Nitrogen Containing Compound Patents (Class 162/168.2)
  • Patent number: 6303002
    Abstract: Paper, board and cardboard are produced from paper stocks which contain tacky impurities by the addition of surfactants and cationic polymers having a charge density of at least 1.5 meq/g (measured at pH 7) and a molar mass Mw of the cationic polymers of at least 15,000 and drainage of the paper stocks with fixation of the tacky impurities in the paper produced.
    Type: Grant
    Filed: October 15, 1999
    Date of Patent: October 16, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Friedrich Linhart, Jaroslav Melzer, Hubert Meixner
  • Patent number: 6287418
    Abstract: Synthetic polymers having moieties capable of covalent or hydrogen bonding to cellulose and one or more amphiphilic moieties are disclosed. These polymers are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: September 11, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
  • Patent number: 6280572
    Abstract: A method of producing dimensionally stable paper and/or paperboard products by treating a hygroreactive cellulosic fiber matrix with a hydrophobic sizing agent solution; and drying the treated fibers using heat and/or pressure so that the hydrophobic sizing agent penetrates the fiber matrix making it hydrophobic.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: August 28, 2001
    Assignee: International Paper Company
    Inventors: Yan C. Huang, Murray Bruce Lyne, Clifford Kent Hatcher, Gurudatta D. Nadkarni
  • Patent number: 6273997
    Abstract: Discloses is a method for sizing paper at a pH of about 5.0 to about 8.5 by incorporating a sizing composition consisting essentially of (a) rosin, (b) at least one hydrocarbon resin, (c) a cationic component consisting essentially of a cationic polyamine resin at a weight ration of the rosin/hydrocarbon resin blend to cationic polyamine of about 5:1 to about 1:2, and (d) up to 0.3% alum. The cationic polyamine resin is selected from the group consisting of polyalkyleneamine-epihalohydrin resins, polyalkyleneamine-dicyandiamide-epihalohydrin resins, poly(diallylamine•HCl)-epihalohydrin resins, poly(methyldiallylamine•HCl)-epihalohydrin resins, epihalohydrin-modified polyethyleneimine resins, amine-modified poly(methyldiallylamine•HCl)-epihalohydrin resins, and mixtures thereof.
    Type: Grant
    Filed: July 17, 2000
    Date of Patent: August 14, 2001
    Assignee: Hercules Incorporated
    Inventors: Susan M. Ehrhardt, D. Bruce Evans
  • Patent number: 6273998
    Abstract: A drainage/retention aid comprising a combination of a) microparticles; and b) a vinylamine copolymer having the general structure: wherein m is from 1-99 mol %, n is from 0 to 50 mol % and o is from 1 to 99 mol %; A is selected from the group consisting of one or more repeating units having the following general structures: and salts thereof wherein p, q and r are mol percentages from 1 to 99, each R1 is independently H or CH3, and X is —CN, —COOR2, —CONR3R4, —OR5, —OCOR6, and mixtures thereof; wherein R2, R3, R4, R5, R6 are independently selected from H or C1 to C4 alkyl; and wherein the vinylamine copolymer has a charge density in a range of from 2 to 24 mEq/g.
    Type: Grant
    Filed: August 16, 1994
    Date of Patent: August 14, 2001
    Assignee: Betzdearborn Inc.
    Inventors: Lawrence Lu Kuo, Roger Yiming Leung, Steven R. Prescott, Thord Hassler
  • Patent number: 6251223
    Abstract: A process for improving gravure and offset printability of coated and uncoated printing papers by increasing filler share in the paper on the top and bottom sides or in the outer layers of the paper web by using a retention agent, and providing the outerlayers of the fiber bearing liquid forming the paper web with additional retention agent before or during sheet formation on or between the wires of the paper making machine.
    Type: Grant
    Filed: January 11, 1999
    Date of Patent: June 26, 2001
    Assignee: Stora Publication Paper AG
    Inventors: Hansjörg Kessler, Dieter Horand, Wolfram Friesen
  • Patent number: 6245874
    Abstract: A process for making paper with increased wet and dry strength by incorporating into the pulp suspension an ionic thermosettable resin which is the reaction product of dialdehyde and epihalohydrin, or epihalohydrin equivalent, with a copolymer containing monomer units derived by polymerization of monomers comprising acrylamide or alkyl-substituted acrylamide and diallylamine or an acid salt thereof. The paper has wet and dry strength greater than that of paper not containing the resin and has a higher repulpability index than wet strength paper that is essentially the same but contains conventional polyazetidinium ion containing wet strength resin instead of the ionic thermosettable resin.
    Type: Grant
    Filed: March 1, 2000
    Date of Patent: June 12, 2001
    Assignee: Hercules Incorporated
    Inventors: Ronald Richard Staib, Joseph Raymond Fanning, William Walter Maslanka
  • Patent number: 6238521
    Abstract: A papermaking process consisting essentially of: forming an aqueous cellulosic papermaking slurry; adding to the slurry certain additives, with said certain additives selected from the group including: coagulants; sizing agents; and mineral fillers; draining the slurry to form a sheet; and drying the sheet to form a paper sheet; the improvement comprising adding to the slurry, prior to it being drained; an effective amount of a cationic dispersion polymer; which cationic dispersion polymer is a copolymer comprising about 30 mole % diallyldimethylammonium chloride (DADMAC) and about 70 mole % acrylamide (AcAm); and adding to the slurry, either before or after said cationic dispersion polymer is added and the slurry is drained, a microparticle selected from the group consisting of a) copolymers of acrylic acid and acrylamide; b) bentonite; and c) dispersed silica; with the proviso that said coagulant cannot be a cationic dispersion copolymer comprising about 30 mole % diallyldimethylammonium chloride
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: May 29, 2001
    Assignee: Nalco Chemical Company
    Inventors: Jane B. Wong Shing, Chidambaram Maltesh, Ramasubramanyam Nagarajan
  • Patent number: 6238520
    Abstract: Starch is added to the thinstock in a papermaking process in the form of a coagulated slurry containing undissolved starch particles, cationic polymeric flocculant and anionic microparticulate network agglomeration aid, such as bentonite. The flocculant and agglomeration aid interact to give network flocculation in which the starch particles are trapped. Improved retention of the starch in the resulting paper is achieved.
    Type: Grant
    Filed: May 10, 1999
    Date of Patent: May 29, 2001
    Assignee: Ciba Specialty Chemicals Water Treatments Limited
    Inventor: Graham Greenwood
  • Patent number: 6235155
    Abstract: Condensation polymers, such as polyamide epichlorohydrin (PAE) resins, can be combined with polysiloxanes in a single molecule to provide several potential benefits, depending upon the specific combination employed, including: (a) wet strength resins that soften; (b) softeners that do not reduce dry or wet tensile strength; (c) wet strength with improved wet/dry tensile ratio; (d) softeners/debonders with reduced linting and sloughing; (e) wet strength aids with controlled absorbency rate; and (f) Yankee dryer additives that provide surface protection and adhesion with controlled release properties.
    Type: Grant
    Filed: January 20, 2000
    Date of Patent: May 22, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
  • Patent number: 6235835
    Abstract: Starch is modified with at least one cationic polymer P) and the modified starch is prepared by a process in which a) an anionically modified starch A) is reacted with a cationic polymer P) or b) a natural starch B) or a starch C) which has not been anionically modified is reacted with the cationic polymer P) in the presence of an anionic modifier M) and the polymer-modified starch is used.
    Type: Grant
    Filed: July 14, 1999
    Date of Patent: May 22, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Niessner, Claudia Nilz, Primoz Lorencak, Martin Rübenacker, Roland Ettl
  • Patent number: 6235150
    Abstract: A method is described for attaining high levels of loading of calcium carbonate fillers in the lumens of wood pulp fibers. The pulp is pretreated with a cationic polymer prior to being impregnated with the filler. Different conditions of pH and temperature are specified depending on whether the filler is a precipitated calcium carbonate or a ground calcium carbonate. The lumen-loaded pulps are used to make novel products with advantages in higher filler retention and sheet strength over conventionally made papers.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: May 22, 2001
    Assignee: Pulp and Paper Research Institute of Canada
    Inventors: Steven R. Middleton, Josée Desmeules, Anthony M. Scallan
  • Patent number: 6228219
    Abstract: Disclosed is a method for sizing paper at a pH of about 5.0-8.5 by incorporating a sizing composition consisting essentially of (1) rosin, (2) a cationic polyamine resin at a weight ratio of rosin to cationic polyamine of about 5:1 to about 1:2, and (3) up to 0.3% alum. The cationic polyamine resin is selected from the group consisting of polyalkyleneamine-epihalohydrin resins, polyalkyleneamine-dicyandiamide-epihalohydrin resins, poly(diallylamine.HCl)-epihalohydrin resins, poly(methyldiallylamine.HCl)-epihalohydrin resins, epihalohydrin-modified polyethyleneimine resins, amine-modified poly(methyldiallylamine.HCl)-epihalohydrin resins and mixtures thereof.
    Type: Grant
    Filed: September 14, 1999
    Date of Patent: May 8, 2001
    Assignee: Hercules Incorporated
    Inventors: Susan M. Ehrhardt, D. Bruce Evans
  • Patent number: 6228217
    Abstract: This invention is directed to a process for preparing an aqueous papermaking suspension containing a polyelectrolyte complex comprising providing an aqueous suspension of pulp fibers containing a water-soluble cationic polymer and a water-soluble anionic polymer that are reactable in the aqueous suspension to form the polyelectrolyte complex, and a multivalent cation having at least a +3 charge, and forming the polyelectrolyte complex. It also includes the process wherein the aqueous suspension of pulp fibers contains surface active carboxyl compounds and water-soluble anionic compounds. It further includes the process wherein the aqueous papermaking suspension is sheeted and dried to obtain paper of improved strength.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: May 8, 2001
    Assignee: Hercules Incorporated
    Inventors: Jay A. Dickerson, Harry J. Goldy, Douglas C. Smith, Ronald R. Staib
  • Patent number: 6228218
    Abstract: A water-disintegratable cleaning sheet consisting of a fibrous sheet having incorporated thereinto, a binder of alkylcellulose; an electrolyte, and (a) a copolymer of a polymerizable acid anhydride and other compounds and/or (b) an amino acid. The water-disintegratable cleaning sheet has excellent water disintegratability and wet strength and further it is not degraded in the water disintegratability and wet strength after storage at high temperatures.
    Type: Grant
    Filed: December 24, 1998
    Date of Patent: May 8, 2001
    Assignee: Uni-Charm Corporation
    Inventors: Naohito Takeuchi, Takayoshi Konishi, Ryuichiro Kurata, Nobuo Morohashi, Masayoshi Matsumoto
  • Patent number: 6224714
    Abstract: Synthetic polymers having hydrogen bonding capability and one or more polysiloxane moieties are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: May 1, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
  • Patent number: 6225437
    Abstract: Provided are alkenyl and/or alkyl succinimides formed from at least one alkenyl or alkyl succinic anhydride and at least one aliphatic amine having one or two primary amino groups in the molecule. These succinimides are characterized in that each alkenyl or alkyl group thereof contains in the range of 16 to 30 carbon atoms. Such group is bifurcated on its alpha carbon atom into two branches neither of which contains less than 2 carbon atoms, one such branch being free of any side chain, and the other such branch either being free of any side chain or containing at most one methyl or methylene side chain. In addition the succinimide has a viscosity at 80° C. of less than about 100 centistokes. These succinimides are especially useful as internal and external sizing agents for paper and paper products.
    Type: Grant
    Filed: June 24, 1999
    Date of Patent: May 1, 2001
    Assignee: Albemarle Corporation
    Inventors: Patrick C. Hu, Valerie N. LeGloahec
  • Patent number: 6222006
    Abstract: An aqueous formulation of a high solid content fully functional thermosettable wet strength resin designed for use in the manufacture of paper products is disclosed. The wet strength resin is the product of reaction of an epihalohydrin and an end-capped polyaminamide polymer. The thermosetting wet strength resins are useful in the manufacture of improved absorbent paper products such as bathroom tissues, facial tissues, napkins, towels, and paperboard products such as dairy cartons and bag paper.
    Type: Grant
    Filed: August 5, 1998
    Date of Patent: April 24, 2001
    Assignee: Fort James Corporation
    Inventors: Bruce Jerome Kokko, Elroy Wayne Post
  • Patent number: 6193838
    Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: February 27, 2001
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
  • Patent number: 6193844
    Abstract: A microparticle composition for paper making includes finely divided particles of a water insoluble solid such as amorphous sodium aluminosilicate, and having an anionic charge of at least 20 millivolts, and preferably from about 40 to 60 millivolts, and a particle size of less than about 0.1 microns.
    Type: Grant
    Filed: September 14, 1999
    Date of Patent: February 27, 2001
    Inventors: John R. McLaughlin, Paul G. Linsen
  • Patent number: 6193842
    Abstract: A is a process for preparing insulant boards based on mineral and paper fiber by slurrying mineral fiber, binder and customary additives in water, forming the insulant board by applying the slurry to a wire, and drying and consolidating the insulant board, which comprises using surface-active compounds to achieve faster and better drainage of the filter residues to be dried.
    Type: Grant
    Filed: August 5, 1997
    Date of Patent: February 27, 2001
    Assignee: Th Goldschmidt Ag
    Inventor: Manfred Schmuck
  • Patent number: 6171444
    Abstract: Compositions and methods are provided for the sizing of paper, to enhance the quality of images printed thereon. The novel sizing compositions contain as a sizing agent a mixture of a polyacid and a polybase. When applied to a paper substrate, such as in an internal or external sizing process, the sizing compositions result in a sized paper substrate that provides high quality printed images when printed with an ink containing a reactive dye having ionizable and/or nucleophilic groups capable of reacting with the sizing agent. Images printed on a paper substrate coated with the sizing compositions of the invention are bleed-resistant, water-resistant (e.g., water-fast), and/or are characterized by an enhanced chroma and hue.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: January 9, 2001
    Assignee: SRI International
    Inventor: Asutosh Nigam
  • Patent number: 6168686
    Abstract: A novel method of improving drainage rate and retention of fines which is effective in unfilled, newsprint-type furnish without a silica/bentonite-type particle is disclosed. The method comprises adding a cationic or amphoteric starch, and a cationic polyelectrolyte followed by the addition of a high molecular weight anionic polyacrylamide copolymer.
    Type: Grant
    Filed: August 19, 1998
    Date of Patent: January 2, 2001
    Assignee: Betzdearborn, Inc.
    Inventors: Frank J. Sutman, Richard A. Hobirk