Lubricating Oils Patents (Class 208/18)
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Patent number: 8846991Abstract: The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C. The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.Type: GrantFiled: June 17, 2010Date of Patent: September 30, 2014Assignee: Dow Global Technologies LLCInventors: Teresa P. Karjala, Selim Yalvac, Thomas Karjala, Daniel D. VanderLende, Brian W. Kolthammer, James C. Stevens, Charles F. Diehl
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Patent number: 8795112Abstract: An oil-free chain is constructed by alternately connecting a pair of outer link plates connected using pins and a pair of inner link plates connected using oil-impregnated bushings into which the adjacent pins of the outer link plates adjacent to the inner link plates are fitted. The oil-impregnated bushings are impregnated with a lubricant having a kinematic viscosity in the range of ISO-VG grade 46 to 460, the weight % of an ingredient having the highest content among the elution ingredients obtained by the GPC method is 95 wt % or more, Mn is 800 or more and 2300 or less, and the ratio of Mw to Mn is 1.0 or more and 1.3 or less. Oil film breakage at the sliding portions of the bushings is suppressed from occurring and the oil film strength is high such that an oil-free chain has a sufficiently long abrasion elongation-resistant life.Type: GrantFiled: July 24, 2008Date of Patent: August 5, 2014Assignee: Tsubakimoto Chain Co.Inventor: Koji Tanaka
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Patent number: 8784642Abstract: A lubricating oil composition of SAE viscosity grade 0W20 which comprises a base oil and additive components comprising a nitrogen-containing ashless dispersant, an alkaline earth metal-containing detergent, a phosphorus-containing wear inhibitor, an oxidation inhibitor and a viscosity index improver and which shows a viscosity index of 200-240, a HTHS viscosity of not less than 2.9 mPa·s s at 150° C. and a Noack evaporation loss of not more than 13% favorably gives a high fuel economy and high wear inhibition to a four cycle gasoline engine of motorcycles and a diesel engine mounted on motor cars equipped with an exhaust gas post-processing apparatus.Type: GrantFiled: November 11, 2011Date of Patent: July 22, 2014Assignee: Chevron Japan Ltd.Inventors: Hiroki Andoh, Morikuni Nakazato
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Patent number: 8784643Abstract: We provide a base stock comprising hydrocarbons with consecutive numbers of carbon atoms, wherein the base stock has a boiling range from 388 to 538° C., a VI from 105 to less than 130, and a Noack volatility from 5 to 11.5 wt % or a CCS VIS at ?25° C. from 2000 to 4000 mPa·s. We also provide a base stock slate comprising the base stock and an additional base stock having an additional boiling range from 371 to 496° C., and other properties.Type: GrantFiled: November 30, 2012Date of Patent: July 22, 2014Assignee: Chevron U.S.A. Inc.Inventors: John Michael Rosenbaum, Brent K Lok, Kathy Ann Helling, Steven Lee, Ryan Joseph Schexnaydre, Susan Marjorie Abernathy
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Patent number: 8754016Abstract: The lubricating base oil of the invention is characterized by having an urea adduct value of not greater than 4% by mass and a viscosity index of 100 or greater. The process for production of a lubricating base oil according to the invention is characterized by comprising a step of hydrocracking/hydroisomerization of a stock oil containing normal paraffins, until the obtained treatment product has an urea adduct value of not greater than 4% by mass and a viscosity index of 100 or greater. A lubricating oil composition according to the invention is characterized by comprising the lubricating base oil of the invention.Type: GrantFiled: March 25, 2008Date of Patent: June 17, 2014Assignee: JX Nippon Oil & Energy CorporationInventors: Kazuo Tagawa, Shinichi Shirahama, Masahiro Taguchi
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Patent number: 8747650Abstract: Provided are formulations, methods of making, and methods of using one or more Fischer-Tropsch Base Oils of the present invention in a low sulfur, low sulfated ash, and low phosphorus engine lubricant to enhance thermal stability of the lubricant as well as the high-temperature performance of an engine housing the lubricant.Type: GrantFiled: December 21, 2006Date of Patent: June 10, 2014Assignee: Chevron Oronite Technology B.V.Inventors: Jeroen Van Leeuwen, Peter Kleijwegt
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Patent number: 8734725Abstract: A system for producing enhanced wax alternatives, including a high shear device comprising a rotor and a stator, and configured to process petroleum wax and base oil with a hydrogen-containing gas under shearing conditions to form a feedstock, wherein at least one of the rotor and the stator comprises a toothed surface; and a reactor comprising a reactor inlet and a reactor outlet, and configured for hydrogenation of the feedstock for a time sufficient to produce enhanced hydrogenated products, wherein the high shear device is in fluid communication with the reactor, whereby the feedstock is transferable therebetween.Type: GrantFiled: May 1, 2013Date of Patent: May 27, 2014Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Publication number: 20140080742Abstract: The present invention provides a lubricating oil composition for an internal combustion engine used mainly to drive a generator and to improve the fuel economy thereof. The composition comprises (A) a base oil being a hydrocarbon base oil having a ratio (CA/CB) of the proportion of the component of 24 or fewer carbon atoms (CA) and the proportion of the component of 25 or more carbon atoms (CB) in the carbon number distribution obtained by gas chromatography distillation of 2.0 or higher, the composition having a ratio (Vs/Vk) of the 80° C. high-temperature high-shear (HTHS) viscosity (Vk) and the 150° C. HTHS viscosity (Vs) of 0.4 or higher and a 100° C. kinematic viscosity of 5.2 mm2/s or higher and 8 mm2/s or lower.Type: ApplicationFiled: January 20, 2012Publication date: March 20, 2014Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Hiroya Miyamoto, Akira Yaguchi
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Patent number: 8663454Abstract: It has been determined that sealant fluid formulations comprising a lubricant oil derived from Fischer-Tropsch waxes demonstrate performance comparable to sealant fluid comprising lubricants derived from polyalphaolefins (PAO's). The sealant fluids of the current invention can provide excellent performance properties similar to those provided by PAO based sealant fluids, but at lower cost.Type: GrantFiled: October 23, 2009Date of Patent: March 4, 2014Assignee: Chevron U.S.A. Inc.Inventor: Ravindra R. Shah
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Patent number: 8658018Abstract: A lubricant base oil blend having a wt % Noack volatility less than 29, comprising a) a light base oil fraction having a kinematic viscosity at 100° C. between 1.5 and 3.6, and a wt % Noack volatility both between 0 and 100 and less than a Noack Volatility Factor, and b) a petroleum-derived base oil fraction. A process to make the lubricant base oil blend having a wt % Noack volatility less than 29. Also, a pour point depressed lubricant base oil blend having a Brookfield viscosity at ?40° C. of less than 18,000 cP, comprising the light base oil fraction, a petroleum-derived base oil fraction, and a pour point depressant.Type: GrantFiled: December 20, 2006Date of Patent: February 25, 2014Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott C. Deskin, Brent K. Lok, Shuibo Xie, Stephen J. Miller
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Patent number: 8642524Abstract: The present invention is directed to a method for controlling soot induced viscosity increase in diesel engines, by using as the diesel engine lubricant an oil formulation comprising a base oil containing about 10 to 80 wt % GTL base stock and/or base oil and/or hydrodewaxed or hydroisomerized/catalytic (or solvent) dewaxed base stock and/or base oil in combination with 20 to 90 wt % conventional Group I petroleum derived base oil, said base oil being further combined with a polymeric viscosity modifier, and to the lubricating oil which effects such control over soot induced viscosity increase.Type: GrantFiled: October 11, 2012Date of Patent: February 4, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Heather M. Haigh, Brandon Thomas Weldon, Jason Zhisheng Gao
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Patent number: 8642517Abstract: The present invention provides a lubricating oil composition comprising: a lubricating base oil including a lubricating base oil component having a urea adduct value of 4% by mass or less, a kinematic viscosity of 25 mm2/s or less at 40° C. and a viscosity index of 120 or greater, wherein the amount of the lubricating base oil component is 10 to 100% by mass based on a total mass of the lubricating base oil, and a poly(meth)acrylate based viscosity index improver including a structural unit represented by general formula (1): wherein R1 represents hydrogen or a methyl group, and R2 represents a straight or branched hydrocarbon group with 16 or more carbon atoms, and wherein the proportion of the structural unit represented by general formula (1) is 0.5 to 70% by mole, the lubricating oil composition having a kinematic viscosity of 4 to 12 mm2/s at 100° C. and a viscosity index of 140 to 300.Type: GrantFiled: December 3, 2008Date of Patent: February 4, 2014Assignee: Nippon Oil CorporationInventors: Shigeki Matsui, Akira Yaguchi
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Patent number: 8637438Abstract: A lubricating oil composition for internal combustion engines comprising a base oil containing at least one component selected from an ?-olefin oligomer having 16 to 40 carbon atoms obtained by oligomerizing ?-olefin(s) having 2 to 20 carbon atoms using a metallocene catalyst, and the hydrogenated derivative thereof; an ?-olefin oligomer having 16 to 40 carbon atoms derived from an ?-olefin dimer obtained using a metallocene catalyst, and the hydrogenated derivative thereof; and the like. The lubricating oil composition has an excellent low-temperature fluidity, a low evaporativity, and a good oxidation stability.Type: GrantFiled: November 14, 2006Date of Patent: January 28, 2014Assignee: Idemitsu Kosan Co., Ltd.Inventor: Ryou Yamada
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Patent number: 8609429Abstract: Methods for determining the fouling propensity of a hydrocarbon stream and for reducing fouling are provided. In one method, the fouling propensity of a hydrocarbon stream is determined by obtaining a parameter value indicative of the fouling propensity at no less than two different temperatures, and an activation energy of fouling by the hydrocarbon stream is derived therefrom. In another method, the thus obtained parameter value at no less than two different temperatures and the activation energy are used to select proper heating fluids and operating temperature and to determine whether to add an antifoulant to the hydrocarbon stream to reduce fouling at a given temperature.Type: GrantFiled: November 17, 2011Date of Patent: December 17, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Teh C. Ho, Glen B. Brons, Limin Song, Tahmid I. Mizan
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Patent number: 8603953Abstract: The shock absorber fluid according to the invention is characterized by comprising a lubricating base oil that has a urea adduct value of not greater than 4% by mass and a viscosity index of 100 or greater. The shock absorber fluid according to the invention can exhibit a high level of all properties including viscosity-temperature characteristic, shear stability and antifoaming property.Type: GrantFiled: March 25, 2008Date of Patent: December 10, 2013Assignee: JX Nippon Oil & Energy CorporationInventors: Tooru Aoki, Kazuo Tagawa, Shinichi Shirahama
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Patent number: 8562819Abstract: We provide a process to manufacture a base stock, comprising hydrocracking, separating, and dewaxing, wherein the base stock has a ratio of Noack volatility to CCS VIS at ?25° C. multiplied by 100 from 0.15 to 0.40. We also provide a base stock made by a process, and a base oil manufacturing plant that produces the base stock.Type: GrantFiled: June 10, 2009Date of Patent: October 22, 2013Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Brent K. Lok, Kathy A. Helling, Steve K. Lee, Ryan J. Schexnaydre
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Patent number: 8540869Abstract: A method for forming a finished lubricant comprises selecting a target high temperature viscosity for the finished lubricant. A target high temperature viscosity for a base oil blend is selected. The target high temperature viscosity for the base oil blend is less than the target high temperature viscosity for the finished lubricant. At least two base oils from at least three viscosity grades of base oils are selected and mixed to form a base oil blend that meets the target high temperature viscosity for the base oil blend. The base oil blend is mixed with performance additive package and viscosity modifier to provide a finished lubricant that meets the target high temperature viscosity for the finished lubricant. The at least two base oils for the base oil blend having the target high temperature viscosity are selected such that less viscosity modifier is needed to meet the target high temperature viscosity of the finished lubricant.Type: GrantFiled: December 10, 2007Date of Patent: September 24, 2013Assignee: Chevron U.S.A. Inc.Inventors: John A. Zakarian, Angelito T. Tirona
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Patent number: 8506888Abstract: Embodiments disclosed herein describe a system for producing enhanced wax alternatives, the system that includes a reactor having a reactor inlet and a reactor outlet; and a high shear device having a device inlet, a device outlet, a rotor, a stator, and a catalytic surface, wherein the device outlet is in fluid communication with the reactor inlet.Type: GrantFiled: November 13, 2012Date of Patent: August 13, 2013Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Patent number: 8491777Abstract: Embodiments disclosed herein describe a system for producing enhanced wax alternatives. The system comprises a reactor with at least one inlet and one outlet and at least one high shear mixing device with at least one inlet and one outlet. The at least one outlet of said high shear mixing device is in fluid communication with at least one inlet of said reactor. The high shear mixing device may comprise counter rotating rotors. The high shear mixing device may also comprise at least one catalytic surface. Embodiments disclosed herein also describe a method of producing enhanced wax alternatives. The method comprises (1) providing petroleum wax and base oil; (2) mixing said petroleum wax and base oil with a hydrogen-containing gas in a high shear device to form a feedstock; and (3) hydrogenating said feedstock for a time sufficient to produce enhanced hydrogenated products.Type: GrantFiled: January 22, 2010Date of Patent: July 23, 2013Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Patent number: 8491778Abstract: Embodiments disclosed herein describe method of producing hydrogenated products, the method that includes providing a wax and an oil; processing the wax and the oil with a gas under high shear conditions to form a high shear product; and hydrogenating the high shear product to produce hydrogenated products. The wax may be a petroleum wax comprising alkane hydrocarbons with formula CnH2n+2, wherein n=20-40.Type: GrantFiled: November 12, 2012Date of Patent: July 23, 2013Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Patent number: 8480880Abstract: A process for making a lubricating base oil having a viscosity index of at least 110, comprising the steps of: combining a waxy light neutral base oil and a wax derived from pyrolyzing a plastics feed comprising polyethylene to form a blend; hydroisomerization dewaxing the blend; and recovering the lubricating base oil from an effluent from the hydroisomerization dewaxing step.Type: GrantFiled: January 18, 2011Date of Patent: July 9, 2013Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller
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Patent number: 8480879Abstract: A process for producing an API Group I base oil, comprising: blending a lower quality base oil that does not meet API Group I specifications with a Fischer-Tropsch derived distillate fraction having defined pour point, viscosity index and Oxidator B, and isolating an API Group I base oil that has improved defined properties. A process for producing an API Group I base oil, consisting essentially of: (a) selecting a lower quality base oil not meeting API Group I specifications, having defined saturates, viscosity index and Oxidator BN; and (b) blending the lower quality base oil with a Group II base oil and a Fischer-Tropsch derived base oil. A process for improving the lubricating properties of a lower quality base oil. Also, a process for operating a base oil plant.Type: GrantFiled: March 13, 2008Date of Patent: July 9, 2013Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Brent K. Lok, David C. Kramer, John O'Brien, Stephen J. Miller
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Patent number: 8475648Abstract: Processes and catalyst systems are provided for dewaxing a heavy hydrocarbon feedstock to form a lubricant base oil. A layered catalyst system of the present invention may comprise a first hydroisomerization dewaxing catalyst disposed upstream from a second hydroisomerization dewaxing catalyst. Each of the first and second hydroisomerization dewaxing catalysts may be selective for the isomerization of n-paraffins. The first hydroisomerization catalyst has a first level of selectivity for the isomerization of n-paraffins, the second hydroisomerization dewaxing catalyst has a second level of selectivity for the isomerization of n-paraffins, and a layered catalyst system comprising the first and second hydroisomerization dewaxing catalysts has a third level of selectivity for the isomerization of n-paraffins. The third level of selectivity may be higher than each of the first level of selectivity and the second level of selectivity.Type: GrantFiled: June 14, 2011Date of Patent: July 2, 2013Assignee: Chevron U.S.A. Inc.Inventors: Kamala Krishna, Guan-Dao Lei
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Patent number: 8449760Abstract: A method for improving the lubricating properties of a distillate base oil characterized by a pour point of 0 degrees C. or less and a boiling range having the 10 percent point falling between about 625 degrees F. and about 790 degrees F. and the 90 percent point falling between about 725 degrees F. and about 950 degrees F., the method comprises blending with said distillate base oil a sufficient amount of a pour point depressing base oil blending component to reduce the pour point of the resulting base oil blend at least 3 degrees C. below the pour point of the distillate base oil, wherein the pour point depressing base oil blending component is an isomerized Fischer-Tropsch derived bottoms product having a pour point that is at least 3 degrees C. higher than the pour point of the distillate base oil.Type: GrantFiled: November 21, 2005Date of Patent: May 28, 2013Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller
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Patent number: 8431012Abstract: The present invention is directed to a heavy hydrocarbon composition useful as a heavy lubricant oil base stock and to a heavy lubricant composition derived from the heavy lubricant oil base stock that remains clear and bright even after being cooled to room temperature and stored for an extended period of time.Type: GrantFiled: October 13, 2009Date of Patent: April 30, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Eric B. Sirota, Roland Saeger
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Publication number: 20130090272Abstract: We provide a base stock comprising hydrocarbons with consecutive numbers of carbon atoms, wherein the base stock has a boiling range from 388 to 538° C., a VI from 105 to less than 130, and a Noack volatility from 5 to 11.5 wt % or a CCS VIS at ?25° C. from 2000 to 4000 mPa·s. We also provide a base stock slate comprising the base stock and an additional base stock having an additional boiling range from 371 to 496° C. and other properties.Type: ApplicationFiled: November 30, 2012Publication date: April 11, 2013Applicant: Chevron U.S.A. Inc.Inventors: John Michael Rosenbaum, Brent K. Lok, Kathy Ann Helling, Steven Lee, Ryan Joseph Schexnaydre, Susan Marjorie Abernathy
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Patent number: 8394258Abstract: The invention relates to a process for producing a new type of high-quality hydrocarbon base oil of biological origin. The process of the invention comprises ketonization, hydrodeoxygenation, and isomerization steps. Fatty acids and/or fatty acid esters based on a biological raw material are preferably used as the feedstock.Type: GrantFiled: November 24, 2010Date of Patent: March 12, 2013Assignee: Neste Oil OyjInventors: Eija Koivusalmi, Johan-Fredrik Selin, Juha Moilanen
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Patent number: 8394745Abstract: The present invention provides a lubricating base oil comprising saturated components of 90% by mass or greater, wherein the proportion of cyclic saturated components among the saturated components is not greater than 40% by mass, and by having a viscosity index of 110 or higher and an iodine value of not greater than 2.5. The lubricating base oil of the invention exhibits excellent viscosity-temperature characteristics and heat and oxidation stability while also allowing additives to exhibit a higher level of function when additives are included. The lubricating base oil of the invention is suitable for use in various lubricating oil fields, and is especially useful for reducing energy loss and achieving energy savings in devices in which the lubricating base oil is applied.Type: GrantFiled: March 28, 2007Date of Patent: March 12, 2013Assignees: Nippon Oil Corporation, Petroleum Energy CenterInventors: Takashi Sano, Shinichi Shirahama, Kazuo Tagawa, Kenichi Komiya, Shigeki Matsui, Osamu Kurosawa
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Patent number: 8394749Abstract: The present invention provides a pressure-medium oil comprising at least one of a hydrocarbon compound and an ether compound and having the following properties (1) to (4): (1) a kinematic viscosity as measured at 40° C. of 2 to 30 mm2/s; (2) a viscosity index of 110 or higher; (3) a density as measured at 15° C. of 0.86 g/cm3 or less; and (4) a pour point of ?50° C. or lower. The pressure-medium oil does not solidify under an ultra-high pressure, for example, 1.5 GPa or higher, and has a low pour point and excellent compatibility with test samples and with the material of the apparatus employed in the test.Type: GrantFiled: October 30, 2006Date of Patent: March 12, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Shoji Aoyama, Keizo Murata, Hiroshi Nagakawa, Tahei Okada
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Patent number: 8388829Abstract: Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.Type: GrantFiled: September 14, 2012Date of Patent: March 5, 2013Assignee: Battelle Memorial InstituteInventors: Richard T. Hallen, Karl O. Albrecht, Heather M. Brown, James F. White
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Patent number: 8372777Abstract: Method of contacting a hydrocarbon feed with a catalyst that includes one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Column 6 of the Periodic Table and a support. The support comprises from 0.01 grams to 0.2 gram of silica and from 0.80 grams to 0.99 grams of alumina per gram of support. The catalyst has a surface area of at least 340 m2/g, a pore size distribution with a median pore diameter of at most 100 ?, and at least 80% of its pore volume in pores having a pore diameter of at most 300 ? or the catalyst exhibits one or more peaks between 35 degrees and 70 degrees, and at least one of the peaks has a base width of at least 10 degrees, as determined by x-ray diffraction at 2-theta.Type: GrantFiled: March 22, 2012Date of Patent: February 12, 2013Assignee: Shell Oil CompanyInventors: Opinder Kishan Bhan, Scott Lee Wellington
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Patent number: 8366907Abstract: Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.Type: GrantFiled: August 2, 2010Date of Patent: February 5, 2013Assignee: Battelle Memorial InstituteInventors: Richard T. Hallen, Karl O. Albrecht, Heather M. Brown, James F. White
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Publication number: 20130001127Abstract: The invention provides a process to prepare very low sul-phur, very low aromatic hydrocarbon fluids having a boiling range in the range of from 100 to 400° C. and a boiling range of not more than 80° C., comprising at least the two successive steps of -deep hydrodesulphurating of middle distillate down to less than 10 ppm sulphur, and -catalytic hy-drogenating the desulphurized middle distillates of preceding step at a temperature from 80 to 180° C. and at a pressure from 60 to 160 bars.Type: ApplicationFiled: November 19, 2010Publication date: January 3, 2013Applicant: TOTAL RAFFINAGE MARKETINGInventors: Christine Aubry, Joelle Nokerman
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Patent number: 8329966Abstract: Synthetic base oil composition comprising dialkyl aromatic compound with alkyl side chain carbon number from C10 to C28, or preferably C11 to C24, or even more preferably, C12 to C18, wherein the branching characteristics of the alkyl side chain has a total methyl number (TMN) determined by C13 NMR spectroscopy to be from more than 2.1 to less than 3.5, or preferably from 2.15 to 3.25, or even more preferably from 2.2 to 3.0, or a branching index (BI) from more than 0.1 to less than 1.5, or more preferably, 0.15 to 1.25, or even more preferably, 0.2 to 1.0. The synthetic base oil composition has a combination of high viscometric index, low volatility, superior low temperature properties, and improved thermal/oxidation stability, and is particularly suitable to be used as a premium synthetic base stock, second base oil component, or additive for lubricant and additive package applications.Type: GrantFiled: October 10, 2007Date of Patent: December 11, 2012Assignee: Formosan Union Chemical Corp.Inventors: Chi-Hsing Tsai, Chien-Hsun Tsai
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Patent number: 8318001Abstract: We provide a base oil comprising hydrocarbons with consecutive numbers of carbon atoms. The base oil has a boiling range from 700 to 925° F. (371 to 496° C.), a VI from 105 to 119, and either a Noack volatility less than 18 wt % or a CCS VIS at ?25° C. less than 1500 mPa·s. The base oil may have a ratio of Noack Volatility to CCS VIS at ?25° C. multiplied by 100 from 0.80 to 1.55.Type: GrantFiled: June 10, 2009Date of Patent: November 27, 2012Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Brent K. Lok, Kathy A. Helling, Ryan J. Schexnaydre, Scott C. Deskin, Susan M. Abernathy
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Patent number: 8318993Abstract: A fluid blend suitable for use as a lube basestock comprises two major components: (A) a copolymer made from ethylene with one or more alpha olefins, the copolymer (i) containing not more than 50 wt % ethylene; (ii) having a number average molecular weight of from 400 to 10,000; and (iii) a molecular weight distribution <3; and (B) a polyalphaolefin fluid or a hydroprocessed oil having a VI greater than 80.Type: GrantFiled: December 15, 2005Date of Patent: November 27, 2012Assignee: Exxonmobil Research and Engineering CompanyInventors: Margaret May-Som Wu, Jon Edmond Randolph Stanat, Kyle D. Lawrence, Richard T. Spissell, James William Gleeson, James Thomas Carey, Charles Lambert Baker
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Patent number: 8303850Abstract: A rust preventive oil composition includes at least one base oil selected from the group consisting of mineral oils and synthetic oils, having a 5%-distillation temperature of not less than 140° C. and not more than 250° C., a 95%-distillation temperature of 250° C. or less, a difference between the 5%-distillation temperature and the 95%-distillation temperature of 90° C. or less, an aromatic content of 5% by volume or less, a naphthene content of not less than 30% by volume and not more than 95% by volume, a density at 15° C. of 0.75 g/cm3 or more, and a kinematic viscosity at 40° C. of not less than 0.3 mm2/s and not more than 5.0 mm2/s; at least one base oil selected from the group consisting of mineral oils and synthetic oils; and a rust-preventing additive.Type: GrantFiled: July 14, 2010Date of Patent: November 6, 2012Assignee: JX Nippon Oil & Energy CorporationInventors: Junichi Shibata, Tadaaki Motoyama, Kazuhiko Endou
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Patent number: 8299006Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.Type: GrantFiled: November 1, 2011Date of Patent: October 30, 2012Assignee: Nippon Oil CorporationInventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
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Patent number: 8298402Abstract: The present invention relates to alkylphenol-aldehyde resins containing oligo- or polymers having a repeat structural unit of the formula where R1 is a branched alkyl or alkenyl radical which has from 10 to 40 carbon atoms and bears at least one carboxyl, carboxylate and/or ester group, R2 is hydrogen or R1 R3 is hydrogen or an alkoxy group of the formula -(A-O)m—H, A is a C2- to C4-alkylene group, m is from 1 to 100, R4 is hydrogen, a C1- to C11-alkyl radicals or a carboxyl group, R5 is C1-C200-alkyl or -alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or -alkenyl, n is from 1 to 100 and k is 1 or 2.Type: GrantFiled: September 22, 2006Date of Patent: October 30, 2012Assignee: Clariant Produkte (Deutschland) GmbHInventors: Matthias Krull, Carsten Cohrs, Heidi Rausch
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Patent number: 8278255Abstract: In one embodiment, a lubricating oil with favorable shear stability is disclosed. The lubricating oil comprising a major amount of base stock selected from the group consisting of Group II, Group III, Group IV, Group V, and any combination thereof, a viscosity index improver comprising a polymethacrylate with a permanent shear stability index of less than 45 defined by ASTM 5621 with 10 percent polymer in a Group I mineral oil, an antioxidant additive and a corrosion additive. In a second embodiment a method of improving shear stability is disclosed. In a third embodiment, a method of blending an oil to provide improved shear stability and favorable viscosity index is disclosed.Type: GrantFiled: March 27, 2009Date of Patent: October 2, 2012Inventor: David G. L. Holt
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Patent number: 8268762Abstract: The invention provides a transmission fluid composition which has a kinematic viscosity as determined at 100° C. of 2 to 10 mm2/s and a viscosity index of 150 or higher and which satisfies a relationship between kinematic viscosity and NOACK evaporation loss amount represented by formula (I): X/3+Y?6.33??(I) (wherein X represents a kinematic viscosity (mm2/s) as determined at 100° C., and Y represents a NOACK evaporation loss amount (mass %) at 200° C. for one hour), and a transmission fluid composition containing, as a base oil, at least one species selected from among ?-olefin oligomers produced through oligomerization of an ?-olefin through a specific method and hydrogenation products of the oligomers. Such transmission fluid compositions exhibit a very small evaporation loss despite having low viscosity, and a long metal fatigue life (e.g.Type: GrantFiled: November 15, 2006Date of Patent: September 18, 2012Assignee: Idemitsu Kosan Co., Ltd.Inventor: Hiroshi Fujita
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Patent number: 8247360Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.Type: GrantFiled: November 1, 2011Date of Patent: August 21, 2012Assignee: Nippon Oil CorporationInventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
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Patent number: 8236740Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.Type: GrantFiled: November 1, 2011Date of Patent: August 7, 2012Assignee: Nippon Oil CorporationInventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
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Patent number: 8231778Abstract: Methods are disclosed for hydrocracking processes that convert a significant portion of a heavy hydrocarbon feedstock such as vacuum gas oil (VGO) to lower molecular weight, lower boiling hydrocarbons. In addition to molecular weight reduction, the processes also substantially reduce the pour point of a recovered higher boiling fraction or unconverted oil, all or a portion of which may be used as a lube base stock, optionally after one or more further treatment steps such as hydrofinishing. The ability to reduce the pour point, through hydroisomerization, of the higher boiling fraction greatly improves the quality of this fraction, or unconverted oil, for use in lube base stock preparation. Advantageously, separate, conventional hydroisomerization and/or dewaxing steps, often requiring a noble metal catalyst, may be avoided in particular embodiments disclosed herein.Type: GrantFiled: December 31, 2008Date of Patent: July 31, 2012Assignee: UOP LLCInventor: Hemant B. Gala
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Patent number: 8232233Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.Type: GrantFiled: November 1, 2011Date of Patent: July 31, 2012Assignee: Nippon Oil CorporationInventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
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Patent number: 8227385Abstract: The lubricating base oil of the invention has a urea adduct value of not greater than 4% by mass, a kinematic viscosity at 40° C. of 25-50 mm2/s, a viscosity index of 140 or greater, a CCS viscosity at ?35° C. of not greater than 15,000 mPa·s and a flash point of 250° C. or higher. The method for producing a lubricating base oil of the invention comprises a step of hydrocracking/hydroisomerizing a feedstock oil containing normal paraffins so as to obtain a treated product having an urea adduct value of not greater than 4% by mass, a kinematic viscosity at 40° C. of 25-50 mm2/s, a viscosity index of 140 or greater, a CCS viscosity at ?35° C. of not greater than 15,000 mPa·s and a flash point of 250° C. or higher. The lubricating oil composition of the invention comprises the lubricating base oil of the invention.Type: GrantFiled: March 23, 2009Date of Patent: July 24, 2012Assignee: JX Nippon Oil & Energy CorporationInventors: Kazuo Tagawa, Shinichi Shirahama, Masahiro Taguchi
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Patent number: 8227384Abstract: The lubricating base oil of the invention has a kinematic viscosity at 40° C. of 7 mm2/s or greater and less than 15 mm2/s, a viscosity index of 120 or greater, a urea adduct value of not greater than 4% by mass, a BF viscosity at ?35° C. of not greater than 10,000 mP·s, a flash point of 200° C. or higher and a NOACK evaporation loss of not greater than 50% by mass. The method for producing a lubricating base oil of the invention comprises a step of hydrocracking/hydroisomerizing a feedstock oil containing normal paraffins so as to obtain a treated product having an urea adduct value of not greater than 4% by mass, a kinematic viscosity at 40° C. of 7 mm2/s or greater and less than 15 mm2/s, a viscosity index of 120 or greater, a BF viscosity at ?35° C. of not greater than 10,000 mP·s, a flash point of 200° C. or higher and a NOACK evaporation loss of not greater than 50% by mass. The lubricating oil composition of the invention comprises the lubricating base oil of the invention.Type: GrantFiled: March 23, 2009Date of Patent: July 24, 2012Assignee: JX Nippon Oil & Energy CorporationInventors: Kazuo Tagawa, Shinichi Shirahama, Masahiro Taguchi
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Patent number: 8227387Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.Type: GrantFiled: November 1, 2011Date of Patent: July 24, 2012Assignee: Nippon Oil CorporationInventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
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Patent number: 8227388Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.Type: GrantFiled: November 1, 2011Date of Patent: July 24, 2012Assignee: Nippon Oil CorporationInventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsumoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
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Patent number: 8216448Abstract: A method for improving the lubricating properties of a distillate base oil characterized by a pour point of 0 degrees C. or less and a boiling range having the 10 percent point falling between about 625 degrees F. and about 790 degrees F. and the 90 percent point falling between about 725 degrees F. and about 950 degrees F., the method comprises blending with said distillate base oil a sufficient amount of a pour point depressing base oil blending component to reduce the pour point of the resulting base oil blend at least 3 degrees C. below the pour point of the distillate base oil, wherein the pour point depressing base oil blending component is an isomerized Fischer-Tropsch derived bottoms product having a pour point that is at least 3 degrees C. higher than the pour point of the distillate base oil.Type: GrantFiled: December 13, 2010Date of Patent: July 10, 2012Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller