properties, corrosion resistance, mechanical properties. The alloy is especially applicable in castings which need cutting and welding under low pressure die casting, such as castings for faucet bodies in the water supply system. The alloy is also suitable for use in components which are produced from casting ingots by die forging.
    Type: Grant
    Filed: January 4, 2010
    Date of Patent: September 25, 2012
    Assignee: Xiamen Lota International Co., Ltd.
    Inventors: Chankai Xu, Zhenqing Hu, Siqi Zhang
  • Patent number: 8246764
    Abstract: A first copper alloy sputtering target comprising 0.5 to 4.0 wt % of Al and 0.5 wtppm or less of Si and a second copper alloy sputtering target comprising 0.5 to 4.0 wt % of Sn and 0.5 wtppm or less of Mn are disclosed. The first and/or the second alloy sputtering target can further comprise one or more elements selected from among Sb, Zr, Ti, Cr, Ag, Au, Cd, In and As in a total amount of 1.0 wtppm or less. A semiconductor element wiring formed by the use of the above targets is also disclosed. The above copper alloy sputtering target allows the formation of a wiring material for a semiconductor element, in particular, a seed layer being stable, uniform and free from the occurrence of coagulation during electrolytic copper plating and exhibits excellent sputtering film formation characteristics.
    Type: Grant
    Filed: February 9, 2009
    Date of Patent: August 21, 2012
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Takeo Okabe, Hirohito Miyashita
  • Publication number: 20120175026
    Abstract: The present invention provides a Cu—Fe—P alloy which has a high strength, high conductivity and superior bending workability. The copper alloy comprises 0.01 to 1.0% Fe, 0.01 to 0.4% P, 0.1 to 1.0% Mg, and the remainder Cu and unavoidable impurities. The size of oxides and precipitates including Mg in the copper alloy is controlled so that the ratio of the amount of Mg measured by a specified measurement method in the extracted residue by a specified extracted residue method to the Mg content in said copper alloy is 60% or less, thus endowing the alloy with a high strength and superior bending workability.
    Type: Application
    Filed: March 23, 2012
    Publication date: July 12, 2012
    Applicant: KABUSHIKI KAISHA KOBE SEIKO SHO (Kobe Steel, Ltd.)
    Inventors: Yasuhiro AGRUGA, Katsura Kajihara, Takeshi Kudo
  • Publication number: 20120073712
    Abstract: Alloy containing between 1% and 20% by weight of Ni, between 1% and 20% by weight of Sn, between 0.5%, 3% by weight of Pb in Cu which represents at least 50% by weight of the alloy; characterized in that the alloy further contains between 0.01% and 5% by weight of P or B alone or in combination. The invention also pertains to a metallic product having enhanced mechanical resistance at intermediate temperatures (300° C. to 700° C.) and excellent machinability. The metallic product of the invention can be advantageously used for the fabrication of connectors, electromechanical, or micromechanical pieces.
    Type: Application
    Filed: October 7, 2011
    Publication date: March 29, 2012
    Applicant: SWISSMETAL- UMS USINES METALLURGIQUES SUISSES SA
    Inventors: Natanael Dewobroto, Doris Empl, Laurent Felberbaum, Vincent Laporte, Andreas Mortensen, Andreas Rossoll, Emmanuel Vincent
  • Patent number: 8137489
    Abstract: A copper alloy material has a rolled surface having a plurality of crystal faces parallel to the rolled surface. The crystal faces includes at least one crystal face selected from a group consisted of {011}, {1nn} (n is an integer, n?1), {11m} (m is an integer, m?1), {023}, {012}, and {135}. Diffraction intensities of the crystal faces in an inverse pole figure obtained by crystal diffraction measurement of the rolled surface as a reference satisfy the relationships of: {011}>{155}>{133}, {011}>{023}>{012}, and {011}>{135}>{112}.
    Type: Grant
    Filed: June 19, 2009
    Date of Patent: March 20, 2012
    Assignee: Hitachi Cable, Ltd.
    Inventors: Takemi Muroga, Noboru Hagiwara, Yoshiki Yamamoto
  • Publication number: 20110247735
    Abstract: A copper alloy material for electric/electronic parts, containing: Sn 3.0 to 13.0 mass %, any one or both of Fe and Ni 0.01 to 2.0 mass % in total, and P 0.01 to 1.0 mass %, with the balance being Cu and unavoidable impurities, wherein an average diameter of grains is 1.0 to 5.0 ?m, wherein a compound X having an average diameter of 30 nm or more and 300 nm or less is dispersed in density 104 to 108 per mm2, wherein a compound Y having an average diameter of more than 0.3 ?m and not more than 5.0 ?m is dispersed in density 102 to 106 per mm2; and wherein a tensile strength is 600 MPa or more.
    Type: Application
    Filed: June 20, 2011
    Publication date: October 13, 2011
    Inventors: Koji SATO, Kiyoshige Hirose, Hiroshi Kaneko, Ryosuke Matsuo
  • Publication number: 20110240180
    Abstract: There is provided a copper alloy sheet including 1.0 to 3.5 mass % Ni, 0.5 to 2.0 mass % Co, and 0.3 to 1.5 mass % Si, a Co/Ni mass ratio being 0.15 to 1.5, an (Ni+Co)/Si mass ratio being 4 to 7, and a balance being composed of Cu and an unavoidable impurity, wherein in observation results of a crystal grain boundary property and crystal orientation by EBSP measurement, a density of twin boundaries among all crystal grain boundaries is 40% or more and an area ratio of crystal grains with Cube orientation is 20% or more, on a rolled surface.
    Type: Application
    Filed: July 9, 2010
    Publication date: October 6, 2011
    Applicant: DOWA METALTECH CO., LTD.
    Inventors: Weilin Gao, Akira Sugawara, Ryosuke Miyahara, Hisashi Suda
  • Publication number: 20110174417
    Abstract: A high strength and high conductivity copper alloy pipe, rod, or wire is composed of an alloy composition containing 0.13 to 0.33 mass % of Co, 0.044 to 0.097 mass % of P, 0.005 to 0.80 mass % of Sn, and 0.00005 to 0.0050 mass % of O, wherein a content [Co] mass % of Co and a content [P] mass % of P satisfy a relationship of 2.9?([Co]?0.007)/([P]?0.008)?6.1, and the remainder includes Cu and inevitable impurities. The high strength and high conductivity copper alloy pipe, rod, or wire is produced by a process including a hot extruding process. Strength and conductivity of the high strength and high conductivity copper pipe, rod, or wire are improved by uniform precipitation of a compound of Co and P and by solid solution of Sn.
    Type: Application
    Filed: February 23, 2009
    Publication date: July 21, 2011
    Applicant: MITSUBISHI SHINDOH CO., LTD.
    Inventor: Keiichiro Oishi
  • Publication number: 20110056596
    Abstract: A high strength and high thermal conductivity copper alloy tube contains: Co of 0.12 to 0.32 mass %; P of 0.042 to 0.095 mass %; and Sn of 0.005 to 0.30 mass %, wherein a relationship of 3.0?([Co]?0.007)/([P]?0.008)?6.2 is satisfied between a content [Co] mass % of Co and a content [P] mass % of P, and the remainder includes Cu and inevitable impurities. Even when a temperature is increased by heat generated by a drawing process, a recrystallization temperature is increased by uniform precipitation of a compound of Co and P and by solid-solution of Sn. Thus, the generation of recrystallization nucleuses is delayed, thereby improving heat resistance and pressure resistance of the high strength and high thermal conductivity copper alloy tube.
    Type: Application
    Filed: November 10, 2008
    Publication date: March 10, 2011
    Applicant: MITSUBISHI SHINDOH CO., LTD.
    Inventor: Keiichiro Oishi
  • Publication number: 20110056591
    Abstract: Brass alloy powder has a brass composition formed by a mixed phase of ?-phase and ?-phase, and contains 0.5 to 5.0 mass % of chromium. The chromium includes a component that is solid-solved in a mother phase of brass, and a component that is precipitated at crystal grain boundaries.
    Type: Application
    Filed: April 24, 2009
    Publication date: March 10, 2011
    Applicants: Japan Science and Technology Agency, Osaka University
    Inventors: Katsuyoshi Kondoh, Gen Katano, Hisashi Imai, Yoshiharu Kosaka, Akimichi Kojima
  • Patent number: 7883588
    Abstract: In a Cu—Bi based sintered alloy, to which hard particles, such as Fe3P, are added, the main constituent components of the microstructure are a Cu matrix, Bi phase and the hard particles. In the sintering method of the present invention, the flow of the Bi phase is suppressed to as low level as possible. The novel structure is that the contact between the Bi phase and hard particles is kept to a low ratio. A lead-free bearing used for a fuel injection pump according to the present invention contains from 1 to 30 mass % of Bi and from 0.1 to 10 mass % of hard particles having from 10 to 50 ?m of the average particle diameter, the balance being Cu and unavoidable impurities. The properties of the main component phases are utilized at a high level such that the sliding properties are equivalent to those of a Pb containing Cu-based sintered alloy.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: February 8, 2011
    Assignees: Taiho Kogyo Co., Ltd., Denso Corporation
    Inventors: Hiromi Yokota, Daisuke Yoshitome, Hiroaki Hayakawa, Naruhiko Inayoshi, Youichi Murakami, Masashi Suzuki, Takahiro Nozu
  • Publication number: 20110017358
    Abstract: A copper alloy material for an electrical/electronic equipment, containing Ni not less than 2.0 mass % and less than 3.3 mass %, having a content of Si within the range of 2.8 to 3.8 in terms of a mass ratio of Ni and Si (Ni/Si), and containing Mg 0.01 to 0.2 mass %, Sn 0.05 to 1.5 mass %, and Zn 0.2 to 1.5 mass %, with the balance of Cu and inevitable impurities, wherein when a test piece with thickness t of 0.20 mm and width w of 2.0 mm is subjected to 180°-bending with bending radius R (mm), a value of the minimum bending radius R causing no cracks is 0 mm to 0.1 mm; and, an electrical/electronic part obtained by working the same.
    Type: Application
    Filed: September 29, 2010
    Publication date: January 27, 2011
    Inventors: Koji Sato, Kiyoshige Hirose, Hiroshi Kaneko
  • Publication number: 20110017357
    Abstract: A copper alloy material for an electrical/electronic equipment, containing Ni 3.3 to 5.0 mass %, having a content of Si within the range of 2.8 to 3.8 in terms of a mass ratio of Ni and Si (Ni/Si), and containing Mg 0.01 to 0.2 mass %, Sn 0.05 to 1.5 mass %, and Zn 0.2 to 1.5 mass %, with the balance of Cu and inevitable impurities, wherein when a test piece with thickness t of 0.20 mm and width w of 2.0 mm is subjected to 90° W-bending with bending radius R of 0.1 mm, no cracks occur on the test piece; and, an electrical/electronic part obtained by working the same.
    Type: Application
    Filed: September 29, 2010
    Publication date: January 27, 2011
    Inventors: Koji SATO, Kiyoshige Hirose, Hiroshi Kaneko
  • Publication number: 20100276039
    Abstract: Copper alloys, methods for producing copper alloys, and copper tubes are provided. The copper alloys include an alpha solid solution formed from phosphorous deoxidized copper and at least one trace element comprising tin. The content of tin ranges from about 0.1% to about 2.0% by weight of the copper alloy. The trace element can further include zinc in an amount from about 0.05% to about 1.0% by weight of the copper alloy. The copper alloys have an increased tensile strength due to the strengthening effect by the alpha solid solution formed by phosphorous deoxidized copper and tin as the trace element, and accordingly a copper tube made from the copper alloy has a significantly improved pressure resistance.
    Type: Application
    Filed: April 28, 2010
    Publication date: November 4, 2010
    Applicant: Golden Dragon Precise Copper Tube Group Inc.
    Inventors: Honglin Guo, Zhenguo Feng, Jinhao Zhao, Daixing Liu, Guowei Liu, Junqi Li
  • Publication number: 20100269959
    Abstract: A copper alloy sheet has a chemical composition containing 0.7 to 4.0 wt % of Ni, 0.2 to 1.5 wt % of Si, and the balance being copper and unavoidable impurities, the copper alloy sheet having a crystal orientation which satisfies I{200}/I0{200}?1.0, assuming that the intensity of X-ray diffraction on the {200} crystal plane on the surface of the copper alloy sheet is I{200} and that the intensity of X-ray diffraction on the {200} crystal plane of the standard powder of pure copper is I0{200}, and which satisfies I{200}/I{422}?15, assuming that the intensity of X-ray diffraction on the {422} crystal plane on the surface of the copper alloy sheet is I{422}.
    Type: Application
    Filed: April 26, 2010
    Publication date: October 28, 2010
    Applicant: DOWA METALTECH CO., LTD.
    Inventors: Weilin Gao, Tomotsugu Aoyama, Hisashi Suda, Hiroto Narieda, Akira Sugawara, Akifumi Onodera
  • Patent number: 7819992
    Abstract: A member for water works is proposed in which the content of lead is limited to a very small values while maintaining its mechanical properties, castability, machinability, pressure resistance, etc. to levels equivalent to those of conventional copper alloys containing lead. A copper alloy is produced which contains not less than 2.0% by weight and not more than 5.9% by weight of tin, not less than 1.5% by weight and not more than 5.0% by weight of nickel, not less than 5.0% by weight and not more than 12.1% by weight of zinc, not less than 0.4% by weight and not more than 3.3% by weight of bismuth, and not less than 0.009% by weight and not more than 0.15% by weight of phosphorus, the balance being copper and impurities.
    Type: Grant
    Filed: June 20, 2006
    Date of Patent: October 26, 2010
    Assignee: Kurimoto, Ltd.
    Inventors: Masaaki Yamamoto, Yoshimasa Hirai, Hiroaki Maedono, Chizuko Maedono, legal representative
  • Patent number: 7806996
    Abstract: A copper-based alloy essentially includes 5.0 to 10.0 wt % of Zn, 2.8 to 5.0 wt % of Sn, 0.4 to 3.0 wt % of Bi, 0<Se?0.35 wt %, 0<P?0.5, one of 0<Sb?2.2 wt % and 0<Ni?4.8 wt %, and a balance of Cu and unavoidable impurities. It may essentially includes 5.0 to 10.0 wt % of Zn, 2.8 to 5.0 wt % of Sn, 0.4 to 3.0 wt % of Bi, 0?Se?0.35 wt %, 0<P<0.5 wt %, one of 0<Sb?2.2 wt % and 0<Ni?4.8 wt %, 1.20 to 4.90 Vol. % of at least one selected from the group consisting of a non-solid solution substance secured with Bi and a non-solid solution secured with Bi and Se, and a balance of Cu and unavoidable impurities.
    Type: Grant
    Filed: May 11, 2007
    Date of Patent: October 5, 2010
    Assignee: Kitz Corporation
    Inventors: Kazuhito Kurose, Yukihiro Hirata, Tomoyuki Ozasa, Hisanori Terui
  • Publication number: 20100243112
    Abstract: A beryllium-free high-strength copper alloy includes, about 10-30 vol % of L12-(Ni,Cu)3(Al,Sn), and substantially excludes cellular discontinuous precipitation around grain boundaries. The alloy may include at least one component selected from the group consisting of: Ag, Cr, Mn, Nb, Ti, and V, and the balance Cu.
    Type: Application
    Filed: March 31, 2009
    Publication date: September 30, 2010
    Applicant: QuesTek Innovations LLC
    Inventors: James A. Wright, Abhijeet Misra
  • Publication number: 20100224292
    Abstract: A copper alloy material has a rolled surface having a plurality of crystal faces parallel to the rolled surface. The crystal faces includes at least one crystal face selected from a group consisted of {011}, {1nn} (n is an integer, n?1), {11m} (m is an integer, m?1), {023}, {012}, and {135}. Diffraction intensities of the crystal faces in an inverse pole figure obtained by crystal diffraction measurement of the rolled surface as a reference satisfy the relationships of: {011}>{155}>{133}, {011}>{023}>{012}, and {011}>{135}>{112}.
    Type: Application
    Filed: June 19, 2009
    Publication date: September 9, 2010
    Inventors: Takemi Muroga, Noboru Hagiwara, Yoshiki Yamamoto
  • Patent number: 7776163
    Abstract: The present invention provides a lead-free free-cutting aluminum brass alloy and its manufacturing method. The alloy comprises: 57.0˜63.0 wt % Cu, 0.3˜0.7 wt % Al, 0.1˜0.5 wt % Bi, 0.2˜0.4 wt % Sn, 0.1˜0.5 wt % Si, 0.01˜0.15 wt % P, at least two elements selected from the group of 0.01-0.15 wt % Mg, 0.0016-0.0020 wt % B, and 0.001-0.05 wt % rare earth elements and the balance being Zn and unavoidable impurities. The inventive alloy has excellent castability, weldability, cuttability and corrosion resistance. It is suitable for low pressure die casting, gravity casting, horizontal continuous casting, forging and extrusion. Its metal material cost is lower than bismuth brass. It is particularly applicable for components used in drinking water supply systems and other structural components. It is a new environmentally-friendly free-cutting aluminum brass alloy.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: August 17, 2010
    Assignee: Xiamen Lota International Co., Ltd.
    Inventors: Chuankai Xu, Zhenqing Hu, Siqi Zhang
  • Patent number: 7744705
    Abstract: This invention relates to group IB-IIIA. VIA quaternary or higher alloys. More particularly, this invention relations to group IB-IIIA-VIA quaternary or pentenary alloys which are suitable for use as semiconductor films. More specifically, the invention relates to quaternary or pentenary alloys which are substantially homogeneous and are characterized by an x-ray diffraction pattern (XRD) having a main [112] peak at a 2? angle (2?(112)) of from 26° to 28° for Cu radiation at 40 kV, wherein a glancing incidence x-ray diffraction pattern (GIXRD) for a glancing angle of from 0.2° to 10° reflects an absolute shift in the 2?(112) angle of less than 0.06°.
    Type: Grant
    Filed: August 13, 2004
    Date of Patent: June 29, 2010
    Assignee: University of Johannesburg
    Inventor: Vivian Alberts
  • Patent number: 7740721
    Abstract: Provided is a copper alloy sputtering target containing 0.01 to (less than) 0.5 wt % of at least 1 element selected from Al or Sn, and containing Mn or Si in a total amount of 0.25 wtppm or less. The above copper alloy sputtering target allows the formation of a wiring material for a semiconductor element, in particular, a seed layer being stable, uniform and free from the occurrence of coagulation during electrolytic copper plating and exhibits excellent sputtering film formation characteristics. A semiconductor element wiring formed with this target is also provided.
    Type: Grant
    Filed: February 19, 2004
    Date of Patent: June 22, 2010
    Assignee: Nippon Mining & Metals Co., Ltd
    Inventor: Takeo Okabe
  • Patent number: 7736448
    Abstract: The present invention relates to a nanocrystalline metallic material, particularly to nano-twin copper material with ultrahigh strength and high electrical conductivity and its preparation method. High-purity polycrystalline Cu material with a microstructure of roughly equiaxed submicron-sized grains (300-1000 nm) has been produced by pulsed electrodeposition technique, by which high density of growth-in twins with nano-scale twin spacing were induced in the grains. Inside each grain, there are high densities of growth-in twin lamellae. The twin lamellae with the same orientations are inter-parallel, and the twin spacing ranges from several nanometers to 100 nm with a length of 100-500 nm. This Cu material invented has more excellent performance than existing ones.
    Type: Grant
    Filed: October 16, 2003
    Date of Patent: June 15, 2010
    Assignee: Institute of Metal Research Chinese Academy of Sciences
    Inventors: Lei Lu, Xiao Si, Yongfeng Shen, Ke Lu
  • Publication number: 20100139822
    Abstract: Provided is a Cu—Ti-based copper alloy sheet material that satisfies all the requirements of high strength, excellent bending workability and stress relaxation resistance and has excellent sprig-back resistance. The copper alloy sheet material has a composition containing, by mass, from 1.0 to 5.0% of Ti, and optionally containing at least one of at most 0.5% of Fe, at most 1.0% of Co and at most 1.5% of Ni, and further optionally containing at least one of Sn, Zn, Mg, Zr, Al, Si, P, B, Cr, Mn and V in an amount within a suitable range, with the balance of Cu and inevitable impurities, and having a crystal orientation satisfying the following expression (1) and preferably also satisfying the following expression (2). The mean crystal grain size of the material is controlled to be from 10 to 60 ?m. I{420}/I0{420}>1.0 ??(1) I{220}/I0{220}?3.
    Type: Application
    Filed: December 8, 2008
    Publication date: June 10, 2010
    Inventors: Weilin Gao, Hisashi Suda, Hiroto Narieda, Akira Sugawara
  • Patent number: 7695578
    Abstract: A copper-based alloy that has the soundness of alloy enhanced by restraining the concentrated occurrence of microporosities while suppressing the lead content and an ingot and a liquid-contacting part using the alloy are provided. The copper-based alloy has the soundness of alloy improved during the course of solidification of the copper-based alloy by crystallizing an intermetallic compound capable of solidifying at a temperature exceeding a solidus line in dendritic gaps of the alloy, suppressing migration of a solute, thereby allowing dispersion of microporosities, utilizing crystallization of the intermetallic compound as well for effecting dispersed crystallization of a low melting metal or a low melting intermetallic compound capable of solidifying at a temperature falling short of a liquidus line, and relying on the low melting metal or low melting intermetallic compound to enter the microporosities and suppress occurrence of microporosities.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: April 13, 2010
    Assignee: Kitz Corporation
    Inventors: Teruhiko Horigome, Kazuhito Kurose
  • Publication number: 20090320964
    Abstract: The present invention discloses a heat resistance copper alloy material characterized in that said copper alloy material comprises 0.15 to 0.33 mass percent of Co, 0.041 to 0.089 mass percent of P, 0.02 to 0.25 mass percent of Sn, 0.01 to 0.40 mass percent of Zn and the remaining mass percent of Cu and inevitable impurities, wherein each content of Co, P, Sn and Zn satisfies the relationships 2.4?([Co]?0.02)/[P]?5.2 and 0.20?[Co]+0.5 [P]+0.9 [Sn]+0.1 [Zn]?0.54, wherein [Co], [P], [Sn] and [Zn] are said mass percents of Co, P, Sn and Zn content, respectively; and said copper alloy material is a pipe, plate, bar, wire or worked material obtained by working said pipe, plate, bar or wire material into predetermined shapes.
    Type: Application
    Filed: September 9, 2009
    Publication date: December 31, 2009
    Applicant: MITSUBISHI SHINDOH CO., LTD.
    Inventor: Keiichiro Oishi
  • Publication number: 20090317290
    Abstract: The invention relates to a multicomponent copper alloy comprising [in % by weight]: Ni from 1.0 to 15.0%, Sn from 2.0 to 12.0%, Mn from 0.1 to 5.0%, Si from 0.1 to 3.0%, balance Cu and unavoidable impurities, if desired up to 0.5% of P, if desired individually or in combination up to 1.5% of Ti, Co, Cr, Al, Fe, Zn, Sb, if desired individually or in combination up to 0.5% of B, Zr, S, if desired up to 5% of Pb, and having Mn—Ni silicide phases which have a mass ratio of the elements [w(Mn)+w(Ni)]/w(Si) in the range from 1.8/1 to 7/1.
    Type: Application
    Filed: April 26, 2007
    Publication date: December 24, 2009
    Inventors: Maher Ababneh, Hans-Achim Kuhn, Volker Voggeser
  • Patent number: 7608157
    Abstract: The present invention discloses a heat resistance copper alloy material characterized in that said copper alloy material comprises 0.15 to 0.33 mass percent of Co, 0.041 to 0.089 mass percent of P, 0.02 to 0.25 mass percent of Sn, 0.01 to 0.40 mass percent of Zn and the remaining mass percent of Cu and inevitable impurities, wherein each content of Co, P, Sn and Zn satisfies the relationships 2.4?([Co]?0.02)/[P]?5.2 and 0.20?[Co]+0.5[P]+0.9[Sn]+0.1[Zn]?0.54, wherein [Co], [P], [Sn] and [Zn] are said mass percents of Co, P, Sn and Zn content, respectively; and said copper alloy material is a pipe, plate, bar, wire or worked material obtained by working said pipe, plate, bar or wire material into predetermined shapes.
    Type: Grant
    Filed: September 19, 2003
    Date of Patent: October 27, 2009
    Assignee: Mitsubishi Shindoh Co., Ltd.
    Inventor: Keiichiro Oishi
  • Publication number: 20090260727
    Abstract: A Sn-containing copper alloy, contains Sn: 0.01 to 16 mass %, Zr: 0.001 to 0.049 mass %, P: 0.01 to 0.25 mass %, and Cu: remainder; satisfying f0=[Cu]?0.5[Sn]?3[P]=61 to 97, f1=[P]/[Zr] 0.5 to 100, f2=3[Sn]/[Zr]=30 to 15000 and f3=3[Sn]/[P]=3 to 2500 (the content of element ‘a’ is represented as [a] mass %). ? and ?-phases and/or ?-phase are included and the total content of the ? and ?-phases and/or ?-phase reaches 90% or more by area ratio, and the mean grain size of the macrostructure during melt-solidification is 300 ?m or less.
    Type: Application
    Filed: August 10, 2005
    Publication date: October 22, 2009
    Applicant: SANBO SHINDO KOGYO KABUSHIKI KAISHA
    Inventor: Keiichiro Oishi
  • Publication number: 20090229716
    Abstract: A copper alloy material for electric/electronic parts, which is produced by the steps containing: finish rolling a copper alloy at a reduction ratio of 40% or less, subjecting the copper alloy finish-rolled to a heat treatment under the conditions at a temperature from 500° C. to 800° C. for a time period from 1 second to 100 seconds by means of a continuous annealing line, and strain relief annealing the copper alloy heat-treated under the conditions at a temperature from 400° C. to 600° C. for a time period from 30 seconds to 1000 seconds, wherein the copper alloy material for electric/electronic parts has rates of dimensional changes before and after the strain relief annealing in both directions parallel to and perpendicular to the rolling direction within the range from ?0.02% to +0.02%.
    Type: Application
    Filed: April 9, 2009
    Publication date: September 17, 2009
    Inventors: Junsuke NAKANO, Keisuke Kitazato, Takao Hirai
  • Patent number: 7510615
    Abstract: An age-hardening copper alloy made of—as expressed in each case in weight %—0.4% to a maximum of 2% cobalt which is partially replaceable by nickel, 0.1% through 0.5% beryllium, optionally 0.03% through 0.5% zirconium, 0.005% through 0.1% magnesium and possibly a maximum of 0.15% of at least one element from the group including niobium, manganese, tantalum, vanadium, titanium, chromium, cerium and hafnium. The remainder is copper inclusive of production-conditioned impurities and usual processing additives. This copper alloy is used as the material for producing casting molds, in particular for the sleeves of continuous casting rolls as components of a two-roll casting installation.
    Type: Grant
    Filed: November 13, 2002
    Date of Patent: March 31, 2009
    Assignee: KME Germany AG & Co. KG
    Inventors: Dirk Rode, Thomas Helmenkamp, Fred Riechert
  • Patent number: 7507304
    Abstract: Provided is a first copper alloy sputtering target comprising 0.5 to 4.0 wt % of Al and 0.5 wtppm or less of Si; a second copper alloy sputtering target comprising 0.5 to 4.0 wt % of Sn and 0.5 wtppm or less of Mn; the first or the second alloy sputtering target further comprising one or more selected from among Sb, Zr, Ti, Cr, Ag, Au, Cd, In and As in a total amount of 1.0 wtppm or less; and a semiconductor element wiring formed by the use of the above target. The above copper alloy sputtering target allows the formation of a wiring material for a semiconductor element, in particular, a seed layer being stable, uniform and free from the occurrence of coagulation during electrolytic copper plating and exhibits excellent sputtering film formation characteristics.
    Type: Grant
    Filed: October 16, 2003
    Date of Patent: March 24, 2009
    Assignee: Nippon Mining & Metals Co., Ltd.
    Inventors: Takeo Okabe, Hirohito Miyashita
  • Publication number: 20090014097
    Abstract: A copper alloy casting with excellent machinability, strength, wear resistance and corrosion resistance contains Sn: 0.5 to 15 mass %; Zr: 0.001 to 0.049 mass %; P: 0.01 to 0.35 mass %; one or more elements selected from Pb: 0.01 to 15 mass %, Bi: 0.01 to 15 mass %, Se: 0.01 to 1.2 mass %, and Te: 0.05 to 1.2 mass %; and Cu: 73 mass % or more serving as a remainder. In this case, f1=[P]/[Zr]=0.5 to 100, f2=3[Sn]/[Zr]=300 to 15000, and f3=3[Sn]/[P]=40 to 2500 (the content of an element ‘a’ is expressed as [a] mass %). The total content of ?, ? and ?-phases is 95% or more, and the mean grain size is 300 ?m or less.
    Type: Application
    Filed: August 10, 2005
    Publication date: January 15, 2009
    Applicant: SANBO SHINDO KOGYO KABUSHIKI KAISHA
    Inventor: Keiichiro Oishi
  • Patent number: 7472927
    Abstract: A tubular member 12 having an internal and/or external metal thread 18, 20 at one end thereof, at least part of the thread 18, 20 being coated with an alloy of copper and tin, said alloy containing 5 wt % to 95 wt % copper. The tubular member 10 can be combined with another tubular member 14, 16 to provide a threaded connection 10 having improved galling resistance.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: January 6, 2009
    Assignees: Hunting Oilfield Services (UK) Ltd., M.P. Eastern Limited
    Inventors: Richard J. Guise, Michael G. Edwards
  • Publication number: 20080210353
    Abstract: The invention aims at providing high-strength copper alloy, especially phosphor bronze, with excellent bending workability. The excellently bendable high-strength copper alloy is obtained through grain size control whereby a finally cold rolled copper alloy with a tensile strength and 0.2% yield strength different by not more than 80 MPa is allowed to have characteristics such that its mean grain size (mGS) after annealing at 425° C. for 10,000 seconds is not more than 5 ?m and the standard deviation of the mean grain size (?GS) is not more than ?×mGS. Improvements in characteristics presumably attributable to the synergistic effect of grain-boundary strengthening and dislocation strengthening are stably achieved by the adjustments of cold rolling and annealing conditions and by the study of the correlation between pertinent characteristic values after the final rolling.
    Type: Application
    Filed: April 11, 2008
    Publication date: September 4, 2008
    Applicant: Nippon Mining & Metals Co., Ltd.
    Inventors: Kazuhiko Fukamachi, Masato Shigyo
  • Publication number: 20080190524
    Abstract: This invention provides a copper alloy sheet material containing, in mass %, Ni: 0.7%-4.2% and Si: 0.2%-1.0%, optionally containing one or more of Sn: 1.2% or less, Zn: 2.0% or less, Mg: 1.0% or less, Co: 2.0% or less, and Fe: 1.0% or less, and a total of 3% or less of one or more of Cr, B, P, Zr, Ti, Mn and V, the balance being substantially Cu, and having a crystal orientation satisfying Expression (1): I{420}/I0{420}>1.0, ??(1) where I{420} is the x-ray diffraction intensity from the {420} crystal plane in the sheet plane of the copper alloy sheet material and I0{420} is the x-ray diffraction intensity from the {420} crystal plane of standard pure copper powder. The copper alloy sheet material has highly improved strength, post-notching bending workability, and stress relaxation resistance property.
    Type: Application
    Filed: February 12, 2008
    Publication date: August 14, 2008
    Inventors: Weilin Gao, Hisashi Suda, Hiroto Narieda, Akira Sugawara
  • Patent number: 7351372
    Abstract: As a raw material of a copper base alloy containing at least one of 0.2 to 12 wt % of tin and 8 to 45 wt % of zinc, at least one of a copper base alloy having a large surface area and containing carbon on the surface thereof, a copper base alloy having a liquidus line temperature of 1050° C. or less, a copper base alloy surface-treated with tin, and a copper base alloy containing 20 to 1000 ppm of carbon, is used for obtaining a copper base alloy having an excellent hot workability. If necessary, when the raw material of the copper base alloy is melted, the material of the copper base alloy may be coated with a solid material containing 70 wt % or more of carbon, or 0.005 to 0.5 wt % of a solid deoxidizer having a stronger affinity with O than C with respect to the weight of the molten metal may be added to the molten metal.
    Type: Grant
    Filed: September 22, 2003
    Date of Patent: April 1, 2008
    Assignee: Dowa Mining Co., Ltd.
    Inventors: Yasuo Inohana, Akira Sugawara, Toshihiro Sato
  • Patent number: 7338631
    Abstract: This copper alloy contains at least zirconium in an amount of not less than 0.005% by weight and not greater than 0.5% by weight, includes a first grain group including grains having a grain size of not greater than 1.5 ?m, a second grain group including grains having a grain size of greater than 1.5 ?m and less than 7 ?m, the grains having a form which is elongated in one direction, and a third grain group including grains having a grain size of not less than 7 ?m, and also the sum of ? and ? is greater than ?, and ? is less than ?, where ? is a total area ratio of the first grain group, ? is a total area ratio of the second grain group, and ? is a total area ratio of the third grain group, based on a unit area, and ?+?+?=1.
    Type: Grant
    Filed: September 23, 2004
    Date of Patent: March 4, 2008
    Assignee: Mitsubishi Shindoh Co., Ltd.
    Inventors: Masahiko Ishida, Junichi Kumagai, Takeshi Suzuki
  • Patent number: 7297215
    Abstract: By exactly comprehending the true properties of the rare elements (such as Bi and Se) which are alternative components for Pb, the alloy is enabled to secure machinability equal to the bronze alloy (CAC406) generally used hitherto and acquire mechanical properties at least equal to the CAC406 as well in spite of a decrease in the content of the rare elements (such as Bi and Se) in the alloy. Further, it is possible to suppress the occurrence of casting defects by elucidating the unresolved influence of the decrease of the alternative components (such as Bi and Se) for Pb on the wholesomeness of a casting. Moreover, it is possible, by decreasing the rare elements, to produce a copper-based alloy containing rare elements at a low cost and to provide a cast ingot and a liquid-contacting part each using the alloy. The copper-based alloy, and the cast ingot and liquid-contacting part each using the alloy individually contain at least 2.8 to 5.0 wt % of Sn, 0.4 to 3.0 wt % of Bi and satisfying 0<Se?0.
    Type: Grant
    Filed: September 9, 2003
    Date of Patent: November 20, 2007
    Assignee: Kitz Corporation
    Inventors: Kazuhito Kurose, Yukihiro Hirata, Tomoyuki Ozasa, Hisanori Terui
  • Patent number: 7182823
    Abstract: A copper alloy having an improved combination of yield strength and electrical conductivity consists essentially of, by weight, from 1% to 2.5% of nickel, from 0.5% to 2.0% of cobalt, from 0.5% to 1.5% of silicon, and the balance is copper and inevitable impurities. Further, the total nickel plus cobalt content is from 1.7% to 4.3%, the ratio of nickel to cobalt is from 1.01:1 to 2.6:1, the amount of (Ni+Co)/Si is between 3.5 and 6, the electrical conductivity is in excess of 40% IACS and the yield strength is in excess of 95 ksi. An optional inclusion is up 1% of silver. A process to manufacture the alloy includes the sequential steps of (a). casting; (b). hot working; (c). solutionizing; (d). first age annealing; (e). cold working; and (f). second age annealing wherein the second age annealing temperature is less than the first age annealing temperature.
    Type: Grant
    Filed: June 30, 2003
    Date of Patent: February 27, 2007
    Assignee: Olin Corporation
    Inventors: Frank N. Mandigo, Peter W. Robinson, Derek E. Tyler, Andreas Boegel, Hans-Achim Kuhn, Frank M. Keppeler, Joerg Seeger
  • Patent number: 7172662
    Abstract: A copper alloy material for parts of electronic and electric machinery and tools contains 1.0 to 3.0 mass % of Ni, 0.2 to 0.7 mass % of Si, 0.01 to 0.2 mass of Mg, 0.05 to 1.5 mass % of Sn, 0.2 to 1.5 mass % of Zn, and less than 0.005 mass % (including 0 mass %) of S, with the balance being Cu and inevitable impurities, wherein the copper alloy material has: (1) a specific crystal grain diameter, and a specific ratio between the longer diameters of a crystal grain on a cross section parallel or perpendicular to a direction of final plastic working; and/or (2) a specific surface roughness after the final plastic working.
    Type: Grant
    Filed: January 30, 2003
    Date of Patent: February 6, 2007
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Takayuki Usami, Takao Hirai
  • Patent number: 7160401
    Abstract: Use of a low-alloyed, phosphorus-deoxidized copper alloy (DHP-Cu) for manufacturing hollow profile components by internal high-pressure forming, the copper alloy having the following composition: 0.030 to 0.080 wt-% of at least one element of a group including tin (Sn), Zinc (Zn), iron (Fe), silver (Ag) and at least 99.90 wt-% of (Cu) as well as unavoidable impurities as the remainder. Because of its cold work hardening properties, such a copper alloy is especially suitable for the manufacture of hollow profile components by internal high-pressure forming.
    Type: Grant
    Filed: August 11, 2003
    Date of Patent: January 9, 2007
    Assignee: KM Europa Metal AG
    Inventors: Mainhard Hecht, Mathias Konczalla, Ulrich Naumann
  • Patent number: 7090732
    Abstract: A high-mechanical strength copper alloy, which comprises Ni 1.0 to 4.5% by mass, Si 0.2 to 1.0% by mass, Mg 0.01 to 0.20% by mass, Sn 0.05 to 1.5% by mass, Zn 0.2 to 1.5% by mass, and S less than 0.005% by mass (including 0% by mass), with the balance being made of Cu and inevitable impurities, wherein the alloy has a tensile strength of 800 N/mm2 or more, and wherein the alloy has a stress relaxation ratio of 10% or less.
    Type: Grant
    Filed: June 25, 2003
    Date of Patent: August 15, 2006
    Assignee: The Furukawa Electric, Co., Ltd.
    Inventors: Takayuki Usami, Takao Hirai
  • Patent number: 6974509
    Abstract: Brass consists essentially of Cu, Sn, Bi, Fe, Ni and P in weight ratios respectively of 58.0-63.2%, 0.3-2.0%, 0.7-2.5%, 0.05-0.3%, 0.10-0.50% and 0.05-0.15% plus the balance of Zn and unavoidable impurities to exhibit excellent tolerance for dezincification, hot forgeability and machinability.
    Type: Grant
    Filed: June 2, 2003
    Date of Patent: December 13, 2005
    Assignee: Kitz Corporation
    Inventors: Koichi Hagiwara, Masaru Yamazaki, Yoshihiro Hirata, Mitsuhide Hirabayashi, Kozo Ito
  • Patent number: 6949150
    Abstract: Copper alloy having the basic composition Cu—Zn—Sn contains 23-28 wt % Zn and 0.3-1.8 wt % Sn and satisfies the relation 6.0?0.25X+Y?8.5 (where X is the addition of Zn in wt % and Y is the addition of Sn in wt %). The alloy is cast into an ingot by melting and cooling over the range from the liquidus line to 600° C. at a rate of at least 50° C./min; the ingot is hot rolled at a temperature not higher than 900° C. and then subjected to repeated cycles of cold rolling and annealing at 300-650° C. to control the size of crystal grains, thereby producing a rolled strip having a 0.2% yield strength of at least 600 N/mm2, a tensile strength of at least 650 N/mm2, an electrical conductivity of at least 20% IACS, a Young's modulus of no more than 120 kN/mm2 and a percent stress relaxation of no more than 20%.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: September 27, 2005
    Assignee: Dowa Mining Co., Ltd.
    Inventors: Akira Sugawara, Kazuki Hatakeyama, Le Ling
  • Patent number: 6946039
    Abstract: The invention includes a physical vapor deposition target composed of a face centered cubic unit cell metal or alloy and having a uniform grain size less than 30 microns, preferably less than 1 micron; and a uniform axial or planar <220> texture. Also described is a method for making sputtering targets. The method can comprise billet preparation; equal channel angular extrusion with a prescribed route and number of passes; and cross-rolling or forging subsequent to the equal channel angular extrusion.
    Type: Grant
    Filed: November 2, 2000
    Date of Patent: September 20, 2005
    Assignee: Honeywell International Inc.
    Inventors: Vladimir M. Segal, Stephane Ferrasse, Frank Alford
  • Patent number: 6942742
    Abstract: A copper-based alloy excellent in dezincing resistance comprises, in percentage by weight, Cu: 57-69%, Sn: 0.3-3%, Si: 0.02-1.5%, Bi: 0.5-3%, and Pb: not more than 0.2%, where the ratio of Si/Sn expressed in weight percentage is in the range of 0.05-1 and apparent zinc content as defined by the following formula is in the range of more than 39-50 wt. %, and the balance of unavoidable impurities: Apparent Zn content=[(Zn %+2.0×Sn %+10.0×Si %)/(Cu %+Zn %+2.0×Sn %+10.0×Si %)]×100. Despite the fact that contains no added environment-unfriendly Pb, the alloy exhibits enhanced cuttability, together with excellent forgeability, dezincing resistance and hot forgeability.
    Type: Grant
    Filed: October 29, 2003
    Date of Patent: September 13, 2005
    Assignee: Dowa Mining Co., Ltd.
    Inventor: Yoshinori Yamagishi