Specific Propping Feature (epo) Patents (Class 166/280.1)
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Patent number: 12104118Abstract: A composition includes a carbon dioxide (CO2) emulsion including a continuous critical or supercritical CO2 phase and a discontinuous phase including a polyacrylate. A method of making a CO2 emulsion includes providing a first solution of a polyacrylic acid and critical or supercritical CO2, providing a second solution of a base and critical or supercritical CO2, and mixing the first solution and the second solution such that the polyacrylic acid and the base react to form an emulsion of polyacrylate droplets in critical or supercritical CO2. A method of treating a hydrocarbon-bearing formation includes introducing an emulsion including a continuous CO2 phase and a discontinuous phase comprising a polyacrylate into the formation, contacting the emulsion with an aqueous reservoir fluid in the hydrocarbon-bearing formation, and absorbing an amount of the aqueous reservoir fluid into the polyacrylate of the emulsion to provide a dense CO2 emulsion.Type: GrantFiled: March 3, 2023Date of Patent: October 1, 2024Assignee: SAUDI ARABIAN OIL COMPANYInventors: Abdulaziz S. Al-Qasim, Yuguo Wang
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Patent number: 12083593Abstract: A 3D printed proppant includes a core having support bars extending from the core to a shell, the shell encapsulating the core and the support bars. Another 3D printed proppant includes a porous core and a shell encapsulating the porous core, where the porous core has a porosity from 25% to 75%. The 3D printed proppant has a particle size from 8 mesh to 140 mesh. The core, the support bars, the porous core, the shell, or combinations thereof includes metal, polymer, ceramic, composite, or combinations thereof. Additionally, a method for producing a 3D printed proppant is provided.Type: GrantFiled: July 1, 2021Date of Patent: September 10, 2024Assignee: Saudi Arabian Oil CompanyInventors: Mohammed Ali Ibrahim Sayed, Yanhui Han, Brent Cooper, Rajesh Saini
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Patent number: 12083492Abstract: The present invention relates to a synthetic filter material comprising grit, one or more oxides or hydroxides of Fe, La and/or Al, cement, fast-setting binder and water, which can serve as filter material for soil filters for phosphate adsorption, and to a process for producing the filter material.Type: GrantFiled: September 28, 2021Date of Patent: September 10, 2024Assignee: Polyplan-Kreikenbaum Gruppe GmbHInventor: Stefan Bruns
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Patent number: 11927086Abstract: A method of pumping an oilfield fluid from a well surface to a wellbore is provided that includes providing a clean stream; operating one or more clean pumps to pump the clean stream from the well surface to the wellbore; providing a dirty stream including a solid material disposed in a fluid carrier; and operating one or more dirty pumps to pump the dirty stream from the well surface to the wellbore, wherein the clean stream and the dirty stream together form said oilfield fluid.Type: GrantFiled: January 7, 2019Date of Patent: March 12, 2024Assignee: Schlumberger Technology CorporationInventors: Rod Shampine, Paul Dwyer, Ronnie Stover, Mike Lloyd, Jean-Louis Pessin, Edward Kent Leugemors, Larry D. Welch, Joe Hubenschmidt, Philippe Gambier, William Troy Huey, Thomas Allan
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Patent number: 11912933Abstract: The invention provides a suspension modifier directly added into fracturing fluid for real-time proppant modification during fracturing and the application thereof, relating to the field of oil and gas production technologies. The suspension modifier is a controlled release nanoemulsion and comprises surface hydrophobic modifier, surfactant, cosurfactant and water. The suspension modifier is directly added into clear-water or active-water fracturing fluid while the proppant is added into water. After stirring, the suspension modifier is capable of self-assembling and being adsorbed on the proppant surface, so that the proppant surface becomes hydrophobic and aerophilic. The invention no longer requires the proppant to be pretreated, and the bubble-suspended proppant can be obtained directly by adding the suspension modifier to the clear-water or active-water fracturing fluid, and meanwhile adding the proppant to the fracturing fluid.Type: GrantFiled: October 27, 2023Date of Patent: February 27, 2024Assignee: Chengdu University of TechnologyInventors: Bo Yang, Yu Liu, Hao Zhang, Di Yang, Min Ren, Yang Yang, Ying Zhong, Bin Yang, Jiping She
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Patent number: 11866643Abstract: A method for removing liquid buildup in gas wells may include introducing a first aqueous solution and a second aqueous solution into the wellbore such that the first aqueous solution and the second aqueous solution may intermix within the wellbore. The first aqueous solution may contain a nitrogen-containing compound and the second aqueous solution may contain a nitrite-containing compound and a foaming agent. The method may further include maintaining the intermixed solution in the wellbore such that gas, heat, and foam may be generated, and removing the excess fluid from the wellbore. Furthermore, the method may include introducing an acid or acid precursor into the wellbore, releasing an acid from the acid precursor into the intermixed solution, and maintaining the acid with the intermixed solution in the wellbore to adjusted the pH of the intermixed solution to less than 7.0.Type: GrantFiled: October 20, 2022Date of Patent: January 9, 2024Assignee: SAUDI ARABIAN OIL COMPANYInventors: Ali Abdullah M. Al-Taq, Abdullah A. Alrustum, Luai A. Alhamad, Hussain A. Al-jeshi
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Patent number: 11851614Abstract: A coated proppant having a proppant particle, an intermediate cross-linked terpolymer layer encapsulating the proppant particle, and an outer resin layer encapsulating the intermediate cross-linked terpolymer layer. The proppant particle is selected from sand, ceramic, glass, and combinations thereof. The intermediate cross-linked terpolymer layer includes styrene, methyl methacrylate, and divinyl benzene. The outer resin layer includes a cured epoxy resin formed from an epoxy resin and a curing agent.Type: GrantFiled: June 18, 2020Date of Patent: December 26, 2023Assignees: Saudi Arabian Oil Company, Alfaisal UniversityInventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
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Patent number: 11828725Abstract: Systems and methods wherein well-treatment fluids are evaluated for use in a subterranean reservoir. The systems and methods utilize quartz crystals configured to be quartz crystal microbalances (QCM). The QCM has a surface with a reservoir-specific material deposited on the surface. The reservoir-specific material is representative of formation material or proppant. Changes in mass of the reservoir-specific material are measured using the QCM. The changes reflect the interaction of the treatment fluid with the reservoir-specific material and/or hydrocarbons in the reservoir-specific material.Type: GrantFiled: December 18, 2019Date of Patent: November 28, 2023Assignee: Halliburton Energy Services, Inc.Inventors: Denise Nicole Benoit, I Wayan Rakananda Saputra, Antonio Recio, III, Kristina Henkel Holan
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Patent number: 11802231Abstract: Accordingly, this disclosure describes systems, compositions, and methods that may use pelletized diverting agent particulates for diversion, fluid loss control, and/or other subterranean treatments for controlling fluid flow in subterranean formations. In an embodiment, a method comprising: introducing a treatment fluid into a wellbore penetrating a subterranean formation wherein the treatment fluid comprises: a base fluid; a pelletized diverting agent comprising a degradable polymer, wherein the pelletized diverting agent at least partially plugs a zone in the subterranean formation; and diverting at least a portion of the treatment fluid and/or a subsequently introduced fluid away from the zone. In an embodiment, a treatment fluid comprising: a base fluid; and a pelletized diverting agent comprising a degradable polymer.Type: GrantFiled: December 29, 2022Date of Patent: October 31, 2023Assignee: Halliburton Energy Services, Inc.Inventors: Travis Hope Larsen, Larry Steven Eoff, Aaron Michael Beuterbaugh, Chris A. Lewis
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Patent number: 11767461Abstract: A method of treating a carbonate formation includes introducing a stimulation fluid into the carbonate formation at a pressure greater than a fracture pressure of the formation and creating openings in the carbonate formation via the stimulation fluid. Then, a fluoride salt solution, optionally including a proppant, may be introduced into the carbonate formation such that it at least partially penetrates into the openings. The fluoride salt may then be reacted with a carbonate surface in the carbonate formation to form fluorite on a surface of the formation thereby increasing a hardness of the carbonate formation.Type: GrantFiled: May 25, 2022Date of Patent: September 26, 2023Assignees: SAUDI ARABIAN OIL COMPANY, KING FAHD UNIVERSITY OF PETROLEUM & MINERALSInventors: Yevgeniy Samarkin, Murtada Saleh Aljawad, Theis Solling, Murtadha J. AlTammar, Khalid Mohammed Alruwaili
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Patent number: 11739258Abstract: Proppant particulates are commonly used in hydraulic fracturing operations to maintain one or more fractures in an opened state following the release of hydraulic pressure. In complex fracture networks, it can be difficult to deposit proppant particulates fully within the fractures. In addition, low crush strengths may result in problematic fines formation. Polyaromatic hydrocarbons, commonly encountered in various refinery process streams, may serve as an advantageous precursor to proppant particulates. Polyaromatic hydrocarbons may undergo crosslinking under acid-catalyzed conditions in an aqueous solvent in the presence of a surfactant to form substantially spherical particulates that may serve as effective proppant particulates during fracturing operations. In situ formation of the proppant particulates may take place in some cases.Type: GrantFiled: December 27, 2022Date of Patent: August 29, 2023Assignee: ExxonMobil Technology and Engineering CompanyInventors: Peter A. Gordon, Huaxing Daniel Zhou
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Patent number: 11739621Abstract: System, methods, and devices for simultaneously fracturing a target formation and an adjacent secondary formation are disclosed. The simultaneous fracturing operations interfere with each other to form in-situ dynamic barriers. The in-situ barriers prevent acid from the fracturing treatment in the target formation from invading the secondary formation and, in some instances, sealing formation rock at the location of the in-situ barrier to prevent or reduce water movement from the secondary formation into the primary formation.Type: GrantFiled: October 1, 2021Date of Patent: August 29, 2023Assignee: Saudi Arabian Oil CompanyInventor: Moataz Mohammad Alharbi
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Patent number: 11732179Abstract: Methods include pumping a fracturing pad fluid into a subterranean formation under conditions of sufficient rate and pressure to create at least one fracture in the subterranean formation, the fracturing pad fluid including a carrier fluid and a plurality of bridging particles, the bridging particles forming a bridge in a fracture tip of a far field region of the formation. Methods further include pumping a first plurality of fibers into the subterranean formation to form a low permeability plug with the bridging particles, and pumping a proppant fluid comprising a plurality of proppant particles.Type: GrantFiled: April 3, 2019Date of Patent: August 22, 2023Assignee: Schlumberger Technology CorporationInventors: Konstantin Vidma, Anna Dunaeva, Changsheng Xiang, Jazmin Godoy-Vargas, Mohan Kanaka Raju Panga, John Thomas Mayo, Dmitriy Usoltsev, Jacob Kariampally
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Patent number: 11618849Abstract: A treatment fluid and process for enhancing hydrocarbon production from a shale formation using a treatment fluid comprising a water soluble delayed release carbonate-dissolving agent and introducing the treatment fluid into the shale formation after or as part of a hydraulic fracturing process.Type: GrantFiled: June 15, 2017Date of Patent: April 4, 2023Assignee: CLEANSORB LIMITEDInventor: Ralph Edmund Harris
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Patent number: 11566170Abstract: Proppant particulates are commonly used in hydraulic fracturing operations to maintain one or more fractures in an opened state following the release of hydraulic pressure. In complex fracture networks, it can be difficult to deposit proppant particulates fully within the fractures. In addition, low crush strengths may result in problematic fines formation. Polyaromatic hydrocarbons, commonly encountered in various refinery process streams, may serve as an advantageous precursor to proppant particulates. Polyaromatic hydrocarbons may undergo crosslinking under acid-catalyzed conditions in an aqueous solvent in the presence of a surfactant to form substantially spherical particulates that may serve as effective proppant particulates during fracturing operations. In situ formation of the proppant particulates may take place in some cases.Type: GrantFiled: November 13, 2019Date of Patent: January 31, 2023Assignee: ExxonMobil Technology and Engineering CompanyInventors: Peter A. Gordon, Huaxing Daniel Zhou
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Patent number: 11555145Abstract: A method for stimulating production of hydrocarbons from a sandstone formation includes the steps of injecting a stimulation fluid formed from a hydrofluoric acid generating precursor and an oxidizing agent, an ammonium containing compound, and a nitrite containing compound into the sandstone formation, where one or both of the hydrofluoric acid generating precursor and the oxidizing agent comprise a degradable encapsulation. The method further includes maintaining the stimulation fluid, the ammonium containing compound, and the nitrite containing compound in the sandstone formation to initiate reaction and generate heat and nitrogen gas. Upon generation of heat and degradation of the degradable encapsulation, the hydrofluoric acid generating precursor and the oxidizing agent react to form hydrofluoric acid in-situ to dissolve silica and silicate minerals and stimulate the sandstone formation.Type: GrantFiled: February 26, 2021Date of Patent: January 17, 2023Assignee: Saudi Arabian Oil CompanyInventors: Ayman R. Al-Nakhli, Amy J. Cairns, Katherine Hull
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Patent number: 11486238Abstract: A deployment method and set of alternative tools for deploying, exchanging, and repairing an Electric Submersible Pump (ESP) and pipe strings utilizing a lubricator and standard pressure control equipment (valves, Blow Out Preventers); this method permits a rig less deployment of an ESP with well control maintained using a short length lubricator and standard pressure containment tools. This method defines a specific set of tools to be incorporated in the method to achieve the assembly of the ESP at surface and deployment in a single run to set the ESP at the pumping depth. This method facilitates the orientation and alignment of the terminals of the ESP motor and gauge and creates a pressure barrier through the ESP string during makeup and break out of the ESP.Type: GrantFiled: October 20, 2021Date of Patent: November 1, 2022Inventor: James R Wetzel
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Patent number: 11473008Abstract: A composition for fracking an unconventional reservoir including hard water and liquid carbon dioxide for in-situ generation of proppant particles. A method for fracturing a rock formation in an unconventional reservoir at high temperature and pressure conditions, including pumping the composition into the rock formation and precipitating calcite and aragonite crystals inside the rock formation.Type: GrantFiled: March 2, 2021Date of Patent: October 18, 2022Assignee: YPF TECNOLOGIA S.A.Inventors: Augusto Nicolás Varela, Remigio Ruiz, Paula Cecilia Dos Santos Claro
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Patent number: 11454098Abstract: A method for stimulating a well includes mixing at least one thermochemical with fracturing fluid to create a fracturing fluid mixture, injecting the fracturing fluid mixture into the well, creating an exothermic reaction with the fracturing fluid mixture, generating a pressure pulse in the well from the exothermic reaction, and fracturing a formation around the well with pressure from the pressure pulse and a hydraulic pressure source.Type: GrantFiled: May 20, 2020Date of Patent: September 27, 2022Assignees: SAUDI ARABIAN OIL COMPANY, KING FAHD UNIVERSITY OF PETROLEUM & MINERALSInventors: Ayman R. Al-Nakhli, Mohammed A. Bataweel, Mohamed Ahmed Nasr El Din Mahmoud, Abdulazeez Abdulraheem, Zeeshan Tariq
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Patent number: 11447690Abstract: A variety of systems, methods and compositions are disclosed, including, in one method, a method may comprise providing a proppant-free fracturing fluid; providing a proppant composition, wherein the proppant composition comprises proppant particulates and degradable thermoplastic particulates; introducing the proppant-free fracturing fluid into a subterranean formation at an injection rate above a fracture gradient to create or enhance at least one fracture in the subterranean formation; introducing the proppant composition into the at least one fracture; and allowing the proppant composition to form a proppant pack in the fracture, wherein the degradable thermoplastic particulates are degradable to generate voids in the proppant pack.Type: GrantFiled: May 17, 2021Date of Patent: September 20, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Loan K. Vo, Matthew Lewis Lahman
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Patent number: 11434718Abstract: A method includes pumping an agent in a well across a target formation zone with rocks containing soluble salt cement. The agent is injected into pore space within the target formation zone extending a radial distance from the well using pressure, and the agent is allowed to cure in the pore space. The method further includes taking a core of the target formation zone containing the cured agent.Type: GrantFiled: June 26, 2020Date of Patent: September 6, 2022Assignee: SAUDI ARABIAN OIL COMPANYInventors: Paul Joseph Tarabbia, Abdulmohsin Mansor
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Patent number: 11414971Abstract: A method of reducing lost circulation in a wellbore includes introducing a fluid including a fluid loss control additive comprising shape memory polymer, shape memory alloy, or both into the wellbore. The method further includes allowing the fluid loss control additive to lodge within fractures within a subsurface formation in the wellbore. The method further includes allowing the fluid loss control additive to expand within the fractures, thereby forming a barrier between the wellbore and the subsurface formation to reduce lost circulation in the wellbore.Type: GrantFiled: December 4, 2020Date of Patent: August 16, 2022Assignee: Saudi Arabian Oil CompanyInventors: Simone Musso, Sivaprakash Shanmugam
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Patent number: 11408264Abstract: Disclosed is a method for determining three-dimensional in-situ stress based on displacement measurement of borehole wall, including the following steps: pumping the prefluid and the sand-carrying fluid into the target interval, and injecting the biological oil displacement agent into the target interval in sequence; pumping temporary plugging agent into the target layer to implement crack plugging diverting; pumping the sand-carrying liquid into the target interval, and injecting the biological oil displacement agent into the target interval. The beneficial effect of the technical scheme proposed in this disclosure is: by injecting oil displacement agent to fracturing fluid, the temporary plugging diverting fracturing is integrated constructed with enhanced oil recovery, at the same time, it can overcome the incomplete removal of temporary plugging agent and the water lock effect of fracturing fluid caused by diverting fracturing.Type: GrantFiled: November 19, 2020Date of Patent: August 9, 2022Assignees: YANGTZE UNIVERSITY, JINGZHOU MODERN PETROLEUM TECHNOLOGY DEVELOPMENT CO. LTDInventors: Weichu Yu, Ying Zhang, Rui Li, Hui Zhao, Lei Zhang, Wenjie Xia, Pingtian Fan, Baocheng Wu, Wenming Shu, Fei Ding
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Patent number: 11407932Abstract: Polymers and fracturing fluid compositions including a base fluid, an effective amount of a hydratable polymer composition including one or more gel-forming hydratable polymers, a friction reducer composition including hydrolyzed or partially hydrolyzed hydrolyzable polymers and copolymers, a cross-linking composition in an amount sufficient to crosslink the one or more gel-forming hydratable polymers to form crosslinked structures within the fracturing fluid composition with or without a proppant and methods including combining an aqueous fluid and an oleaginous fluid to prepare an invert emulsion comprising a polymerizable composition, degassing the invert emulsion under an extensional flow regime through an elongated passageway of an extender and thereby removing oxygen to produce a degassed invert emulsion and compositions and methods including a hydratable additive concentrate comprising a hydratable additive that is at least substantially hydrated and a hydrating liquid, wherein the hydratable additiveType: GrantFiled: November 16, 2020Date of Patent: August 9, 2022Assignee: PfP Industries, LLCInventors: Asoke Kumar Deysarkar, Michael Joseph Callanan, Robert Ray McDaniel, Brian James Keola DeCaires, Nikhil Patel, Nathalie Rasolomiarantsoa, James Nguyen, Rajendra Ghimire, Madhukar Chetty
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Patent number: 11371314Abstract: Embodiments disclosed provide a pump assembly including a first pump for delivering at least one fluid. The first pump may include a first inlet coupled to the first pump for delivering at least one first fluid to the first pump, a second inlet coupled to the first pump for delivering at least one second fluid to the first pump, a first discharge coupled to the first pump for delivering the at least one first fluid at a first pressure, and a second discharge coupled to the first pump for delivering the at least one second fluid at a second pressure. In some embodiments, the first discharge and the second discharge are isolated from each other.Type: GrantFiled: March 10, 2017Date of Patent: June 28, 2022Assignee: Schlumberger Technology CorporationInventors: Jacques Orban, Shunfeng Zheng, Bartley Patton, Eric Erickson
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Patent number: 11371328Abstract: The invention discloses an integrated method for nitrogen-assisted carbon dioxide fracturing and development of shale oil reservoirs, comprising the following steps: fracture the target shale reservoir with nitrogen-assisted carbon dioxide; after fracturing, firstly inject carbon dioxide gas into the target shale oil reservoir, and then inject nitrogen gas to push the carbon dioxide gas into the further location of the oil reservoir; shut in the well in the target shale oil reservoir; after shut-in, open the well to implement depletion production; after the first cycle of production, the slug volume of the injected gas and the shut-in time are 1.5 times of those in the previous cycle in the subsequent production, and Steps 5 to 7 are repeated for each cycle.Type: GrantFiled: December 9, 2021Date of Patent: June 28, 2022Assignee: Southwest Petroleum UniversityInventors: Xiang Zhou, Qi Jiang, Yongchao Wang, Jie He, Chunsheng Yu, Siyuan Huang, Yang Zhang, Jiali Liu, Fangjie Wu, Guoqiang Tian
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Patent number: 11365340Abstract: Methods and compositions for modifying the rheological properties of non-aqueous fluids for treating subterranean formation are provided. In one or mom embodiment, the compositions comprise a non-aqueous fluid; a weighting agent; and one or more associative polymers that are capable of associating to form one or more supramolecular assemblies. In one or more embodiments, the methods comprise introducing a treatment fluid into a wellbore penetrating at least a portion of a subterranean formation, wherein the treatment fluid comprises a non-aqueous fluid and one or more associative polymers.Type: GrantFiled: June 6, 2019Date of Patent: June 21, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Jay Paul Deville, Hui Zhou
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Patent number: 11313211Abstract: A system and method of hydraulic fracturing a geological formation in the Earth crust, including providing fracing fluid through a wellbore into the geological formation, wherein the hydraulic fracturing includes complex shear fracturing.Type: GrantFiled: July 13, 2020Date of Patent: April 26, 2022Assignee: Shear Frac Group, LLCInventor: Wesley W. Johnson
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Patent number: 11299663Abstract: A method for treating a hydrocarbon-containing formation includes injecting an aqueous solution that contains an alkali nitrite, an ammonium halide, and a foaming agent into the formation, injecting supercritical carbon dioxide into the formation, allowing a portion of the carbon dioxide to dissolve in the aqueous solutions, causing the alkali nitrite and ammonium halide to react and generate nitrogen gas, and allowing a foam to form by the interaction of the nitrogen gas with the foaming agent.Type: GrantFiled: June 4, 2020Date of Patent: April 12, 2022Assignee: SAUDI ARABIAN OIL COMPANYInventors: Ali Abdullah Al-Taq, Zuhair AlYousif, Othman Alswaie
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Patent number: 11279801Abstract: Various embodiments disclosed relate to a silane-functionalized polyalkyleneimine (PAI) clay stabilizer for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include placing in the subterranean formation a silane-functionalized PAI clay stabilizer.Type: GrantFiled: October 16, 2015Date of Patent: March 22, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Tatyana V. Khamatnurova, Gladys Rocio Montenegro-Galindo, Denise Nicole Benoit
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Patent number: 11261688Abstract: An arrangement is for providing a flowable solidifier into a subsea hydrocarbon well comprising a valve assembly with an opening to a well bore. The arrangement has a connection device comprising a well control unit with a lubricator device with a first through opening, an inlet connector with an inlet for the flowable solidifier to a second through opening. The arrangement further has an elongated injection tubing with a third through opening. The injection tubing is adapted to be displaced through the lubricator device to a certain position enabling the third through opening to receive the flowable solidifier from the inlet of the inlet connector and extending into the opening of the valve assembly so that one or more valves of the valve assembly are shielded from interaction with the flowable solidifier.Type: GrantFiled: March 20, 2018Date of Patent: March 1, 2022Assignee: TIOS ASInventors: Per Buset, Darren Chalmers
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Patent number: 11254860Abstract: A method may comprise: introducing a treatment fluid into a wellbore penetrating a subterranean formation wherein the treatment fluid comprises a base fluid; a carbonate compound, wherein the carbonate compound at least partially plugs a zone in the subterranean formation; and an acid; and diverting at least a portion of the treatment fluid and/or a subsequently introduced fluid away from the zone.Type: GrantFiled: October 31, 2017Date of Patent: February 22, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Larry Steven Eoff, Aaron Michael Beuterbaugh, Travis Hope Larsen, Shoy George Chittattukara, Vishwajit Manajirao Ghatge, Antonio Recio, III
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Patent number: 11236599Abstract: The disclosure provides a method comprising of determining an injection flow rate for each one of a plurality of wells, determining a total injection flow rate for the plurality of wells, introducing sequentially a series of treatment fluids into a well bore of each one of the plurality of wells, wherein each of the well bores penetrates at least a portion of a subterranean formation, the series of treatment fluids comprising: a first treatment fluid that comprises a base fluid and a reactive agent; and a second treatment fluid that comprises a microproppant slurry, allowing the first treatment fluid to form one or more fractures in the subterranean formation, and depositing at least a portion of a microproppant in the microproppant slurry in at least a portion of the one or more fractures in the subterranean formation.Type: GrantFiled: January 8, 2020Date of Patent: February 1, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Ronald Glen Dusterhoft, Stanley V. Stephenson
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Patent number: 11208588Abstract: A method of dissolving a gas hydrate in a pipeline includes introducing a gas hydrate dissolving solution into the pipeline and allowing the gas hydrate dissolving solution to at least partially dissolve the gas hydrate in the pipeline. The gas hydrate dissolving solution includes a strong acid and a weak organic acid, and the strong acid expedites the reaction.Type: GrantFiled: November 5, 2020Date of Patent: December 28, 2021Assignee: Saudi Arabian Oil CompanyInventors: Mohammed Sayed, Rajesh Kumar Saini
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Patent number: 11149188Abstract: Treatment fluids and associated methods for treating a subterranean formation. An example method includes introducing a treatment fluid into a wellbore penetrating the subterranean formation. The treatment fluid includes an oleofuransulfonate surfactant; a treatment fluid additive capable of interaction with a cation; and an aqueous fluid. The cation is present in the treatment fluid or contacts the treatment fluid. The method further includes solvating the treatment fluid additive with the oleofuransulfonate surfactant.Type: GrantFiled: March 16, 2020Date of Patent: October 19, 2021Assignee: Halliburton Energy Services, Inc.Inventors: Antonio Recio, III, Janette Cortez, Hong Sun
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Patent number: 11125068Abstract: The present invention relates to a channel fracturing method with alternative injection of conventional and capsule-type soluble proppants. The method includes the following steps: injecting pad fluid into a wellbore to break a formation and form fractures in the formation; alternately injecting a sand-carrying fluid containing conventional proppant and a sand-carrying fluid containing capsule-type soluble proppant into the wellbore in sequence to support fractures in the formation and continue to fracture the formation; injecting displacement fluid into the wellbore to completely displace the sand-carrying fluids in the wellbore into the fractures. The conventional proppant of less dosage is used. The capsule-type soluble proppant is less difficult to be developed and its solubility is sensitive to the fracture closure, which is conducive to the quick flowback after fracturing.Type: GrantFiled: April 9, 2021Date of Patent: September 21, 2021Assignee: SOUTHWEST PETROLEUM UNIVERSITYInventors: Youshi Jiang, Yan Kou, Yongming Li, Zhibin He, Jing Jia, Wang Tang, Ang Luo, Bo Chen
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Patent number: 11111765Abstract: A well livening downhole tool for the in-situ production of nitrogen is provided. The well livening downhole tool may produce nitrogen in-situ in a well to lighten the fluid column and lift the well fluids. The well livening downhole tool may include sodium azide and other reactants to produce nitrogen and scavenge other reaction products to produce alkaline silicate and water. The well-livening downhole tool may include multiple modules each having nitrogen-producing reactants and ignition components such that each module may be activated independently to produce nitrogen at different depths. A process for lifting the well fluids using the well livening downhole tool is also provided.Type: GrantFiled: April 16, 2018Date of Patent: September 7, 2021Assignee: Saudi Arabian Oil CompanyInventors: Abdulrahman Abdulaziz Al-Mulhem, Mohammed Abdullah Bataweel
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Patent number: 11066915Abstract: Methods, systems, and controllers for detecting and mitigating well screen outs may include a controller configured to operate a fracturing pump to supply fluid at a discharge rate to a wellhead at a fracturing well site. The controller may also operate a blender positioned to deliver a blend of proppant and fluid to the fracturing pump. The controller may compare a fluid pressure increase rate to a preselected increase rate indicative of a potential well screen out. The controller may incrementally decrease the discharge rate of the fracturing pump and a flow rate of a blender when the fluid pressure increase rate of the wellhead exceeds the preselected increase rate and the fluid pressure is within a preselected percentage of a maximum wellhead pressure until the fluid pressure of the fluid supplied to the wellhead is stabilized.Type: GrantFiled: February 23, 2021Date of Patent: July 20, 2021Assignee: BJ Energy Solutions, LLCInventors: Tony Yeung, Ricardo Rodriguez-Ramon, Joseph Foster
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Patent number: 11060008Abstract: A date palm seed-based lost circulation material (LCM) is provided. A date palm seed LCM may be manufactured by drying date palm seeds and grinding the dried date palm seeds to create a plurality of particles. The particles may have sizes less than 4 mm, from 1 mm to 2 mm, or from 2 mm to 4 mm. The date palm seed LCM may have a volumetric swelling greater than an LCM formed from tree nuts and may have a volumetric swelling of at least 0.3 cubic centimeters per gram. The date palm seed LCM may have a D50 shift factor less than an LCM formed from calcium carbonate and may have a D50 shift factor of at least 0.38%. The date palm seed LCM may have a stability index of at least 0.95. Methods of lost circulation control and manufacture of a date palm seed LCM are also provided.Type: GrantFiled: September 12, 2019Date of Patent: July 13, 2021Assignee: Saudi Arabian Oil CompanyInventor: Md Amanullah
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Patent number: 11008506Abstract: Fracturing fluids and liquid concentrate proppant slurry compositions comprising high-density micro-proppants and low-density particulates in a single treatment fluid. The low-density particulates enhance the suspension of the high-density particulates resulting in improved vertical distribution and longitudinal transport and coverage in the complex fracture network. Methods of hydraulic fracturing using the disclosed fracturing fluids and liquid concentrate proppant slurries as well as methods of preparing liquid concentrate proppant slurries with improved storage properties, are provided.Type: GrantFiled: October 15, 2015Date of Patent: May 18, 2021Assignee: HALLIBURTON ENERGY SERVICES, INC.Inventors: Philip D. Nguyen, Janette Cortez
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Patent number: 10988674Abstract: Methods including introducing a first treatment fluid comprising a first aqueous base fluid and a chelating etching agent into a low-permeability subterranean formation comprising carbonate material having a first fracture network at a first treatment interval therein, wherein the first fracture network comprises a first main fracture and a first microfracture. The method further comprises placing the chelating etching agent in the first fracture network and reacting it with the carbonate material in the first fracture network. In certain embodiments, the reacting removes the carbonate material, thereby creating at least one conductive channel on a face of the first fracture network. The method further comprises introducing a second treatment fluid comprising a second aqueous base fluid and micro-sized proppant particulates into the low-permeability subterranean formation and placing the micro-sized proppant particulates into the first fracture network to form a partial monolayer in the first microfracture.Type: GrantFiled: May 1, 2015Date of Patent: April 27, 2021Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Ronald G. Dusterhoft, Jessica Lynn Heeter, Aaron M. Beuterbaugh, Enrique A. Reyes, Christopher R. Parton, Loan K. Vo
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Patent number: 10975660Abstract: The present invention relates to a downhole apparatus and a valve arrangement for a downhole apparatus having a tubular body having first and second ports in a wall thereof; and a method of operating a valve arrangement of a downhole apparatus. The valve arrangement has at least one locked configuration and the first port provides fluid communication with a tool or a device which is a sand control element having at least one fluid deformable device. The present invention also provides a method of setting a sand control completion, extending the sand control filter element thereof to a wellbore surface and isolating the reservoir from an upper portion of the wellbore.Type: GrantFiled: May 2, 2017Date of Patent: April 13, 2021Assignee: HALLIBURTON MANUFACTURING AND SERVICES LIMITEDInventors: Stephen Edmund Bruce, David Grant, Scott E. Wallace, Ewan Smith
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Patent number: 10975293Abstract: A method for treating a subterranean formation with a foamed acid system is disclosed. The method includes introducing a treatment fluid into the formation. The treatment fluid includes a first solution and a second solution. The first solution includes an ammonium containing compound and an acid. The second solution includes a nitrite containing compound. One or both of the solutions further include a foaming agent. The solutions are mixed within the formation to generate a nitrogen gas. The method further includes, allowing the compounds to generate nitrogen in the presence of the foaming agent to form a foam and generate the foamed acid system within the formation. The acid present in the foamed acid system reacts with soluble substances in the subterranean formation to increase permeability of the subterranean formation and enable enhanced production of reservoir fluids.Type: GrantFiled: July 24, 2019Date of Patent: April 13, 2021Assignee: Saudi Arabian Oil CompanyInventors: Ali Abdullah Al-Taq, Zuhair A. Al-Yousif
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Patent number: 10961833Abstract: A method for stimulating production of hydrocarbons from a sandstone formation includes the steps of injecting a stimulation fluid into the sandstone formation, the stimulation fluid formed from a hydrofluoric acid precursor and an oxidizer; injecting an ammonium containing compound into the sandstone formation; and injecting a nitrite containing compound into the sandstone formation. The method further includes maintaining the stimulation fluid, the ammonium containing compound, and the nitrite containing compound in the sandstone formation to initiate reaction of the ammonium containing compound and the nitrite containing compound to generate heat and nitrogen gas, where upon generation of heat within the formation the hydrofluoric acid precursor and the oxidizer react to form hydrofluoric acid in-situ to dissolve silica and silicate minerals and stimulate the sandstone formation.Type: GrantFiled: May 15, 2019Date of Patent: March 30, 2021Assignee: Saudi Arabian Oil CompanyInventors: Ayman R. Al-Nakhli, Amy J. Cairns
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Patent number: 10961440Abstract: A method for stimulating production of hydrocarbons from a sandstone formation includes the steps of injecting a stimulation fluid formed from a hydrofluoric acid generating precursor and an oxidizing agent, an ammonium containing compound, and a nitrite containing compound into the sandstone formation, where one or both of the hydrofluoric acid generating precursor and the oxidizing agent comprise a degradable encapsulation. The method further includes maintaining the stimulation fluid, the ammonium containing compound, and the nitrite containing compound in the sandstone formation to initiate reaction and generate heat and nitrogen gas. Upon generation of heat and degradation of the degradable encapsulation, the hydrofluoric acid generating precursor and the oxidizing agent react to form hydrofluoric acid in-situ to dissolve silica and silicate minerals and stimulate the sandstone formation.Type: GrantFiled: April 17, 2020Date of Patent: March 30, 2021Assignee: Saudi Arabian Oil CompanyInventors: Ayman R. Al-Nakhli, Amy J. Cairns, Katherine Hull
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Patent number: 10954430Abstract: Improved hydraulic fracturing compositions are disclosed which help reduce potential negative environmental impact by hydraulic fracturing. The disclosed compositions have flammability and toxicity and are relatively safe for the environment. The compositions may also contain biodegradable components.Type: GrantFiled: December 19, 2016Date of Patent: March 23, 2021Inventor: Courtney Gene Rogers
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Patent number: 10947443Abstract: Provided are compositions, methods, and systems that relate to use of viscoelastic surfactant gels in well perforation. A method for well treatment comprising: introducing a viscoelastic surfactant gel into a wellbore; and forming one or more perforation channels in an interval of the wellbore while the viscoelastic surfactant gel is disposed in the wellbore. A method for well treatment comprising: introducing a viscoelastic surfactant gel into a wellbore over an interval of the wellbore to be perforated; disposing a perforating gun into the wellbore such that the viscoelastic surfactant gel is disposed between the perforating gun and a casing of the wellbore; and forming one or more perforation channels in the interval of the wellbore. A downhole perforating system comprising: a perforating gun disposed at a distal end of a work string; and a viscoelastic surfactant gel.Type: GrantFiled: December 20, 2017Date of Patent: March 16, 2021Assignee: Halliburton Energy Services, Inc.Inventors: Jose Luis Carvalho Mota, William Walter Shumway
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Patent number: 10876044Abstract: A method of fracturing a subterranean formation wherein a silicate component and a silica precipitation agent are each mixed with the fracturing fluid. The fracturing fluid is introduced to a subterranean formation such that the fracturing fluid is allowed to precipitate silica and form micro-proppant particulates in situ in a microfracture. The silicate component can be selected from potassium silicate, sodium silicate and combinations thereof.Type: GrantFiled: December 20, 2016Date of Patent: December 29, 2020Assignee: Halliburton Energy Services, Inc.Inventors: Rajender Salla, Sairam Eluru, Sumukh Deshprabhu, Philip D. Nguyen
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Patent number: 10870791Abstract: Fracturing fluid compositions including a base fluid including a high TDS produced and/or flow back water, brackish water, RO reject water, clear brine, and mixtures thereof with or without added fresh water and systems, and methods for making and using same, where the method includes: (a) adding a first buffer to adjust the pH of a base fluid to an acidic pH, (b) adding a hydratable polymer or polymer slurry to the base fluid to form a hydratable polymer fracturing fluid, (c) adding a cross-linking composition to the hydratable polymer fracturing fluid to form a pre-cross-linked fracturing fluid, and (d) if needed, adding a second buffer to the pre-cross-linked fracturing fluid to adjust the pH of the pre-cross-linked fracturing fluid to form a viscosified fracturing fluid having a crosslinked structure.Type: GrantFiled: August 13, 2018Date of Patent: December 22, 2020Assignee: PfP Industries LLCInventors: Asoke Deysarkar, Nikhil Patel, Nathalie Rasolomiarantsoa, James Nguyen, Rajendra Ghimire, Michael J. Callanan, Robert McDaniel, Madhukar Chetty
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Patent number: 10844280Abstract: A coated article, such as a proppant, includes a base substrate and one or more polyurethane based coatings on an outer surface of the base substrate. The one or more polyurethane based coatings including the reaction product of an isocyanate component that has at least one isocyanate and an isocyanate-reactive component that has one or more simple polyols and one or more polyether monols at a ratio from 1:18 to 18:1. An isocyanate index is greater than 0.2 and less than 1.0.Type: GrantFiled: March 21, 2018Date of Patent: November 24, 2020Assignees: Dow Global Technologies LLC, DOW SILICONES CORPORATIONInventors: Sachit Goyal, Arjun Raghuraman, Kaoru Aou, Juan Carlos Medina, Lenin Petroff, James Young, Jr.