With Ageing, Solution Treating (i.e., For Hardening), Precipitation Hardening Or Strengthening Patents (Class 148/671)
  • Publication number: 20090056841
    Abstract: A process for making parts from titanium or a titanium alloy is disclosed. The process includes the step of preparing an intermediate form of titanium or a titanium alloy. The intermediate form is then solution heat treated under conditions of temperature and time that are selected to produce a desired level of strength when the titanium or titanium alloy part is subsequently age hardened. The solution treated intermediate form is then thermomechanically formed into a desired part or a preform for a desired part. The as-formed part or preform is then age-hardened under conditions of temperature and time that are selected to produce the desired level of strength in the finished part. The age-hardening step is performed without solution heat treating the as-formed part or preform again.
    Type: Application
    Filed: August 30, 2007
    Publication date: March 5, 2009
    Inventor: Buford R. Riffee, JR.
  • Publication number: 20090032152
    Abstract: A titanium-alloy article is produced by providing a workpiece of an alpha-beta titanium alloy having a beta-transus temperature, and thereafter mechanically working the workpiece at a mechanical-working temperature above the beta-transus temperature. The mechanically worked workpiece is solution heat treated at a solution-heat-treatment temperature of from about 175° F. below the beta-transus temperature to about 25° F. below the beta-transus temperature, quenched, overage heat treated at an overage-heat-treatment temperature of from about 400° F. below the beta-transus temperature to about 275° F. below the beta-transus temperature, and cooled from the overage-heat-treatment temperature.
    Type: Application
    Filed: October 10, 2008
    Publication date: February 5, 2009
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Andrew Philip WOODFIELD, Wesley Douglas PRIDEMORE, Bernard Harold LAWLESS, Nancy Ann SULLIVAN, Peter WAYTE, Michael James WEIMER, Thomas Froats BRODERICK
  • Patent number: 7481898
    Abstract: A Ti-6Al-4V-0.2O (Ti64) forged article is fabricated by forging a workpiece to make a forged gas turbine engine component having a thick portion thereof with a section thickness greater than 2¼ inches. The forged article is heat treated by solution heat treating at a temperature of from about 50° F. to about 75° F. below the beta-transus temperature of the alloy, thereafter water quenching the gas turbine engine component to room temperature, and thereafter aging the gas turbine engine component at a temperature of from about 900° F. to about 1000° F. The resulting machined gas turbine engine component has a 0.2 percent yield strength of from about 120 ksi to about 140 ksi at its centerline, and a 0.2 percent yield strength of from about 160 ksi to about 175 ksi at a location about ½ inch below a surface thereof.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: January 27, 2009
    Assignee: General Electric Company
    Inventors: Peter Wayte, Ming Cheng Li
  • Patent number: 7479194
    Abstract: A damage tolerant microstructure for a lamellar alloy, such as a lamellar ?TiAl alloy, is provided in accordance with the present invention. The alloy comprises a matrix and a plurality of grains or lamellar colonies, a portion of which exhibit a nonplanar morphology within said matrix. Each of the lamellar colonies contains a multitude of lamella with irregularly repeating order. The ?TiAl platelets have a triangular (octahedral) unit cell and stack with ? twins. The ?2Ti3Al platelets are irregularly interspersed. The unit cell for ?2Ti3Al is hexagonal. Each of the layers has a curved, nonplanar structure for resisting crack formation and growth.
    Type: Grant
    Filed: August 8, 2005
    Date of Patent: January 20, 2009
    Assignee: United Technologies Corporation
    Inventor: Daniel P. DeLuca
  • Publication number: 20080283162
    Abstract: A method for manufacturing a high-strength titanium alloy golf club head part includes making at least one golf club head part with a titanium alloy. The golf club head part is then heated to a temperature higher than a critical temperature of generating martensite and maintained above the critical temperature not more than thirty minutes. The golf club head part is then cooled to a temperature below the critical temperature at a cooling rate higher than 10° C./s. Next, the golf club head part is heated to a heat-treatment temperature higher than 450° C. and maintained at the heat-treatment temperature at least one hour. The golf club head part is then cooled to room temperature. The mechanical characteristics of a golf club head formed by the golf club head part are enhanced.
    Type: Application
    Filed: April 9, 2008
    Publication date: November 20, 2008
    Inventor: Ming-Jui Chiang
  • Patent number: 7449075
    Abstract: A titanium-alloy article is produced by providing a workpiece of an alpha-beta titanium alloy having a beta-transus temperature, and thereafter mechanically working the workpiece at a mechanical-working temperature above the beta-transus temperature. The mechanically worked workpiece is solution heat treated at a solution-heat-treatment temperature of from about 175° F. below the beta-transus temperature to about 25° F. below the beta-transus temperature, quenched, overage heat treated at an overage-heat-treatment temperature of from about 400° F. below the beta-transus temperature to about 275° F. below the beta-transus temperature, and cooled from the overage-heat-treatment temperature.
    Type: Grant
    Filed: June 28, 2004
    Date of Patent: November 11, 2008
    Assignee: General Electric Company
    Inventors: Andrew Philip Woodfield, Wesley Douglas Pridemore, Bernard Harold Lawless, Nancy Ann Sullivan, Peter Wayte, Michael James Weimer, Thomas Froats Broderick
  • Patent number: 7261782
    Abstract: A titanium alloy obtained by a cold-working step, in which 10% or more of cold working is applied to a raw titanium alloy, comprising a Va group element and the balance of titanium substantially, and an aging treatment step, in which a cold-worked member, obtained after the cold-working step, is subjected to an aging treatment so that the parameter “P” falls in a range of from 8.0 to 18.5 at a treatment temperature falling in a range of from 150° C. to 600° C.; and characterized in that its tensile elastic limit strength is 950 MPa or more and its elastic deformation capability is 1.6% or more. This titanium alloy is of high elastic deformation capability as well as high tensile elastic limit strength, and can be utilized in a variety of products extensively.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: August 28, 2007
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: JungHwan Hwang, Tadahiko Furuta, Kazuaki Nishino, Takashi Saito
  • Patent number: 7132021
    Abstract: A process for making a work piece from a ?-type titanium alloy material includes subjecting the ?-type titanium alloy material to cold working with controlling the reduction rate thereof to vary the reduction rate depending on a position across a plain direction of the ?-type titanium alloy material, and then subjecting the ?-type titanium alloy material to an aging treatment.
    Type: Grant
    Filed: June 4, 2004
    Date of Patent: November 7, 2006
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Kouichi Kuroda, Satoshi Matsumoto, Keisuke Nagashima, Nozomu Ariyasu
  • Patent number: 7115177
    Abstract: In a method for the treatment of metallic materials especially for the consolidation of the texture of the materials, a blank of the metallic material is heated to a transformation temperature and the blank is then subjected to twisting preferably while, at the same time, being compressed. In this way, the texture can be refined to a large degree in a simple and inexpensive manner.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: October 3, 2006
    Assignee: Gkss-Forschungszentrum Geesthacht GmbH
    Inventors: Fritz Appel, Stephen Eggert, Uwe Lorenz, Michael Oehring
  • Patent number: 7083687
    Abstract: A super-elastic titanium alloy for medical use consisting essentially of: molybdenum (Mo) as a ? stabilizer element of titanium (Ti): from 2 to 12 at %; an ? stabilizer element of the titanium (Ti): from 0.1 to 14 at %; and the balance being titanium (Ti) and inevitable impurities. The ? stabilizer element is at least one element selected from the group consisting of aluminum (Al), gallium (Ga) and germanium (Ge).
    Type: Grant
    Filed: March 21, 2005
    Date of Patent: August 1, 2006
    Assignee: Furukawa Techno Material Co., Ltd.
    Inventors: Toyonobu Tanaka, Hiroshi Horikawa, Shuichi Miyazaki, Hideki Hosoda
  • Patent number: 7008491
    Abstract: A method for fabricating an article of a titanium-base alloy, such as an alpha-beta titanium gas turbine fan or compressor disk, uses a starting ingot having a thickness of at least about 20 inches, and which is made of a titanium-base alloy having a temperature-composition phase diagram with a beta-phase field and an alpha-beta phase field. The method includes first forging the starting ingot in the beta-phase field to form an in-process billet, thereafter second forging the in-process billet in the alpha-beta phase field, thereafter heating the in-process billet into the beta-phase field to recrystallize the in-process billet, and thereafter third forging the in-process billet. The step of third forging includes forging the in-process billet from a first forging thickness of not less than about 15 inches to a second forging thickness of not more than about 13 inches, at a third-forging temperature of from about 1550° F. to about 1725° F.
    Type: Grant
    Filed: November 12, 2002
    Date of Patent: March 7, 2006
    Assignee: General Electric Company
    Inventor: Andrew Philip Woodfield
  • Patent number: 6997995
    Abstract: The invention relates to a method for producing components with a high load capacity from ?+? TiAl alloys, especially for producing components for aircraft engines or stationary gas turbines. According to this method, enclosed TiAl blanks of globular structure are preformed by isothermal primary forming in the ?+?? or ? phase area. The preforms are then shaped out into components with a predeterminable contour by means of at least one isothermal secondary forming process, with dynamic recrystallization in the ?+?? or ? phase area. The microstructure is adjusted by solution annealing the components in the ? phase area and then cooling them off rapidly.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: February 14, 2006
    Assignees: Leistrits Turbinenkomponenten Remscheid GmbH, Rolls-Royce Deutschland LTD & Co KG
    Inventors: Peter Janschek, Lothar Knippschild, Karl Schreiber, Dan Roth-Fagaraseanu
  • Patent number: 6979375
    Abstract: A titanium alloy member is characterized in that it comprise 40% by weight or more titanium (Ti), a IVa group element and/or a Va group element other than the titanium, wherein a summed amount including the IVa group element and/or the Va group element as well as the titanium is 90% by weight or more, and one or more members made in an amount of from 0.2 to 2.0% by weight and selected from an interstitial element group consisting of oxygen, nitrogen and carbon, and that its basic structure is a body-centered tetragonal crystal or a body-centered cubic crystal in which a ratio (c/a) of a distance between atoms on the c-axis with respect to a distance between atoms on the a-axis falls in a range of from 0.9 to 1.1. This titanium alloy member has such working properties that conventional titanium alloys do not have, is flexible, exhibits a high strength, and can be utilized in a variety of products.
    Type: Grant
    Filed: May 1, 2001
    Date of Patent: December 27, 2005
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Tadahiko Furuta, Yoshiki Seno, JungHwan Hwang, Kazuaki Nishino, Takashi Saito
  • Patent number: 6974507
    Abstract: A damage tolerant microstructure for a lamellar alloy, such as a lamellar ?TiAl alloy, is provided in accordance with the present invention. The alloy comprises a matrix and a plurality of grains or lamellar colonies, a portion of which exhibit a nonplanar morphology within said matrix. Each of the lamellar colonies contains a multitude of lamella with irregularly repeating order. The ?TiAl platelets have a triangular (octahedral) unit cell and stack with ? twins. The ?2Ti3Al platelets are irregularly interspersed. The unit cell for ?2Ti3Al is hexagonal. Each of the layers has a curved, nonplanar structure for resisting crack formation and growth.
    Type: Grant
    Filed: March 3, 2003
    Date of Patent: December 13, 2005
    Assignee: United Technologies Corporation
    Inventor: Daniel P. DeLuca
  • Patent number: 6939419
    Abstract: The invention relates to plastic metal working, more specifically to methods for producing parts of the disk- or shell-type having conical, hemispherical, and also combined parts, such as disk-and-shaft ones. The invention is instrumental in producing large axially symmetric parts from hard-to-work multiphase alloys. The method consists in that the billet is heated in a temperature range above 0.4 m.p. but below the temperature at which a total content of precipitates or an allotropic modification of the matrix of a multiphase alloy is not below 7%. Then the preheated billet is rolled, while controlling its temperature and the tool load, as well as the rolling speed. Once rolled the billet is heat-treated at a temperature depending on the microstructure of the billet material resulting from rolling. Prerolling preparing of a specified microstructure of the billet material is also described.
    Type: Grant
    Filed: June 19, 1997
    Date of Patent: September 6, 2005
    Assignees: General Electric Company, Institute of Metals Superplascity Problems of Academy of Science
    Inventors: Farid Zainullaevich Utyashev, Oscar Akramovich Kaibyshev, Vener Anvarovich Valitov
  • Patent number: 6923934
    Abstract: TiAl alloy includes 46 to 50 at % of Al, 5 at % or less of combination of Mo, V and Si, provided that Si content is 0.7 at % or less, and Mo content satisfies an equation of ?0.3x +17.5 at % or less where x represents Al (at %), and the remainder being Ti and inevitable impurities. Mo may be replaced by Fe or combination of Mo and Fe. TiAl alloy is heated to a melt, poured into a mold, and cooled at a rate of 150 to 250° C./min within a temperature range of 1500 to 1100° C. The resulting product can be used as cast. If desired, however, heat treatment such as HIP or homogenization may be performed within a temperature range of 1100 to 800° C. After the heat treatment, the melt is cooled at a rate of 100° C./min or more until room temperature.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: August 2, 2005
    Assignee: Ishikawajima-Harima Heavy Industries Co., Ltd.
    Inventor: Sadao Nishikiori
  • Patent number: 6918972
    Abstract: A Ni-base alloy which has excellent resistance to permanent set at high temperature and which can be produced at low cost, a heat-resistant spring made of the Ni-base alloy, and a process for producing the spring. The Ni-base alloy of the present invention consists of 0.01 to 0.15 mass % of C, 2.0 mass % or less of Si, 2.5 mass % or less of Mn, 12 to 25 mass % of Cr, 5.0 mass % or less of Mo and/or 5.0 mass % or less of W on condition that Mo+W/2 does not exceed 5.0 mass % or less, 1.5 to 3.5 mass % of Ti, 0.7 to 2.5 mass % of Al, 20 mass % or less of Fe, and the balance of Ni and unavoidable impurities. The ratio of Ti/Al in terms of atomic percentage ranges from 0.6 to 1.5 and the total content of Ti and Al ranges from 4.0 to 8.5 atomic %.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: July 19, 2005
    Assignee: Daido Tokushuko Kabushiki Kaisha
    Inventors: Shigeki Ueta, Toshiharu Noda
  • Patent number: 6918974
    Abstract: An alpha-beta titanium alloy workpiece, preferably furnished in the form of a cast ingot, is processed by mechanically working in the beta phase field and in the alpha-beta phase field, and thereafter quenching from the beta phase field. The workpiece is thereafter mechanically worked at a first alpha-beta phase field temperature in the alpha-beta phase field and quenched from the first alpha-beta phase field temperature. The workpiece is thereafter mechanically worked at a second alpha-beta phase field temperature in the alpha-beta phase field, wherein the second alpha-beta phase field temperature is lower than the first alpha-beta phase field temperature, and optionally quenched from the second alpha-beta phase field temperature. The resulting microstructure is a distribution of globularized coarse alpha-phase particles and globularized fine alpha-phase particles in fine transformed beta grains.
    Type: Grant
    Filed: August 26, 2002
    Date of Patent: July 19, 2005
    Assignee: General Electric Company
    Inventor: Andrew Philip Woodfield
  • Patent number: 6855215
    Abstract: Tableware of Ti or a Ti alloy having a surface hardened layer comprising a first hardened layer in which nitrogen and oxygen are diffused so as to form a solid solution and a second hardened layer which is formed in a region deeper than the first hardened layer. The substrate may have a hard decorative coating film. A substrate comprising Ti or a Ti alloy has on its surface an internal hardened layer comprising a first hardened layer and a second hardened layer, wherein the hard decorative coating film is formed on the surface of the internal hardened layer. The cutlery comprises a working part and a grip, the grip provided with a floating means such as a hollow part. Titanium tableware having excellent long-term mar resistance and high quality appearance, increasing the decorative value of the tableware. Further, a process for surface treatment to obtain the titanium tableware with high productivity and a substrate having a hard decorative coating film with excellent mar resistance and high surface hardness.
    Type: Grant
    Filed: July 3, 2001
    Date of Patent: February 15, 2005
    Assignee: Citizen Watch Co., Ltd.
    Inventors: Hachirou Kushida, Yutaka Fukumura, Yukio Miya
  • Publication number: 20040241037
    Abstract: A composition comprises about 8 to about 12 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition. A method for making an article comprises cold-working a shape from a composition comprising about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition; solution heat treating the shape; and cooling the shape.
    Type: Application
    Filed: June 16, 2004
    Publication date: December 2, 2004
    Inventor: Ming H. Wu
  • Patent number: 6814820
    Abstract: An article is formed of an alpha-beta titanium-base alloy, preferably an alloy having more than about 3.5 weight percent molybdenum. An example of such an article is a gas turbine compressor blade having a nominal composition, in weight percent, of about 4 percent aluminum, about 4 percent molybdenum, about 2 percent tin, about 0.5 percent silicon, balance titanium and impurities. The article is processed to form a martensitic structure therein. The processing, which typically involves forging or weld repairing, includes the steps of first heating the article to a first-heating temperature of greater than about 1600° F., and thereafter first cooling the article to a temperature of less than about 800° F. The article is thereafter second heated to a second-heating temperature of from about 1275° F. to about 1375° F. for a time of from about 1 to about 7 hours, and thereafter second cooled to a temperature of less than about 800° F.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: November 9, 2004
    Assignee: General Electric Company
    Inventor: Kazim Ozbaysal
  • Patent number: 6800153
    Abstract: The diamter of &bgr;-titanium alloy wire is reduced by cold wire-drawing and the &bgr;-titanium alloy wire is subjected to heat treatment. The heat treatment comprises the first aging process for precipitation strengthening and the second aging process for removing processing strain. &bgr;-titanium alloy wire is heat-treated under the supply of tension at the second aging process.
    Type: Grant
    Filed: April 11, 2002
    Date of Patent: October 5, 2004
    Assignees: Terumo Corporation, Tokusen Kogyo Co., Ltd.
    Inventors: Naoki Ishii, Takashi Kaneko, Shin Sumimoto, Hideki Yamamoto, Ichiro Nagao
  • Patent number: 6759134
    Abstract: A process for forming a metallic article having a black ornamental surface includes the steps of metallurgically providing an alloy containing between about 51 and 70 about percent by weight of titanium, between about 3 and about 17 percent by weight of niobium, and the balance of a metal selected from the group consisting of zirconium, tantalum, molybdenum, hafnium zirconium, chromium, and mixtures thereof. The alloy is then casted and/or metal worked into a workpiece having a desired geometry and surface texture. The workpiece thereof is then baked in a kiln or oven in a substantially air atmosphere of between about 450 and about 850 degrees C. for a period of between about one and about 29 minutes. Resultant of such baking, there is produced a durable black surface layer consisting substantially of an oxide of niobium which is adhered to the substrate of the workpiece which remains unoxidized.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: July 6, 2004
    Inventor: Edward Rosenberg
  • Publication number: 20040099356
    Abstract: An article is manufactured from a composition comprising about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % chromium, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition. An article is manufactured by a method comprising forming a shape from a composition comprising about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % chromium, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition; cold working the shape; and heat treating the shape.
    Type: Application
    Filed: June 27, 2003
    Publication date: May 27, 2004
    Inventor: Ming H. Wu
  • Publication number: 20040094248
    Abstract: The invention relates to a method for producing components with a high load capacity from &agr;+&ggr; TiAl alloys, especially for producing components for aircraft engines or stationary gas turbines. According to this method, enclosed TiAl blanks of globular structure are preformed by isothermal primary forming in the &agr;+&ggr;− or &agr; phase area. The preforms are then shaped out into components with a predeterminable contour by means of at least one isothermal secondary forming process, with dynamic recrystallization in the &agr;+&ggr;− or &agr; phase area. The microstructure is adjusted by solution annealing the components in the &agr; phase area and then cooling them off rapidly.
    Type: Application
    Filed: April 25, 2003
    Publication date: May 20, 2004
    Inventors: Peter Janschek, Lothar Knippschild, Karl Schreiber, Dan Roth-Fagaraseanu
  • Publication number: 20040089380
    Abstract: A method for fabricating an article of a titanium-base alloy, such as an alpha-beta titanium gas turbine fan or compressor disk, uses a starting ingot having a thickness of at least about 20 inches, and which is made of a titanium-base alloy having a temperature-composition phase diagram with a beta-phase field and an alpha-beta phase field. The method includes first forging the starting ingot in the beta-phase field to form an in-process billet, thereafter second forging the in-process billet in the alpha-beta phase field, thereafter heating the in-process billet into the beta-phase field to recrystallize the in-process billet, and thereafter third forging the in-process billet. The step of third forging includes forging the in-process billet from a first forging thickness of not less than about 15 inches to a second forging thickness of not more than about 13 inches, at a third-forging temperature of from about 1550° F. to about 1725° F.
    Type: Application
    Filed: November 12, 2002
    Publication date: May 13, 2004
    Inventor: Andrew Philip Woodfield
  • Publication number: 20040052676
    Abstract: A composition comprises about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition. A method for making an article comprises cold-working a shape from a composition comprising about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition; solution heat treating the shape; and cooling the shape.
    Type: Application
    Filed: June 27, 2003
    Publication date: March 18, 2004
    Inventor: Ming H. Wu
  • Publication number: 20040035509
    Abstract: An alpha-beta titanium alloy workpiece, preferably furnished in the form of a cast ingot, is processed by mechanically working in the beta phase field and in the alpha-beta phase field, and thereafter quenching from the beta phase field. The workpiece is thereafter mechanically worked at a first alpha-beta phase field temperature in the alpha-beta phase field and quenched from the first alpha-beta phase field temperature. The workpiece is thereafter mechanically worked at a second alpha-beta phase field temperature in the alpha-beta phase field, wherein the second alpha-beta phase field temperature is lower than the first alpha-beta phase field temperature, and optionally quenched from the second alpha-beta phase field temperature. The resulting microstructure is a distribution of globularized coarse alpha-phase particles and globularized fine alpha-phase particles in fine transformed beta grains.
    Type: Application
    Filed: August 26, 2002
    Publication date: February 26, 2004
    Inventor: Andrew Philip Woodfield
  • Publication number: 20030209298
    Abstract: The present invention provides non-axially symmetrical manufactured parts of thickness less than 10 mm, made of &bgr; or quasi-&bgr; titanium alloy, having a core microstructure constituted by whole grains presenting a slenderness ratio greater than 4 and an equivalent diameter lying in the range 10 &mgr;m to 300 &mgr;m. The invention also provides a method of manufacturing said parts by forging.
    Type: Application
    Filed: February 28, 2003
    Publication date: November 13, 2003
    Applicant: SNECMA MOTEURS
    Inventors: Blandine Barbier, Philippe Gallois, Claude Mons, Agathe Venard, Pascal Vignolles
  • Patent number: 6638381
    Abstract: A method for preparing ultra-fine grain titanium or titanium-alloy articles used for adjoining or assembling of detail components. Coarse-grained titanium or titanium-alloy materials typically are heated and forced under constant pressure through a friction stir processing tooling device containing a stirring chamber and a stirring rod. As the material is passed through the stirring chamber, the stirring rod solutionizes the titanium or titanium-alloy material and stirs the material to obtain a homogeneous or uniform material condition. As the processed material exits the stirring chamber of the friction stir process tooling device, it reconsolidates as an extremely homogeneous structure possessing ultra-fine grain structure. Titanium or titanium-alloy materials having been processed to achieve such ultra-fine grain material structure may then be manufactured into aerospace structural articles or components such as fasteners or articles that do not require a subsequent thermal or heat-treatment steps.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: October 28, 2003
    Assignee: The Boeing Company
    Inventors: Steven G. Keener, Edward Litwinski
  • Patent number: 6632304
    Abstract: A near-&bgr; or &bgr; titanium alloy having high strength, high ductility, and high toughness which is capable of coil rolling at a high temperature and recoiling for high productivity, and a process for producing said titanium alloy. The titanium alloy contains not more than 1.0% (excluding 0%) of Si alone or in combination with not more than 10% of Sn. The process comprises heating a &bgr; alloy or near-&bgr; alloy containing not more than 1.0% (excluding 0%) of Si alone or in combination with not more than 10% of Sn and subjecting said alloy to plastic deformation while keeping silicides solved in it at a temperature above the &bgr;-transus, so that silicides precipitate in the form of fine particles, with recrystallization suppressed. The resulting titanium alloy is good in workability and has high strength after aging treatment.
    Type: Grant
    Filed: July 5, 2001
    Date of Patent: October 14, 2003
    Assignee: Kabushiki Kaisha Kobe Seiko Sho
    Inventors: Hideto Oyama, Shinya Ishigai, Masamitsu Fujii, Tadasu Abumiya
  • Publication number: 20030188810
    Abstract: A super-elastic titanium alloy for medical use consisting essentially of:
    Type: Application
    Filed: March 25, 2003
    Publication date: October 9, 2003
    Inventors: Toyonobu Tanaka, Hiroshi Horikawa, Shuichi Miyazaki, Hideki Hosoda
  • Publication number: 20030168138
    Abstract: An embodiment of the present invention comprises processing a beta titanium alloy by a method including the steps of cold working the alloy and then direct aging the alloy for a total aging time of less than 4 hours. Any beta titanium alloy may be used in the method, for example, Ti-38-644 alloy. The method may include fabricating the alloy into an article of manufacture such as, for example, a bar, wire, a coil spring. The method may be utilized to produce articles with high tensile strength while retain ductility.
    Type: Application
    Filed: June 7, 2002
    Publication date: September 11, 2003
    Inventor: Brian J. Marquardt
  • Patent number: 6596099
    Abstract: A titanium article for an ultrasonic inspection is provided in which the titanium article can be ultrasonic inspected for determining its acceptability in for microstructurally sensitive applications. The ultrasonic inspection method comprises providing a titanium article, directing ultrasonic energy of ultrasonic inspection to the titanium article; scattering reflected energy in the titanium article; determining an amount of noise generated by the ultrasonic inspection of the titanium article; and characterizing the titanium article as acceptable if the amount of noise as a function of ultrasonic frequency or wavelength is characteristic of predominantly Rayleigh scattering and the magnitude of the noise is less than a pre-determined noise level. The titanium article comprises an uniform-fine grain microstructure. The uniform-fine grain microstructure generates predominantly Rayleigh scattering when undergoing ultrasonic inspection. The invention also sets forth a method of forming a titanium article.
    Type: Grant
    Filed: April 12, 2001
    Date of Patent: July 22, 2003
    Assignee: General Electric Company
    Inventors: Bernard Patrick Bewlay, John Broddus Deaton, Jr., Michael Francis Xavier Gigliotti, Jr., Robert Snee Gilmore
  • Publication number: 20030132108
    Abstract: A titanium material for a target has a microstructure in which the grain size is small and uniform and also has a macrostructure of the surface of the titanium material which is non-patterned and is excellent in surface property. A titanium ingot in which Vacuum Arc Remelting or Electron Beam Melting is performed is roughly forged at a temperature from 700° C. up to the &bgr; transformation temperature, and is then forged for finishing at room temperature to 350° C., and is finally annealed.
    Type: Application
    Filed: January 14, 2003
    Publication date: July 17, 2003
    Inventors: Shoichi Takahashi, Takao Iwabuchi, Kensuke Ushijima
  • Patent number: 6589371
    Abstract: A method of manufacturing titanium alloys in large-section semi-finished product form with controlled microstructure in micrograin and subcrystalline states of aggregation, with reduced metallographic texture, is achieved with the desired combination of mechanical properties in the titanium alloy product.
    Type: Grant
    Filed: April 23, 1999
    Date of Patent: July 8, 2003
    Assignees: General Electric Company, Institute of Metals Superplasticity Problems of the Russian Academy of Sciences
    Inventors: Oskar Akramovich Kaibyshev, Gennady Alekseevich Salischev, Rafael Manurovich Galeyev, Ramil Yavatovich Lutfullin, Oleg Rayazovich Valiakhmetov
  • Publication number: 20030111147
    Abstract: A method for preparing ultra-fine grain titanium or titanium-alloy articles used for adjoining or assembling of detail components. Coarse-grained titanium or titanium-alloy materials typically are heated and forced under constant pressure through a friction stir processing tooling device containing a stirring chamber and a stirring rod. As the material is passed through the stirring chamber, the stirring rod solutionizes the titanium or titanium-alloy material and stirs the material to obtain a homogeneous or uniform material condition. As the processed material exits the stirring chamber of the friction stir process tooling device, it reconsolidates as an extremely homogeneous structure possessing ultra-fine grain structure. Titanium or titanium-alloy materials having been processed to achieve such ultra-fine grain material structure may then be manufactured into aerospace structural articles or components such as fasteners or articles that do not require a subsequent thermal or heat-treatment steps.
    Type: Application
    Filed: December 18, 2001
    Publication date: June 19, 2003
    Inventors: Steven G. Keener, Edward Litwinski
  • Publication number: 20030102062
    Abstract: A titanium alloy member is characterized in that it comprises 40% by weight or more titanium (Ti), a IVa group element and/or a Va group element other than the titanium, wherein a summed amount including the IVa group element and/or the Va group element as well as the titanium is 90% by weight or more, and one or more members made in an amount of from 0.2 to 2.0% by weight and selected from an interstitial element group consisting of oxygen, nitrogen and carbon, and that its basic structure is a body-centered tetragonal crystal or a body-centered cubic crystal in which a ratio (c/a) of a distance between atoms on the c-axis with respect to a distance between atoms on the a-axis falls in a range of from 0.9 to 1.1.
    Type: Application
    Filed: January 2, 2002
    Publication date: June 5, 2003
    Inventors: Tadahiko Furuta, Yoshiki Seno, JungHwan Hwang, Kazuaki Nishino, Takashi Saito
  • Patent number: 6565683
    Abstract: The invention relates to plastic working of metals and alloys, predominantly low-plastic and hard-to-work ones, e.g., nickel-, titanium-, and iron-base high-temperature alloys, and producing billets for parts made by plastic working of said billets. The method comprises thermomechanical processing which is performed beginning with the temperature at which a total content of precipitates or an allotropic modification of the matrix exceeds 7%, followed by a stage-by-stage decrease of the working temperature down to the temperature at which a stable fine-grained microstructure of the material is obtained, with ratio between the grain size of various phases differing by not more than 10 times, the billet under processing undergoes deformation with a 1.2 to 3.9 times change in the billet cross-sectional area. When preparing billets from nickel-base alloys a stage-by-stage decrease of the working temperature is carried out so as to provide a maximum 14% gain in the &ggr;-phase at each stage.
    Type: Grant
    Filed: February 14, 2000
    Date of Patent: May 20, 2003
    Assignee: General Electric Company
    Inventors: Farid Zainullaevich Utyashev, Oscar Akramovich Kaibyshev, Vener Anvarovich Valitov
  • Patent number: 6536110
    Abstract: The present invention relates to a method for-fabricating an integrally bladed rotor which comprises providing a hub section, preferably formed from a titanium based alloy, and welding an airfoil, also preferably formed from a titanium based alloy, to the hub section. The method further comprises partially aging and cooling the hub section prior to welding and aging the airfoil and the weld joint between the airfoil and the hub section subsequent to welding. The post welding aging step is preferably carried out using a novel encapsulated local airfoil heating device having a plurality of heating elements woven into a jacket made from a high temperature cloth material. The method of the present invention may also be used to repair integrally bladed rotors.
    Type: Grant
    Filed: April 17, 2001
    Date of Patent: March 25, 2003
    Assignee: United Technologies Corporation
    Inventors: Michael P. Smith, Janet Stanley, David S. Murphy, Robert W. Baumgarten, Thomas DeMichael, Stephen L. Mayers
  • Publication number: 20020195176
    Abstract: The present invention relates to a method for fabricating an integrally bladed rotor which comprises providing a hub section, preferably formed from a titanium based alloy, and welding an airfoil, also preferably formed from a titanium based alloy, to the hub section. The method further comprises partially aging and cooling the hub section prior to welding and aging the airfoil and the weld joint between the airfoil and the hub section subsequent to welding. The post welding aging step is preferably carried out using a novel encapsulated local airfoil heating device having a plurality of heating elements woven into a jacket made from a high temperature cloth material. The method of the present invention may also be used to repair integrally bladed rotors.
    Type: Application
    Filed: August 23, 2002
    Publication date: December 26, 2002
    Inventors: Michael P. Smith, Janet M. Stanley, David S. Murphy, Robert W. Baumgarten, Thomas DeMichael, Stephen L. Mayers
  • Publication number: 20020174922
    Abstract: The diamter of &bgr;-titanium alloy wire is reduced by cold wire-drawing and the &bgr;-titanium alloy wire is subjected to heat treatment. The heat treatment comprises the first aging process for precipitation strengthening and the second aging process for removing processing strain. &bgr;-titanium alloy wire is heat-treated under the supply of tension at the second aging process.
    Type: Application
    Filed: April 11, 2002
    Publication date: November 28, 2002
    Applicant: Terumo Corporation
    Inventors: Naoki Ishii, Takashi Kaneko, Shin Sumimoto, Hideki Yamamoto, Ichiro Nagao
  • Publication number: 20020112796
    Abstract: A process for treating an alpha-beta titanium alloy to improve cryogenic notch tensile ratio comprises heating the alloy to near or above its beta transus temperature for a sufficient time to dissolve substantially all alpha grains and thus transform the alloy to the beta form, rapidly cooling the alloy from this temperature to induce a martensitic transformation and produce a fine platelet microstructure, isothermally forging the alloy about 50 to 80 percent at about 300° C. below the beta transus temperature to attain a fine equiaxed microstructure such that the largest microstructural unit is about 2-5 &mgr;m, and then aging the alloy at a temperature about 25° C. to 75° C. below the beta transus to grow the refined equiaxed microstructure such that the largest microstructural unit is about 5-10 &mgr;m.
    Type: Application
    Filed: January 16, 2001
    Publication date: August 22, 2002
    Applicant: The Boeing Company
    Inventor: Patrick Lyle Martin
  • Patent number: 6399215
    Abstract: We disclose ultrafine-grained titanium. A coarse-grained titanium billet is subjected to multiple extrusions through a preheated equal channel angular extrusion (ECAE) die, with billet rotation between subsequent extrusions. The resulting billet is cold processed by cold rolling and/or cold extrusion, with optional annealing. The resulting ultrafine-grained titanium has greatly improved mechanical properties and is used to make medical implants.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: June 4, 2002
    Assignee: The Regents of the University of California
    Inventors: Yuntian T. Zhu, Terry C. Lowe, Ruslan Z. Valiev, Vladimir V. Stolyarov, Vladimir V. Latysh, Georgy J. Raab
  • Patent number: 6391128
    Abstract: The present invention provides a rolling bearing having an excellent corrosion resistance and toughness which can fairly operate at a high rotary speed. At least the inner race is formed by a titanium alloy, and the rolling elements are formed by ceramics. Alternatively, at least one of the inner race and the outer race is formed by a &bgr; type titanium alloy. The percent cold working of the &bgr; type titanium alloy is predetermined to not less than 20% or a range of from 5 to 20%. The cold working is followed by shot peening. Further, the surface hardness Hv is predetermined to not less than 600. The volumetric ratio of residual &bgr; phase in the &bgr; type titanium alloy is predetermined to a range of from 30 to 80%.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: May 21, 2002
    Assignee: NSK Ltd.
    Inventors: Kouji Ueda, Manabu Ohori
  • Patent number: 6387197
    Abstract: A method is set forth for processing titanium and titanium alloys into titanium articles, in which the titanium exhibits enhanced ultrasonic inspection results for determining its acceptability in microstructurally sensitive titanium applications. The method for processing titanium comprises providing titanium at a temperature above its &bgr;-transus temperature; quenching the titanium from a temperature above the &bgr;-transus temperature, the step of quenching titanium forming an &agr;-plate microstructure in the titanium; and deforming the quenched titanium into a titanium article, the step of deforming the quenched titanium transforming the &agr;-plate microstructure into discontinuous &agr; particles without crystallization textures. The discontinuous-randomly textured &agr; particles lead to a reduction in ultrasonic noise during ultrasonic inspection.
    Type: Grant
    Filed: January 11, 2000
    Date of Patent: May 14, 2002
    Assignees: General Electric Company, Ladish Company, Inc.
    Inventors: Bernard Patrick Bewlay, Michael Francis Xavier Gigliotti, Jr., David Ulrich Furrer, Gangshu Shen, Jacek Marian Franczak
  • Patent number: 6372063
    Abstract: The process for manufacturing a metallic component, such as a wheel part for the rolling system of a vehicle, which includes, in an initial stage, forming the component of a metallic material in a semi-solid state and having a thixotropic structure, and in a subsequent cold-treatment stage, cold-treating at least part of said component by blasting it with projectiles with a view to plastic deformation thereof. A wheel in which a metallic disk is welded to a wheel rim and in which the metallic disk is obtained by the manufacturing process.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: April 16, 2002
    Assignee: Michelin Recherche et Technique, S.A.
    Inventor: Gilles Grillon
  • Publication number: 20020020476
    Abstract: A method of carburizing treatment is proposed in which if carburizing is carried out at a low temperature, carbon will not turn amorphose and deposit on the surface of a titanium metal but reliably penetrate into between metallic atoms. It is a method of surface treatment of a titanium metal comprising the steps of heating the titanium metal to a temperature of 400-690° C. in a cleaning gas atmosphere containing hydrogen gas, subjecting the surface of the titanium metal to cleaning by applying a DC voltage of 200-1500 V, and plasma carburizing in an atmosphere comprising a carburizing gas having the molar ratio of hydrogen atoms (H) to carbon atoms (C) adjusted to (H/C)≦9 at a pressure of 13-400 Pa and a temperature of 400-690° C. Ionization reaction in the gas is suppressed suitably. Because there exists no excessive carbon which is not used for carburization but turns soot or glass-like carbon, in the atmosphere during carburization, carburizing reaction progresses smoothly.
    Type: Application
    Filed: July 11, 2001
    Publication date: February 21, 2002
    Inventors: Eiichi Ishii, Takumi Sone, Yukihiro Sato, Kei Demizu, Hideo Kakutani, Koichi Tanaka, Shinichi Tanaka, Noriyoshi Tsuji
  • Patent number: 6332935
    Abstract: A starting workpiece of a titanium-base alloy having a temperature-composition phase diagram with a beta region and an alpha-beta region separated by a beta transus temperature is processed by first forging the starting workpiece at a first temperature in the beta region to form a billet, thereafter second forging the billet at a second temperature in the alpha-beta region, thereafter third forging the billet at a third temperature in the beta region, thereafter fourth forging the billet at a fourth temperature in the alpha-beta region so that the step of fourth forging accomplishes a reduction in cross-sectional area of from about 5 to about 40 percent, and thereafter ultrasonic testing the billet. The beta-region third forging step combined with a relatively small reduction during the alpha-beta-region fourth forging step produce a microstructure that is conducive to ultrasonic inspection with minimal interference from noise.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: December 25, 2001
    Assignee: General Electric Company
    Inventors: Mark D. Gorman, Andrew P. Woodfield
  • Patent number: H2227
    Abstract: A high speed titanium alloy microstructural conversion method from lamellar to equiaxed is disclosed. The method includes identification and estimation of process parameters such that the average strain rate is between about 1-100 s?1 and the deformation temperature of the material is in the range of about 975°-1010° C.
    Type: Grant
    Filed: November 13, 2002
    Date of Patent: December 2, 2008
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Seshacharyulu Tamirisakandala, Prasad VRK Yellapregada, Steven C. Medeiros, William G. Frazier, James C. Malas