Abstract: A lead calcium tin alloy to which cobalt has been added is described. The alloy is useful in the formation of anodes to be used in electrowinning cells. Electrowinning cells containing the cobalt alloys are particularly suited for electrowinning metals, such as copper, from sulfuric acid electrolytes. The cobalt-containing anodes improve the efficiency of oxygen evolution at the anode during electrowinning and reduce corrosion of the anode.
Abstract: Electrolytic solutions containing organic additive(s) selected from a described class of additives (e.g., 4,6-dihydroxypyrimidine) reduce overall applied electrical potential of electrolytic cells and/or reduce gas formation at the anode(s) or increase copper production rate. Benefits include reducing overall power consumption and reducing acid mist during electrolytic processes.
Type:
Grant
Filed:
July 10, 2002
Date of Patent:
June 10, 2008
Assignee:
3M Innovative Properties Company
Inventors:
Michael J. Sierakowski, L. Charles Hardy, Michael S. Terrazas, Jennifer E. Waddell, Bryan J. Johnson
Abstract: There is disclosed a method for copper electrowinning and a modified lead electrode for use in such method. The modified electrode is suitable for use as an oxygen anode in low current density, oxygen-evolving applications.
Type:
Grant
Filed:
August 25, 2000
Date of Patent:
April 9, 2002
Assignee:
Eltech Systems Corporation
Inventors:
Kenneth L. Hardee, Lynne M. Ernes, Carl W. Brown, Jr.