Fat, Fatty Oil, Or Higher Fatty Acid Patents (Class 162/179)
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Patent number: 6444024Abstract: The present invention relates to a substantially water-free sizing composition, an aqueous sizing dispersion and a process for the production of paper and board. The composition or dispersion comprises a cellulose reactive sizing agent and a copolymer which is prepared from a monomer mixture comprising one or more olefins and one or more derivatives of unsaturated carboxylic acids. More specifically, the composition or dispersion comprises a copolymer prepared form a monomer mixture comprising one or more &agr;-olefins and one or more derivatives of &agr;,&bgr;-unsaturated dicarboxylic acids.Type: GrantFiled: December 16, 1999Date of Patent: September 3, 2002Assignee: Akzo Nobel NVInventors: Robert J. Mills, Jochen Hoffmann, Ralf Krückel, Albert Van Den Berg
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Publication number: 20020117280Abstract: A method and composition are disclosed for providing a two-part polymer binder additive for a fibrous sheet by improving both its strength and durability. The polymer binder comprises both the addition of a resin system and an anionic polymer which impart both increased strength and resistance to moisture and sagging. The resin system includes a polyamidoamine-epihalohydrin resin, a latex and an anionic polymer.Type: ApplicationFiled: July 27, 2001Publication date: August 29, 2002Inventors: Matthew Howle, Karl B. Himmelberger
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Publication number: 20020117278Abstract: The present invention provides a paper quality improver composition for papermaking, which is excellent in improved efficiencies of bulky value, brightness, opacity and the like of pulp sheet, demanded at lightening paper and increasing a blending amount of deinked pulp, even by adding a small amount thereof as well as which is further excellent in an improved efficiency of paper-strength. That is, the present invention provides a paper quality improver composition for papermaking; which comprises (A) a compound having lyotropic degree measured by a specific method of not less than 4% and satisfying at least two of (i) standard improved bulky value of not less than 0.02 g/cm3, (ii) standard improved brightness of not less than 0.5 point, and (iii) standard improved opacity of not less than 0.5 point and (B) a water-soluble polymer satisfying an average molecular weight and/or a viscosity thereof of specific value.Type: ApplicationFiled: December 19, 2000Publication date: August 29, 2002Inventors: Yasushi Ikeda, Takaaki Tadokoro, Hiromichi Takahashi
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Publication number: 20020112830Abstract: A process for increasing the tactile properties of a base web without adversely affecting the strength of the web is disclosed. In general, the process includes the steps of placing a base web in between a first moving conveyor and a second moving conveyor. The conveyors are then wrapped around a shear inducing roll which creates shear forces that act upon the base web. The shear forces disrupt the web increasing the softness and decreasing the stiffness of the web. The shear inducing roll typically has a relatively small diameter. In some applications, more than one shear inducing roll may be incorporated into the system.Type: ApplicationFiled: November 29, 2001Publication date: August 22, 2002Applicant: Kimberly-Clark Worldwid, Inc.Inventors: Andrew P. Bakken, Troy M. Runge, Kenneth J. Zwick
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Patent number: 6432269Abstract: A novel opacifying composition for use with alkaline paper which does not react with alkyl succinic anhydride, is provided. The opacifier comprises a mixture of an aromatic polymer, preferably a styrene acrylic polymer, and a stearamide which preferably comprises either a mono-stearamide or a di-stearamide of amino ethyl ethanol amine or both a mono-stearamide or a di-stearamide of amino ethyl ethanol amine. The opacifying composition comprises the opacifier and water. The water is preferably present in an effective amount to provide the opacifying composition in a liquid, emulsion form. Preferably the opacifier comprises from 5% to 60%, more preferably from 15% to 50% , most preferably from 30% to 40% aromatic polymer and preferably from 40% to 95%, more preferably from 50% to 85%, most preferably from 60% to 70% of the stearamide. A base is preferably present in an effective amount to provide the opacifying composition with a pH of from 7.5 to 11.0.Type: GrantFiled: June 12, 2000Date of Patent: August 13, 2002Assignee: Omnova Solutions Inc.Inventor: Louis Robert Dragner
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Publication number: 20020100567Abstract: A process for sizing paper comprising adding to an aqueous suspension containing cellulosic fibers, and optional fillers, an anionic or cationic sizing dispersion, and a sizing promoter comprising a cationic organic polymer having an aromatic group; and an anionic polymer having an aromatic group selected from step-growth polymers, polysaccharides and naturally occurring aromatic polymers, wherein the sizing dispersion and sizing promoter are added separately to the aqueous suspension.Type: ApplicationFiled: August 6, 2001Publication date: August 1, 2002Inventors: Erik Lindgren, Sten Frolich, Michael Persson
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Publication number: 20020096290Abstract: A process for sizing paper comprising adding to an aqueous suspension containing cellulosic fibers, and optional fillers, a sizing dispersion comprising a polymer having an aromatic group, and a sizing promoter comprising a polymer having an aromatic group, wherein the sizing dispersion and the sizing promoter are added separately to the aqueous suspension.Type: ApplicationFiled: August 6, 2001Publication date: July 25, 2002Inventors: Erik Lindgren, Sten Frolich, Michael Persson, Barbro Magnusson
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Publication number: 20020096294Abstract: The present invention refers to an aqueous sizing dispersion comprising a ketene dimer based sizing agent, wherein the sizing agent is obtained byType: ApplicationFiled: August 7, 2001Publication date: July 25, 2002Inventors: John Franklin Nicholass, Nicholas Stuart Morgan
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Publication number: 20020096291Abstract: A binder is applied to particles which are then combined with fibers to bind the particles to the fibers. The particles have functional sites for forming a hydrogen bond or a coordinate covalent bond. The fibers have hydrogen bonding functional sites. The binder comprises binder molecules, the binder molecules having at least one functional group that is capable of forming a hydrogen bond or a coordinate covalent bond with the particles, and at least one functional group that is capable of forming a hydrogen bond with the fibers. A substantial portion of the particles that are adhered to the fibers may be adhered in particulate form by hydrogen bonds or coordinate covalent bonds to the binder, and the binder in turn may be adhered to the fibers by hydrogen bonds. Fibers containing particles bound by this method are easily densified.Type: ApplicationFiled: May 3, 2001Publication date: July 25, 2002Applicant: Weyerhaeuser CompanyInventors: Michael R. Hansen, Richard H. Young
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Publication number: 20020096292Abstract: A binder is applied to particles which are then combined with fibers to bind the particles to the fibers. The particles have functional sites for forming a hydrogen bond or a coordinate covalent bond. The fibers have hydrogen bonding functional sites. The binder comprises binder molecules, the binder molecules having at least one functional group that is capable of forming a hydrogen bond or a coordinate covalent bond with the particles, and at least one functional group that is capable of forming a hydrogen bond with the fibers. A substantial portion of the particles that are adhered to the fibers may be adhered in particulate form by hydrogen bonds or coordinate covalent bonds to the binder, and the binder in turn may be adhered to the fibers by hydrogen bonds. Fibers containing particles bound by this method are easily densified.Type: ApplicationFiled: May 4, 2001Publication date: July 25, 2002Applicant: Weyerhaeuser CompanyInventors: Michael R. Hansen, Richard H. Young
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Patent number: 6419791Abstract: A novel method of opacifying paper, and a novel opacifier and opacifying composition which opacify as well as brighten paper, is provided. The novel opacifier comprises at least one diglyceride and at least one amino-ester compound. The opacifying composition comprises: solids and preferably water. The solids comprise opacifier and surfactant. Preferably, the opacifying composition is an emulsion of the solids in water.Type: GrantFiled: June 12, 2000Date of Patent: July 16, 2002Assignee: Omnova Solutions Inc.Inventor: Louis Robert Dragner
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Publication number: 20020088578Abstract: New and improved methods and products are disclosed relating to increasing the softness of paper sheets, without effecting their wetability. Increased softness, without loss of wetability is obtained by adding deactivated ketene dimer sizing agents to the sheet.Type: ApplicationFiled: April 27, 2001Publication date: July 11, 2002Applicant: Kimberly-Clark Worldwide, Inc.Inventors: David A. Jones, Nancy S. Clungeon
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Patent number: 6413370Abstract: A coated roll printing paper for printing with the cold-set offset-printing process is described, which gives a printing result comparable with that of low-weight coated matte grades. The paper is characterized by a high proportion of a fine calcium carbonate in the coating pigment, and a relatively low proportion of highly active binders.Type: GrantFiled: August 7, 2000Date of Patent: July 2, 2002Assignee: Haindl Papier GmbHInventors: Hartmut Wurster, Hans-Peter Hofmann
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Publication number: 20020074098Abstract: Modified condensation polymers containing azetidinium groups, such as polyamide epichlorohydrin (PAE) resins, can be combined with amphiphilic hydrocarbons containing polyethers into a single molecule to provide several potential benefits, depending upon the specific combination employed, including: (a) wet strength aids that impart softness; (b) softeners that do not reduce wet strength: (c) wet strength with improved wet/dry strength ratio; (d) surface feel modifiers with reduced linting and sloughing; (e) wet strength aids with controlled absorbency; (f) wet strength aids with controlled decay rate after wetting; and (g) Yankee dryer additives that provide surface protection and adhesion with controlled release properties.Type: ApplicationFiled: October 31, 2001Publication date: June 20, 2002Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Daniel Arthur Clarahan, Wen Zyo Schroeder
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Patent number: 6383336Abstract: A relatively soft, strong, opaque paper product and a process for making the same are provided. In particular, a tissue, or other paper product, is formed by incorporating into the product an alkylamide or alkylimide softening agent along with particulate fillers during a non-compressive tissue-formation process.Type: GrantFiled: December 14, 1999Date of Patent: May 7, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventor: Thomas G. Shannon
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Patent number: 6372087Abstract: Single-ply absorbent tissue paper wherein of the fibers incorporated in the web: (a) at least 20% by weight have a coarseness exceeding 23 mg/100 m; (b) at least about 20% by weight have a coarseness of less than about 12 mg/100 m; and (c) the weight average fiber coarseness to length ratio is less than about 8.5 mg/100 m/mm. The single-ply tissue having: a serpentine configuration; low sidedness; a basis weight of at least about 12.5 lbs. per 3000 square foot ream; specific total tensile strength between 40 and 200 g/3 inches/lb per 3000 square foot ream; a cross direction specific wet tensile strength between 2.75 and 20.0 g/3 inches/lb per 3000 square foot ream; an MD tensile to CD tensile ratio between 1.25 and 2.75; a specific geometric mean tensile stiffness between 0.5 and 3.2 g/inch/% strain per pound per 3000 square foot ream; a friction deviation less than 0.250; and a sidedness parameter less than 0.30.Type: GrantFiled: June 18, 2001Date of Patent: April 16, 2002Assignee: Fort James CorporationInventors: Frank David Harper, Taiye Philips Oriaran, John Dennis Litvay
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Patent number: 6368454Abstract: The present invention relates to a soft, thick, single-ply tissue and to a process for the manufacture of such tissue product having a basis weight of at least about 15 lbs./3,000 square foot ream and having low sidedness, said tissue exhibiting a specific total tensile strength of between 40 and 75 grams per 3 inches per pound per 3000 square feet ream, a cross direction specific wet tensile strength of between 2.75 and 7.5 grams per 3 inches per pound per 3000 square feet ream, the ratio of MD tensile to CD tensile of between 1.00 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 1.2 grams per inch per percent strain per pound per 3000 square feet ream, a ratio of product cross direction stretch to base sheet cross direction stretch of at least about 1.4, a friction deviation of less than 0.225, and a sidedness parameter of less than 0.275.Type: GrantFiled: January 18, 2000Date of Patent: April 9, 2002Assignee: Fort James CorporationInventors: John H. Dwiggins, T. Philips Oriaran, Frank D. Harper, Galyn A. Schulz
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Patent number: 6348132Abstract: Novel alkenyl succinic anhydride (ASA) compositions and the use thereof. The disclosed ASA compositions may be derived from maleic anhydride and olefins having desirable carbon chain lengths and double bond distributions. The present ASA compositions provide superior paper sizing properties.Type: GrantFiled: May 30, 2000Date of Patent: February 19, 2002Assignee: Hercules IncorporatedInventors: Jian Jian Zhang, Shiow-Meei Lai
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Patent number: 6346554Abstract: A natural gum is used to provide emulsification of alkenyl succinic anhydride (ASA) sizing agents for paper products. The natural gum can be nonionic, cationic, anionic, amphoteric, oxidized, derivatized or modified. The alkenyl succinic anhydride size emulsion formed with the natural gum improves stability and the film formed is evenly distributed, thereby promoting more uniform sizing of the paper product. The ratio of the ASA to natural gum in the emulsion ranges from 0.01:1 to 100:1, and preferably 0.1:1 to 20:1. The amount of ASA size is 1 lb./ton to 10 lbs./ton of finished paper product. A surfactant may be used to further improve the stability of the emulsion.Type: GrantFiled: January 18, 2001Date of Patent: February 12, 2002Assignee: Calgon CorporationInventors: Daniel R. Dostie, Roman J. Nowicki
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Patent number: 6346169Abstract: This invention is to provide a paper bulking promoter with which a highly bulky sheet can be obtained without impairing paper strength. Namely, this invention provides a process for producing a bulky paper, comprising the step of making paper from pulp in the presence of a bulking promoter comprising at least one compound selected from the group consisting of a cationic compound, an amine compound, an acid salt of an amine compound, an amphoteric compound, an amide compound, a quaternary ammonium salt, and an imidazoline derivative.Type: GrantFiled: December 31, 1998Date of Patent: February 12, 2002Assignee: Kao CorporationInventors: Yasushi Ikeda, Yoichi Ishibashi, Takaaki Tadokoro, Hiromichi Takahashi
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Patent number: 6340411Abstract: A densifying agent is applied to fibers in order to improve the densification properties of the fibers. The fibers have hydrogen bonding functional groups. The densifying agent are denser than the fibers to which the densifying agent is applied. The densifying agent can be organic or inorganic. The improved densification properties are observed without the presence of particles bound to the fibers or in the presence of particles that are not bound to the fibers. Softening agents can also be applied to the fibers in order to soften the fibers and articles including such fibers. Softening agents may be selected from the group of densifying agents.Type: GrantFiled: October 7, 1998Date of Patent: January 22, 2002Assignee: Weyerhaeuser CompanyInventors: Michael R. Hansen, Richard H. Young, Sr.
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Patent number: 6334931Abstract: The present invention relates to a soft, thick, single-ply tissue having a serpentine configuration and to a process for the manufacture of such tissue product having a basis weight of at least about 15 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.0 grams per 3 inches per pound per 3000 square foot ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 3.2 grams per inch per percent strain per pound per 3000 square foot ream, a friction deviation of less than 0.250, and a sidedness parameter of less than 0.30.Type: GrantFiled: December 11, 1997Date of Patent: January 1, 2002Assignee: Georgia-Pacific CorporationInventors: John H. Dwiggins, Ranga Ramesh, Frank D. Harper, Anthony O. Awofeso, T. Philips Oriaran, Galyn A. Schulz, Dinesh M. Bhat
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Publication number: 20010054491Abstract: The present invention relates to a method of manufacturing a paper of multi-colour ink-jet printable grade. A proper hydrophicity for the paper is secured by using an 2-oxetanone size in the appropriate sizing steps. The size is made from non-branched and branched-chain fatty acids having main chain comprising 6-22 carbons linked with each other by saturated bonds.Type: ApplicationFiled: July 2, 2001Publication date: December 27, 2001Inventors: Olof Malmstrom, Markku Nurminen, Raija Savolainen, Ari Teijo, Claes Zetter
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Patent number: 6331228Abstract: The present invention relates to a soft, thick, single-ply, printed, absorbent paper product having a Yankee side and an air side wherein the absorbent paper is printed on before or after embossing on the Yankee side, air side, or both sides, said absorbent paper exhibiting a serpentine configuration. This inventions also relates to a process for the manufacture of such absorbent paper product having a basis weight of at least about 12.5 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.0 grams per 3 inches per pound per 3000 square foot ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 3.2 grams per inch per percent strain per pound per 3000 square foot ream, a friction deviation of less than 0.Type: GrantFiled: May 10, 2000Date of Patent: December 18, 2001Assignee: Fort James CorporationInventors: Michael S. Heath, T. Philips Oriaran, Mark S. Siegel, Frank D. Harper, John H. Dwiggins
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Patent number: 6328849Abstract: The present invention relates to a soft, thick, single-ply tissue having a serpentine configuration and to a process for the manufacture of such tissue product having a basis weight of at least about 15 lbs./3,000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 75 grams per 3 inches per pound per 3000 square feet ream, a cross direction specific wet tensile strength of between 2.75 and 7.5 grams per 3 inches per pound per 3000 square feet ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 1.2 grams per inch per percent strain per pound per 3000 square feet ream, a friction deviation of less than 0.225, and a sidedness parameter of less than 0.275.Type: GrantFiled: June 18, 2001Date of Patent: December 11, 2001Inventors: John H. Dwiggins, Ranga Ramesh, Frank D. Harper, Anthony O. Awofeso, T. Philips Oriaran, Galyn A. Schulz, Dinesh M. Bhat
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Patent number: 6325893Abstract: A sizing agent for paper that is a 2-oxetanone ketene multimer which is not solid at 35° C., particularly a multimer mixture in which at least 25 weight percent of the hydrocarbon substituents contain irregularities such as branched alkyl groups or linear or branched alkenyl groups. Paper surface sized with the 2-oxetanone ketene multimer sizing agent and the method of surface sizing paper are also disclosed.Type: GrantFiled: November 8, 1999Date of Patent: December 4, 2001Assignee: Hercules IncorporatedInventors: Clement L. Brungardt, Richard J. Riehle, Jian Jian Zhang
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Patent number: 6306255Abstract: The invention relates to an aqueous disperion containing a cellulose-reactive sizing agent and an anionic hydrophobicailly modified cellulose-derivative, its preparation and use in the production of paper. The invention also relates to a substantially water-free composition containing a cellulose-reactive sizing agent and an anionic hydrophobicailly modified cellulose-derivative, its preparation and use in the preparation of an aqueous dispersion of cellulose-reactive sizing agent. The invention further relates to a process for sizing cellulosic fibers by addition of an aqueous sizing dispersion containing a cellulose-reactive sizing agent and a hydroically modified dispersing agent to a stock containing cellulosic fibers, and optional fillers, and dewatering the stock on a wire to obtain a web containing cellulosic fibers.Type: GrantFiled: May 15, 2000Date of Patent: October 23, 2001Assignee: Akzo Nobel NVInventors: Sten Frölich, Erik Lindgren, Rein Sikkar
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Patent number: 6299729Abstract: The present invention relates to a soft, thick, single-ply, printed, absorbent paper product having a Yankee side and an air side wherein the absorbent paper is printed on before or after embossing on the Yankee side, air side, or both sides, said absorbent paper exhibiting a serpentine configuration. This inventions also relates to a process for the manufacture of such absorbent paper product having a basis weight of at least about 12.5 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.0 grams per 3 inches per pound per 3000 square foot ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 3.2 grams per inch per percent strain per pound per 3000 square foot ream, a friction deviation of less than 0.Type: GrantFiled: May 10, 2000Date of Patent: October 9, 2001Assignee: Fort James CorporationInventors: Michael S. Heath, T. Philips Oriaran, Mark S. Siegel, Frank D. Harper, John H. Dwiggins
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Patent number: 6284099Abstract: Sizing dispersions of liquid reactive size are made by dispersing the reactive size as a neat liquid into a dispersion of bentonite or other anionic microparticulate material in water. These dispersions can be used for internal sizing, for instance wherein the dispersion is used as the anionic microparticulate stage in a microparticulate retention paper-making process, or they can be used for external sizing.Type: GrantFiled: August 21, 1998Date of Patent: September 4, 2001Assignee: Ciba Specialty Chemicals Water Treatments LimitedInventors: Peter Peutherer, Ian Mark Waring, Lesley Collett
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Patent number: 6280570Abstract: The present invention relates to a process of making a soft, thick, single-ply, absorbent paper in the form of a bathroom tissue, facial tissue, or napkin wherein the cellulosic fibers incorporated in the furnish comprise: (a) at least 20 percent by weight of the fibers in the web have a coarseness exceeding 23 mg/100 m; (b) at least about 20 percent by weight of the fibers in the web have a coarseness of less than about 1.2 mg/100 m; and (c) the weight average coarseness to length ratio of the fibers in the web is less than about 8.5 mg/100 m/mm having a serpentine configuration and to a process for the manufacture of such absorbent paper having a basis weight of about 15 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.Type: GrantFiled: September 29, 2000Date of Patent: August 28, 2001Assignee: Fort James CorporationInventors: Frank David Harper, Taiye Philips Oriaran, John Dennis Litvay
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Patent number: 6268414Abstract: Paper sizing compositions comprising (a) cellulose-reactive size, (b) dispersant system comprising primary anionic dispersant, and secondary dispersant selected from cationic and/or non-ionic dispersant, and (c) inorganic salt.Type: GrantFiled: April 16, 1999Date of Patent: July 31, 2001Assignee: Hercules IncorporatedInventor: Tingdong Lin
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Publication number: 20010009180Abstract: Method of processing pulp with a sizing agent, comprising adding to a cellulosic pulp, in a wet part of a paper making process, a sizing mixture of (a) rosin material and (b) an AKD sizing agent wherein at least a portion of the wet part of the paper making process is at a temperature of at least about 40° C.Type: ApplicationFiled: November 5, 1997Publication date: July 26, 2001Applicant: HERCULES INC.Inventors: MALCOLM JAMES WELCH, ANDREW MEARS
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Patent number: 6245197Abstract: A tissue paper of improved softness, strength and absorbency; and a manufacturing process for such a tissue paper where the generation of foam is reduced, or eliminated altogether. These are obtained using a tissue paper softener system comprising a substantially equimolar, ion-paired mixture of an anionic surfactant and a cationic quaternary ammonium compound, wherein the softener system is formulated such that the charge density of the anionic surfactant/cationic quaternary ammonium compound mixture will be about neutral.Type: GrantFiled: October 20, 1999Date of Patent: June 12, 2001Assignee: Fort James CorporationInventors: T. Philips Oriaran, Anthony O. Awofeso, Gary L. Schroeder, David W. White, Nga Thuy Luu, Bruce J. Kokko
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Patent number: 6238519Abstract: New and improved methods and products are disclosed relating to increasing the softness of paper sheets, without effecting their wetability. Increased softness, without loss of wetability is obtained by adding deactivated ketene dimer sizing agents to the sheet.Type: GrantFiled: November 18, 1998Date of Patent: May 29, 2001Assignee: Kimberly Clark Worldwide, Inc.Inventors: David A. Jones, Nancy C. Clungeon
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Patent number: 6231721Abstract: A highly densifiable wood pulp product is disclosed. In one embodiment, the densifiable product includes fibers having low coarseness, preferably having a fiber coarseness less than about 22 mg/100 m, and a densifying agent. In another embodiment, the densifiable product further includes fibers having coarseness greater than about 22 mg/100 m. Juvenile wood fibers are the preferred source of fibers having low coarseness. A densified pulp product formed by compacting a fibrous composite that includes fibers having a fiber coarseness less than about 22 mg/100 m, a densifying agent, and optionally, fibers having coarseness greater than about 22 mg/100 m is also disclosed. The pulp products can be advantageously incorporated into absorbent articles and can optionally further include superabsorbent material. Methods for forming the densifiable and densified fibrous products are also disclosed.Type: GrantFiled: October 9, 1998Date of Patent: May 15, 2001Assignee: Weyerhaeuser CompanyInventors: Robert H. Quick, Daniel M. Shellhammer, Michael R. Hansen, Richard H. Young, Sr.
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Patent number: 6231659Abstract: The sizing agents are mixtures of alkenyl succinic anhydrides in which the alkenyl groups have in the range of about 6 to about 40 carbon atoms, and in which at least 97 wt % of the alkenyl groups are bifurcated on the alpha carbon atom into two branches neither of which has less than two carbon atoms. Other characteristics of the mixture are that (1) 20-50% of the bifurcated alkenyl groups have only one methyl or methylene substituent and no other side chain, and the remainder of such bifurcated groups have two straight chain branches (no side chain) emanating from the alpha carbon atom, (2) at least 3 alkenyl succinic anhydrides that differ in the number of alkenyl carbon atoms are each present in at least 5 wt % in the mixture, (3) no more than about 50 wt % of the alkenyl succinic anhydrides is any given alkenyl succinic anhydride or mixture of isomers having the same number of carbon atoms in their alkenyl groups, (4) the average number of carbon atoms in the alkenyl groups is ca.Type: GrantFiled: June 24, 1999Date of Patent: May 15, 2001Assignee: Albemarle CorporationInventors: Patrick C. Hu, Valerie N. LeGloahec, Michelle R. Free, Dixie E. Goins
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Patent number: 6228217Abstract: This invention is directed to a process for preparing an aqueous papermaking suspension containing a polyelectrolyte complex comprising providing an aqueous suspension of pulp fibers containing a water-soluble cationic polymer and a water-soluble anionic polymer that are reactable in the aqueous suspension to form the polyelectrolyte complex, and a multivalent cation having at least a +3 charge, and forming the polyelectrolyte complex. It also includes the process wherein the aqueous suspension of pulp fibers contains surface active carboxyl compounds and water-soluble anionic compounds. It further includes the process wherein the aqueous papermaking suspension is sheeted and dried to obtain paper of improved strength.Type: GrantFiled: January 13, 1995Date of Patent: May 8, 2001Assignee: Hercules IncorporatedInventors: Jay A. Dickerson, Harry J. Goldy, Douglas C. Smith, Ronald R. Staib
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Patent number: 6228218Abstract: A water-disintegratable cleaning sheet consisting of a fibrous sheet having incorporated thereinto, a binder of alkylcellulose; an electrolyte, and (a) a copolymer of a polymerizable acid anhydride and other compounds and/or (b) an amino acid. The water-disintegratable cleaning sheet has excellent water disintegratability and wet strength and further it is not degraded in the water disintegratability and wet strength after storage at high temperatures.Type: GrantFiled: December 24, 1998Date of Patent: May 8, 2001Assignee: Uni-Charm CorporationInventors: Naohito Takeuchi, Takayoshi Konishi, Ryuichiro Kurata, Nobuo Morohashi, Masayoshi Matsumoto
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Patent number: 6207014Abstract: The invention concerns in particular a composition for a softening lotion used in fiber treatment. In the invention, the lotion composition is aqueous and liquid at a temperature of at least 5° C. and comprises, as active substances: (a) one or more saturated linear fatty alcohols having at least 16 carbon atoms, and (b) one or more waxy esters having a total of at least 24 carbon atoms. The application of the invention is to the manufacture of fibrous products such as disposable absorbent paper products.Type: GrantFiled: September 10, 1998Date of Patent: March 27, 2001Assignees: Fort James France, Sidobre SinnovaInventors: Christian de Haut, Benoit Abribat, Maria Da Silva Marques, Bruno Bret, Jean-Francois Leboeuf
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Patent number: 6193838Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.Type: GrantFiled: July 1, 1999Date of Patent: February 27, 2001Assignee: Fort James CorporationInventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
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Patent number: 6193842Abstract: A is a process for preparing insulant boards based on mineral and paper fiber by slurrying mineral fiber, binder and customary additives in water, forming the insulant board by applying the slurry to a wire, and drying and consolidating the insulant board, which comprises using surface-active compounds to achieve faster and better drainage of the filter residues to be dried.Type: GrantFiled: August 5, 1997Date of Patent: February 27, 2001Assignee: Th Goldschmidt AgInventor: Manfred Schmuck
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Patent number: 6179961Abstract: Strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels are disclosed. At least one surface of the tissue papers has uniform discrete surface deposits of a substantively affixed chemical softening mixture comprising a mixture of a quartenary ammonium compound, an emollient, and a sorbitan ester.Type: GrantFiled: October 8, 1997Date of Patent: January 30, 2001Assignee: The Procter & Gamble CompanyInventors: Jonathan Andrew Ficke, Kenneth Douglas Vinson
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Patent number: 6165319Abstract: The present invention relates to a soft, thick, single-ply, printed, absorbent paper product having a Yankee side and an air side wherein the absorbent paper is printed on before or after embossing on the Yankee side, air side, or both sides, said absorbent paper exhibiting a serpentine configuration. This inventions also relates to a process for the manufacture of such absorbent paper product having a basis weight of at least about 12.5 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting:a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.0 grams per 3 inches per pound per 3000 square foot ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 3.2 grams per inch per percent strain per pound per 3000 square foot ream, a friction deviation of less than 0.Type: GrantFiled: May 11, 1998Date of Patent: December 26, 2000Assignee: Fort James CorporationInventors: Michael S. Heath, T. Philips Oriaran, Mark S. Siegel, Frank D. Harper, John H. Dwiggins
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Patent number: 6165321Abstract: The invention relates to the sizing of substrates including paper, paperboard, wood and textiles, using an acetal sizing agent including 1,1-octadecoxyoctadecane, the distearyl acetal of stearyl aldehyde.Type: GrantFiled: April 27, 1999Date of Patent: December 26, 2000Assignee: Penford CorporationInventors: Edward P. Pauley, Katherine Sue Neighbor
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Patent number: 6162836Abstract: A process for preparing an aqueous dispersion of a higher fatty acid zinc salt which comprises adding a molten higher fatty acid to an aqueous dispersion of zinc oxide and reacting the higher fatty acid with the zinc oxide in the presence of a surfactant or a water-soluble polyvinyl alcohol with stirring while the aqueous dispersion is maintained at a temperature that is higher than the melting point of the higher fatty acid used.Type: GrantFiled: May 28, 1999Date of Patent: December 19, 2000Assignee: Nissin Kagaku Kenkyusho Co., Ltd.Inventor: Yasuo Kato
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Patent number: 6162328Abstract: There is disclosed a method for sizing paper by adding to the surface of the paper a sizing composition comprising cellulose reactive and cellulose non-reactive size. The sized paper performs better in ink jet printing than does paper that is the same except that the size composition contains only cellulose reactive size or only cellulose non-reactive size, when the printing is evaluated for at least one property selected from the group consisting of optical density, feathering, wicking, edge roughness and bleed. The sized paper also has higher toner adhesion, a higher coefficient of friction and a lower coefficient of friction bandwidth than does paper that is the same except that the size composition contains only cellulose reactive size. The paper is also capable of performing effectively in tests that measure its convertibility on state-of-the-art converting equipment and its performance on high speed end-use machinery.Type: GrantFiled: September 30, 1997Date of Patent: December 19, 2000Assignee: Hercules IncorporatedInventors: Marco Franco Cenisio, Edwin Rene Hensema, Andrew Mears, Daniel Felix Varnell
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Patent number: 6159339Abstract: Disclosed are a paper size consisting essentially of a) alkyl ketene dimer and/or alkenyl succinic acid anhydride; b) degraded, liquid cationic starch having a cationic charge density of 0.5 to 3.5 meqv/g, a degree of substitution of more than 0.1 and a viscosity of less than 10000 cps (30% by weight solution in water at 25.degree. C.); and c) water, and a process for making paper products in which this paper size is added to the pulp. The invention allows the production of AKD and/or ASA sizes on-site in paper plants using simple mixing equipment.Type: GrantFiled: August 19, 1998Date of Patent: December 12, 2000Assignee: BetzDearborn Inc.Inventors: Thord G. Hassler, Jurgen F. Schuetz, Bryan C. Smith
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Patent number: 6156387Abstract: The invention relates to a process for the thermomechanical surface treatment of flat webs of material, particularly those made of paper and carton, and to agents for performing said process. According to the process of the invention, adhesion between the flat web of material and the surface of the tool used in thermomechanical surface treatment, e.g., a roll or a press, is reduced or prevented by using an abhesive agent, which contains dicarboxylic dialkyl esters and/or diisoalkyl esters of C.sub.2 -C.sub.12 dicarboxylic acids with C.sub.1 -C.sub.13 n- and/or iso-alkanols as component with abhesive effect. The abhesive agent is preferably employed as an oil-in-water emulsion and is either applied to the surface of the tool used in said thermomechanical treatment or is added to the impregnating fluid or the paper coating mass or the moistening water or the steam in pre-moistening, or is applied to the paper web after the impregnating unit or directly before the smoothing roll.Type: GrantFiled: November 5, 1998Date of Patent: December 5, 2000Assignees: Stockhausen GmbH & Co. KG, Kaemmerer GmbHInventors: Joachim Werres, Bernd Reinhardt
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Patent number: 6156157Abstract: The invention relates to tissue products having improved softness properties and methods of making them. Specifically, improved softness is achieved by incorporating one or more softeners/debonders into the fiber furnish at the wet end of the tissue machine prior to formation, followed by a topical treatment with one or more softeners/debonders after the tissue web is dried. The result is a tissue product with added bulk and a smooth surface feel, both properties contributing to improved softness characteristics.Type: GrantFiled: April 21, 1997Date of Patent: December 5, 2000Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Wen Zyo Schroeder, Gary Vance Anderson, Duane Gerard Krzysik, Gary Lee Shanklin, Michael John Smith
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Patent number: 6153053Abstract: The present invention relates to a soft, thick, single-ply, absorbent paper in the form of a bathroom tissue, facial tissue, or napkin wherein the cellulosic fibers incorporated in the furnish comprise: (a) at least 20 percent by weight of the fibers in the web have a coarseness exceeding 23 mg/100 m; (b) at least about 20 percent by weight of the fibers in the web have a coarseness of less than about 1.2 mg/100 m; and (c) the weight average coarseness to length ratio of the fibers in the web is less than about 8.5 mg/100 m/mm having a serpentine configuration and to a process for the manufacture of such absorbent paper having a basis weight of about 15 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting:a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.Type: GrantFiled: April 15, 1998Date of Patent: November 28, 2000Assignee: Fort James CorporationInventors: Frank David Harper, Taiye Philips Oriaran, John Dennis Litvay