Abstract: A coalescence media for separation of water-hydrocarbon emulsions comprises an emulsion-contacting sheet formed of: (a) at least one component of the group consisting of natural fibers, cellulose fibers, natural-based fibers, and cellulose-based fibers, at least one component of the group consisting of high-surface-area fibrillated fibers, surface-area-enhancing synthetic material, glass microfibers, and nanoceramic functionalized fibers; and (c) at least one component of the group consisting of a dry strength additive, and a wet strength additive, wherein the fibrous components of the media constitute at least about 70% of the media. In preferred embodiments, the coalescence media comprises kraft fibers, fibrillated lyocell fibers, glass microfibers or nanoceramic functionalized fibers, a wet strength additive, and a dry strength additive. Preferably, the coalescence media is formed as a single, self-supporting layer from a wet-laid process using a homogenously distributed, wet-laid furnish.

Abstract: The present invention relates to demulsifying and dehydrating formulations of heavy crude oil based block copolymers amine bifunctionalized with low polydispersities. These formulations can contain solvents whose boiling point is in the range from 35 to 200° C., preferably: dichloromethane, chloroform, toluene, xylenes, turbosine, naphtha or mixtures thereof.

Abstract: The present invention provides environmentally friendly demulsifiers for the breakdown of petroleum oil applications. The demulsification formulations of the present invention are biodegradable and are low in toxicity. The demulsifiers include a poly(tetramethylene glycol) and an alkylene glycol copolymer linked to the poly(tetramethylene glycol) by a difunctional coupling agent.

Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.

Abstract: One exemplary embodiment can be a process for removing one or more disulfide compounds from a caustic stream. The process may include passing the caustic stream, previously contacted with a hydrocarbon stream for removing one or more thiol compounds, through a vessel containing a coalescing element to remove the one or more disulfide compounds downstream of a three-phase separator and a thiol oxidation zone.

Abstract: Lysine-based polymers, particularly copolymers of lysine and maleic acid, are useful as coagulants for clarification of wastewaters, including produced waters from oils sands mining operations. They can be advantageously used in combination with commercial coagulants, and in combination with flocculants. Such combinations may include dry blends. Also described are methods of preparation of lysine homopolymers and copolymers.

Abstract: Systems and methods for treating a stream comprising a hydrocarbon liquid and an aqueous-based liquid are provided. The systems and methods may utilize a media composite comprising a mixture of a cellulose-based material and a polymer. In certain systems and methods, the media composite is capable of being backwashed. The stream comprising the hydrocarbon liquid and aqueous-based liquid may be separated by contacting the stream with the media composite. In certain system and methods, the stream comprising the hydrocarbon liquid and aqueous-based liquid may be coalesced by contacting the stream with the media composite.

Abstract: A process for the treatment of water/oil (W/O) emulsions is described which includes the addition of an ionic liquid, under heating, to a water/oil emulsion containing between 0.5% and 85% of water per volume as a dispersion phase, until the concentration of the ionic liquid in the emulsion remains within the range of 0.01 ?L/g to 100 ?L/g. The ionic liquid used is a salt of a general C+ A? formula in a liquid state at temperatures below 150° C., where A? is an anion and C+ is a cation, which has at least a hydrophobic alkyl chain connected to a cation group. The heating method includes conventional heating and heating via microwaves. In the heating via microwaves, the salts of the general C+ A? formula present synergic behavior in separation efficiency in relation to conventional heating.

Abstract: A method and apparatus are provided for the controlled application of ultrasonic energy for conditioning of mixtures of gas and liquids by evolving and/or agglomerating gas bubbles existing with or in a liquid or for coalescing droplets of liquid dispersed in another liquid. The invention in preferred embodiments thereof comprises a coalescing apparatus for increasing the droplet size of a mixture formed as a liquid dispersed in another liquid, and a de-gassing apparatus arranged to evolve and/or agglomerate gaseous bubbles in a gas/liquid mixture. In the apparatuses, ultrasonic transducers are used to impart vibrational energy to the mixtures.

Abstract: A deoiling or demulsifying composition including talc. Also disclosed is a process for removal of hydrocarbons, oil or oil-bearing formations from an aqueous stream by adding talc to the aqueous stream. The process may also include one or more of: aerating or injecting air or gas into the aqueous stream; agitating the treated stream to form a layer comprising the hydrocarbons, oil or oil-bearing formations; and separating the layer from the aqueous stream.

Abstract: One exemplary embodiment can be a process for purifying a disulfide oil. The process can include obtaining at least a portion of a disulfide oil coalesced from an alkaline stream, and passing the at least a portion of the disulfide oil through a mesh for recovering a purified disulfide oil stream.

Abstract: The invention provides for a process for treating wastewater containing fluoropolymer resin waste solids comprising: passing the wastewater through hollow fiber membranes to separate fluoropolymer resin waste solids and produce treated filtrate water; and removing the fluoropolymer resin waste solids from the wastewater.

Abstract: A oil and water emulsion breaking system having a reactor including an inner vessel connected to an inlet and an outlet of the reactor and allowing microwaves to pass therethrough, a packed bed of activated carbon retained within and across the inner vessel along at least part of a length thereof and configured for circulation of the emulsion therethrough, and a microwave applicator configured to direct microwaves to the packed bed through the inner vessel.

Abstract: An emulsifier concentrate for producing a working solution comprising 30-50 Vol % of a natural plant oil, selected from colza oil, corn oil, sunflower oil, 10-25 Vol % of octanol as a solubilizer, and 27-55 Vol % of an emulsifier, consisting of 26.5-45 Vol % of a non-ionic tenside, and 0.5-10 Vol % of an anionic tenside.

Abstract: A filter system for removing contaminants from oil based industrial liquids and the like includes a support tube with a permeable sidewall through which the industrial liquid flows in an inside out direction. A multilayer coalescence media surrounds the support tube, and includes at least one layer of a non-woven fibrous material that is partially wettable by the dispersed water in the industrial liquid, and commences coalescence of the same to form small primary water droplets, and at least one sheet of a precisely woven monofilament fabric stacked on the downstream side of the non-woven material. The woven fabric is substantially wettable by the dispersed water, and has a fixed open mesh with uniformly sized and spaced apart pore openings which continue to coalesce the primary water droplets into large water drops which fall from the filter for collection along the bottom of the apparatus.

Abstract: Operation of an oil-water separator or other liquid mixture separator is monitored. The separator uses a vessel through which a mixture of different liquid components flows horizontally. A plurality of ultrasound transducers is provided on a wall of the vessel at different heights at a common stage along the direction of the horizontal flow. Ultrasound at a plurality of different ultrasound wavelengths is transmitted through the vessel between transducers and ultrasound arriving transducers is detected. Parameter values of a model are fitted to the detection. A model is used that relates height dependent properties of liquid in the vessel to properties of the detected ultrasound transmission between transceivers, the model comprising at least a fittable parameter of a height dependent droplet size distribution in a least a sub-range of a height of liquid in the vessel. The model relating the droplet size distribution to ultrasound wavelength dependence of the properties of ultrasound transmission.

Abstract: Oil-containing water is separated in a separator in an automated/continuous operation using devices that is free of moving parts in the separation container. Operation is preferably entirely controlled via adjustment of various flow rates, typically using flow control valves and/or feed pumps in response to measurement of a guided wave radar device or other IDLT.

Abstract: A method of flocculating coal fines from produced water that includes the steps of: (A) mixing at least: (i) produced water, wherein the produced water comprises suspended coal fines; (ii) one or more oil-soluble phosphate esters; and (iii) water-immiscible solvent; wherein the mixing is in proportions to obtain an oil-in-water emulsion; (B) allowing or mechanically causing the oil-in-water emulsion to substantially break into: (i) a first fluid having a continuous phase comprising at least some of the water from the produced water; and (ii) a second fluid having a continuous phase comprising at least some of the water-immiscible solvent; and (C) mechanically separating the first fluid and the second fluid. Optionally, the step of mixing further includes mixing with a crosslinker for the one or more phosphate esters to form a gel for suspending the separated coal fines.

Abstract: The present invention relates to a group and method for the separation of a mixture comprising two fluid phases mutually at least partially immiscible and with different specific density characterized in that it comprises a closed chamber (11) which extends between an upper outlet mouth (12a) of a fluid phase with lower specific density separated from the mixture, positioned at a first upper height, and a lower outlet mouth (12b) of a fluid phase with greater specific density separated from the mixture, positioned at a second lower height with respect to the first upper height, an inlet (15,33) for said mixture inside said closed chamber (11) also being present at a height interposed between said upper and lower heights, a first upper gross separation device (13) of said mixture and a second lower fine separation device (14,14?) of said mixture, hydraulically connected to each other (13) (14), being situated in succession, inside said closed chamber (11), between said upper outlet mouth (12a) and said lower o

Abstract: The present invention provides a method and system for separating phases of a liquid mixture or dispersion from each other. The system includes a settler system, which includes a coalescing-enhancing plate comprising a front face and rear face and a plurality of openings. The openings are configured to selectively manipulate the flux of portions of the mixture to thereby increase phase separation of the mixture.

Abstract: An oil/water emulsion is mixed with functional solid particles to agglomerate oil droplets and/or water droplets having functional solid particles and the functional solid particles are hydrophobicized for the agglomeration of oil droplets or are hydrophilicized for the agglomeration of water droplets. This enables oil and water to be separated from an oil/water emulsion under gravitational forces.

Abstract: Method and system for extracting and recovering hydrocarbons from wastewater and treating the water to improve its condition. A series of specific unit operations result in the extraction of hydrocarbons, solids and contaminants and the treatment of water to a condition which is fit for re-use or environmentally sustainable discharge. Phase separation between the water and hydrocarbons is effected using flotation techniques followed by collection of the hydrocarbons using a movable collection surface. The aqueous phase is processed by multiple filtration steps. The result is significant extraction and recovery of hydrocarbons and conservation of water for re-use or discharge to the environment in a process which is continuous and scalable for large or small operations.

Abstract: Fibrillar bacterial proteins can be mixed with oil in or on water. The interaction of the proteins at the oil-water interface can result in oil dispersion in water in the form of droplets surrounded by an aggregated protein film The film may be formed by multiple layers of the fibrillar proteins with water between adjacent protein layers. The proteins may be derived from bacterial cells, such as Bacillus subtilis. The encapsulated oil droplets can be collected from the water, for example, as part of an oil spill clean-up or oil storage. The oil may be removed from the collected droplets, for example, by evaporation to produce a three-dimensional network composed of the aggregated films. The three-dimensional network material can be used as a coating for transplant material, grafted onto implant material to improve biocompatibility, as a precursor for tissue growth or engineering, or provided into a human or animal body.

Abstract: An immiscible lipophilic or hydrophilic liquid phase is separated respectively from a continuous hydrophilic or a lipophilic phase liquid. Fibers having hydrophilic and hydrophobic properties are formed into a filter. The separation mechanism involves coalescence of the small droplets into larger droplets as the immiscible liquid flows through the fiber filter, and release of the large immiscible droplets from the filter. With respect to separation of a hydrophilic immiscible fluid in a lipophilic continuous fluid, the hydrophobic fibers cause small water droplets to migrate towards the hydrophilic fibers whereby large droplets are formed on hydrophilic surface. The large droplets coalescence until they are so large that they are released and drained off of the filter. The filter media can be designed by mixing hydrophilic and hydrophobic fibers in various proportions to achieve an optimum wettability range for separation of the immiscible liquid from the continuous phase liquid.

Abstract: The use of alkoxylated polyalkanolamines as demulsifiers for splitting oil-water emulsions, especially for splitting crude oil emulsions.

Abstract: Processes for recovering an organic solvent extractant phase from a solid-stabilized emulsion formed in a hydrometallurgical solvent extraction circuit are disclosed. One such process includes mixing a de-emulsifier comprising an effective amount of a polymeric aggregating agent with the solid-stabilized emulsion, thereby separating the emulsion into its aqueous, organic, and solid phase components; and removing the organic solvent extractant phase from the other components, thereby recovering the organic solvent extractant phase from the solid-stabilized emulsion.

Abstract: A system adapted to condition an initial water feed stream into a treated water stream and to discharge the treated water stream. The initial water feed stream includes at least one of: a plurality of particles; an oil; a volatile organic compound; a hydrogen sulfide; a non-volatile compound; a heavy metal; and, a dissolved ion. The system includes a particle and oil removal subsystem adapted to treat the initial water feed stream to remove the plurality of particles and the oil to form a first partial treated water stream, a chemical oxygen demand reduction subsystem adapted to treat the first partial treated water stream to remove the volatile organic compound, the hydrogen sulfide and/or the non-volatile organic compound to form a second partial treated water stream, and a heavy metal and dissolved ion removal subsystem adapted to treat the second partial treated water stream to remove the heavy metal and the dissolved ion to form a treated water stream.

Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a polyorganosiloxane demulsifier into an emulsion comprising an oil phase and an aqueous phase. The invention also relates to compositions containing polyorganosiloxane demulsifier and the water and oil phases of an emulsion.

Abstract: A system for processing drilling mud, the system including a primary separation tank having an inlet for receiving drilling waste and an outlet in fluid communication with a feed line, and an injection pump in fluid communication with a polymer tank and the feed line. The system also includes a clarifying tank in fluid communication with the feed line and a first collection tank, wherein effluent from the clarifying tank is discharged into the first collection tank, and a centrifuge in fluid communication with the clarifying tank and a second collection tank, wherein effluent from the centrifuge is discharged into the second collection tank.

Abstract: An emulsion treating unit and process. A subcooled boiling zone in the unit comprises a heat transfer surface to contact an emulsion at a temperature in excess of the saturation temperature of an aqueous phase in the emulsion, wherein the boiling zone is atmospherically vented. The unit also provides means for recovering an oil-rich layer from adjacent a vapor-liquid interface; and means for recovering an aqueous-rich layer from below the oil-rich layer. The process provides operation of the treating unit to heat an emulsion in the subcooled boiling zone, wherein the boiling zone is atmospherically vented, recovering an oil-rich layer and recovering an aqueous-rich layer from below the oil-rich layer. In one embodiment the boiling zone comprises a heat transfer surface having a temperature in excess of the saturation temperature of the aqueous-rich layer, wherein the vapor-liquid interface is subcooled with respect to the saturation temperature of the aqueous layer.

Abstract: A method for retracting oil on a water surface, and a method for reducing the quantity of oil on an oil control boom are described. Spreading of oil can be reversed by reducing the surface tension of the seawater, for example by using a low concentration of a water-soluble surfactant, such as a non-ionic surfactant. A controlled amount of the surfactant may be continuously discharged at the inner-wall of a spill control boom surrounding the oil spill. The spilled oil is caused to retract away from the boom toward the center of the area encircled thereby, such that the oil layer becomes sufficiently thick to be more effectively removed mechanically. The surfactant also reduces the amount of oil on the spill control boom, whereby the boom can easily be removed from a remediated oil spill and reused at a later date without further cleaning.

Abstract: A device and method for continuously breaking an initial emulsion of the water-in-oil type includes a first step of mixing the initial emulsion with a superheated washing water so as to obtain an intermediate emulsion of the water-in-oil type that comprises a hydrophilic phase and a hydrophobic phase, and that has a number-average diameter of the droplets less than or equal to 50 ?m, and a temperature above 100° C. and below the boiling point of the hydrophilic phase at the pressure of the intermediate emulsion. A second step includes destruction of the intermediate emulsion by a liquid-liquid separator so as to obtain a separated hydrophilic phase and a separated hydrophobic phase.

Abstract: Disclosed is a process which comprises mixing an alkylated aromatic acid with a mixture comprising a first liquid and a second liquid, thereby causing formation of an organogel comprising the alkylated aromatic acid and the first liquid.

Abstract: Our idea is a new procedure that can be used to clean up and recover oil from spills or oil leaking from damaged ships or rigs. The reclamation is accomplished by restoring the oil's light density. This is accomplished with density control by adding light cycle oil, (LCO), with a density of 0.82 g/ml, to the oil being recovered for the purpose of reprocessing in refineries. Recovery is made possible through the application of solubility rules found in organic chemistry. LCO is a mixture of many different molecular weight hydrocarbons that have many different numbers of carbons in their chains, branches, or rings. Each of these hydrocarbons dissolves a small part of the oil preparing the mixture for collection and reprocessing as refinery feedstock. Furthermore, this idea can prevent the need for landfill storage and offset the cost of recovery.

Abstract: This invention relates to devices and processes for removing asphaltenes and/or metals from crude oil to increase refinery processing of heavy materials. The desalters of this invention reduce and/or remove at least a portion of asphaltenes and/or metals form the crude oil. The separation occurs by mixing water with the crude oil to result in an aqueous phase having water and water soluble salts, an interface phase having asphaltenes and/or metals along with water, and a hydrocarbon phase haying desalted, deasphalted and/or reduced metal crude oil.

Abstract: A method and system for recovering fluid (e.g. liquid) hydrocarbons from both naturally-occurring and man-made mixtures of hydrocarbons and mineral substrates by the exploiting of buoyant beads.

Abstract: Methods and systems for enhanced water treatment comprise inorganic filter systems for impurity removal. Embodiments for water impurity removal include introducing contaminated water into an impurity removal system having an inorganic filter. The inorganic filter comprises an inorganic membrane layer supported by an inorganic support. The inorganic membrane layer comprises pores sized from about 1,000 Daltons to about 10 microns for filtering impurities such as kinetic hydrate inhibitor. Other pre-treatment and post-treatment stages may be included. The inorganic membrane layer or inorganic membrane support may comprise a ceramic such as alumina, zirconia, silica, silicon carbide, and mixed oxides.

Abstract: Despite advances in off-shore oil exploration and drilling technology, accidental oil spills do occur. Depending on their magnitude and location, irreparable damage may be inflicted on marine and coastal ecosystems. Emulsification of a water/surfactant /oil system results in the production of oil droplets and this depends on the formulation and composition variables, mixing characteristics and system preparation. Thus, research is ongoing on improving methods of cleaning up oil spills. Cactus mucilage was used to disperse and absorb oil from a simulated oil slick in different salt concentrations. Results show correlations between emulsion properties and interfacial characteristics of mucilage as function of aqueous phase salinity. Mucilage powder added to the oil floating on the water dispersed the oil film and absorbed the oil while remaining afloat, facilitates removal of the oil-mucilage aggregate.

Abstract: A coalescing apparatus including a casing having an inner chamber for accommodating insulating fluid. At least one tube of electrically insulating material extends through the casing and the chamber. Each tube forms a flow channel for emulsion to be treated. A set of electrodes is mounted in the chamber. The tube is allotted at least one pair of electrodes of the set. A voltage set is configured to apply mutually different electric potentials to the electrodes of each electrode pair so as to form an electric field between them and thereby an electric field inside the respective tube. A heater is configured to heat the insulating fluid so as to allow the insulating fluid to transfer heat to emulsion flowing through at least one tube and thereby raise the temperature of the emulsion. An emulsion treatment system includes a coalescing apparatus. A coalescing method.

Abstract: Methods are described for removing contaminates from aqueous industrial wastewater process streams, specifically industrial laundries to yield a less contaminated aqueous effluent for discharge to a sewer and reduce the sludge generated therefrom. A premixed medium/high molecular weight and medium/high charged cationic coagulant solution polymer and an inorganic aluminum species is added to the wastewater, and after at least a two second delay, a high molecular weight highly charged anionic flocculent is injected into the wastewater which reduces sludge generation, while maintaining or exceeding effluent quality. Also, no coagulant, flocculent or sludge aids are needed to attain the results and the sludge can be dewatered in a plate and frame press.

Abstract: Disclosed is a process for the alteration of the ratio of the specific gravities of the oil and water phases resulting from the conversion of biomass to liquid products, the reduction of the conductivity and of metals of the product mixture, which each can aid in the removal of solids contained in the oil phase.

Abstract: This invention provides a semisolid complex exhibiting (i) the ability to float on water, (ii) the ability to provide liquid oil upon being deformed, and (iii) the ability to function as a fuel, the complex comprising a high proportion of liquid oil, the density of the oil being lower than the density of water, the complex also comprising fibers, the fibers being oriented in a plurality of directions, the fibers forming a framework, the framework being incorporated in the complex, the framework being substantially in the plane of the complex in case that the complex is in the form of a sheet, and the framework extending substantially over the area of the complex in case that the complex is in the form of a sheet, the complex further comprising a low proportion of bentonite, the bentonite being associated with the oil, the associating substantially involving coagulation, the oil and the bentonite being substantially held by the framework.

Abstract: A method and apparatus are disclosed for separating a multiphase fluid stream that includes a heavier fluid component and a lighter fluid component. The fluid flows along a first helical flowpath with a first pitch. The first helical flowpath is sufficiently long to establish a stabilised rotating fluid flow pattern for the stream. The uniform rotating fluid also flows along a second helical flowpath, the second helical flowpath having a second pitch greater than the first pitch. The lighter fluid is removed from a radially inner region of the second helical flowpath. The method and apparatus are particularly suitable for the separation of oil droplets from water, especially from water for reinjection into a subterranean formation as part of an oil and gas production operation. The method and apparatus are conveniently applied on a modular basis.

Abstract: In a process and apparatus for treating produced water, for example for re-use in an oil or bitumen extraction operation of for treating frac water, the produced water flows through a series of treatment units. A portion of the produced water may by-pass one or more of the treatment units but the by-pass portion may be such that the treated water is still acceptable, for example for discharge or reuse. Concentrations of oil and grease, organic carbon, silica, pH or related parameters in the produced water may be monitored and used to control the process or apparatus. Control of the process may involve one or more of altering a by-pass portion, altering the addition of chemicals, and altering the operation of a unit process. The process may be controlled to respond to upset conditions, or such that the concentration of one or more limiting contaminants is near, but not over, a specified maximum for re-use or discharge.

Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.

Abstract: An apparatus for separating hydrophilic material from hydrophobic material, comprising: (a) a body having a first and second parallel walls defining an elongated cavity; (b) a water-absorbing material in the cavity along the first wall and having a surface essentially parallel to the second wall, thereby defining a channel between the surface and the second wall; (c) a first inlet having a first inlet end disposed in the channel, the first inlet being configured for injecting a mixture of hydrophilic and hydrophobic material; (d) a first outlet having a first outlet end disposed in the channel proximate the surface downstream of the first inlet end and configured for removing the hydrophilic material; and (e) a second outlet having a second outlet end disposed in the channel a distance from the surface downstream of the first inlet end and configured for removing the hydrophobic material.

Abstract: A method for removing contaminants such as oil and solids from water by feeding a mixture of water containing the contaminants and carbon dioxide to a cyclone; separating water from the mixture; separating a second mixture of oil, carbon dioxide and water from the mixture and feeding the second mixture to a separator wherein oil, carbon dioxide and water are recovered from the separator.

Abstract: A separation process for separating two or more immiscible liquids using contactors utilizing high surface area vertical hanging fibers is disclosed. This separation process is especially useful in the separation of disulfide oil formed during the oxidation of spent caustic solution that was used to remove sulfur contaminates from light hydrocarbons.

Abstract: An integrated unit operations for the treatment of a waste stream, such as spent caustic, is provided in a single vertical vessel having at least three separate zones: a mixing, a settling, and a mass transfer zone.

Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.