With Group Viii Metal Or Metal Oxide (i.e., Iron, Or Platinum Group Metal, Or Oxide Thereof) Patents (Class 208/111.35)
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Patent number: 11492562Abstract: The present disclosure generally relates to upgrading difficult to process heavy-oil. In particular, the disclosure relates to upgrading heavy oil and other high carbon content materials by using an integrated thermal-process (ITP) that utilizes anti-coking management and toluene insoluble organic residues (TIOR) management to directly incorporate lighter hydrocarbons into high molecular weight, low hydrogen content hydrocarbons such as thermally processed heavy oil products. This process can be integrated with other thermal processing schemes, such as cokers and visbreakers, to improve the conversion and yields from these integrated processes.Type: GrantFiled: July 11, 2019Date of Patent: November 8, 2022Assignee: SUNCOR ENERGY INC.Inventors: Kelly Benham, Bernard Mark Archer, Nicholas Daniel Benham
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Patent number: 11180703Abstract: Improved processes for production of gasoline with 95 RONC including a C5-C6 isomerization zone, two C7 isomerization zones, and a reforming zone are described. The first and second C7 isomerization zones share a common stabilizer which strips off the chlorides and removes the light ends. The capital and operating costs of the processes are reduced through the elimination of one of the stabilizer columns and the associated condenser, receiver, trim cooler, and reboiler. The processes improve the RONC of the C7 isomerization product because unconverted methylcyclohexane is recycled back to the second C7 isomerization zone to be converted into dimethylcyclopentane.Type: GrantFiled: January 27, 2020Date of Patent: November 23, 2021Assignee: UOP LLCInventors: Charles P. Luebke, Lin Jin, Cora Wang Ploentham
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Patent number: 10913054Abstract: A hydrocracking catalyst comprising a zeolite beta having an average domain size from 800 to 1500 nm2; a zeolite USY; a catalyst support; and at least one metal selected from the group consisting of elements from Group 6 and Groups 8 through 10 of the Periodic Table. The zeolite beta has an OD acidity of 20 to 50 ?mol/g and the catalyst support comprises an amorphous silica aluminate and a second support material when the weight percentage content of the zeolite beta is less than the weight percentage of the zeolite USY, and, when the weight percentage content of the zeolite beta is greater than the weight percentage of the zeolite USY, the zeolite beta has an OD acidity of 20 to 400 ?mol/g, the zeolite beta content is from 0.5 to 10 wt. % and the zeolite USY has an ASDI between 0.05 and 0.12 with a corresponding zeolite USY content of from 0 to 5 wt. %. A process for hydrocracking a hydrocarbonaceous feedstock using the catalyst is also described as is a method for making the hydrocracking catalyst.Type: GrantFiled: August 7, 2018Date of Patent: February 9, 2021Assignee: Chevron U.S.A. Inc.Inventors: Yihua Zhang, Theodorus Ludovicus Michael Maesen, Yalin Hao, Thomas Michael Rea, Don Ramon Bushee
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Patent number: 10760014Abstract: This invention relates to a process for hydro cracking of heavy oils. More particularly, this invention relates to a catalytic process for converting heavy oils, such as vacuum gas oil (VGO) and VGO containing a high proportion of vacuum resid (VR) to middle distillate products.Type: GrantFiled: August 17, 2016Date of Patent: September 1, 2020Assignee: INDIAN OIL CORPORATION LIMITEDInventors: Pravesh Kumar, Pappu Naresh, Vinay Kumar Chaudhary, Darshankumar Manubhai Dave, Kamal Kumar, Murugan Balasundaram, Karumanchi Ramesh, Ganesh Vitthalrao Butley, Om Prakash Nandwani, Madhusudan Sau, Brijesh Kumar, Biswapriya Das
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Patent number: 10655075Abstract: The invention provides a process for hydrotreating and dewaxing a hydrocarbon feedstock, comprising the steps of: (a) hydrotreating the feedstock under hydrotreating conditions in a first reaction zone to obtain a first stage hydrotreated effluent; and (b) introducing at least part of the first stage hydrotreated effluent into a second reaction zone in which the first stage hydrotreated effluent is subjected to a series of alternating dewaxing steps and hydrotreating steps.Type: GrantFiled: November 26, 2013Date of Patent: May 19, 2020Assignee: SHELL OIL COMPANYInventors: Laurent Georges Huve, Meng Loong Chua
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Patent number: 10626337Abstract: There is described a hydroprocessing process of at least one gas oil cut having a weighted mean temperature (TMP) between 240° C. and 350° C. using a catalyst comprising at least one metal of the group VIB and/or at least one metal of the group VIII of the periodic classification and a support comprising an amorphous mesoporous alumina having a connectivity (Z) greater than 2.7, the hydroprocessing process operating at a temperature between 250° C. and 400° C., at a total pressure between 2 MPa and 10 MPa with a ratio of hydrogen volume to volume of hydrocarbon-containing feedstock between 100 and 800 litres per litre and at an Hourly Volume Rate (HVR) which is defined by the ratio of the volume flow rate of liquid hydrocarbon-containing feedstock to volume of catalyst fed into the reactor between 1 and 10 h?1.Type: GrantFiled: June 9, 2015Date of Patent: April 21, 2020Assignee: IFP Energies nouvellesInventors: Malika Boualleg, Elodie Devers, Bertrand Guichard
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Patent number: 10550344Abstract: Naphtha boiling range compositions are provided that can have improved combustion properties (relative to the research octane number of the composition) in spark ignition engines and/or compression ignition engines. The improved combustion properties can be achieved by controlling the total combined amounts of n-paraffins and isoparaffins that include a straight-chain propyl group (R1—CH2—CH2—CH2—R2). For such a straight-chain propyl group, R2 can correspond to any convenient CxHy group that can appear in a paraffin or isoparaffin. R1 can correspond to a hydrogen atom, making the straight-chain propyl group a terminal n-propyl group; or R1 can correspond to any convenient CxHy group that can appear in a paraffin or isoparaffin.Type: GrantFiled: October 20, 2017Date of Patent: February 4, 2020Assignee: ExxonMobil Reseach and Engineering CompanyInventors: Eugine Choi, Matthew W. Boland, Zhisheng Gao, Luca Salvi, Shamel Merchant, Bruce W. Crawley
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Patent number: 10479947Abstract: An integrated hydrocracking and solvent deasphalting process that provides for removal from the heavy oil recycle stream heavy polycyclic aromatic compounds formed in the hydrocracking step and recycling the resulting deasphalted paraffinic oil as a feed to the hydrocracker reactor of the process for further conversion.Type: GrantFiled: October 5, 2015Date of Patent: November 19, 2019Assignee: SHELL OIL COMPANYInventor: Aristides Macris
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Patent number: 10195604Abstract: The invention pertains to a zeolite catalyst, methods of making same, and its use in the catalytic cracking of naphtha for the production of lower molecular weight olefins and alkanes, while minimizing production less desirable products. A zeolite is modified by base leaching and by the addition of a metal cation, thereby lowering the Si/Al2 ratio and improving the stability of the formed catalyst.Type: GrantFiled: May 8, 2014Date of Patent: February 5, 2019Assignee: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Nabil Al-Yassir, Mohammed Al-Hazmi, Mohammed Abdul Bari Siddiqui, Yaming Jin, Abdullah Aitani, Sulaiman Al-Khattaf
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Patent number: 10046317Abstract: A hydrocracking catalyst is provided comprising: a. from 0.5 to 10 wt % zeolite beta having an OD acidity of 20 to 400 ?mol/g and an average domain size from 800 to 1500 nm2; b. from 0 to 5 wt % zeolite USY having an ASDI between 0.05 and 0.12; wherein a wt % of the zeolite beta is greater than the wt % of the zeolite USY; c. a catalyst support; and d. at least one metal selected from the group consisting of elements from Group 6 and Groups 8 through 10 of the Periodic Table. A process for hydrocracking using the hydrocracking catalyst to produce middle distillates is provided. A method for making the hydrocracking catalyst is also provided.Type: GrantFiled: August 11, 2015Date of Patent: August 14, 2018Assignee: Chevron U.S.A. Inc.Inventors: Yihua Zhang, Theodorus Ludovicus Michael Maesen, Yalin Hao, Don Ramon Bushee, Thomas Michael Rea
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Patent number: 9944865Abstract: Methods are provided for dewaxing distillate feeds using a dewaxing catalyst with improved aromatic saturation activity. The dewaxing can be performed using a catalyst including a zeolitic molecular sieve with a beneficial ratio of zeolitic molecular sieve to binder and/or using a catalyst including a zeolitic molecular sieve with a reduced ratio of silica to alumina.Type: GrantFiled: December 16, 2016Date of Patent: April 17, 2018Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Matthew S. Ide, Stephen J. McCarthy, Gary P. Schleicher
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Patent number: 9919986Abstract: The energy is minimized that is required to lower the concentration of the high boiling point components (containing the poisoning substance for the dehydrogenation catalyst) contained in the hydrogenated aromatic compound produced by the hydrogenation of an aromatic compound. The hydrogenation system (2) for an aromatic compound comprises a hydrogenation reaction unit (11) for adding hydrogen to an aromatic compound by a hydrogenation reaction to produce a hydrogenated aromatic compound, a first separation unit (12) for separating a gas and a liquid component from a product of the hydrogenation reaction unit while maintaining a temperature of the product generally higher than a boiling point of the hydrogenated aromatic compound, and a second separation unit (13) for separating the hydrogenated aromatic compound from the gas component separated by the first separation unit.Type: GrantFiled: January 29, 2015Date of Patent: March 20, 2018Assignee: CHIYODA CORPORATIONInventors: Kenichi Imagawa, Hironori Kawai, Masato Shiraga, Yusuke Nakajima
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Patent number: 9687828Abstract: Disclosed herein is an activated EU-2 zeolite, including: pores having a diameter of 30 to 40 ? while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 ?, wherein the volume of the pores having a diameter of 30 to 40 ? is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 ? is 0.07 to 0.4 cc/g.Type: GrantFiled: October 17, 2014Date of Patent: June 27, 2017Assignees: SK Innovation Co., Ltd., SK Lubricants Co., Ltd.Inventors: Yoon Kyung Lee, Seung Woo Lee, Jae Suk Choi, Tae Jin Kim, Do Woan Kim, Seon Ju Lim
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Patent number: 9403148Abstract: A method of forming the highly selective ultra-small pore amorphous adsorbent includes introducing an ion-exchange material to a sodium aluminosilicate zeolite such that an ion-exchanged zeolite forms, calcinating the ion-exchanged zeolite at a calcination temperature such that the ion-exchanged zeolite collapses and forms the decationized amorphous adsorbent, and introducing a back ion-exchange material to the decationized amorphous adsorbent such that the highly selective ultra-small pore amorphous adsorbent forms. The highly selective ultra-small pore amorphous adsorbent has a pore aperture size operable to permit carbon dioxide to adsorb into the amorphous adsorbent and operable to deny methane from adsorbing into the amorphous adsorbent.Type: GrantFiled: June 23, 2014Date of Patent: August 2, 2016Assignee: Saudi Arabian Oil CompanyInventors: Yuguo Wang, Cemal Ercan, Rashid M. Othman, Minkee Choi, Hyeonbin Kim
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Patent number: 9272276Abstract: A system and method for efficiently treating metal catalyst resident in a reactor vessel comprises a sulfiding module, a sulfur source, an ammonia source, and/or a coking source, a hydrogen sulfide detection module, a hydrogen gas detection module, a pH detection module, an ammonia gas detection module and a remote computer all arranged and configured to communicate wirelessly and to allow remote control and monitoring of the modules and process so that catalyst may be sulfided, passivated and/or soft-coked in situ.Type: GrantFiled: October 31, 2014Date of Patent: March 1, 2016Inventors: James Maxie Robinson, James Michael Robinson
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Patent number: 9049844Abstract: A system for removal of hair includes an instrument having a frame with a trailing handle segment and a leading treatment segment, a manually manipulative actuator mounted relative to the trailing handle segment of the frame and a drive member operatively coupled to the actuator and extending at least partially within the leading treatment segment of the frame. The drive member is movable between an initial condition and a deployed condition in response to corresponding movement of the actuator. A blade assembly is mountable relative to the leading treatment segment of the frame. The blade assembly includes a blade housing mountable relative to the treatment segment of the frame, a blade mounted to the blade housing and having hair teeth for grooming a pet and an ejector member mounted relative to the blade housing. The ejector member is couplable to the drive member of the instrument and positioned to facilitate removal of hair from the blade upon movement toward the advanced position.Type: GrantFiled: March 15, 2013Date of Patent: June 9, 2015Assignee: Conair CorporationInventor: Kam Fai Fung
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Patent number: 8999145Abstract: One exemplary embodiment can be a slurry hydrocracking process. The process can include providing one or more hydrocarbon compounds having an initial boiling point temperature of at least about 340° C., and a slurry catalyst to a slurry hydrocracking zone. The slurry catalyst may have about 32-about 50%, by weight, iron; about 3-about 14%, by weight, aluminum; no more than about 10%, by weight, sodium; and about 2-about 10%, by weight, calcium. Typically, all catalytic component percentages are as metal and based on the weight of the dried slurry catalyst.Type: GrantFiled: October 15, 2012Date of Patent: April 7, 2015Assignee: UOP LLCInventors: Lorenz J. Bauer, Maureen L. Bricker, Beckay J. Mezza, Alakananda Bhattacharyya
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Patent number: 8933283Abstract: This invention relates to a petroleum refining method for producing high value-added clean petroleum products and aromatics (Benzene/Toluene/Xylene) together, by which low pollution petroleum products including liquefied petroleum gas or low-sulfur gas oil and aromatics can be efficiently produced together from a fluid catalytic cracked oil fraction.Type: GrantFiled: November 26, 2008Date of Patent: January 13, 2015Assignee: SK Innovation Co., Ltd.Inventors: Cheol Joong Kim, Jae Wook Ryu, Kyeong Hak Seong, Byoung Mu Chang, Byeung Soo Lim, Jong Hyung Lee, Kyung Seok Noh, Hyuck Jae Lee, Sam Ryong Park, Sun Choi, Seung Hoon Oh, Yong Seung Kim, Gyung Rok Kim
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Patent number: 8894839Abstract: One exemplary embodiment can be a process for a hydrocarbon feed. The process can include passing a stream through a separation zone forming a void for separating one or more gases from one or more liquids and at least partially containing a catalyst. The catalyst may include at least one group VIII noble metal. Typically, the separation zone is downstream of a hydrocracking zone for reducing the operating pressure in the hydrocracking zone.Type: GrantFiled: February 22, 2010Date of Patent: November 25, 2014Assignee: UOP LLCInventor: Vinod Ramaseshan
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Publication number: 20140339134Abstract: The invention relates to a process for preparing a hydroconversion catalyst based on a modified zeolite of the FAU framework type with preserved crystallinity and microporosity, comprising the steps of: A—preparation of a modified zeolite of the FAU framework type, whose intracrystalline structure presents at least one network of micropores, at least one network of small mesopores with a mean diameter of 2 to 5 nm and at least one network of large mesopores with a mean diameter of 10 to 50 nm; these various networks being interconnected; B—mixing the zeolite with a binder, shaping the mixture, and then calcining; C—impregnation of the shaped zeolite with at least one compound of a catalytic metal chosen from compounds of a metal from group VIII and/or from group VIB, in acidic medium, provided that at least one compound of a catalytic metal is soluble within said acidic medium and that the acid acts as a complexing or chelating agent for at least one compound of a catalytic metal.Type: ApplicationFiled: October 23, 2012Publication date: November 20, 2014Applicant: TOTAL RAFFINAGE FRANCEInventors: Delphine Minoux, Nadiya Danilina
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Patent number: 8883669Abstract: The present invention relates to a hydrocracking catalyst comprising an acidic silica-alumina, an optional alumina, an effective quantity of at least one VIII Group metal component(s), an effective quantity of at least one VIB Group metal component(s) and an organic additive, wherein the organic additive is one or more selected from the group consisting of an oxygen-containing or nitrogen-containing organic compound, and the molar ratio of the organic additive to the VIII Group metal component(s) is 0.01-10. The present invention relates further to a process for producing the hydrocracking catalyst and use of the catalyst in a process for hydrocracking hydrocarbon oils. The hydrocracking catalyst provided according to the present invention shows a higher activity for aromatic hydrosaturating and ring-opening reaction, as compared with the prior art hydrocracking catalyst.Type: GrantFiled: December 3, 2010Date of Patent: November 11, 2014Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Yichao Mao, Hong Nie, Jianwei Dong, Zhenlin Xiong, Zhihai Hu, Yahua Shi, Dadong Li
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Publication number: 20140326641Abstract: The invention relates to a method of preparing a catalyst comprising a) preparation of a support comprising 0.2 to 30 wt % of zeolite NU-86 and from 70 to 99.8 wt % of a porous mineral matrix, the percentages by weight being expressed relative to the total weight of said support, b) impregnation of the support prepared according to step a) with at least one solution containing at least one precursor of at least one metal selected from group VIII metals and group VIB metals, used alone or as a mixture, c) at least one ripening step, and d) at least one drying step carried out at a temperature below 150° C., without a subsequent calcining step. The present invention also relates to a process for hydrocracking hydrocarbon feeds using the catalyst prepared according to the method of preparation according to the invention.Type: ApplicationFiled: November 23, 2012Publication date: November 6, 2014Applicant: IFP ENERGIES NOUVELLESInventors: Audrey Bonduelle, Emmanuelle Guillon, Magalie Roy-Auberger
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Patent number: 8845881Abstract: The invention relates to a process for the production of middle distillates from a paraffinic feedstock that is produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one zeolite that has at least one series of channels of which the opening is defined by a ring with 12 oxygen atoms modified by a) a stage for introducing at least one alkaline cation that belongs to group IA or IIA of the periodic table, b) a stage for treatment of said zeolite in the presence of at least one molecular compound that contains at least one silicon atom, c) at least one stage for partial exchange of said alkaline cations by NH4+ cations such that the remaining content of alkaline cations in the modified zeolite at the end of stage c) is such that the alkaline cation/aluminum molar ratioType: GrantFiled: October 13, 2010Date of Patent: September 30, 2014Assignees: IFP Energies Nouvelles, ENI S.p.A.Inventors: Laurent Simon, Christophe Bouchy
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Patent number: 8778171Abstract: This invention relates to hydrocracking catalysts utilizing stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 ?m. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more. This invention also relates to the use of such catalysts in hydrocracking processes for the conversion of heavy oils into lighter fuel products. The invention is particularly suited for the selective production of diesel range products from gas oil range feedstock materials under hydrocracking conditions.Type: GrantFiled: March 6, 2012Date of Patent: July 15, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Christopher G. Oliveri, Wenyih Frank Lai, Ajit B. Dandekar, Scott J. Weigel, Jason Wu, Robert E. Kay
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Patent number: 8747655Abstract: A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations.Type: GrantFiled: December 17, 2013Date of Patent: June 10, 2014Assignee: UOP LLCInventors: Mark A. Miller, Christopher P. Nicholas, Stephen T. Wilson
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Publication number: 20140124410Abstract: A hydrocracking catalyst having a support of a composite of mesoporous materials, molecular sieves and alumina, is used in the last bed of a multi-bed system for treating heavy crude oils and residues and is designed to increase the production of intermediate distillates having boiling points in a temperature range of 204° C. to 538° C., decrease the production of the heavy fraction (>538° C.), and increase the production of gasoline fraction (<204° C.). The feedstock to be processed in the last bed contains low amounts of metals and is lighter than the feedstock that is fed to the first catalytic bed.Type: ApplicationFiled: November 6, 2013Publication date: May 8, 2014Inventors: Patricia RAYO MAYORAL, Jorge ANCHEYTA JUAREZ, Gustavo Jesus MARROQUIN SANCHEZ, Guillermo CENTENO NOLASCO, Jorge Fernando RAMIREZ SOLIS
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Publication number: 20140124411Abstract: The hydrocracking catalyst of the present invention is a hydrocracking catalyst comprising a catalyst support comprising a zeolite and an amorphous composite metal oxide having solid acidity, and at least one active metal supported by the catalyst support and selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the hydrocracking catalyst contains a carbonaceous substance comprising a carbon atom, and the content of the carbonaceous substance in the hydrocracking catalyst is 0.05 to 1% by mass in terms of the carbon atom.Type: ApplicationFiled: March 26, 2012Publication date: May 8, 2014Applicants: JAPAN OIL, GAS AND METALS NATIONAL CORPORATION, INPEX CORPORATION, NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD., JAPAN PETROLEUM EXPLORATION CO., LTD., COSMO OIL CO., LTD., JX NIPPON OIL & ENERGY CORPORATIONInventors: Yuichi Tanaka, Takuya Nitsuma, Kazuhiko Tasaka, Marie Iwama
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Patent number: 8696886Abstract: A new family of crystalline microporous silicometallophosphates designated MAPSO-64 and modified forms thereof have been synthesized. These silicometallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as ETMA+ or DEDMA+, M is an alkaline earth or transition metal cation of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The MAPSO-64 compositions are characterized by a BPH framework topology and have catalytic properties for carrying out various hydrocarbon conversion processes, and separation properties for separating at least one component.Type: GrantFiled: October 16, 2013Date of Patent: April 15, 2014Assignee: UOP LLCInventors: Gregory J. Lewis, Lisa M. Knight, Paulina Jakubczak, Justin E. Stanczyk
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Patent number: 8691080Abstract: One exemplary embodiment can include a slurry hydrocracking process. The process can include combining one or more hydrocarbons and a slurry hydrocracking catalyst as a feed to a slurry hydrocracking reaction zone, fractionating an effluent from the slurry hydrocracking reaction zone, separating the pitch from at least a portion of the slurry hydrocracking catalyst, and recycling the suspension to the slurry hydrocracking reaction zone. The slurry hydrocracking catalyst may include a support. Fractionating the effluent may provide a light vacuum gas oil, a heavy vacuum gas oil, and a mixture comprising a pitch and the slurry hydrocracking catalyst. Generally, the separated slurry hydrocracking catalyst is comprised in a suspension.Type: GrantFiled: June 10, 2010Date of Patent: April 8, 2014Assignee: UOP LLCInventor: Robert Haizmann
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Patent number: 8685231Abstract: The invention provides a process for converting a paraffinic feedstock comprising at least 50 wt % of compounds boiling above 370° C., a paraffin content of at least 60 wt %, an aromatics content below 1 wt %, a naphthenic content below 2 wt %, a nitrogen content below 0.1 wt %, and a sulphur content below 0.1 wt %, comprising: (a) reacting the feedstock with hydrogen at a temperature between 175 and 400° C. and a pressure between 20 and 100 bar using a catalyst comprising 0.005 to 5.0 wt % of a Group VIII noble metal on a carrier comprising 0.1-15 wt % zeolite beta and at least 40 wt % amorphous silica-alumina (b) withdrawing the effluent (c) subjecting the effluent to a fractionation step to form a heavy fraction, an intermediate fraction, and a light fraction; and (d) providing at least part of the heavy fraction to the reaction zone.Type: GrantFiled: November 23, 2010Date of Patent: April 1, 2014Assignee: Shell Oil CompanyInventors: Jolinde Machteld Van De Graaf, Arend Hoek, Johannes Petrus De Jonge, Wiebe Sjoerd Kijlstra, Antonius Adrianus Maria Roovers, Jelle Rudolf Anne Sietsma, Johannes Anthonius Robert Van Veen
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Publication number: 20140083907Abstract: The regenerated hydrocracking catalyst according to the present invention is a regenerated hydrocracking catalyst prepared by regenerating a used hydrocracking catalyst including: a catalyst support containing zeolite and an amorphous composite metal oxide having solid acidity; and at least one active metal supported by the catalyst support, selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the regenerated hydrocracking catalyst contains 0.05 to 1% by mass of a carbonaceous substance in terms of carbon atoms based on the entire mass of the catalyst.Type: ApplicationFiled: March 26, 2012Publication date: March 27, 2014Applicants: JAPAN OIL, GAS AND METALS NATIONAL CORPORATION, INPEX CORPORATION, NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD., JAPAN PETROLEUM EXPLORATION CO., LTD., COSMO OIL CO., LTD., JX NIPPON OIL & ENERGY CORPORATIONInventors: Yuichi Tanaka, Takuya Niitsuma, Kazuhiko Tasaka, Marie Iwama
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Publication number: 20140005031Abstract: Inorganic material having at least two elementary spherical particles, each of said spherical metallic particles: a polyoxometallate with formula (XxMmOyHh)q?, where H is hydrogen, O is oxygen, X is phosphorus, silicon, boron, nickel or cobalt and M is one or more vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x is 0, 1, 2 or 4, m is 5, 6, 7, 8, 9, 10, 11, 12 or 18, y is 17 to 72, h is 0 to 12 and q is 1 to 20.Type: ApplicationFiled: December 15, 2011Publication date: January 2, 2014Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, IFP ENERGIES NOUVELLES, UNIVERSITE PIERRE ET MARIE CURIEInventors: Alexandra Chaumonnot, Clement Sanchez, Cedric Boissiere, Frederic Colbeau-Justin, Karin Marchand, Elodie Devers, Audrey Bonduelle, Denis Uzio, Antoine Daudin, Bertrand Guichard, Denis Uzio, Antoine Daudin
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Publication number: 20140004024Abstract: A new family of crystalline microporous metallophosphates designated AlPO-57 has been synthesized. These metallophosphates are represented by the empirical formula R+rMmn+EPxSiyOz where R is an organoammonium cation such as the DEDMA+, M is a divalent framework metal such as an alkaline earth or transition metal, and E is a framework element such as aluminum or gallium. The microporous AlPO-57 compositions are characterized by a new unique ABC-6 net structure and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.Type: ApplicationFiled: June 29, 2012Publication date: January 2, 2014Applicant: UOP LLCInventors: Gregory J. Lewis, Lisa M. Knight, Paulina Jakubczak, Justin E. Stanczyk
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Publication number: 20130299388Abstract: The invention relates to a method for preparing a hydroconversion catalyst based on mesoporous silica or silica-alumina, comprising the following steps: (A) deposition of alumina on a mesoporous material having interconnected pores by treatment with at least one aluminium-based reactant, so as to obtain a compound having a Si/Al ratio of between 0.1 and 1000; (B) addition of at least one catalytically active species chosen from the group formed by the metals of group VIII and/or of group VIB; and (C) drying followed by thermal and/or chemical treatment according to the invention. The invention also relates to the catalyst thus obtained as well as a method of hydroconverting (hydrocracking, hydroisomerizing) a hydrocarbon feedstock, which comprises bringing the feedstock to be treated into contact with the hydroconversion catalyst according to the invention.Type: ApplicationFiled: December 23, 2011Publication date: November 14, 2013Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, TOTAL RAFFINAGE MARKETINGInventors: Metin Bulut, Régine Kenmogne-Gatchuissi, François Fajula, Jean-Pierre Dath, Sander Van Donk, Annie Finiels, Vasile Hulea
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Patent number: 8557106Abstract: This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.Type: GrantFiled: September 20, 2011Date of Patent: October 15, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: William J. Novak, Robert A. Bradway, Stuart S. Shih, Timothy L. Hilbert, Michel Daage
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Patent number: 8535515Abstract: The invention relates to a hydroconversion catalyst, which comprises a refractory oxide support, at least one metal selected from group VIII and at least one metal selected from group VIB and which is characterized in that it has at least one organic compound containing at least one oxime group of formula (I)>C?NOR1, in which R1 is selected among hydrogen and alkyl, allyl, aryl, alkylene or cycloaliphatic groups, and combinations thereof, these groups being able to be substituted by at least one electron donor group.Type: GrantFiled: August 4, 2004Date of Patent: September 17, 2013Assignee: Total FranceInventors: Thierry Cholley, Jean-Pierre Dath
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Publication number: 20130153465Abstract: Systems and methods that include providing, e.g., obtaining or preparing, a material that includes a hydrocarbon carried by an inorganic substrate, and exposing the material to a plurality of energetic particles, such as accelerated charged particles, such as electrons or ions.Type: ApplicationFiled: February 15, 2013Publication date: June 20, 2013Applicant: XYLECO, INC.Inventor: Marshall Medoff
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Patent number: 8460540Abstract: A hydrocracking catalyst comprising zeolite crystallized as a layer on the surface of a porous alumina-containing matrix, said zeolite-layered matrix arranged in a configuration to provide macropores in which the zeolite layer is provided on the walls of the macropores. Hydrogenating metals can be incorporated into the catalyst.Type: GrantFiled: February 26, 2007Date of Patent: June 11, 2013Assignee: BASF CorporationInventors: David M. Stockwell, Bruce A. Lerner
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Publication number: 20130105363Abstract: This invention describes a process for the production of middle distillates comprising at least one hydrocracking stage that oligomerizes a paraffinic feedstock produced by Fischer-Tropsch synthesis, said process using a catalyst that comprises at least one hydrogenating-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, by themselves or in a mixture, and a substrate that comprises a beta zeolite in the form of crystallites with a mean size that is less than 100 nm dispersed in at least one porous mineral matrix, whereby said beta zeolite has a mesopore volume of less than 0.4 ml/g.Type: ApplicationFiled: October 26, 2012Publication date: May 2, 2013Applicants: UNIVERSITE DE POITIERS, IFP ENERGIES NOUVELLES, C.N.R.S.Inventors: Universite De Poitiers, C.N.R.S., IFP Energies nouvelles
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Patent number: 8366911Abstract: The present invention provides a method of producing a liquid fuel enabling production of middle distillate at a high yield from a feed oil containing paraffinic hydrocarbons having 20 to 100 carbon atoms as main components without losing the high cracking activity and also enabling provision of high quality gas oil included in the middle distillate. A feed oil containing paraffinic hydrocarbons having 20 to 100 carbon atoms as main components is subjected to hydrotreating in the present of a prespecified hydrotreating catalyst and under the conditions for hydrotreating including a temperature of 200 to 350° C., a liquid hourly space velocity of 0.1 to 5.0 h?1, and a partial pressure of hydrogen of 0.5 to 8 MPa to obtain an effluent oil, and then the effluent oil is fractionated to obtain middle distillate including a gas oil with a cetane number of 75 or over and a pour point of ?27.5° C. or below at a yield of 55% or over against a total weight of the feed oil.Type: GrantFiled: April 26, 2008Date of Patent: February 5, 2013Assignees: Nippon Oil Corporation, JGC Catalysts & Chemicals Ltd.Inventors: Hiroyuki Seki, Masahiro Higashi, Sumio Saito, Ryuzo Kuroda, Takashi Kameoka
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Patent number: 8334231Abstract: The present invention provides a hydrocracking catalyst comprising a moulded composite support of a zeolite molecular sieve with alumina, at least one of VIII Group metal components, at least one of VIB Group metal components and an organic additive; said organic additive is one or more compounds selected from the group consisting of oxygen-containing or nitrogen-containing organic compounds; the content of said zeolite molecular sieve is 3˜60 wt %, the content of said alumina is 10˜80 wt %, and the content of said organic additive is 0.1˜40 wt % based on the weight of said catalyst; the content of said VIII Group metal component is 1˜15 wt % and the content of said VIB Group metal component is 5˜40 wt % as calculated on oxide and based on the weight of said catalyst. The present invention relates also to a preparation method of said hydrocracking catalyst and use of the catalyst in the hydrocracking process of hydrocarbon oil.Type: GrantFiled: April 26, 2006Date of Patent: December 18, 2012Assignees: China Petroleum and Chemical Corporation, Research Institute of Petroleum Processing, SINOPECInventors: Yichao Mao, Hong Nie, Jianwei Dong, Zhenlin Xiong, Zhihai Hu, Yahua Shi, Dadong Li
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Patent number: 8329610Abstract: The present invention relates to a hydrogenation catalyst composition, process for preparing the same and use thereof. The composition comprises a hydrogenation catalyst, an organonitrogen compound in an amount of 0.01%-20% by weight of the catalyst, a sulfiding agent in an amount of 30%-150% by weight of the sulfur-requiring amount calculated theoretically of the hydrogenation catalyst, and an organic solvent in an amount of 0.1%-50% by weight of the catalyst. The preparation process comprises introducing the required substances onto the hydrogenation catalyst in oxidation state. By introduction of the organonitrogen compound, sulfur and organic solvent, the hydrogenation catalyst composition of the present invention may further increase the sulfur-maintaining ratio of the catalyst during the activation, slow down the concentrative exothermic phenomenon, decrease the rate of temperature rise of the catalyst bed layer, and improve the activity of the catalyst.Type: GrantFiled: November 14, 2006Date of Patent: December 11, 2012Assignees: China Petroleum & Chemical Corporation, Fushun Research Institute of Petroleum and Petrochemicals, Sinopec Corp.Inventors: Yulan Gao, Xiangchen Fang, Gang Wang, Fenglan Cao, Chonghui Li, Guang Chen
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Patent number: 8318006Abstract: The present invention concerns an improved once-through process for hydrocracking hydrocarbon-containing feeds with high nitrogen contents, with partial elimination of ammonia, for example by a hot flash located between the hydrorefining zone and the hydrocracking zone. Said hot flash drum functions at a pressure close to that of the hydrorefining reactor and at a temperature in the range from 150° C. to the hydrorefining reactor outlet temperature.Type: GrantFiled: October 15, 2002Date of Patent: November 27, 2012Assignee: IFP Energies NouvellesInventors: Eric Benazzi, Pierre Marion, Christophe Gueret
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Patent number: 8288599Abstract: Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.Type: GrantFiled: June 29, 2009Date of Patent: October 16, 2012Assignee: KiOR, Inc.Inventors: Steve Yanik, Paul O'Connor, Robert Bartek
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Publication number: 20120193270Abstract: Provided is a catalyst for hydrocracking of heavy oil which is excellent in both functions of cracking activity and desulfurization activity with respect to heavy oil by striking a balance between the cracking activity and desulfurization activity and which includes a support including a crystalline aluminosilicate and a porous inorganic oxide excluding the crystalline aluminosilicate, with an active metal being supported on the support, in which (a) the support includes the crystalline aluminosilicate in an amount of 45% by mass or greater and smaller than 60% by mass and the porous inorganic oxide excluding the crystalline aluminosilicate in an amount of greater than 40% by mass and 55% by mass or smaller, based on the sum of an amount of the crystalline aluminosilicate and an amount of the porous inorganic oxide excluding the crystalline aluminosilicate, (b) the active metal is at least one kind of metal selected from metals belonging to Groups 6, 8, 9, and 10 of the Periodic Table, and (c) the catalyst foType: ApplicationFiled: August 2, 2010Publication date: August 2, 2012Inventors: Kazuhiro Inamura, Akira Ilno, Nobuyuki Takahashi, Yoji Sunagawa, Mitsunori Watabe, Yuichi Yamahata, Shinya Eura, Yuji Shirahama
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Patent number: 8231778Abstract: Methods are disclosed for hydrocracking processes that convert a significant portion of a heavy hydrocarbon feedstock such as vacuum gas oil (VGO) to lower molecular weight, lower boiling hydrocarbons. In addition to molecular weight reduction, the processes also substantially reduce the pour point of a recovered higher boiling fraction or unconverted oil, all or a portion of which may be used as a lube base stock, optionally after one or more further treatment steps such as hydrofinishing. The ability to reduce the pour point, through hydroisomerization, of the higher boiling fraction greatly improves the quality of this fraction, or unconverted oil, for use in lube base stock preparation. Advantageously, separate, conventional hydroisomerization and/or dewaxing steps, often requiring a noble metal catalyst, may be avoided in particular embodiments disclosed herein.Type: GrantFiled: December 31, 2008Date of Patent: July 31, 2012Assignee: UOP LLCInventor: Hemant B. Gala
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Patent number: 8202815Abstract: In one embodiment, a catalyst composition comprises from about 5 weight percent to about 70 weight percent of silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal. In another embodiment, a method for processing hydrocarbons comprises hydro-treating the hydrocarbons in the presence of a catalyst composition, wherein the catalyst comprises from about 5 weight percent to about 70 weight percent silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal.Type: GrantFiled: December 26, 2008Date of Patent: June 19, 2012Assignee: General Electric CompanyInventors: Gregg Anthony Deluga, Daniel Lawrence Derr
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Patent number: 8187456Abstract: An improved process for hydrocracking heavy petroleum feedstocks wherein hydrogen-containing streams associated with a hydrocracker are subjected to rapid cycle pressure swing adsorption having a cycle time of less than 30 S.Type: GrantFiled: January 23, 2006Date of Patent: May 29, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: John W. Viets, Narasimhan Sundaram, Bal K. Kaul, David L. Stern
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Patent number: 8137532Abstract: The invention concerns a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises 0.2% to 2.5% by weight of an oxide of a doping element selected from boron, phosphorus, silicon, at least one hydrodehydrogenating element selected from the group formed by noble elements from group VIII of the periodic table, a non-zeolitic support based on silica-alumina containing more than 5% by weight and 95% by weight or less of silica (SiO2), specifically defined pore characteristics, a BET specific surface area in the range 100 to 550 m2/g, and with an X ray diffraction diagram which contains at least the characteristic principal peaks of at least one of the transition aluminas included in the group composed of alpha, rho, khi, eta, gamma, kappa, theta and delta aluminas.Type: GrantFiled: December 14, 2006Date of Patent: March 20, 2012Assignee: IFP Energies NouvellesInventors: Patrick Euzen, Christophe Gueret
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Publication number: 20120055846Abstract: Process of preparing a hydrocracking catalyst carrier comprising amorphous binder and zeolite Y, which process comprises subjecting zeolite Y having a silica to alumina molar ratio of at least 10 to calcination at a temperature of from 700 to 1000° C., hydrocracking catalyst carrier comprising amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10, the infrared spectrum of which catalyst has a peak at 3690 cm?1, substantially reduced peaks at 3630 cm?1 and 3565 cm?1 and no peak at 3600 cm?1, hydrocracking catalyst carrier comprising an amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10, which catalyst has an acidity as measured by exchange with perdeuterated benzene of at most 20 micro-mole/gram, hydrocracking catalyst derived from such carrier and hydrocracking process with the help of such catalyst.Type: ApplicationFiled: April 15, 2010Publication date: March 8, 2012Inventors: László Domokos, Cornelis Ouwehand