Lubricating Oils Patents (Class 208/18)
  • Patent number: 8846991
    Abstract: The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C. The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.
    Type: Grant
    Filed: June 17, 2010
    Date of Patent: September 30, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Teresa P. Karjala, Selim Yalvac, Thomas Karjala, Daniel D. VanderLende, Brian W. Kolthammer, James C. Stevens, Charles F. Diehl
  • Patent number: 8795112
    Abstract: An oil-free chain is constructed by alternately connecting a pair of outer link plates connected using pins and a pair of inner link plates connected using oil-impregnated bushings into which the adjacent pins of the outer link plates adjacent to the inner link plates are fitted. The oil-impregnated bushings are impregnated with a lubricant having a kinematic viscosity in the range of ISO-VG grade 46 to 460, the weight % of an ingredient having the highest content among the elution ingredients obtained by the GPC method is 95 wt % or more, Mn is 800 or more and 2300 or less, and the ratio of Mw to Mn is 1.0 or more and 1.3 or less. Oil film breakage at the sliding portions of the bushings is suppressed from occurring and the oil film strength is high such that an oil-free chain has a sufficiently long abrasion elongation-resistant life.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: August 5, 2014
    Assignee: Tsubakimoto Chain Co.
    Inventor: Koji Tanaka
  • Patent number: 8784642
    Abstract: A lubricating oil composition of SAE viscosity grade 0W20 which comprises a base oil and additive components comprising a nitrogen-containing ashless dispersant, an alkaline earth metal-containing detergent, a phosphorus-containing wear inhibitor, an oxidation inhibitor and a viscosity index improver and which shows a viscosity index of 200-240, a HTHS viscosity of not less than 2.9 mPa·s s at 150° C. and a Noack evaporation loss of not more than 13% favorably gives a high fuel economy and high wear inhibition to a four cycle gasoline engine of motorcycles and a diesel engine mounted on motor cars equipped with an exhaust gas post-processing apparatus.
    Type: Grant
    Filed: November 11, 2011
    Date of Patent: July 22, 2014
    Assignee: Chevron Japan Ltd.
    Inventors: Hiroki Andoh, Morikuni Nakazato
  • Patent number: 8784643
    Abstract: We provide a base stock comprising hydrocarbons with consecutive numbers of carbon atoms, wherein the base stock has a boiling range from 388 to 538° C., a VI from 105 to less than 130, and a Noack volatility from 5 to 11.5 wt % or a CCS VIS at ?25° C. from 2000 to 4000 mPa·s. We also provide a base stock slate comprising the base stock and an additional base stock having an additional boiling range from 371 to 496° C., and other properties.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: July 22, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: John Michael Rosenbaum, Brent K Lok, Kathy Ann Helling, Steven Lee, Ryan Joseph Schexnaydre, Susan Marjorie Abernathy
  • Patent number: 8754016
    Abstract: The lubricating base oil of the invention is characterized by having an urea adduct value of not greater than 4% by mass and a viscosity index of 100 or greater. The process for production of a lubricating base oil according to the invention is characterized by comprising a step of hydrocracking/hydroisomerization of a stock oil containing normal paraffins, until the obtained treatment product has an urea adduct value of not greater than 4% by mass and a viscosity index of 100 or greater. A lubricating oil composition according to the invention is characterized by comprising the lubricating base oil of the invention.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: June 17, 2014
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Kazuo Tagawa, Shinichi Shirahama, Masahiro Taguchi
  • Patent number: 8747650
    Abstract: Provided are formulations, methods of making, and methods of using one or more Fischer-Tropsch Base Oils of the present invention in a low sulfur, low sulfated ash, and low phosphorus engine lubricant to enhance thermal stability of the lubricant as well as the high-temperature performance of an engine housing the lubricant.
    Type: Grant
    Filed: December 21, 2006
    Date of Patent: June 10, 2014
    Assignee: Chevron Oronite Technology B.V.
    Inventors: Jeroen Van Leeuwen, Peter Kleijwegt
  • Patent number: 8734725
    Abstract: A system for producing enhanced wax alternatives, including a high shear device comprising a rotor and a stator, and configured to process petroleum wax and base oil with a hydrogen-containing gas under shearing conditions to form a feedstock, wherein at least one of the rotor and the stator comprises a toothed surface; and a reactor comprising a reactor inlet and a reactor outlet, and configured for hydrogenation of the feedstock for a time sufficient to produce enhanced hydrogenated products, wherein the high shear device is in fluid communication with the reactor, whereby the feedstock is transferable therebetween.
    Type: Grant
    Filed: May 1, 2013
    Date of Patent: May 27, 2014
    Assignee: H R D Corporation
    Inventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
  • Publication number: 20140080742
    Abstract: The present invention provides a lubricating oil composition for an internal combustion engine used mainly to drive a generator and to improve the fuel economy thereof. The composition comprises (A) a base oil being a hydrocarbon base oil having a ratio (CA/CB) of the proportion of the component of 24 or fewer carbon atoms (CA) and the proportion of the component of 25 or more carbon atoms (CB) in the carbon number distribution obtained by gas chromatography distillation of 2.0 or higher, the composition having a ratio (Vs/Vk) of the 80° C. high-temperature high-shear (HTHS) viscosity (Vk) and the 150° C. HTHS viscosity (Vs) of 0.4 or higher and a 100° C. kinematic viscosity of 5.2 mm2/s or higher and 8 mm2/s or lower.
    Type: Application
    Filed: January 20, 2012
    Publication date: March 20, 2014
    Applicant: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Hiroya Miyamoto, Akira Yaguchi
  • Patent number: 8663454
    Abstract: It has been determined that sealant fluid formulations comprising a lubricant oil derived from Fischer-Tropsch waxes demonstrate performance comparable to sealant fluid comprising lubricants derived from polyalphaolefins (PAO's). The sealant fluids of the current invention can provide excellent performance properties similar to those provided by PAO based sealant fluids, but at lower cost.
    Type: Grant
    Filed: October 23, 2009
    Date of Patent: March 4, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventor: Ravindra R. Shah
  • Patent number: 8658018
    Abstract: A lubricant base oil blend having a wt % Noack volatility less than 29, comprising a) a light base oil fraction having a kinematic viscosity at 100° C. between 1.5 and 3.6, and a wt % Noack volatility both between 0 and 100 and less than a Noack Volatility Factor, and b) a petroleum-derived base oil fraction. A process to make the lubricant base oil blend having a wt % Noack volatility less than 29. Also, a pour point depressed lubricant base oil blend having a Brookfield viscosity at ?40° C. of less than 18,000 cP, comprising the light base oil fraction, a petroleum-derived base oil fraction, and a pour point depressant.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: February 25, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott C. Deskin, Brent K. Lok, Shuibo Xie, Stephen J. Miller
  • Patent number: 8642524
    Abstract: The present invention is directed to a method for controlling soot induced viscosity increase in diesel engines, by using as the diesel engine lubricant an oil formulation comprising a base oil containing about 10 to 80 wt % GTL base stock and/or base oil and/or hydrodewaxed or hydroisomerized/catalytic (or solvent) dewaxed base stock and/or base oil in combination with 20 to 90 wt % conventional Group I petroleum derived base oil, said base oil being further combined with a polymeric viscosity modifier, and to the lubricating oil which effects such control over soot induced viscosity increase.
    Type: Grant
    Filed: October 11, 2012
    Date of Patent: February 4, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Heather M. Haigh, Brandon Thomas Weldon, Jason Zhisheng Gao
  • Patent number: 8642517
    Abstract: The present invention provides a lubricating oil composition comprising: a lubricating base oil including a lubricating base oil component having a urea adduct value of 4% by mass or less, a kinematic viscosity of 25 mm2/s or less at 40° C. and a viscosity index of 120 or greater, wherein the amount of the lubricating base oil component is 10 to 100% by mass based on a total mass of the lubricating base oil, and a poly(meth)acrylate based viscosity index improver including a structural unit represented by general formula (1): wherein R1 represents hydrogen or a methyl group, and R2 represents a straight or branched hydrocarbon group with 16 or more carbon atoms, and wherein the proportion of the structural unit represented by general formula (1) is 0.5 to 70% by mole, the lubricating oil composition having a kinematic viscosity of 4 to 12 mm2/s at 100° C. and a viscosity index of 140 to 300.
    Type: Grant
    Filed: December 3, 2008
    Date of Patent: February 4, 2014
    Assignee: Nippon Oil Corporation
    Inventors: Shigeki Matsui, Akira Yaguchi
  • Patent number: 8637438
    Abstract: A lubricating oil composition for internal combustion engines comprising a base oil containing at least one component selected from an ?-olefin oligomer having 16 to 40 carbon atoms obtained by oligomerizing ?-olefin(s) having 2 to 20 carbon atoms using a metallocene catalyst, and the hydrogenated derivative thereof; an ?-olefin oligomer having 16 to 40 carbon atoms derived from an ?-olefin dimer obtained using a metallocene catalyst, and the hydrogenated derivative thereof; and the like. The lubricating oil composition has an excellent low-temperature fluidity, a low evaporativity, and a good oxidation stability.
    Type: Grant
    Filed: November 14, 2006
    Date of Patent: January 28, 2014
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Ryou Yamada
  • Patent number: 8609429
    Abstract: Methods for determining the fouling propensity of a hydrocarbon stream and for reducing fouling are provided. In one method, the fouling propensity of a hydrocarbon stream is determined by obtaining a parameter value indicative of the fouling propensity at no less than two different temperatures, and an activation energy of fouling by the hydrocarbon stream is derived therefrom. In another method, the thus obtained parameter value at no less than two different temperatures and the activation energy are used to select proper heating fluids and operating temperature and to determine whether to add an antifoulant to the hydrocarbon stream to reduce fouling at a given temperature.
    Type: Grant
    Filed: November 17, 2011
    Date of Patent: December 17, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Teh C. Ho, Glen B. Brons, Limin Song, Tahmid I. Mizan
  • Patent number: 8603953
    Abstract: The shock absorber fluid according to the invention is characterized by comprising a lubricating base oil that has a urea adduct value of not greater than 4% by mass and a viscosity index of 100 or greater. The shock absorber fluid according to the invention can exhibit a high level of all properties including viscosity-temperature characteristic, shear stability and antifoaming property.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: December 10, 2013
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Tooru Aoki, Kazuo Tagawa, Shinichi Shirahama
  • Patent number: 8562819
    Abstract: We provide a process to manufacture a base stock, comprising hydrocracking, separating, and dewaxing, wherein the base stock has a ratio of Noack volatility to CCS VIS at ?25° C. multiplied by 100 from 0.15 to 0.40. We also provide a base stock made by a process, and a base oil manufacturing plant that produces the base stock.
    Type: Grant
    Filed: June 10, 2009
    Date of Patent: October 22, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: John M. Rosenbaum, Brent K. Lok, Kathy A. Helling, Steve K. Lee, Ryan J. Schexnaydre
  • Patent number: 8540869
    Abstract: A method for forming a finished lubricant comprises selecting a target high temperature viscosity for the finished lubricant. A target high temperature viscosity for a base oil blend is selected. The target high temperature viscosity for the base oil blend is less than the target high temperature viscosity for the finished lubricant. At least two base oils from at least three viscosity grades of base oils are selected and mixed to form a base oil blend that meets the target high temperature viscosity for the base oil blend. The base oil blend is mixed with performance additive package and viscosity modifier to provide a finished lubricant that meets the target high temperature viscosity for the finished lubricant. The at least two base oils for the base oil blend having the target high temperature viscosity are selected such that less viscosity modifier is needed to meet the target high temperature viscosity of the finished lubricant.
    Type: Grant
    Filed: December 10, 2007
    Date of Patent: September 24, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: John A. Zakarian, Angelito T. Tirona
  • Patent number: 8506888
    Abstract: Embodiments disclosed herein describe a system for producing enhanced wax alternatives, the system that includes a reactor having a reactor inlet and a reactor outlet; and a high shear device having a device inlet, a device outlet, a rotor, a stator, and a catalytic surface, wherein the device outlet is in fluid communication with the reactor inlet.
    Type: Grant
    Filed: November 13, 2012
    Date of Patent: August 13, 2013
    Assignee: H R D Corporation
    Inventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
  • Patent number: 8491777
    Abstract: Embodiments disclosed herein describe a system for producing enhanced wax alternatives. The system comprises a reactor with at least one inlet and one outlet and at least one high shear mixing device with at least one inlet and one outlet. The at least one outlet of said high shear mixing device is in fluid communication with at least one inlet of said reactor. The high shear mixing device may comprise counter rotating rotors. The high shear mixing device may also comprise at least one catalytic surface. Embodiments disclosed herein also describe a method of producing enhanced wax alternatives. The method comprises (1) providing petroleum wax and base oil; (2) mixing said petroleum wax and base oil with a hydrogen-containing gas in a high shear device to form a feedstock; and (3) hydrogenating said feedstock for a time sufficient to produce enhanced hydrogenated products.
    Type: Grant
    Filed: January 22, 2010
    Date of Patent: July 23, 2013
    Assignee: H R D Corporation
    Inventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
  • Patent number: 8491778
    Abstract: Embodiments disclosed herein describe method of producing hydrogenated products, the method that includes providing a wax and an oil; processing the wax and the oil with a gas under high shear conditions to form a high shear product; and hydrogenating the high shear product to produce hydrogenated products. The wax may be a petroleum wax comprising alkane hydrocarbons with formula CnH2n+2, wherein n=20-40.
    Type: Grant
    Filed: November 12, 2012
    Date of Patent: July 23, 2013
    Assignee: H R D Corporation
    Inventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
  • Patent number: 8480880
    Abstract: A process for making a lubricating base oil having a viscosity index of at least 110, comprising the steps of: combining a waxy light neutral base oil and a wax derived from pyrolyzing a plastics feed comprising polyethylene to form a blend; hydroisomerization dewaxing the blend; and recovering the lubricating base oil from an effluent from the hydroisomerization dewaxing step.
    Type: Grant
    Filed: January 18, 2011
    Date of Patent: July 9, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen J. Miller
  • Patent number: 8480879
    Abstract: A process for producing an API Group I base oil, comprising: blending a lower quality base oil that does not meet API Group I specifications with a Fischer-Tropsch derived distillate fraction having defined pour point, viscosity index and Oxidator B, and isolating an API Group I base oil that has improved defined properties. A process for producing an API Group I base oil, consisting essentially of: (a) selecting a lower quality base oil not meeting API Group I specifications, having defined saturates, viscosity index and Oxidator BN; and (b) blending the lower quality base oil with a Group II base oil and a Fischer-Tropsch derived base oil. A process for improving the lubricating properties of a lower quality base oil. Also, a process for operating a base oil plant.
    Type: Grant
    Filed: March 13, 2008
    Date of Patent: July 9, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: John M. Rosenbaum, Brent K. Lok, David C. Kramer, John O'Brien, Stephen J. Miller
  • Patent number: 8475648
    Abstract: Processes and catalyst systems are provided for dewaxing a heavy hydrocarbon feedstock to form a lubricant base oil. A layered catalyst system of the present invention may comprise a first hydroisomerization dewaxing catalyst disposed upstream from a second hydroisomerization dewaxing catalyst. Each of the first and second hydroisomerization dewaxing catalysts may be selective for the isomerization of n-paraffins. The first hydroisomerization catalyst has a first level of selectivity for the isomerization of n-paraffins, the second hydroisomerization dewaxing catalyst has a second level of selectivity for the isomerization of n-paraffins, and a layered catalyst system comprising the first and second hydroisomerization dewaxing catalysts has a third level of selectivity for the isomerization of n-paraffins. The third level of selectivity may be higher than each of the first level of selectivity and the second level of selectivity.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: July 2, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Kamala Krishna, Guan-Dao Lei
  • Patent number: 8449760
    Abstract: A method for improving the lubricating properties of a distillate base oil characterized by a pour point of 0 degrees C. or less and a boiling range having the 10 percent point falling between about 625 degrees F. and about 790 degrees F. and the 90 percent point falling between about 725 degrees F. and about 950 degrees F., the method comprises blending with said distillate base oil a sufficient amount of a pour point depressing base oil blending component to reduce the pour point of the resulting base oil blend at least 3 degrees C. below the pour point of the distillate base oil, wherein the pour point depressing base oil blending component is an isomerized Fischer-Tropsch derived bottoms product having a pour point that is at least 3 degrees C. higher than the pour point of the distillate base oil.
    Type: Grant
    Filed: November 21, 2005
    Date of Patent: May 28, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen J. Miller
  • Patent number: 8431012
    Abstract: The present invention is directed to a heavy hydrocarbon composition useful as a heavy lubricant oil base stock and to a heavy lubricant composition derived from the heavy lubricant oil base stock that remains clear and bright even after being cooled to room temperature and stored for an extended period of time.
    Type: Grant
    Filed: October 13, 2009
    Date of Patent: April 30, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Eric B. Sirota, Roland Saeger
  • Publication number: 20130090272
    Abstract: We provide a base stock comprising hydrocarbons with consecutive numbers of carbon atoms, wherein the base stock has a boiling range from 388 to 538° C., a VI from 105 to less than 130, and a Noack volatility from 5 to 11.5 wt % or a CCS VIS at ?25° C. from 2000 to 4000 mPa·s. We also provide a base stock slate comprising the base stock and an additional base stock having an additional boiling range from 371 to 496° C. and other properties.
    Type: Application
    Filed: November 30, 2012
    Publication date: April 11, 2013
    Applicant: Chevron U.S.A. Inc.
    Inventors: John Michael Rosenbaum, Brent K. Lok, Kathy Ann Helling, Steven Lee, Ryan Joseph Schexnaydre, Susan Marjorie Abernathy
  • Patent number: 8394258
    Abstract: The invention relates to a process for producing a new type of high-quality hydrocarbon base oil of biological origin. The process of the invention comprises ketonization, hydrodeoxygenation, and isomerization steps. Fatty acids and/or fatty acid esters based on a biological raw material are preferably used as the feedstock.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: March 12, 2013
    Assignee: Neste Oil Oyj
    Inventors: Eija Koivusalmi, Johan-Fredrik Selin, Juha Moilanen
  • Patent number: 8394745
    Abstract: The present invention provides a lubricating base oil comprising saturated components of 90% by mass or greater, wherein the proportion of cyclic saturated components among the saturated components is not greater than 40% by mass, and by having a viscosity index of 110 or higher and an iodine value of not greater than 2.5. The lubricating base oil of the invention exhibits excellent viscosity-temperature characteristics and heat and oxidation stability while also allowing additives to exhibit a higher level of function when additives are included. The lubricating base oil of the invention is suitable for use in various lubricating oil fields, and is especially useful for reducing energy loss and achieving energy savings in devices in which the lubricating base oil is applied.
    Type: Grant
    Filed: March 28, 2007
    Date of Patent: March 12, 2013
    Assignees: Nippon Oil Corporation, Petroleum Energy Center
    Inventors: Takashi Sano, Shinichi Shirahama, Kazuo Tagawa, Kenichi Komiya, Shigeki Matsui, Osamu Kurosawa
  • Patent number: 8394749
    Abstract: The present invention provides a pressure-medium oil comprising at least one of a hydrocarbon compound and an ether compound and having the following properties (1) to (4): (1) a kinematic viscosity as measured at 40° C. of 2 to 30 mm2/s; (2) a viscosity index of 110 or higher; (3) a density as measured at 15° C. of 0.86 g/cm3 or less; and (4) a pour point of ?50° C. or lower. The pressure-medium oil does not solidify under an ultra-high pressure, for example, 1.5 GPa or higher, and has a low pour point and excellent compatibility with test samples and with the material of the apparatus employed in the test.
    Type: Grant
    Filed: October 30, 2006
    Date of Patent: March 12, 2013
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shoji Aoyama, Keizo Murata, Hiroshi Nagakawa, Tahei Okada
  • Patent number: 8388829
    Abstract: Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: March 5, 2013
    Assignee: Battelle Memorial Institute
    Inventors: Richard T. Hallen, Karl O. Albrecht, Heather M. Brown, James F. White
  • Patent number: 8372777
    Abstract: Method of contacting a hydrocarbon feed with a catalyst that includes one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Column 6 of the Periodic Table and a support. The support comprises from 0.01 grams to 0.2 gram of silica and from 0.80 grams to 0.99 grams of alumina per gram of support. The catalyst has a surface area of at least 340 m2/g, a pore size distribution with a median pore diameter of at most 100 ?, and at least 80% of its pore volume in pores having a pore diameter of at most 300 ? or the catalyst exhibits one or more peaks between 35 degrees and 70 degrees, and at least one of the peaks has a base width of at least 10 degrees, as determined by x-ray diffraction at 2-theta.
    Type: Grant
    Filed: March 22, 2012
    Date of Patent: February 12, 2013
    Assignee: Shell Oil Company
    Inventors: Opinder Kishan Bhan, Scott Lee Wellington
  • Patent number: 8366907
    Abstract: Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
    Type: Grant
    Filed: August 2, 2010
    Date of Patent: February 5, 2013
    Assignee: Battelle Memorial Institute
    Inventors: Richard T. Hallen, Karl O. Albrecht, Heather M. Brown, James F. White
  • Publication number: 20130001127
    Abstract: The invention provides a process to prepare very low sul-phur, very low aromatic hydrocarbon fluids having a boiling range in the range of from 100 to 400° C. and a boiling range of not more than 80° C., comprising at least the two successive steps of -deep hydrodesulphurating of middle distillate down to less than 10 ppm sulphur, and -catalytic hy-drogenating the desulphurized middle distillates of preceding step at a temperature from 80 to 180° C. and at a pressure from 60 to 160 bars.
    Type: Application
    Filed: November 19, 2010
    Publication date: January 3, 2013
    Applicant: TOTAL RAFFINAGE MARKETING
    Inventors: Christine Aubry, Joelle Nokerman
  • Patent number: 8329966
    Abstract: Synthetic base oil composition comprising dialkyl aromatic compound with alkyl side chain carbon number from C10 to C28, or preferably C11 to C24, or even more preferably, C12 to C18, wherein the branching characteristics of the alkyl side chain has a total methyl number (TMN) determined by C13 NMR spectroscopy to be from more than 2.1 to less than 3.5, or preferably from 2.15 to 3.25, or even more preferably from 2.2 to 3.0, or a branching index (BI) from more than 0.1 to less than 1.5, or more preferably, 0.15 to 1.25, or even more preferably, 0.2 to 1.0. The synthetic base oil composition has a combination of high viscometric index, low volatility, superior low temperature properties, and improved thermal/oxidation stability, and is particularly suitable to be used as a premium synthetic base stock, second base oil component, or additive for lubricant and additive package applications.
    Type: Grant
    Filed: October 10, 2007
    Date of Patent: December 11, 2012
    Assignee: Formosan Union Chemical Corp.
    Inventors: Chi-Hsing Tsai, Chien-Hsun Tsai
  • Patent number: 8318001
    Abstract: We provide a base oil comprising hydrocarbons with consecutive numbers of carbon atoms. The base oil has a boiling range from 700 to 925° F. (371 to 496° C.), a VI from 105 to 119, and either a Noack volatility less than 18 wt % or a CCS VIS at ?25° C. less than 1500 mPa·s. The base oil may have a ratio of Noack Volatility to CCS VIS at ?25° C. multiplied by 100 from 0.80 to 1.55.
    Type: Grant
    Filed: June 10, 2009
    Date of Patent: November 27, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventors: John M. Rosenbaum, Brent K. Lok, Kathy A. Helling, Ryan J. Schexnaydre, Scott C. Deskin, Susan M. Abernathy
  • Patent number: 8318993
    Abstract: A fluid blend suitable for use as a lube basestock comprises two major components: (A) a copolymer made from ethylene with one or more alpha olefins, the copolymer (i) containing not more than 50 wt % ethylene; (ii) having a number average molecular weight of from 400 to 10,000; and (iii) a molecular weight distribution <3; and (B) a polyalphaolefin fluid or a hydroprocessed oil having a VI greater than 80.
    Type: Grant
    Filed: December 15, 2005
    Date of Patent: November 27, 2012
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Margaret May-Som Wu, Jon Edmond Randolph Stanat, Kyle D. Lawrence, Richard T. Spissell, James William Gleeson, James Thomas Carey, Charles Lambert Baker
  • Patent number: 8303850
    Abstract: A rust preventive oil composition includes at least one base oil selected from the group consisting of mineral oils and synthetic oils, having a 5%-distillation temperature of not less than 140° C. and not more than 250° C., a 95%-distillation temperature of 250° C. or less, a difference between the 5%-distillation temperature and the 95%-distillation temperature of 90° C. or less, an aromatic content of 5% by volume or less, a naphthene content of not less than 30% by volume and not more than 95% by volume, a density at 15° C. of 0.75 g/cm3 or more, and a kinematic viscosity at 40° C. of not less than 0.3 mm2/s and not more than 5.0 mm2/s; at least one base oil selected from the group consisting of mineral oils and synthetic oils; and a rust-preventing additive.
    Type: Grant
    Filed: July 14, 2010
    Date of Patent: November 6, 2012
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Junichi Shibata, Tadaaki Motoyama, Kazuhiko Endou
  • Patent number: 8299006
    Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: October 30, 2012
    Assignee: Nippon Oil Corporation
    Inventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
  • Patent number: 8298402
    Abstract: The present invention relates to alkylphenol-aldehyde resins containing oligo- or polymers having a repeat structural unit of the formula where R1 is a branched alkyl or alkenyl radical which has from 10 to 40 carbon atoms and bears at least one carboxyl, carboxylate and/or ester group, R2 is hydrogen or R1 R3 is hydrogen or an alkoxy group of the formula -(A-O)m—H, A is a C2- to C4-alkylene group, m is from 1 to 100, R4 is hydrogen, a C1- to C11-alkyl radicals or a carboxyl group, R5 is C1-C200-alkyl or -alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or -alkenyl, n is from 1 to 100 and k is 1 or 2.
    Type: Grant
    Filed: September 22, 2006
    Date of Patent: October 30, 2012
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Carsten Cohrs, Heidi Rausch
  • Patent number: 8278255
    Abstract: In one embodiment, a lubricating oil with favorable shear stability is disclosed. The lubricating oil comprising a major amount of base stock selected from the group consisting of Group II, Group III, Group IV, Group V, and any combination thereof, a viscosity index improver comprising a polymethacrylate with a permanent shear stability index of less than 45 defined by ASTM 5621 with 10 percent polymer in a Group I mineral oil, an antioxidant additive and a corrosion additive. In a second embodiment a method of improving shear stability is disclosed. In a third embodiment, a method of blending an oil to provide improved shear stability and favorable viscosity index is disclosed.
    Type: Grant
    Filed: March 27, 2009
    Date of Patent: October 2, 2012
    Inventor: David G. L. Holt
  • Patent number: 8268762
    Abstract: The invention provides a transmission fluid composition which has a kinematic viscosity as determined at 100° C. of 2 to 10 mm2/s and a viscosity index of 150 or higher and which satisfies a relationship between kinematic viscosity and NOACK evaporation loss amount represented by formula (I): X/3+Y?6.33??(I) (wherein X represents a kinematic viscosity (mm2/s) as determined at 100° C., and Y represents a NOACK evaporation loss amount (mass %) at 200° C. for one hour), and a transmission fluid composition containing, as a base oil, at least one species selected from among ?-olefin oligomers produced through oligomerization of an ?-olefin through a specific method and hydrogenation products of the oligomers. Such transmission fluid compositions exhibit a very small evaporation loss despite having low viscosity, and a long metal fatigue life (e.g.
    Type: Grant
    Filed: November 15, 2006
    Date of Patent: September 18, 2012
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Hiroshi Fujita
  • Patent number: 8247360
    Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: August 21, 2012
    Assignee: Nippon Oil Corporation
    Inventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
  • Patent number: 8236740
    Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: August 7, 2012
    Assignee: Nippon Oil Corporation
    Inventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
  • Patent number: 8231778
    Abstract: Methods are disclosed for hydrocracking processes that convert a significant portion of a heavy hydrocarbon feedstock such as vacuum gas oil (VGO) to lower molecular weight, lower boiling hydrocarbons. In addition to molecular weight reduction, the processes also substantially reduce the pour point of a recovered higher boiling fraction or unconverted oil, all or a portion of which may be used as a lube base stock, optionally after one or more further treatment steps such as hydrofinishing. The ability to reduce the pour point, through hydroisomerization, of the higher boiling fraction greatly improves the quality of this fraction, or unconverted oil, for use in lube base stock preparation. Advantageously, separate, conventional hydroisomerization and/or dewaxing steps, often requiring a noble metal catalyst, may be avoided in particular embodiments disclosed herein.
    Type: Grant
    Filed: December 31, 2008
    Date of Patent: July 31, 2012
    Assignee: UOP LLC
    Inventor: Hemant B. Gala
  • Patent number: 8232233
    Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: July 31, 2012
    Assignee: Nippon Oil Corporation
    Inventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
  • Patent number: 8227385
    Abstract: The lubricating base oil of the invention has a urea adduct value of not greater than 4% by mass, a kinematic viscosity at 40° C. of 25-50 mm2/s, a viscosity index of 140 or greater, a CCS viscosity at ?35° C. of not greater than 15,000 mPa·s and a flash point of 250° C. or higher. The method for producing a lubricating base oil of the invention comprises a step of hydrocracking/hydroisomerizing a feedstock oil containing normal paraffins so as to obtain a treated product having an urea adduct value of not greater than 4% by mass, a kinematic viscosity at 40° C. of 25-50 mm2/s, a viscosity index of 140 or greater, a CCS viscosity at ?35° C. of not greater than 15,000 mPa·s and a flash point of 250° C. or higher. The lubricating oil composition of the invention comprises the lubricating base oil of the invention.
    Type: Grant
    Filed: March 23, 2009
    Date of Patent: July 24, 2012
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Kazuo Tagawa, Shinichi Shirahama, Masahiro Taguchi
  • Patent number: 8227384
    Abstract: The lubricating base oil of the invention has a kinematic viscosity at 40° C. of 7 mm2/s or greater and less than 15 mm2/s, a viscosity index of 120 or greater, a urea adduct value of not greater than 4% by mass, a BF viscosity at ?35° C. of not greater than 10,000 mP·s, a flash point of 200° C. or higher and a NOACK evaporation loss of not greater than 50% by mass. The method for producing a lubricating base oil of the invention comprises a step of hydrocracking/hydroisomerizing a feedstock oil containing normal paraffins so as to obtain a treated product having an urea adduct value of not greater than 4% by mass, a kinematic viscosity at 40° C. of 7 mm2/s or greater and less than 15 mm2/s, a viscosity index of 120 or greater, a BF viscosity at ?35° C. of not greater than 10,000 mP·s, a flash point of 200° C. or higher and a NOACK evaporation loss of not greater than 50% by mass. The lubricating oil composition of the invention comprises the lubricating base oil of the invention.
    Type: Grant
    Filed: March 23, 2009
    Date of Patent: July 24, 2012
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Kazuo Tagawa, Shinichi Shirahama, Masahiro Taguchi
  • Patent number: 8227387
    Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: July 24, 2012
    Assignee: Nippon Oil Corporation
    Inventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
  • Patent number: 8227388
    Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: July 24, 2012
    Assignee: Nippon Oil Corporation
    Inventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
  • Patent number: 8216448
    Abstract: A method for improving the lubricating properties of a distillate base oil characterized by a pour point of 0 degrees C. or less and a boiling range having the 10 percent point falling between about 625 degrees F. and about 790 degrees F. and the 90 percent point falling between about 725 degrees F. and about 950 degrees F., the method comprises blending with said distillate base oil a sufficient amount of a pour point depressing base oil blending component to reduce the pour point of the resulting base oil blend at least 3 degrees C. below the pour point of the distillate base oil, wherein the pour point depressing base oil blending component is an isomerized Fischer-Tropsch derived bottoms product having a pour point that is at least 3 degrees C. higher than the pour point of the distillate base oil.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: July 10, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen J. Miller