Gaseous Compositions Patents (Class 252/372)
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Publication number: 20100176331Abstract: Provided are azeotrope-like compositions comprising heptafluoropropane and trifluoroiodomethane and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agents, fire suppressant compositions, and aerosol propellants.Type: ApplicationFiled: January 13, 2009Publication date: July 15, 2010Applicant: HONEYWELL INTERNATIONAL INC.Inventors: Rajiv Ratna Singh, Hang T. Pham, Robert G. Richard
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Publication number: 20100176332Abstract: Provided are azeotrope-like compositions comprising heptafluoropropane and trifluoroiodomethane and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agents, fire suppressant compositions, and aerosol propellants.Type: ApplicationFiled: January 13, 2009Publication date: July 15, 2010Applicant: HONEYWELL INTERNATIONAL INC.Inventors: Rajiv Ratna Singh, Hang T. Pham, Robert G. Richard
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Publication number: 20100171079Abstract: A composition comprising: hydrogen; and an oxygenate odorant; wherein the oxygenate odorant has a vapor pressure of about 0.002 psi. or greater at 25° C. and having a smell detectable at less than 1 ppm by a human nose; wherein the oxygenate odorant includes one or more carbonyl groups; and wherein the oxygenate odorant consists only of carbon, hydrogen and oxygen. The oxygenate odorants may be cyclic or acyclic.Type: ApplicationFiled: May 21, 2009Publication date: July 8, 2010Applicant: ENERSOL, INC., N.A. L.P.Inventors: PATRICK J. FLYNN, Michael J. Sprague
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Publication number: 20100163801Abstract: The present invention concerns a nitrogen-free and sulfur-free odorant for hydrogen gas containing at least one acrylic acid CrC6-alkyl ester and methyl salicylate, its use for the odorisation of hydrogen gas, a process for the odorisation of hydrogen gas and hydrogen gas containing an odorant according to the invention.Type: ApplicationFiled: December 19, 2005Publication date: July 1, 2010Applicant: SYMRISE GMBH & CO. KGInventors: Norbert Braun, Jörg Eilers, Dirk Müller
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Publication number: 20100163802Abstract: A hydrogen supply device and a method of supplying hydrogen are provided in which a hydrogen gas odorized with the odor agent is supplied by applying heat to a granular mixture of hydrogen storage glass beads and odor agent encapsulating capsules using irradiation with infrared light emitted from a light source.Type: ApplicationFiled: June 8, 2007Publication date: July 1, 2010Inventor: Katsuhiko Oshikawa
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Publication number: 20100133472Abstract: Process for the co-production of methanol and ammonia from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units, water gas shift and carbon dioxide removal steps.Type: ApplicationFiled: November 25, 2009Publication date: June 3, 2010Inventor: PAT A. HAN
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Publication number: 20100123099Abstract: A method for producing hydrogen from a light hydrocarbon gas with the hydrocarbon gas being converted to particulate carbon and hydrogen and thereafter quenched with liquid sulfur with the purified hydrogen being recovered as a product.Type: ApplicationFiled: April 30, 2009Publication date: May 20, 2010Inventors: Peter D. Clark, Justin A. Lamar, David K. Stevens
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Patent number: 7708980Abstract: Propellants comprising a combination of: (a) a liquid component that is soluble in the organic chemical-based material; (b) a soluble gas component that has a solubility of at least about 3% by weight in the organic chemical-based material; and, (c) a substantially insoluble gas component that has a solubility of less than about 3% by weight of the organic chemical-based material are effective for a wide range of airless applications. Adjustment of the ratios of (a) to (b) to (c) can lead to propellants that provide excellent spray patterns for a wide range of organic chemical-based formulations.Type: GrantFiled: February 10, 2006Date of Patent: May 4, 2010Assignee: Illinois Tool Works Inc.Inventors: Michael Atwater, Donald R. Williams, Frederick P. Walnut, Keith D. Begin
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Publication number: 20100096594Abstract: Disclosed herein is an apparatus and methods for decontaminating syngas generated in a fluidized-bed gasifier wherein metal contaminants, inter alia, alkali metals, halogens, particulates, and transition metals and sulfur containing contaminants are removed prior to the catalytic thermal cracking of tar and ammonia. Further disclosed is an apparatus and methods for removing ammonia from syngas.Type: ApplicationFiled: October 22, 2009Publication date: April 22, 2010Inventors: Robert S. Dahlin, Thomas K. Gale
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Publication number: 20100087615Abstract: A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source with a catalyst comprising synthetic cryptomelane or octahedral molecular sieve. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.Type: ApplicationFiled: September 17, 2009Publication date: April 8, 2010Inventors: Scott Han, Daniel J. Martenak, Lei Jin, Steven Lawrence Suib
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Publication number: 20100051872Abstract: A process for the removal of heavy metals from flue gas deriving from combustion processes comprising the following steps: a) optional removal by filtration of solid particles or of particulate of heavy metals or their compounds, having an average diameter higher than 10 micron; b) flue gas washing performed with an aqueous phase and transfer of the heavy metals or their compounds to the aqueous phase; c) flue gas cooling and partial condensation of the steam contained in the flue gas and separation of a condensed phase; d) discharge of the flue gases substantially free from heavy metals or their compounds into the environment; f) discharge of the aqueous phase substantially free from heavy metals or their compounds into the environment.Type: ApplicationFiled: December 19, 2007Publication date: March 4, 2010Applicant: ITEA S.p.A.Inventors: Massimo Malavasi, Grazia Di Salvia, Edoardo Rossetti
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Publication number: 20100025634Abstract: A process for the treatment of a high-pressure hydrocarbon gas stream to make a carbon dioxide-rich product stream and a treated hydrocarbon gas product stream by contacting within a contactor the high-pressure hydrocarbon gas stream with a solvent containing aqueous ammonia and, optionally, a reaction product of a liquid ammonia-carbon dioxide-water system. A fat solvent containing precipitated solids is withdrawn from the contactor and is regenerated whereby carbon dioxide is released and the fat solvent and a lean solvent is provided for reuse as the solvent.Type: ApplicationFiled: July 9, 2009Publication date: February 4, 2010Inventors: Jose Luis BRAVO, Ashok Kumar Rupkrishen DEWAN, Raymond Nicholas FRENCH, Amrit Lal KALRA, Pervaiz NASIR, Jiri Peter Thomas VAN STRAELEN
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Publication number: 20100012900Abstract: The present disclosure relates to non-ignitable gaseous compositions comprising difluoromethane and tetrafluoroethylene. When the pressure is at least 150 psig, the molar percentage of tetrafluoroethylene in the non-ignitable gaseous composition is no more than 111.6?0.124X. When the pressure is less than 150 psig, the molar percentage of tetrafluoroethylene in the non-ignitable gaseous composition is no more than 102?0.06X. X is the pressure in the unit of psig. The present disclosure also provides processes for making such non-ignitable gaseous compositions. Also disclosed are azeotropic compositions of TFE and HFC-32.Type: ApplicationFiled: September 4, 2007Publication date: January 21, 2010Applicant: E.I. DU PONT DE NEMOURS AND COMPANYInventor: Barry Asher Mahler
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Publication number: 20100006803Abstract: A method of treating a high-pressure hydrocarbon stream, such as natural or synthetic gas, contaminated with a high concentration of carbon dioxide, by contacting the contaminated high-pressure hydrocarbon stream with a chilled aqueous ammonia solution in an absorber at high pressure to produce a treated gas stream having a substantially reduced carbon dioxide content and a carbon dioxide-rich ammonia solution. The carbon dioxide-rich ammonia solution is regenerated by stripping, thus producing a concentrated carbon dioxide stream at high pressure suitable for sequestration or other uses.Type: ApplicationFiled: July 9, 2009Publication date: January 14, 2010Inventors: Jose Luis Bravo, Ashok Kumar Rupkrishen Dewan, Raymond Nicholas French, Amrit Lal Kalra, Pervaiz Nasir, Jiri Peter Thomas Van Straelen
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Publication number: 20100001236Abstract: A fluidized bed reactor (FBR) for producing tri-chlorosilane (TCS) from metallurgical silicon (MGSI) and method of producing TCS stably with the FBR is disclosed.Type: ApplicationFiled: June 25, 2009Publication date: January 7, 2010Inventors: YongChae Chee, Tetsunori Kunimune
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Publication number: 20090320771Abstract: Ionic fluid mixtures are described that include an ionic liquid and a solid-phase material. The ionic liquid and the solid-phase material are selected to convert the solid-phase material into a gas phase material at a temperature that is lower than a conversion of the ionic liquid into a gas phase ionic material. In addition, methods of supplying a gaseous precursor to an application are described. These methods include providing a mixture of an ionic liquid and a solid-phase starting material, heating the mixture to a temperature that vaporizes at least a portion of the solid-phase starting material into the gaseous precursor, and transporting the gaseous precursor from the mixture to the application that utilizes the gaseous precursor.Type: ApplicationFiled: June 9, 2009Publication date: December 31, 2009Applicant: Matheson Tri-GasInventors: Robert Torres, JR., Dane C. Scott
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Publication number: 20090297272Abstract: The present invention provides a method and a gaseous composition for bioremediation of soil and groundwater contaminated with organic compounds, including halogenated organic compounds and explosives. The gaseous composition contains (a) at least one gaseous microbial metabolic inducer and (b) a carrier gas. The gaseous composition may also optionally include one or more of a gas phase nutrient, a gaseous carbon source, a gas phase reductant, and a moisture source.Type: ApplicationFiled: August 5, 2009Publication date: December 3, 2009Inventors: Lamar E. Priester, III, Brian Harmison, John Huff
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Publication number: 20090286898Abstract: A composition which comprises 1,1,1,3,3-pentafluorobutane (HFC-365mfc) and 1,1,1,3,3-pentafluoropropane (HFC-245fa) in a weight ratio HFC-365mfc/HFC-245fa of from 60:40 to 75:25.Type: ApplicationFiled: March 9, 2009Publication date: November 19, 2009Applicant: SOLVAY S.A.Inventors: Lothar Zipfel, Werner Kruecke, Karsten Boerner, Pierre Dournel, Dierk-Ingolf Recke
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Publication number: 20090269239Abstract: To provide a method for producing an aluminum ingot whose oxides is reduced by preventing the surface of molten aluminum from being oxidized. The method according to the present invention includes a melting step (melting furnace 1) of melting an aluminum base metal into a molten aluminum or molten aluminum alloy; a holding step (holding furnace 2) of holding the resulting molten aluminum or molten aluminum alloy; a dehydrogenation step (dehydrogenation unit 3) of removing hydrogen gas from the molten aluminum or molten aluminum alloy; a filtration step (filter 4) of removing inclusions from the molten aluminum or molten aluminum alloy; and a casting step (casting device 5) of solidifying the molten aluminum or molten aluminum alloy into a predetermined shape, wherein at least one of the above steps is conducted in the atmosphere of a protective gas containing fluorinating gas, carbon dioxide gas, and nitrogen and/or argon gas.Type: ApplicationFiled: December 19, 2006Publication date: October 29, 2009Applicant: Taiyo Nippon Sanso CorporationInventors: Yutaka Nagakura, Kenji Tokuda, Makoto Morishita, Hiroshi Sanui, Yuji Nomura
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Publication number: 20090242840Abstract: Gas mixtures which comprise acids like HF, HCl and/or HBr and other constituents, especially gas mixtures which comprise or consist of carboxylic acid fluorides, C(O)F2 or phosphorous pentafluoride and HCl and optionally HF, can be separated by ionic liquids. The process is performed reversibly. Ionic liquids are applied, the anion of which corresponds to a stronger acid than the acid to be removed. Highly purified products, for example, highly purified carbonyl fluoride can be obtained.Type: ApplicationFiled: April 25, 2007Publication date: October 1, 2009Applicant: SOLVAY FLUOR GMBHInventors: Jens Olschimke, Carsten Brosch, Andreas Grossmann
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Publication number: 20090224206Abstract: The present invention concerns a nitrogen-free and sulfur-free odorant for hydrogen gas containing at least one acrylic acid C1-C6-alkyl ester and acetophenone, its use for the odorisation of hydrogen gas, a process for the odorisation of hydrogen gas and hydrogen gas containing an odorant according to the invention.Type: ApplicationFiled: December 19, 2005Publication date: September 10, 2009Applicant: SYMRISE GMBH & CO. KGInventors: Norbert Braun, Jörg Eilers, Dirk Müller
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Publication number: 20090224207Abstract: Provided are azeotropic and azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) and hydrogen fluoride (HF). Such azeotropic and azeotrope-like compositions are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).Type: ApplicationFiled: March 3, 2009Publication date: September 10, 2009Inventors: Hang T. Pham, Daniel C. Merkel, Konstantin A. Pokrovski, HsuehSung Tung, Rajiv R. Singh
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Publication number: 20090224205Abstract: The present invention concerns a nitrogen-free and sulfur-free odorant for hydrogen gas containing at least one acrylic acid C1-C6-alkyl ester and at least one acetic acid C5-alkyl ester, its use for the odorisation of hydrogen gas, a process for the odorisation of hydrogen gas and hydrogen gas containing an odorant according to the invention.Type: ApplicationFiled: December 19, 2005Publication date: September 10, 2009Applicant: SYMRISE GMBH & CO. KGInventors: Norbert Braun, Jörg Eilers, Dirk Müller
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Publication number: 20090194741Abstract: A catalytic filter system is disclosed. The catalytic filter system contains a catalyst including a ternary nitride and at least one of gold, osmium, iridium, palladium, rhodium, rhenium, ruthenium, or cesium. The catalytic filter system may further include an energy source situated to impart energy to the catalyst.Type: ApplicationFiled: January 31, 2008Publication date: August 6, 2009Inventors: Herbert Florey Martins DaCosta, Thomas Edward Paulson, Svetlana Mikhailovna Zemskova, James Joshua Driscoll
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Publication number: 20090179177Abstract: The present invention provides a method for evaluating the properties of hydrogen to improve the safety of hydrogen fuel, and provides a method for selecting proper odorants for hydrogen. Odorized hydrogen containing suitable odorants in appropriate concentrations with hydrogen are also provided.Type: ApplicationFiled: March 20, 2009Publication date: July 16, 2009Applicant: Enersol, Inc. N.A., L.P.Inventors: Patrick J. FLYNN, Michael SPRAGUE
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Publication number: 20090127511Abstract: A device and method for providing a gaseous substance mixture which includes at least one reducing agent and/or at least one reducing agent precursor, includes a reservoir for an aqueous solution which includes at least one reducing agent precursor that can be flow connected to an evaporator chamber, and a device for dosing the aqueous solution in the evaporator chamber. A device can heat the evaporator chamber to a temperature higher than or equal to a critical temperature, in which the aqueous solution is at least partially evaporated. The device and method enable reducing agent to be provided for selective catalytic reduction of nitrogen oxides in the exhaust of an internal combustion engine. Preferably, an evaporator unit is configured as the evaporator chamber and a hydrolysis catalytic converter is disposed outside the exhaust system. As a result, the size of the hydrolysis catalytic converter is reduced, allowing compact construction.Type: ApplicationFiled: November 17, 2008Publication date: May 21, 2009Applicant: EMITEC GESELLSCHAFT FUR EMISSIONSTECHNOLOGIE MBHInventors: Rolf Bruck, Marc Brugger, Thomas Harig, Peter Hirth, Ulf Klein
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Publication number: 20090108237Abstract: A novel molecular alloy of O2 and H2 and a method of producing such a molecular alloy are provided. When subjected to high pressure and extensive x-radiation, H2O molecules cleaved, forming O—O and H—H bonds. In the method of the present invention, the O and H framework in ice VII was converted into a molecular alloy of O2 and H2. X-ray diffraction, x-ray Raman scattering, and optical Raman spectroscopy demonstrate that this crystalline solid differs from previously known phases.Type: ApplicationFiled: October 24, 2008Publication date: April 30, 2009Inventors: Ho-kwang Mao, Wendy L. Mao
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Publication number: 20090078912Abstract: A method for determining a carbon content value of a hydrocarbon-containing mixture. At least one composition-dependent bulk property of the hydrocarbon-containing mixture is measured and optionally at least one non-hydrocarbon component concentration is measured with the resulting measurements used in a carbon content correlation for calculating the carbon content of the hydrocarbon-containing mixture. The carbon content may be used in a hydrogen and/or synthesis gas production process for calculating a target flow rate of steam to be combined with the hydrocarbon-containing mixture to form a mixed feed having a target steam-to-carbon ratio.Type: ApplicationFiled: September 26, 2007Publication date: March 26, 2009Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Xiang-Dong Peng, Blaine Edward Herb, Matthew H. MacConnell, Winfried Stephen Hoglen
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Patent number: 7501103Abstract: Tropospheric volume elements enriched with vital elements and/or protective substances as well as procedures for their production and application. The term “vital elements” applies to all matter supporting the development of life within the earth's biosphere and the term “protective substances” means all those substances which contribute directly or indirectly to the prevention of harmful effects on the earth's biosphere and in particular on man. Tropospheric volume elements in the form of clouds which contain contaminants and which can escape from industrial facilities due to damage or malfunction are enriched with protective substances which prevent the organism from taking in radioactive elements and minimize the extent of the area affected by the clouds and possess additional warning and identification properties.Type: GrantFiled: July 29, 2002Date of Patent: March 10, 2009Inventor: Franz-Dietrich Oeste
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Publication number: 20090047447Abstract: The present invention relates to plasma cleaning methods for removing surface deposits from a surface, such as the interior of a depositions chamber that is used in fabricating electronic devices. The present invention also provides gas mixtures and activated gas mixtures which provide superior performance in removing deposits from a surface. The methods involve activating a gas mixture comprising a carbon or sulfur source, NF3, and optionally, an oxygen source to form an activated gas, and contacting the activated gas mixture with surface deposits to remove the surface deposits wherein the activated gas mixture acts to passivate the interior surfaces of the apparatus to reduce the rate of surface recombination of gas phase species.Type: ApplicationFiled: August 2, 2006Publication date: February 19, 2009Inventors: Herbert H. Sawin, Bo Bai, Ju Jin An
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Publication number: 20090001320Abstract: A method for removing hydrogen sulfide from a sour gas stream comprising hydrogen sulfide by oxidizing hydrogen sulfide in a converter by contacting the sour gas stream with an aqueous catalytic solution, thereby producing a desulfurized gas stream and a liquid stream comprising reduced catalyst and elemental sulfur, introducing an oxidant and the liquid stream comprising reduced catalyst and elemental sulfur into a high shear device and producing a dispersion wherein the mean bubble diameter of the oxidant gas in the dispersion is less than about 5 ?m, introducing the dispersion into a vessel from which a sulfur-containing slurry is removed and a regenerated catalyst stream is removed, wherein the sulfur slurry comprises elemental sulfur and aqueous liquid, and recycling at least a portion of the regenerated catalyst stream to the converter. A system of apparatus for carrying out the method is also provided.Type: ApplicationFiled: June 12, 2008Publication date: January 1, 2009Applicant: H R D CORPORATIONInventors: Abbas Hassan, Ebrahim Bagherzadeh, Rayford G. Anthony, Gregory Borsinger, Aziz Hassan
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Publication number: 20080210908Abstract: A method for producing a hydrogen enriched fuel and carbon nanotubes includes the steps of providing a flow of methane gas, and providing a catalyst mixture comprising a Fe based catalyst and carbon. The method also includes the steps of pretreating the catalyst mixture using microwave irradiation and exposure to CH4, heating the catalyst mixture and the methane gas using microwave irradiation at a selected microwave power, directing the flow of methane gas over the catalyst mixture, and controlling the microwave power to produce a product gas having a selected composition and the carbon nanotubes. For producing multi walled carbon nanotubes (MWNTs) only a flow of methane gas into the reactor is required. For producing single walled carbon nanotubes (SWNTs), a combination of hydrogen gas and methane gas into the reactor is required.Type: ApplicationFiled: March 1, 2008Publication date: September 4, 2008Inventors: Zhonghua John Zhu, Jiuling Chen, Gaoqing Max Lu, Gregory Solomon
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Publication number: 20080199408Abstract: Azeotropic and azeotrope-like compositions of methyl iodide and at least one fluorocarbon or hydrofluorocarbon such as 1,1,1,3,3-pentafluoropropane (HFC-245fa). The compositions are present as a gas, at temperatures of about 30° C. or below. The inventive compositions serve as a non-ozone-depleting gaseous fumigant which is useful in a variety of applications, in place of methyl bromide. These compositions serve as a drop-in replacement for gaseous methyl bromide, providing the benefits of a methyl iodide fumigant while also utilizing existing methyl bromide equipment.Type: ApplicationFiled: February 16, 2007Publication date: August 21, 2008Inventors: Andrew J. Poss, Rajiv R. Singh, Hang T. Pham
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Publication number: 20080163956Abstract: There is provided a protective gas composition for preventing a rapid oxidation or combustion of a molten magnesium/magnesium alloy, comprising a fluorine-containing organic compound and a carrier gas. Furthermore, there is provided a method for preventing a rapid oxidation or combustion of a molten magnesium or magnesium alloy, which is characterized in that the above gas composition is used as a protective gas for preventing an oxidation or combustion of a molten magnesium or magnesium alloy in a magnesium or magnesium alloy production.Type: ApplicationFiled: April 26, 2006Publication date: July 10, 2008Applicant: CENTRAL GLASS COMPANY, LIMITEDInventors: Yasuo Hibino, Ryoichi Tamai, Satoru Okamoto, Fuyuhiko Sakyu
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Patent number: 7388170Abstract: This invention provides a method for on-site production of a protective gas mixture for arc joining, in particular for arc welding. Gaseous argon is removed from a liquid argon supply and helium is added to the argon, and a doping gas premix which is prepared separately on-site is added. Various combinations of argon, helium and the doping gas premix are supplied via a protective gas supply device which supplies multiple workplaces with different gas mixtures without the need for specialty gas mixing equipment.Type: GrantFiled: April 28, 2005Date of Patent: June 17, 2008Assignee: Linde AktiengesellschaftInventor: Thomas Ammann
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Publication number: 20080132723Abstract: The present invention provides an integrated, optimized process for the production of ethylene, carbon monoxide and acetic acid from an ethane feed, including reacting ethane with oxygen in the presence of a catalyst to produce ethylene, carbon monoxide and acetic acid in a reactor, wherein the catalyst comprises the elements Mo, Pd, X, and Y in the gram-atomic ratios MOa Pdb Xc Yd, and the oxygen partial pressure in the reactor is about 15 psia to about 50 psia. The partial pressure of ethane in the reactor is about 50 psia to about 150 psia.Type: ApplicationFiled: December 4, 2006Publication date: June 5, 2008Inventors: Victor J. Johnston, Joseph G. Duff, Debra Ann Ryan, Deborah R. Repman, Melchior A. Meilchen, David W. Townsend, Cathy L. Tway
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Publication number: 20080128656Abstract: Process of depositing nanoparticles of a metal or of an alloy of said metal, said metal being chosen from the metals from columns VIIIB and IB of the Periodic Table, dispersed on a substrate by chemical vapour deposition (CVD), from one or more precursors, in which the deposition is carried out in the presence of a gas comprising more than 50 vol % of a reactive oxidizing gas. Substrate comprising at least one surface, dispersed on which are nanoparticles made of a metal or of an alloy of metals, for example made of silver or a silver alloy. Use of the substrate to catalyse a chemical reaction, for example an NOx elimination reaction.Type: ApplicationFiled: December 23, 2005Publication date: June 5, 2008Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE DE POITIERSInventors: Stéphanie Thollon, Fabien Luc, Joel Barrault, Sabine Valange, Erwan Guelou, Marco Daturi, Fabien Can
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Patent number: 7338670Abstract: The presently disclosed subject matter provides methods for increasing perfusion in hypoxic regions of tissues in subjects. Also provided are methods for treating diseases and/or disorders associated with hypoxia in subjects, methods for increasing sensitivity of tumors to radiation and/or chemotherapy treatments, methods for delaying tumor growth in subjects, and methods for inhibiting tumor blood vessel growth in subjects. In some embodiments, the presently disclosed methods involve administering to subjects in need thereof a first composition selected from the group consisting of a nitrosylated hemoglobin and an agent that induces nitrosylation of endogenous hemoglobin in the subject and a second composition comprising a hyperoxic gas. In some embodiments, the presently disclosed methods also include treating a tumor with radiation therapy, chemotherapy, photodynamic therapy, immunotherapy, or combinations thereof. Also provided are inhalable gases that can be employed in the presently disclosed methods.Type: GrantFiled: April 13, 2006Date of Patent: March 4, 2008Assignee: Duke UniversityInventors: Mark W. Dewhirst, Jonathan S. Stamler, Timothy J. McMahon, Pierre Sonveaux
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Publication number: 20080042104Abstract: A layered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. In one or more embodiments, the catalyst comprises three layers in conjunction with a carrier: a first layer deposited on the carrier and comprising palladium deposited on a refractory metal oxide and an oxygen storage component; a second layer deposited on the first layer and comprising rhodium deposited on a refractory metal oxide and an oxygen storage component; and a third layer deposited on the second layer and comprising palladium deposited on a refractory metal oxide.Type: ApplicationFiled: June 7, 2007Publication date: February 21, 2008Inventors: Shau-Lin F. Chen, Harold Rabinowitz, Jin Sakakibara, Tian Luo
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Patent number: 7307234Abstract: A protective gas supply device for on-site supply of workplaces is provided, in which a liquid argon reservoir, a liquid oxygen reservoir or a liquid carbon dioxide reservoir, and a helium supply are connected to first and second mixers supplying gas to site workplaces. The liquid argon reservoir and the liquid oxygen or carbon dioxide reservoir are connected to the feed side of the first mixer via lines, and the discharge side of the first mixer is connected to at least one workplace and to the feed side of a second mixer. The feed side of the second mixer also receives helium from the helium supply, and the discharge side of the second mixer is connected to at least one additional workplace. The invention permits economical mixing and supply of variable protective gas mixtures to work stations in an on-site environment.Type: GrantFiled: April 28, 2005Date of Patent: December 11, 2007Assignee: Linde AktiengesellschaftInventor: Thomas Ammann
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Patent number: 7247293Abstract: A process for the producton of pure syngas (hydrogen and carbon dioxide) by fast gasification of liquid, muddy, or solid raw materials, either produced for the purpose or from industrial processes in which they can not be recycled, or fuels from wastes or biomass, which process is carried out in a modular reactor including a raw materials feeding area, a gasification area, a discharging area of the residues in powdery or vitrified form. The obtained syngas is sent to a purification and compression step.Type: GrantFiled: December 18, 2001Date of Patent: July 24, 2007Assignee: Nesi Plant S.A.Inventor: Vincenzo Sorace
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Patent number: 7229667Abstract: Compositions comprising a reactive gas and a matrix gas are disclosed, as well as articles of manufacture and methods of making the articles. The methods of manufacturing preferably employ zeolites to remove moisture from the reactive gas and from the matrix gas, and then combine the moisture reduced gases either in a container, or prior to filling a container, which has been previously vacuum-baked and passivated. The invention produces stable standard gas compositions having improved shelf-life.Type: GrantFiled: February 22, 2005Date of Patent: June 12, 2007Assignee: American Air Liquide, Inc.Inventors: Tracey Jacksier, Robert Benesch, John Kuhn
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Patent number: 7211765Abstract: The invention relates to a shielding gas for use in the arc welding of metallic work pieces. The invention further relates to a process for the arc welding of metallic work pieces using consumable electrodes, whereby a shielding gas stream is supplied to the work piece adjacent to the electrode. According to the invention, for shielding gases recommended for use in the MSG welding, preferably the MAG welding, of rust-proof steels, especially nickel-based materials, specialty steels, or high-alloy steels, a) if the shielding gas contains no helium, it contains carbon dioxide in a proportion of between 0.001% by volume and 1.9% by volume and b) if the shielding gas does contain helium, it contains carbon dioxide in a proportion of between 0.001% by volume and 0.9% by volume, in addition to argon, nitrogen, and, if applicable, helium.Type: GrantFiled: June 17, 2005Date of Patent: May 1, 2007Assignee: Linde AktiengesellschaftInventors: Stefan Trube, Thomas Ammann
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Patent number: 7108803Abstract: A mixture of acrylic acid and nitrogen compounds is particularly adapted to achieve a sulfur-free odorization of a gas.Type: GrantFiled: August 4, 1999Date of Patent: September 19, 2006Assignee: Symrise GmbH & Co. KGInventors: Gerd Mansfeld, Ute Rohde, Fritz Henke, Heribert Kaesler
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Patent number: 6991748Abstract: In a process for the production of a shielding gas mixture argon is withdrawn from a liquid argon supply, vaporized and mixed with a gas premix. The gas premix contains helium and/or argon and a doping gas. A shielding gas mixture prepared this way is outstandingly suited, especially because of the helium content, for arc welding of aluminum and aluminum alloys.Type: GrantFiled: December 20, 2002Date of Patent: January 31, 2006Assignee: Linde AktiengesellschaftInventors: Ernst Miklos, Burkhard Haas
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Patent number: 6963046Abstract: A process gas for use in laser welding with a laser beam focused onto the work piece to be welded. The inventive process gas comprises helium, nitrogen, and at least one of carbon dioxide in an amount of up to 40% by volume, and oxygen in an amount of up to 30% by volume. The gas may comprise not more than 85% by volume of helium. Also disclosed are methods of laser welding using the inventive process gas. The invention is suitable for laser welding of low-alloy steels and coated, especially zinc-coated steels.Type: GrantFiled: November 30, 2001Date of Patent: November 8, 2005Assignee: Linde AktiengesellschaftInventor: Johann Herrmann
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Patent number: 6847007Abstract: A process gas and a process of laser machining, such as laser beam fusion cutting or laser beam welding is provided. A gas mixture that contains at least oxygen and hydrogen, in addition to an inert has, is used as the process gas. The ratio of oxygen to hydrogen in the process gas is hypostoichiometric with respect to the reaction 2 H2+O2+?2 H2O, which causes the process gas to exhibit a reductive effect.Type: GrantFiled: June 23, 2003Date of Patent: January 25, 2005Assignee: Linde AktiengsellschaftInventor: Wolfgang Danzer
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Publication number: 20040245505Abstract: A process for the production of a fluorinated organic compound, characterized by fluorinating an organic compound having a hydrogen atoms using IF5; and a novel fluorination process for fluorinating an organic compound having a hydrogen atoms by using a fluorinating agent containing IF5 and at least one member selected from the group consisting of acids, bases, salts and additives.Type: ApplicationFiled: July 7, 2004Publication date: December 9, 2004Applicant: Daikin Industries, Ltd.Inventors: Norihiko Yoneda, Tsuyoshi Fukuhara, Kazuhiro Shimokawa, Kenji Adachi, Satoshi Oishi
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Publication number: 20040225275Abstract: The occurrence of hypercapneic acidosis in a fetus during a laparoscopic procedure carried out on a pregnant female, is prevented or ameliorated by inclusion in or addition to the carbon dioxide insufflation gas, of a nitric oxide donor, e.g., ethyl nitrite. Administration of nitric oxide donor in insufflation gas causes increase in fetal cerebral oxygenation.Type: ApplicationFiled: February 3, 2004Publication date: November 11, 2004Inventors: James Dixon Reynolds, Jonathan S. Stamler
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Patent number: 6796369Abstract: An apparatus and a method for inhibiting metal dusting corrosion of a tubesheet inside a shell-and-tube heat exchanger having at least one exit nozzle for transmitting at least one process fluid from the shell-and-tube heat exchanger include and use: an isolation baffle disposed inside the shell-and-tube heat exchanger at a location between a first exit nozzle and the tubesheet, whereby an isolated space exists between the tubesheet and the isolation baffle; and a means for purging the isolated space with a purging fluid.Type: GrantFiled: April 4, 2003Date of Patent: September 28, 2004Assignee: Air Products and Chemicals, Inc.Inventor: Stephen Paul DiMartino, Sr.