Nitrogen Containing Patents (Class 162/164.6)
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Publication number: 20140060763Abstract: The current invention includes a composition having stability additives of selected inorganic salts and/or organic incorporated into an aldehyde-functionalized polymer product. The stability additive can be post added to the finished polymer product, added to the reaction vessel prior to inducing functionalization of the non-functionalized polymer, or added at any stage during the functionalization reaction. Methods for forming the composition and using the composition to produce a cellulosic fiber-based medium are also disclosed.Type: ApplicationFiled: October 12, 2012Publication date: March 6, 2014Inventors: Heinrich E. Bode, Michael R. St. John, Mei Liu, Robert M. Lowe
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Publication number: 20140053996Abstract: The present invention relates to a process for production of paper, card and board comprising draining a filler-containing paper stock comprising at least one water-soluble polymer with sheet formation in the wire section and then pressing the paper in the press section, wherein a paper stock having a fibrous concentration in the range from 20 to 40 g/l has the at least one water-soluble polymer added to it, then the paper stock is diluted to a fibrous concentration in the range from 5 to 15 g/l, the diluted paper stock is drained to form a sheet and the sheet is pressed in the press section to a solids content G(x) wt % or greater and G(x) computes according to G(x)=48 +(x?15)·0.Type: ApplicationFiled: August 19, 2013Publication date: February 27, 2014Applicant: BASF SEInventors: Anton ESSER, Hans-Joachim Haehnle
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Patent number: 8647472Abstract: The invention provides a method of producing paper with a higher proportion of mineral filler particles than is otherwise be possible without the expected loss in paper strength by preflocculating the filler particles. The method allows for the use of the greater amount of filler particles by coating at least some of the filler particles with a material that prevents the filler materials form adhering to a strength additive. The strength additive holds the paper fibers together tightly and is not wasted on the filler particles.Type: GrantFiled: March 19, 2010Date of Patent: February 11, 2014Assignee: Nalco CompanyInventors: Weiguo Cheng, Ross T. Gray
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Patent number: 8647471Abstract: The present invention relates to a process for the production of sized and/or wet-strength papers, paperboards or cardboards, wherein an aqueous radiation-curable dispersion containing water and at least one polymer, characterized in that the polymer contains cationic groups, is mixed with suspended wood pulp and/or chemical pulp and this mixture is sieved, pressed, thermally dried and then radiation-cured, characterized in that the dispersion is employed in amounts, based on its non-aqueous content in relation to the solid content of the wood pulp and/or chemical pulp, of from 0.001 to 10 wt. %, the papers, paperboards and cardboards produced by this process, and compositions comprising suspended wood pulp and/or chemical pulp and an aqueous radiation-curable dispersion containing at least one polymer, characterized in that the polymer contains cationic groups.Type: GrantFiled: December 22, 2010Date of Patent: February 11, 2014Assignees: Bayer MaterialScience LLC, Bayer MaterialScience AGInventors: Stefan Sommer, Erhard Luehmann, Serkan Unal, Micheal J. Dvorchak
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Publication number: 20140034259Abstract: The disclosure provides a paper slurry comprising a treated inorganic pigment, wherein the treated inorganic pigment comprises an inorganic pigment comprising a pigment surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, and wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11.Type: ApplicationFiled: April 24, 2012Publication date: February 6, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: Daniel C. Kraiter
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Patent number: 8636875Abstract: A process is disclosed for the production of paper with enhanced dry strength comprising adding to the wet end of a paper machine, (a) a glyoxalated acrylamide-containing polymer and (b) a cationic aqueous dispersion polymer. Guidelines for the properties of the polymers that make this coadditive system effective are established. Polymer properties discussed include molecular weight, cationic charge, polymer composition and functionalization, and relative additive amounts.Type: GrantFiled: January 20, 2012Date of Patent: January 28, 2014Assignee: Hercules IncorporatedInventor: Jonathan M. McKay
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Publication number: 20140020858Abstract: Compositions and methods related to new wet strength resins are provided. By using functionally-symmetrical cross-linkers and mono-functional modifiers, and separating the steps of reacting a prepolymer with the cross-linkers from the reaction of intermediate cross-linked prepolymer with epichlorohydrin, new wet strength resin products are provided having improved properties.Type: ApplicationFiled: July 18, 2013Publication date: January 23, 2014Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson
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Patent number: 8632659Abstract: A stable paper sizing composition comprising a dispersion of ketene dimer and a pH adjusted vinylamine containing polymer is disclosed. The method of preparing the stable sizing composition and the method of using the stable sizing composition is also disclosed.Type: GrantFiled: December 17, 2010Date of Patent: January 21, 2014Assignee: Hercules IncorporatedInventors: Susan M. Ehrhardt, Kyle J. Bottorff
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Publication number: 20140000828Abstract: Compositions and methods of producing an optically-enhanced paper-based material are disclosed. The composition can include an optical brightening agent and an additive having an aromatic portion, where the aromatic portion is associated with an optical brightening agent. The paper-based material can exhibit a higher capacity for the optical brightening agent relative to a paper-based material that lacks the additive. Techniques for increasing optical brightening agent retention in a paper-based material are also disclosed. The techniques include using an additive having an aromatic portion, where the aromatic portion associates with an optical brightening agent so that the retention of the optical brightening agent is improved.Type: ApplicationFiled: June 13, 2013Publication date: January 2, 2014Inventors: LYNN REIS, DAVID S. SOANE, GANGADHAR JOGIKALMATH
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Publication number: 20130340963Abstract: The invention provides methods and compositions for softening paper. An inventive composition and method of its use softens paper products (like tissue paper) by de-bonding its cellulose fibers and by improving the smoothness of the resulting paper. The invention forms a surfactant-polymer complex that attaches de-bonding non-ionic surfactants to cellulose fibers that would otherwise not be retained by the cellulose fibers. This complex prevents the fibers from bonding with each other and makes the paper product smoother. Best of all, the composition is environmentally superior and is a non-toxic.Type: ApplicationFiled: August 23, 2013Publication date: December 26, 2013Applicant: Nalco CompanyInventors: Gary S. Furman, Gillian Frette, Frank Koenig, Tobias Maurer
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Patent number: 8613836Abstract: A process is provided for making a fluff pulp sheet, comprising contacting at least one cationic trivalent metal, salt thereof, or combination thereof with a composition comprising fluff pulp fibers and water at a first pH, to form a first mixture; contacting at least one debonder surfactant with the first mixture and raising the pH to a second pH, which is higher than the first pH, to form a fluff pulp mixture; forming a web from the fluff pulp mixture; and drying the web, to make the fluff pulp sheet. A fluff pulp sheet is also provided, comprising a web comprising fluff pulp fibers; at least one cationic trivalent metal, salt thereof, or combination thereof; at least one debonder surfactant; and a fiberization energy of <145 kJ/kg. Products and uses of the fluff pulp sheet are also provided.Type: GrantFiled: August 5, 2010Date of Patent: December 24, 2013Assignee: International Paper CompanyInventors: James E. Sealey, Michael Hevenor
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Patent number: 8613832Abstract: The present invention relates to a drainage and retention aid composition which comprises: (d) a first anionic component which is a water-soluble anionic organic polymer; (e) a second anionic component which is a water-dispersible or branched anionic organic polymer; and (f) a third anionic component which is an anionic siliceous material; wherein the first, second and third anionic components are present in a dry matter content of from 0.01 to 50% by weight.Type: GrantFiled: February 15, 2012Date of Patent: December 24, 2013Assignee: Akzo Nobel N.V.Inventors: Johan Nyander, Fredrik Solhage
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Publication number: 20130333853Abstract: A fluff pulp or other pulp, comprises a multivalent cationic metal ion selected from the group consisting of Al+3, B+3, Mn+2, Cu+2, Cu+3, Zn+2, Sn+2, Sn+4, water-soluble salt thereof, or combination thereof; an amine-containing anti-static agent; and pulp. Methods of making and using the pulp, as well as articles therefrom, are provided.Type: ApplicationFiled: June 13, 2013Publication date: December 19, 2013Inventors: JAMES E. SEALEY, PETER M. FROASS, SYLVIE MARIE RITA CARRIERE
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Patent number: 8604128Abstract: Methods for forming rosin-derived cationic compounds are provided. The method can include attaching a cationic group to a conjugated diene on a hydrophenathrene-based ring of a resin acid (e.g., levopimaric acid, abietic acid, dehydroabietic acid, or a mixture thereof) to form a rosin-derived cationic compound. Attaching the cationic group to the conjugated diene on the hydrophenathrene-based ring of the resin acid can be achieved via a Diels-Alder reaction of a dienophile with the hydrophenathrene-based ring of the resin acid. Rosin-derived cationic compounds are also provided. The rosin-derived cationic compound can include a cationic group attached to a conjugated diene on a hydrophenathrene-based ring of a resin acid, wherein the rosin-derived cationic compound further comprises a carboxylic acid group.Type: GrantFiled: February 15, 2012Date of Patent: December 10, 2013Assignee: University of South CarolinaInventors: Chuanbing Tang, Jifu Wang, Alan W. Decho, Yung Pin Chen
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Patent number: 8604134Abstract: Vinylamine-containing polymers are disclosed where the amine groups are substituted with (1) cationic functional groups, (2) anionic functional groups, (3) hydrophobic functional groups, (4) hydrophilic functional groups, (5) functional groups that impart amphoteric characteristics to the polymers, or (6) combinations thereof. Also disclosed are processes for preparing such polymers, as well as compositions comprising such polymers. Among other applications, these polymers can be used in papermaking applications as dry strength additives, wet strength additives, retention aids, drainage aids, and pitch and stickies control agents.Type: GrantFiled: July 31, 2008Date of Patent: December 10, 2013Assignee: Hercules IncorporatedInventors: Qu-Ming Gu, Jonathan M. McKay, Richard J. Riehle
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Patent number: 8597467Abstract: A cationic copolymer is obtained by the Hofmann rearrangement (also referred to as the Hofmann degradation reaction) in aqueous solution in the presence of an alkaline-earth and/or alkali hydroxide and an alkaline-earth and/or alkaline hypohalide, on a base copolymer comprising at least one nonionic monomer selected from the group comprising acrylamide (and/or methacrylamide), N,N-dimethylacrylamide and/or acrylonitrile The copolymer is branched after the Hofmann rearrangement, in the presence of at least one polyfunctional branching agent, and is soluble in water.Type: GrantFiled: July 11, 2008Date of Patent: December 3, 2013Assignee: S.P.C.M. SAInventors: Christian Jehn-Rendu, Rene Hund, Muttalif Duong
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Publication number: 20130306257Abstract: A pulp making process in which fibrous cellulosic material is pulped to form an aqueous suspension of cellulosic material, the suspension is drained through a screen to form a pulp sheet and that the pulp sheet is dried to form a dry market pulp, in which a water soluble cationic polymer is added to the suspension as the sole drainage aid wherein the water-soluble cationic polymer is either, i) a copolymer comprising (a) between 1 and 70 mole % (meth) acrylamide and (b) between 30 and 99 mole % (meth) acryloyloxyethyl-trimethyl ammonium chloride with an intrinsic viscosity between 5 and 9 dl/g; or ii) a hydrolysed homopolymer of vinylformamide comprising between 1 and 100 mole % vinyl amine units and having a K value of between 45 and 240. The process of the invention provides improved drainage time and solids content of the dewatered pulp.Type: ApplicationFiled: November 14, 2011Publication date: November 21, 2013Applicant: BASF SEInventors: Christian Jehn-Rendu, Joachim Hege, Detlef Kannengießer
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Publication number: 20130306261Abstract: The invention provides a method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in a papermaking process. The method improves the efficiency of dewatering aid by coating at least some of the filler particles with a material that prevents the filler materials form adhering to dewatering aids. The dewatering aid holds the paper fibers together tightly and is not wasted on the filler particles.Type: ApplicationFiled: May 25, 2012Publication date: November 21, 2013Inventors: Yulin ZHAO, Jun LI, Qing Long RAO, Weiguo CHENG
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Publication number: 20130299109Abstract: The invention relates to a method for improving papermaking or board making process. The method comprises forming a fibre stock, and leading the fibre stock to a headbox and feeding it to a wire to form a wet fibrous web. A at least one polysaccharide having 1,4-?-anomeric configuration in linkages between saccharide units of the polysaccharide backbone or the main polysaccharide backbone is applied to the fibre stock after machine chest or on the wet fibrous web. The invention relates also to paper made by the method and to the use of polysaccharide.Type: ApplicationFiled: September 30, 2011Publication date: November 14, 2013Inventors: Matti Hietaniemi, Kristian Salminen, Janne Kataja-aho, Elias Retulainen
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Publication number: 20130299110Abstract: The invention provides a method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in a papermaking process The method improves the efficiency of drainage aids or wet web strength aids or wet strength aid by coating at least some of the filler particles with a material that prevents the filler materials form adhering to a those additives. The drainage additive or wet web strength additive or wet strength aid holds the cellulose fibers together tightly and is not wasted on the filler particles.Type: ApplicationFiled: June 17, 2013Publication date: November 14, 2013Inventors: Yulin Zhao, Jun Li, Qing Long Rao, Weiguo Cheng
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Publication number: 20130277002Abstract: The present invention relates to a process for producing paper which comprises: (vii) providing an aqueous suspension comprising cellulosic fibres, (viii) adding to the suspension after all points of high shear a first polymer being a cationic polymer having a charge density above 2.5 meq/g; a second polymer, and a third polymer being an organic or inorganic anionic polymer; and (ix) dewatering the obtained suspension to form paper.Type: ApplicationFiled: October 10, 2012Publication date: October 24, 2013Inventor: AKZO NOBEL N.V.
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Publication number: 20130280503Abstract: Fibrous structures that contain hydroxyl polymer filaments and solid additives and methods for making same are provided.Type: ApplicationFiled: April 23, 2013Publication date: October 24, 2013Applicant: The Procter & Gamble CompanyInventors: David William CABELL, Hasan EROGLU
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Patent number: 8562787Abstract: In a method for manufacturing paper or the like, in which cationic polymer microparticles comprised of polyacrylamide and a fine-particle inorganic component are added to the paper pulp following the final shearing step and prior to the headbox, whereupon the paper pulp is subjected to dehydration while forming sheets, followed by sheet drying, a polymer mixture comprising a linear cationic polymer and a linear anionic copolymer, whose overall ionicity is anionic, is additionally added immediately prior to the headbox.Type: GrantFiled: November 3, 2010Date of Patent: October 22, 2013Assignee: Applied Chemicals Handels-GmbHInventor: Alexander Frank
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Publication number: 20130269894Abstract: The present invention relates to a process for producing paper which comprises: providing an aqueous suspension comprising cellulosic fibres, adding to the suspension, after all points of high shear, a cationic polysaccharide; an inorganic polymer P1 being a cationic polyaluminium compound; and a polymer P2 being an anionic polymer; and, dewatering the obtained suspension to form paper.Type: ApplicationFiled: September 6, 2012Publication date: October 17, 2013Applicant: AKZO NOBEL N.V.Inventors: Fredrik Solhage, Joakim Carlén, Birgitta Johansson
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Publication number: 20130255898Abstract: Fibrous structures that exhibit improved wet compression properties, and more particularly to wet compression-enhancing agent-containing fibrous structures that provide superior wet compression properties compared to the same fibrous structures without the wet compression-enhancing agent, are provided.Type: ApplicationFiled: March 28, 2013Publication date: October 3, 2013Applicant: The Procter & Gamble CompanyInventors: Charles WilAllenliam REDD, Charles William NEAL
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Publication number: 20130228300Abstract: The invention relates to a method for impregnating and drying a continuous paper web (1) by means of a urea resin dissolved in water, and to a corresponding system. Such paper webs (1) are employed for example as furniture foil or floor laminate, wherein in the known art melamine resin is used exclusively for bonding to a substrate. This is relatively expensive. Therefore the object of the invention is to create a method in which the paper web (1) which is impregnated by means of urea resin can be bonded to the substrate with a high degree of operational reliability. Said object is achieved in that the temperature of the paper web (1) is determined separately in each of the drying zones (3.1, 3.2, 3.3, 3.4), that for each of the drying zones (3.1, 3.2, 3.3, 3.4) an amount and/or a temperature of the circulating air are regulated so that the maximum temperature of the paper web (1) is 99° C., and that exhaust air is extracted from a first one of the drying zones (3.1, 3.2, 3.3, 3.Type: ApplicationFiled: November 4, 2011Publication date: September 5, 2013Inventors: Udo Unger, Adnan Doengelli, Daniel James, Willi Erkelenz
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Patent number: 8524042Abstract: A method for inhibiting resinous and sticky substances from filling or forming deposits on or within papermaking forming wire, by applying to said wire an effective inhibiting amount of a composition comprising at least one cationic agent selected from the group consisting of (a) cationic polyureas, (b) hydrophobically modified cationic polymers, (c) alkylammonium or/and alkylimidazolium salts, and optionally at least one nonionic amphiphilic copolymer selected from (i) hydrophobically modified polyethylene glycols], (ii) hydrophobically modified cellulose ethers, (iii) copolymers of vinyl alcohol and vinyl alkonate, (iv) polyoxyalkylene block copolymers, and (v) hydrophilically modified polydimethylsiloxanes.Type: GrantFiled: August 22, 2011Date of Patent: September 3, 2013Assignee: Hercules IncorporatedInventors: Fushan Zhang, Tien-Feng Ling
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Patent number: 8518215Abstract: Vinylamine-containing polymers are disclosed where the amine groups are substituted with cationic functional groups. Processes for preparing such polymers, as well as compositions comprising such polymers are also disclosed. Among other applications, these polymers can be used in papermaking applications as dry strength additives, wet strength additives, retention aids, drainage aids, and pitch and stickies control agents.Type: GrantFiled: January 29, 2010Date of Patent: August 27, 2013Assignee: Hercules IncorporatedInventors: Jonathan M. McKay, Qu-Ming Gu, Richard J. Riehle
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Publication number: 20130213596Abstract: A method regulating the formation of a fibrous web, such as a paper, cardboard, or tissue web, in which method the formation of the fibrous web is measured online as a controlled variable and is held at a predefinable setpoint level via automatic formation regulation. In addition to the formation, the charge concentration of the suspension is measured as a controlled variable and is taken into consideration during the formation regulation.Type: ApplicationFiled: March 20, 2013Publication date: August 22, 2013Applicant: Voith Patent GmbHInventor: Voith Patent GmbH
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Patent number: 8512520Abstract: A paper size which comprises a stable aqueous dispersion of a reactive size, from 5 to 100% by weight, based on the reactive size, of a substantially linear nitrogen-comprising polymer having at least 3 mmol/g of basic nitrogen atoms, and from 1 to 50% by weight of cationic starch having a degree of substitution of at least 0.05 is described. The paper size has a good sizing effect and a stable viscosity.Type: GrantFiled: November 29, 2005Date of Patent: August 20, 2013Assignee: BASF AktiengesellschaftInventors: Markus Schmid, Roland Ettl, Klaus Lorenz, Rainer Dyllick-Brenzinger, Andreas Brockmeyer
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Patent number: 8506757Abstract: Disclosed herein are hydrophobically-modified poly(aminoamides) useful as fixative detackifiers for stickies and pitch control in papermaking processes. These polymers are prepared via modification of amine-containing water-soluble poly(aminoamides) with reactive functional group-containing hydrophobic compounds. In particular, poly(aminoamides) may be modified, under appropriate reaction conditions, with long chain alkyl glycidyl ether, AKD (alkyl ketene dimer), ASA (alkyl succinyl anhydride), or Quab (3-chloro-2-hydroxypropyl-N,N,N-dimethylalkyl ammonium chloride). These novel polymers are effective in inhibiting deposition of organic contaminants in pulp and papermaking systems.Type: GrantFiled: November 18, 2009Date of Patent: August 13, 2013Assignee: Hercules IncorporatedInventors: Qu-Ming Gu, Lloyd A. Lobo, Erin A. S. Doherty, Huai N. Cheng
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Publication number: 20130192782Abstract: Disclosed herein are compositions and methods to increase paper machine performance and enhance sizing. The compositions include a sizing agent, an emulsifier, and an aqueous component. The emulsifier may be an aldehyde-functionalized polymer.Type: ApplicationFiled: March 13, 2013Publication date: August 1, 2013Inventor: NALCO COMPANY
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Publication number: 20130180679Abstract: The invention relates to a method for improving the removal of water in a composition containing microfibrillated cellulose. According to the invention, a cationic polyelectrolyte that has a low molecular weight and a molecular weight of less than 10000 is provided in the composition containing microfibrillated cellulose.Type: ApplicationFiled: September 14, 2011Publication date: July 18, 2013Applicant: UPM-Kymmene CorporationInventors: Janne Laine, Tero Taipale, Isko Kajanto
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Publication number: 20130180678Abstract: A method of preparing a treated article comprises the step of providing a slurry comprising fibers. The method further comprises the step of combining the slurry and a first fluorinated composition to form a mixture. In addition, the method comprises the step of forming at least one sheet from the mixture. Finally, the method comprises the step of applying a second fluorinated composition on at least one surface of the at least one sheet to prepare the treated article.Type: ApplicationFiled: January 17, 2012Publication date: July 18, 2013Inventors: Michael J. Sanchez, James L. Scott
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Patent number: 8486227Abstract: A process for the production of paper, board and cardboard by draining a paper stock containing interfering substances in the presence of polymers which contain vinylamine units and which have an average molar mass Mw of at least 1 million, a high-consistency stock first being prepared, at least one polymer containing vinylamine units and having an average molar mass Mw of at least 1 million and a degree of hydrolysis of from 1 to 20 mol % being metered into the high-consistency stock, the high-consistency stock being diluted to a low-consistency stock by adding water, and the low-consistency stock being drained, the polymers being hydrolyzed homo- or copolymers of N-vinylcarboxamides additives for reducing deposits in the wire part, press section and drying section of paper machines.Type: GrantFiled: September 11, 2012Date of Patent: July 16, 2013Assignee: BASF SEInventors: Anton Esser, Rainer Blum, Joachim Kuhn, Marc Leduc, Ralf Hemel
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Patent number: 8475630Abstract: Compositions and methods of producing an optically-enhanced paper-based material are disclosed. The composition can include an optical brightening agent and an additive having an aromatic portion, where the aromatic portion is associated with an optical brightening agent. The paper-based material can exhibit a higher capacity for the optical brightening agent relative to a paper-based material that lacks the additive. Techniques for increasing optical brightening agent retention in a paper-based material are also disclosed. The techniques include using an additive having an aromatic portion, where the aromatic portion associates with an optical brightening agent so that the retention of the optical brightening agent is improved.Type: GrantFiled: April 16, 2010Date of Patent: July 2, 2013Assignee: NanoPaper, LLCInventors: Lynn Reis, Gangadhar Jogikalmath, David S. Soane
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Publication number: 20130160959Abstract: Paper strength systems including polyamine-polyamidoamine-epihalohydrin (PPAE) resin are disclosed. Also disclosed are methods of forming a paper including applying a strength system comprising PPAE to cellulosic fiber, as well as the resultant paper.Type: ApplicationFiled: December 22, 2011Publication date: June 27, 2013Applicant: KEMIRA OYJInventors: Scott Rosencrance, Vladimir Grigoriev, Chen Lu
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Publication number: 20130153166Abstract: This invention relates to paper products and/or substrates suitable for being made and/or converted into wallboard tape; which also may be known as joint tape and/or drywall tape, having a pH of at least 7.0 and containing a plurality of cellulose fibers, a wet strength additive, an alkaline sizing agent, and an anionic promoter, as well as methods of making and using the same.Type: ApplicationFiled: February 13, 2013Publication date: June 20, 2013Applicant: INTERNATIONAL PAPER COMPANYInventor: INTERNATIONAL PAPER COMPANY
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Patent number: 8465624Abstract: A fluff pulp or other pulp, comprises a multivalent cationic metal ion selected from the group consisting of Al+3, B+3, Mn+2, Cu+2, Cu+3, Zn+2, Sn+2, Sn+4, water-soluble salt thereof, or combination thereof; an amine-containing anti-static agent; and pulp. Methods of making and using the pulp, as well as articles therefrom, are provided.Type: GrantFiled: July 18, 2011Date of Patent: June 18, 2013Assignee: International Paper CompanyInventors: James E. Sealey, Peter M. Froass, Sylvie Marie Rita Carriere
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Patent number: 8465623Abstract: The invention provides a method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in a papermaking process The method improves the efficiency of drainage aids or wet web strength aids or wet strength aid by coating at least some of the filler particles with a material that prevents the filler materials form adhering to a those additives. The drainage additive or wet web strength additive or wet strength aid holds the cellulose fibers together tightly and is not wasted on the filler particles.Type: GrantFiled: October 13, 2011Date of Patent: June 18, 2013Assignee: Nalco CompanyInventors: Yulin Zhao, Jun Li, Qing Long Rao, Weiguo Cheng
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Publication number: 20130146241Abstract: Expandable microspheres formed by suspension polymerization using a shot growth method are provided. The microspheres are formed of a continuous, gas impermeable shell surrounding a blowing agent. The shell includes a first polymer layer formed from primary monomers and a second layer that includes a chemically reactive monomer or a high Tg monomer. To form the microspheres, the primary monomers are polymerized in a reaction vessel to an approximate 90% polymerization, at which time a secondary monomer that is either a monomer having a Tg of at least 85° C. or a chemically reactive monomer, is added to the reaction vessel to drive the polymerization reaction to completion. The outer layer thus contains either a larger amount of the high Tg monomer or a chemically reactive monomer that possesses the ability to covalently bond a cationic species. The microspheres may be used in papermaking processes to increase the paper bulk.Type: ApplicationFiled: February 7, 2013Publication date: June 13, 2013Applicant: INTERNATIONAL PAPER COMPANYInventor: INTERNATIONAL PAPER COMPANY
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Publication number: 20130139980Abstract: Methods and systems are provided for producing market pulp which include treatment of pulp with diverse ionic compounds before pulp drying. Cationically and anionically charged compounds can be used to treat pulp before pulp drying to improve pulp dewatering performance and efficiency in the production of market pulp. Market pulp products containing the treatment compounds are also described.Type: ApplicationFiled: November 26, 2012Publication date: June 6, 2013Applicant: BUCKMAN LABORATORIES INTERNATIONAL, INC.Inventor: Buckman Laboratories Internatinal, Inc.
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Publication number: 20130139985Abstract: The present disclosure is directed to a continuous process for preparing cellulose reactive adducts of polyvinylamide.Type: ApplicationFiled: December 6, 2012Publication date: June 6, 2013Applicant: BASF SEInventor: BASF SE
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Patent number: 8454798Abstract: A method is described for making paper or paper board by applying a composition containing enzyme and cationic coagulant to papermaking pulp prior to paper forming to preferably improve drainage, retention, or both. Sheets of pulp from which paper or paperboard products are made with the method can exhibit excellent drainage, excellent retention of pulp fines, or both. The method also can be applied to other pulp treatments, such as waste water treatments. A system for making such treatments of paper furnish is also provided.Type: GrantFiled: April 14, 2011Date of Patent: June 4, 2013Assignee: Buckman Laboratories International, Inc.Inventors: Weiping Ban, Gary Headrick, Rosa M. Covarrubias
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Patent number: 8454796Abstract: A process of making filled paper comprising the steps of providing a thick stock cellulosic suspension that contains mechanical pulp and filler, diluting the thick stock suspension to form a thin stock suspension, in which the filler is present in the thin stock suspension in an amount of at least 10% by weight based on dry weight of thin stock suspension, flocculating the thick stock suspension and/or the thin stock using a polymeric retention/drainage system, draining the thin stock suspension on a screen to form a sheet and then drying the sheet, in which the polymeric retention/drainage system comprises, i) a water-soluble branched anionic polymer and ii) a water-soluble cationic or amphoteric polymer. The process is particularly suitable for making filled mechanical grade paper, such as SC grade paper. The process enables the separation of retention and drainage parameters, especially useful for fast draining paper machines, such as Gapformers.Type: GrantFiled: January 21, 2008Date of Patent: June 4, 2013Assignee: BASF SEInventor: Holger Reinicke
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Patent number: 8449721Abstract: Aqueous slurries of finely divided fillers which are at least partly covered by anionic latices, the slurries being obtainable by treating aqueous slurries of finely divided fillers with at least one anionic latex which comprises, incorporated in the form of polymerized units, at least one monomer comprising phosphonic and/or phosphoric acid groups, preparation of the aqueous slurries and their use as an additive to the paper stock in the production of filler-containing paper, filler-containing cardboard or filler-containing board by draining the paper stock.Type: GrantFiled: June 30, 2009Date of Patent: May 28, 2013Assignee: BASF SEInventors: Juergen Schmidt-Thuemmes, Anton Esser, Joerg Nieberle
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Publication number: 20130126114Abstract: The present invention generally relates to resins and uses thereof in composite materials and products. The present invention also relates to extraction processes for obtaining resins from plants and plant materials. The invention also relates to resin extracts obtained from a plant of the genus Triodia, commonly known as Spinifex, processes for obtaining resins, modified resins and composite products incorporating resins.Type: ApplicationFiled: October 20, 2010Publication date: May 23, 2013Applicant: SPINIFEX RESINS PTY LTDInventors: Charles Capps, Paul Ah Chee, Philip Delacretaz
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Stable and aqueous compositions of polyvinylamines with cationic starch, and utility for papermaking
Patent number: 8444818Abstract: A stable aqueous composition comprising polyvinylamine and liquid cationic starch in a ratio of from 90 to 55 parts of polyvinylamine on active basis to 10 to 45 parts of liquid cationic starch on active basis is disclosed. The composition can be used in papermaking as a strength or as a drainage aid.Type: GrantFiled: April 7, 2011Date of Patent: May 21, 2013Assignee: Hercules IncorporatedInventors: Frank J. Sutman, Christopher P. Dilkus, Qu-Ming Gu -
Publication number: 20130118699Abstract: Surfactant mediated, free radical initiated emulsion/dispersion polymerization of n-vinylformamide with styrene or substituted styrene copolymers, and its subsequently hydrolyzed products bearing formamide, amine and styrenic functionality are disclosed. Processes for polymerization, polymer composition, and hydrolysis of such polymers are also disclosed. These polymers bearing cationic functionality can be used in papermaking applications as dry strength additives, wet strength additives, retention aids, drainage aids, sizing agent, sizing promoter and pitch and stickies control agents.Type: ApplicationFiled: November 1, 2012Publication date: May 16, 2013Applicant: HERCULES INCORPORATEDInventor: HERCULES INCORPORATED
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Publication number: 20130112360Abstract: The present invention relates to a process for manufacturing paper or board, wherein paper or board pulp is diluted with acidic water and wherein the pH value of the pulp is raised with an alkali simultaneously with increasing the solids content of the pulp by filtration, compression and evaporation on the wire, press and drying sections, and, at the same time, filler is precipitated from the acidic water into the paper or board structure. The invention also relates to moistening of paper or board, with a dry matter content of over 40%, in acidic water, after which the pH value is raised with an alkali, and the paper or board is dried, or it is dried after the moistening without raising the pH value.Type: ApplicationFiled: June 3, 2011Publication date: May 9, 2013Applicant: NORDKALK OY ABInventors: Pentti Virtanen, Sakari Saastamoinen