Abstract: A gas concentration measuring apparatus is provided which includes a gas concentration sensor consisting of a pump cell, a sensor cell, and a monitor cell. The pump cell works to determine the concentration of O2. The sensor cell works to decompose an oxygen containing gas such as NOx and provide an output indicative of the concentration of NOx. The apparatus also includes an applying voltage determining circuit which looks up a predetermined voltage-to-current relation to determine a target voltage to be applied to the pump cell as a function of the current produced by the pump cell so as to preclude the pump cell from decomposing the oxygen containing gas component, thereby minimizing an error in determining the concentration of oxygen containing gas as a function of the output of the sensor cell.

Abstract: The NOx concentration in a gas is determined with a thick-film measuring sensor which has two measuring cells. The raw measured value of the measuring sensor is corrected by a multiplicative correction value and an additive correction value, which are both taken from a characteristic map. The characteristic map depends on the oxygen-ion pumping current in the second measuring cell, the measured gas temperature, and the measuring sensor temperature.

Abstract: An electrochemical gas sensor for determining the concentration of gas components in a gas mixture, in particular for determining NOx and HC. The gas sensor includes a first measuring gas space which is connected to the measuring gas, and a second measuring gas space which is connected to the first measuring gas space by a connecting channel. Furthermore, a first electrode and a second electrode, arranged in the first measuring gas space, and at least one third electrode arranged in the second measuring gas space, and at least one fourth electrode are provided. The two measuring gas spaces are arranged in layer planes on top of one another and are separated from one another by at least one oxygen ion conducting layer, the connecting channel passing through the oxygen ion conducting layer.

Abstract: A control circuit unit which enables an existing NOx sensor to serve not only as an NOx sensor but also as an oxygen concentration sensor by attachment to an existing NOx sensor. A control circuit unit 31 is connected to an NOx sensor 1. A first pump element control circuit 56 controls a voltage applied to a first pump element 3 so as to control the partial pressure of oxygen in a first processing chamber 9 such that an output voltage of an oxygen concentration detection element becomes substantially constant. A first pump current is detected using a current detection resistor 101 and is then output via an A/D converter circuit 65. A second pump element control circuit 57 applies a constant voltage to a second pump element 5 in a direction so as to pump out oxygen from a second processing chamber 10. A second pump current is detected using a current detection resistor 107 and is then output via an A/D converter circuit 65.

Abstract: A gas sensor having a laminate structure composed of thin sheets of solid electrolyte and including a cavity portion 21 and an oxygen concentration cell 5. The oxygen concentration in the cavity portion 21 is held constant. The oxygen concentration cell 5 includes an active electrode 12 having a relatively high catalytic capability with respect to NOx or combustible gas and an inner common electrode 13/15 (serving as an inactive electrode and an oxygen-concentration-sensing electrode) having a relatively low catalytic capability with respect to NOx or combustible gas. The oxygen concentration cell 5 is disposed in the gas sensor so as to be exposed to the interior of the cavity portion 21. The concentration of NOx or combustible gas is determined based on an electromotive force (of the order of mV) generated between the active electrode 12 and the inner common electrode 13/15 by a concentration cell effect.

Abstract: A method and apparatus which enable accurate measurement of the concentration of NOx in a gas under measurement, even when the NOx concentration is low. A gas under measurement is introduced into a first chamber 3 through a first diffusion passage 2. A pump voltage V1 is applied from a direct-current power source E1 to a first oxygen ion pump cell 6 such that the electric potential of an oxygen-concentration-measuring cell 7 is held constant. As a result, oxygen is pumped out from the first chamber 3 such that the oxygen concentration measured at an inlet to a second chamber 5 becomes constant. A first pump current Ip1 flowing to the first oxygen ion pump cell 6 is measured. Next, the gas under measurement contained in the first chamber 3 is introduced into the second chamber 5 through a second diffusion passage 4.

Abstract: Disclosed is a gas sensor for controlling a concentration of oxygen and/or measuring NOx by allowing a current to flow through an ion-conductive member for conducting oxygen ion, by the aid of a current supply circuit, wherein the current, which is outputted from the current supply circuit, has a pulse waveform (current signal) having a constant crest value, and the current supply circuit comprises a rectangular wave-generating circuit for controlling a frequency of the current signal on the basis of an electromotive force generated in the ion-conductive member to which the current signal is supplied. Accordingly, it is possible to highly accurately measure the predetermined gas component while scarcely being affected by the electric noise or the like.

Abstract: A NOx gas detecting apparatus including an oxygen pumping cell for removing oxygen from a measurement gas, and a NOx detecting cell positioned downstream from the oxygen pumping cell to detect concentration of NOx in the measurement gas, the NOx detecting cell being configured to measure current which flows when oxygen generated from reducing NOx is pumped, wherein the NOx detecting cell has a NOx detecting cathode made of an electrode material including at least one alloy selected from the group consisting of a Pt-Pd alloy, a Pt-Au-Pd alloy, and a Pt-Pd-Rh alloy.

Abstract: A mixed potential electrochemical sensor for the detection of gases has a ceria-based electrolyte with a surface for exposing to the gases to be detected, and with a reference wire electrode and a sensing wire electrode extending through the surface and fixed within the electrolyte as the electrolyte is compressed and sintered. The electrochemical sensor is formed by placing a wire reference electrode and a wire sensing electrode in a die, where each electrode has a first compressed planar section and a second section depending from the first section with the second section of each electrode extending axially within the die. The die is filled with an oxide-electrolyte powder and the powder is pressed within the die with the wire electrodes. The wire-electrodes and the pressed oxide-electrolyte powder are sintered to form a ceramic electrolyte base with a reference wire electrode and a sensing wire electrode depending therefrom.

Abstract: A solid state electrochemical cell (10a) for measuring the concentration of a component of a gas mixture (12) includes first semiconductor electrode (14) and second semiconductor electrode (16) formed from first and second semiconductor materials, respectively. The materials are selected so as to undergo a change in resistivity upon contacting a gas component, such as CO or NO. An electrolyte (18) is provided in contact with the first and second semiconductor electrodes. A reference cell can be included in contact with the electrolyte. Preferably, a voltage response of the first semiconductor electrode is opposite in slope direction to that of the second semiconductor electrode to produce a voltage response equal to the sum of the absolute values of the control system uses measured pollutant concentrations to direct adjustment of engine combustion conditions.

Abstract: In a maltilayer exhaust gas component sensor for measuring NOX (nitrogen oxide) and HC (hydrocarbon), the reliability and the productivity are improved without degrading the detecting sensitivity. A gas sensing portion is formed by laminating porous solid electrolyte layers having gas permeability together with an electrode protecting film, porous electrodes having catalytic activity, a porous electric insulating layer and a closely-compacted (dense) solid electrolyte layer, and by placing a heater as a temperature control means in contact with or near the laminated layer body.

Abstract: A gas sensor element which may be employed in measuring the concentration of gas such O2, NOx, or CO. The gas sensor element consists of an electrochemical cell made up of a solid electrolyte body formed by a partially stabilized zirconia and a pair of electrodes disposed on the solid electrolyte body. The electrochemical cell is subjected to an aging treatment in which the dc current is applied to the electrodes at a given voltage to enhance the activation of the electrochemical cell.

Abstract: A gas sensor is disclosed comprising an oxygen pump cell having at least one exterior pump electrode and at least one interior pump electrode disposed on opposite sides of a first solid electrolyte layer. An emf cell having a first and second emf electrodes and first and second reference gas electrodes are disposed on opposite sides of a second solid electrolyte layer. At least one insulating layer is in contact with the first and second emf electrodes. At least one via hole is disposed through the first solid electrolyte layer. At least one air channel is disposed through at least one insulating layer. An air vent is disposed in at least one insulating layer in contact with the first and second reference gas electrodes. A heater is disposed in thermal communication with the sensor. And at least five electrical leads are in electrical communication with said sensor. A method of using a gas sensor is also disclosed.

Abstract: A method and apparatus for selectively removing oxygen from a gas stream containing NOx and oxygen by contacting the gas stream with an electrochemical cell made from an electrode consisting of La1-XMXFeO3, (where M is selected from the group consisting of Sr, Ba, Ca, and combinations thereof, and X is between 0.05 and 0.5), a solid oxide electrolyte and a counter electrode, wherein the La1-XMXFeO3 electrode is on one side of a solid oxide electrolyte, and a counter electrode is on the opposite side of the solid oxide electrolyte, and applying a voltage to the electrochemical cell. The apparatus is preferably employed in a two chambered NOx sensor utilizing solid electrolyte electrochemical cells, wherein an electrochemical cell capable of catalyzing oxygen reduction without catalyzing NOx decomposition is formed as integral to the first chamber.

Abstract: A method of manufacturing a gas sensor, including a substrate electrode layer forming step, and a surface electrode layer forming step. The gas sensor includes first and second processing spaces, an oxygen concentration detection element, an oxygen pumping element, an oxidation catalyst and a combustible gas component concentration detection element.

Abstract: A gas sensor for measuring concentration of a gas component in a measured gas, including a solid electrolytic substrate and at least two electrodes fixed to the substrate. At least a first electrode of the electrodes is disposed in the environment of the measurement gas, at least one of electrodes is polarized by applying a bias current or bias voltage, and a change in the potential of the polarized electrode is measured to thereby measure the concentration of the target gas.

Abstract: A gas concentration measuring apparatus which has a gas sensor designed to measure, for example, the concentrations of O2 and HOx contained in exhaust emissions of an automotive engine is provided. The apparatus includes a signal processing circuit which converts a current signal outputted from the gas sensor as a function of the concentration of either of O2 and HOx into a voltage signal. The gas sensor and the signal processing circuit are connected electrically through a conductor. The conductor has a length which is determined as a function of a level of the current signal outputted from the gas sensor. The weaker the level of the current signal is, the shorter the length of the conductor. This minimizes addition of electrical noises to the current signal outputted from the gas sensor.

Abstract: Apparatus for detecting the NOx concentration includes a first measurement chamber 20 communicating with the gas under measurement via a diffusion rate defining layer 4d and a second measurement chamber 26 communicating with the first measurement chamber 20 via diffusion limiting layers 6d, 22d. A first pump current IP1 is controlled so that an output of a Vs cell 6 will be equal to the reference voltage VCO for controlling the oxygen concentration in the first measurement chamber 20 to a pre-set low value. A constant voltage is applied across the second pump cell 8 for decomposing the NOx component in the second measurement chamber 26 for pumping out oxygen for detecting the NOx concentration from a second pump current IP2. The sensor temperature is detected from the internal resistance of the Vs cell for controlling the current supplied to the heaters 12, 14. If the temperature of the gas under measurement is changed rapidly, the sensor temperature is changed.

Abstract: A method for detecting the concentration of a specific gas (NOx) in an engine exhaust gas using a gas sensor and a process of correcting the gas sensor. According to the correcting process, the amount of moisture in the exhaust gas is estimated, then a gas concentration detection signal output by the gas sensor on the basis of an estimated amount of moisture is corrected.

Abstract: A gas sensor for measuring an amount of a measurement gas component, including a solid electrolyte having an internal space, a gas-introducing port for introducing measurement gas from an external space into the internal space, diffusion rate-determining means between the internal space and the gas-introducing port, and inner and outer pumping electrodes for pumping-processing oxygen contained in the measurement gas. The diffusion rate-determining means includes slits each having, when viewed in a plane substantially perpendicular to a longitudinal extension axis thereof, two dimensions, with at least one dimension of each slit being not more than 10 microns.

Abstract: A method and apparatus which enable accurate measurement of the concentration of NOx in a gas under measurement, even when the NOx concentration is low. A gas under measurement is introduced into a first chamber 3 through a first diffusion passage 2. A pump voltage V1 is applied from a direct-current power source E1 to a first oxygen ion pump cell 6 such that the electric potential of an oxygen-concentration-measuring cell 7 is held constant. As a result, oxygen is pumped out from the first chamber 3 such that the oxygen concentration measured at an inlet to a second chamber 5 becomes constant. A first pump current Ip1 flowing to the first oxygen ion pump cell 6 is measured. Next, the gas under measurement contained in the first chamber 3 is introduced into the second chamber 5 through a second diffusion passage 4.

Abstract: An electrochemical gas sensor and a method for determining the concentration of gaseous components in a gas mixture, particularly of NOx in exhaust gases of internal combustion engines. The gas sensor includes a first measuring-gas compartment which is in communication with the measuring gas, and two additional measuring-gas compartments which are connected to the first measuring-gas compartment via diffusion barriers. The first measuring-gas compartment contains a first pump cell which, with the aid of pump electrodes arranged on a solid electrolyte, transports oxygen into and out of the measuring-gas compartment. The second and third measuring-gas compartments contain further pump cells, the second measuring-gas compartment being used for measuring the oxygen concentration of the mixture, and the third measuring-gas compartment being used for measuring the sum of the oxygen concentration and the concentration of the gaseous component in the gas mixture.

Abstract: A thick-film measurement sensor includes two measurement cells and is used to measure the NOx concentration in the exhaust gas from an internal combustion engine. The 1/&lgr; value of the exhaust gas is determined from an oxygen ion pump current flowing in the first measurement cell, for example, by a characteristic diagram, and, a measurement error, which can be used to correct the measured NOx concentration, is determined from this 1/&lgr; value, for example, by a characteristic curve that has previously been determined in a calibration measurement. The invention is based on the discovery that the measurement error is dependent on the air ratio in the exhaust gas. If this is expressed by the 1/&lgr; value, there is no need for a complex division calculation during the correction.

Abstract: A control circuit unit which enables an existing NOx sensor to serve not only as an NOx sensor but also as an oxygen concentration sensor by attachment to an existing NOx sensor. A control circuit unit 31 is connected to an NOx sensor 1. A first pump element control circuit 56 controls a voltage applied to a first pump element 3 so as to control the partial pressure of oxygen in a first processing chamber 9 such that an output voltage of an oxygen concentration detection element becomes substantially constant. A first pump current is detected using a current detection resistor 101 and is then output via an A/D converter circuit 65. A second pump element control circuit 57 applies a constant voltage to a second pump element 5 in a direction so as to pump out oxygen from a second processing chamber 10. A second pump current is detected using a current detection resistor 107 and is then output via an A/D converter circuit 65.

Abstract: A NOx sensor for measuring NOx concentration including a main pumping cell and a detecting electrode, the main pumping cell-including an electrode having no decomposing/reducing ability for NOx or a low decomposing/reducing ability for NOx, to be used to control oxygen concentration in a measurement gas to have a predetermined value at which NO is not substantially decomposable, and the detecting electrode having a certain decomposing/reducing ability for NOx or a high decomposing/reducing ability for NOx, to be used so that NOx is decomposed to measure the NOx concentration by measuring an amount of oxygen produced during this process, wherein a cermet electrode composed of a Pt—Rh alloy and a ceramic component is used as the detecting electrode. Accordingly, it is possible to suppress the oxidation of Rh and the reconversion into the metal contained in the detecting electrode, stabilize the impedance, and stabilize the sensitivity to NOx.

Abstract: Emission of NOx during acid-piclding treatment of metals in an aqueous solution containing at least nitric acid is controlled by the addition of hydrogen peroxide. The addition amount of hydrogen peroxide is minimized to avoid excessive addition by monitoring the potentiostatic electrolytic current of the solution or by combinedly monitoring the potentiostatic electrolytic current and the redox potential of the solution.

Abstract: A combined gas sensor of the invention is equipped with a second oxygen sensing electrode 5 active only to oxygen, which is disposed on a solid electrolyte substrate 3a such that it is directly exposed to detection gases. Sensor disorder is detected by measuring an electromotive force (signal output 2) generated between a reference electrode 7 and the second oxygen sensing electrode 5 as an oxygen concentration in an exhaust gas atmosphere, and comparing and judging the detected result with a signal output 1 corresponding to an electromotive force between a first oxygen sensing electrode 4 and the sit reference electrode 7, or with a signal output of an oxygen pump current.

Abstract: A modified universal exhaust gas oxygen sensor, referred to herein as a CEGA sensor, is provided which can be used to measure the concentration of a variety of components of a gaseous fuel emission including CO, CO2, O2, H2, and H2O. The CEGA sensor-employs at least one additional electrode on a ceramic substrate which possess a different catalytic activity relative to the electrodes that normally found on a UEGO sensor. The ceramic substrate may be made of any suitable ceramic and is preferably made of zirconia. The difference in catalytic activity between the additional electrode(s) and the electrodes native to the UEGO sensor create an oxygen gradient which enables a measure of combustion completeness to be calculated. In combination with an air/fuel ratio measured by the sensor, the concentrations of different components in the emission can be calculated.

Abstract: A method for detecting the concentration of a specific gas (NOx) in an engine exhaust gas using a gas sensor and a process of correcting the gas sensor. According to the correcting process, the amount of moisture in the exhaust gas is estimated, then a a gas concentration detection signal output by the gas sensor on the basis of an estimated amount of moisture is corrected.

Abstract: A detector for an air/fuel ratio sensor, which is comprised of a structure formed by stacking an oxygen reference electrode, a dense zirconia solid electrolyte, a negative electrode, a porous zirconia solid electrolyte, a positive electrode and a porous protection film on one another, is formed over a ceramic substrate having a heater built therein. Thus, a combined air/fuel ratio sensor can be obtained which is operated in a short time (about 5 seconds or less) after power-on so as to comply with emission control applied immediately after startup and provides low power consumption and a high degree of reliability.

Abstract: A circuit configuration for controlling a pump current includes a microcontroller, an analog circuit and a read-only memory. A pulse-width modulated signal, which is output by the micro-controller, is converted, by using the analog circuit, into the pump current for a pump cell of an exhaust probe which operates according to the principle of the galvanic oxygen concentration cell with a solid electrolyte. A pump current actual value is determined from a voltage drop across a measuring resistor, and a pump current setpoint value is determined from a voltage difference between an actual value of a Nernst voltage in the corresponding measuring cell and a predefined setpoint value. An exhaust probe configuration is also provided.

Abstract: A modified universal exhaust gas oxygen sensor, referred to herein as a CEGA sensor, is provided which can be used to measure the concentration of a variety of components of a gaseous fuel emission including CO, CO2, O2, H2, and H2O. The CEGA sensor-employs at least one additional electrode on a ceramic substrate which possess a different catalytic activity relative to the electrodes that normally found on a UEGO sensor. The ceramic substrate may be made of any suitable ceramic and is preferably made of zirconia. The difference in catalytic activity between the additional electrode(s) and the electrodes native to the UEGO sensor create an oxygen gradient which enables a measure of combustion completeness to be calculated. In combination with an air/fuel ratio measured by the sensor, the concentrations of different components in the emission can be calculated.

Abstract: An exemplary embodiment of a planar exhaust gas sensor for determining the nitrogen oxide concentration in exhaust gas is disclosed herein. The sensing element has a first pumping electrochemical cell, a reference cell, and a second pumping cell arranged so that both oxygen and nitrogen oxide partial pressures in an exhaust gas can be sensed. Nitrogen oxides in an exhaust gas enter the sensing element through a protective material. The nitrogen oxides then diffuse through a first pumping cell, and a porous material. At the pumping electrode of a second pumping cell, the nitrogen oxide is reduced, and the ionic oxygen thereby produced is pumped across a solid electrolyte to a second inner electrode. A measured current produced in a second pumping cell circuit is directly proportional to the nitrogen oxides in the exhaust gas.

Abstract: An electrochemical gas sensor has a first gas diffusion electrode for a first reaction gas, which is inactive with respect to a second reaction gas at least in a first potential window, and a second gas diffusion electrode for the second reaction gas, which is active with respect to the second reaction gas at least in a second potential window for measuring two different gases in gas mixtures in a casing. The two gas diffusion electrodes are electronically isolated from one another, but electrically connected electrolytically to a reversibly loadable electrode and have contacts for connecting external closing circuits for adjusting the cell currents. The gas mixture is fed to the gas diffusion electrodes in series or parallel. The casing containing the electrodes is, in particular, in the form of a button cell. The reversibly loadable electrode is a Cu/CuO, Zn/ZnO or hydrogen electrode. The gas diffusion electrodes have a porous structure based on carbon or have a porous silver structure.

Abstract: The present invention is a gas component sensor comprising novel electrolyte compositions. The electrolyte compositions in bulk, sintered or thin film embodiments are capable of forming with different-metal sensing and reference electrodes a highly stable gas oxide sensors. The novel electrolyte composition changes electrochemical reactions at the sensing and reference electrodes and the overall reaction of the electrodes and electrolyte. The novel electrolyte compositions have: (1) excellent chemical stability and thermal compatibility as to the electrodes and a preferred ceramic substrate, (2) excellent chemical stability with the environment as to the reference and sensing electrodes, which need not be sealed against the atmosphere to be sensed, (3) effective adherence to the substrate and electrode metals. An improvement is disclosed where a correction of calculated gas concentration is made by comparison of measured voltages of two gas sensors.

Abstract: Disclosed is a NOx sensor for measuring a NOx concentration comprising a main pumping cell and a detecting electrode, the main pumping cell including an electrode (an inner pumping electrode and an outer pumping electrode) having no decomposing/reducing ability for NOx or a low decomposing/reducing ability for NOx, to be used so that an oxygen concentration in a measurement gas is controlled to have a predetermined value at which NO is not substantially decomposable, and the detecting electrode having a certain decomposing/reducing ability for NOx or a high decomposing/reducing ability for NOx, to be used so that NOx is decomposed to measure the NOx concentration by measuring an amount of oxygen produced during this process, wherein a cermet electrode composed of a Pt—Rh alloy and a ceramic component is used as the detecting electrode.

Abstract: A nitrogen oxide gas sensor wherein an alloy electrode of platinum and rhodium or a cermet electrode of platinum, rhodium, and zirconia or of a rhodium alloy and zirconia is used as the gas sensing electrode. The electrode of the sensor is suitable for measuring nitrogen oxide such as NO and NO2 in an exhaust gas.

Abstract: The end of a regeneration interval of an NOx accumulating catalytic converter for an engine run on a lean mixture is determined by detecting the end of the regeneration phase of the NOx accumulator using a sensor having a cross-sensitivity NOx and to a reducing agent in an exhaust-gas constituent which passes through the catalytic converter at the end of the regeneration phase. Exhaust-gas reducing constituents such as CO and NH3, which can be detected by a cross-sensitive NOx sensor, can be the exhaust-gas products detected at the end of the regeneration phase. By determining the end and beginning of a regeneration phase, different control functions and various types of information can be deduced, including control of the completion of rich-mixture engine operations, correction of a stored regeneration model in the engine management system, and ageing of the catalytic converter.

Abstract: A method is presented for correcting the output of the NOx sensor during a time period starting with the end of the NOx purge cycle and ending when the amount of tail pipe O2 exceeds a preselected value. During that period, fuel is being deposited on the NOx sensor thus causing an incorrect reading. Proper amount of NOx generated during that time is calculated by assuming that the NOx level during the incorrect reading is equal to the NOx reading after the end of the incorrect reading, and multiplying that amount by total integrated air mass. This method helps avoid unnecessary NOx purges and improves fuel economy.

Abstract: The time profile of the output signal of an NOx measurement transducer arranged downstream of the NOx storage catalyst is used, during and after the regeneration phase, to derive a criterion as to whether the quantity of regeneration agent to be supplied to the NOx storage catalyst in a regeneration phase must be changed in order to achieve an optimum action of the exhaust-gas purification system. The output signal is picked off at the amperometric NOx measurement transducer at two electrodes. The measurement transducer exhibits the two-position behavior necessary for the method.

Abstract: A gas concentration sensing apparatus includes a gas introducing portion for introducing a measurement gas. A first cell opposed to the gas introduction portion operates for pumping oxygen from the measurement gas in the gas introducing portion. A second cell opposed to the gas introducing portion operates for sensing a concentration in a specific component of the measurement gas from which oxygen has been pumped by the first cell. There is a reference gas chamber to which at least one of the first cell and the second cell is exposed. The one of the first cell and the second cell which is exposed to the reference gas chamber includes an electrode facing the gas introducing portion. A current flowing through the first cell is sensed. A voltage is applied to the first cell in response to the sensed current through the first cell. A current flowing through the second cell is sensed. A voltage is applied to the second cell in response to the sensed current through the second cell.

Abstract: A structural arrangement for NOx sensors including a first selectively oxygen ion-conductive layer and a second gas-permeable, nonconductive layer, the latter having a porous spinel structure or porous platinum. The oxygen ion-conductive layer made from a mixed-conductive ceramic can have an additional layer of a material which is catalytically inactive to NOx.

Abstract: A combined oxygen and NOx sensor is provided. Generally, the combined sensor employs a sensor body that includes two different types of electrodes—oxygen-porous electrode layers and dissociative oxygen-porous electrode layers. In accordance with one embodiment of the present invention, the sensor comprises a sensor body, an oxygen content electrical signal output, and a NOx content electrical signal output. The sensor body is disposed in the gas and comprises a plurality of oxygen-porous electrode layers and a plurality of dissociative oxygen-porous electrode layers. The dissociative oxygen-porous electrode layers comprise a material selected to catalyze dissociation of NOx into nitrogen and oxygen.

Abstract: A nitrogen oxide concentration detector has a first measurement chamber 2 into which is introduced a measurement gas via a first diffusion resistance 1; an oxygen concentration detection electrode 7a for measuring the oxygen concentration in the measurement gas in said first measurement chamber 1; a first oxygen ion pump cell 6 for pumping out oxygen in the measurement gas from said first measurement chamber 2 based on the potential of said oxygen concentration detection electrode 7a; a second measurement chamber 8 into which the gas is introduced from said first measurement chamber 2 via a second diffusion resistance 3; and a second oxygen ion pump cell 8 having a pair of electrodes 8a,8b across which a voltage is applied to decompose NOx in the second measurement chamber 4 to pump out dissociated oxygen to cause a circuit Ip2 corresponding to the NOx concentration to flow in the second oxygen ion pump cell 8. Variation of NOx concentration is a function of variation of Ip2.

Abstract: A NOx concentration of a gas is measured with a NOx measuring sensor which has two measuring cells. An oxygen concentration is respectively corrected by a oxygen-ion pumping current. A controller is used for correcting a transitional resistance through which the first oxygen-ion pumping current flows at the first measuring cell, the controller correcting at least partially a correction value for the transitional resistance by using the second oxygen-ion pumping current at the second measuring cell.

Abstract: A composite gas sensor comprises a pump cell, a NOx sensor cell and an oxygen sensor cell. The NOx sensor cell is connected to a first ammeter and a constant power source to measure the NOx concentration of a sample gas. The pump cell is connected to a second ammeter and a variable power source to measure an air-fuel ratio of the sample gas. The oxygen sensor cell is connected to a voltmeter. A controller adjusts the variable power source to produce a constant value from the voltmeter.

Abstract: Disclosed are a gas sensor and a nitrogen oxide sensor each comprising a first diffusion rate-determining section for giving a predetermined diffusion resistance to a measurement gas to be introduced into a first chamber, the first diffusion rate-determining section being formed with a slit having a laterally extending aperture formed at a front end portion of a second spacer layer to make contact with the lower surface of a second solid electrolyte layer in which the aperture is formed to extend with an identical aperture width up to the first chamber, and a slit having a laterally extending aperture formed at a front end portion of the second spacer layer to make contact with the upper surface of a first solid electrolyte layer in which the aperture is formed to extend with an identical aperture width up to the first chamber.

Abstract: A nitrogen oxide concentration detector has a first measurement chamber 2 into which is introduced a measurement gas via a first diffusion resistance 1; an oxygen concentration detection electrode 7a for measuring the oxygen concentration in the measurement gas in said first measurement chamber 1; a first oxygen ion pump cell 6 for pumping out oxygen in the measurement gas from said first measurement chamber 2 based on the potential of said oxygen concentration detection electrode 7a; a second measurement chamber 8 into which the gas is introduced from said first measurement chamber 2 via a second diffusion resistance 3; and a second oxygen ion pump cell 8 having a pair of electrodes 8a,8b across which a voltage is applied to decompose NOx in the second measurement chamber 4 to pump out dissociated oxygen to cause a current Ip2 corresponding to the NOx concentration to flow in the second oxygen ion pump cell 8. Variation of NOx concentration is a function of variation of Ip2.

Abstract: An apparatus and method using a two-serial space sensor (having first and second internal spaces 2,3) for accurately measuring NOx concentration in gas, e.g., exhausted from an internal combustion engine. Both NOx (nitrogen oxide) and oxygen are forced to be partially dissociated in the first space 2 to an oxygen concentration level of 2×10−7 to 2×10−10 atm by pumping out oxygen from the first space 2. The NOx concentration is determined based on the second current measured in the second space 4 and based on the NO dissociation percentage in the first chamber which is 0.5-50%, or preferably 2-20%. The NOx measurement accuracy is further improved when the above oxygen concentration level is maintained from 2×10−8 to 2×10−9 and the temperature drift of the sensor is maintained within ±5° C. under a sensor temperature range of 700-900° C.

Abstract: It is intended to avoid invasion of oxygen through any route except for an introducing port for a measurement gas so that the amount of oxide or inflammable gas contained in the measurement gas may be measured highly accurately. Insulative layers are provided for respective lead wires at positions corresponding to portions at which the temperature of the oxygen ion-conductive solid electrolyte is increased due to heat generation effected by a heater. Each of the insulative layers is formed to have a pattern in which one end is exposed to a first chamber or a second chamber, and the other end terminates at a position separated by a predetermined distance from a corresponding through-hole. At least the lead wires, which lead to an auxiliary pumping electrode and a detecting electrode, are densified. Preferably, the insulative layers for these lead wires are also densified.