Plural Parallel Stages Of Chemical Conversion Patents (Class 208/78)
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Publication number: 20140014555Abstract: A fluid catalytic cracking apparatus and process is disclosed, providing for efficient conversion of heavy hydrocarbon feeds to light olefins, aromatics, and gasoline. A countercurrent flow reactor operating in bubbling or turbulent fluidization regimes is integrated with a fluid catalytic cracking riser reactor. A heavy hydrocarbon feed is catalytically cracked to naphtha and light olefins in the riser reactor, a co-current flow reactor. To enhance the yields and selectivity to light olefins, cracked hydrocarbon products from the riser reactor, such as C4 and naphtha range hydrocarbons, may be recycled and processed in the countercurrent flow reactor. The integration of the countercurrent flow reactor with a conventional FCC riser reactor and catalyst regeneration system may overcome heat balance issues commonly associated with two-stage cracking processes, may substantially increase the overall conversion and light olefins yield, and/or may increases the capability to process heavier feedstocks.Type: ApplicationFiled: July 12, 2012Publication date: January 16, 2014Applicant: LUMMUS TECHNOLOGY INC.Inventors: Rama Rao Marri, Dalip Singh Soni, Pramod Kumar
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Patent number: 8586812Abstract: Processes for upgrading condensate in a first hydrocarbon stream to provide distillate material may involve ionic liquid catalyzed olefin oligomerization of olefins in the first hydrocarbon stream to provide a first distillate enriched stream, dechlorination of the first distillate enriched stream, hydroprocessing at least one of a second and a third hydrocarbon stream to provide a second distillate enriched stream, and separation of a distillate product from the first and second distillate enriched streams.Type: GrantFiled: December 22, 2010Date of Patent: November 19, 2013Assignee: Chevron U.S.A. Inc.Inventors: Hye-Kyung C. Timken, Bi-Zeng Zhan
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Patent number: 8540949Abstract: An apparatus and process is disclosed for hydroprocessing hydrocarbon feed in a hydroprocessing unit and hydrotreating a second hydrocarbon. A warm separator sends vaporous hydrotreating effluent to be flashed with liquid hydroprocessing effluent to produce a vapor flash overhead that can be recycled to the hydrotreating unit to provide hydrogen requirements.Type: GrantFiled: June 24, 2011Date of Patent: September 24, 2013Assignee: UOP LLCInventors: Andrew P. Wieber, Joao J. da Silva Ferreira Alves
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Patent number: 8491781Abstract: The present invention describes a reaction zone comprising at least two fluidized reactors, a principal reactor for cracking a heavy hydrocarbon cut, the other, additional, reactor for cracking one or more light cuts, the effluents from the two reactors being treated in a common gas-solid separation and quench zone. Performance is enhanced because the thermal degradation reactions in the reaction zone are controlled in an optimum manner.Type: GrantFiled: May 23, 2008Date of Patent: July 23, 2013Assignee: IFP Energies NouvellesInventors: Thierry Gauthier, Vincent Coupard, Jan Verstraete, Romain Roux
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Publication number: 20130130889Abstract: The present invention provides an improved fluidized catalytic cracking process coupled with a two stage regeneration process in which the activity of the circulating catalyst is independently controlled for cracking hydrocarbon feedstocks or the vapors at low severity to produce maximum light cycle oil/distillate in one riser whilst cracking recycle streams comprising heavy cycle oil (HCO), light cracked naphtha (LCN) etc. in a second riser operating at high severity to produce LPG.Type: ApplicationFiled: November 17, 2011Publication date: May 23, 2013Applicant: Stone & Webster Process Technology, Inc.Inventors: Eusebius Gbordzoe, Marc Bories, Warren Stewart Letzsch, Patrick Leroy, Chris Santner, Joseph L. Ross, JR.
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Patent number: 8419930Abstract: The invention discloses a system for preparing high-quality gasoline through component oil refining hydrocarbon recombination hydrogenation and a method thereof, which is characterized by comprising an extraction system, a distillation system and a hydrogenation device, wherein the upper part of the extraction system is connected with the distillation system through a pipeline, and the lower part of the extraction system is connected with an extract oil hydrogenation device through the pipeline; light gasoline is recovered by the upper part of the distillation system through the pipeline; the lower part of the distillation system is connected with the heavy gasoline hydrogenation device through the pipeline; and reformate or ethylene feed are recovered through the lower part of the heavy gasoline hydrogenation device through the pipeline.Type: GrantFiled: January 21, 2009Date of Patent: April 16, 2013Assignee: Beijing Grand Golden-Bright Engineering & Technologies Co., Ltd.Inventor: Ranfeng Ding
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Patent number: 8394259Abstract: One exemplary embodiment can be a fluid catalytic cracking unit. The fluid catalytic cracking unit can include a first riser, a second riser, and a disengagement zone. The first riser can be adapted to receive a first feed terminating at a first reaction vessel having a first volume. The second riser may be adapted to receive a second feed terminating at a second reaction vessel having a second volume. Generally, the first volume is greater than the second volume. What is more, the disengagement zone can be for receiving a first mixture including at least one catalyst and one or more products from the first reaction vessel, and a second mixture including at least one catalyst and one or more products from the second reaction vessel. Typically, the first mixture is isolated from the second mixture.Type: GrantFiled: February 8, 2012Date of Patent: March 12, 2013Assignee: UOP LLCInventors: Paolo Palmas, Robert L. Mehlberg
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Patent number: 8373013Abstract: A process for combining the catalytic conversion of organic oxygenates and the catalytic conversion of hydrocarbons: an organic oxygenate feedstock is contacted with a Y-zeolite containing catalyst to produce a reaction stream, and a coked catalyst and a product stream are obtained after separating the reaction stream; a hydrocarbon feedstock is contacted with a Y-zeolite containing catalyst to produce a reaction stream, a spent catalyst and a reaction oil vapor are obtained after separating the reaction stream, and the reaction oil vapor is further separated to give the products such as gas, gasoline and the like; a part or all of the coked catalyst and a part or all of the spent catalyst enter the regenerator for the coke-burning regeneration, and the regenerated catalyst is divided into two portions, wherein one portion returns to be contacted with the hydrocarbon feedstock, and the other portion, after cooling, returns to be contacted with the organic oxygenate feedstock.Type: GrantFiled: July 12, 2007Date of Patent: February 12, 2013Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SINOPECInventors: Wenhua Xie, Genquan Zhu, Qiang Fu, Zhiguo Wu, Shaobing Yu, Yihua Yang, Qiang Liu, Zhiqiang Qiao, Xuhong Mu, Chaogang Xie, Yibin Luo, Jiushun Zhang, Xingtian Shu
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Publication number: 20130001129Abstract: A catalytic conversion process for increasing the cetane number barrel of diesel, in which contacting the feedstock oil with a catalytic cracking catalyst having a relatively homogeneous activity containing mainly the large pore zeolites in a catalytic conversion reactor, wherein the reaction temperature, residence time of oil vapors and weight ratio of the catalyst/feedstock oil are sufficient to obtain a reaction product containing from about 12 to about 60% by weight of a fluid catalytic cracking gas oil relative to the weight of the feedstock oil and containing a diesel; the reaction temperature ranges from about 420° C. to about 550° C.; the residence time of oil vapors ranges from about 0.1 to about 5 seconds; the weight ratio of the catalytic cracking catalyst/feedstock oil is about 1-about 10. The fluid catalytic cracking gas oil is fed into other unit for further treatment or is fed back to the initial catalytic conversion reactor.Type: ApplicationFiled: October 20, 2010Publication date: January 3, 2013Applicants: Research Institute of Petroleum Processing, Sinopec, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Youhao Xu, Jianhong Gong, Congli Cheng, Shouye Cui, Zhihai Hu, Yun Chen
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Publication number: 20120292229Abstract: An apparatus and process is disclosed for hydroprocessing hydrocarbon feed in a hydroprocessing unit and hydrotreating a second hydrocarbon. A warm separator sends vaporous hydrotreating effluent to be flashed with liquid hydroprocessing effluent to produce a vapor flash overhead that can be recycled to the hydrotreating unit to provide hydrogen requirements.Type: ApplicationFiled: June 24, 2011Publication date: November 22, 2012Applicant: UOP LLCInventors: Andrew P. Wieber, Joao J. da Silva Ferreira Alves
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Publication number: 20120292228Abstract: An apparatus and process is disclosed for hydroprocessing hydrocarbon feed in a hydroprocessing unit and hydrotreating a second hydrocarbon. The hydrotreating effluent is mixed with hydroprocessing effluent and together fractionated.Type: ApplicationFiled: June 24, 2011Publication date: November 22, 2012Applicant: UOP LLCInventor: Andrew P. Wieber
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Patent number: 8287720Abstract: Processes for upgrading resid hydrocarbon feeds are disclosed. The upgrading processes may include: hydrocracking a resid in a first reaction stage to form a first stage effluent; hydrocracking a deasphalted oil fraction in a second reaction stage to form a second stage effluent; fractionating the first stage effluent and the second stage effluent to recover at least one distillate hydrocarbon fraction and a resid hydrocarbon fraction; feeding the resid hydrocarbon fraction to a solvent deasphalting unit to provide an asphaltene fraction and the deasphalted oil fraction.Type: GrantFiled: June 23, 2009Date of Patent: October 16, 2012Assignee: Lummus Technology Inc.Inventors: Mario C. Baldassari, Ujjal K. Mukherjee, Avinash Gupta
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Publication number: 20120248011Abstract: A process is disclosed for hydroprocessing two hydrocarbon streams at two different pressures. A hydrogen stream is compressed and split. A first split compressed stream is further compressed to feed a first hydroprocessing unit that requires higher pressure for operation. A second split compressed stream is fed to a second hydroprocessing unit that requires lower pressure. Recycle hydrogen from the second hydroprocessing unit is recycled back to the compression section.Type: ApplicationFiled: March 31, 2011Publication date: October 4, 2012Applicant: UOP LLCInventor: Andrew P. Wieber
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Patent number: 8277637Abstract: Systems and methods for processing one or more hydrocarbons are provided. One or more hydrocarbons can be selectively separated to provide one or more heavy deasphalted oils. At least a portion of the heavy deasphalted oil can be cracked using a fluidized catalytic cracker to provide one or more lighter hydrocarbon products.Type: GrantFiled: December 27, 2007Date of Patent: October 2, 2012Assignee: Kellogg Brown & Root LLCInventors: Anand Subramanian, Raymond Floyd
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Patent number: 8273930Abstract: A process for producing ethylene from ethanol combining the catalytic conversion of hydrocarbons: an ethanol feedstock is contacted with a Y-zeolite containing catalyst to give a product stream, and a coked catalyst and an target product of ethylene are obtained after separating the reaction stream; a hydrocarbon feedstock is contacted with a Y-zeolite containing catalyst to give a product stream, a spent catalyst and an oil vapor are obtained after separating the reaction stream, and the oil vapor is further separated to give the products such as gas, gasoline and the like; a part or all of the coked catalyst and a part or all of the spent catalyst enter the regenerator for the coke-burning regeneration, and the regenerated catalyst is divided into two portions, wherein one portion returns to be contacted with the hydrocarbon feedstock, and the other portion, after cooling, returns to be contacted with ethanol feedstock.Type: GrantFiled: July 12, 2007Date of Patent: September 25, 2012Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Zhiguo Wu, Wenhua Xie, Chaogang Xie, Qiang Liu, Xuhong Mu, Jiushun Zhang, Yibin Luo, Xingtian Shu, Chenghan Yan
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Patent number: 8236169Abstract: A process for hydroprocessing heavy oil feedstock is disclosed. The process operates in once-through mode, employing a plurality of contacting zones and at least a separation zone to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock. At least an additive material selected from inhibitor additives, anti-foam agents, stabilizers, metal scavengers, metal contaminant removers, metal passivators, and sacrificial materials, in an amount of less than 1 wt. % of the heavy oil feedstock, is added to at least one of the contacting zones. In one embodiment, the additive material is an anti-foam agent. In another embodiment, the additive material is a sacrificial material for trapping heavy metals in the heavy oil feed and/or deposited coke, thus prolonging the life of the slurry catalyst.Type: GrantFiled: July 21, 2009Date of Patent: August 7, 2012Assignee: Chevron U.S.A. IncInventors: Joseph V Nguyen, Axel Brait, Julie Chabot, Bo Kou, Erin Maris, Rahul S. Bhaduri, Alexander E. Kuperman
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Patent number: 8231777Abstract: The present invention comprises a thermocatalytic cracking process for the production of diesel oil from a charge of vegetable origin made from seeds of oleaginous plants in refineries possessing at least two FCC reactors. At least one of such reactors processes heavy gas oil or residue under conventional conditions while at least one of such reactors processes the charge of vegetable origin made from seeds of oleaginous plants under conditions suitable, for production of diesel oil. Said process employs the same catalyst utilized in the fluid catalytic cracking process which, simultaneously, processes a conventional charge. The diesel, or biodiesel, oil produced by means of said process is of superior quality having a cetane number exceeding 40 given that the cracking reactions occur at low temperatures and the products obtained are less oxidized and consequently purer than products obtained by means of existing technology.Type: GrantFiled: June 17, 2008Date of Patent: July 31, 2012Assignee: Petroleo Brasileiro S.A.—PetrobrasInventors: Mauro Silva, Andrea de Rezende Pinho, Wilson Kenzo Huziwara, Amilcar Pereira da Silva Neto, Carlos Nagib Khalil, Julio Amilcar Ramos Cabral, Lúcia Cristina Ferreira Leite, Luiz Carlos Casavechia, Raul de Carvalho Silva
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Patent number: 8231776Abstract: A method for obtaining a petroleum distillate product is provided, the method includes subjecting an untreated light Fischer-Tropsch liquid to a two-step hydrogenation process, each step to be carried in the presence of a catalyst comprising an amorphous substrate having a metallic composition embedded therein. After the first step of hydrogenation, an intermediate hydrotreated light Fischer-Tropsch liquid is obtained, followed by the second step of hydrogenation thereof, obtaining the petroleum distillate product as a result. An apparatus for carrying out the method is also provided.Type: GrantFiled: March 24, 2010Date of Patent: July 31, 2012Assignee: UOP LLCInventor: Peter Kokayeff
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Patent number: 8137531Abstract: An integrated process for producing liquid fuel and lubricating base oil from Fischer-Tropsch derived products which comprises (a) recovering separately from a Fischer-Tropsch synthesis reactor a Fischer-Tropsch wax and condensate; (b) hydroprocessing the wax and recovering a waxy intermediate and a hydrogen-rich normally, liquid fraction; (c) mixing the condensate and at least part of the hydrogen-rich normally liquid fraction to form a Fischer-Tropsch condensate mixture; (d) hydrotreating the condensate mixture and recovering a Fischer-Tropsch condensate product; (e) recovering from the condensate product a liquid fuel; (f) separately dewaxing the waxy intermediate and recovering a base oil; (g) hydrofinishing the base oil; (h) recovering from the hydrofinishing zone a stabilized base oil and a hydrogen-rich gas; and (i) recycling the hydrogen-rich gas to the wax hydroprocessing zone wherein the total pressure in the hydrofinishing zone is at least as high as the total pressure in the wax hydroprocessing zoType: GrantFiled: November 5, 2003Date of Patent: March 20, 2012Assignee: Chevron U.S.A. Inc.Inventors: Darush Farshid, Richard O. Moore, Jr.
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Patent number: 8137532Abstract: The invention concerns a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises 0.2% to 2.5% by weight of an oxide of a doping element selected from boron, phosphorus, silicon, at least one hydrodehydrogenating element selected from the group formed by noble elements from group VIII of the periodic table, a non-zeolitic support based on silica-alumina containing more than 5% by weight and 95% by weight or less of silica (SiO2), specifically defined pore characteristics, a BET specific surface area in the range 100 to 550 m2/g, and with an X ray diffraction diagram which contains at least the characteristic principal peaks of at least one of the transition aluminas included in the group composed of alpha, rho, khi, eta, gamma, kappa, theta and delta aluminas.Type: GrantFiled: December 14, 2006Date of Patent: March 20, 2012Assignee: IFP Energies NouvellesInventors: Patrick Euzen, Christophe Gueret
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Patent number: 8083965Abstract: The refrigerating machine oil of the present invention contains a mineral oil whose nitrogen content is not more than 50 ppm by mass and whose percent in aromatic ring structures (% CA) is from 5 to 25. With the refrigerating machine oil of the present invention, high levels of lubricity, stability, and miscibility with refrigerants are attained, with a good balance between these, so refrigerating and air conditioning machines can be operated stably over a longer period.Type: GrantFiled: March 2, 2005Date of Patent: December 27, 2011Assignee: Nippon Oil CorporationInventors: Kazuo Tagawa, Katsuya Takigawa
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Patent number: 8083932Abstract: A process for making lower olefins from a wide boiling range hydrocarbon feed by use of a combination of one or more vapor/liquid separation devices, and then pyrolytically cracking the vapor phase in separate sets of pyrolysis radiant tubes, thereby producing a higher level of lower olefin product.Type: GrantFiled: August 21, 2008Date of Patent: December 27, 2011Assignee: Shell Oil CompanyInventors: Arthur James Baumgartner, Robert Lawrence Blackbourn, Danny Yuk Kwan Ngan
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Patent number: 8002967Abstract: Partial conversion hydrocracking process comprising the steps of (a) hydrotreating a hydrocarbon feedstock with a hydrogenrich gas to produce a hydrotreated effluent stream comprising a liquid/vapor mixture and separating the liquid/vapor mixture into a liquid phase and a vapor phase, and (b) separating the liquid phase into a controlled liquid portion and an excess liquid portion, and (c) combining the vapor phase with the excess liquid portion to form a vapor plus liquid portion, and (d) separating an FCC feed-containing fraction from the controlled liquid portion and simultaneously hydrocracking the vapor plus liquid portion to produce a dieselcontaining fraction, or hydrocracking the controlled liquid portion to produce a diesel-containing fraction and simultaneously separating a FCC feed-containing fraction from the vapor plus liquid portion. The invention also includes an apparatus for carrying out the partial conversion hydrocracking process.Type: GrantFiled: September 12, 2006Date of Patent: August 23, 2011Assignee: Haldor Topsøe A/SInventors: Michael Glenn Hunter, Angelica Hidalgo Vivas, Lars Skov Jensen, Gordon Gongngai Low
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Publication number: 20110163000Abstract: Methods, systems and other embodiments associated with upgrading heavy oil are presented. A method of upgrading heavy oil with reconfigurable units connects reconfigurable units into an original configuration of reconfigurable units for upgrading raw heavy oil. The raw heavy oil is upgraded in the original configuration of reconfigurable units by creating high pressure pulses in the raw heavy oil. The high pressure pulses crack the raw heavy oil to produce an oil with a lower viscosity than the raw heavy oil.Type: ApplicationFiled: January 7, 2010Publication date: July 7, 2011Inventors: Jose J. P. Lourenco, John Gordon Murphy
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Publication number: 20110139679Abstract: The invention relates to a method for catalytic cracking to maximize the production of diesel base stocks, comprising a cracking reaction step in an upflow fluidized bed reactor (1), a step of separating the cracked hydrocarbons and coked catalyst, a step of fractionating the cracked hydrocarbons and a step of regenerating said coked catalyst, wherein the hydrocarbon feedstock is injected into the upflow reactor on a catalyst partially deactivated by prior coking of at least part thereof in the same upflow reactor, so that the reaction temperature of the effluents leaving said reactor varies from 470 to 600° C. The invention also relates to a device for implementing the cracking method.Type: ApplicationFiled: December 13, 2010Publication date: June 16, 2011Applicant: TOTAL RAFFINAGE MARKETINGInventors: Marc BORIES, Patrick LEROY, Michael ECHARD, Thierry GAUTHIER
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Publication number: 20110049010Abstract: Systems and methods for hydroprocessing a heavy oil feedstock are disclosed. The system employs a plurality of contacting zones and at least one separation zone, wherein a solvating hydrocarbon having a normal boiling point less than 538° C. (1000° F.) is employed. In the system, a mixture of heavy oil feedstock and solvating hydrocarbon is provided to a contact zone along with a slurry catalyst feed in a hydrocarbon diluent. The contacting zone operates at a temperature and pressure near the critical temperature and pressure of the heavy oil and solvating hydrocarbon mixture to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products.Type: ApplicationFiled: August 31, 2009Publication date: March 3, 2011Inventors: Tayseer A. Abdel-Halim, Axel Brait
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Patent number: 7883618Abstract: Systems and processes for producing one or more olefins. A feed containing 90% by weight or more C4 and higher hydrocarbons can be cracked at conditions sufficient to provide an olefinic mixture and an aromatic mixture. The olefinic mixture can comprise 90% by weight or more C1 to C3 hydrocarbons. The aromatic mixture can comprise 90% by weight or more C4 and higher hydrocarbons and one or more aromatics. The aromatic mixture can be contacted with one or more solvents to selectively separate at least a portion of the one or more aromatics therefrom to provide an aromatic-rich mixture and an aromatic-lean mixture. At least a portion of the aromatic-lean mixture can be recycled to the feed prior to cracking.Type: GrantFiled: February 28, 2008Date of Patent: February 8, 2011Assignee: Kellogg Brown & Root LLCInventors: Alan Claude, Anand Subramanian
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Publication number: 20110017637Abstract: A process for hydroprocessing heavy oil feedstock is disclosed. The process operates in once-through mode, employing a plurality of contacting zones and separation zones in sequential mode, parallel mode, or combinations thereof to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock. In one embodiment, the effluent stream from the contacting zone is sent to a separation zone in series operating at a pressure drop of at most 100 psi from the contacting zone. In another embodiment, the effluent from a contacting zone to the next contacting zone in series for further upgrade, with the next contacting zone having a pressure drop of at most 100 psi, with the pressure drop is not due to a pressure reducing device as in the prior art.Type: ApplicationFiled: July 21, 2009Publication date: January 27, 2011Inventors: Bruce Reynolds, Julie Chabot
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Publication number: 20110017636Abstract: A process for hydroprocessing heavy oil feedstock is disclosed. The process operates in once-through mode, employing a plurality of contacting zones and at least a separation zone to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock. At least an additive material selected from inhibitor additives, anti-foam agents, stabilizers, metal scavengers, metal contaminant removers, metal passivators, and sacrificial materials, in an amount of less than 1 wt. % of the heavy oil feedstock, is added to at least one of the contacting zones. In one embodiment, the additive material is an anti-foam agent. In another embodiment, the additive material is a sacrificial material for trapping heavy metals in the heavy oil feed and/or deposited coke, thus prolonging the life of the slurry catalyst.Type: ApplicationFiled: July 21, 2009Publication date: January 27, 2011Inventors: Joseph V. Nguyen, Bo Kou, Julie Chabot, Erin Maris, Axel Brait, Rahul S. Bhaduri, Alexander E. Kuperman
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Publication number: 20100314289Abstract: The invention relates to a catalytic cracking process for reducing sulfur content in gasoline and the device thereof, which includes a fluidized bed reactor in addition of a heavy oil catalytic cracking riser, characterized in enhancing contact time of oil-gas with the catalyst, further desulfurizing and reducing olefin content and increasing octane number in gasoline; regenerating all recycling catalysts, quality of products being stable and easily operated, reducing sulfur of gasoline to a maximum limit; adding a cooling device so as to avoid coking when the catalyst contacts with oil-gas in high temperature and decrease of yield of light oil resulted by excessively high reaction temperature of gasoline upgrading, improving products distribution, being flexible to change catalyst-oil ratio and reaction temperature of catalytic cracking reaction.Type: ApplicationFiled: June 10, 2010Publication date: December 16, 2010Applicant: PETROCHINA COMPANY LIMITEDInventors: Xionghou GAO, Shuhong SUN, Lin WANG, Xinmei PANG, Zhifeng WANG, Yongfu GAO, Zhaoyong LIU, Conghua LIU, Jinsen GAO, Gang WANG, Yanhui ZHANG, Tao LIU, Juanjuan LIU
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Publication number: 20100294696Abstract: Disclosed is a method of manufacturing a diesel fuel base stock improved in low-temperature flowability, including: fractionating in a first fractionator a synthetic oil obtained by Fisher-Tropsch synthesis into at least two fractions of a first middle fraction containing a component having a boiling range corresponding to diesel fuel oil, and a wax fraction containing a wax component heavier than the first middle fraction; hydroisomerizing the first middle fraction by bringing the first middle fraction into contact with a hydroisomerizing catalyst to produce a hydroisomerized middle fraction; hydrocracking the wax fraction by bringing the wax fraction into contact with a hydrocracking catalyst to produce a wax-decomposition component; and fractionating in a second fractionator a mixture of the produced hydroisomerized middle fraction and the produced wax-decomposition component, wherein rectification conditions in the first fractionator and/or rectification conditions in the second fractionator are adjustedType: ApplicationFiled: September 25, 2008Publication date: November 25, 2010Inventors: Yuichi Tanaka, Kazuhito Sato
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Patent number: 7837860Abstract: A process for the production of low sulfur diesel and high octane naphtha. Separate high pressure vapor liquid separators serve to maintain and isolate the high octane naphtha produced in the hydrocracking zone thereby maximizing the value of the hydrocarbon streams produced.Type: GrantFiled: December 12, 2005Date of Patent: November 23, 2010Assignee: UOP LLCInventors: Richard K. Hoehn, Srinivasa G. Varadarajan, Douglas W. Kocher-Cowan
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Patent number: 7837861Abstract: A process for the removal of sulfur compounds and benzene of a catalytically cracked petroleum naphtha comprising benzene, organic sulfur compounds and olefins, by fractionating the cracked naphtha into a relatively low boiling range, olefinic, light catalytic naphtha (LCN) and an olefinic heavy catalytic naphtha (HCN) which boils above the range of the LCN the boiling ranges of the LCN and the HCN being defined by a cut point selected to maintain most of the benzene in the cracked naphtha in the LCN together with olefins in the boiling range of the LCN. The LCN is subjected to an optional non-hydrogenative desulfurization step followed by a fixed bed alkylation step in which the benzene in the LCN is alkylated with the olefins contained in this fraction. The HCN is treated by a similar an alkylation step using the olefins contained in this fraction to alkylate the sulfur compounds, forming alkylated products which boil above the gasoline boiling range.Type: GrantFiled: September 14, 2007Date of Patent: November 23, 2010Assignee: ExxonMobil Research & Engineering Co.Inventors: Benjamin S. Umansky, James F. Stanley, Tomas R. Melli, Sean C. Smyth, Eugene M. Roundtree
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Patent number: 7815789Abstract: A process to prepare a base oil having a viscosity index of above 80 and a saturates content of above 90 wt % from a crude derived feedstock by (a) contacting a crude derived feedstock in the presence of hydrogen with a catalyst having at least one Group VIB metal component and at least one non-noble Group VIII metal component supported on a refractory oxide carrier; (b) adding to the effluent of step (a) or part of the effluent of step (a) a Fischer-Tropsch derived fraction boiling at least partly in the base oil range in an amount effective to achieve the target viscosity index of the final base oil; and (c) dewaxing the mixture as obtained in step (b).Type: GrantFiled: June 21, 2004Date of Patent: October 19, 2010Assignee: Shell Oil CompanyInventors: Peter James Wardle, William Leonard Alexander King
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Patent number: 7736491Abstract: A process for the fluid catalytic cracking of mixed hydrocarbon feeds from different sources is described, such as feeds A and B of different crackability, the process being especially directed to obtaining light fractions such as LPG and comprising injecting feed A in the base of the riser reactive section and feed B, of lower crackability, at a height between 10% and 80% of the riser, with feed B comprising between 5% and 50% of the total processed feed. The process requires that the feeds present differences in the contaminant content, improved dispersion of feeds A and B and feed B injection temperature same or higher than that of feed A.Type: GrantFiled: May 19, 2004Date of Patent: June 15, 2010Assignee: Petroleo Brasileiro S.A. - PetrobrasInventors: Claudia Maria de Lacerda Alvarenga Baptista, Henrique Soares Cerqueira, Emanuel Freire Sandes
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Patent number: 7727378Abstract: A process to prepare a waxy raffinate product by performing the following steps: (a) subjecting a Fischer-Tropsch derived product having a weight ratio of compounds boiling above 540° C. and compounds boiling between 370 and 540° C. of greater than 2 to a hydroconversion step and (b) fractionating the effluent of step (a) to obtain products boiling in the fuels range and a waxy raffinate product boiling between 350 and 600° C.Type: GrantFiled: July 2, 2004Date of Patent: June 1, 2010Assignee: Shell Oil CompanyInventors: Jan Lodewijk Maria Dierickx, Arend Hoek, Lip Piang Kueh
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Patent number: 7718052Abstract: A process for independently and concurrently cracking at least two different hydrocarbon feedstocks to olefins. The process is carried out in a furnace for cracking hydrocarbon feed which has at least a first and second independent radiant cracking zone to produce a first cracked product and second cracked product that are separately withdrawn from the furnace.Type: GrantFiled: October 9, 2007Date of Patent: May 18, 2010Assignee: Stone & Webster Technology, Inc.Inventors: John Brewer, David Brown, Svend Rumbold
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Patent number: 7713491Abstract: Two or more cyclone systems can be contained in a single vessel. Each cyclone system can be in fluid communication with an inlet stream and a fluid discharge line. First cyclone system can include a vent open to the cyclone containing vessel. Second cyclone system can be sealed to restrict fluid entry from and/or exit into vessel, which can inhibit product vapors from exiting the vent of one cyclone system into the vessel and flowing into the vent of the other cyclone system.Type: GrantFiled: December 6, 2006Date of Patent: May 11, 2010Assignee: Kellogg Brown & Root LLCInventor: Alan M. Claude
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Patent number: 7708877Abstract: A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the converted oil while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. Fully converted oil is subsequently hydrofinished for the nearly complete removal of hetoroatoms such as sulfur and nitrogen.Type: GrantFiled: April 24, 2006Date of Patent: May 4, 2010Assignee: Chevron USA Inc.Inventors: Darush Farshid, Bruce Reynolds
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Patent number: 7691256Abstract: Heavy hydrocarbon charges are converted in a deasphalting section in the presence of solvents and obtaining two streams, one consisting of deasphalted oil and the other one containing asphaltenes, mixing the deasphalted oil stream with a hydrogenation catalyst and passing the thus obtained mixture to a hydroprocessing section containing hydrogen or hydrogen/H2S, mixing the stream consisting of asphaltenes discharged from the deasphalting section with an appropriate hydrogenation catalyst and passing the obtained mixture to a second hydroprocessing section where it is reacted with hydrogen or a mixture of hydrogen and H2S, passing both the stream containing the reaction product with dispersed catalyst from the hydroprocessing section and the stream containing the reaction product with dispersed catalyst from the second hydroprocessing section, to one or more distillation or flash stages, whereby the more volatile fractions are separated from the distillation residue (tar) or from the liquid discharged from theType: GrantFiled: December 20, 2005Date of Patent: April 6, 2010Assignees: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.Inventors: Romolo Montanari, Mario Marchionna, Sergio Rosi, Nicoletta Panariti, Alberto Delbianco
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Patent number: 7686941Abstract: A process for simultaneously hydrocracking multiple feedstocks wherein a first feedstock is hydrotreated in a hydrotreating zone to produce a hydrotreating zone effluent which is separated to provide a first vaporous hydrocarbonaceous stream and a first liquid hydrocarbonaceous stream. The second feedstock and the first vaporous hydrocarbonaceous stream are hydroprocessed in a hydroprocessing zone to produce a hydroprocessing zone effluent. A third feedstock and the first liquid hydrocarbonaceous stream are hydrocracked in a hydrocracking zone to produce a hydrocracking zone effluent. The hydrocracking zone effluent and the hydroprocessing zone effluent are separated to recover hydrocracked hydrocarbons.Type: GrantFiled: September 11, 2006Date of Patent: March 30, 2010Assignee: UOP LLCInventors: Gary R. Brierley, Vasant P. Thakkar, Milan Skripek
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Patent number: 7678951Abstract: The subject of the invention is a method for treating a natural gas containing ethane, comprising the following stages: (a) extraction of at least one part of the ethane from the natural gas; (b) reforming of at least one part of the extracted ethane into a synthesis gas; (c) methanation of the synthesis gas into a methane-rich gas; and (d) mixing of the methane-rich gas with the natural gas. Installation for implementing this method.Type: GrantFiled: November 17, 2006Date of Patent: March 16, 2010Assignee: Total S.A.Inventor: Denis Chretien
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Patent number: 7670476Abstract: Process to optimize the yield of gas oils from a Fischer-Tropsch derived feed by performing the following steps: (a) performing a hydroconversion/hydroisomerisation step on part of the Fischer-Tropsch derived feed; (b) performing a hydroconversion/hydroisomerisation step on another part of the Fischer-Tropsch feed at a conversion greater than the conversion in step (a); and (c) isolating by means of distillation a gas oil fraction from the two reaction products obtained in steps (a) and (b).Type: GrantFiled: November 18, 2005Date of Patent: March 2, 2010Assignee: Shell Oil CompanyInventors: Jan Lodewijk Maria Dierickx, Arend Hoek, Lip Piang Kueh
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Patent number: 7658837Abstract: A process and device to optimize the yield of fluid catalytic cracking products through a reactive stripping process are disclosed. One or more hydrocarbon streams (3) are introduced in an intermediary region of the stripper (1) of a fluid catalytic cracking unit (FCC), from a device that allows a homogeneous distribution with adequate dispersion. This/these stream(s) react(s) with the catalyst of FCC, although its activity is reduced due to the adsorption of hydrocarbons in the reaction zone, generating products that improve and/or change the global distribution of products, providing a refinery profile adequate to meet quality demands and requirements.Type: GrantFiled: July 28, 2005Date of Patent: February 9, 2010Assignee: Petroleo Brasileiro S.A.-PetrobrasInventors: Henrique Soares Cerqueira, Claudia Maria de Lacerda Alvarenga Baptista, William Richard Gilbert, Oscar Rene Chamberlain Pravia
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Patent number: 7655134Abstract: Process to optimize the yield of base oils from a Fischer-Tropsch derived feed by performing the following steps (a) performing a hydroconversion/hydroisomerization step on part of the Fischer-Tropsch derived feed; (b) performing a hydroconversion/hydroisomerization step on another part of the Fischer-Tropsch feed at a conversion greater than the conversion in step (a); and (c) isolating by means of distillation a fraction boiling in the base oil range from the two reaction products obtained in steps (a) and (b) and performing a pour point reducing step on said fraction.Type: GrantFiled: November 18, 2005Date of Patent: February 2, 2010Assignee: Shell Oil CompanyInventors: Jan Lodewijk Maria Dierickx, Arend Hoek, Lip Piang Kueh
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Patent number: 7655822Abstract: A gas-solid reactor and method including two fluidized reaction zones having an integrated gas-solid separation system which achieves rigorously controlled residence times in the reactor.Type: GrantFiled: December 19, 2006Date of Patent: February 2, 2010Assignee: Institut Francais du PetroleInventors: Joseph Ross, Thierry Gauthier, Régis Andreux
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Patent number: 7651606Abstract: The invention concerns a process for the hydrodesulphurization of gasoline cuts for the production of gasolines with a low sulphur and mercaptans content. Said process comprises at least two hydrodesulphurization steps, HDS1 and HDS2, operated in parallel on two distinct cuts of the gasoline constituting the feed. The flow rate of hydrogen in the hydrodesulphurization step HDS2 is such that the ratio between the flow rate of hydrogen and the flow rate of feed to be treated is less than 80% of the ratio of the flow rates used to desulphurize in the hydrodesulphurization step HDS1.Type: GrantFiled: April 23, 2007Date of Patent: January 26, 2010Assignee: Institut Francais du PetroleInventors: Florent Picard, Quentin Debuisschert, Annick Pucci
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Patent number: 7638038Abstract: A method for controlling the pseudo-isothermicity of a chemical reaction in a respective reaction zone. (9) in which the use of heat exchangers (6) is foreseen having an operating heat exchange fluid flowing through them and in which heat exchange critical areas (9a) are identified, the method being distinguished by the fact that it reduces and controls, in the critical areas (9a) of the reaction zone, the value of the heat exchange coefficient between the operating fluid and the zone (9), through thermal insulation of the portions (6a, 6b) of such exchangers extending in such areas (9a).Type: GrantFiled: October 2, 2002Date of Patent: December 29, 2009Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
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Patent number: 7632977Abstract: Disclosed is a process for making middle distillate and lower olefins. The process includes catalytically cracking a gas oil feedstock within a riser reactor zone by contacting under suitable catalytic cracking conditions within the riser reactor zone the gas oil feedstock with a middle distillate selective cracking catalyst that comprises amorphous silica alumina and a zeolite to yield a cracked gas oil product and a spent cracking catalyst. The spent cracking catalyst is regenerated to yield a regenerated cracking catalyst. Within an intermediate cracking reactor such as a dense bed reactor zone and under suitable high severity cracking conditions a gasoline feedstock is contacted with the regenerated cracking catalyst to yield a cracked gasoline product and a used regenerated cracking catalyst. The used regenerated cracking catalyst is utilized as the middle distillate selective catalyst.Type: GrantFiled: January 17, 2006Date of Patent: December 15, 2009Assignee: Shell Oil CompanyInventors: Weijian Mo, Georghios Agamemnonons Hadjigeorge, Frank Hsian Hok Khouw
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Publication number: 20090294324Abstract: A process for producing at least one blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from glycerides and free fatty acids in feedstocks such as plant and animal oils. The cyclic rich component is generated from biomass derived pyrolysis oil. The source of the animal or plant oil and the biomass may be the same renewable source.Type: ApplicationFiled: April 6, 2009Publication date: December 3, 2009Inventors: Timothy A. Brandvold, Michael J. McCall