With Ageing, Solution Treating (i.e., For Hardening), Precipitation Hardening Or Strengthening Patents (Class 148/671)
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Publication number: 20090056841Abstract: A process for making parts from titanium or a titanium alloy is disclosed. The process includes the step of preparing an intermediate form of titanium or a titanium alloy. The intermediate form is then solution heat treated under conditions of temperature and time that are selected to produce a desired level of strength when the titanium or titanium alloy part is subsequently age hardened. The solution treated intermediate form is then thermomechanically formed into a desired part or a preform for a desired part. The as-formed part or preform is then age-hardened under conditions of temperature and time that are selected to produce the desired level of strength in the finished part. The age-hardening step is performed without solution heat treating the as-formed part or preform again.Type: ApplicationFiled: August 30, 2007Publication date: March 5, 2009Inventor: Buford R. Riffee, JR.
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Publication number: 20090032152Abstract: A titanium-alloy article is produced by providing a workpiece of an alpha-beta titanium alloy having a beta-transus temperature, and thereafter mechanically working the workpiece at a mechanical-working temperature above the beta-transus temperature. The mechanically worked workpiece is solution heat treated at a solution-heat-treatment temperature of from about 175° F. below the beta-transus temperature to about 25° F. below the beta-transus temperature, quenched, overage heat treated at an overage-heat-treatment temperature of from about 400° F. below the beta-transus temperature to about 275° F. below the beta-transus temperature, and cooled from the overage-heat-treatment temperature.Type: ApplicationFiled: October 10, 2008Publication date: February 5, 2009Applicant: GENERAL ELECTRIC COMPANYInventors: Andrew Philip WOODFIELD, Wesley Douglas PRIDEMORE, Bernard Harold LAWLESS, Nancy Ann SULLIVAN, Peter WAYTE, Michael James WEIMER, Thomas Froats BRODERICK
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Patent number: 7481898Abstract: A Ti-6Al-4V-0.2O (Ti64) forged article is fabricated by forging a workpiece to make a forged gas turbine engine component having a thick portion thereof with a section thickness greater than 2¼ inches. The forged article is heat treated by solution heat treating at a temperature of from about 50° F. to about 75° F. below the beta-transus temperature of the alloy, thereafter water quenching the gas turbine engine component to room temperature, and thereafter aging the gas turbine engine component at a temperature of from about 900° F. to about 1000° F. The resulting machined gas turbine engine component has a 0.2 percent yield strength of from about 120 ksi to about 140 ksi at its centerline, and a 0.2 percent yield strength of from about 160 ksi to about 175 ksi at a location about ½ inch below a surface thereof.Type: GrantFiled: October 24, 2003Date of Patent: January 27, 2009Assignee: General Electric CompanyInventors: Peter Wayte, Ming Cheng Li
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Patent number: 7479194Abstract: A damage tolerant microstructure for a lamellar alloy, such as a lamellar ?TiAl alloy, is provided in accordance with the present invention. The alloy comprises a matrix and a plurality of grains or lamellar colonies, a portion of which exhibit a nonplanar morphology within said matrix. Each of the lamellar colonies contains a multitude of lamella with irregularly repeating order. The ?TiAl platelets have a triangular (octahedral) unit cell and stack with ? twins. The ?2Ti3Al platelets are irregularly interspersed. The unit cell for ?2Ti3Al is hexagonal. Each of the layers has a curved, nonplanar structure for resisting crack formation and growth.Type: GrantFiled: August 8, 2005Date of Patent: January 20, 2009Assignee: United Technologies CorporationInventor: Daniel P. DeLuca
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Publication number: 20080283162Abstract: A method for manufacturing a high-strength titanium alloy golf club head part includes making at least one golf club head part with a titanium alloy. The golf club head part is then heated to a temperature higher than a critical temperature of generating martensite and maintained above the critical temperature not more than thirty minutes. The golf club head part is then cooled to a temperature below the critical temperature at a cooling rate higher than 10° C./s. Next, the golf club head part is heated to a heat-treatment temperature higher than 450° C. and maintained at the heat-treatment temperature at least one hour. The golf club head part is then cooled to room temperature. The mechanical characteristics of a golf club head formed by the golf club head part are enhanced.Type: ApplicationFiled: April 9, 2008Publication date: November 20, 2008Inventor: Ming-Jui Chiang
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Patent number: 7449075Abstract: A titanium-alloy article is produced by providing a workpiece of an alpha-beta titanium alloy having a beta-transus temperature, and thereafter mechanically working the workpiece at a mechanical-working temperature above the beta-transus temperature. The mechanically worked workpiece is solution heat treated at a solution-heat-treatment temperature of from about 175° F. below the beta-transus temperature to about 25° F. below the beta-transus temperature, quenched, overage heat treated at an overage-heat-treatment temperature of from about 400° F. below the beta-transus temperature to about 275° F. below the beta-transus temperature, and cooled from the overage-heat-treatment temperature.Type: GrantFiled: June 28, 2004Date of Patent: November 11, 2008Assignee: General Electric CompanyInventors: Andrew Philip Woodfield, Wesley Douglas Pridemore, Bernard Harold Lawless, Nancy Ann Sullivan, Peter Wayte, Michael James Weimer, Thomas Froats Broderick
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Patent number: 7261782Abstract: A titanium alloy obtained by a cold-working step, in which 10% or more of cold working is applied to a raw titanium alloy, comprising a Va group element and the balance of titanium substantially, and an aging treatment step, in which a cold-worked member, obtained after the cold-working step, is subjected to an aging treatment so that the parameter “P” falls in a range of from 8.0 to 18.5 at a treatment temperature falling in a range of from 150° C. to 600° C.; and characterized in that its tensile elastic limit strength is 950 MPa or more and its elastic deformation capability is 1.6% or more. This titanium alloy is of high elastic deformation capability as well as high tensile elastic limit strength, and can be utilized in a variety of products extensively.Type: GrantFiled: December 5, 2001Date of Patent: August 28, 2007Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: JungHwan Hwang, Tadahiko Furuta, Kazuaki Nishino, Takashi Saito
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Patent number: 7132021Abstract: A process for making a work piece from a ?-type titanium alloy material includes subjecting the ?-type titanium alloy material to cold working with controlling the reduction rate thereof to vary the reduction rate depending on a position across a plain direction of the ?-type titanium alloy material, and then subjecting the ?-type titanium alloy material to an aging treatment.Type: GrantFiled: June 4, 2004Date of Patent: November 7, 2006Assignee: Sumitomo Metal Industries, Ltd.Inventors: Kouichi Kuroda, Satoshi Matsumoto, Keisuke Nagashima, Nozomu Ariyasu
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Patent number: 7115177Abstract: In a method for the treatment of metallic materials especially for the consolidation of the texture of the materials, a blank of the metallic material is heated to a transformation temperature and the blank is then subjected to twisting preferably while, at the same time, being compressed. In this way, the texture can be refined to a large degree in a simple and inexpensive manner.Type: GrantFiled: December 11, 2001Date of Patent: October 3, 2006Assignee: Gkss-Forschungszentrum Geesthacht GmbHInventors: Fritz Appel, Stephen Eggert, Uwe Lorenz, Michael Oehring
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Patent number: 7083687Abstract: A super-elastic titanium alloy for medical use consisting essentially of: molybdenum (Mo) as a ? stabilizer element of titanium (Ti): from 2 to 12 at %; an ? stabilizer element of the titanium (Ti): from 0.1 to 14 at %; and the balance being titanium (Ti) and inevitable impurities. The ? stabilizer element is at least one element selected from the group consisting of aluminum (Al), gallium (Ga) and germanium (Ge).Type: GrantFiled: March 21, 2005Date of Patent: August 1, 2006Assignee: Furukawa Techno Material Co., Ltd.Inventors: Toyonobu Tanaka, Hiroshi Horikawa, Shuichi Miyazaki, Hideki Hosoda
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Patent number: 7008491Abstract: A method for fabricating an article of a titanium-base alloy, such as an alpha-beta titanium gas turbine fan or compressor disk, uses a starting ingot having a thickness of at least about 20 inches, and which is made of a titanium-base alloy having a temperature-composition phase diagram with a beta-phase field and an alpha-beta phase field. The method includes first forging the starting ingot in the beta-phase field to form an in-process billet, thereafter second forging the in-process billet in the alpha-beta phase field, thereafter heating the in-process billet into the beta-phase field to recrystallize the in-process billet, and thereafter third forging the in-process billet. The step of third forging includes forging the in-process billet from a first forging thickness of not less than about 15 inches to a second forging thickness of not more than about 13 inches, at a third-forging temperature of from about 1550° F. to about 1725° F.Type: GrantFiled: November 12, 2002Date of Patent: March 7, 2006Assignee: General Electric CompanyInventor: Andrew Philip Woodfield
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Patent number: 6997995Abstract: The invention relates to a method for producing components with a high load capacity from ?+? TiAl alloys, especially for producing components for aircraft engines or stationary gas turbines. According to this method, enclosed TiAl blanks of globular structure are preformed by isothermal primary forming in the ?+?? or ? phase area. The preforms are then shaped out into components with a predeterminable contour by means of at least one isothermal secondary forming process, with dynamic recrystallization in the ?+?? or ? phase area. The microstructure is adjusted by solution annealing the components in the ? phase area and then cooling them off rapidly.Type: GrantFiled: November 16, 2001Date of Patent: February 14, 2006Assignees: Leistrits Turbinenkomponenten Remscheid GmbH, Rolls-Royce Deutschland LTD & Co KGInventors: Peter Janschek, Lothar Knippschild, Karl Schreiber, Dan Roth-Fagaraseanu
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Patent number: 6979375Abstract: A titanium alloy member is characterized in that it comprise 40% by weight or more titanium (Ti), a IVa group element and/or a Va group element other than the titanium, wherein a summed amount including the IVa group element and/or the Va group element as well as the titanium is 90% by weight or more, and one or more members made in an amount of from 0.2 to 2.0% by weight and selected from an interstitial element group consisting of oxygen, nitrogen and carbon, and that its basic structure is a body-centered tetragonal crystal or a body-centered cubic crystal in which a ratio (c/a) of a distance between atoms on the c-axis with respect to a distance between atoms on the a-axis falls in a range of from 0.9 to 1.1. This titanium alloy member has such working properties that conventional titanium alloys do not have, is flexible, exhibits a high strength, and can be utilized in a variety of products.Type: GrantFiled: May 1, 2001Date of Patent: December 27, 2005Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Tadahiko Furuta, Yoshiki Seno, JungHwan Hwang, Kazuaki Nishino, Takashi Saito
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Patent number: 6974507Abstract: A damage tolerant microstructure for a lamellar alloy, such as a lamellar ?TiAl alloy, is provided in accordance with the present invention. The alloy comprises a matrix and a plurality of grains or lamellar colonies, a portion of which exhibit a nonplanar morphology within said matrix. Each of the lamellar colonies contains a multitude of lamella with irregularly repeating order. The ?TiAl platelets have a triangular (octahedral) unit cell and stack with ? twins. The ?2Ti3Al platelets are irregularly interspersed. The unit cell for ?2Ti3Al is hexagonal. Each of the layers has a curved, nonplanar structure for resisting crack formation and growth.Type: GrantFiled: March 3, 2003Date of Patent: December 13, 2005Assignee: United Technologies CorporationInventor: Daniel P. DeLuca
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Patent number: 6939419Abstract: The invention relates to plastic metal working, more specifically to methods for producing parts of the disk- or shell-type having conical, hemispherical, and also combined parts, such as disk-and-shaft ones. The invention is instrumental in producing large axially symmetric parts from hard-to-work multiphase alloys. The method consists in that the billet is heated in a temperature range above 0.4 m.p. but below the temperature at which a total content of precipitates or an allotropic modification of the matrix of a multiphase alloy is not below 7%. Then the preheated billet is rolled, while controlling its temperature and the tool load, as well as the rolling speed. Once rolled the billet is heat-treated at a temperature depending on the microstructure of the billet material resulting from rolling. Prerolling preparing of a specified microstructure of the billet material is also described.Type: GrantFiled: June 19, 1997Date of Patent: September 6, 2005Assignees: General Electric Company, Institute of Metals Superplascity Problems of Academy of ScienceInventors: Farid Zainullaevich Utyashev, Oscar Akramovich Kaibyshev, Vener Anvarovich Valitov
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Patent number: 6923934Abstract: TiAl alloy includes 46 to 50 at % of Al, 5 at % or less of combination of Mo, V and Si, provided that Si content is 0.7 at % or less, and Mo content satisfies an equation of ?0.3x +17.5 at % or less where x represents Al (at %), and the remainder being Ti and inevitable impurities. Mo may be replaced by Fe or combination of Mo and Fe. TiAl alloy is heated to a melt, poured into a mold, and cooled at a rate of 150 to 250° C./min within a temperature range of 1500 to 1100° C. The resulting product can be used as cast. If desired, however, heat treatment such as HIP or homogenization may be performed within a temperature range of 1100 to 800° C. After the heat treatment, the melt is cooled at a rate of 100° C./min or more until room temperature.Type: GrantFiled: August 6, 2002Date of Patent: August 2, 2005Assignee: Ishikawajima-Harima Heavy Industries Co., Ltd.Inventor: Sadao Nishikiori
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Patent number: 6918972Abstract: A Ni-base alloy which has excellent resistance to permanent set at high temperature and which can be produced at low cost, a heat-resistant spring made of the Ni-base alloy, and a process for producing the spring. The Ni-base alloy of the present invention consists of 0.01 to 0.15 mass % of C, 2.0 mass % or less of Si, 2.5 mass % or less of Mn, 12 to 25 mass % of Cr, 5.0 mass % or less of Mo and/or 5.0 mass % or less of W on condition that Mo+W/2 does not exceed 5.0 mass % or less, 1.5 to 3.5 mass % of Ti, 0.7 to 2.5 mass % of Al, 20 mass % or less of Fe, and the balance of Ni and unavoidable impurities. The ratio of Ti/Al in terms of atomic percentage ranges from 0.6 to 1.5 and the total content of Ti and Al ranges from 4.0 to 8.5 atomic %.Type: GrantFiled: February 20, 2003Date of Patent: July 19, 2005Assignee: Daido Tokushuko Kabushiki KaishaInventors: Shigeki Ueta, Toshiharu Noda
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Patent number: 6918974Abstract: An alpha-beta titanium alloy workpiece, preferably furnished in the form of a cast ingot, is processed by mechanically working in the beta phase field and in the alpha-beta phase field, and thereafter quenching from the beta phase field. The workpiece is thereafter mechanically worked at a first alpha-beta phase field temperature in the alpha-beta phase field and quenched from the first alpha-beta phase field temperature. The workpiece is thereafter mechanically worked at a second alpha-beta phase field temperature in the alpha-beta phase field, wherein the second alpha-beta phase field temperature is lower than the first alpha-beta phase field temperature, and optionally quenched from the second alpha-beta phase field temperature. The resulting microstructure is a distribution of globularized coarse alpha-phase particles and globularized fine alpha-phase particles in fine transformed beta grains.Type: GrantFiled: August 26, 2002Date of Patent: July 19, 2005Assignee: General Electric CompanyInventor: Andrew Philip Woodfield
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Patent number: 6855215Abstract: Tableware of Ti or a Ti alloy having a surface hardened layer comprising a first hardened layer in which nitrogen and oxygen are diffused so as to form a solid solution and a second hardened layer which is formed in a region deeper than the first hardened layer. The substrate may have a hard decorative coating film. A substrate comprising Ti or a Ti alloy has on its surface an internal hardened layer comprising a first hardened layer and a second hardened layer, wherein the hard decorative coating film is formed on the surface of the internal hardened layer. The cutlery comprises a working part and a grip, the grip provided with a floating means such as a hollow part. Titanium tableware having excellent long-term mar resistance and high quality appearance, increasing the decorative value of the tableware. Further, a process for surface treatment to obtain the titanium tableware with high productivity and a substrate having a hard decorative coating film with excellent mar resistance and high surface hardness.Type: GrantFiled: July 3, 2001Date of Patent: February 15, 2005Assignee: Citizen Watch Co., Ltd.Inventors: Hachirou Kushida, Yutaka Fukumura, Yukio Miya
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Publication number: 20040241037Abstract: A composition comprises about 8 to about 12 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition. A method for making an article comprises cold-working a shape from a composition comprising about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition; solution heat treating the shape; and cooling the shape.Type: ApplicationFiled: June 16, 2004Publication date: December 2, 2004Inventor: Ming H. Wu
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Patent number: 6814820Abstract: An article is formed of an alpha-beta titanium-base alloy, preferably an alloy having more than about 3.5 weight percent molybdenum. An example of such an article is a gas turbine compressor blade having a nominal composition, in weight percent, of about 4 percent aluminum, about 4 percent molybdenum, about 2 percent tin, about 0.5 percent silicon, balance titanium and impurities. The article is processed to form a martensitic structure therein. The processing, which typically involves forging or weld repairing, includes the steps of first heating the article to a first-heating temperature of greater than about 1600° F., and thereafter first cooling the article to a temperature of less than about 800° F. The article is thereafter second heated to a second-heating temperature of from about 1275° F. to about 1375° F. for a time of from about 1 to about 7 hours, and thereafter second cooled to a temperature of less than about 800° F.Type: GrantFiled: July 6, 2001Date of Patent: November 9, 2004Assignee: General Electric CompanyInventor: Kazim Ozbaysal
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Patent number: 6800153Abstract: The diamter of &bgr;-titanium alloy wire is reduced by cold wire-drawing and the &bgr;-titanium alloy wire is subjected to heat treatment. The heat treatment comprises the first aging process for precipitation strengthening and the second aging process for removing processing strain. &bgr;-titanium alloy wire is heat-treated under the supply of tension at the second aging process.Type: GrantFiled: April 11, 2002Date of Patent: October 5, 2004Assignees: Terumo Corporation, Tokusen Kogyo Co., Ltd.Inventors: Naoki Ishii, Takashi Kaneko, Shin Sumimoto, Hideki Yamamoto, Ichiro Nagao
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Patent number: 6759134Abstract: A process for forming a metallic article having a black ornamental surface includes the steps of metallurgically providing an alloy containing between about 51 and 70 about percent by weight of titanium, between about 3 and about 17 percent by weight of niobium, and the balance of a metal selected from the group consisting of zirconium, tantalum, molybdenum, hafnium zirconium, chromium, and mixtures thereof. The alloy is then casted and/or metal worked into a workpiece having a desired geometry and surface texture. The workpiece thereof is then baked in a kiln or oven in a substantially air atmosphere of between about 450 and about 850 degrees C. for a period of between about one and about 29 minutes. Resultant of such baking, there is produced a durable black surface layer consisting substantially of an oxide of niobium which is adhered to the substrate of the workpiece which remains unoxidized.Type: GrantFiled: April 30, 2002Date of Patent: July 6, 2004Inventor: Edward Rosenberg
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Publication number: 20040099356Abstract: An article is manufactured from a composition comprising about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % chromium, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition. An article is manufactured by a method comprising forming a shape from a composition comprising about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % chromium, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition; cold working the shape; and heat treating the shape.Type: ApplicationFiled: June 27, 2003Publication date: May 27, 2004Inventor: Ming H. Wu
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Publication number: 20040094248Abstract: The invention relates to a method for producing components with a high load capacity from &agr;+&ggr; TiAl alloys, especially for producing components for aircraft engines or stationary gas turbines. According to this method, enclosed TiAl blanks of globular structure are preformed by isothermal primary forming in the &agr;+&ggr;− or &agr; phase area. The preforms are then shaped out into components with a predeterminable contour by means of at least one isothermal secondary forming process, with dynamic recrystallization in the &agr;+&ggr;− or &agr; phase area. The microstructure is adjusted by solution annealing the components in the &agr; phase area and then cooling them off rapidly.Type: ApplicationFiled: April 25, 2003Publication date: May 20, 2004Inventors: Peter Janschek, Lothar Knippschild, Karl Schreiber, Dan Roth-Fagaraseanu
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Publication number: 20040089380Abstract: A method for fabricating an article of a titanium-base alloy, such as an alpha-beta titanium gas turbine fan or compressor disk, uses a starting ingot having a thickness of at least about 20 inches, and which is made of a titanium-base alloy having a temperature-composition phase diagram with a beta-phase field and an alpha-beta phase field. The method includes first forging the starting ingot in the beta-phase field to form an in-process billet, thereafter second forging the in-process billet in the alpha-beta phase field, thereafter heating the in-process billet into the beta-phase field to recrystallize the in-process billet, and thereafter third forging the in-process billet. The step of third forging includes forging the in-process billet from a first forging thickness of not less than about 15 inches to a second forging thickness of not more than about 13 inches, at a third-forging temperature of from about 1550° F. to about 1725° F.Type: ApplicationFiled: November 12, 2002Publication date: May 13, 2004Inventor: Andrew Philip Woodfield
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Publication number: 20040052676Abstract: A composition comprises about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition. A method for making an article comprises cold-working a shape from a composition comprising about 8 to about 10 wt % molybdenum, about 2.8 to about 6 wt % aluminum, up to about 2 wt % vanadium, up to about 4 wt % niobium, with the balance being titanium, wherein the weight percents are based on the total weight of the alloy composition; solution heat treating the shape; and cooling the shape.Type: ApplicationFiled: June 27, 2003Publication date: March 18, 2004Inventor: Ming H. Wu
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Publication number: 20040035509Abstract: An alpha-beta titanium alloy workpiece, preferably furnished in the form of a cast ingot, is processed by mechanically working in the beta phase field and in the alpha-beta phase field, and thereafter quenching from the beta phase field. The workpiece is thereafter mechanically worked at a first alpha-beta phase field temperature in the alpha-beta phase field and quenched from the first alpha-beta phase field temperature. The workpiece is thereafter mechanically worked at a second alpha-beta phase field temperature in the alpha-beta phase field, wherein the second alpha-beta phase field temperature is lower than the first alpha-beta phase field temperature, and optionally quenched from the second alpha-beta phase field temperature. The resulting microstructure is a distribution of globularized coarse alpha-phase particles and globularized fine alpha-phase particles in fine transformed beta grains.Type: ApplicationFiled: August 26, 2002Publication date: February 26, 2004Inventor: Andrew Philip Woodfield
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Publication number: 20030209298Abstract: The present invention provides non-axially symmetrical manufactured parts of thickness less than 10 mm, made of &bgr; or quasi-&bgr; titanium alloy, having a core microstructure constituted by whole grains presenting a slenderness ratio greater than 4 and an equivalent diameter lying in the range 10 &mgr;m to 300 &mgr;m. The invention also provides a method of manufacturing said parts by forging.Type: ApplicationFiled: February 28, 2003Publication date: November 13, 2003Applicant: SNECMA MOTEURSInventors: Blandine Barbier, Philippe Gallois, Claude Mons, Agathe Venard, Pascal Vignolles
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Patent number: 6638381Abstract: A method for preparing ultra-fine grain titanium or titanium-alloy articles used for adjoining or assembling of detail components. Coarse-grained titanium or titanium-alloy materials typically are heated and forced under constant pressure through a friction stir processing tooling device containing a stirring chamber and a stirring rod. As the material is passed through the stirring chamber, the stirring rod solutionizes the titanium or titanium-alloy material and stirs the material to obtain a homogeneous or uniform material condition. As the processed material exits the stirring chamber of the friction stir process tooling device, it reconsolidates as an extremely homogeneous structure possessing ultra-fine grain structure. Titanium or titanium-alloy materials having been processed to achieve such ultra-fine grain material structure may then be manufactured into aerospace structural articles or components such as fasteners or articles that do not require a subsequent thermal or heat-treatment steps.Type: GrantFiled: December 18, 2001Date of Patent: October 28, 2003Assignee: The Boeing CompanyInventors: Steven G. Keener, Edward Litwinski
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Patent number: 6632304Abstract: A near-&bgr; or &bgr; titanium alloy having high strength, high ductility, and high toughness which is capable of coil rolling at a high temperature and recoiling for high productivity, and a process for producing said titanium alloy. The titanium alloy contains not more than 1.0% (excluding 0%) of Si alone or in combination with not more than 10% of Sn. The process comprises heating a &bgr; alloy or near-&bgr; alloy containing not more than 1.0% (excluding 0%) of Si alone or in combination with not more than 10% of Sn and subjecting said alloy to plastic deformation while keeping silicides solved in it at a temperature above the &bgr;-transus, so that silicides precipitate in the form of fine particles, with recrystallization suppressed. The resulting titanium alloy is good in workability and has high strength after aging treatment.Type: GrantFiled: July 5, 2001Date of Patent: October 14, 2003Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Hideto Oyama, Shinya Ishigai, Masamitsu Fujii, Tadasu Abumiya
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Publication number: 20030188810Abstract: A super-elastic titanium alloy for medical use consisting essentially of:Type: ApplicationFiled: March 25, 2003Publication date: October 9, 2003Inventors: Toyonobu Tanaka, Hiroshi Horikawa, Shuichi Miyazaki, Hideki Hosoda
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Publication number: 20030168138Abstract: An embodiment of the present invention comprises processing a beta titanium alloy by a method including the steps of cold working the alloy and then direct aging the alloy for a total aging time of less than 4 hours. Any beta titanium alloy may be used in the method, for example, Ti-38-644 alloy. The method may include fabricating the alloy into an article of manufacture such as, for example, a bar, wire, a coil spring. The method may be utilized to produce articles with high tensile strength while retain ductility.Type: ApplicationFiled: June 7, 2002Publication date: September 11, 2003Inventor: Brian J. Marquardt
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Patent number: 6596099Abstract: A titanium article for an ultrasonic inspection is provided in which the titanium article can be ultrasonic inspected for determining its acceptability in for microstructurally sensitive applications. The ultrasonic inspection method comprises providing a titanium article, directing ultrasonic energy of ultrasonic inspection to the titanium article; scattering reflected energy in the titanium article; determining an amount of noise generated by the ultrasonic inspection of the titanium article; and characterizing the titanium article as acceptable if the amount of noise as a function of ultrasonic frequency or wavelength is characteristic of predominantly Rayleigh scattering and the magnitude of the noise is less than a pre-determined noise level. The titanium article comprises an uniform-fine grain microstructure. The uniform-fine grain microstructure generates predominantly Rayleigh scattering when undergoing ultrasonic inspection. The invention also sets forth a method of forming a titanium article.Type: GrantFiled: April 12, 2001Date of Patent: July 22, 2003Assignee: General Electric CompanyInventors: Bernard Patrick Bewlay, John Broddus Deaton, Jr., Michael Francis Xavier Gigliotti, Jr., Robert Snee Gilmore
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Publication number: 20030132108Abstract: A titanium material for a target has a microstructure in which the grain size is small and uniform and also has a macrostructure of the surface of the titanium material which is non-patterned and is excellent in surface property. A titanium ingot in which Vacuum Arc Remelting or Electron Beam Melting is performed is roughly forged at a temperature from 700° C. up to the &bgr; transformation temperature, and is then forged for finishing at room temperature to 350° C., and is finally annealed.Type: ApplicationFiled: January 14, 2003Publication date: July 17, 2003Inventors: Shoichi Takahashi, Takao Iwabuchi, Kensuke Ushijima
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Patent number: 6589371Abstract: A method of manufacturing titanium alloys in large-section semi-finished product form with controlled microstructure in micrograin and subcrystalline states of aggregation, with reduced metallographic texture, is achieved with the desired combination of mechanical properties in the titanium alloy product.Type: GrantFiled: April 23, 1999Date of Patent: July 8, 2003Assignees: General Electric Company, Institute of Metals Superplasticity Problems of the Russian Academy of SciencesInventors: Oskar Akramovich Kaibyshev, Gennady Alekseevich Salischev, Rafael Manurovich Galeyev, Ramil Yavatovich Lutfullin, Oleg Rayazovich Valiakhmetov
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Publication number: 20030111147Abstract: A method for preparing ultra-fine grain titanium or titanium-alloy articles used for adjoining or assembling of detail components. Coarse-grained titanium or titanium-alloy materials typically are heated and forced under constant pressure through a friction stir processing tooling device containing a stirring chamber and a stirring rod. As the material is passed through the stirring chamber, the stirring rod solutionizes the titanium or titanium-alloy material and stirs the material to obtain a homogeneous or uniform material condition. As the processed material exits the stirring chamber of the friction stir process tooling device, it reconsolidates as an extremely homogeneous structure possessing ultra-fine grain structure. Titanium or titanium-alloy materials having been processed to achieve such ultra-fine grain material structure may then be manufactured into aerospace structural articles or components such as fasteners or articles that do not require a subsequent thermal or heat-treatment steps.Type: ApplicationFiled: December 18, 2001Publication date: June 19, 2003Inventors: Steven G. Keener, Edward Litwinski
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Publication number: 20030102062Abstract: A titanium alloy member is characterized in that it comprises 40% by weight or more titanium (Ti), a IVa group element and/or a Va group element other than the titanium, wherein a summed amount including the IVa group element and/or the Va group element as well as the titanium is 90% by weight or more, and one or more members made in an amount of from 0.2 to 2.0% by weight and selected from an interstitial element group consisting of oxygen, nitrogen and carbon, and that its basic structure is a body-centered tetragonal crystal or a body-centered cubic crystal in which a ratio (c/a) of a distance between atoms on the c-axis with respect to a distance between atoms on the a-axis falls in a range of from 0.9 to 1.1.Type: ApplicationFiled: January 2, 2002Publication date: June 5, 2003Inventors: Tadahiko Furuta, Yoshiki Seno, JungHwan Hwang, Kazuaki Nishino, Takashi Saito
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Patent number: 6565683Abstract: The invention relates to plastic working of metals and alloys, predominantly low-plastic and hard-to-work ones, e.g., nickel-, titanium-, and iron-base high-temperature alloys, and producing billets for parts made by plastic working of said billets. The method comprises thermomechanical processing which is performed beginning with the temperature at which a total content of precipitates or an allotropic modification of the matrix exceeds 7%, followed by a stage-by-stage decrease of the working temperature down to the temperature at which a stable fine-grained microstructure of the material is obtained, with ratio between the grain size of various phases differing by not more than 10 times, the billet under processing undergoes deformation with a 1.2 to 3.9 times change in the billet cross-sectional area. When preparing billets from nickel-base alloys a stage-by-stage decrease of the working temperature is carried out so as to provide a maximum 14% gain in the &ggr;-phase at each stage.Type: GrantFiled: February 14, 2000Date of Patent: May 20, 2003Assignee: General Electric CompanyInventors: Farid Zainullaevich Utyashev, Oscar Akramovich Kaibyshev, Vener Anvarovich Valitov
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Patent number: 6536110Abstract: The present invention relates to a method for-fabricating an integrally bladed rotor which comprises providing a hub section, preferably formed from a titanium based alloy, and welding an airfoil, also preferably formed from a titanium based alloy, to the hub section. The method further comprises partially aging and cooling the hub section prior to welding and aging the airfoil and the weld joint between the airfoil and the hub section subsequent to welding. The post welding aging step is preferably carried out using a novel encapsulated local airfoil heating device having a plurality of heating elements woven into a jacket made from a high temperature cloth material. The method of the present invention may also be used to repair integrally bladed rotors.Type: GrantFiled: April 17, 2001Date of Patent: March 25, 2003Assignee: United Technologies CorporationInventors: Michael P. Smith, Janet Stanley, David S. Murphy, Robert W. Baumgarten, Thomas DeMichael, Stephen L. Mayers
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Publication number: 20020195176Abstract: The present invention relates to a method for fabricating an integrally bladed rotor which comprises providing a hub section, preferably formed from a titanium based alloy, and welding an airfoil, also preferably formed from a titanium based alloy, to the hub section. The method further comprises partially aging and cooling the hub section prior to welding and aging the airfoil and the weld joint between the airfoil and the hub section subsequent to welding. The post welding aging step is preferably carried out using a novel encapsulated local airfoil heating device having a plurality of heating elements woven into a jacket made from a high temperature cloth material. The method of the present invention may also be used to repair integrally bladed rotors.Type: ApplicationFiled: August 23, 2002Publication date: December 26, 2002Inventors: Michael P. Smith, Janet M. Stanley, David S. Murphy, Robert W. Baumgarten, Thomas DeMichael, Stephen L. Mayers
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Publication number: 20020174922Abstract: The diamter of &bgr;-titanium alloy wire is reduced by cold wire-drawing and the &bgr;-titanium alloy wire is subjected to heat treatment. The heat treatment comprises the first aging process for precipitation strengthening and the second aging process for removing processing strain. &bgr;-titanium alloy wire is heat-treated under the supply of tension at the second aging process.Type: ApplicationFiled: April 11, 2002Publication date: November 28, 2002Applicant: Terumo CorporationInventors: Naoki Ishii, Takashi Kaneko, Shin Sumimoto, Hideki Yamamoto, Ichiro Nagao
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Publication number: 20020112796Abstract: A process for treating an alpha-beta titanium alloy to improve cryogenic notch tensile ratio comprises heating the alloy to near or above its beta transus temperature for a sufficient time to dissolve substantially all alpha grains and thus transform the alloy to the beta form, rapidly cooling the alloy from this temperature to induce a martensitic transformation and produce a fine platelet microstructure, isothermally forging the alloy about 50 to 80 percent at about 300° C. below the beta transus temperature to attain a fine equiaxed microstructure such that the largest microstructural unit is about 2-5 &mgr;m, and then aging the alloy at a temperature about 25° C. to 75° C. below the beta transus to grow the refined equiaxed microstructure such that the largest microstructural unit is about 5-10 &mgr;m.Type: ApplicationFiled: January 16, 2001Publication date: August 22, 2002Applicant: The Boeing CompanyInventor: Patrick Lyle Martin
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Patent number: 6399215Abstract: We disclose ultrafine-grained titanium. A coarse-grained titanium billet is subjected to multiple extrusions through a preheated equal channel angular extrusion (ECAE) die, with billet rotation between subsequent extrusions. The resulting billet is cold processed by cold rolling and/or cold extrusion, with optional annealing. The resulting ultrafine-grained titanium has greatly improved mechanical properties and is used to make medical implants.Type: GrantFiled: March 28, 2000Date of Patent: June 4, 2002Assignee: The Regents of the University of CaliforniaInventors: Yuntian T. Zhu, Terry C. Lowe, Ruslan Z. Valiev, Vladimir V. Stolyarov, Vladimir V. Latysh, Georgy J. Raab
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Patent number: 6391128Abstract: The present invention provides a rolling bearing having an excellent corrosion resistance and toughness which can fairly operate at a high rotary speed. At least the inner race is formed by a titanium alloy, and the rolling elements are formed by ceramics. Alternatively, at least one of the inner race and the outer race is formed by a &bgr; type titanium alloy. The percent cold working of the &bgr; type titanium alloy is predetermined to not less than 20% or a range of from 5 to 20%. The cold working is followed by shot peening. Further, the surface hardness Hv is predetermined to not less than 600. The volumetric ratio of residual &bgr; phase in the &bgr; type titanium alloy is predetermined to a range of from 30 to 80%.Type: GrantFiled: March 30, 2001Date of Patent: May 21, 2002Assignee: NSK Ltd.Inventors: Kouji Ueda, Manabu Ohori
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Patent number: 6387197Abstract: A method is set forth for processing titanium and titanium alloys into titanium articles, in which the titanium exhibits enhanced ultrasonic inspection results for determining its acceptability in microstructurally sensitive titanium applications. The method for processing titanium comprises providing titanium at a temperature above its &bgr;-transus temperature; quenching the titanium from a temperature above the &bgr;-transus temperature, the step of quenching titanium forming an &agr;-plate microstructure in the titanium; and deforming the quenched titanium into a titanium article, the step of deforming the quenched titanium transforming the &agr;-plate microstructure into discontinuous &agr; particles without crystallization textures. The discontinuous-randomly textured &agr; particles lead to a reduction in ultrasonic noise during ultrasonic inspection.Type: GrantFiled: January 11, 2000Date of Patent: May 14, 2002Assignees: General Electric Company, Ladish Company, Inc.Inventors: Bernard Patrick Bewlay, Michael Francis Xavier Gigliotti, Jr., David Ulrich Furrer, Gangshu Shen, Jacek Marian Franczak
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Patent number: 6372063Abstract: The process for manufacturing a metallic component, such as a wheel part for the rolling system of a vehicle, which includes, in an initial stage, forming the component of a metallic material in a semi-solid state and having a thixotropic structure, and in a subsequent cold-treatment stage, cold-treating at least part of said component by blasting it with projectiles with a view to plastic deformation thereof. A wheel in which a metallic disk is welded to a wheel rim and in which the metallic disk is obtained by the manufacturing process.Type: GrantFiled: June 8, 2000Date of Patent: April 16, 2002Assignee: Michelin Recherche et Technique, S.A.Inventor: Gilles Grillon
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Publication number: 20020020476Abstract: A method of carburizing treatment is proposed in which if carburizing is carried out at a low temperature, carbon will not turn amorphose and deposit on the surface of a titanium metal but reliably penetrate into between metallic atoms. It is a method of surface treatment of a titanium metal comprising the steps of heating the titanium metal to a temperature of 400-690° C. in a cleaning gas atmosphere containing hydrogen gas, subjecting the surface of the titanium metal to cleaning by applying a DC voltage of 200-1500 V, and plasma carburizing in an atmosphere comprising a carburizing gas having the molar ratio of hydrogen atoms (H) to carbon atoms (C) adjusted to (H/C)≦9 at a pressure of 13-400 Pa and a temperature of 400-690° C. Ionization reaction in the gas is suppressed suitably. Because there exists no excessive carbon which is not used for carburization but turns soot or glass-like carbon, in the atmosphere during carburization, carburizing reaction progresses smoothly.Type: ApplicationFiled: July 11, 2001Publication date: February 21, 2002Inventors: Eiichi Ishii, Takumi Sone, Yukihiro Sato, Kei Demizu, Hideo Kakutani, Koichi Tanaka, Shinichi Tanaka, Noriyoshi Tsuji
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Patent number: 6332935Abstract: A starting workpiece of a titanium-base alloy having a temperature-composition phase diagram with a beta region and an alpha-beta region separated by a beta transus temperature is processed by first forging the starting workpiece at a first temperature in the beta region to form a billet, thereafter second forging the billet at a second temperature in the alpha-beta region, thereafter third forging the billet at a third temperature in the beta region, thereafter fourth forging the billet at a fourth temperature in the alpha-beta region so that the step of fourth forging accomplishes a reduction in cross-sectional area of from about 5 to about 40 percent, and thereafter ultrasonic testing the billet. The beta-region third forging step combined with a relatively small reduction during the alpha-beta-region fourth forging step produce a microstructure that is conducive to ultrasonic inspection with minimal interference from noise.Type: GrantFiled: March 24, 2000Date of Patent: December 25, 2001Assignee: General Electric CompanyInventors: Mark D. Gorman, Andrew P. Woodfield
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Patent number: H2227Abstract: A high speed titanium alloy microstructural conversion method from lamellar to equiaxed is disclosed. The method includes identification and estimation of process parameters such that the average strain rate is between about 1-100 s?1 and the deformation temperature of the material is in the range of about 975°-1010° C.Type: GrantFiled: November 13, 2002Date of Patent: December 2, 2008Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Seshacharyulu Tamirisakandala, Prasad VRK Yellapregada, Steven C. Medeiros, William G. Frazier, James C. Malas