Oxygen And Hydrogen Produced Patents (Class 205/628)
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Patent number: 8632672Abstract: The corrosion resistance of stainless steel anodes for use in alkaline water electrolysis was increased by immersion of the stainless steel anode into a caustic solution prior to electrolysis. Also disclosed herein are electrolyzers employing the so-treated stainless steel anodes. The pre-treatment process provides a stainless steel anode that has a higher corrosion resistance than an untreated stainless steel anode of the same composition.Type: GrantFiled: August 18, 2006Date of Patent: January 21, 2014Assignee: General Electric CompanyInventor: Grigorii Lev Soloveichik
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Patent number: 8632663Abstract: There is provided a hydrogen production device high in light use efficiency and capable of producing hydrogen with high efficiency. The hydrogen production device according to the present invention includes a photoelectric conversion part having a light acceptance surface and a back surface, a first gas generation part provided on the back surface, and a second gas generation part provided on the back surface, in which one of the first gas generation part and the second gas generation part is a hydrogen generation part to generate H2 from an electrolytic solution, another one thereof is an oxygen generation part to generate O2 from the electrolytic solution, the first gas generation part is electrically connected to the back surface, and the second gas generation part is electrically connected to the light acceptance surface via a first conductive part.Type: GrantFiled: June 25, 2010Date of Patent: January 21, 2014Assignee: Sharp Kabushiki KaishaInventors: Akihito Yoshida, Shunsuke Sata, Masaki Kaga
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Publication number: 20140014529Abstract: A PEM water electrolyser module and method comprising a plurality of structural plates each having a sidewall extending between opposite end faces with a half cell chamber opening, at least one oxygen degassing chamber opening, and at least one hydrogen gas collection manifold opening, extending through the structural plate between opposite end faces. The structural plates are arranged in face to face juxtaposition between opposite end plates.Type: ApplicationFiled: September 19, 2013Publication date: January 16, 2014Applicant: Next Hydrogen CorporationInventors: James T. HINATSU, Michael C. STEMP
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Patent number: 8623195Abstract: An electrolyser (100) comprising an electrolysis cell stack (101) inside a pressure vessel (115), wherein the first terminal end plate (107a) of the cell stack is integral with one a closed ends of the pressure vessel, thus forming a stationary head (107) of the cell stack equipped with the fluid and electric connections, and the second terminal end plate (108a) of the cell stack is inside the vessel and is free to move in a longitudinal direction in response to thermal expansion or contraction, thus forming a floating head (108) of the stack. The pressure vessel (115) is preferably pressurized using a gaseous product obtained in the process of electrolysis.Type: GrantFiled: September 17, 2009Date of Patent: January 7, 2014Assignee: Casale Chemicals SAInventor: Giancarlo Sioli
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Patent number: 8617361Abstract: A PEM water electrolyser module comprising a plurality of structural plates each having a sidewall extending between opposite end faces with a half cell chamber opening, at least one oxygen degassing chamber opening, and at least one hydrogen gas collection manifold opening, extending through the structural plate between opposite end faces. The structural plates are arranged in face to face juxtaposition between opposite end plates.Type: GrantFiled: August 3, 2010Date of Patent: December 31, 2013Assignee: Next Hydrogen CorporationInventors: James T. Hinatsu, Michael C. Stemp
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Patent number: 8608915Abstract: In one embodiment of the present invention an electrolytic cell is provided comprising a containment vessel; a first electrode; a second electrode; a source of electrical current in electrical communication with the first electrode and the second electrode; an electrolyte in fluid communication with the first electrode and the second electrode; a gas, wherein the gas is formed during electrolysis at or near the first electrode; and a separator; wherein the separator includes an inclined surface to direct flow of the electrolyte and the gas due to a difference between density of the electrolyte and the combined density of the electrolyte and the gas such that the gas substantially flows in a direction distal to the second electrode.Type: GrantFiled: June 24, 2011Date of Patent: December 17, 2013Assignee: McAlister Technologies, LLCInventor: Roy Edward McAlister
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Patent number: 8608936Abstract: A device for producing hydrogen in an electric field includes a shaft rotationally coupled via bearings to a vacuum protection housing, which encloses a disc like structure fastened to the shaft that supplies a split medium provided through inlet channels situated at one longitudinal end of the shaft to split cells arranged at a periphery of the disc like structure. Each split cell includes first and second electrodes. To the vacuum protection housing are fastened diffusor-spirals where a produced gas and a material residue from the split cells are provided through a plurality of nozzles, each of which is arranged inside one of the diffusor-spirals with minimal clearance between an outer wall of the nozzle and an inner wall of the associated diffusor-spiral. A rotation of the disk like structure is supported by a gas pressure generated by the produced gas emitted from the nozzles.Type: GrantFiled: June 2, 2008Date of Patent: December 17, 2013Inventor: Åge Jørgen Skomsvold
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Patent number: 8591718Abstract: A method and apparatus for producing a carbon monoxide containing product in which cathode and anode sides of an electrically driven oxygen separation device are contacted with carbon dioxide and a reducing agent, respectively. The carbon dioxide is reduced to carbon monoxide through ionization of oxygen and the reducing agent lowers the partial pressure of oxygen at the anode side to partially drive oxygen ion transport within the device through the consumption of the oxygen and to supply heat. The lowering of oxygen partial pressure reduces voltage and therefore, electrical power required to be applied to the device and the heat is supplied to heat the device to an operational temperature and to the reduction of the carbon dioxide occurring at the cathode side. The device can be used as part of an integrated apparatus in which the carbon dioxide is supplied from a waste stream of a process plant.Type: GrantFiled: December 7, 2010Date of Patent: November 26, 2013Assignee: Praxair Technology, Inc.Inventors: Jonathan Andrew Lane, Gervase Maxwell Christie, Dante Patrick Bonaquist
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Patent number: 8591707Abstract: A hydrogen generating device comprising an anode, a cathode, a housing having an internal cavity and a perforated wall within the cavity electrically connected to the anode or the cathode and separating an end portion of the cavity from a main portion of the cavity. The device includes water in the housing extending continuously from the main portion of the cavity through the perforated wall and into the end portion of the cavity. The housing includes two ends and a perforated wall within the cavity near each end separating end portions of the cavity from a main portion of the cavity, the anode or the cathode extending through one end of the housing through one perforated wall into the main portion of the cavity, through the other perforated wall into the other end portion of the cavity and through the other end of the housing.Type: GrantFiled: May 3, 2011Date of Patent: November 26, 2013Assignee: Hydroripp, LLCInventor: Scott Gotheil-Yelle
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Patent number: 8568573Abstract: The present disclosure is generally directed to devices and methods of treating aqueous solutions to help remove or otherwise reduce levels, concentrations or amounts of one or more contaminants. The present disclosure relates to an apparatus comprising spaced-apart electrode structural support members extending from a first sidewall to a second sidewall, the spaced-apart electrode structural support members each having at least one photoelectrode and counterelectrode coupled to respective terminals adapted to be electrically coupled to a power supply, and at least one ultraviolet light source between the spaced-apart electrode support members.Type: GrantFiled: February 18, 2013Date of Patent: October 29, 2013Assignee: AquaMost, Inc.Inventors: Douglas S. Winkie, Terence P. Barry
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Patent number: 8557090Abstract: An electrolysis installation for decomposing water into hydrogen and oxygen comprises: an electrolysis stack; a water recirculation system supplying water to the stack and comprising a circuit and a recirculation pump, first and second separators for separating from water hydrogen and oxygen respectively produced in the stack; a hydraulic supply means supplying the recirculation circuit with deionised water to compensate for water consumed by production of gaseous hydrogen and oxygen, and an extinguishing means for inertising the first and second separators when the installation is shut down, wherein the extinguishing means comprises first and second relief valves provided on the first and second separators, respectively, wherein the valves relieve pressure in the two separators simultaneously while keeping the water level inside the two separators substantially constant, and the extinguishing means controls the supply means to completely fill the two separators with water once the two separators are relievedType: GrantFiled: July 9, 2008Date of Patent: October 15, 2013Assignee: Swiss Hydrogen Power SHP SAInventor: Alexis Duret
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Publication number: 20130264218Abstract: An oxygen concentrator is for generating a flow of oxygen by electrolysis of atmospheric humidity. It comprises a cathode (24) and an anode (26) contacting opposite sides of a proton-conducting membrane (12). A catalytic apparatus (14) comprises a diffusion layer (28) which spaces a catalyst (30) from the cathode. The cathode and the catalytic apparatus are contained within a cathode chamber which comprises a ventilation means (44) for allowing a controlled flow of air to the catalyst. In operation water is electrolysed at the anode and hydrogen generated at the cathode flows through the diffusion layer to the catalyst, where it reacts with atmospheric oxygen to form water which flows back to the proton-conducting membrane for further electrolysis.Type: ApplicationFiled: September 13, 2011Publication date: October 10, 2013Applicant: Inotec AMD LimitedInventors: Melvin Frederick Vinton, Derek John Fray
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Patent number: 8551304Abstract: An Alkaline Electrolyzer Cell Configuration (AECC) has a hydrogen half cell; an oxygen half cell; a GSM (Gas Separation Membrane); two inner hydrogen half cell spacer screens; an outer hydrogen half cell spacer screen; a hydrogen electrode; two inner oxygen half cell spacer screens; an outer oxygen half cell spacer screen; and an oxygen electrode. The hydrogen half cell includes the hydrogen electrode which is located between said two inner hydrogen half cell spacer screens and said outer hydrogen half cell spacer screen. The oxygen half cell includes the oxygen electrode which is located between said two inner oxygen half cell spacer screens and said outer oxygen half cell spacer screen. The GSM is provided between said two inner hydrogen half cell spacer screens of the hydrogen half cell and said two inner oxygen half cell spacer screens of the oxygen half cell to from the electrolyzer.Type: GrantFiled: February 23, 2012Date of Patent: October 8, 2013Inventors: William R Richards, Alan L Volker
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Patent number: 8545691Abstract: A super absorbent polymer material is contacted with an aqueous medium to absorb at least a portion of the aqueous medium. At least portion of the aqueous medium absorbed super absorbent material is subsequently regenerated to release water therefrom and to form a regenerated super absorbent material suitable for the contacting with a second quantity of an aqueous medium. Also disclosed are layered composites including an electrically conductive metal support layer, a layer of super absorbent material disposed thereon, and a layer of a selective semi-permeable material disposed adjacent the layer of the super absorbent material and spaced apart from the electrically conductive metal support layer.Type: GrantFiled: April 30, 2009Date of Patent: October 1, 2013Assignee: Illinois Institute of TechnologyInventors: Fouad Teymour, Said Al-Hallaj
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Publication number: 20130248376Abstract: A process is provided for producing electrolytic decomposition products of water by effecting a DC potential across a membrane comprising ripstop nylon interposed between an anode and a cathode. In electrolyzer mode, the electrochemical process produces hydrogen as well as oxygen products. In fuel-cell mode, the electrochemical process produces electricity from hydrogen and oxygen.Type: ApplicationFiled: May 15, 2013Publication date: September 26, 2013Inventors: Christopher M. McWhinney, David C. Erbaugh
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Patent number: 8540856Abstract: An apparatus and method for generating hydrogen. The hydrogen generator of the present invention includes a closed body having a sidewall and two end plates defining a cavity therein. A plurality of electrodes and a plurality of proton exchange membranes are disposed within the cavity. Each proton exchange membrane is sandwiched between two electrodes thereby creating a plurality of hydrogen generating cells disposed along the inner wall of the sidewall. An inflated bladder insures intimate contact between the electrodes and proton exchange membranes. The hydrogen generating cells are operated in series by applying a DC voltage of opposite polarity to electrodes at opposing ends of the cells. Applying the voltage and admitting water into the generator enables hydrogen generation at 12 volts or higher while limiting the potential on each proton exchange membrane to 2 volts thereby protecting the proton exchange membranes from damage or failure by voltage overload.Type: GrantFiled: October 18, 2010Date of Patent: September 24, 2013Inventors: Fred T. Mayers, Sr., Edward N. Miller, Fred T. Mayers, Jr.
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Publication number: 20130206609Abstract: This invention relates to an electrolysis method and electrolysis apparatus (10) for producing oxygenated and hydrogenated fluid. The apparatus (10) comprises first and second outer end members (12 and 14), both being of polyethylene and at least two spaced apart permeable electrodes (16 and 18). The permeable electrode (16 and 18) are each of a foraminous or perforated material, such as nickel foam sheet material. The two permeable electrodes (16 and 18) are arranged generally parallel to one another and are relatively closely spaced from one another. An inlet chamber (20) is therefore defined between the first and second permeable electrodes (16 and 18). A first oxygenated fluid collection chamber (22) is disposed between the first permeable electrode (16) and the first end member (12) and a second hydrogenated fluid collection chamber (24) is disposed between the second permeable electrode (18) and the second end member (14).Type: ApplicationFiled: July 8, 2011Publication date: August 15, 2013Applicant: Hydrox Holdings LimitedInventor: George Anagnostopoulos
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Patent number: 8500971Abstract: An electrolyser including a stack of a plurality of elementary electrolysis cells, each cell including a cathode, an anode, and an electrolyte provided between the cathode and the anode. An interconnection plate is interposed between each anode of an elementary cell and a cathode of a following elementary cell, the interconnection plate being in electric contact with the anode and the cathode. A pneumatic fluid is to be brought into contact with the cathodes, and the electrolyser further includes a mechanism ensuring circulation of the pneumatic fluid in the electrolyser for heating it up before contacting the same with the cathodes.Type: GrantFiled: September 23, 2008Date of Patent: August 6, 2013Assignee: Commissariat a l'Energie AtomiqueInventors: Patrick Le Gallo, Pierre Baurens
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Publication number: 20130192999Abstract: A process for oxidizing water using amorphous cobalt tungstate is disclosed. A plurality of amorphous cobalt tungstate nanoparticles are supported on an electrode and are able to catalytically interact with water molecules generating oxygen. The catalyst can be used as part of a electrochemical or photo-electrochemical cell for the generation of electrical energy.Type: ApplicationFiled: January 31, 2012Publication date: August 1, 2013Applicants: Toyota Motor Corporation, Toyota Motor Engineering & Manufacturing North America, Inc.Inventors: Hongfei Jia, Takeshi Sekito
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Patent number: 8486239Abstract: Methods systems and devices for impeding an anode from being corroded or dissolved are provided. In one example, an electrolysis system includes an anode, the anode disposed on a support including a housing, the housing having an inverted cup on an end, the anode on an interior wall of the inverted cup such that electrical contact with an electrolysis solution is made along a concave portion of the inverted cup. Such an example may further include a cathode, the cathode disposed within a collection pipe such that gas produced at the cathode is retained within a channel of the collection pipe.Type: GrantFiled: August 4, 2010Date of Patent: July 16, 2013Inventor: Michael Anderson
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Patent number: 8465629Abstract: A membrane for use with an electrochemical apparatus is provided. The electrochemical apparatus may include a fuel cell or electrolyzer, for example, an electrolyzer adapted to produce hydrogen. The membrane comprises a fabric made from a synthetic fiber such as nylon where the nylon, in an exemplary embodiment, is woven into ripstop nylon fabric. The electrochemical apparatus is constructed with frames comprising high-density polyethylene (HDPE) which provide support and structure to the membranes as well as to internal electrodes. A method of making an electrochemical apparatus, such as an electrolyzer, containing a membrane comprising ripstop nylon is also disclosed, as is a method for producing hydrogen gas with an electrolyzer containing a membrane comprising ripstop nylon.Type: GrantFiled: April 10, 2009Date of Patent: June 18, 2013Inventors: Christopher M. McWhinney, David C. Erbaugh
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Publication number: 20130149755Abstract: Compositions and methods for a hybrid biological and chemical process that captures and converts carbon dioxide and/or other forms of inorganic carbon and/or CI carbon sources including but not limited to carbon monoxide, methane, methanol, formate, or formic acid, and/or mixtures containing CI chemicals including but not limited to various syngas compositions, into organic chemicals including bio-fuels or other valuable biomass, chemical, industrial, or pharmaceutical products are provided. The present invention, in certain embodiments, fixes inorganic carbon or CI carbon sources into longer carbon chain organic chemicals by utilizing microorganisms capable of performing the oxyhydrogen reaction and the autotrophic fixation of CO2 in one or more steps of the process.Type: ApplicationFiled: April 27, 2011Publication date: June 13, 2013Applicant: Kiverdi ,Inc.Inventors: John S. Reed, Lisa Dyson
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Patent number: 8460832Abstract: A method of performing an electrochemical reaction in an electrochemical cell comprising electrodes separated by a hydrophilic ion-exchange membrane, comprises conducting the reaction in the presence of an aqueous solution of an electrolyte of which the concentration is controlled.Type: GrantFiled: September 24, 2010Date of Patent: June 11, 2013Assignee: ITM Power (Research) LimitedInventor: Donald James Highgate
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Publication number: 20130140189Abstract: Devices, systems and methods for improved electrical appliances which allow for efficient and safe production of hydrogen and oxygen gas for a flame are disclosed. An appliance for providing gas for combustion may comprise a water inlet, a power source, and an electrolyzer with at least one electrolysis transistor generating hydrogen and oxygen. The appliance may also comprise a gas handling unit for collecting the output of the electrolyzer and transporting it to a burner, and an output interface.Type: ApplicationFiled: December 14, 2012Publication date: June 6, 2013Applicant: Transphorm, Inc.Inventor: Transphorm, Inc.
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Patent number: 8454807Abstract: A photoelectrochemical cell (1) is a photoelectrochemical cell for decomposing water by irradiation with light so as to produce hydrogen.Type: GrantFiled: January 28, 2011Date of Patent: June 4, 2013Assignee: Panasonic CorporationInventors: Takaiki Nomura, Takahiro Suzuki, Kenichi Tokuhiro, Tomohiro Kuroha, Noboru Taniguchi, Kazuhito Hatoh, Shuzo Tokumitsu
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Patent number: 8454808Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: June 4, 2013Assignee: HNO Greenfuels, Inc.Inventor: Donald Owens
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Patent number: 8454817Abstract: A mechanism of initiating a redox reaction, such as hydrogen gas production by direct-water-splitting, is provided in which a piezoelectric material is mechanically stressed by actively applying a mechanical stress to the material. The mechanical stress applied to the piezoelectric material causes an electrical potential build up on the surface of the material due to the piezoelectric properties of the material. When the piezoelectric material stressed in this manner is placed in direct contact with the redox reaction reactant(s), the potential on the polarized surface can be used as chemical driving energy to initiate the reaction, such as to split water and generate hydrogen gas. In this manner the mechanical energy applied to the piezoelectric material, such as vibration energy from natural or man-made sources, can be converted directly into chemical energy to initiate the reaction.Type: GrantFiled: July 14, 2009Date of Patent: June 4, 2013Assignee: Wisconsin Alumni Research FoundationInventors: Huifang Xu, Kuang-Sheng Hong, Xiaochun Li
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Patent number: 8449737Abstract: An electrolyzer assembly includes an electrolysis unit having: a hermetically-sealed case made at least partially from a durable dielectric polymer material, the case having a gas outlet and an electrolyte inlet; at least one set of series-coupled, equally-spaced, rectangular, vertically-oriented metal plates installed within the case, each set having first and second end plates, each plate having each side edge sealed to a case wall panel and a bottom edge sealed to the bottom panel; a ground connection to each first end plate; and a voltage connection to each second end plate that is non-zero with respect to the ground connection, thereby providing at least a 1.5 voltage differential between each pair of adjacent plates when gaps between each adjacent pair of plates are filled with electrolyte.Type: GrantFiled: September 14, 2009Date of Patent: May 28, 2013Inventor: David Thomas Richardson
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Patent number: 8449754Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: May 28, 2013Assignee: HNO Greenfuels, Inc.Inventor: Donald Wade Owens
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Patent number: 8449736Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: May 28, 2013Assignee: HNO Greenfuels, Inc.Inventor: Donald Wade Owens
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Patent number: 8449735Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: May 28, 2013Assignee: HNO Greenfuels, Inc.Inventor: Donald Wade Owens
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Patent number: 8449733Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: May 28, 2013Assignee: HNO Greenfuels, Inc.Inventor: Donald Wade Owens
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Patent number: 8449734Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: May 28, 2013Assignee: HNO GreenFuels, Inc.Inventor: Donald Wade Owens
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Patent number: 8444847Abstract: A method is provided for conducting electrolysis at or below 1.23 V. The method comprises filling an electrolysis reactor having an aluminum anode and a copper cathode with a sufficient amount of solution such that at least a portion of the anode and the cathode are immersed in the solution; the solution comprising water, an electrolyte and a catalyst; and applying a voltage across the reactor of less than or equal to 1.23 V. The solution is comprised of water, aluminum sulfate and an ammonium salt. The method allows for total gas to be produced at a rate in excess of the theoretical maximum 1.06 l/min at a current of 93 amps.Type: GrantFiled: February 17, 2010Date of Patent: May 21, 2013Inventors: Craig Evans, Brian Evans, John Evans, Sr., Randy Evans, John Evans, Jr., Todd E. Starner
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Patent number: 8419910Abstract: Some embodiments of the present invention provide a balance-of-plant system and apparatus suited for regulating the operation of an electrolyzer cell stack. Specifically, in some embodiments, a balance-of-plant system and apparatus is operable to regulate the respective pressures of at least two reaction products relative to one another. Various examples are provided to demonstrate how the respective pressures of two reaction products can be regulated in relation to one another in a pressure following configuration, thereby regulating the pressure differential across an electrolyte layer according to aspects of different embodiments of the invention. Some of the examples provided also include design simplifications and alternatives that may reduce production costs of electrochemical cells configured according to aspects of different embodiments of the invention.Type: GrantFiled: September 12, 2008Date of Patent: April 16, 2013Assignee: Hydrogenics CorporationInventors: Ali Rusta-Sallehy, Michael Vale, David Frank, Nathaniel Ian Joos
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Patent number: 8413420Abstract: To alleviate and possibly even reverse global warming while providing a liquid fuel to replace petroleum, apparatus and methods are disclosed for capturing CO2 from an air mixture and converting it to a useful substance, especially a methanol-containing fuel, utilizing preferably an MgO-loaded cartridge, which is converted partly into MgCO3 as it captures CO2 by a carbonation reaction and is reconverted into MgO by a calcination reaction while emitting a stream of substantially pure CO2. The emitted CO2 stream is reacted with hydrogen or water to yield a methanol-containing fuel or other useful chemical agent. The hydrogen is preferably derived from water electrolysis using inexpensive solar or wind driven electricity thereby also reducing the cost of such electricity by providing an economical energy storage means. Said air mixture may be the effluent from an internal combustion engine of a motor vehicle or from other fossil fuel burning sources or from the ambient atmosphere.Type: GrantFiled: April 13, 2009Date of Patent: April 9, 2013Inventor: Solomon Zaromb
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Patent number: 8409422Abstract: This invention relates to a process and an apparatus for generating hydrogen and oxygen gas by electrolysis of water. The process involves forming an electrolyte including alkaline ions and the water and generating plasma between electrodes immersed in the electrolyte by applying an electrical potential between the electrodes. The plasma ionizes the electrolyte, thereby generating hydrogen and oxygen gas. The process further involves controlling the process by relocating the generated plasma between two or more further electrodes.Type: GrantFiled: May 16, 2008Date of Patent: April 2, 2013Assignee: Hope Cell Technologies Pty LtdInventor: Robert Vancina
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Patent number: 8404099Abstract: A method for the electrolytic production of hydrogen where radiation excited water from a spent fuel pool of a nuclear power plant is delivered to one or more electrolysers where DC current is applied to pairs of electrodes in the electrolysers to form hydrogen and oxygen. The hydrogen is collected. The collection of hydrogen can be carried out in a grid energy storage system to produce large quantities of hydrogen during low grid demand for electricity with little or no hydrogen during high grid electricity demand.Type: GrantFiled: September 2, 2009Date of Patent: March 26, 2013Inventor: David E. Fowler
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Patent number: 8404098Abstract: Devices, apparatus, methods and processes are adapted and arranged to efficiently produce both hydrogen and oxygen, while at the same time producing electricity. Advantageously, virtually no undesirable by-products are produced, thus yielding environmentally friendly sources of fuels and energy. Through the cyclic use and re-use of acidic compounds, and especially sulfuric acid, water is processed to produce hydrogen, oxygen and electricity. One or more of the hydrogen, oxygen and electrical output of the methods, devices and apparatus of the invention can be stored, or can be used in many ways, for example, in a fuel cell to produce additional electricity or other reaction products.Type: GrantFiled: August 22, 2008Date of Patent: March 26, 2013Assignee: Diaxiom Technologies Inc.Inventor: Thomas Charles Savage
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Publication number: 20130068629Abstract: Improvements in an ocean wave energy conversion unit that converts kinetic energy from oceanic waves into useable form of energy that will benefit society called and Aqua-tamer. The unit is designed to be modular in nature where the units can be deployed to function individually or assembled into groups where units will rely on each other and function together as a whole. Each individual unit has an electrical output. As a group (Colony) during deep sea surface applications, the electrical output of each Aqua-Tamer unit will be consolidated and used to operate a water-electrolysis operation that produces Oxygen Gas (O2) and Hydrogen Gas (H2). This production of O2 and H2, instead of electrical output, is designed to eliminate the requirements of an Ocean-wide electrical grid system and still facilitate an economic logistically efficient) method of energy transportation (energy in a gas state.Type: ApplicationFiled: March 5, 2012Publication date: March 21, 2013Inventor: Anthony Lim BULACLAC, JR.
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Patent number: 8398828Abstract: The present disclosure is generally directed to devices and methods of treating aqueous solutions to help remove or otherwise reduce levels, concentrations or amounts of one or more contaminants. The present disclosure relates to an apparatus comprising spaced-apart electrode structural support members extending from a first sidewall to a second sidewall, the spaced-apart electrode structural support members each having at least one photoelectrode and counterelectrode coupled to respective terminals adapted to be electrically coupled to a power supply, and at least one ultraviolet light source between the spaced-apart electrode support members.Type: GrantFiled: July 9, 2012Date of Patent: March 19, 2013Assignee: AquaMost, Inc.Inventors: Douglas S. Winkie, Terence P. Barry
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Publication number: 20130052563Abstract: A reinforced membrane comprises: (I) a planar reinforcing component made from metal, carbon, polymer or a composite thereof, and (ii) an ion-conducting material, wherein the planar reinforcing component is a cellular structure, comprising a plurality of discrete cells, wherein the wall of each cell extends through the thickness of the component such that the cell wall is impermeable to the proton-conducting material and wherein the proton-conducting material fills the cells of the planar reinforcing component. Such a membrane is of use in a fuel cell or an electrolyser.Type: ApplicationFiled: February 23, 2011Publication date: February 28, 2013Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Jonathan David Brereton Sharman, Michael Ian Petch
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Publication number: 20130032490Abstract: A process of electrolyzing water at high temperatures implemented by a cell stack reactor, including: a) simultaneously circulating water vapour at each cathode and at each anode as a leaching gas, temperatures of the water vapour at an inlet of each anode and each cathode being lower than high temperatures at which electrolysis is carried out and the water vapour circulating at the anode being at an overpressure with respect to the cathode; b) upon starting the electrolysis, supplying electrical power having a substantially constant electrical voltage across terminals of the stack and maintaining same. In event of breakage of one or more cells, complete destruction of the stack is avoided and high production efficiency is maintained, and efficiency is maintained during ageing.Type: ApplicationFiled: March 11, 2011Publication date: February 7, 2013Applicant: Commissariat a l'energie atomique et aux energies alternativesInventors: Patrick Le Gallo, Christian Perret
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Patent number: 8366902Abstract: Methods and systems are provided for producing syngas utilizing heat from thermochemical conversion of a carbonaceous fuel to support decomposition of at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells. Simultaneous decomposition of carbon dioxide and water or steam by one or more solid-oxide electrolysis cells may be employed to produce hydrogen and carbon monoxide. A portion of oxygen produced from at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells is fed at a controlled flow rate in a gasifier or combustor to oxidize the carbonaceous fuel to control the carbon dioxide to carbon monoxide ratio produced.Type: GrantFiled: March 24, 2008Date of Patent: February 5, 2013Assignee: Battelle Energy Alliance, LLCInventors: Grant L. Hawkes, James E. O'Brien, Carl M. Stoots, J. Stephen Herring, Michael G. McKellar, Richard A. Wood, Robert A. Carrington, Richard D. Boardman
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Patent number: 8361304Abstract: A water electrolysis system includes a water electrolysis apparatus for producing high-pressure hydrogen by electrolyzing pure water and a casing. The casing defines therein an accommodating chamber accommodating the water electrolysis apparatus etc. therein, first electric component compartments separate from the accommodating chamber and housing a controller and an electrolysis power supply therein, the first electric component compartments having first fans for introducing external air, and a second electric component compartment separate from the accommodating chamber and housing a relay, the second electric component compartment being connected to the first electric component compartments by a pipe.Type: GrantFiled: March 30, 2011Date of Patent: January 29, 2013Assignee: Honda Motor Co., Ltd.Inventors: Nobuyoshi Yoshida, Koji Nakazawa, Masanori Okabe, Jun Takeuchi
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Patent number: 8357269Abstract: An intrinsically safe electrolysis system for generating hydrogen gas includes an electrolyzer containing an electrolyte and providing an outlet for generated gasses. An enclosure encloses the electrolyzer and a portion of the gas outlet. A safety interlock mounted within the enclosure and outside the electrolyzer includes a radiative element and a thermal switch, the thermal switch connected in series with a power supply for the electrolyzer and mounted in a proximity to the radiative element so that when a rated current is applied to the radiative element, the thermal switch in response to receiving heat from the radiative element changes state to provide power to the electrolyzer. The electrolyzer may generate hydrogen or oxygen gas as a fuel supplement deliverable to an internal combustion engine via the gas outlet. The electrolyzer may be mounted within a vehicle compartment that may serve as the enclosure.Type: GrantFiled: December 2, 2010Date of Patent: January 22, 2013Inventor: Stuart I. Smedley
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Patent number: 8354010Abstract: The electrolytic cell of the preferred embodiment includes an electrode pair and a cavitating jet. The electrode pair includes a cathode electrode and an anode electrode and defines an electrical path between the cathode electrode and the anode electrode. The cavitating jet, which is located along the electrical path between the cathode electrode and the anode electrode, functions to cavitate a fluid, such as water. The electrode pair and the cavitating jet cooperate to initiate a plasma state in the water. The water in the plasma state acts a virtual electrode with a higher current density than the cathode electrode and/or anode electrode. The plasma virtual electrode, through thermolysis and/or electrolysis, produces hydrogen.Type: GrantFiled: April 20, 2007Date of Patent: January 15, 2013Inventor: Benjamin Pless
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Publication number: 20130001094Abstract: The application generally relates to a process for generating hydrogen, oxygen or both from water. More particularly, the application generally relates to a lanthanide-mediated electrochemical and/or photoelectrochemical process for generating hydrogen, oxygen or both from water.Type: ApplicationFiled: May 7, 2012Publication date: January 3, 2013Applicant: MOLYCORP MINERALS, LLCInventors: Robert Cable, Anthony J. Perrotta, Carl Hassler, John Burba
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Publication number: 20120325677Abstract: An electrochemistry method to produce a reaction gas of a lesser molar mass than that of an initial constituent of gas or vapor, according to which the gas or vapor of the initial constituent is made to flow, and the reaction gas is recovered in the path in which the initial constituent is made to flow. At least one vortex is created in a zone upstream from the reaction gas recovery zone, wherein the vortex can separate the produced reaction gas from the initial constituent still present to subject the initial constituent to an electrochemical process in the upstream zone. In a high-temperature water electrolysis application according to the method, by the vortex, the produced hydrogen is separated from the surplus steam to subject the surplus stream to an electrolytic process within the electrolyser itself.Type: ApplicationFiled: March 11, 2011Publication date: December 27, 2012Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVESInventor: Patrick Le Gallo
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Patent number: 8337678Abstract: A hydrogen electrolysis apparatus includes a stack of unit cells each having a membrane electrode assembly sandwiched between an anode separator and a cathode separator. The anode separator has a first flow field which is supplied with water, and the cathode separator has a second flow field which produces high-pressure hydrogen through an electrolysis of the water. The cathode separator also has a first seal groove defined therein which extends around the second flow field and a first seal member inserted in the first seal groove. The first seal groove and the second flow field are held in fluid communication with each other through passageways. The passageways keep the first seal groove and the second flow field in direct fluid communication with each other in bypassing relation to the boundary between the cathode separator and a solid polymer electrolyte membrane.Type: GrantFiled: February 25, 2010Date of Patent: December 25, 2012Assignee: Honda Motor Co., Ltd.Inventors: Hiroyuki Ishikawa, Masanori Okabe, Koji Nakazawa, Eiji Haryu