Abstract: The present invention relates to a phosphor comprising a nitride or an oxynitride, comprising an X-ray powder diffraction pattern comprising at least one Region having at least one peak with an intensity ratio I of 8% or less, the X-ray powder diffraction pattern measured in the 2? range from 10° to 60° using a CuK? line (1.54184 {acute over (?)}), wherein the Region is the 2? range from 41.5° to 47°, the intensity of each peak is a value obtained after background correction, and the intensity ratio I is defined by the formula (Ip×100)/Imax (%), where Imax represents the height of the most intense peak present in the 2? range from 34° to 37° and Ip represents the height of each peak.

Abstract: A red-emitting phosphor composed of an M-Al—Si—N system, comprising a cation M, wherein M is represented by at least one of the elements Ca or Ba or Sr and, if appropriate, can additionally be combined with at least one further element from the group Mg, Zn, Cd, wherein the phosphor is activated with Eu, which partly replaces M, and wherein the phosphor additionally contains LiF.

Abstract: Provided are: a silicon nitride powder for siliconitride phosphors with higher luminance, which can be used for a fluorescent display tube (VFD), a field emission display (FED), a plasma display panel (PDP), a cathode ray tube (CRT), a light emitting diode (LED), and the like; a CaAlSiN3 phosphor, an Sr2Si5N8 phosphor, an (Sr, Ca)AlSiN3 phosphor and an La3Si6N11 phosphor, each using the silicon nitride powder; and methods for producing the phosphors. The present invention relates to a silicon nitride powder for siliconitride phosphors, which is characterized by being a crystalline silicon nitride powder that is used as a starting material for producing a siliconitride phosphor that includes silicon element and nitrogen element but does not contain oxygen element as a constitutent element, and which is characterized by having an oxygen content of 0.2% by weight to 0.

Abstract: A silicate fluorescent material is provided. The general chemical formula of the luminescent material is Ln2SiO5:Tb, M, wherein Ln represents at least one of the elements selected from Y, Gd, La or Lu, M represents at least one of the nanoparticles selected from Ag, Au, Os, Ir, Pt, Ru, Rh or Pd, the mole ratio of Tb to Ln is greater than 0 but not greater than 0.25. The porous glass containing metal nanoparticles is prepared by introducing metal nano ions into the porous glass and extracting the uniformly dispersed metal nanoparticles from the porous glass via a chemical reduction method. A silicate fluorescent material with enhanced luminescence is obtained by substituting SiO2 which is the raw material in the process for preparing the silicate fluorescent material via the conventional high temperature solid phase sintering with the porous glass containing metal nanoparticles.

Abstract: Exemplary embodiments of the present invention relate to inorganic phosphors based on silicate compounds having improved stability under a resulting radiation load and resistance to atmospheric humidity, which are capable of converting higher-energy excitation radiation, i.e. ultraviolet (UV) or blue light, with high efficiency into a longer-wavelength radiation which may be in the visible spectral range. A calcium molar fraction x having a value between 0 and 0.05 is added to a silicate phosphor having the general formula Sr3-x-y-zCaxMIIySiO5:Euz.

Abstract: A phosphor of formula I is included in a phosphor composition in a lighting apparatus capable of emitting white light, Ca3-x-zSrxCezM12M2AlSiO12??(I) wherein M1 is Hf, Zr, or a combination thereof; M2 is Al, or a combination of Al and Ga; z<3?x; and 0.2>x?0. The lighting apparatus includes a semiconductor light source in addition to the phosphor composition.

Abstract: A phosphor represented by Formula 1: (A1?(a+b)EuaLnb)1?x(B1?cMnc)2Al(6+b?2x)Si(9?b+2x)O30??Formula 1 wherein A includes at least one element selected from the group consisting of Ca, Sr and Ba, Ln includes at least one metal selected from the group consisting of a trivalent rare earth metal, B includes at least one element selected from the group consisting of Mg, Zn, Ge and Co, a is greater than 0 and equal to or less than about 0.5, b is greater than 0 and equal to or less than about 0.25, c is greater than 0 and less than about 0.8, and x is 0 to about 0.2. Also a white light emitting device including the phosphor.

Abstract: A white light emitting glass-ceramic. The chemical formula of the glass-ceramic is aSiO2.bAl2O3.cNaF.dCeF3.nDyF3.mAg, wherein a, b, c, d, n and m are, by mol part, 25-50, 15-30, 10-30, 10-25, 0.01-1 and 0.01-1, respectively, and a+b+c+d-100. A method for producing said glass-ceramic is also provided. Silver ion is doped in the glass-ceramic in the form of silver particles by means of sintering and reduction annealing treatment, and thus the luminescence properties of rare earth ion is improved.

Abstract: A preparation method of rare earth ions doped alkali metal silicate luminescent glass is provided. The steps involves: step 1, mixing the source compounds of cerium, terbium and alkali metals and putting the mixture into solvent to get a mixed solution; step 2, impregnating the nanometer micropores glass with the mixed solution obtained in step 1; step 3: calcining the impregnated nanometer micropores glass obtained in step 2 in a reducing atmosphere, cooling to room temperature, then obtaining the cerium and terbium co-doped alkali metal silicate luminescent glass. Besides, the rare earth ions doped alkali metal silicate luminescent glass prepared with aforesaid method is also provided. In the prepared luminescent glass, cerium ions can transmit absorbed energy to terbium ions under the excitation of UV light due to the co-doping of cerium ions. As a result, the said luminescent glass has higher luminous intensity than the glass only doped with terbium.

Abstract: Oxide luminescent materials and preparation methods thereof are provided. The said luminescent materials are represented by the general formula: aRe2O3.bSiO2.cEu2O3.dM, wherein Re is at least one selected from Gd and Y, M is selected from metal nano-particles, (a+c):b=0.5-5, d:b=5×10?5-5×10?3, c:(a+c)=0.02-0.1. Compared to the oxide luminescent materials in the art, the said luminescent materials have higher luminescent intensity.

Abstract: Silicate luminescent materials and preparation methods thereof are provided. The luminescent materials are represented by the general formula: M2aM3bSicO[a+3(b+x)/2+2c]:xCe3+, yM0, M2 is at least one selected from Ca, Sr, Ba, Mg and at least contains Ca, M3 is Sc, Sc and Y, M0 is one selected from metal nano particles of Ag, Au, Pt, Pd or Cu, wherein 2.8?a?3.2, 1.8?b?2.1, 2.9?c?3.3, 0.01?x?0.2 and 1×10?4?y?1×10?2. Compared to the luminescent materials in the prior art, the said luminescent materials have higher luminous efficiency and more stable performance and structure. The said methods have simple technique and low cost, therefore are appropriate to be used in industry.

Abstract: A light-emitting device is produced using a phosphor composition containing a phosphor host having as a main component a composition represented by a composition formula: aM3N2.bAlN.cSi3N4, where “M” is at least one element selected from the group consisting of Mg, Ca, Sr, Ba, and Zn, and “a”, “b”, and “c” are numerical values satisfying 0.2?a/(a+b)?0.95, 0.05?b/(b+c)?0.8, and 0.4?c/(c+a)?0.95. This enables a light-emitting device emitting white light and satisfying both a high color rendering property and a high luminous flux to be provided.

Abstract: The embodiment provides a red light-emitting fluorescent substance represented by the following formula (1): (M1-xECx)aM1bAlOcNd??(1). In the formula (1), M is an element selected from the group consisting of IA group elements, IIA group elements, IIIA group elements, IIIB group elements, rare earth elements and IVA group elements; EC is an element selected from the group consisting of Eu, Ce, Mn, Tb, Yb, Dy, Sm, Tm, Pr, Nd, Pm, Ho, Er, Cr, Sn, Cu, Zn, As, Ag, Cd, Sb, Au, Hg, Tl, Pb, Bi and Fe; M1 is different from M and is selected from the group consisting of tetravalent elements; and x, a, b, c and d are numbers satisfying the conditions of 0<x<0.2, 0.63<a<0.80, 2.1<b<2.63, 0<c?0.24 and 4<d<5, respectively. This substance emits luminescence having a peak in the wavelength range of 620 to 670 nm when excited by light of 250 to 500 nm.

Abstract: The invention relates to an improved red light emitting material of the formula M1?yA1+xSi4?xN7?x?2yOx+2y:RE whereby M is selected out of the group comprising Ba, Sr, Ca, Mg or mixtures thereof, A is selected out of the group comprising Al, Ga, B or mixtures thereof, RE is selected out of the group comprising rare earth metals, Y, La, Sc or mixtures thereof and x is ?0 and ?1 and y is ?0 and ?0.2. This material is believed to crystallize in a novel structure type that comprises two individual lattice sites for rare earth metal incorporation, which leads to an improved lighting behaviour.

Abstract: An object of the present invention is to provide an inorganic phosphor having fluorescence properties emitting an orange or red light which has a longer wavelength as compared with the cases of conventional sialon phosphors activated with a rare earth. The invention relates to a design of white light-emitting diode rich in a red component and having good color-rendering properties by employing a solid solution crystal phase phosphor which uses as a host crystal an inorganic compound having the same crystal structure as that of a CaSiAlN3 crystal phase and to which M (wherein M is one or two or more elements selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb) is added as an emission center.

Abstract: A luminescent material and a preparation method thereof are provided. The said luminescent material is represented by the following chemical formula: Ln2?EuxSn2O7, wherein Ln is selected from one of Gd, Y and La, 0.1?x?1.5. The said luminescent material has good electrical performance, anti-electron bombardment and stable luminescent property. It is appropriate to be used in field emission light-emitting devices. The said preparation method has simple technique, no pollution, manageable process conditions, low preparation temperature and low equipment requirement, and is beneficial to industry production.

Abstract: A luminescent material of silicate is provided. The luminescent material has a formula of Ln2-x-ySiO5:Cex,Tby,Agz, wherein, Ln is one of Y, Gd, La and Lu, 0<x-0.05, 0.01y0.25, 0<z0.005. The method for preparing the luminescent material comprises the following steps: weighing the source compounds of Ln, Ce, Tb, Ag and silica aerogel; dissolving the silica aerogel in the alcoholic solution of the source compound of silver, stirring, drying and sintering to obtain silica aerogel containing Ag; after mixing the weighed source compounds of Ln, Ce, Tb and the silica aerogel containing Ag, sintering under reducing atmosphere to obtain the luminescent material of silicate.

Abstract: Disclosed is a halogen silicate luminescent material having a chemical structural formula of (N1-a-bEuaMnb)10Si6O21Cl2:xM, and the preparation method thereof, where M is at least one of Ag, Au, Pt and Pd, N is an alkaline earth metal and specifically at least one of Mg, Ca, Sr and Ba, 0<x?1×10?2, 0<a?0.3, and 0?b?0.3.

Abstract: Provided is a fluorescent powder of halogen-silicate containing nano-metal particles with the formula of CaX2.y(Ca1-a-bEuaMnbO).SiO2:zM, wherein X is fluorin or/and chlorine, y is 1 or 2, z is molar ratio of nano-metal particles and fluorescent powder CaX2.y(Ca1-a-bEuaMnbO).SiO2, 0<z1×10?2, 0<a0.3, 0b0.3. The method for preparing the fluorescent powder is also provided. For the surface plasma resonance effect occurring on the surface of the nano-metal particles, the fluorescent powder has stronger luminous intensity. The preparation method is simple to operate, no pollution, easy to control, easy to produce in industry, and can be widely used in the preparation field of fluorescent powder.

Abstract: Offered is a fluorescent substance consisting of Eu-activated ?-sialon and capable of enhancing the brightness of a light emitting device such as a white LED using blue or ultraviolet light as a light source. The fluorescent substance has as its main constituent a ?-sialon represented by the general formula Si6-zAlzOzN8-z and containing Eu, wherein the spin density is 2.0×1017/g or less as measured by electron spin resonance spectroscopy corresponding to an absorption of g=2.00±0.02 at 25° C. In the above fluorescent substance, it is preferable that lattice constant a of the ?-sialon be 0.7608-0.7620 nm, the lattice constant c be 0.2908-0.2920 nm, and the Eu content be 0.1-3 mass %.

Abstract: The formula of a luminescent material is NaY1-xLnxGeO4, wherein Ln is lanthanon, and the value of x is 0<x?0.2. The luminescent material adulterated with lanthanon constitutes germanate luminescent material comprising lanthanon, which improves efficiently the stability and luminescent performance of the luminescent material. The presence of lanthanon enables the luminescent material to emit light with different colors such as red, green, blue, etc. under the excitation of cathode rays, and be better used in a filed emission device. In the preparation method of the luminescent material, source components are mixed up and directly and sintered, and the luminescent material is acquired.

Abstract: A transparent glass ceramic emitting white light and preparation method thereof are provided. The chemical formula of the transparent glass ceramic is aSiO2.bAl2O3.cNa.dCeF3.xDyF3, wherein a, b, c, d, and x are mole fractions, a is 35˜50, b is 15˜30, c is 5˜20, d is 5˜20, x is 0.01˜1, and a+b+c+d=100. The transparent glass ceramic can be substituted for the combination of epoxy resin or silica gel and fluorescent powder to seal LED. The transparent glass ceramic has strong excitation spectrum with broadband at ultraviolet area, and can emit strong white light under the excitation of ultraviolet light.

Abstract: To provide a new phosphor of which fluorescence contains much red light component and has a large full width at half maximum, the crystal phase represented by the formula [I] is included in the phosphor. R3?x?y?z+w2MzA1.5x+y?w2Si6?w1?w2AlW1+w2Oy+w1N11?y?w1??[I] (R represents La, Gd, Lu, Y and/or Sc, M represents Ce, Eu, Mn, Yb, Pr and/or Tb, A represents Ba, Sr, Ca, Mg and/or Zn, and x, y, z, w1 and w2 are the numeric values in the following ranges: ( 1/7)?(3?x?y?z+w2)/6<(½), 0<(1.

Abstract: The invention is a phosphor which includes a phosphor material having a composition represented by a general formula: M(0)aM(1)bM(2)x?(vm+n)M(3)(vm+n)?yOnNz?n, wherein M(0) is one or more elements selected from Li, Na, Be, Mg, Ca, Sr, Ba, Sc, Y, La, Gd and Lu; M(1) is one or more activators selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm and Yb; M(2) is one or more elements selected from Si, Ge, Sn, Ti, Hf and Zr; M(3) is one or more elements selected from Be, B, Al, Ga, In, Tl and Zn; O is oxygen; N is nitrogen; and an atomic ratio of M(0), M(1), M(2), M(3), O and N is adjusted to satisfy the following: x, y and z satisfy 33?x?51, 8?y?12 and 36?z?56; a and b satisfy 3?a+b?7 and 0.001?b?1.2; m and n satisfy 0.8·me?m?1.2·me and 0?n?7 in which me=a+b; and v satisfies v={a·v(0)+b·v(1)}/(a+b) (wherein v(0) is a valence of M(0) ion and v(1) is a valence of M(1) ion). The invention also relates to a method for producing the phosphor and a light-emitting device using the phosphor.

Abstract: A red-emitting phosphor composed of an M-Al—Si—N system, comprising a cation M, wherein M is represented by at least one of the elements Ca or Ba or Sr and, if appropriate, can additionally be combined with at least one further element from the group Mg, Zn, Cd, wherein the phosphor is activated with Eu, which partly replaces M, and wherein the phosphor additionally contains LiF.

Abstract: An oxynitride fluorescent material includes a JEM phase as a mother crystal and a luminescence center element Ce. The oxynitride fluorescent material has a fluorescence spectrum with a maximum emission wavelength of 420 nm to 500 nm inclusive and an excitation spectrum with a maximum excitation wavelength of 250 nm to 400 nm inclusive.

Abstract: To provide a phosphor having an emission spectrum with a broad peak in a range from green color to yellow color, having a broad and flat excitation band capable of using lights of broad range from near ultraviolet/ultraviolet to blue lights as excitation lights, and having excellent emission efficiency and luminance. The problem is solved by providing the phosphor expressed by a general composition formula MmAaBbOoNn:Z (where element M is one or more kinds of elements having bivalent valency, element A is one or more kinds of elements having tervalent valency, element B is one or more kinds of elements having tetravalent valency, O is oxygen, N is nitrogen, and element Z is one or more kinds of elements acting as the activator), satisfying 4.0<(a+b)/m<7.0, a/m?0.5, b/a>2.5, n>o, n=2/3m+a+4/3b?2/3o, and having an emission spectrum with a peak wavelength of 500 nm to 650 nm when excited by light in a wavelength range from 300 nm to 500 nm.

Abstract: There are provide a silicate-based phosphor excellent in emission intensity and a manufacturing method of the same. A manufacturing method of a silicate-based phosphor is characterized by: introducing in a vessel raw material powders having a compound containing light-emitting ions selected from at least one of Eu, Ce, Mn, and Tb; and firing the raw material powders while supplying SiOx (0.5?x?1.9, preferably, 0.8?x?1.2) in a gas phase. The raw material powders preferably further contains at least one of an alkali metal compound, an alkaline-earth metal compound, a magnesium compound, and a rare-earth compound. The silicate-based phosphor is preferably M2SiO4:Eu2+ (wherein M is one or more selected from a group consisting of Ca, Sr and Ba). The firing is preferably performed by supplying the SiOx to the raw material powders in a gas atmosphere at a temperature of 1200 to 1700° C. and subjecting the raw material powders to a gas-solid phase reaction at a temperature of 700 to 1700° C.

Abstract: The invention provides a phosphor composed of (M1?xREx)5SiO4?yX6+2y, wherein M is Ba individually or in combination with at least one of Mg, Ca, Sr, or Zn; RE is Y, La, Pr, Nd, Eu, Gd, Tb, Ce, Dy, Yb, Er, Sc, Mn, Zn, Cu, Ni, or Lu; X is F, Cl, Br, or combinations thereof; 0.001?x?0.6, and 0.001?y?1.5. Under excitation, the phosphor of the invention emits visible light and may be collocated with other phosphors to provide a white light illumination device.

Abstract: A method for producing an ?-sialon-based oxynitride phosphor includes a mixed powder blended such that the product is represented by the formula: MxSi12?(m+n)Al(m+n)OnN16?n:Lny (wherein M is at least one metal selected from Li, Ca, Mg, Y and a lanthanide metal excluding La and Ce, Ln is at least one lanthanide metal selected from Eu, Dy, Er, Tb and Yb), the mixed powder containing an amorphous silicon nitride powder having an loose bulk density of 0.16 to 0.22 g/cm3, and is fired at 1,400 to 2,000° C. in a nitrogen-containing inert gas atmosphere.

Abstract: A silicate luminescent material and the production method thereof are provided. The chemical formula of the silicate luminescent material is Re4?xTbxMgSi3O13, wherein Re is at least one element selected from the group consisting of Y, Gd, La, Lu and Sc, and 0.05?x?1. The silicate luminescent material has a short afterglow of 2.13 ms, and it can emit strong green light under the vacuum ultraviolet excitation. Additionally, the silicate luminescent material has stable physical and chemical properties. The production method for producing the silicate luminescent material is simple and cost-efficient.

Abstract: The invention relates to a new class of luminescent substances (phosphorous) based on an universally dopable matrix made of an amorphous, at the most partially crystalline network of the elements P, Si, B, Al and N, preferably the composition Si3B3N7. Optical excitation and emission can be varied in this system over the entire practically relevant field by incorporation of any cationic activators, alone or in combination, but also by incorporation of oxygen as anionic component. This opens up the entire spectrum of use of luminescent substances, such as illumination systems or electronic screens.

Abstract: A method of manufacturing an oxynitride phosphor is revealed. A precursor is sintered under 0.1-1000 MPa nitrogen pressure for synthesis of an oxynitride phosphor. The general formula of the oxynitride phosphors is MxAyBzOuNv (0.00001?x?5; 0.00001?y?3; 0.00001?z?6; 0.00001?u?12; 0.00001?v?12). M is an activator or a mixture of activators. A is a bivalent element or a mixture of bivalent elements. B is a trivalent element, a tetravalent element, a mixture of trivalent elements or a mixture of tetravalent elements. O is a univalent element, a bivalent element, a mixture of univalent elements, or a mixture of bivalent elements. N is a univalent element, a bivalent element, a trivalent element, a mixture of univalent elements, a mixture of bivalent elements, or a mixture of trivalent elements. Thus pure phosphor can be mass-produced.

Abstract: An oxynitride phosphor and a method of manufacturing the same are revealed. The formula of the oxynitride phosphor is Ba3-x-ySi6O12N2:Cey, Eux (0?x?1, 0?y?1). Europium (Eu) and cerium (Ce) are luminescent centers. The oxynitride phosphor is synthesized by solid-state reaction. The oxynitride phosphor is excited by vacuum ultraviolet light with a wavelength range of 130 nm to 300 nm or ultraviolet to visible light with a wavelength range of 350 nm to 550 nm. The emission wavelength of the oxynitride phosphor is ranging from 400 nm to 700 nm. Thus the oxynitride phosphor can be applied to plasma display panels and ultraviolet (UV) excitation sources. The energy transfer occurs between Ce and Eu of the oxynitride phosphor and the oxynitride phosphor has a blue light emission peak and a green light emission peak. Thus color rendering index of the oxynitride phosphor is improved.

Abstract: A white light emitting device capable of expanding the wavelength range of a blue LED used for realizing white light. The white light emitting device according to the present invention includes a blue LED and a mixture of orange phosphor and green phosphor disposed above the blue LED.

Abstract: A luminous nano-glass-ceramics used as white LED source and the preparing method of nano-glass-ceramics are provided. The glass is a kind of non-porous compact SiO2 glass in which luminous nano-microcrystalites are dispersed. The luminous nano-microcrystalite has the chemical formula of YxGd3-xAl5O12:Ce, wherein 0?x?3. The stability of the said glass is good and its irradiance is uniform. The preparing method comprises the following steps: dissolving the compound raw materials in the solvent to form mixed solution, dipping the nano-microporous SiO2 glass in the solution, taking it out and air drying, sintering at the temperature of 1100-1300° C. for 1-5 hours by stage heating, and obtaining the product. The method has a simple process, convenient operation and low cost.

Abstract: The present invention relates to a waterproof multiple rare-earth co-activated long-afterglow luminescent material having its general chemical composition depicted by a formula aMO.bAl2O3.cSiO2.dGa2O3:xEu.yB.zN, wherein a, b, c, d, x, y, and z are coefficients with the ranges of 0.5?a?2, 0.5?b?3, 0.001?c?1, 0.0001?d?1, 0.0001?x?1, 0.0001?y?1, 0.0001?z?1, M is Ca or Sr, N is Dy or Nd, wherein Sr (or Ca), Al, Si, Ga are main substrate matrix elements and Eu, B, Dy (or Nd) elements are activators. The waterproof multiple rare-earth co-activated long-afterglow luminescent material according to the present invention not only has advantage of a longer afterglow time, but also has water resistance greatly superior to rare-earth activated aluminate long-afterglow luminescent material in the prior art, and still keeps higher long-afterglow property after dipping into water for 60 hours, especially shows its superiority when working or used under the environment of dipping into water or dampness.

Abstract: The present invention provides a ?-SiAlON phosphor that contains a ?-SiAlON represented by a general formula Si6-zAlzOzN8-z (0<z<4.2) as a matrix and Eu2+ in a form of a solid solution as an emission center, and exhibits a peak within a wavelength range from 520 to 560 nm when excited by blue light. The average diffuse reflectance of this ?-SiAlON phosphor in the wavelength range from 700 to 800 nm is 90% or higher, and the diffuse reflectance in the fluorescent peak wavelength is 85% or higher.

Abstract: A method of manufacturing ?-SiAlON represented by a general formula Si6-zAlzOzN8-z:Eu, including a baking step for baking a powdered material that contains Al content from 0.3 to 1.2 mass %, O content from 0.15 to 1 mass %, O/Al molar ratio from 0.9 to 1.3, Si content from 58 to 60 mass %, N content from 37 to 40 mass %, N/Si molar ratio from 1.25 to 1.45, and Eu content from 0.3 to 0.7 mass %. The baking step is a step of baking the powdered material in a nitrogen atmosphere at temperatures from 1850° C. to 2050° C., and the manufactured ?-SiAlON satisfies 0.280?x?0.340 and 0.630?y?0.675 on the CIExy chromaticity coordinate.

Abstract: The present invention provides an organic/inorganic composite containing an inorganic phase dispersed in an organic polymer, the inorganic phase comprises one or more metal atoms that are coordinated to at least one rare earth metal atom via oxygen. The composite contains at least 5 mass % of rare earth metal. This rare earth metal is dispersed in the inorganic phase.

Abstract: A phosphor, which is given by a general composition formula expressed by MmAaDdOoNn:Z, (wherein element M is at least one kind of element having bivalent valency, element A is at least one kind of element having tervalent valency selected from the group consisting of Al, Ga, In, Tl, Y, Sc, P, As, Sb, and Bi, element D is Si and/or Ge, O is oxygen, N is nitrogen, and element Z is at least one kind of element selected from rare earth elements or transitional metal elements, satisfying m>0, a>0, b>0 o?0, and n=2/3 m+a+4/3b?2/3o), where a content of the element Fe is smaller than 200 ppm.

Abstract: To provide a phosphor given by a general composition formula expressed by MmAaBbOoNn:Z, (wherein element M is one or more kinds of elements having bivalent valency, element A is one or more kinds of elements having tervalent valency, element B is one or more kinds of elements having tetravalent valency, O is oxygen, N is nitrogen, and element Z is one or more kind of activating agent, satisfying m>0, a>0, b>0, o?0, and n>0), with a change rate of a ratio of element B atoms to the total numbers of atoms being smaller by 10% or the change rate of oxygen atoms to the total numbers of atoms being smaller by 40% in a range from a particle surface up to depth 2000 nm, having a broad emission spectrum in a range of blue color, having a broad flat excitation band in a range of near ultraviolet/ultraviolet, and having excellent emission efficiency, emission intensity, and luminance.

Abstract: A complex fluoride A2MF6 wherein M is a tetravalent element Si, Ti, Zr, Hf, Ge or Sn, A is an alkali metal Li, Na, K, Rb or Cs is prepared by providing a first solution containing a fluoride of M, providing a second solution containing a compound of A and/or the compound of A in solid form, mixing the first solution with the second solution and/or the solid for reacting the fluoride of M with the compound of A, and recovering the resulting solid product via solid-liquid separation.

Abstract: To provide sialon phosphor particles or a powder exhibiting high emission intensity in the region from ultraviolet to blue and not requiring a strong pulverization operation for pulverizing a sintered body or a large aggregated lump, and a production method thereof. Sialon phosphor particles represented by the formula: MxLnySi12?(m+n)Al(m+n)OnN16?n (wherein M is at least one metal selected from the group consisting of Li, Ca, Mg and Y, Ln is a lanthanide metal containing at least Eu, and assuming that the valence of the metal M is a and the valence of the lanthanide metal Ln is b, ax+by=m, x is 0<x, y?2.0, 0.3?m<4.5 and 0.5?n<2.5), wherein in the surface analysis by X-ray photoelectron spectroscopy, the ratio between the peak area of 3d5/2 spectrum of europium and the peak area of 2p spectrum of Si is 0.5 or less.

Abstract: This invention relates to luminescent materials for ultraviolet light or visible light excitation comprising copper-alkaline-earth dominated inorganic mixed crystals activated by rare earth elements. The luminescent material is composed of one or more than one compounds of silicate type and/or germinate or germanate-silicate type. Accordingly, the present invention is a very good possibility to substitute earth alkaline ions by copper for a shifting of the emission bands to longer or shorter wavelength, respectively. Luminescent compounds containing Copper with improved luminescent properties and also with improved stability against water, humidity as well as other polar solvents are provided. The present invention is to provide copper containing luminescent compounds, which has high correlated color temperature range from about 2,000K to 8,000K or 10,000K and CRI up to over 90.

Abstract: Disclosed is a silicate phosphor represented by Formula: Lia-xAxSrb-y-z-lByEuzClSic-mDmOd-nEn where A includes at least one ion selected from the group consisting of Na, K, Rb, and Cs. B includes at least one ion selected from the group consisting of Mg, Ca, Ba and Zn. C includes at least one ion selected from the group consisting of Sc, Y, La, Gd, Ce, Pr, Nd, Sm, Tb, Dy, Ho, Er, Tm, Yb, Lu and Bi. D includes at least one ion selected from the group consisting of B, Al, Ga, In and Tl. E includes at least one ion selected from the group consisting of F, Cl, Br, and I. Further disclosed is a white light emitting device including the silicate phosphor.

Abstract: A method for producing a phosphor includes: providing a blend composed of: (i) a magnesium source; (ii) a silicon source; (iii) an aluminum source; (iv) an oxygen source; (v) a solid nitrogen source; (vi) an ammonium halide; and (vii) an activator ion source; coating the blend with an initiator to obtain a tablet; placing the tablet in a heat insulator; placing a ceramic powder between the tablet and the heat insulator; and heating the tablet to obtain a magnesium-alpha-SiAlON-hosted phosphor.

Abstract: Bismuth ion sensitized rare earth germanate luminescence materials and preparation methods are disclosed. The luminescence materials are the compounds of the following general formula (Y1-x-y-zAxBiyLnz)2GeO5. The preparation methods comprise: using oxides, carbonates, oxalates, acetates, nitrates or halides of Y, A, Bi, Ln and Ge as raw materials, wherein A is one of Gd, Lu, Sc and La, and Ln is at least one of Tm, Ho, Sm, Tb, Eu and Dy, homogeneously grinding the raw materials, sintering at 1300-1500° C. for 6-24 h, and then cooling them to room temperature to obtain the bismuth ion sensitized rare earth germanate luminescence materials.

Abstract: The present invention provides a phosphor having high luminance, a property of low luminance degradation during driving of a light-emitting device and manufacturing processes, and chromaticity y in PDP comparable to that of BAM:Eu. The present invention is the phosphor represented by the general formula xSrO.yEuO.MgO.zSiO2 where 2.970?x?3.500, 0.001 ?y?0.030, and 1.900?z?2.100 are satisfied, wherein a main peak is present in the range of diffraction angle 2?=16.1 to 16.5 degree in the X-ray diffraction pattern obtained by measurement on the blue phosphor using an X-ray with a wavelength of 0.774 ?, and at least one condition of the following conditions (A1) and (A2) is satisfied: (A1) at least two peaks whose tops are located in the range of diffraction angle 2?=15.3 to 16.1 degree are present; and (A2) at least two peaks whose tops are located in the range of diffraction angle 2?=22.2 to 23.3 degree are present.

Abstract: To provide a phosphor for an electron beam excitation with a small deterioration in an emission efficiency and capable of maintaining a high luminance, even when an excitation density of an electron beam for a phosphor excitation is increased. As raw materials, Ca3N2(2N), AlN(3N), Si3N4(3N), and Eu2O3(3N) are prepared, and the raw materials thus prepared are measured and mixed, so that a molar ratio of each element becomes (Ca+Eu):Al:Si=1:1:1. Then, the mixture thus obtained is maintained and fired for at 1500° C. for 3 hours, and thereafter crushed, to manufacture the phosphor having a composition formula Ca0.985SiAlN3:Eu0.015.