Abstract: Described is a process for preparing a three-dimensional article of a lyotropic polymer comprising the steps of (a) forming a shaped article of a liquid crystalline solution of a lyotropic polymer; (b) washing the shaped article with a washing fluid under conditions sufficient to reduce the solvent content of the article to less than about 2,000 parts per million, wherein the dimensions of the washed article are no less than 0.05 inches by 0.05 inches by 0.05 inches. Such articles are useful for many applications, particularly those requiring fire- and/or heat-resistance.

Abstract: An apparatus for de-silvering a silver-containing solution, comprises a plurality of electrolysis cells (10, S1, S2) each having an anode (20, 120, 220) and a cathode (30, 130, 230). A master cell (10) further comprises a reference electrode (45). The remaining cell or cells constitute slave cells (S1, S2). Control means (41) adjust the cathode potential applied to the slave cells (S1, S2) in response to the current flow (I.sub.M) through the master cell (10). The apparatus is particularly suitable for de-silvering large volumes of silver-containing solution, without the use of high currents.

Abstract: A leaching device for electrolyzed silver comprising a pair of silver electrodes an electrolysis power source for applying a DC electrolyzing voltage between both of the electrodes, a power source control circuit for ON/OFF control of the electrolysis power source, a current control circuit for controlling the electrolyzing current flowing between both of the electrodes thereby controlling the leaching amount of silver, a polarity switching circuit for switching the polarity of the electrolyzing voltage, a driving circuit for driving the polarity switching circuit, and an abnormality sensing circuit that senses the abnormality of the silver electrode based on the change of an electric current flowing to the silver electrode.

Abstract: An electrochemical system for the recovery of metals from metal ores in which reactions are carried out in separate anode and cathode tanks with the liquid product from the anode tank being separated and purified before being returned to the cathode tank for metal deposition. The separation includes thickening such as liquid solid separation with the liquid proceeding to the cathode tank. A reaction stage may be included before the thickening stage. Purification may include removal of impurities, adjustment of chemical and physical conditions and the addition of cathode reaction enhancers.

Abstract: A material handling device for reducing spillage of flowable or particulate material dispensed into a storage bin, the device comprising an upper region defining a first opening for receiving such material and a pair of discharge members extending in a direction opposite the first opening. The device is particularly suited for placement over a horizontal support rod from which the bin is typically suspended from. The device finds wide use in electroplating applications providing methods of maintaining a uniform arrangement of bins in an electroplating tank, and methods of protecting hardware utilized for suspending bins from electroplating tank support rods.

Abstract: A cleaning system for electrolytic tanks consisting of a cell with a preferably rectangular layout, very long relative to its width, and which is provided with at least one conduit with perforated walls, and preferably two, which run over the bottom of the cell, along its length, and ascend alongside the shorter walls until they reach, approximately, the level of liquid of the tank, said cell being provided below with surfaces which are inclined towards the perforated conduits, said conduits having sufficient cross-sectional area to act as guides through which are inserted a suction head and pipe for sludge extraction.

Abstract: A method of recovering catalyst material from latent catalyst material solids includes: a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and d) recovering catalyst material from the oxidized catalyst species of the mixture.

Abstract: An electrolytic silver recovery system for recovering silver from photographic fixing solutions, by means of an electrolytic cell (28) having an anode (52) and a cathode (53), and circulation pumps (29a, 29b) for removing solution from the cell and returning it to the cell, which device comprises a hydrocyclone (56) located in the liquid path (55) from the cell to the suction side of the pumps and connected at its outlet directly to the suction side of the pumps. The suction pressure of the circulating pump maintains a low pressure differential of less than about 0.6 bar between the inlet and outlet of the hydrocyclone which establishes the liquid flow through the hydrocyclone.

Abstract: Oxygen is extracted from a fluid mixture feedstock by circulating a carrier fluid from an oxygen loading station to an electrochemical cell. The carrier fluid includes a carrier compound capable of reversibly binding oxygen, with oxygen binding dependent on the oxidation state of the compound. Oxygen bound to the carrier compound in a first oxidation state is released as the oxidation state is altered at the first electrode of the electrochemical cell. The carrier compound is then returned to the first oxidation state at the second electrode at the electrochemical cell. The loading station typically comprises an oxygen-permeable membrane which prevents bulk mixing of the fluid mixture and the carrier fluid.

Abstract: Methods and apparatus for the extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising linear, pentadentate polyalkylamines and transition metal ions. The carrier compounds have the general formula: ##STR1## where, each of R.sub.1 and R.sub.2 is independently an organic group including a sulfur, an oxygen or a nitrogen coordinated to M;each of m, n, o, and p is 1, 2, 3, or 4;X is selected from the group consisting of 2,6-pyridyl, 2,6-piperidyl, 2,5-pyrrolyl, 2,4-imidazolyl, substituted heterocyclic amines, --)--, --S--, ##STR2## and ##STR3## where R.sub.3 is hydrogen, lower alkyl or aralkyl; and M is a transition metal ion.

Abstract: Methods and apparatus for electrochemical extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising macrocyclic amines having the general formulas: ##STR1## where: A, B, C, D, E, and F are each nitrogen, oxygen, sulfur, or phosphorous;m, n, o, p, q, and r are each typically 2, 3, 4, 5, or 6;the R substituents are each generally H or short chain (linear or branched) alkyl, although R.sub.2 may represent ketyl (.dbd.o); andM is a suitable transition metal ion.

Abstract: A liquid carrier having mineral ore in the form of free particles or a salt dissolved therein is contained within a suitable container. A box member which has walls which are pervious to the liquid by virtue of apertures formed therein or the porous nature of such walls is filled with a collection material such as carbon which may be in the form of filaments or particles. This box member is suspended in the liquid carrier. An elastic member which may be a plate of steel has an orbitting mass oscillator attached to the top end thereof. This elastic member is suspended in the liquid in opposing relationship to the box member. The rotor of the oscillator is rotatably driven so as to generate sonic energy in the elastic member. The carbon particles provide an electrode of an electrolytic system such that the mineral in the carrier, e.g. gold migrates to the carbon particles and deposits thereon.

Abstract: A novel leaching process for separating extractable material from a particulate solid material that comprises extractable and non-extractable portions includes the steps of introducing the particulate solid material and a liquid solvent to an extraction zone; agitating the liquid solvent to a degree sufficient to suspend the particulate solid material and effect segregation of particles thereof in relation to their propensity to settle; maintaining contact between the liquid solvent and the particulate solid material for a time sufficient to leach extractable material therefrom; and selectively withdrawing particles of the solid material from the extraction zone. In a preferred embodiment, the leaching process is a multi-stage process in which the selectively withdrawn particles from each stage are introduced to the next successive stage of the series.

Abstract: Cerium and rare earth values are separated from an aqueous medium comprised thereof, by (i) anodically electrolytically treating such aqueous medium and oxidizing the Ce (III) values therein to Ce (IV) values, (ii) extracting said electrolyzed aqueous medium with a selective organic extractant for said Ce (IV) values, and permitting the extracted medium to separate into an organic phase enriched in Ce (IV) values and a product aqueous phase enriched in rare earth values, (iii) reducing the Ce (IV) values in said organic phase to Ce (III) values and admixing same with an aqueous medium, and (iv) permitting said admixture to separate into an organic phase and a product aqueous phase enriched in Ce (III) values.

Abstract: A method, process, system, and apparatus for recovering metal values such as gold and silver from ores. The process contemplates the prior separation, through appropriate apparatus, of primary slimes from the coarse fraction of ores and each fraction is processed separately and by particular methods most suitable for maximum economic recovery of metal values from each fraction. The coarse fraction materials are routed to constitute one leg of the method to a series of heap-leach piles that are processed in a totally distinct manner by a very low trickle (0.0002 gal/sq.ft./min) of required strength cyanide solution. Metal values are thereby obtained in solution high enough to pass direct to electro-winning cells by-passing expensive intermediate concentrating steps.

Abstract: Disclosed is a cyclone for use in conjunction with electrolytic cells for separating a gas such as hydrogen from the electrolyte solution so as to significantly increase the efficiency of subsequent cells connected in series in a large bank of electrolytic cells. The subject cyclone is especially useful in a sea water hypochlorite electrolytic cell wherein the flow rate of electrolyte is in the range of 20 to 80 gallons per minute (75 to 300 liters per minute).

Abstract: Process for the recovery of the zinc contained in the residual solutions obtained after electrolytic deposition by fixing the zinc (none of the other metals present in the solution being included in said complex), in the form of a complex by adding of a alkaline metal halide (sodium chloride preferred) to the residual solution adjusted to a low acidity, for example, by dialysis. The process permits the almost total recovery of zinc, and a large part of sulfuric acid.

Abstract: The ore is subjected to nitric acid leaching and the leach solution is heated to a temperature at which one of the additional sulfur and iron values is selectively insolubilized with respect to the solution, while the other is maintained in solution for subsequent separation from the liquor after the insolubles have been removed and the liquor has been neutralized. In addition, in one embodiment of the invention the heating and acid neutralization steps are controlled within certain prescribed limits to make it possible to remove the metals from the liquor by solvent extraction without the problem of lasting precipitates forming in the liquor and fouling the extraction process. Where there is a sizable amount of dissolved iron in the liquor, the liquor may be subjected to autoclaving at a temperature above about 149.degree. C (300.degree. F) to precipitate the iron as the oxide thereof. This effect is possible even where the liquor is high in sulfate concentration.