Abstract: Methods of subterranean cementing involving cement compositions comprising particulate foamed elastomers and associated methods are provided. In one embodiment, the methods comprise introducing a cement composition into a subterranean location, wherein the cement composition comprises a hydraulic cement, a particulate foamed elastomer, and an aqueous fluid; and allowing the cement composition to set in the subterranean location.

Abstract: Treatment fluid compositions may comprise transient polymer networks for use in methods related to subterranean applications. In one aspect, a method may include providing a treatment fluid comprising an aqueous base fluid and a transient polymer network, and placing the treatment fluid in a subterranean formation. In another aspect, a subterranean treatment fluid may include an aqueous-base fluid and a transient polymer network.

Abstract: The present disclosure is directed to compositions and methods that may be used for enhanced oil recovery, for modifying the permeability of subterranean formations and for increasing the mobilization and/or recovery rate of hydrocarbon fluids present in the formations. The compositions may include, for example, expandable cross linked polymeric microparticles having an unexpanded volume average particle size diameter of from about 0.05 to about 5,000 microns and a cross linking agent content of from about 100 to about 200,000 ppm of hydrolytically labile silyl ester or silyl ether crosslinkers and from 0 to about 300 ppm of non-labile crosslinkers.

Abstract: A self-healing cement for use in wells in which acid gases are injected, stored or extracted, comprises an acid-swelling material. In the event of cement-matrix failure, or bonding failure between the cement/casing interface or the cement/borehole-wall interface, the material swells when contacted by acid gases, including carbon dioxide and hydrogen sulfide. The swelling seals voids in the cement matrix, or along the bonding interfaces, thereby restoring zonal isolation. The acid swelling material may also be used without cement for remedial treatments to restore zonal isolation.

Abstract: A method for the treatment of a subterranean formation which contains sand particles, said method comprising contacting said formation with a positively charged polymer capable of increasing the residual matrix strength of said sand particles whereby to reduce or prevent their migration while minimizing any decrease in the permeability of said formation. Polymer materials suitable for use in the method of the invention include polyaminoacids, poly (diallyl ammonium salts) and mixtures thereof.

Abstract: Methods and compositions are provided that utilize pumice and various additives. An embodiment provides a method of remedial cementing in a subterranean formation comprising: providing a lightweight settable composition comprising pumice, a calcium activator, and water, wherein the lightweight settable composition has a density of less than about 13.5 pounds per gallon and is free of Portland cement; and using the lightweight settable composition in a remedial cementing method to seal one or more voids in a well bore. Also provided are pumice-containing remedial compositions and systems for remedial cementing.

Abstract: Downhole conditions in a wellbore may be monitored in real time by pumping into the well a sensing treatment fluid which includes a piezoelectric or piezoresistive material and measuring changes in electrical resistivity within the wellbore. The monitoring in real time of the piezoelectric or piezoresistive material enhances the integrity of the wellbore during the setting of the treatment fluid as well as during the lifetime of the well.

Abstract: The present invention relates to methods and compositions that can be used to delay crystallization of a treatment solution so that thief zones or fractures are plugged in subterranean formations at a substantial distance from a wellbore. A supersaturated sodium aluminate solution, or other solutions, is introduced into the reservoir. The solution is relatively stable in the supersaturated state. Crystallization, or de-stabilizing the solution, can be controlled, which in turn plugs the thief zone or fracture at a designed point of time. By controlling the time that crystallization starts, that is, the induction period, thief zones that are located at a substantial distant from the wellbore can be plugged.

Abstract: The method of the present invention deploys controlled electrolytic material, CEM, into the existing perforations to seal them and then using a bottom hole assembly, BHA, that isolates a portion of the wellbore to deliver a material that removes the CEM at a predetermined rate so that the BHA can be used to refracture the recently opened perforation. Additional new perforations can be made and fractured during the process.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a method of cementing in a subterranean formation, comprising: providing a set-delayed cement composition comprising water, pumice, hydrated lime, and a set retarder; activating the set-delayed cement composition; introducing the set-delayed cement composition into a subterranean formation; and allowing the set-delayed cement composition to set in the subterranean formation.

Abstract: A method for removing water from a wellbore fluid may include the steps of contacting a wellbore fluid with a water absorbing polymer, where the wellbore fluid includes an aqueous fluid, allowing the water absorbing polymer to interact with the wellbore fluid for a sufficient period of time so that the water absorbing polymer absorbs at least a portion of water in the aqueous fluid, and separating the water absorbing polymer containing the absorbed water from the wellbore fluid.

Abstract: A method for sealing a wellbore around a pipe placed within it is disclosed. The method includes providing to a wellbore site a pre-mixed pre-polymer sealant solution and storing the sealant until use. The sealant material may be injected into wellbore in the space exterior to the pipe so that the sealant material contacts at least some portion of the pipe exterior surface and the wellbore interior surface. Upon injection, the sealant material may begin to cure from contact with moisture in the ground, the curing causing the sealant material to release a gas and form a sealing foam into the extra-pipe space. The sealing foam may then be permitted to cure to form a flexible and stable seal.

Abstract: A well apparatus including a magnetic field source positioned in a borehole and a magnetorheological fluid that forms a barrier pill proximate to the magnetic field source where the barrier pill formation isolates one well zone from another well zone. The apparatus may be used to define a treatment or cementation zone. A method for utilizing the apparatus for creation or maintenance of a well includes introducing a magnetorheological fluid into a borehole, forming a downhole barrier pill by providing a magnetic field source proximate to the fluid, and isolating one well zone from another well zone.

Abstract: Light to ultra-light cement compositions with modified rheological properties. The cement composition includes cement, hydrophobic nano-silica, at least one additive and a sufficient amount of water to make a cement slurry with high compressive strength, low porosity, low free water, and low fluid loss with a quick thickening time.

Abstract: A cement composition: (a) a hydraulic cement; (b) water; and (c) an alkyl polyglycoside derivative, wherein the alkyl polyglycoside derivative is selected from the group consisting of: sulfonates, betaines, an inorganic salt of any of the foregoing, and any combination of any of the foregoing. A method comprising the steps of: (A) forming the cement composition; and (B) introducing the cement composition into the well. Preferably, the cement composition is foamed.

Abstract: A method of segregating flowable materials in conjunction with a subterranean well can include segregating flowable cement from a fluid by placing a flowable barrier substance between the cement and the fluid, and the barrier substance substantially preventing displacement of the cement by force of gravity through the barrier substance and into the fluid. Another method of segregating flowable materials can include flowing a barrier substance into a wellbore above a fluid already in the wellbore, and then flowing cement into the wellbore above the barrier substance. A system for use in conjunction with a subterranean well can include a flowable cement isolated from a fluid by a flowable barrier substance positioned between the cement and the fluid, whereby the barrier substance substantially prevents displacement of the cement by force of gravity through the barrier substance and into the fluid.

Abstract: The current invention relates to the use of chitin nanocrystals and chitin nanocrystal derivatives. More specifically, the present invention relates to the use of chitin nanocrystals and chitin nanocrystals used in oil and gas operations. The chitin nanocrystals and chitin nanocrystals derivatives can be used as additives to cement and wellbore fluids and can be used to inhibit corrosion in pipelines, on downhole tools and on other oil and gas related equipment.

Abstract: A method for manufacturing stable lightweight cement slurry in a continuous manner for downhole injection comprising the steps of manufacturing a foamed gas having desired density ranging from about 2.15 to about 2.35 lb/cubic ft. and utilizing foam stabilizing nonionic surfactant. And, an apparatus for carrying out the method.

Abstract: A cement slurry composition is described as having cement, water, and organic polymeric particles. The composition also includes non-ionic surfactants, which may contain ethoxylate groups or contain both ethoxylate groups and propyxlate groups in the hydrophilic part. The non-ionic surfactant acts to disperse the hydrophobic polymeric particles in the slurry and to reduce or prevent foaming. The cement slurry composition is prepared and then pumped into the subterranean well and placed in a zone of the subterranean well. Time is then allowed for the cement slurry composition to set into a solid mass in the zone.

Abstract: This invention relates to drilling a well, particularly an oil or gas well, where casing or liner will be installed to stabilize the wellbore. The present invention is intended to permit more drilling and longer lengths of casing or liner to be installed at one time. The present invention includes a combination of a smear tool and specially sized granular lost circulation material solids in the drilling mud which work together to close and seal leaking formations and fractures whether pre-existing or induced by drilling. By the natural collection of the inventive solids along with the conventional particles in the drilling mud to form a filter cake at the problem areas along the wall of the wellbore and the smear tool arranged to compress the filter cake into the problem areas, lost circulation is minimized. Maintaining circulation naturally allows for longer drilling cycles and potentially fewer liner joints in the well.

Abstract: The present invention provides for methods of treating a fluid loss zone in a wellbore in a subterranean formation including providing interlocking notched particulates having an outer face comprising at least one notch therethrough; wherein the at least one notch has a shape and an inner perimeter value; providing interlocking protruding particulates having an outer perimeter portion that protrudes in an approximate equivalent to the shape and value of the inner perimeter of the at least one notch; introducing the interlocking protruding particulates and the interlocking notched particulates into the wellbore in the subterranean formation; interlocking the interlocking protruding particulates and the interlocking notched particulates through the at least one notch to form an interlocking network of at least one interlocking protruding particulate and at least one interlocking notched particulate; sealing at least a portion of the fluid loss zone.

Abstract: Methods of treating a fluid loss zone in a wellbore in a subterranean formation including providing swellable particles having an initial unswelled volume, wherein the swellable particles upon swelling adopt a specific shape; introducing the swellable particles into the wellbore in the subterranean formation; and swelling the swellable particles so as to adopt a swelled volume beyond the initial unswelled volume; and sealing at least a portion of the fluid loss zone.

Abstract: Methods of subterranean cementing involving cement compositions comprising particulate foamed elastomers and associated methods are provided. In one embodiment, the methods comprise introducing a cement composition into a subterranean location, wherein the cement composition comprises a hydraulic cement, a particulate foamed elastomer, and an aqueous fluid; and allowing the cement composition to set in the subterranean location. In one embodiment, the particulate foamed elastomer may comprise polyurethane foam.

Abstract: A method for using or removing unused rock debris from a bored passageway through subterranean strata using at least one rock breaking apparatus engaged with a conduit string and placed within the subterranean passageway proximal region, using a member adapted to increase the volume of reduced particle size rock debris generated by increasing the frequency of impact and associated breakage of the rock debris inventory, per revolution of the conduit string and/or per volume of fluid slurry circulated. The used volume of rock debris inventory coats the unlined strata wall of said passageway to inhibit strata fracture initiation or propagation, and the unused rock debris inventory is urged from the passageway at an increased rate by the associated reduction in fluid slurry suspension or velocities needed to urge the rock debris through the unlined strata passageway of improved pressure integrity from inhibiting said initiation or propagation of strata fractures.

Abstract: Disclosed herein are cement compositions and methods of using set-delayed cement compositions in subterranean formations. In one embodiment a method of plugging a wellbore is described. The method comprises providing a set-delayed cement composition comprising pumice, hydrated lime, a cement set retarder, and water; activating the set-delayed cement composition to produce an activated set-delayed cement composition; introducing the activated set-delayed cement composition into the wellbore; and allowing the activated set-delayed cement composition to form a plug in the wellbore that has a permeability of less than 0.1 millidarcy.

Abstract: Mineral particles may provide for wellbore fluids with tailorable properties and capabilities, and methods relating thereto. Mineral particles may be utilized in methods that include introducing a wellbore fluid having a density of about 7 ppg to about 50 ppg into a wellbore penetrating a subterranean formation, the wellbore fluid comprising a base fluid and a plurality of mineral particles, and the wellbore fluid having a first viscosity; contacting at least some of the mineral particles with a linking agent so as to link the at least some of the mineral particles, thereby increasing the first viscosity to a second viscosity.

Abstract: An apparatus for controlling water ingress into a pipe useful in the production of hydrocarbons from underground reservoirs comprises a multi-layer tubular, the multi-layered tubular comprising an outer pipe layer, an inner pipe layer longitudinally aligned within the outer pipe layer, and a hydrophilic composite material between the outer pipe layer and the inner pipe layer. The composite comprises a material selected from the group consisting of sand, silt and clay and mixtures thereof. The composite material is non chemically reactive and has absorption properties such that the material swells in the presence of water but is non-absorptive of hydrocarbons. Upon exposure to water, composite material creates an impervious shield covering at least a portion of the inner pipe layer.

Abstract: Disclosed herein are cement compositions and methods of using set-delayed cement compositions in subterranean formations. An embodiment includes a method of cementing in a subterranean formation comprising: providing a cement composition comprising water, pumice, hydrated lime, a set retarder, and a strength enhancer, wherein the strength enhancer comprises at least one material selected from the group consisting of cement kiln dust, slag, amorphous silica, a pozzolan, and any combination thereof; introducing the cement composition into the subterranean formation; and allowing the cement composition to set in the subterranean formation.

Abstract: A cement composition comprises: cement; water; and an additive, wherein the additive is a pozzolan and a strength-retrogression inhibitor, and wherein a mixture consisting essentially of: the additive; water; and a source of calcium develops a compressive strength of at least 500 psi at a time of 24 hours, a temperature of 190° F., and a pressure of 3,000 psi. A method of cementing in a subterranean formation comprises: introducing the cement composition into the subterranean formation and allowing the cement composition to set. The compressive strength of the test cement composition consisting essentially of: the cement; the water; and the additive at a final time of 72 hours has a percent change greater than ?5% from the compressive strength of the test cement composition at an initial time of 24 hours when tested at a temperature of 300° F. and a pressure of 3,000 psi.

Abstract: Mixtures of fibers and solid particles are effective for curing fluid losses and lost circulation in a subterranean well. Stiff fibers are more effective than flexible ones; however, mixtures of stiff and flexible fibers have a synergistic effect. The quantity and particle-size distribution of the solids are optimized according to the stiffness, dimensions and concentrations of fibers.

Abstract: A system for blocking fast flow paths in geological formations includes preparing a solution of colloidal silica having a nonviscous phase and a solid gel phase. The solution of colloidal silica is injected into the geological formations while the solution of colloidal silica is in the nonviscous phase. The solution of colloidal silica is directed into the fast flow paths and reaches the solid gel phase in the fast flow paths thereby blocking flow of fluid in the fast paths.

Abstract: In some general aspects, methods for intersecting a first, cased well bore include drilling a second well bore that has a distal end proximal to the first, cased well bore to be intersected, disposing a mill guiding device in the second well bore near a casing of the first, cased well bore, the mill guiding device being configured to direct a mill of a milling assembly away from a central axis of the second well bore and towards the first, cased well bore, inserting the milling assembly into the second well bore, operating the mill of the mill assembly and guiding the milling assembly along the mill guide and into the casing of the first well bore, and removing material from the casing of the first well bore until the first, cased well bore and the second well bore are fluidly connected.

Abstract: The present invention relates to hollow hydrogel capsules. In various embodiments, the present invention provides a method of treating a subterranean formation with a hollow hydrogel capsule including a hydrogel shell including a hydrolyzed and crosslinked polymerized composition. The hollow hydrogel capsule also includes a hollow interior including at least one component of a downhole composition for subterranean petroleum or water well drilling, stimulation, clean-up, production, completion, abandonment, or a combination thereof. In various embodiments, the present invention provides compositions comprising the hollow hydrogel capsules and methods of making the hollow hydrogel capsules.

Abstract: A drilling fluid, spacer fluid and cementing compositions for use in subterranean wells are disclosed along with methods for making using same, where the compositions include a particulate weighted elastomeric composition system including at least one higher density weighting agent and at least one elastomer, where the higher density weighting agents have a density of at least 5.0 g/cm3 and conventional weighting agents, to produce compositions having a desired high density, while retaining other fluid properties such as pumpability, gas tight sealing, low tendency to segregate, and reduced high temperature cement strength retrogression.

Abstract: A method of treating a well the method including the steps of: (A) forming a fluid including: (i) a shear-thinning aqueous liquid phase; and (ii) an inorganic setting material; wherein the fluid is shear-thinning, pumpable, and settable; and (B) introducing the fluid into the well.

Abstract: A method of servicing a wellbore within a subterranean formation comprising providing a drill string disposed within the wellbore having one or more tubulars associated therewith and forming one or more annuli around the drill string; placing an insulating packer fluid comprising an aqueous base fluid and a viscosifying agent into at least one of the one or more annuli surrounding the drill string; and performing a drill stem test while the insulating packer fluid is in place. A method of servicing a wellbore within a subterranean formation comprising placing an insulating packer fluid in an annular space between a tubular and a marine riser extending from a surface vessel or platform and a subsea wellhead, wherein the insulating packer fluid comprising an aqueous base fluid and a viscosifying agent and has a thermal conductivity of from about 0.008 BTU/(hr·ft·F) to about 0.245 BTU/(hr·ft·F).

Abstract: A breaker fluid may include a base fluid; and an inactive chelating agent. A process may include pumping a first wellbore fluid comprising an inactive chelating agent into a wellbore through a subterranean formation; and activating the inactive chelating agent to release an active chelating agent into the wellbore.

Abstract: A lost circulation material and method for well treatment employing the material that is effective at sealing or plugging fractured zones and has utility over a wide range of temperatures, including high temperatures. The lost circulation material includes particulate material to quickly de-fluidize the fluid formulation, fibrous material to suspend particles in the slurrified form of the composition and increase the shear strength of the resultant seal, and non-Portland cement material for increasing the compressive strength.

Abstract: A composition of a packer fluid including biodiesel glycerin which can be used in deep and ultra-deep wells in environments containing CO2 and a process of using the same. This fluid may have a specific mass of at least 1.15 g/cm3, adequate viscosity for pumping at less than 2,000 cP and corrosive potential of up to 3 mm in 30 years. In addition, the packer fluid is compatible with the elastomers normally employed and does not degrade when exposed to temperatures lower than 100° C. The packer fluid is injected into an oil well as part of a well packer process.

Abstract: Cement compositions containing biowaste ash and methods of cementing in subterranean formations using such cement compositions. Examples of suitable biowaste ash include agricultural waste ash, municipal waste ash, waste-water treatment waste ash, animal waste ash, non-human-non-animal industrial waste ash, and combinations thereof.

Abstract: The present invention provides a method for selectively sealing a thief zone in a hydrocarbon reservoir located in a calcium-rich formation and penetrated by a borehole comprising injecting into the thief zone a sealing fluid comprising a mixture of and hydronium ions (H+) and a source of sulfate ions (SO42?) which mixture can provide precipitation of a designated calcium sulfate compound.

Abstract: The current application discloses methods and systems for generating high pressure dual phase mixture. In some embodiments, the methods and systems involve mounting a dual phase mixture generator on a transportable platform wherein the dual phase mixture generator comprises a mixing chamber connected with at least a first inlet, a second inlet, and a first outlet. A first container and a first pump are also mounted on the transportable platform wherein the first pump is operably connected with the first container. The transportable platform and the mounted equipments are then deployed at a wellsite. A base fluid is pumped into the first inlet under high pressure, and a gas is pumped into the second inlet under high pressure. The base fluid and the gas is combined in the mixing chamber to generate a high pressure dual phase mixture, which is then discharged via the outlet.

Abstract: The present invention provides a cement slurry composition, containing a hydraulic cement material, (A) a first water-soluble low molecular weight compound and (B) a second water-soluble low molecular weight compound differing from the compound (A), wherein a combination of the compounds (A) and (B) is (I) the compound (A) selected from cationic surfactants and the compound (B) selected from anionic aromatic compounds; or (II) the compound (A) selected from cationic surfactants and the compound (B) selected from brominated compounds, and in the compound (A), a ratio of compounds having a hydrocarbon group of 18 or more carbon atoms is not less than 45% by weight.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a method of treating a subterranean formation comprising: providing coated particles, wherein the coated particles comprise solid particles coated with an expandable coating; and introducing the coated particles into a permeable zone of the subterranean formation such that the coated particles form a barrier to fluid flow in the permeable zone. In another embodiment, a method of drilling a well bore may be provided, the method comprising: including coated particles in a drilling fluid, the coated particles comprising solid particles coated with an expandable coating; using a drill bit to enlarge the well bore; and circulating the drilling fluid past the drill bit.

Abstract: Fracturing operations can be problematic in completed wellbores containing at least one existing fracture, since it can be difficult to seal an existing fracture and initiate a new fracture within a reasonable timeframe due to the presence of particulate materials in the wellbore. Methods for fracturing a completed wellbore can comprise introducing a treatment fluid comprising a plurality of degradable sealing particulates into a completed wellbore penetrating a subterranean formation having an existing fracture therein; sealing the existing fracture with at least a portion of the degradable sealing particulates, thereby forming a degradable particulate seal; after sealing, allowing any degradable sealing particulates remaining in the treatment fluid to degrade, such that the treatment fluid becomes substantially particulate free; and after the treatment fluid becomes substantially particulate free, fracturing the subterranean formation so as to introduce at least one new fracture therein.

Abstract: A method of cementing a wellbore comprising preparing a wellbore cementing composition comprising a cementitious materials and a modified biopolymer additive wherein the modified biopolymer additive is the reaction product of a process comprising contacting a biopolymer and an organic carbonate to form a reaction mixture and subjecting the reaction mixture to a temperature of from about 100° F. to about 250° F. and placing the wellbore cementing fluid in the wellbore. A method of cementing a wellbore comprising contacting a modified biopolymer additive with a cementitious slurry to produce a wellbore cementing composition having an initial viscosity, v0; placing the wellbore cementing composition to a desired depth in a subterranean formation wherein the wellbore cementing composition has a transitional viscosity, vt, during placement in the subterranean formation and a final viscosity, vf, at the desired depth wherein vf?vt>v0; and allowing the wellbore cementing composition to set.

Abstract: In aspects, the disclosure provides a method for cementing a borehole that includes selecting a location in the borehole for cementing. The method further includes providing a cement slurry comprising a cement and shape memory members having a first shape, the shape memory members configured to expand from the first shape to a second shape upon application of heat to the shape memory members, placing the cement slurry in the selected space and heating the shape memory members in the selected space to attain the second shape.

Abstract: A method of servicing a wellbore in a subterranean formation comprising placing a first wellbore servicing fluid comprising a self-degrading diverter material into the wellbore wherein the self-degrading diverter materials comprises (i) a diverting material and (ii) a degradation accelerator; allowing the self-degrading diverter material to form a diverter plug at a first location in the wellbore or subterranean formation; diverting the flow of a second wellbore servicing fluid to a second location in the wellbore or subterranean formation; and removing the diverter plug, wherein the first and second wellbore servicing fluids may be the same or different.

Abstract: Method of treating a subterranean hydrocarbon-bearing formation comprising unconsolidated or poorly consolidated particulates, by contacting the formation with a solution or a dispersion of an organosilane which is a silylated polymer of formula (I): (RO)3-nRnSi-A-B-A-Si(OR)3-nRns??(I) wherein each R is independently a substituted or unsubstituted, alkyl group having from 1 to 6 carbon atoms, or a —C(O)R group where R is as hereinbefore defined; n is 0, 1 or 2; each A is a divalent organic radical; and B is a poly(oxyalkylene) linking group, a polyurethane linking group, or a poly(meth)acrylate linking group wherein the poly(oxyalkylene) linking group or the polyurethane linking group has a number average molar mass in the range of 600 to 20,000 g mol?1. The poly(meth)acrylate linking group has a number average molar mass in the range of 600 to 40,000 g mol?1.

Abstract: Water and gas flow into a subterranean reservoir may be reduced by pumping into the reservoir a multi-aldehyde crosslinking agent and a low molecular weight polyacrylamide capable of crosslinking with the crosslinking agent. The reaction product forms a gel plug impermeable to water and gas.