Directly Heated Chamber Patents (Class 202/99)
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Patent number: 5891310Abstract: The cycle time for a delayed coker unit is reduced by externally heating the coke drum near the junction of the drum shell and the supporting skirt thereof prior to beginning the hot coker feed fill step. This reduces the thermal stresses at the area around the welds of the drum skirt.Type: GrantFiled: June 20, 1997Date of Patent: April 6, 1999Assignee: Conoco Inc.Inventor: David K. Nelsen
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Patent number: 5824193Abstract: A method of thermally treating plastics material includes the steps of heating a treatment chamber at least to the melting point of at least a fraction of the plastic material, maintaining an oxygen level in the treatment chamber below combustion level of liquid or gaseous products from the plastic material, feeding the plastic material into the treatment chamber at a rate ensuring a built-up of a film of liquified plastic material on at least a part of the interior of the surface of the treatment chamber, with the liquified plastic material undergoing a transition into the gaseous phase as a result of the heating of the treatment chamber, and exiting of the gaseous phase out of the treatment chamber caused by vaporization pressure of the gaseous phase within the treatment chamber.Type: GrantFiled: March 27, 1997Date of Patent: October 20, 1998Inventor: Raymond S. Edwards
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Patent number: 5709779Abstract: A device for conveying waste includes a waste feed chute. A stationary conveyor pipe is connected to the waste feed chute and has a sealed-off end and a housing with a nonround cross section defining a longitudinal direction. A screw conveyor is disposed in the longitudinal direction of the conveyor pipe. A motor drives the screw conveyor. A pyrolysis reactor into which the conveyor pipe discharges, defines a first space between the housing of the conveyor pipe and the pyrolysis reactor. The pyrolysis reactor has an inlet end and a longitudinal axis about which the pyrolysis reactor is rotatable. An inlet tube in which the sealed-off end of the conveyor pipe is disposed, defines a second space between the inlet tube and the conveyor pipe. The inlet tube communicates with the inlet end of the pyrolysis reactor and has a smaller cross section than the pyrolysis reactor. At least one supply line leads from outside into the pyrolysis reactor.Type: GrantFiled: March 27, 1996Date of Patent: January 20, 1998Assignee: Siemens AktiengesellschaftInventors: Karl May, Hartmut Herm, Karlheinz Unverzagt
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Patent number: 5639353Abstract: An apparatus for the carbonization of materials, such as coal, comprising an elongated coking retort defined by an annulus which constitutes the coking chamber within which the coal is carbonized indirectly by conduction. In order to provide an efficient mechanism for transferring thermal energy to the coal by conduction, highly conductive tiles equipped with flues and adapted to transport hot flue gas makes up the walls of the annulus within which the coal is carbonized. The raw gas (discharged from carbonization) and the cooled flue gas (discharged from the flues) are collected and separately treated to prevent polluting emissions.Type: GrantFiled: September 4, 1996Date of Patent: June 17, 1997Inventor: Albert Calderon
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Patent number: 5616216Abstract: Process for treating industrial and/or urban waste comprising notably a drying stage, a waste thermolysis stage and a dechlorination stage by washing the solids resulting from the thermolysis.According to the invention, said thermolysis is achieved by direct contact of the waste with warm gases having a low oxygen content.The invention further relates to the plant for implementing the process.Type: GrantFiled: June 2, 1995Date of Patent: April 1, 1997Assignee: Institut Francais du PetroleInventors: Gerard Martin, Robert Gaulard
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Patent number: 5607556Abstract: This invention discloses a new method for the production of coke from coals. In the present invention, coke is continuously produced by heating a moving charge of coal inside the annular space between two tubes. The coking chamber, which includes a large tube and a smaller tube, is force-fed with a coal such as a metallurgical coal. The coal is bi-directionally heated along a controlled temperature gradient between the outer wall of the small tube and the inner wall of the large tube. The coal is transformed to coke as it travels through the annulus of the coking chamber. Coke is discharged from the chamber at the end opposite to which it was charged and is cooled before being exposed to the atmosphere. Gases generated during the coking process are collected and treated. All of these operations are accomplished in a closed system to prevent pollution.Type: GrantFiled: November 9, 1994Date of Patent: March 4, 1997Inventor: Albert Calderon
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Patent number: 5584969Abstract: A thermal decomposition apparatus for plastics wherein plastics are melted and thermally decomposed, and the resulting decomposition gas is cooled for condensation and recovered in the form of a thermal decomposition oil. The apparatus comprises a thermal decomposition reactor for melting and thermally decomposing the plastics therein, an extraneous matter discharge duct having one end opened in a melt of plastics within the reactor, an extraneous matter collecting container connected to the other end of the discharge duct, and an aspirator for aspirating extraneous matter within the reactor together with the melt through the discharge duct into the container.Type: GrantFiled: July 29, 1994Date of Patent: December 17, 1996Assignee: Hitachi Zosen CorporationInventors: Kenichi Nagai, Kenji Yasuda, Toshio Hama, Yoshitoshi Sekiguchi, Toshio Tachibana, Osamu Nakanishi, Tadashi Moriyama
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Patent number: 5547549Abstract: A vibrating bed pyrolysis system has a vibrating bed which is supplied with hot solid particles. Dry coal particles are rapidly heated by the hot solid particles to drive off hydrocarbon vapors. The vapors are condensed in a jet condenser, and products are flowed to a header tank. A portion of the liquid product is stored at room temperature for later use. A small portion of the liquid product is pumped from the header tank and cooled to ambient temperature and is sprayed in the jet condenser, which is positioned above the vibrating pyrolysis bed. A dryer bed vibrated by the same vibrating machine which vibrates the pyrolysis bed is supplied with hot solid particles and the crushed coal. Moisture in the coal particles is evaporated, and water vapors entrain coal fines before the coal particles are passed to the pyrolysis bed. The hot solid particles are taken from a fluidized bed combustor and are returned to the combustor with the coal char particles by entrainment into the gas lift system.Type: GrantFiled: June 2, 1995Date of Patent: August 20, 1996Inventor: Arthur P. Fraas
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Patent number: 5512070Abstract: A two stage carbonizer places as much heat as possible into the gas streams entering the carbonizer to drive off volatile matter and reduce tars and oils by thermal cracking which is enhanced by the addition of sorbent. The carbonizer operates as a fluidized bed with a combustor providing flue gas as one fluidizing medium and preheated air as the other. This allows the coal to be devolatilized and the tars and oils to be thermally cracked due to the direct contact with the coal and hot flue gas. The device is designed to operate at high pressures from about 12-20 atmospheres.Type: GrantFiled: February 16, 1995Date of Patent: April 30, 1996Assignee: The Babcock & Wilcox CompanyInventor: David A. Stats
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Patent number: 5505822Abstract: A process for treating industrial and/or urban waste includes the steps of drying the waste; effecting thermolysis of the dried waste by direct contact with warm gases, and washing solids resulting from the thermolysis with water to effect dechlorination thereof. Thermolysis is effected by direct contact of the waste with warm gases having a low oxygen content and water for washing the solids is obtained from condensation of vapors generated during drying of the waste A plant for treating industrial and/or urban waste includes a drier for drying the waste, a reactor for thermolyzing the waste, washing the solids from the reactor with water, such as from a condenser, to dechlorinate the solids, and a gas generator to generate warm gases, of which a part of the warm gases are used to heat the drier.Type: GrantFiled: July 9, 1992Date of Patent: April 9, 1996Assignee: Institut Francais du PetroleInventors: Gerard Martin, Robert Gaulard
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Patent number: 5387321Abstract: Apparatus and method for the pyrolysis of waste material which is not itself susceptible to heating by microwave radiation. The method comprises:(a) contacting the waste material, under an atmosphere wherein flame generation is substantially prevented, with a bed of pulverulent carbonaceous material (such as pulverised scrap tires) which is susceptible to heating by microwave irradiation; and(b) heating the pulverulent material by means of microwave irradiation so as to transfer thermal energy from the pulverulent material to the waste material and cause substantial pyrolysis of the waste material.Type: GrantFiled: January 27, 1992Date of Patent: February 7, 1995Inventor: Kenneth M. Holland
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Patent number: 5377220Abstract: An apparatus for drying moist or wet carbon particles in a series of tubular drying sections by electrical resistance heating where the current is introduced into the column of carbon particles through a graphite block positioned at the center of the top of the column and suspended above the top of the column by attachment to a steel plate that includes a flat or a V-shaped shelf and that is provided with openings to allow the moisture to escape in the form of steam, and wherein the section consisting of graphite block, carbon column, and steel plate may provide entry of the carbon into a second or into a sequential plurality of similar sections provided with similar graphite blocks similarly positioned.Type: GrantFiled: July 12, 1993Date of Patent: December 27, 1994Inventor: Cornelius J. du Plessis
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Patent number: 5368723Abstract: Waste plastics are heated so as to be thermally decomposed and produce a vapor product containing oil and gas components. The vapor product is brought into contact with a solid acid catalyst containing a hydrochloric acid as a decomposing activator to be cracked so as to recover a low boiling point hydrocarbon oil.Type: GrantFiled: February 10, 1993Date of Patent: November 29, 1994Assignee: Mazda Motor CorporationInventors: Toshiki Takahashi, Yoshio Tanimoto
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Patent number: 5296102Abstract: A method of and apparatus for recovering oil from solid hydrocarbonaceous terial, such as oil shale, in particulate form using a combustion chamber and a reaction chamber arranged side-by-side and connected by a first passageway extending between the upper regions of the chambers and a return passageway. The particulate material is fluidized in the chambers and induced to circulate therebetween by the configuration of the chambers and passageways and/or the nature of the fluidization. Residual carbon on the spent hydrocarbonaceous material introduced into the combustion chamber through the return passageway is burnt, heating the material which then circulates through the first passageway to mix with and heat fresh feed material introduced into the reaction chamber giving off effluent vapours which are collected and processed.Type: GrantFiled: July 25, 1991Date of Patent: March 22, 1994Assignee: Southern Pacific Petroleum NL and Central Pacific Minerals NLInventor: Donald J. Nicklin
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Patent number: 5240565Abstract: Apparatus for the production of charcoal by the comingling of a source of wood and ground sludge where the sludge is received from a paper making plant as wet sludge, grinding the wet sludge to a desired reduction, feeding the ground sludge into a furnace where it is comingled with wood, and circulating the furnace hot gas exhaust back through the grinding of the wet sludge to initiate the drying thereof.Type: GrantFiled: November 30, 1992Date of Patent: August 31, 1993Inventor: Robert M. Williams
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Patent number: 5104490Abstract: Apparatus for thermally decomposing municipal waste to produce condensable gases, char, and non-condensable gases has a vertically extending reaction chamber receiving the waste particles at the upper end, discharging char at the lower end, and receiving a hot gas at the lower end for upward flow through descending waste particles in the chamber. A dual function cone suspended at the upper end of the chamber receives the waste particles therearound, receives the gases therein and funnels the gases to a combined inlet-outlet having an inlet portion receiving a propelling air stream, an intermediate section communicating with the top of the cone and an outlet portion discharging the air and gases from the cone.Type: GrantFiled: October 25, 1988Date of Patent: April 14, 1992Assignee: W.E.R.E. International Inc. of IowaInventors: Glen Brinkman, Harold Massner, Richard J. Taeger
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Patent number: 5098481Abstract: Process and apparatus for near-zero discharge soil remediation, preferably in conjunction with an asphalt plant, comprising heating soil contaminated with up to about 30,000 ppm light hydrocarbons in an inclined, axially-fired rotating separator, and sampling the output soil to determine the remaining contaminants. If below 100 ppm (preferably 10 ppm) it may be reemplaced as clean fill. If it does meet D.O.T./CALTRANS standards and is below about 100 ppm it may be used as roadbed fill. If between about 1000 and 100 ppm and meets standards it may be used as aggregate, being mixed with hot oil to form asphalt. The separator offgases are condensed, the reclaimed liquid hydrocarbons separated and combined with the hot oil. The hot condenser offgases are supplied as secondary air to a main dryer, improving efficiency of operation. A dust/mud blow down system clears the heat exchange plenums with compressed air.Type: GrantFiled: March 6, 1991Date of Patent: March 24, 1992Assignee: Reed & Graham, Inc.Inventor: Kenneth J. Monlux
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Patent number: 5068010Abstract: An apparatus for removing oil, gas and by-products from pyrobituminous shale impregnated with hydrocarbons utilizes a vertically disposed reactor having a top portion, a middle portion and a bottom portion. As shale is introduced into the top portion of the reactor through a rotary seal mechanism, hot gasses are introduced into the middle portion of the reactor through hollow, parallel tubes having a hexagonal configuration with gas introducing holes disposed in the side walls which are protected by overhanging portions of the top walls. Relatively cool gasses are introduced into the bottom portion of the reactor through horizontally disposed circumferentially spaced pipes having downwardly and outwardly chamfered inner ends to prevent clogging of the pipes. The hot effluent gasses from the top portion of the reactor are passed through the cyclone, a heat regenerator for reducing the temperature of the gaseous stream and an electrostatic precipitator prior to being compressed.Type: GrantFiled: May 9, 1990Date of Patent: November 26, 1991Assignee: Petroleo Brasileiro S.A. - PetrobrasInventors: Rene Mundstock, Kuniyuki Terabe, Antonio R. Lamprecht, Joao C. Teixeira, Altair R. D. Batista, Edson d. Dias, Luiz D. Santos, Osvaldo Amorim, Joel Rezende, Jorge H. Filho, Joao C. Gobbo, Romeu Machado
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Patent number: 5034021Abstract: Apparatus is described for the pyrolysis of coal comprising a pyrolysis tower through which crushed coal and hot gas are counter-currently passed. The tower enables a controlled temperature profile to be maintained in the tower, and contains inner appurtenances which define cascading passageways to promote heat exchange and mixing of the coal with the hot gas. The coal volatiles are carried out of the top of the tower by the gas. The pyrolysis tower may be conjoined with a gasifier so as to most directly utilize the char residuals remaining after pyrolysis of the coal while they are still hot to more efficiently produce a hot synthesis gas, to be used to perform thermal pyrolysis in the tower.Type: GrantFiled: July 12, 1989Date of Patent: July 23, 1991Inventor: Reginald D. Richardson
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Patent number: 4948468Abstract: A retorting apparatus including a vertical kiln and a plurality of tubes for delivering rock to the top of the kiln and removal of processed rock from the bottom of the kiln so that the rock descends through the kiln as a moving bed. Distributors are provided for delivering gas to the kiln to effect heating of the rock and to disturb the rock particles during their descent. The distributors are constructed and disposed to deliver gas uniformly to the kiln and to withstand and overcome adverse conditions resulting from heat and from the descending rock. The rock delivery tubes are geometrically sized, spaced and positioned so as to deliver the shale uniformly into the kiln and form symmetrically disposed generally vertical paths, or "rock chimneys", through the descending shale which offer least resistance to upward flow of gas. When retorting oil shale, a delineated collection chamber near the top of the kiln collects gas and entrained oil mist rising through the kiln.Type: GrantFiled: February 22, 1989Date of Patent: August 14, 1990Assignee: The New Paraho CorporationInventors: Adam A. Reeves, Earl L. Mast, Melvin J. Greaves
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Patent number: 4944845Abstract: Apparatus for the treatment of a liquid hydrocarbon charge containing solids or solids-forming contaminants, e.g., inorganic solids, metals and asphaltenes, which includes a contactor vessel having a liquid charge inlet, a vaporizing media inlet above the charge inlet and a vapor-solids outlet. An atomizer is positioned in the charge inlet for forming small particles of the liquid charge and directing the particles of liquid in a substantially horizontal flat pattern into the contactor vessel. A premix downcomer having a dispersion grid positioned therein is located in the vaporizing media inlet for introducing a fluidized mixture of a gas dispersion media and hot circulating solid particles into the contactor vessel in a substantially vertical flat pattern to traverse the path of the liquid particles and intimately contact the liquid particles.Type: GrantFiled: July 3, 1989Date of Patent: July 31, 1990Inventor: David B. Bartholic
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Patent number: 4909237Abstract: A portable charcoal maker is disclosed for home use. The charcoal maker can also be used to start ordinary charcoal briquettes as well. The device consists of a tapered housing having a large cylindrical hopper placed on the top of the tapered housing. The device has a flared base for support. The junction of the flared base and the tapered housing forms a venturi that will accelerate the flow of air through the device. Up to two additional venturis can be added to the device by forming restrictions in the walls of the device. The additional venturis produce variable air pressures through the device which produce a high efficiency for combustion. Ordinary charcoal placed within the hopper will start and be ready for cooking in six to seven minutes, using only four pieces of newspaper to ignite the charcoal. To make charcoal, wood block are placed in the device and ignited.Type: GrantFiled: March 27, 1989Date of Patent: March 20, 1990Inventor: Walter Karpinia
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Patent number: 4867848Abstract: An apparatus and process for producing coke in a vertical furnace having an upper part for preheating and devolitalizing raw ovoids of coal, an electrically heated median part for carbonizing and coking the ovoids and a lower part for partially cooling the coked ovoids by counter current flow of recycled product gases recovered from the upper part of the furnace. A cooling chamber is connected to the lower part of the furnace for further cooling the coked ovoids by countercurrent flow of a portion of the recycled product gases which are withdrawn after flowing through the partially cooled coked ovoids and introduced into the upper part of the furnace to prevent condensation of condensibles contained in the product gases. The median part of the furnace may be electrically heated by electrodes, induction coils or a combination of electrodes and induction coils.Type: GrantFiled: June 15, 1987Date of Patent: September 19, 1989Assignee: Usinor AciersInventors: Jean A. G. Cordier, Bernard E. A. Dussart, Pierre H. Rollot
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Patent number: 4820382Abstract: A method for forming a terraced structure in the upper surface of a particulate solid bed, typically oil shale, moving upward through an upflow retort and removing particulate solids from the upper surface, which includes rotating a scraping means comprising a shaft having a plurality of scrapers secured thereto arranged in a vertically spaced-apart relationship and in a radially outwardly-stepped relationship relative to a vertical axis of the shaft.Type: GrantFiled: April 11, 1988Date of Patent: April 11, 1989Assignee: Union Oil Company of CaliforniaInventor: Delwin E. Cobb
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Patent number: 4786368Abstract: Oil shale is well mixed and efficiently, effectively, and economically retorted in a special gravity flow retorting process and system which utilizes novel arrangements of internal baffles in a static mixer.Type: GrantFiled: January 20, 1987Date of Patent: November 22, 1988Assignee: Amoco CorporationInventors: Earl D. York, Jay C. Knepper, John M. Forgac
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Patent number: 4752359Abstract: Active form coke is made from coal by passing the coal granulate downwardly through a preheating and pyrolysis zone, a heating zone, an aftertreatment zone and a cooling zone by moving respective grate bars of grates in each zone so that a bed of granules on one grate trickles uniformly onto the next lower grate. In the preheating, heating and aftertreatment zone CO.sub.2 or steam are passed through the beds by laterally introducing the gas at one side and withdrawing the gas on the opposite side of a respective bed.Type: GrantFiled: January 9, 1986Date of Patent: June 21, 1988Assignee: Perfluktiv Technik AGInventors: Erich Sundermann, Hanno Laurien, Hans Reye
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Patent number: 4743341Abstract: A pyrolysis chamber includes a bath of molten salt divided by a horizontally disposed baffle into an upper layer and a lower layer. Connected to one end of the chamber is a furnace including submerged burners for heating the salt and for maintaining it in its molten state. The molten salt flows from the furnace across the upper bath layer and back to the furnace in the lower layer. Hydrocarbon containing material is fed onto the upper bath layer and is pyrolyzed as it moves toward the discharge end of the chamber where the spent material is removed; the hydrocarbon gases being recovered by an exhaust system in the chamber. The molten salt acts as a seal between the atmospheres of the furnace and the pyrolysis chamber and also functions to remove pollutants from the combustion gases of the burners in the furnace.Type: GrantFiled: July 27, 1983Date of Patent: May 10, 1988Assignees: Harry S. Allen, John L. BuzziInventor: Kenneth W. Hladun
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Patent number: 4727657Abstract: An apparatus for contacting solids with gases, preferably a needle coke preheater, which includes an elongated housing having an entrance and an exit and means for introducing solids into the entrance of the housing. A bed support divides the housing into an upper chamber and a lower chamber and is declined from the horizontal at an angle such that the solids introduced into the entrance of the housing slide down the bed support toward the exit of the housing. The bed support contains a plurality of openings distributed between two solid rectangular borders which serve as the two long parallel sides of the bed support. The openings are sufficiently large so that gases can flow from the lower chamber in contact with the solids and then into the upper chamber. The solid rectangular borders prevent preferential flow of the gases up the walls of the housing by forcing the gases to flow toward the center of the bed support.Type: GrantFiled: May 29, 1986Date of Patent: March 1, 1988Assignee: Union Oil Company of CaliforniaInventor: Robert E. Miller
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Patent number: 4722768Abstract: Untreated coal is activated with steam at temperatures of 600.degree. to 950.degree. C. in a vibrating fluid bed, which is directly heated. The untreated coal is pre-dried by counter-current passage of the waste gases from the reaction either during feeding of the untreated coal or in the first part of the vibrating fluid bed trough. During the activation, secondary air can be passed in through a sparge pipe which is arranged parallel to the vibrating fluid bed trough. It is possible to carry out the heating exclusively with the supply of secondary air.Type: GrantFiled: April 22, 1986Date of Patent: February 2, 1988Assignee: Degussa AktiengesellschaftInventors: Ruediger Schirrmacher, Gisbert Semmerau
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Patent number: 4718984Abstract: An internally-fired vertical shaft kiln for calcining coke wherein a downwardly moving coke bed has a co-current preheat gas stream in the upper portion of the kiln and a counter-current combustion gas stream in the lower portion of the kiln. Both gases are removed at the midportion of the kiln. Combustion air is introduced to the kiln through an inclined grate at the bottom of the kiln which retains a layer of coke thereon for internal combustion. The calcined coke moves over the combusting coke layer on the grate and then through a passage to a cooling chamber where a gas stream is passed through the calcined coke for cooling. The gas stream heated in the cooling chamber can be used as the co-current gas preheat stream in the upper section of the kiln.Type: GrantFiled: July 18, 1986Date of Patent: January 12, 1988Assignee: Conoco Inc.Inventors: James R. McConaghy, Jr., Charles J. Swartz
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Patent number: 4670104Abstract: A process and system is provided to produce and dedust oil from oil shale and other types of solid hydrocarbon-containing material. In the process, raw oil shale is retorted, preferably with solid heat carrier material, to liberate an effluent product stream of hydrocarbons containing entrained particulates of dust derived from the oil shale or other solid hydrocarbon-containing material. A fraction of oil containing most of the dust is separated from the effluent product stream and fed to one or more dedusters. The dust-laden oil is dissolved in a special mixture of dedusting solvents which contains both polar and non-polar dedusting solvents. In the deduster, the dissolved oil is separated into a dedusted stream of oil and solvents and a residual stream of dust-laden sludge. Solvents are recovered from the dedusted stream as well as the sludge. The recovered solvents are recycled to the deduster for use in dedusting the oil.Type: GrantFiled: June 28, 1985Date of Patent: June 2, 1987Assignees: Standard Oil Company (Indiana), Gulf Oil Corporation (Pennsylvania)Inventor: James L. Taylor
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Patent number: 4652430Abstract: An apparatus for the multi-stage refining of organic bulk materials according to the fluidized bed principle comprising a plurality of horizontally aligned cells (23) including an upper drying chamber (1), a middle degasification chamber (2) and a lower refining chamber (3) separated from each other by an individual gas permeable floor (19) or a gas impermeable floor (20). Adjacent cells are connected to each other by common discharge/charge chutes having vertical separation walls extending therein.Type: GrantFiled: September 26, 1984Date of Patent: March 24, 1987Assignee: VEB Schwermaschinenbau "Karl Liebknecht" MagdeburgInventors: Wolfgang Michel, Heinz Paul, Dieter Kostler, Frank Wilhelm, Andreas Rummel, Gero Seher, Wilfried Henze, Ralf Hander, Jurgen Heinemann, Manfred Ossowski
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Patent number: 4619738Abstract: A cascading bed retorting process and apparatus in which cold raw crushed shale enters at the middle of a retort column into a mixer stage where it is rapidly mixed with hot recycled shale and thereby heated to pyrolysis temperature. The heated mixture then passes through a pyrolyzer stage where it resides for a sufficient time for complete pyrolysis to occur. The spent shale from the pyrolyzer is recirculated through a burner stage where the residual char is burned to heat the shale which then enters the mixer stage.Type: GrantFiled: August 2, 1984Date of Patent: October 28, 1986Assignee: The United States of America as represented by the United States Department of EnergyInventors: Arthur E. Lewis, Robert L. Braun, Richard G. Mallon, Otis R. Walton
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Patent number: 4606138Abstract: An apparatus for gas treating a particle bed wherein a uniform temperature gradient is achieved. A support member, such as a grate, serves to support a bed of particles on a surface thereof. The support member is moved in a predetermined direction. Gas is released from a plurality of positions at different depths in the bed.Type: GrantFiled: January 18, 1985Date of Patent: August 19, 1986Assignee: Phillips Petroleum CompanyInventor: Cecil C. Gentry
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Patent number: 4588478Abstract: An apparatus for a process for solar retorting of oil shale which comprises pyrolyzing fluidized ground oil shale particles by solar radiation in a retort, wherein said ground oil shale particles are provided in a state of continuous fluidization entrained in a gas and exposed to solar radiation focused through a transparent window, and retorted shale oil fines, gases, and shale oil are removed from the retort to separation and recovery.Type: GrantFiled: September 15, 1983Date of Patent: May 13, 1986Assignee: Phillips Petroleum CompanyInventor: F. Morgan Warzel
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Patent number: 4551206Abstract: A dry sealing leg apparatus is comprised of four chambers through which a moving bed of retorted shale particulates from an oil shale retort is passed serially: a surge chamber, a gas injection chamber, a seal leg chamber, and a gas disengaging chamber. In the gas injection chamber, a sealing gas penetrates the moving bed of shale and divides into two portions. One portion travels countercurrently to the shale through the surge chamber and enters the retort at a positive pressure to seal product gases therein. A second portion travels co-currently with the shale through the seal leg chamber and gas disengaging chamber and exits at a pressure less than that of the retort, having been reduced in pressure by resistance to its passage through the shale.Type: GrantFiled: January 4, 1984Date of Patent: November 5, 1985Assignee: Union Oil Company of CaliforniaInventors: Roland F. Deering, John H. Duir
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Patent number: 4523979Abstract: Retorted shale particles are recovered from a retort and delivered to a gas lift for transport to a fluidized combustor by passage, serially, through a sealing vessel, a crusher preferably operating at retort pressure, and a surge vessel. In the sealing vessel, a sealing gas is introduced, and after commingling with the shale, the gas passes countercurrently to the shale and enters the retort, thus sealing the retort gases in the retort while separating the retorted shale from the retort gases. Retorted shale from the sealing vessel is transported to a crusher, wherein the shale is reduced in size to that suitable for combustion under fluidized conditions. To prevent the crushed shale from packing, the shale is passed to a surge vessel, wherein the crushed shale is held as a fluidized bed, from which the crushed shale is continuously withdrawn at a regulated rate and introduced into the gas lift leading to the fluidized combustor.Type: GrantFiled: January 9, 1984Date of Patent: June 18, 1985Assignee: Union Oil Company of CaliforniaInventors: Roland F. Deering, John H. Duir
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Patent number: 4511434Abstract: A fluid bed system for retorting solid hydrocarbon-containing material, such as oil shale, coal and tar sands, in which solid hydrocarbon-containing material and heat carrier material are fed into a mixing chamber, mixed and rapidly transported upwardly by a lift gas through a lift pipe into a solids-containing vessel to retort the hydrocarbon-containing material with minimal thermal cracking of the liberated hydrocarbons to increase the recovery of condensable hydrocarbons. The retorted material can be conveyed to a dilute phase lift pipe and combustor vessel where carbon residue in the retorted material is combusted leaving hot spent material that can be fed into the mixing chamber as solid heat carrier material.Type: GrantFiled: September 27, 1982Date of Patent: April 16, 1985Assignee: Standard Oil Company (Indiana)Inventor: Iacovos Vasalos
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Patent number: 4505809Abstract: A process for extracting hydrocarbons from oil shale comprising the steps of subjecting oil shale under superatmospheric pressure in the presence of hydrogen and steam, to low temperature hydrogenating distillation; separating the resulting fluid distillation mixture into liquid and gaseous products; and returning water and hydrogen separated from the fluid distillation mixture to the low temperature distillation; in which:heat is drawn-off from the hot oil shale, after treatment in a low temperature hydrogenating distillation reactor, by the shale being sprayed wtih water whereby saturated steam is produced in decreasing pressure stages;the saturated steam of the pressure stages and water extracted during product separation are fed into the individual stages of a multi-stage compressor driven by a gas turbine, and are then delivered via a steam supply line to the reactor;the gas turbine is fuelled by supplying separated-off gaseous distillation products thereto; andthe exhaust gases of the gas turbine are feType: GrantFiled: October 31, 1983Date of Patent: March 19, 1985Assignee: Kraftwerk Union AktiengesellschaftInventors: Gerd Brunner, Rainer Hoffmann, Konrad Kunstle
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Patent number: 4501644Abstract: A staged retort is provided for the retorting of certain types of carbonaceous materials such as oil shale, coal or lignite, wherein the staged retort includes a number of separate retort chambers arranged in a modular configuration, with one retort chamber above the other, and mounted transversely within the staged retort. Each retort chamber is heated to a different temperature, and carbonaceous material is moved from a given retort chamber to a retort chamber having a higher temperature, whereby heavier fractions of liquid and/or gaseous hydrocarbons are formed as the carbonaceous materials undergo pyrolysis. Arrangements such as pressure regulating valves are provided to reduce mixing of the various fractions between the individual retort chambers to nearly zero, and conduits are provided to separately withdraw the hydrocarbon gases and/or liquids from each retort chamber.Type: GrantFiled: September 28, 1982Date of Patent: February 26, 1985Inventor: Delbert D. Thomas
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Patent number: 4495032Abstract: A shale oil retort apparatus is provided for retorting oil shale under airtight conditions. The retort apparatus employs a split hub wheel device which allows for the axial feeding of crushed oil shale and the axial dispensing of spent oil shale. The retort apparatus utilizes a rotatable shaft on a stationary axle, said shaft containing three spokes that are set approximately equidistant apart. The spokes serve to feed raw oil shale, dip it into a hot oil bath and dispense spent oil shale out of the apparatus.Type: GrantFiled: October 17, 1983Date of Patent: January 22, 1985Inventor: Carl G. Everman
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Patent number: 4475987Abstract: Fragile agglomerates with crushed rock fragments, such as fines which are subsequently agglomerated and which result in the crushing of rock fragments, such as oil shale prepared for retorting are mixed and delivered onto conveying means, such as a travelling grate by charging the rock fragments into a bin which delivers through a choke-feed onto the conveyor or travelling grate by introducing the agglomerates through a series of space conduits or tubes terminating inside the bin below the level of the lump material or fragments in the bin where the rock fragments have a downward travel such as to enable the aggregates to diffuse from the ends of the spaced pipes into and through the fragments and while so separated and diffused through the fragments move with the fragments onto the grate.Type: GrantFiled: December 29, 1982Date of Patent: October 9, 1984Assignee: Dravo CorporationInventor: Frank Forbes
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Patent number: 4466863Abstract: Devolatilizable fine-grained material which contains hydrocarbons is devolatilized by means of fine-grained solids which have been heated to temperatures of about 500.degree. to 1000.degree. C. The devolatilizable fine-grained material is mixed with the heated solids and is thus heated to temperatures of about 400.degree. to 900.degree. C. The mixture is passed through a dwell zone, and gaseous and vaporous devolatilization products are withdrawn and cooled. The heated solids are fed to the dwell zone as a loosened stream in a trickling and/or agitated state of motion, and the devolatilizable fine-grained material is introduced into said stream in order to be admixed thereto. The heated solids and the devolatilizable fine-grained material can be mixed in a weight ratio of 3:1 to 12:1. The stream of trickling heated soids can be deflected at least in part.Type: GrantFiled: June 13, 1983Date of Patent: August 21, 1984Assignee: Metallgesellschaft AktiengesellschaftInventors: Roland Rammler, Alfons Bussmann
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Patent number: 4465556Abstract: A process and system for continuously pyrolyzing organic feedstock produces a solid carbonaceous residue of controlled volatility, in a manner that is highly energy efficient. The value of the gaseous product and of the pyrolytic oil produced are also optimized.Type: GrantFiled: July 28, 1982Date of Patent: August 14, 1984Assignee: American Carbons, Inc.Inventors: Mack D. Bowen, Kenneth R. Purdy
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Patent number: 4461674Abstract: An oil shale retorting method and apparatus moves a bed of oil bearing shale particles along a generally horizontal path and passes through the bed at spaced points a plurality of discrete nonoxidizing gas streams heated to different oil educting temperatures to vaporize and educe different weight fractions of oil from the kerogen in the shale into the gas streams. Preferably the heated gas streams are also passed through the moving shale bed upstream from distillation of the volatile oil constituents to preheat the shale particles and condense the educted oils which become suspended as stable mists and are mechanically separated from the gas streams. Heat energy is preferably removed from the spent shale particles of the moving bed by burning them with combustion air downstream from the retorting sites, and such heat energy is transferred to the nonoxidizing streams to raise them to different oil educting temperatures before they are passed through the moving bed to educe oil from the shale particles.Type: GrantFiled: September 22, 1982Date of Patent: July 24, 1984Assignee: Allis-Chalmers CorporationInventors: Bobby P. Faulkner, Michael H. Weinecke
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Patent number: 4459136Abstract: An apparatus for drying, pyrolyzing and possibly also gasifying of lump wood in a cylindrical vessel with a hearth case includes a vessel of a type which differs from prior art vessel units by a top cooling hood with an annular cooling duct and an outer annular air space for preheating suction air and an inner, likewise annular, gas space to discharge to some external destination the gas recovered from the predried wood. The air drawn from the outer annular space is fed to the hearth via an air chamber and nozzles. Condensate precipitated on the inside faces of the hood drops into an annular gutter and is subjected to evaporation in the further course of the process. A method for operating this apparatus is also provided.Type: GrantFiled: August 4, 1982Date of Patent: July 10, 1984Assignee: Fritz Werner Industrie-Ausrustungen GmbHInventors: Hans Linneborn, Josef Weisz
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Patent number: 4447297Abstract: The present invention is directed to a combined fluidized bed retorting and combustion system particularly useful for extracting energy values from oil shale. The oil-shale retort and combustor are disposed side-by-side and in registry with one another through passageways in a partition therebetween. The passageways in the partition are submerged below the top of the respective fluid beds to preclude admixing or the product gases from the two chambers. The solid oil shale or bed material is transported through the chambers by inclining or slanting the fluidizing medium distributor so that the solid bed material, when fluidized, moves in the direction of the downward slope of the distributor.Type: GrantFiled: April 14, 1982Date of Patent: May 8, 1984Assignee: The United States of America as represented by the United States Department of EnergyInventors: Jer-Yu Shang, John E. Notestein, Joseph S. Mei, Li-Wen Zeng
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Patent number: 4431483Abstract: An apparatus for distilling shale oil from oil shale, which comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communicating with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling cType: GrantFiled: March 24, 1982Date of Patent: February 14, 1984Assignee: Nippon Kokan Kabushiki KaishaInventors: Takeyoshi Shishido, Yoshio Sato
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Patent number: 4409068Abstract: Combustion gas such as air, oxygen-enriched air or oxygen is introduced at an intermediate level in a vertical shaft kiln for the calcining of petroleum coke using a plurality of radially disposed combustion gas injectors. The injectors include means for circulating coolant around the periphery of the injector so that common metals may be used in the high temperature (above 2000.degree. F.) environment of the shaft kiln.Type: GrantFiled: June 14, 1982Date of Patent: October 11, 1983Assignee: Conoco Inc.Inventors: Richard L. Davis, Harlan G. Graf, Don L. Edwards
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Patent number: 4407701Abstract: Apparatus for treating gases produced from the conversion of coal, e.g., from carbonization of coal, to remove the undesirable constituents thereof is disclosed. The method involves passing the hot raw gases from the coal conversation process over a coke bed at a temperature of more than 1100.degree. K. The coke bed is located in the coal gasification reactor and is provided with an ordinary air supply. The subject method achieves a significant reduction in undesirable constituents in the gas and eliminates the need for auxiliary gas treatment systems, oxygen production systems and the like.Type: GrantFiled: August 2, 1982Date of Patent: October 4, 1983Assignee: Didier Engineering GmbHInventors: Dietrich Wagener, Horst Fach, Peter Sauder, Otto Abel