Oxygen Organic Compound Containing Patents (Class 252/396)
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Patent number: 7297191Abstract: A corrosion inhibitor composition includes between about 95 and about 99 percent by weight ammonium benzoate, and between 1 and about 5 percent by weight of silica. The composition may be water soluble for use in solution-based applications.Type: GrantFiled: October 6, 2006Date of Patent: November 20, 2007Assignee: Cortec CorporationInventors: Boris A. Miksic, Margarita Karshan, Ashish Gandhi
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Patent number: 7141102Abstract: An object of the present invention is to provide an antifreeze solution which is used by adding it to a heating medium of a heat exchanger or a radiator coolant for an internal combustion car engine, which can be used to prevent the icing of road surfaces, which is easy to use and environmentally friendly, and which does not contain environmentally harmful substances such as ethylene glycol so that it can be easily treated for disposal after use. Another object of the present invention is to provide an antifreeze solution which contains water as a main component and glycerin. The undiluted antifreeze solution does not freeze even at ?20° C. or less at normal pressures and is composed of components at a certain ratio.Type: GrantFiled: January 29, 2004Date of Patent: November 28, 2006Assignee: Kikuko FukutaniInventors: Yasuo Fukutani, Etsushi Tanaka, Yukio Wada
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Patent number: 7118615Abstract: A corrosion inhibitor composition includes between about 90 and about 99 percent by weight ammonium benzoate, and one or more additive components in an amount of between 1 and about 10 percent by weight of the composition. The one or more additive components are selected from the group consisting of silica, triazoles, and wetting agents.Type: GrantFiled: September 12, 2003Date of Patent: October 10, 2006Assignee: Cortec CorporationInventors: Boris A. Miksic, Margarita Karshan, Ashish Gandhi
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Patent number: 7081143Abstract: The present invention relates to emulsion compositions for starting a reformer of a fuel cell system. In particular, the invention includes emulsion compositions comprising hydrocarbon fuel, water and alkoxylated triazine surfactants for starting a reformer of a fuel cell system.Type: GrantFiled: December 20, 2002Date of Patent: July 25, 2006Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramesh Varadaraj, Paul Joseph Berlowitz
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Patent number: 6982062Abstract: This invention relates to a corrosion inhibiting composition comprising (a) an aliphatic amine, (b) an azole selected from the group consisting of (1) tolyltriazole, (2) benzotriazole, and (3) mixtures thereof, and (c) a benzoate. The compositions are particularly useful in inhibiting the corrosion of metal equipment, particularly equipment made from cast iron and aluminum, and more particularly, engine blocks that have been subjected to water flushing. The invention also relates to a process for inhibiting corrosion, particularly the vapor phase corrosion of metal equipment.Type: GrantFiled: July 22, 2003Date of Patent: January 3, 2006Assignee: Ashland Inc.Inventors: Frank L. M. DeCordt, Niklas Dahlberg, Joseph Mihelic, Michelle Blackowski
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Patent number: 6964746Abstract: The invention relates to mixtures of phosphonite (component A) and/or an ester and/or salt of a long-chain fatty acid (component B), and/or a carboxylic ester, and/or carboxylic amide (component C), and also to their use in polyamides or in polyesters.Type: GrantFiled: June 12, 2003Date of Patent: November 15, 2005Assignee: Clariant GmbHInventors: Elke Schlosser, Wolfgang Wanzke, Christian Lechner
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Patent number: 6858097Abstract: A chromium- and nitrogen-free brightening and passivating treatment for metal surfaces, particularly iron and steel, comprises: at least one acid; at least one substance containing a peroxy moiety; and at least one organic substance selected from the group consisting of; molecules that contain both at least one ether moiety and at least one hydroxyl moiety; molecules that contain at least two ether moieties; and molecules that contain in each molecule both at least one ether moiety and one nitrogen atom that is covalently bonded to at least three carbon atoms. Preferably part of the acid contains phosphorus, which has been found to act synergistically with the organic substance to stabilize peroxy compounds against decomposition, particularly in the presence of metal ions.Type: GrantFiled: December 21, 2000Date of Patent: February 22, 2005Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGAA)Inventors: Paolo B. Giordani, Valentino Gasparetto, Dario Negri
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Patent number: 6833087Abstract: Compositions and methods are disclosed for preventing the oxidative corrosion of metal surfaces by exposing a metal surface to an anti-corrosion agent characterized as 2,4-trans, trans-hexadienoic acid (2,4-HDA), its alkali salt identified as potassium sorbate (KHDA), or other derivatives that conserve or embody the 2,4-trans, trans-hexadiene-type moiety present in their molecular structures as an active anti-corrosion agent (ACA), in combination with a material capable of forming a moisture retentive barrier over the metal surface. The compositions and methods of the invention provide a practical, non-toxic way of ensuring anti-corrosion protection for metals, or devices containing exposed metals, stored or operated in water or in the presence of water vapor.Type: GrantFiled: October 25, 2001Date of Patent: December 21, 2004Assignees: Wonders of Water, LLC, Intellectual Concepts, LLCInventors: Robert A. Beck, Paul D. Manos
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Patent number: 6802988Abstract: Antifreeze concentrates are based on a mixture of at least two different C3- to C16-dicarboxylic acids, molybdate and a mixture of at least two different triazoles or thiazoles.Type: GrantFiled: April 17, 2002Date of Patent: October 12, 2004Assignee: BASF AktiengesellschaftInventors: Bernd Wenderoth, Ralf Strauss, Jacques Lonchampt
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Patent number: 6780824Abstract: Emulsifier system containing a) ethoxylates/propoxylates of fatty alcohols with 8 to 18 C atoms in the alcohol with 2 to 6 ethylene oxide units and 4 to 8 propylene oxide units, b) fatty alcohols and/or fatty alcohol propoxylates with 12 to 24 C atoms in the alcohol and 0 to 3 propylene oxide units and/or distillation residue of these fatty alcohols and c) phosphates, selected from: c1) mono- and/or diesters of phosphoric acid with alkanols with 10-20 C atoms, c2) mono- and/or diesters of phosphoric acid with ethoxylated and/or propoxylated alkanols with 10-20 C atoms and/or c3) phosphates of polyethylene glycol ethers and/or polypropylene glycol ethers, and the water-soluble salts of each of these, in a weight ratio a:b:c=1:0.3:0.1 to 1:4:1; anti-corrosive and emulsifier system with these components, emulsion concentrate with these components, oil-in-water emulsion obtainable therefrom and use thereof as a cleaning, anti-corrosive and low-temperature lubricant emulsion.Type: GrantFiled: October 31, 2002Date of Patent: August 24, 2004Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)Inventors: Hans-Peter Oelscher, Juergen Geke
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Patent number: 6767413Abstract: The present invention provides a non-chromium metal surface treating agent which has excellent adhesion with a coating and corrosion resistance, and also has excellent workability and stability. A metal surface treating agent comprising a water-soluble zirconium compound, a water-soluble or water-dispersant acrylic resin and a water-soluble or water-dispersant thermosetting crosslinking agent, wherein said water-soluble zirconium compound has a zirconium content of 500 to 15000 ppm on a mass basis, said acrylic resin has an acid value of solid matter of 150 to 740 mgKOH/g, a hydroxyl value of solid matter of 24 to 240 mgKOH/g, and a solid matter content of 500 to 30000 ppm on a mass basis, and said thermosetting crosslinking agent has a solid matter content of 125 to 7500 ppm on a mass basis.Type: GrantFiled: March 14, 2002Date of Patent: July 27, 2004Assignee: Nippon Paint Co., Ltd.Inventor: Satoshi Nishimura
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Patent number: 6645400Abstract: The present invention describes an innovative means of inhibiting corrosion of metals which experience active-passive transition in contact with an electrolyte. This invention incorporates hydrogen peroxide and/or peroxycarboxylic acids or their constituents to inhibit corrosion by inducing passivation of the metal. Application of this technology reduces the potential for fouling, scaling and deposition as well as outperforming existing methods of corrosion control in these applications.Type: GrantFiled: December 10, 2001Date of Patent: November 11, 2003Assignee: United States Filter CorporationInventor: Roy Martin
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Patent number: 6585933Abstract: A method and composition for controlling corrosion of metals, particularly ferrous-based metals in contact with aqueous systems is disclosed, which includes treating industrial waters with a combination of a tetrazolium salt of the general formula: where R1, R2 and R3 may be various organic or inorganic substitutents, where n may be 1 or 2, and at least one other aqueous system treatment material.Type: GrantFiled: May 3, 1999Date of Patent: July 1, 2003Assignee: BetzDearborn, Inc.Inventors: William C. Ehrhardt, Longchun Cheng, Dawn Stasney, Kim A. Whitaker
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Publication number: 20030103865Abstract: This invention relates to a corrosion inhibiting composition for use in commercial, institutional, and industrial water systems. The compositions comprise a mixture of (1) a fatty acid ester, and (2) a polyethylene glycol ester. These compositions are useful in inhibiting the corrosion of metals such as steel, copper, and brass, which are exposed to water.Type: ApplicationFiled: October 29, 2001Publication date: June 5, 2003Inventors: Bruce L. Libutti, Joseph Mihelic
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Patent number: 6569264Abstract: The present invention provides a corrosion inhibitor composition for magnesium or magnesium alloys which contains as an effective component, at least one compound selected from among aromatic carboxylic acids and salts thereof as an effective component. Further, the present invention provides a surface treating agent for magnesium and/or magnesium alloy components which contains a phosphate, at least one compound selected from among aromatic carboxylic acids and salts thereof, and further, as required, at least one compound selected from among pyrazole compounds and triazole compounds,and surface-treating method using the surface treating agent.Type: GrantFiled: July 3, 2001Date of Patent: May 27, 2003Assignee: Otsuka Kagaku Kabushiki KaishaInventors: Kazunori Fukumura, Takahiko Shiraishi
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Patent number: 6559104Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of an additive aromatic compound tri-substituted with acidic functionalities selected from 5-hydroxyisophthalic acid and 1,3,5-benzenetricarboxylic acid, typically up to 1000 wppm, to the metal surface.Type: GrantFiled: July 13, 2001Date of Patent: May 6, 2003Assignee: ExxonMobil Research and Engineering Co.Inventors: Guido Sartori, David Craig Dalrymple, Saul Charles Blum, Liza Marie Monette, Mohsen S. Yeganeh, Andreas Vogel
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Patent number: 6555506Abstract: A method of preventing corrosion in pipelines comprising draining pipeline of all residual compounds, blowing through with nitrogen and rinsing with a corrosion inhibiting rinsing agent.Type: GrantFiled: November 29, 2001Date of Patent: April 29, 2003Assignee: Illinois Tool Works Inc.Inventors: William Hopkins, Christopher Nettleship
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Patent number: 6548459Abstract: A process for the preparation of CNSL phenoxy carboxylic acid derivatives for use as an additive in a lubricant composition so as to impart improved rust inhibiting properties, including the steps of (a) partially hydrogenating distilled technical cashew nut shell liquid with palladium or nickel or platinum catalyst; to hydrogenate the olefinic chain; (b) reacting cashew nut shell liquid or partially hydrogenated technical cashew nut shell liquid with halogeno carboxylic acid derivatives to obtain unpolymerized cashew nut shell liquid phenoxy carboxylic acid derivatives, the reaction being carried out at a temperature ranging from 20 to 140° C. A lubricant containing a major proportion of a material selected from the group consisting of an oil of lubricating viscosity and a grease; and remainder an additive including CNSL phenoxy carboxylic acid derivative prepared by the foregoing process.Type: GrantFiled: April 2, 2002Date of Patent: April 15, 2003Assignee: Indian Oil Corporation LimitedInventors: Pankaj Kumar Mondal, Khem Chand Dohhen, Rakesh Sarin, Deepak Kumar Tuli, Niranjan Raghunath Raje, Akhilesh Kumar Bhatnagar
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Patent number: 6540934Abstract: The present provides novel deicing and anti-icing compositions which are especially adapted for and are highly useful as deicing and anti-corrosion products, especially on many surfaces which require protection against icing and corrosion, such as airport runways.Type: GrantFiled: July 13, 2001Date of Patent: April 1, 2003Assignee: Metss CorporationInventors: Richard Sapienza, William Ricks, Joseph Sanders
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Patent number: 6540844Abstract: A method for forming a sol-gel on a metal surface to provide an interface for promoting adhesion between the metal surface and an organic resin involves application of at least one metal alkoxide compound having at least one labile sulfur atom, and at least one metal alkoxide compound having at least one reactive moiety which is capable of bonding with an organic resin. The metal alkoxide compound having at least one labile sulfur atom is capable of bonding to various metal surfaces, including surfaces of noble metals, such as gold, by a sulfur-metal linkage with the metal surface. The metal alkoxide compound having at least one labile sulfur atom reacts with the metal alkoxide compound having at least one reactive moiety which is capable of bonding with the organic resin to form a sol-gel which bonds to the surface of the metal, and which includes reactive moieties which are capable of bonding with an organic resin.Type: GrantFiled: November 8, 2000Date of Patent: April 1, 2003Assignee: Corning IncorporatedInventor: Russell A. Crook
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Patent number: 6533962Abstract: The anticorrosive plastic packaging materials for protecting iron, aluminum and alloys of these metals against corrosion comprise synergistic mixture of contact-vapour phase corrosion inhibitors containing salt or salts selected from the salts of ammonium and alkali metals or alkaline-earth metals derived from benzoic acid and for nitrous acid and 1,3-benzodiazole and for its 1-methyl derivative and 1H-benzotriazole and/or its methyl derivative and amorphous silicium oxide. As the anticorrosive plastic packaging article are predominantly used films or packaging products made of film, containers, either of mono- or multi-layer construction, wherein in case of multilayer packaging articles the synergistic mixture of contact-vapour phase inhibitors is with advantage added to the layer or layers closer to the article to be protected.Type: GrantFiled: June 15, 2001Date of Patent: March 18, 2003Assignees: Vojensky Technicky Ustav Ochrany, Polymer Institute Brno, Spol.S. R.O.Inventors: Jaromír Tulka, Eva Jan{haeck over (c)}ová, Ji{haeck over (r)}í Sedlá{haeck over (r)}, Ji{haeck over (r)}í Pác
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Publication number: 20030050198Abstract: A process for the preparation of CNSL phenoxy carboxylic acid derivatives for use as an additive in a lubricant composition so as to impart improved rust inhibiting properties, including the steps of (a) partially hydrogenating distilled technical cashew nut shell liquid with palladium or nickel or platinum catalyst; to hydrogenate the olefinic chain; (b) reacting cashew nut shell liquid or partially hydrogenated technical cashew nut shell liquid with halogeno carboxylic acid derivatives to obtain unpolymerized cashew nut shell liquid phenoxy carboxylic acid derivatives, the reaction being carried out at a temperature ranging from 20 to 140° C. A lubricant containing a major proportion of a material selected from the group consisting of an oil of lubricating viscosity and a grease; and remainder an additive including CNSL phenoxy carboxylic acid derivative prepared by the foregoing process.Type: ApplicationFiled: April 2, 2002Publication date: March 13, 2003Applicant: Indian Oil Corporation LimitedInventors: Pankaj Kumar Mondal, Khem Chand Dohhen, Rakesh Sarin, Deepak Kumar Tuli, Niranjan Raghunath Raje, Akhilesh Kumar Bhatnagar
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Patent number: 6518374Abstract: Free radical polymerizations immediately terminated by a process comprising the addition of an inhibitor solution which contains phenothiazine and at least 50% (w/w) N-alkylpyrrolidone to a system undergoing free radical polymerization, wherein the inhibitor solution also contains p-methoxyphenol (MEHQ).Type: GrantFiled: October 29, 2001Date of Patent: February 11, 2003Assignee: BASF AktiengesellschaftInventors: Heinrich Aichinger, Gerhard Nestler, Jürgen Schröder
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Patent number: 6511613Abstract: The reaction of propargyl alcohol and iodine gives 2,3di-iodo-2-propen-1-ol, and it has been discovered that this compound is effective as an intermediate in a corrosion inhibitor for metals in acid media, particularly halogen acids. The compound provides iodine to the media in a stable form that does not appear to degrade over time.Type: GrantFiled: June 21, 2002Date of Patent: January 28, 2003Assignee: Baker Hughes IncorporatedInventors: Arthur Cizek, James A. Hackerott
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Publication number: 20030015685Abstract: The present provides novel deicing and anti-icing compositions which are especially adapted for and are highly useful as deicing and anti-corrosion products, especially on many surfaces which require protection against icing and corrosion, such as airport runways.Type: ApplicationFiled: July 13, 2001Publication date: January 23, 2003Inventors: Richard Sapienza, William Ricks, Joseph Sanders
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Patent number: 6464763Abstract: A composition for use in forming a dry film coating on metal surfaces to at least temporarily protect the surfaces from oxidation comprises at least 20% by weight of a combination of at least one saturated linear carboxylic monoacid with at least one unsaturated linear carboxylic monoacid. The monoacids are in the form of alkaline, alkaline-earth or amine salts. The carbon chain of each acid comprises an uneven number of carbon atoms varying from 5 to 21. At least 0.5% by weight of a triazole derivative can be added to enhance the anti-corrosion effect. The composition is water-soluble and the dry protective film can be formed by diluting the composition in water, applying the diluted composition to a metal surface and then air drying it.Type: GrantFiled: May 22, 2001Date of Patent: October 15, 2002Assignee: Elf Antar FranceInventors: Pierre Steinmetz, Jacques Cotteret, Corinne Chauvineau
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Patent number: 6432355Abstract: Described herein is a process of corrosion inhibition of a steel pipeline during transport of water and gas, or water and an oil, or mixtures thereof, therethrough, including introducing a copolymer of vinyl caprolactam and vinylpyridine into said pipeline.Type: GrantFiled: October 12, 1999Date of Patent: August 13, 2002Assignee: ISP Investments Inc.Inventors: Kirill N. Bakeev, Jui-Chang Chuang, Thomas Winkler, Michael A. Drzewinski, David E. Graham
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Patent number: 6423126Abstract: There is provided an anticorrosive composition for a memory unit bearing so as to control outgas generation which would cause magnetic head crushing or memory error. The anticorrosive composition for a memory unit bearing contains a carbonic ester represented by the following formula: wherein R and R′ are branched alkyl groups of 13 to 15 carbon atoms and may either be the same or different.Type: GrantFiled: March 29, 2000Date of Patent: July 23, 2002Assignee: Minebea Co., Ltd.Inventor: Motoharu Akiyama
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Patent number: 6420323Abstract: A low-foam emulsifier system is presented containing (a) an ethoxylate/propoxylate of one or more C8-C18 fatty alcohols, where the ethoxylate/propoxylate contains 2 to 6 ethylene oxide units and 4 to 8 propylene oxide units, with (b) a fatty alcohol propoxylate or distillation residue of fatty alcohol or fatty alcohol propoxylate, where the fatty alcohol contains 12 to 24 carbon atoms and up to three propylene oxide units. The weight ratio of (a) to (b) is from 1:0.3 to 0.3:1. The emulsifier system produces a low amount of foam, and is useful in industrial metal processing applications such as cleaning, corrosion protection or cooling lubricant emulsions.Type: GrantFiled: July 27, 1999Date of Patent: July 16, 2002Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Juergen Geke, Horst-Dieter Speckmann, Bernd Stedry
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Publication number: 20020066889Abstract: The present invention provides methods and compositions for the reduction of the corrosion rate of already corroding steel reinforcements embedded in a hardened concrete structure as well as for the protective corrosion inhibition of uncorroded steel reinforcements embedded in a hardened concrete structure exposed to aggressive environments.Type: ApplicationFiled: May 11, 1999Publication date: June 6, 2002Inventors: BEAT MARAZZANI, THEODOR A. BURGE, URS MADER
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Patent number: 6399547Abstract: An acidic fluid that is useful in stimulation and workover operations, and in particular, in matrix acidizing treatments, comprises an acid, such as hydrochloric acid; water; an aliphatic aldehyde having 1-10 carbon atoms; and an aromatic aldehyde having 7-20 carbon atoms. The aliphatic aldehyde preferably has 1-6 carbon atoms. Glyoxylic acid and glyoxal are especially preferred aliphatic aldehydes. The aromatic aldehyde preferably has 7-10 carbon atoms. Cinnamaldehyde is especially preferred.Type: GrantFiled: February 24, 2000Date of Patent: June 4, 2002Assignee: Schlumberger Technology CorporationInventors: Wayne W. Frenier, Donald G. Hill
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Patent number: 6398984Abstract: Corrosion protection of magnesium and aluminum alloys in engine coolants and heat-exchange fluids is achieved by the use of a select group of aliphatic and aromatic carboxylate acids or the alkaline metal, ammonium or amine salts thereof in combination with a fluoride and/or a fluorocarboxylic acid or salt thereof. These compositions have been found to significantly improve the high temperature magnesium corrosion protection properties of coolants, and are of use in automobile engine coolant systems.Type: GrantFiled: October 13, 1999Date of Patent: June 4, 2002Assignee: Texaco Inc.Inventors: Jean-Pierre Leopold Maes, Serge Stefan Lievens
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Patent number: 6391257Abstract: This invention relates to antifreeze compositions comprising a mixture of organic acid corrosion inhibitors. The compositions comprise (a) from about 90% to about 99.89% by weight of a liquid alcohol which functions as a freezing point depressant, or mixture thereof; (b) from about 0.1% to about 5.5% by weight of a carboxylic acid selected from the group consisting of saturated and unsaturated aliphatic, and aromatic, mono-, di- and tri-carboxylic acids, and salts and isomers thereof, and any mixture thereof, and (c) from about 0.1% to about 2% by weight of a cyclohexenoic acid, or salt, isomer or mixture thereof, having the formula: wherein each of R1, R2 and R3 is, independently, selected from the group consisting of H, OH, COOH, C1-C10 alkyl groups, glycol esters, or combinations thereof.Type: GrantFiled: August 19, 1998Date of Patent: May 21, 2002Assignee: Prestone Products CorporationInventor: Peter M. Woyciesjes
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Publication number: 20020043650Abstract: The present invention describes an innovative means of inhibiting corrosion of metals which experience active-passive transition in contact with an electrolyte. This invention incorporates hydrogen peroxide and/or peroxycarboxylic acids or their constituents to inhibit corrosion by inducing passivation of the metal. Application of this technology reduces the potential for fouling, scaling and deposition as well as outperforming existing methods of corrosion control in these applications.Type: ApplicationFiled: December 10, 2001Publication date: April 18, 2002Inventor: Roy Martin
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Patent number: 6350395Abstract: A stabilizer composition comprising a) an N-alkyl morpholine and b) a straight-chain or cyclic aliphatic amine containing no hetroatoms other than N with a boiling point of at least 150° C. The stabilizer composition is useful for stabilizing a halogenated hydrocarbon against degradation.Type: GrantFiled: June 16, 2000Date of Patent: February 26, 2002Assignee: The Dow Chemical CompanyInventor: Marius Kuemin
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Patent number: 6231688Abstract: A zinc phosphate-type conversion film having microfine-sized crystals is formed on metal surfaces using a conversion treatment bath that contains zinc ions and phosphate ions along with 50 to 1500 ppm of an organoperoxide conversion accelerator, and optionally surfactant. Surface-conditioning treatments can be omitted from this method.Type: GrantFiled: June 8, 1998Date of Patent: May 15, 2001Assignee: Henkel CorporationInventors: Hitoshi Ishii, Yasuhiko Nagashima
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Patent number: 6207079Abstract: This invention relates to a scale inhibiting composition for aqueous systems comprising (a) polyaspartic acid, and (b) a water soluble phosphonated oligomer. The compositions are effective scale and/or corrosion inhibitors, but are also advantageous from an environmental standpoint because they are non-toxic, contain no heavy metals, and have little or no phosphorus. They also have sufficient calcium/hardness tolerance, are chlorine/bromine stable, and are effective corrosion inhibitors.Type: GrantFiled: January 28, 1999Date of Patent: March 27, 2001Assignee: Ashland Inc.Inventors: Pavol Kmec, Dwight E. Emerich
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Patent number: 6203719Abstract: The present invention provides corrosion inhibition formulations and compositions for inhibiting mineral scale and the corrosion of metals particularly the cavitation corrosion of aluminum in the presence of aqueous liquids. The combination of a mixture of polymeric polycarboxylates, azoles, nitrate salts, phosphates, stabilized silicates and transition metal compounds provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.Type: GrantFiled: January 10, 1997Date of Patent: March 20, 2001Assignee: Ashland Inc.Inventors: David E. Turcotte, Frances E. Lockwood
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Patent number: 6176907Abstract: Formulation for anti-corrosion coating materials, comprising (i) 3-30% by mass of a monomeric and/or polymeric, metal-free or metal-containing, chelate-forming compound, (ii) 10-80% by mass of a material which binds hydroxide ions, and (iii) 5-65% by mass of a conductive pigment based on carbon.Type: GrantFiled: January 19, 1999Date of Patent: January 23, 2001Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventor: Ralf Glausch
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Patent number: 6117364Abstract: An acid corrosion inhibitor composition is provided for petroleum wells and water wells subjected to stimulation with acid solutions. The inhibitor combines cinnamaldehyde and an organo-sulfur compound. The inhibitor provides a reduced rate of corrosion and fewer instances of pitting than inhibitors which include cinnamaldehyde alone. The inhibitor does not suffer from the well-known oil field aldehyde/polyacrylamide crosslinking incompatibility. The enhanced performance by the inhibitor of the present invention is provided by a synergistic action between the cinnamaldehyde and an organo-sulfur compound.Type: GrantFiled: May 27, 1999Date of Patent: September 12, 2000Assignee: Nalco/Exxon Energy Chemicals, L.P.Inventors: Mark A. Vorderbruggen, Dennis A. Williams
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Patent number: 6103459Abstract: Novel compounds that may be used as chemical vapor deposition precursors, thermochromic materials, conductive polymers, light-emitting diode precursors, and molecular charge-transfer salt precursors are provided. In addition, a novel compound that can be used to make the aforementioned compounds is provided. Still further, another aspect of the present invention is to provide methods for making and using the novel compounds provided.Type: GrantFiled: March 9, 1999Date of Patent: August 15, 2000Assignee: Midwest Research InstituteInventor: Bruce Diel
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Patent number: 6071436Abstract: Compositions and methods relating to cementitious compositions are provided. The addition of an amidoamine that is the reaction product of polyalkylenepolyamines and short-chain alkanedioic acids or reactive derivatives thereof to cementitious compositions has been found useful in inhibiting the corrosion of ferrous metal articles in contact with said composition. The amidoamine is advantageously employed in combination with a hydrophobe compound that enhances corrosion inhibition. The invention also provides aqueous emulsions which contain the amidoamine, one or more hydrophobes, and an emulsifier for the hydrophobe.Type: GrantFiled: April 12, 1996Date of Patent: June 6, 2000Assignee: GEO Specialty Chemicals, Inc.Inventor: Michael J. Incorvia
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Patent number: 6022401Abstract: Several copolymers of aspartic acid and another monomer provide effective mild steel corrosion inhibitors and scale formation inhibitors under oil field conditions. The copolymers are polymers of modified polyaspartic acid mer units and polyaspartic acid mer units. The resulting polymers are biodegradable.Type: GrantFiled: April 17, 1998Date of Patent: February 8, 2000Assignee: Nalco Chemical CompanyInventors: Jiansheng Tang, Shi-Liang Fu, Daniel H. Emmons
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Patent number: 5989322Abstract: The present invention provides a method and compositions useful for inhibiting corrosion of a corrodible metal resulting from contact of water and air with the metal. In this method, a stannous salt and a hydrocarbyl substituted succinimide of a polyethylene polyamine, separately or in combination, are added to the water in a minor amount and reduce corrosion of the metal to a substantially low rate.Type: GrantFiled: December 3, 1998Date of Patent: November 23, 1999Assignee: A.S. IncorporatedInventor: Olen Lonnie Riggs, Jr.
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Patent number: 5980619Abstract: A description is given of compounds of the formula ##STR1## in which the general symbols are as defined in claim 1, and of their zirconium, bismuth and calcium salts, and of the salts with the compounds of the formula II ##STR2## in which the general symbols are as defined in claim 1, as corrosion inhibitors in coating compositions for protecting metallic surfaces.Type: GrantFiled: February 12, 1997Date of Patent: November 9, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Adalbert Braig, Andreas Kramer, Jean-Pierre Wolf, Markus Frey
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Patent number: 5976414Abstract: The prevention of corrosion on the surfaces of airwasher systems and particularly systems containing low levels of hardness is controlled utilizing a corrosion inhibiting amount of a composition including an alkali metal silicate, a hydroxycarboxylic acid or its water soluble salts, a polyacrylate or its water soluble salts, and a water soluble polymer which acts as a dispersant. Superior corrosion inhibition is achieved using the compositions of this invention as corrosion inhibitors, particularly in industrial airwasher systems employing mild steel metallurgy.Type: GrantFiled: October 24, 1997Date of Patent: November 2, 1999Assignee: Nalco Chemical CompanyInventors: Binaifer S. Bedford, Daniel A. Meier
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Patent number: 5958850Abstract: A rust preventive composition which is obtained by blending at least one base oil selected from the group consisting of a hydrocarbon solvent, a mineral oil and a synthetic oil with, as essential components,(A) an organophosphoric ester calcium salt represented by the following general formula (1) in an amount of 0.1 to 5.0% by mass based on the total mass of the composition ##STR1## wherein R.sup.1 and R.sup.2 are each an alkyl group having 6 to 18 carbon atoms; and a and b are each an integer of 1 to 6,(B) water in an amount of 0.1 to 3.0 parts by weight based on 1 part by weight of the component (A), and(C) a rust inhibitor in an amount of 2.0 to 30% by mass based on the total mass of the composition.Type: GrantFiled: April 10, 1997Date of Patent: September 28, 1999Assignee: Nippon Oil., Ltd.Inventors: Yukio Matsuzaki, Yoshihiro Iwamura, Yoshitaka Natsume
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Patent number: 5948267Abstract: The present invention relates to a composition and method for inhibiting chloride-induced corrosion and limescale formation on ferrous metal surfaces and alloys in process systems in which aqueous solutions are concentrated, the composition containing a corrosion inhibiting amount of at least one polycarboxylic acid and/or its alkali metal or alkaline earth metal salts and a sufficient amount of a base to bring the water to a pH effective to inhibit both chloride-induced corrosion and limescale formation.Type: GrantFiled: May 2, 1997Date of Patent: September 7, 1999Assignee: Kay Chemical CompanyInventors: Michael Whittemore, Gerald LaCosse, Jennifer Riley
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Patent number: 5904990Abstract: Until recently, conducting polymers have been used as protective coatings. lthough these types of polymers appear to be effective in most cases, problems have resulted when attempting to bind these polymers to an aluminum surface. The polymers of this invention adhere extremely well to aluminum and aluminum alloys and thus, provide a very effective form of corrosion protection.Type: GrantFiled: March 13, 1998Date of Patent: May 18, 1999Assignee: The United States of America as represented by the Secretary of the NavyInventors: John D. Stenger-Smith, Melvin H. Miles, William P. Norris, John Nelson, Peter Zarras, John W. Fischer, Andrew P. Chafin
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Patent number: RE36291Abstract: A method for inhibiting corrosion of metal surfaces in an aqueous medium, comprising incorporating into the medium a corrosion inhibitor in an amount sufficient to inhibit corrosion, the corrosion inhibitor comprising a water-soluble agent selected from the group consisting of compositions of the formula ##STR1## compositions of the formula ##STR2## and mixtures thereof, wherein R is R.sup.2 .paren open-st.OCH.sub.2 CH.sub.2 .paren close-st..sub.x, wherein R.sup.2 is a substituted or unsubstituted alkyl, aryl, or aralkyl group of from about five to about fifteen carbon atoms, each carbon atom having at least one hydrogen and x is an integer of from about one to about ten, and R'N is a basic nitrogen compound that is at least water-dispersible.Type: GrantFiled: December 12, 1995Date of Patent: September 7, 1999Assignee: Baker Hughes IncorporatedInventor: Richard L. Martin