Zinc(zn), Zinc Base Alloy Or Unspecified Galvanizing Patents (Class 148/533)
  • Patent number: 10378077
    Abstract: A method for producing a cold rolled steel sheet having a tensile strength ?1470 MPa and a total elongation TE?19%, the method comprising the steps of annealing at an annealing temperature AT?Ac3 a non-treated steel sheet whose chemical composition contains in weight %: 0.34%?C?0.40%, 1.50%?Mn?2.30%, 1.50?Si?2.40%, 0%<Cr?0.5%, 0%<Mo?0.3%, 0.01%?A1?0.07%, the remainder being Fe and unavoidable impurities, quenching the annealed steel sheet by cooling it to a quenching temperature QT<Ms transformation point and between 150° C. and 250° C., and making a partitioning treatment by reheating the quenched steel sheet to a partitioning temperature PT between 350° C. and 420° C. and maintaining the steel sheet at this temperature during a partitioning time Pt between 15 seconds and 120 seconds.
    Type: Grant
    Filed: July 3, 2014
    Date of Patent: August 13, 2019
    Assignee: ArcelorMittal
    Inventors: Olga A. Girina, Damon Panahi
  • Patent number: 10344350
    Abstract: The present disclosure relates to a production of a high-strength steel sheet with excellent combination of strength and ductility, and a method of manufacturing the same. In accordance with a method of manufacturing a high-strength steel sheet, the method may include: heating a steel sheet which can have a residual austenite upon cooling, to form an austenite; primary cooling the austenitized steel sheet to T1 for a bainite region and subjecting to a primary isothermal transformation; and secondary cooling the primary isothermal transformed steel sheet to T2, which is lower than T1 by 50° C. ore more, for a bainite region, and subjecting to a secondary isothermal transformation.
    Type: Grant
    Filed: December 16, 2015
    Date of Patent: July 9, 2019
    Assignee: KOREA INSTITUTE OF MACHINERY AND MATERIALS
    Inventor: Chang-Hoon Lee
  • Patent number: 10344361
    Abstract: The present invention relates to an ultra-high strength, hot-dip galvanized steel sheet having excellent surface quality and coating adherence and to a method for manufacturing thereof, the ultra-high strength, hot-dip galvanized steel sheet comprising: 0.1-0.3% by weight carbon (C); 0.1-2.0% by weight silicon (Si); 0.005-1.5% by weight aluminum (Al); 1.5-3.5% by weight manganese (Mn); 0.04% by weight or less phosphorus (P) (excluding 0% by weight); 0.015% by weight or less sulphur (S) (excluding 0% by weight); 0.02% by weight or less nitrogen (N) (excluding 0% by weight); the balance being Fe; and other inevitable impurities, and further comprising 0.01 wt.% to 0.07 wt.% of at least one kind of element selected from the group consisting of bismuth (Bi), tin (Sn) and antimony (Sb).
    Type: Grant
    Filed: December 8, 2015
    Date of Patent: July 9, 2019
    Assignee: POSCO
    Inventors: Myung-Soo Kim, Ki-Cheol Kang
  • Patent number: 10301701
    Abstract: Disclosed is a high-strength hot-dip galvanized steel sheet produced from a steel sheet containing Si and Mn as a base material and a method for producing the same. The method using the following conditions for a heating process for annealing: (1) The rate of temperature rise when the temperature inside an annealing furnace is in a temperature range of from 450° C. to A° C. inclusive (where A is an arbitrary value selected in a range of 500?A) is 7° C./sec. or more; (2) The maximum steel sheet temperature reached during the annealing is 600° C. or higher and 750° C. or lower; (3) When the temperature of the steel sheet is in a temperature range of from 600° C. to 750° C. inclusive during the annealing, the transit time of the steel sheet is 30 seconds or longer and 10 minutes or shorter, and the dew point of an atmosphere is ?45° C. or lower.
    Type: Grant
    Filed: February 6, 2015
    Date of Patent: May 28, 2019
    Assignee: JFE STEEL CORPORATION
    Inventors: Yusuke Fushiwaki, Yoshiyasu Kawasaki
  • Patent number: 10167541
    Abstract: Provided is an alloyed hot-dip galvanized steel sheet including a base steel sheet, the base steel sheet containing a given amount of C, Si, Mn, and other elements. The alloyed hot-dip galvanized steel sheet is provided with an alloyed hot-dip galvanized layer on a surface of the base steel sheet, the alloyed hot-dip galvanized layer containing, in mass %, Fe: more than or equal to 5% and less than or equal to 15%, and having a thickness of more than or equal to 3 ?m and less than or equal to 30 ?m.
    Type: Grant
    Filed: November 5, 2013
    Date of Patent: January 1, 2019
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Soshi Fujita, Shintaro Yamanaka
  • Patent number: 10106867
    Abstract: A steel strip is annealed in a vertical annealing furnace including a heating zone and a soaking zone through which the steel strip is vertically conveyed, an atmosphere gas is supplied into the furnace to form a furnace gas that is discharged from a steel strip entrance at a lower portion of the heating zone, a part of the furnace gas is sucked and discharged into a refiner to form a gas having a lowered dew point that is returned into the furnace. A gas injector having a plurality of gas outlets arranged in a direction of a travel of the steel strip is disposed to suppress a mixing of an atmosphere in the furnace upstream of the gas injector and an atmosphere in the furnace downstream of the gas injector, and a temperature of the steel strip passing through the gas injector is controlled to 600° C. to 700° C.
    Type: Grant
    Filed: June 10, 2013
    Date of Patent: October 23, 2018
    Assignee: JFE Steel Corporation
    Inventor: Hideyuki Takahashi
  • Patent number: 10087511
    Abstract: There are provided a method for manufacturing a high manganese hot-dip galvanized steel sheet having superior coatability and ultra-high strength, and a high manganese hot-dip galvanized steel sheet manufactured by the method. The method includes: cold rolling a hot-rolled steel sheet to form a cold-rolled steel sheet, the hot-rolled steel sheet including, by wt %, C: 0.3% to 1%, Mn: 8% to 25%, Si: 0.1% to 3%, Al: 0.01% to 8%, Cr: 0.1% to 2%, Ti: 0.01% to 0.2%, B: 0.0005% to 0.01%, Ni: 0.01% to 2%, Sn: 0.06% to 0.2%, and a balance of Fe and inevitable impurities; heating the cold-rolled steel sheet; cooling the heated steel sheet to, or maintaining the heated steel sheet; and performing a hot-dip galvanizing process on the cooled or temperature-maintained steel sheet by dipping the cooled or temperature-maintained steel sheet into a hot-dip galvanizing bath.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: October 2, 2018
    Assignee: POSCO
    Inventors: Sun-Ho Jeon, Kwang-Geun Chin, Won-Tae Cho
  • Patent number: 10030280
    Abstract: The present invention provides a steel sheet with chemical components including, by mass %, 0.18-0.35% of C, 1.0%-3.0% of Mn, 0.01%-1.0% of Si, 0.001%-0.02% of P, 0.0005%-0.01% of S, 0.001%-0.01% of N, 0.01%-1.0% of Al, 0.005%-0.2% of Ti, 0.0002%-0.005% of B, and 0.002%-2.0% of Cr, and the balance of Fe and inevitable impurities, wherein: by volume %, a fraction of the ferrite is 50% or more, and a fraction of a non-recrystallized ferrite is 30% or less; and Cr?/CrM is 2 or less, where Cr? is a concentration of Cr subjected to solid solution in iron carbide and CrM is a concentration of Cr subjected to solid solution in a base material, or Mn0/MnM is 10 or less, where Mn0 is a concentration of Mn subjected to solid solution in an iron carbide, and MnM is a concentration of Mn subjected to solid solution in a base material.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: July 24, 2018
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Kunio Hayashi, Toshimitsu Aso, Toshimasa Tomokiyo
  • Patent number: 9994941
    Abstract: A high strength cold rolled steel sheet has a chemical composition including, by mass %, C: 0.06 to 0.13%, Si: 1.2 to 2.3%, Mn: 0.6 to 1.6%, P: not more than 0.10%, S: not more than 0.010%, Al: 0.01 to 0.10% and N: not more than 0.010%, the balance comprising Fe and inevitable impurities. The steel sheet includes a microstructure containing not less than 90% in terms of volume fraction of ferrite with an average grain diameter of less than 20 ?m and 1.0 to 10% in terms of volume fraction of pearlite with an average grain diameter of less than 5 ?m. The ferrite has an average Vickers hardness of not less than 130. The steel sheet has a yield ratio of not less than 65% and a tensile strength of not less than 590 MPa.
    Type: Grant
    Filed: December 3, 2012
    Date of Patent: June 12, 2018
    Assignee: JFE Steel Corporation
    Inventors: Katsutoshi Takashima, Yuki Toji, Kohei Hasegawa
  • Patent number: 9920407
    Abstract: A cold rolled steel sheet according to the present invention satisfies an expression of (5×[Si]+[Mn])/[C]>11 when [C] represents an amount of C by mass %, [Si] represents an amount of Si by mass %, and [Mn] represents an amount of Mn by mass %, a metallographic structure before hot stamping includes 40% to 90% of a ferrite and 10% to 60% of a martensite in an area fraction, a total of an area fraction of the ferrite and an area fraction of the martensite is 60% or more, a hardness of the martensite measured with a nanoindenter satisfies an H2/H1<1.10 and ?HM<20 before the hot stamping, and TS×? which is a product of a tensile strength TS and a hole expansion ratio ? is 50000 MPa·% or more.
    Type: Grant
    Filed: January 11, 2013
    Date of Patent: March 20, 2018
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Toshiki Nonaka, Satoshi Kato, Kaoru Kawasaki, Toshimasa Tomokiyo
  • Patent number: 9896751
    Abstract: High strength steel sheet and high strength galvanized steel sheet which are excellent in shapeability which secure a tensile maximum strength 900 MPa or more high strength while obtaining excellent ductility and stretch flangeability, which sheets have predetermined compositions of ingredients, have steel sheet structures which contain volume fraction 1 to 20% of residual austenite phases, and which have martensite transformation points of the residual austenite phases of ?60° C. or less.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: February 20, 2018
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Yuji Yamaguchi, Natsuko Sugiura
  • Patent number: 9828663
    Abstract: Provided is a galvannealed steel sheet with excellent anti-powdering property when press forming is performed, without controlling the contents of chemical elements in steel which are effective for strengthening a steel sheet, such as Si and P, to be low in order to achieve required material properties and without increasing cost due to, for example, processes being complicated. A galvannealed steel sheet with excellent anti-powdering property has a coated layer taking in grains of a base steel sheet such that the grains constitute 2.0% or more and 15.0% or less of the coated layer in terms of cross section area ratio.
    Type: Grant
    Filed: June 18, 2013
    Date of Patent: November 28, 2017
    Assignee: JFE Steel Corporation
    Inventors: Yoichi Makimizu, Yoshitsugu Suzuki, Hideki Nagano, Yasunobu Nagataki
  • Patent number: 9790567
    Abstract: A coated dual-phase steel and process for producing the coated dual-phase steel is provided. The process includes providing a steel slab with a desired chemistry, soaking the slab at an elevated temperature and then hot rolling the slab to produce hot-rolled strip. The hot-rolled strip is coiled and has a ferrite-pearlite microstructure. The coiled hot-rolled strip is cold-rolled into cold-rolled sheet with at least a 60% reduction in thickness compared to the thickness of the coiled hot-rolled strip. The cold-rolled sheet is subjected to an intercritical anneal followed by rapid cooling with the absence of an isothermal heat treatment or hold after rapid cooling near the molten metal pot temperature—during which, before or after which the steel is coated. The coated steel sheet has a dual-phase ferrite-martensite microstructure, a yield strength of at least 310 MPa, a tensile strength of at least 580 MPa and a total elongation to failure of at least 18%.
    Type: Grant
    Filed: November 20, 2013
    Date of Patent: October 17, 2017
    Assignee: Thyssenkrupp Steel USA, LLC
    Inventors: Ranbir Jamwal, Joseph Frimpong, Bertram Wilhelm Ehrhardt, Harald Van Bracht, Roger Dale Boggs, Stanley Wayne Bevans
  • Patent number: 9708684
    Abstract: There is provided a hot-dip galvanized steel sheet and a hot-dip galvannealed steel sheet, which have excellent elongation properties, and methods for manufacturing the hot-dip galvanized steel sheet and the hot-dip galvannealed steel sheet. The present disclosure relates to a hot-dip galvanized steel sheet in which a hot-dip galvanized layer is formed on a surface of a base steel sheet, the hot-dip galvanized steel sheet having excellent elongation properties and being characterized by the composition and the microstructure thereof.
    Type: Grant
    Filed: December 23, 2015
    Date of Patent: July 18, 2017
    Assignee: POSCO
    Inventors: Sang Ho Han, Seong Ho Han
  • Patent number: 9694561
    Abstract: High strength steel sheet which secures tensile maximum strength 900 MPa or more high strength while having excellent shapeability, which high strength steel sheet which is excellent in shapeability characterized by having a predetermined composition of ingredients, by the steel sheet structure including a ferrite phase and martensite phase, by the ratio of Cu particles incoherent with the bcc iron being 15% or more with respect to the Cu particles as a whole, by a density of Cu particles in the ferrite phase being 1.0×1018/m3 or more, and by an average particle size of Cu particles in the ferrite phase being 2.0 nm or more.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: July 4, 2017
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Masafumi Azuma, Takuya Kuwayama, Shigeru Yonemura
  • Patent number: 9598745
    Abstract: The present invention provides a method for manufacturing a hot stamped body, the method including: a hot-rolling step; a coiling step; a cold-rolling step; a continuous annealing step; and a hot stamping step, in which the continuous annealing step includes a heating step of heating the cold-rolled steel sheet to a temperature range of equal to or higher than Ac1° C. and lower than Ac3° C.; a cooling step of cooling the heated cold-rolled steel sheet from the highest heating temperature to 660° C. at a cooling rate of equal to or less than 10° C./s; and a holding step of holding the cooled cold-rolled steel sheet in a temperature range of 550° C. to 660° C. for one minute to 10 minutes.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: March 21, 2017
    Assignees: NIPPON STEEL & SUMITOMO METAL CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHA, AISIN TAKAOKA CO., LTD.
    Inventors: Kunio Hayashi, Toshimitsu Aso, Toshimasa Tomokiyo, Hitoshi Tanino, Ryozo Wada
  • Patent number: 9551055
    Abstract: A high-strength hot-dip galvanized steel sheet containing a main component, the steel sheet having at least 40 wt. % of ferrite as a main phase in terms of the volumetric ratio, and 8-60% inclusive of residual austenite, the remaining structure comprising one or more of bainite, martensite, or pearlite. Austenite particles within a range where the average residual stress (sigmaR) thereof satisfies the expression ?400 MPa<=sigmaR<=200 MPa (formula (1)) are present in an amount of 50% or more in the hot-dip galvanized steel sheet. The surface of the steel sheet has a hot-dip galvanized layer containing less than 7 wt. % of Fe, the remainder comprising Zn, Al and inevitable impurities.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: January 24, 2017
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Koichi Sato, Shintaro Yamanaka, Soshi Fujita
  • Patent number: 9476111
    Abstract: A hot dip galvanized steel sheet includes a steel sheet, a hot dip galvanizing layer, and an intermetallic compound, in which the steel sheet has a chemical composition containing, by mass %, C: 0.03% or more and 0.70% or less, Si: 0.10% or less, Mn: 0.5% or more and 0.9% or less, P: 0.020% or more and 0.050% or less, S: 0.010% or less, Nb: 0.010% or more and 0.035% or less, N: 0.005% or less, Al: 0.10% or less, and the balance being Fe and inevitable impurities, in which the hot dip galvanizing layer contains 0.3% or more and 0.6% or less of Al, and in which the intermetallic compound contains 0.12 gm?2 or more and 0.22 gm?2 or less of Al and Fe2Al5 having an average grain diameter of 1 ?m or less.
    Type: Grant
    Filed: December 24, 2013
    Date of Patent: October 25, 2016
    Assignee: JFE Steel Corporation
    Inventors: Yoshitsugu Suzuki, Mai Miyata, Yasunobu Nagataki
  • Patent number: 9334555
    Abstract: Exemplary embodiments of the present invention can provide a hot dip galvannealed steel sheet which has excellent corrosion resistance, workability, coatability and appearance. The exemplary galvannealed sheet can include an ultra-low carbon steel sheet having a plating layer which includes about 8 to 13% Fe, about 0.05 to 1.0% Ni, about 0.15 to 1.5% Al, and a balance of Zn and unavoidable impurities. An exemplary method for producing a hot dip galvannealed steel sheet is also provided which can include cleaning an annealed ultra-low carbon steel sheet, preplating it with Ni, rapidly heating the sheet in a nonoxidizing or reducing atmosphere, plating the sheet in a galvanization bath containing Al, wiping it, then rapidly reheating it and either cooling the sheet without any soaking time or soaking and holding it for less than 15 seconds and then cooling it.
    Type: Grant
    Filed: January 17, 2013
    Date of Patent: May 10, 2016
    Assignee: NIPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Kiyokazu Ishizuka, Kazumi Nishimura, Ikuo Kikuchi, Akihiro Miyasaka
  • Patent number: 9322091
    Abstract: There is provided a high-strength galvanized steel sheet including, on a mass percent basis, C: more than 0.060% and 0.13% or less, Si: 0.01% or more and 0.7% or less, Mn: 1.0% or more and 3.0% or less, P: 0.005% or more and 0.100% or less, S: 0.010% or less, sol.Al: 0.005% or more and 0.100% or less, N: 0.0100% or less, Nb: 0.005% or more and 0.10% or less, Ti: 0.03% or more and 0.15% or less, and the balance comprising Fe and incidental impurities, satisfying the relationship of (Nb/93+Ti*/48)/(C/12)>0.08 (wherein Ti*=Ti?(48/14)N?(48/32)S). The high-strength galvanized steel sheet has a structure including ferrite and martensite. The ferrite has an average grain diameter of 15 ?m or less and an area percentage of 80% or more. The martensite has an area percentage of 1% or more and 15% or less.
    Type: Grant
    Filed: January 28, 2013
    Date of Patent: April 26, 2016
    Assignee: JFE STEEL CORPORATION
    Inventors: Hideyuki Kimura, Katsutoshi Takashima, Shinjiro Kaneko
  • Patent number: 9290834
    Abstract: A galvanized steel sheet has a composition containing, by mass %, C: 0.05% or more and 0.5% or less, Si: 0.01% or more and 2.5% or less, Mn: 0.5% or more and 3.5% or less, P: 0.003% or more and 0.100% or less, S: 0.02% or less, Al: 0.010% or more and 0.5% or less, B: 0.0002% or more and 0.005% or less, Ti: 0.05% or less, a relationship of Ti>4N being satisfied, and the balance comprising Fe and inevitable impurities, and a microstructure containing 60% or more and 95% or less of tempered martensite in terms of area ratio and 5% or more and 20% or less of retained austenite in terms of area ratio.
    Type: Grant
    Filed: October 7, 2011
    Date of Patent: March 22, 2016
    Assignee: JFE Steel Corporation
    Inventors: Hiroshi Hasegawa, Tatsuya Nakagaito, Shinjiro Kaneko, Yasunobu Nagataki, Yoshitsugu Suzuki
  • Patent number: 9290835
    Abstract: The invention provides a cold-rolled steel sheet excellent in paint bake hardenability and ordinary-temperature non-aging property comprising, in mass %, C: 0.0005-0.0040%, Si: 0.8% or less, Mn: 2.2% or less, S: 0.0005-0.009%, Cr: 0.4-1.3%, O: 0.003-0.020%, P: 0.045-0.12%, B: 0.0002-0.0010%, Al: 0.008% or less, N: 0.001-0.007%, and a balance of Fe and unavoidable impurities. Ultra-low-carbon steel retaining solute N and containing added Cr, P, B and O is used to produce hot-rolled and cold-rolled steel sheet and hot-dip galvanized cold-rolled steel sheet that exhibit both high paint bake hardenability and ordinary-temperature non-aging property.
    Type: Grant
    Filed: October 5, 2005
    Date of Patent: March 22, 2016
    Assignee: Nippon Steel & Summitomo Metal Corporation
    Inventors: Naoki Yoshinaga, Naoki Maruyama, Manabu Takahashi, Natsuko Sugiura
  • Patent number: 9234253
    Abstract: A readily formable flat steel product has a ductile edge layer that is from 10 to 200 ?m thick and has a ductility greater than a ductility of an inner core layer of the flat steel product. The readily formable flat steel product is produced by annealing a flat steel product having a C content of from 0.1 to 0.4% by weight in a continuous furnace. The annealing is carried out under an annealing atmosphere that contains from 0.1 to 25% by vol. of H2 and H2O, with the balance being N2 and technically unavoidable impurities. A dew point is between ?20° C. and +60° C., and a ratio of H2O/H2 is a maximum of 0.957. In the course of the annealing, the flat steel product is heated to a holding temperature of from 600 to 1100° C. and for a holding time of from 10 to 360 seconds.
    Type: Grant
    Filed: December 3, 2010
    Date of Patent: January 12, 2016
    Assignee: ThyssenKrupp Steel Europe AG
    Inventors: Wilhelm Warnecke, Manfred Meurer, Jens Kondratiuk, Marc Blumenau, Martin Norden, Thiemo Wuttke
  • Patent number: 9181598
    Abstract: A high-strength alloyed hot-dip galvanized steel sheet obtained by subjecting the surface of a high-strength steel sheet to alloyed hot-dip galvanization, and formed from a steel sheet containing, in mass %, main components, and containing at least 40 vol % bainite and/or martensite, 8-60 vol % retained austenite, and less than 40 vol % ferrite, with the remainder comprising unavoidable structures. In the alloyed hot-dip galvanized steel sheet, the total thickness of the Gamma1 layer and the Gamma layer (Tgamma1+Tgamma) is 2 ?m or less in the alloy layers formed by hot-dip galvanization, and the Gamma1 phase/Gamma phase thickness ratio (Tgamma1/Tgamma) is 1 or less. A tensile strength of 980 MPa or above can be easily imparted to the alloyed hot-dip galvanized steel sheet. The alloyed hot-dip galvanized steel sheet has excellent coating adherence, and coating separation during machining can be suppressed.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: November 10, 2015
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Shintaro Yamanaka, Soshi Fujita, Koichi Sato
  • Patent number: 9175374
    Abstract: A high strength hot-dip galvanized steel sheet has TS of 440 MPa or more and an average r value of 1.30 or more, where the absolute value of the planar anisotropy of the r value (?r) is 0.20 or less. A chemical composition contains C: 0.010% or more and 0.04% or less, Si: more than 1.0% and 1.5% or less, Mn: 1.0% or more and 3.0% or less, P: 0.005% or more and 0.1% or less, S: 0.01% or less, sol. Al: 0.005% or more and 0.5% or less, N: 0.01% or less, Nb: 0.010% or more and less than 0.05%, Ti: 0.015% or more and 0.120% or less, and the remainder composed of Fe and incidental impurities, wherein (Nb/93)/(C/12) 0.20 and 0.005<C*?0.020 are satisfied.
    Type: Grant
    Filed: August 23, 2012
    Date of Patent: November 3, 2015
    Assignee: JFE Steel Corporation
    Inventors: Hideyuki Kimura, Kaneharu Okuda, Yasunobu Nagataki, Kenji Kawamura
  • Patent number: 9163305
    Abstract: An annealing and manufacturing method of hot-dip galvanized steel strips includes suppression of oxide formation of elements in the steel strips. An annealing furnace includes a heating zone, a soaking zone, and a cooling zone in which a portion of gas is introduced to decrease the gas dew point. A gas suction rate Qo1 in a portion of the cooling zone, a gas suction rate Qo2 in an upper portion and a gas feed rate Qi2 in a lower portion of the soaking zone, a gas feed rate Qi1 in a connection part between the soaking and cooling zones, an atmosphere gas supply rate Qf1 into the cooling zone and its subsequent zone, an atmosphere gas supply rate Qf2 into the soaking zone, an internal volume Vs of the soaking zone, and an average furnace temperature Ts of the soaking zone satisfy relationships including 0.3×Qf1<Qo1.
    Type: Grant
    Filed: December 13, 2011
    Date of Patent: October 20, 2015
    Assignee: JFE STEEL CORPORATION
    Inventors: Hideyuki Takahashi, Nobuyuki Sato, Kazuki Nakazato, Masato Iri
  • Patent number: 9150940
    Abstract: A high-strength alloyed hot-dip galvanized steel sheet obtained by subjecting the surface of a high-strength steel sheet to alloyed hot-dip galvanization, and formed from a steel sheet containing, in mass %, main components, and containing at least 40 vol % bainite and/or martensite, 8-60 vol % retained austenite, and less than 40 vol % ferrite, with the remainder comprising unavoidable structures. In the alloyed hot-dip galvanized steel sheet, the total thickness of the Gamma1 layer and the Gamma layer (Tgamma1+Tgamma) is 2 ?m or less in the alloy layers formed by hot-dip galvanization, and the Gamma1 phase/Gamma phase thickness ratio (Tgamma1/Tgamma) is 1 or less. A tensile strength of 980 MPa or above can be easily imparted to the alloyed hot-dip galvanized steel sheet. The alloyed hot-dip galvanized steel sheet has excellent coating adherence, and coating separation during machining can be suppressed.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: October 6, 2015
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Shintaro Yamanaka, Soshi Fujita, Koichi Sato
  • Patent number: 9127329
    Abstract: A method for manufacturing a coated part having very high mechanical properties using hot forming techniques. The method includes: —providing an annealed steel strip or blank or pre-shaped part that was coated with a metal or metal alloy before the annealing —if a strip is provided, cutting a blank from the strip before or after the annealing —optionally forming a pre-shaped part from the blank —heating the blank or preshaped part to a temperature of 500° C. at an average heating rate of 16° C./s or more —further heating the blank or pre-shaped part to a temperature between 700 and 1000° C. —hot forming the blank or preshaped part into a hot formed part —hardening the hot formed part. A method for manufacturing a coated steel strip, blank or pre-shaped part, and a coated steel strip, blank or part and a hot formed part.
    Type: Grant
    Filed: July 19, 2011
    Date of Patent: September 8, 2015
    Assignee: TATA STEEL IJMUIDEN B.V.
    Inventors: Willem Cornelis Verloop, Marc Jacco van Genderen, Ronald Theodoor van Tol, Guido Cornelis Hensen, Jenny Loiseaux
  • Patent number: 9096918
    Abstract: Exemplary embodiments of a facility or an arrangement capable of producing a high strength steel sheet or a hot dip zinc coated high strength steel sheet according to the present invention are provided which can make a quenching facility and tempering facility continuous treatment facilities. For example, an improvement in the material quality can be effectuated due to tempering enable improvement of the hole expandability. In addition, an elongation of the sheet can be improved.
    Type: Grant
    Filed: November 9, 2005
    Date of Patent: August 4, 2015
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Hirokazu Taniguchi, Toshiki Nonaka, Hiroki Murayama, Koji Yanaba, Satoshi Kato
  • Patent number: 9090960
    Abstract: A strain aging hardening type steel sheet excellent in aging resistance, and manufacturing method thereof, said steel sheet comprises: in mass %, C: 0.0010 to 0.010%; Si: 0.005 to 1.0%; Mn: 0.08 to 1.0%; P: 0.003 to 0.10%; S: 0.0005 to 0.020%; Al: 0.010 to 0.10%; Cr: 0.005 to 0.20%; Mo: 0.005 to 0.20%; Ti: 0.002 to 0.10%; Nb: 0.002 to 0.10%; N: 0.001 to 0.005%; and a balance being composed of Fe and inevitable impurities, in which a ferrite fraction is 98% or more, an average grain diameter of ferrite is 5 to 30 ?m, a minimum value of dislocation density in a portion having a ½ thickness of a sheet thickness and a minimum value of dislocation density in a surface layer portion are each 5×1012/m2 or more, and an average dislocation density falls within a range of 5×1012 to 1×1015/m2.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: July 28, 2015
    Assignee: NIPPON STEEL AND SUMITOMO METAL CORPORATION
    Inventors: Naoki Maruyama, Koji Hashimoto, Masaharu Kameda
  • Patent number: 9073292
    Abstract: A high strength galvanized steel sheet includes a steel sheet which is a base sheet and a galvanized layer on a surface of the steel sheet, the steel sheet has a composition including, by mass %, 0.08 to 0.15% of C, 0.5 to 1.5% of Si, 0.5 to 1.5% of Mn, 0.1% or less of P, 0.01% or less of S, 0.01 to 0.1% of Al, 0.005% or less of N, and the balance Fe with inevitable impurities, and a microstructure composed of 75 to 90% of a ferrite phase as a main phase and 10 to 25% of a second phase including at least pearlite in terms of an area fraction with respect to the entire microstructure; an average grain size of the pearlite is 5 ?m or smaller; and the pearlite has an area fraction of 70% or greater with respect to the total area of the second phase.
    Type: Grant
    Filed: June 29, 2011
    Date of Patent: July 7, 2015
    Assignee: JFE Steel Corporation
    Inventors: Kenji Kawamura, Hidetaka Kawabe, Kazuhiro Seto
  • Publication number: 20150147589
    Abstract: A rolled steel sheet or blank is provided, the composition of which comprises the elements listed below in per cent by weight: C?0.1%; 0.5%?Mn?7%; 0.5%?Si?3.5%; 0.5%<Ti?2%; 2%<Ni?7%; Al?0.10%; Cr?2%; Cu?2%; Co?2%; Mo?2%; S?0.005%; P?0.03%; Nb?0.1%; V?0.1%; B<0.005%; N?0.008%, and the silicon and titanium contents are such that: Si + Ti ? 2.5 ? % , Ti Si ? 0.3 the remainder of the composition consisting of iron and unavoidable impurities resulting from processing. A method for the fabrication of a part for a land motor vehicle from the sheet or blank by hot stamping is also provided. The microstructure of the part consisting essentially of martensite and intermetallic precipitates of type Fe2TiSi with an area percentage between 1 and 5% intermetallic precipitates.
    Type: Application
    Filed: September 6, 2011
    Publication date: May 28, 2015
    Applicant: Arcelormittal Investigacion Y Desarrollo, S.L.
    Inventors: Olivier Bouaziz, David Barbier, Coralie Jung
  • Patent number: 9028626
    Abstract: A method of manufacturing a high-strength galvanized steel sheet includes hot-rolling a slab to form a steel sheet; during continuous annealing, heating the steel sheet to a temperature of 750° C. to 900° C. at an average heating rate of at least 10° C./s at a temperature of 500° C. to an A1 transformation point; holding that temperature for at least 10 seconds; cooling the steel sheet from 750° C. to a temperature of (Ms point—100° C.) to (Ms point—200° C.) at an average cooling rate of at least 10° C./s; reheating the steel sheet to a temperature of 350° C. to 600° C.; holding that temperature for 10 to 600 seconds; and galvanizing the steel sheet.
    Type: Grant
    Filed: March 25, 2013
    Date of Patent: May 12, 2015
    Assignee: JFE Steel Corporation
    Inventors: Tatsuya Nakagaito, Saiji Matsuoka, Shinjiro Kaneko, Yoshiyasu Kawasaki, Yoshitsugu Suzuki
  • Publication number: 20150125716
    Abstract: Provided is a method for producing a plated steel sheet with high Si content for hot stamping, which is capable of suppressing the generation of unplated portions, while maintaining high bonding strength in a welded part in cases where a galvanized steel sheet containing a large amount of Si, namely, 0.7% or more of Si is used for hot stamping applications. In this production method, a hot-rolled pickled steel sheet or cold-rolled steel sheet containing 0.10-0.5% by mass of C, 0.7-2.5% by mass of Si, 1.0-3% by mass of Mn, and 0.01-0.5% by mass of Al is annealed in a reducing atmosphere and then plated, thereby producing a galvanized steel sheet for hot stamping. This method for producing a galvanized steel sheet for hot stamping is characterized in that the annealing is carried out within the range of 500 to 700° C. for 30 to 270 seconds.
    Type: Application
    Filed: April 23, 2013
    Publication date: May 7, 2015
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventors: Takeshi Kojima, Hiroshi Irie, Takeshi Minowa
  • Publication number: 20150111064
    Abstract: Provided are: a high-strength hot-dip galvanized steel sheet in which bending workability of the high-strength hot-dip galvanized steel sheet is improved, and in which strength difference between a center part and end parts in the sheet width direction is reduced; and a method for manufacturing a high-strength hot-dip galvanized steel sheet. The steel sheet is a hot-dip galvanized steel sheet having a hot-dip galvanizing layer on a surface of a base steel sheet containing: C, Mn, P, S, and Al; Ti and B in amounts satisfying equation (1); and N; and Si as needed; the remainder comprising iron and unavoidable impurities; the metallographic structure of the base steel sheet having martensite, bainite, and ferrite, the ratios of each with respect to the overall metallographic structure being 50 area % or more of the martensite, 15-50 area % of the bainite, and 5 area % or less of the ferrite, 0.005×[Mn]+0.02×[B]1/2+0.025?[Ti]?0.15.
    Type: Application
    Filed: March 22, 2013
    Publication date: April 23, 2015
    Applicant: KABUSHIKI KAISHA KOBE SEIKO SHO(KOBE STEEL, LTD.)
    Inventors: Muneaki Ikeda, Masaaki Miura
  • Patent number: 9011614
    Abstract: A high-strength galvanized steel sheet has excellent mechanical properties such as a TS of 1200 MPa or more, an El of 13% or more, and a hole expansion ratio of 50% or more and a method for manufacturing the same. A high-strength galvanized steel sheet excellent in formability contains 0.05% to 0.5% C, 0.01% to 2.5% Si, 0.5% to 3.5% Mn, 0.003% to 0.100% P, 0.02% or less S, and 0.010% to 0.5% Al on a mass basis, the remainder being Fe and unavoidable impurities, and has a microstructure which contains 0% to 10% ferrite, 0% to 10% martensite, and 60% to 95% tempered martensite on an area basis as determined by structure observation and which further contains 5% to 20% retained austenite as determined by X-ray diffractometry.
    Type: Grant
    Filed: January 28, 2009
    Date of Patent: April 21, 2015
    Assignee: JFE Steel Corporation
    Inventors: Tatsuya Nakagaito, Saiji Matsuoka, Yoshitsugu Suzuki, Yuki Toji
  • Publication number: 20150101712
    Abstract: Provided is a method that enables manufacture, with good productivity, of a high-strength cold-rolled steel with improved elongation (EL), stretch-flangeability (?), bendability (R), and balance of these properties (TS×EL×?/1000), outstanding composite workability as evaluated by Erichsen test, and a tensile strength of at least 980 MPa. A steel material satisfying a prescribed constituent composition is held and soaked for at least fifty seconds at a temperature at or above the Ac3 point, after which the steel material is cooled at an average cooling rate of at least 15° C./sec to a discretionary temperature (T) that satisfies expression (1) below, held for 5-180 seconds in a temperature range that satisfies expression (1) below, then heated to a temperature region that satisfies expression (2) below, held for at least 50 seconds in this temperature region, and then cooled. 300° C.?T1 (° C.)<400° C. ??(1) 400° C.?T2 (° C.)<540° C.
    Type: Application
    Filed: February 28, 2013
    Publication date: April 16, 2015
    Applicant: KABUSHIKI KAISHA KOBE SEIKO SHO (KOBE STEEL, LTD.)
    Inventors: Yuichi Futamura, Michiharu Nakaya
  • Patent number: 8999084
    Abstract: A galvanized steel sheet includes a zinc plating layer which is disposed on a steel sheet containing 0.01% to 0.15% C, 0.001% to 2.0% Si, 0.1% to 3.0% Mn, 0.001% to 1.0% Al, 0.005% to 0.060% P, and 0.01% or less S on a mass basis, the remainder being Fe and unavoidable impurities, and which has a mass per unit area 20 g/m2 to 120 g/m2. An oxide of at least one selected from the group consisting of Fe, Si, Mn, Al, and P is present in a surface portion of the steel sheet that lies directly under the zinc plating layer and that extends up to 100 ?m from the surface of a base steel sheet. The amount of the oxide per unit area is 0.05 g/m2 or less in total. The steel sheet has excellent corrosion resistance, anti-powdering property during heavy machining, and strength.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: April 7, 2015
    Assignee: JFE Steel Corporation
    Inventors: Yusuke Fushiwaki, Yoshiharu Sugimoto
  • Publication number: 20150086808
    Abstract: A high-strength cold-rolled steel sheet has a specific chemical composition and has a steel microstructure meeting conditions: a total content of bainitic ferrite (BF) and tempered martensite (TM) is 65% (in area percent, hereinafter the same for steel microstructure) or more; a fresh martensite (M) content is 3% to 18%; a retained austenite content is 5% or more; and a polygonal ferrite (F) content is 5% or less. The steel sheet has a specific average KAM<1.00° of 0.50° or more and has a tensile strength of 980 MPa or more. The high-strength cold-rolled steel sheet excels in formability and shape fixability.
    Type: Application
    Filed: March 6, 2013
    Publication date: March 26, 2015
    Applicant: KABUSHIKI KAISHA KOBE SEIKO SHO (Kobe Steel, Ltd.)
    Inventors: Kouji Kasuya, Yuichi Futamura, Yukihiro Utsumi
  • Publication number: 20150079420
    Abstract: The steel for hot forming has the following composition in weight %: C: 0.10-0.25, Mn: 1.4-2.8, Si: ?1.0, Cr: ?1.0, Ti: ?0.05, Nb: ?0.05, V: ?0.1, Mo: ?0.1, Al: ?0.05, P: ?0.02, S: ?0.005, Ca: ?0.005, O: ?0.01, N: ?0.02, B: ?0.0004, the remainder being iron and unavoidable impurities. Also disclosed is a strip, sheet or blank produced with such a steel, a method for producing a hot formed product, such a product and the use thereof.
    Type: Application
    Filed: September 17, 2014
    Publication date: March 19, 2015
    Inventors: David Neal HANLON, Stefanus Matheus Cornelis VAN BOHEMEN
  • Patent number: 8968494
    Abstract: The present invention provides a high-strength galvanized steel sheet having excellent ductility, stretch flangeability, and fatigue resistance, and a method for manufacturing the same. A high-strength galvannealed steel sheet having excellent formability and fatigue resistance is characterized in that the steel sheet is composed of steel having a composition containing, by % by mass, C: 0.05% to 0.3%, Si: 0.5% to 2.5%, Mn: 1.0% to 3.5%, P: 0.003% to 0.100%, S: 0.02% or less, Al: 0.010% to 0.1%, and the balance including iron and unavoidable impurities, and the steel sheet has a microstructure containing 50% or more of ferrite, 5% to 35% of martensite, and 2% to 15% of pearlite in terms of an area ratio, the martensite having an average gain size of 3 ?m or less and an average distance of 5 ?m or less between adjacent martensite grains.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: March 3, 2015
    Assignee: JFE Steel Corporation
    Inventors: Tatsuya Nakagaito, Yoshiyasu Kawasaki, Shinjiro Kaneko, Saiji Matsuoka, Yoshitsugu Suzuki
  • Publication number: 20150056468
    Abstract: The high strength steel sheet has a chemical composition including 0.08% to 0.20% of C, 0.3% or less of Si, 0.1% to 3.0% of Mn, 0.10% or less of P, 0.030% or less of S, 0.10% or less of Al, 0.010% or less of N, 0.20% to 0.80% of V, and the remainder composed of Fe and incidental impurities on a percent by mass basis, and a microstructure which includes 95% or more of ferrite phase on an area percentage basis, in which fine precipitates are dispersed having a distribution in such a way that the number density of precipitates having a particle size of less than 10 nm is 1.0×105/?m3 or more and the standard deviation of natural logarithm values of precipitate particle sizes with respect to precipitates having a particle size of less than 10 nm is 1.5 or less.
    Type: Application
    Filed: April 18, 2013
    Publication date: February 26, 2015
    Inventors: Taro Kizu, Yoshimasa Funakawa, Hidekazu Ookubo, Tokunori Kanemura, Masato Shigemi, Shoji Kasai, Shinji Yamazaki, Yusuke Yasufuku
  • Publication number: 20150047753
    Abstract: The invention relates to a method for producing a component from transformable steel by hot forming, in which a plate first is cut out of a strip or sheet as the pre-material, and is then heated to forming temperature and pre-formed, having an at least partially martensitic transformation structure after forming. Instead of a press mould hardening, the at least partially martensitic transformation structure is created in the pre-material, or in the plate to be formed, by austenitisation and quenching already before forming, and then the thus-conditioned plate is reheated after forming, while maintaining the at least partially martensitic transformation structure, to a temperature below the Ac1 transformation temperature, and formed at this temperature.
    Type: Application
    Filed: February 27, 2013
    Publication date: February 19, 2015
    Inventors: Friedrich Luther, Thomas Evertz, Stefan Muetze, Michael Braun
  • Publication number: 20150044503
    Abstract: A method for manufacturing a high strength galvanized steel sheet and a high strength galvanized steel sheet are provided. A base steel sheet having a chemical composition comprising C: 0.03% to 0.35%, Si: 0.01% to 0.50%, Mn: 3.6% to 8.0%, Al: 0.001% to 1.000%, P?0.10%, S?0.010%, and the balance comprising Fe and incidental impurities, on a percent by mass basis, is subjected to annealing and galvanization treatment, wherein the maximum steel sheet temperature in an annealing furnace is 600° C. or higher and 700° C. or lower, the steel sheet transit time in a temperature region of the maximum steel sheet temperature of 600° C. or higher and 700° C. or lower is specified to be 30 seconds or more and 10 minutes or less, and the dew point in an atmosphere is specified to be ?45° C. or lower.
    Type: Application
    Filed: March 7, 2013
    Publication date: February 12, 2015
    Applicant: JFE STEEL CORPORATION
    Inventors: Yusuke Fushiwaki, Yoshiyasu Kawasaki, Yasunobu Nagataki
  • Publication number: 20150044504
    Abstract: A high strength hot dip galvanized steel strip including, in mass percent, of the following elements: 0.10-0.18% C, 1.90-2.50% Mn, 0.30-0.50% Si, 0.50-0.70% Al, 0.10-0.50% Cr, 0.001-0.10% P, 0.01-0.05% Nb, max 0.004% Ca, max 0.05% S, max 0.007% N, and optionally at least one of the following elements: 0.005-0.50% Ti, 0.005-0.50% V, 0.005-0.50% Mo, 0.005-0.50% Ni, 0.005-0.50% Cu, max 0.005% B, the balance Fe and inevitable impurities, wherein 0.80%<Al+Si<1.05% and Mn+Cr>2.10%. This steel offers improved formability at a high strength, has a good weldability and surface quality together with a good produce-ability and coat-ability.
    Type: Application
    Filed: October 28, 2014
    Publication date: February 12, 2015
    Inventors: Bernard Leo Ennis, David Neal HANLON
  • Publication number: 20150044502
    Abstract: Disclosed is a hot-dip galvanized steel sheet for stamping, which has excellent cold workability, has such satisfactory surface quality as to be free from unplating and other defects even in the absence of dedicated facilities, and ensures a strength of 1370 MPa or more after quenching even when cooled at a low rate. Also disclosed is a method effective for the produce of the hot-dip galvanized steel sheet for stamping. The hot-dip galvanized steel sheet for stamping comprises a base steel sheet and a hot-dip galvanized layer on a surface of the base steel sheet, in which the base steel sheet has a predetermined chemical composition and has a microstructure comprising equiaxed ferrite having an average aspect ratio of 4.0 or less and cementite and/or pearlite having an average major axis of grains of 20 ?m or less.
    Type: Application
    Filed: March 28, 2013
    Publication date: February 12, 2015
    Applicants: KABUSHIKI KAISHA KOBE SEIKO SHO (Kobe Steel, Ltd.), VOESTALPINE STAHL GMBH
    Inventors: Michiharu Nakaya, Tatsuya Asai, Andreas Pichler, Thomas Kurz
  • Patent number: 8951366
    Abstract: A high-strength cold-rolled steel sheet includes, by mass %, C: 0.10% to 0.40%, Mn: 0.5% to 4.0%, Si: 0.005% to 2.5%, Al: 0.005% to 2.5%, Cr: 0% to 1.0%, and a balance of iron and inevitable impurities, in which an amount of P is limited to 0.05% or less, an amount of S is limited to 0.02% or less, an amount of N is limited to 0.006% or less, the microstructure includes 2% to 30% of retained austenite by area percentage, martensite is limited to 20% or less by area percentage in the microstructure, an average particle size of cementite is 0.01 ?m to 1 ?m, and 30% to 100% of the cementite has an aspect ratio of 1 to 3.
    Type: Grant
    Filed: January 26, 2011
    Date of Patent: February 10, 2015
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Kohichi Sano, Chisato Wakabayashi, Hiroyuki Kawata, Riki Okamoto, Naoki Yoshinaga, Kaoru Kawasaki, Natsuko Sugiura, Nobuhiro Fujita
  • Publication number: 20150030881
    Abstract: A method for manufacturing a high strength galvanized steel sheet and a high strength galvanized steel sheet are provided. A high strength galvanized steel sheet having a zinc coating layer with an amount of deposition of coating of 20 to 120 g/m2 per one surface on the surface of a base steel sheet having a chemical composition comprising C: 0.03% to 0.35%, Si: 0.01% to 0.50%, Mn: 3.6% to 8.0%, Al: 0.001% to 1.000%, P?0.10%, S?0.010%, and the balance comprising Fe and incidental impurities, on a percent by mass basis, is produced. At this time, in annealing and galvanization treatment of the base steel sheet in a continuous galvanizing line, the maximum steel sheet temperature in an annealing furnace is 600° C. or higher and 750° C. or lower, the steel sheet transit time in a temperature region of the maximum steel sheet temperature of 600° C. or higher and 750° C. or lower is specified to be 30 seconds or more and 10 minutes or less, and the dew point in an atmosphere is specified to be ?10° C. or higher.
    Type: Application
    Filed: March 7, 2013
    Publication date: January 29, 2015
    Applicant: JEF STEEL CORPORATION
    Inventors: Yusuke Fushiwaki, Yoshiyasu Kawasaki, Yasunobu Nagataki
  • Publication number: 20150030880
    Abstract: The present invention provides a high-strength hot-rolled steel sheet having both excellent strength and excellent workability (particularly, bending workability), and a method of producing the same. The steel sheet of the present invention has a certain composition as well as microstructures such that an area ratio of ferrite phase is 95% or more, an average grain size of the ferrite phase is 8 ?m or less, and carbides in grains of the ferrite phase have an average particle size of less than 10 nm. The steel sheet of the present invention also has a tensile strength of 980 MPa or more.
    Type: Application
    Filed: January 21, 2013
    Publication date: January 29, 2015
    Applicant: JEF STEEL CORPORATION
    Inventors: Noriaki Kosaka, Yoshimasa Funakawa, Masato Shigemi, Hidekazu Ookubo, Tokunori Kanemura
  • Publication number: 20150027596
    Abstract: The invention provides a steel sheet for hot press-forming that can reliably give hot press-formed parts having excellent paint adhesiveness, perforation corrosion resistance and joint corrosion resistance, and also provides a method for manufacturing the steel sheet for hot press-forming, and a method for producing hot press-formed parts using the steel sheet for hot press-forming. The steel sheet for hot press-forming includes a base steel sheet and a Zn-based coating layer with a mass of coating of 10 to 90 g/m2 on the base steel sheet, wherein the average ferrite grain diameter in the surface microstructure of the base steel sheet is not more than 20 ?m.
    Type: Application
    Filed: March 4, 2013
    Publication date: January 29, 2015
    Applicant: JEF STEEL CORPORATION
    Inventors: Tatsuya Miyoshi, Seiji Nakajima, Satoru Ando