Sulphur Organic Compound Containing Patents (Class 252/402)
  • Patent number: 6797197
    Abstract: The present invention provides a method of treating boiler and condensate water by the addition of an effective amount of a hydroxyamine-acid ester treatment reagent or an all-in-one treatment composition comprising a hydroxyamine-acid ester. Modification of a hydroxyamine to a hydroxyamine-acid ester generally reduces the odors of the amine while providing a means to formulate the composition into a solid form. The ester typically decomposes at conditions in the boiler to release the hydroxyamine to treat the boiler water. Other components used to treat boiler water and condensate related problems may be formulated with the hydroxyamine-acid ester to form the all-in-one treatment composition.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: September 28, 2004
    Assignee: JohnsonDiversey, Inc.
    Inventors: Lyle H. Steimel, James Emerson, Sue Ann Balow
  • Patent number: 6774170
    Abstract: A heat stabilizing composition for polyolefins comprises an oxidized, non-cationized, non-silylated sulfur black pigment, a hindered phenolic antioxidant a sulfur-containing secondary stabilizer, each in stabilizing amount, and a hindered amine. The heat stabilizing composition yields polyolefin compounds and articles having improved long term heat aging stability. Preferably, the sulfur black pigment is treated by washing, to thereby reduce the concentration of soluble sodium salts.
    Type: Grant
    Filed: December 7, 2001
    Date of Patent: August 10, 2004
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Joseph R. Webster
  • Patent number: 6759457
    Abstract: A composition including 8-hydroxyquinaldine and an N-acyl taurate is useful in compounding elastomer compositions. Compositions are described containing elastomers such as rubbers, metal oxides, plasticizers, fillers, antidioxants and curing agents. Rubber compositions of the invention have utility in a wide variety of applications.
    Type: Grant
    Filed: February 21, 2002
    Date of Patent: July 6, 2004
    Assignee: Zeon Chemicals, L.P.
    Inventors: Edmee Files, Thomas Hofer
  • Patent number: 6706215
    Abstract: Coatings comprising A) a binder based on an organic polymer and B) as stabilizer against damage by light, heat and oxygen, a 2-(2′-hydroxyphenyl)-1,3-pyrimidine of the formula I  in which the radicals R1 to R6 are as defined in claim 1 have an outstanding resistance to the damaging effects of light, oxygen and heat. Compounds of the formula Ib defined in claim 18 are suitable in general for the stabilization of organic material.
    Type: Grant
    Filed: June 23, 1997
    Date of Patent: March 16, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Andreas Valet, Jean-Luc Birbaum, Gerhard Rytz, Norbert Wüms
  • Patent number: 6706214
    Abstract: A composition and process for inhibiting the corrosion of metallic substrates is revealed. The process utilizes an aqueous treatment solution comprising chitosan which has been reacted with an additive selected from the group consisting of phosphorus-containing compounds and sulfur-containing compounds and mixtures thereof. More preferably, the phosphorus-containing compound is a phosphonic acid and the sulfur-containing compound is a mercapto, thio, or thienyl containing compound or a mercapto functional silane. The composition and process are particularly useful in providing corrosion protection for aluminum and aluminum alloys.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: March 16, 2004
    Inventor: Gerald Wojcik
  • Publication number: 20030227006
    Abstract: The present invention encompasses a novel organic based composition which includes at least one organic based heat stabilizer component, and at least one stabilizer modifying component selected from the group of liquid calcium soap and 1,3,5-tris (2-hydroxyethyl) cyanuric acid. The invention also encompasses heat stabilized polymer compositions made with the novel organic based composition disclosed herein.
    Type: Application
    Filed: March 3, 2003
    Publication date: December 11, 2003
    Inventors: Paul Brian Adams, Tod Charles Duvall, Gene Kelly Norris
  • Patent number: 6646037
    Abstract: A treatment for pigments is provided. This treatment, which uses certain organosulfonic compounds, imparts improved physical and chemical qualities including lacing resistance, improved dispersion and decreased chemical reactivity when these treated pigments are incorporated into polymeric matrices. The addition of organosulfonic compounds may flexibly be incorporated into known processes at varying points, and are preferably added downstream of any filtering steps.
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: November 11, 2003
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Modasser El-Shoubary, Robert Kostelnik, Charles Wheddon
  • Publication number: 20030189192
    Abstract: Stablizing mixtures for organic polymers comprising: (a) at least one compound belonging to the group of 3-pyrazolidinones; (b) at least one compound belonging to the group of organic phosphites or phosphonites; (c) at least one compound belonging to the group of sterically hindered phenols; and, optionally, (d) at least one compound belonging to the group of sterically hindered amines. The above mixtures can be used as stabilizers of organic polymers to degradation caused by oxygen, heat and/or light.
    Type: Application
    Filed: February 4, 2003
    Publication date: October 9, 2003
    Inventors: Daniele Girelli, Fabjo Broussard, Vincenzo Malatesta
  • Patent number: 6620867
    Abstract: Crystalline modification of mixtures comprising (a) a nickel-quencher corresponding to [2,2′-thio-bis(4-t-octylphenolate)-n-butylamine Nickel (II)] and (b) a 2-hydroxy-4-alkyloxybenzophenone corresponding to 2-hydroxy-4-n-octyloxybenzophenone wherein it has two diffraction lines at angles 2{acute over (ø)}=6.291 and 2{acute over (ø)}=6.888 in the X-Ray diffraction spectrum from powders. The said crystalline modification can be used as a light stabilizer for agricultural films based on polyolefins or polyolefinic copolymers.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: September 16, 2003
    Assignee: Great Lakes Chemical (Europe) GmbH
    Inventors: Carlo Neri, Luciano Pallini, Giovanni Sandre
  • Patent number: 6610218
    Abstract: Halogen-containing polymer compositions comprising a latent mercaptan-containing heat stabilizer composition substantially free from the offensive odor typically associated with mercaptans are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan may be the sole heat stabilizer additive but the free mercaptan released during processing may also synergize the activity of metal-based heat stabilizers such as metal salts and organometallic stabilizers such as organotin carboxylates and mercaptides in the polymer composition. The odor of primary mercaptan-containing heat stabilizers in halogenated polymer compositions is masked by a small amount of a latent mercaptan.
    Type: Grant
    Filed: August 4, 1999
    Date of Patent: August 26, 2003
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Paul B. Adams, Gene K. Norris
  • Patent number: 6592781
    Abstract: A novel composition of thiazolidines of the following formula and a method to prepare the same are disclosed. The method involves reacting a dihydrothiazole with a mixture comprising formic acid and an aldehyde. These new thiazolidines are useful as corrosion inhibitors.
    Type: Grant
    Filed: May 29, 2002
    Date of Patent: July 15, 2003
    Assignee: Baker Hughes Incorporated
    Inventors: Bernardus Antonius Maria Oude Alink, Benjamin T. Outlaw
  • Patent number: 6548016
    Abstract: The present invention provides a composition and method for inhibiting hydrogen permeation in metal refinery equipment comprising incorporating into a product stream handled by said equipment a polyamine amide of 3-hydrocarbyl thiopropionic acid in an amount sufficient to inhibit said hydrogen permeation. In a preferred embodiment, the polyamine amide of 3-hydrocarbyl thiopropionic acid is selected from the group consisting of propanamide, N-[2-[2-[3-(dodecenyl)-2,5-dioxo-1-pyrrolidinyl]ethyl]amino]ethyl]-3-[dodecylthio]-2-methyl and 15-thia-5,8,11-triazaheptacosanoic acid, 2-(dodecenyl)-13-methyl-4,12-dioxo, and combinations thereof.
    Type: Grant
    Filed: May 2, 1996
    Date of Patent: April 15, 2003
    Assignee: Baker Hughes Incorporated
    Inventor: Bradley G. Borgard
  • Patent number: 6540943
    Abstract: The corrosion of metal equipment which is cleaned with an inorganic acid is inhibited by treating the equipment with a corrosion inhibitor composition containing at least one quaternary ammonium compound, a sulfur-containing compound and a nonionic surfactant in a solvent.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: April 1, 2003
    Assignee: Ondeo Nadco Company
    Inventors: Duane S. Treybig, Dennis A. Williams
  • Patent number: 6537466
    Abstract: Halogen-containing polymer compositions comprising a latent mercaptan-containing heat stabilizer composition substantially free from the offensive odor typically associated with mercaptans are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan may be the sole heat stabilizer additive but the free mercaptan released during processing may also synergize the activity of metal-based heat stabilizers such as metal salts and organometallic stabilizers such as organotin carboxylates and mercaptides in the polymer composition. The odor of primary mercaptan-containing heat stabilizers in halogenated polymer compositions is masked by a small amount of a latent mercaptan.
    Type: Grant
    Filed: August 4, 1999
    Date of Patent: March 25, 2003
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Paul B. Adams, Gene K. Norris
  • Patent number: 6508958
    Abstract: A composition and process for inhibiting the corrosion of metallic substrates is revealed. The process utilizes an aqueous treatment solution comprising chitosan which has been reacted with an acid selected from the group consisting of phosphonic acids, carboxylic acids and mixtures thereof. The composition and process are particularly useful in providing corrosion protection for aluminum and aluminum alloys.
    Type: Grant
    Filed: July 16, 2001
    Date of Patent: January 21, 2003
    Inventor: Gerald Wojcik
  • Patent number: 6419857
    Abstract: A novel composition of thiazolidines of the following formula and a method to prepare the same are disclosed. The method involves reacting a dihydrothiazole with a mixture comprising formic acid and an aldehyde. These new thiazolidines are useful as corrosion inhibitors.
    Type: Grant
    Filed: December 6, 1999
    Date of Patent: July 16, 2002
    Assignee: Baker Hughes Incorporated
    Inventors: Bernardus Antonius Maria Oude Alink, Benjamin T. Outlaw
  • Patent number: 6403679
    Abstract: Granular form of a mixture comprising: (a) a nickel-quencher corresponding to [2,2′-thio-bis(4-t-octyl-phenolate)-n-butylamine Nickel (II)]; (b) a 2-hydroxy-4-alkyloxybenzophenone corresponding to 2-hydroxy-4-n-octyloxybenzophenone; characterized in that it has two diffraction lines at angles 2&thgr;=17.593 and 2&thgr;=22.023 in the X-Ray diffraction spectrum from powders. The above granular form can be used as a light stabilizer for agricultural films based on polyolefins or olefinic copolymers.
    Type: Grant
    Filed: August 23, 2000
    Date of Patent: June 11, 2002
    Assignee: Great Lakes Chemical (Europe) GmbH
    Inventors: Carlo Neri, Luciano Pallini, Giovanni Sandre
  • Patent number: 6403850
    Abstract: Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of: A) at least one stable hindered nitroxyl compound having the structural formula:  wherein R1 and R4 are independently selected from the group consisting of hydrogen, alkyl, and heteroatom-substituted alkyl and R2 and R3 are independently selected from the group consisting of alkyl and heteroatom-substituted alkyl; and X1 and X2 (1) are independently selected from the group consisting of halogen, cyano, COOR7, —S—COR7, —OCOR7, (wherein R7 is alkyl of 1 to 15 carbon atoms, or (2) taken together, form a ring structure with the nitrogen; and B) at least one phenylenediamine, and, optionally, C) at least one nitroaromatic compound.
    Type: Grant
    Filed: July 17, 2000
    Date of Patent: June 11, 2002
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Brigitte Benage, Andrew J. Eisenstein
  • Patent number: 6270692
    Abstract: Dispersion powders with a reduced tendency to autoignition are obtained by adding antioxidants to dispersions before spray drying or to dispersion powders after spray drying.
    Type: Grant
    Filed: June 26, 1996
    Date of Patent: August 7, 2001
    Assignee: Clariant GmbH
    Inventors: Ulrich Geissler, Helmut Rinno
  • Patent number: 6222080
    Abstract: This invention relates to a vinyl aromatic, especially styrene, polymerization inhibitor system comprising an N-phenyl-1,4-benzoquinoneimine compound and optionally an aryl-substituted phenylenediamine.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: April 24, 2001
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Howard Stephen Friedman, Paul Edwin Stott
  • Patent number: 6194494
    Abstract: A stabiliser combination, mainly for PVC, is described, comprising A) at least one compound of formula I  wherein R*1 and R*2 are each independently of the other C1-C12alkyl, C3-C6lkenyl, C5-C8cycloalkyl that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or by chlorine atoms, or C7-C9phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or chlorine atoms, and R*1 and R*2 may additionally be hydrogen and C1-C12alkyl, and Y is S or O, and B) at least one compound from the following groups: B1) perchlorate compounds, B2) glycidyl compounds, B3) beta-diketones and beta-keto esters, B4) dihydropyridines and polydihydropyridines, B5) polyols and disaccharide alcohols, B6) sterically hindered amines (tetraalkylpiperidine compounds), B7) alkali aluminosilicates (zeolites), B8) hydrotalcites, B9) alkali aluminocarbonates (dawsonite
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: February 27, 2001
    Assignee: Witco Vinyl Additives GmbH
    Inventors: Wolfgang Wehner, Hans-Helmut Friedrich, Kornelia Malzacher, Hans-Ludwig Mehner, Rolf Drewes
  • Patent number: 6060545
    Abstract: Organic materials having excellent stability against oxidative, thermal or light-induced degradation comprise as stabilisers (i) at least one compound of formula I ##STR1## wherein the general symbols are as defined in claim 1, and (ii) calcium lactate and/or calcium stearoyl-2-lactylate.
    Type: Grant
    Filed: September 23, 1998
    Date of Patent: May 9, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Bernard Gilg
  • Patent number: 6056965
    Abstract: The invention relates to 2-mercaptoimidazole derivatives substituted in the 4(or 5)-position.These 2-mercaptoimidazole derivatives are of the general formula (I) below: ##STR1## wherein: R.sub.1, R.sub.2, R.sub.5, R.sub.7 and R.sub.8 are hydrogen, a lower alkyl, an aralkyl or a substituted aralkyl, wherein at least one of R.sub.1 and R.sub.2 is hydrogen;R.sub.3 is (CH.sub.2).sub.n COR.sub.4, --(CH.sub.2).sub.n N.sup.+ (R.sub.5 R.sub.6 R.sub.7).X.sup.- or --CH.sub.2 CH(COR.sub.4)N.sup.+ (R.sub.5 R.sub.6 R.sub.7).X.sup.- ;R.sub.4 is OR.sub.8, --NHR.sub.5, --.alpha.-amino acid,--NHCH.sub.2 CH.sub.2 SO.sub.3.sup.-.Y.sup.+, --NHCH.sub.2 CH.sub.2 CO.sub.2.sup.- Y.sup.+, --OCH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.3.X.sup.- ; ##STR2## n=1 or 2; X.sup.31 is an anion of an acid acceptable in cosmetics, pharmaceuticals or foodstuffs; andY.sup.+ is a cation of a base acceptable in cosmetics, pharmaceuticals or foodstuffs.
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: May 2, 2000
    Assignee: Oxis Isle of Man, Limited
    Inventors: Jean-Claude Y. Yadan, Jinzhu Xu, Marc E. Moutet, Jean R. Chaudiere
  • Patent number: 6039895
    Abstract: This invention relates to a vinyl aromatic, especially styrene, polymerization inhibitor system comprising an N-phenyl-1,4-benzoquinoneimine compound and optionally an aryl-substituted phenylenediamine.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: March 21, 2000
    Inventors: Howard Stephen Friedman, Paul Edwin Stott
  • Patent number: 5985958
    Abstract: A light-curing composite material is described which is characterized by a content of anaerobic stabilizer and/or stable organic radicals and which has a reduced light sensitivity and an improved vacuum stability and is therefore suitable in particular as a dental filling material.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: November 16, 1999
    Assignee: Ivoclar AG
    Inventors: Norbert Moszner, Volker Rheinberger
  • Patent number: 5976397
    Abstract: A photofading inhibitor compound comprising a singlet oxygen quenching moiety having a quenching rate of 1.times.10.sup.6 L mol.sup.-1 S.sup.-1 or faster and a cationic moiety.
    Type: Grant
    Filed: September 26, 1997
    Date of Patent: November 2, 1999
    Assignee: Lever Brothers Company
    Inventor: Ian Paul Wilkes
  • Patent number: 5968498
    Abstract: The freshness of meat, vegetables and fruits in a refrigerator or food storage box can be retained for a long period of time by using (1) a freshness retaining gel composition which comprises a freshness retainer component comprising an isothiocyanic acid compound and an aliphatic carboxylic acid or (2) a freshness retaining gel composition which comprises a freshness retainer component comprising an isothiocyanic acid compound, a nonionic surfactant or a fatty acid ester, and a gelling agent.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: October 19, 1999
    Inventors: Toru Okada, Kenji Kuranari, Yukari Mihara
  • Patent number: 5871669
    Abstract: A description is given of novel stabilizer mixtures comprising at least one compound of the formula ##STR1## and at least one compound of the formula ##STR2## in which the variables are as defined in the claims. The novel stabilizer mixtures are suitable for stabilizing organic material, especially textile fibre materials, against damage by light, oxygen and heat.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: February 16, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rolf Tittmann, Francesco Fuso, Gerhard Reinert, Hans Peter Harri
  • Patent number: 5730906
    Abstract: An aviation turbine oil of reduced deposit forming tendencies and improved anti-oxidancy is disclosed which comprises a major portion of a suitable aviation turbine oil base stock and a minor amount of a non-sulfur containing triazine derivative and a mercapto alkyl alcohol.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: March 24, 1998
    Assignee: Exxon Research and Engineering Company
    Inventor: Paul Joseph Berlowitz
  • Patent number: 5686513
    Abstract: A process for the production of a polyamide stabilizer concentrate in which the concentrate consists of at least two interactive stabilizer components with defined particle sizes and, optionally, micro-dispersed silicic acid, as well as a wax bonding agent with a solidification temperature t.sub.A between 65.degree. and 120.degree. C., in which a homogeneous mixture of these ingredients is compacted into tablets when subjected to a compression force p that is sufficient to heat the mixture to a temperature of at least 40.degree. C. and equal to t.sub.A minus 10.degree. to 50.degree. C.
    Type: Grant
    Filed: September 9, 1996
    Date of Patent: November 11, 1997
    Assignee: Zimmer Aktiengesellschaft
    Inventor: Hartmut Liehr
  • Patent number: 5672730
    Abstract: The present invention relates to a compound of the formula ##STR1## wherein n is an integer from 1 to 4, R is selected from the group consisting of hydrogen and methyl; wherein when n is 1, R.sup.1 is selected from the group consisting of alkyl radicals having 1 to 18 carbon atoms, aryl radicals having 6 to 12 carbon atoms, aralkyl radicals having 7 to 12 carbon atoms, cycloalkyl radicals having 5 to 12 carbon atoms and radicals of the formula: ##STR2## wherein x is an integer of from 1 to 7; wherein when n is 2, R.sup.1 is selected from the group consisting of alkylene radicals having 2 to 18 carbon atoms, cycloalkylene radicals having 5 to 12 carbon atoms, arylene radicals having 6 to 12 carbon atoms, ##STR3## polyalkyl glycol ether radicals having the following structure ##STR4## wherein x is an integer from 1 to 7.
    Type: Grant
    Filed: September 22, 1995
    Date of Patent: September 30, 1997
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Kirkwood Storer Cottman
  • Patent number: 5668200
    Abstract: A mixture comprising a compound of the formula I and a compound of the formula II ##STR1## in which n is 1 or 2; R.sub.1, R'.sub.1, R.sub.2, R'.sub.2, R.sub.3 and R.sub.4, independently of one another, are H, C.sub.1 -C.sub.12 alkyl; C.sub.2 -C.sub.6 alkenyl; C.sub.1 -C.sub.12 alkoxy; C.sub.2 -C.sub.18 alkenoxy; halogen; trifluoromethyl; C.sub.7 -C.sub.11 phenylalkyl; phenyl; phenyl which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen; phenoxy; or phenoxy which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen;R.sub.6 is hydrogen, C.sub.1 -C.sub.24 alkyl, C.sub.5 -C.sub.12 cycloalkyl or C.sub.7 -C.sub.15 phenylalkyl;R.sub.7, in the case where n=1, and R'.sub.7, independently of one another, are hydrogen or C.sub.1 -C.sub.18 alkyl; or are C.sub.1 -C.sub.12 alkyl which is substituted by OH, C.sub.1 -C.sub.18 alkoxy, allyloxy, halogen, --COOH, --COOR.sub.8, --CONH.sub.2, --CONHR.sub.9, --CON(R.sub.9)(R.sub.10), --NH.sub.2, --NHR.sub.9, --N(R.sub.9)(R.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: September 16, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Andreas Valet, Gerhard Rytz, Pascal Hayoz
  • Patent number: 5658721
    Abstract: Hydrophilic colloids, such as gelatin, which are employed in the manufacture of photographic elements are commonly treated with a hardening composition, among the most useful of which are hardening compositions containing vinyl sulfone hardening agents such as bis(vinylsulfonyl)methane. In accordance with this invention, citric acid or salts of citric acid are utilized as an effective inhibitor of homopolymerization in such hardening compositions.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: August 19, 1997
    Assignee: Eastman Kodak Company
    Inventors: Mary Jane Griggs, Lewis Robert Hamilton, Peter Anthony Marr, Philip Raymond Martell
  • Patent number: 5648574
    Abstract: Compositions and methods for inhibiting the polymerization of vinyl aromatic monomers in oxygen-free processing systems are disclosed. The compositions comprise a hydroxylamine compound, a phenylenediamine compound and a vinyl aromatic monomer. The methods comprise adding to the monomer bis-N,N'(hydroxypropyl)hydroxylamine.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: July 15, 1997
    Assignee: BetzDearborn Inc.
    Inventors: Graciela B. Arhancet, Inge K. Henrici
  • Patent number: 5620632
    Abstract: A process for preparing a solid particle dispersion of an epoxy compound of the formula SI, ##STR1## wherein R is H, an alkyl group, or an aryl group; L.sub.1 is an alkylene group or an arylene group; L.sub.2 is --O--, --CO--, --S--, --SO.sub.2 --, --PO.sub.2 --, --CO.sub.2 --, --NHCO-- or --NHSO.sub.2 --, wherein L.sub.2 may be orientated in either direction; L.sub.3 is an alkylene group; m is 0 or 1; p is 0 or 1; and X is ##STR2## wherein R' is H or an alkyl or aryl group, with the proviso that where L.sub.2 comprises an ionizable group, X may also be an alkyl group or an aryl group is disclosed. The process comprising the steps of: (a) forming a coarse aqueous slurry of solid particles of said compound; and (b) milling said slurry in the presence of a hydrophobic, photographically inert, liquid second component which has a logP.sub.(calc) greater than about 6.0 for time sufficient to provide particles of the desired average particle size.
    Type: Grant
    Filed: April 25, 1995
    Date of Patent: April 15, 1997
    Assignee: Eastman Kodak Company
    Inventor: Krishnan Chari
  • Patent number: 5616637
    Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub.36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: April 1, 1997
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Steinmann
  • Patent number: 5560852
    Abstract: A method of improving the light fastness of textile materials using an aqueous dispersion of a compound of formula I, ##STR1## having a first (A) and a second (B) benzoxazine-4-one ring joined by a phenylene bridging member; a variable bond between the first benzoxazine-4-one ring (A) and the phenylene bridging member, said variable bond being meta- or para- to the bond between the second benzoxazine-4-one ring (B) and the bridging member; wherein each R.sub.1 is independently hydrogen, halogen, nitro, C.sub.1-2 alkyl, C.sub.1-4 alkoxy, carboxy, sulfonic acid, C.sub.1-3 alkylcarbonyl, benzoyl or C.sub.1-4 alkoxycarbonyl and; R.sub.2 is hydrogen, chlorine, bromine, methyl, C.sub.1-2 alkoxy, phenyl, hydroxy, nitro, carboxy or sulfonic acid.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: October 1, 1996
    Assignee: Sandoz Ltd.
    Inventor: Jean-Luc Mura
  • Patent number: 5514535
    Abstract: Hydrophilic colloids, such as gelatin, which are employed in the manufacture of photographic elements are commonly treated with a hardening composition, among the most useful of which are hardening compositions containing vinyl sulfone hardening agents such as bis(vinylsulfonyl)methane. In accordance with this invention, a sulfate, such as sodium sulfate, is utilized as both an effective conductivity marker and an effective inhibitor of homopolymerization in such hardening compositions.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: May 7, 1996
    Assignee: Eastman Kodak Company
    Inventors: Lewis R. Hamilton, Peter A. Marr, Philip R. Martell, Kristine F. Ohman
  • Patent number: 5510547
    Abstract: Methods for inhibiting the polymerization of vinyl aromatic monomers in oxygen-free processing systems are disclosed. The methods comprise adding from 1 to 10,000 parts of a combination of a hydroxylamine compound and a phenylenediamine compound to the vinyl aromatic monomer.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: April 23, 1996
    Assignee: Betz Laboratories, Inc.
    Inventors: Graciela B. Arhancet, Inge K. Henrici
  • Patent number: 5490946
    Abstract: Adducts of benzotriazole or substituted benzotriazole with formaldehyde or with thiadiazole or substituted thiadiazole are useful as ashless anti-wear/anti-friction/anti-oxidant additives for lubricants. Formulated lubricants containing such adducts exhibit compound levels of anti-wear, anti-friction and oxidation stability performance.
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: February 13, 1996
    Assignee: Exxon Research and Engineering Company
    Inventors: Morton Beltzer, Manuel A. Francisco, John W. Frankenfeld
  • Patent number: 5424349
    Abstract: Tertiary amides have been developed which have low volatility and good thermal stability and which are effective in stabilizing organic materials that are normally susceptible to oxidative deterioration. The novel antioxidants are tertiary amides corresponding to the formula: ##STR1## wherein R is a mono-, di-, or trivalent aromatic or saturated aliphatic hydrocarbon group containing 1-20 carbons; n is an integer of 1-3 which is equal to the valence of R; R' is phenyl, benzyl, or C.sub.1 -C.sub.6 alkyl; m is an integer of 1-3; R" is a C.sub.1 -C.sub.4 alkylene group; Z and Z' are independently selected from hydrogen and alkyl; and Q is carbonyl or sulfonyl.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: June 13, 1995
    Assignee: Albemarle Corporation
    Inventor: Vincent J. Gatto
  • Patent number: 5396004
    Abstract: Methods and compositions are provided for inhibiting the polymerization of vinyl aromatic monomers under distillation conditions. The compositions comprise a combination of a phenylenediamine compound and a hydroxylamine compound.
    Type: Grant
    Filed: September 8, 1993
    Date of Patent: March 7, 1995
    Assignee: Betz Laboratories, Inc.
    Inventors: Graciela B. Arhancet, Inge K. Henrici
  • Patent number: 5380890
    Abstract: A method of producing an antioxidant containing compound, and in particular, an antioxidant glyceride derivative, comprises reacting a first compound with a second medium. By this reaction, a product is formed whereby an active component of the first compound, e.g., the antioxidant, is covalently incorporated into the second medium.The second medium comprises glyceride derivatives, silicones, fluorocarbons and alkoxylates containing reactive groups such as hydroxy, amino, carboxyl, ester, or amides.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: January 10, 1995
    Inventors: George H. Greene, Robert Miller, James L. Williams, James C. Phillips, Jerry F. Stults, Jan P. E. Tellings
  • Patent number: 5362410
    Abstract: The incorporation of the heterocyclic saccharin functionality into the alkenylsuccinimide dispersant structures via the Mannich alkylaminoalkylation procedure provides a class of ashless non-phosphorus dispersants with multifunctional antiwear, antioxidant and corrosion inhibiting properties in lubricant compositions.
    Type: Grant
    Filed: September 13, 1993
    Date of Patent: November 8, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Abraham O. M. Okorodudu, Angeline B. Cardis
  • Patent number: 5336420
    Abstract: An aromatic functional fluid, specifically a monoalkylated tetradecyl diphenyl oxide synthetic lubricant, contains a polymer-supported reaction product of an organic quaternary ammonium salt, derived from a mercapto-heterocycle and a quaternary ammonium salt. To produce the polymer-supported organic quaternary ammonium salt, the salt is reacted with a dicarboxylic acid or anhydride, specifically 2-dodecen-1-ylsuccinic anhydride. An arylamine antioxidant, such as alkylated phenyl naphthylamine, can be added to the polymer supported organic quaternary ammonium salt-treated functional fluid to impart extra antioxidant and stability properties.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: August 9, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Andrew G. Horodysky, Shih-Ying Hsu, Andrew Jeng, Leslie R. Rudnick
  • Patent number: 5322872
    Abstract: Compositions of (a) a salt of a metal and a carboxylic acid having at least 6 carbon atoms and (b) at least one salt of a metal other than the metal of (a) and a carboxylic acid having at least 6 carbon atoms in a fluid medium are stabilized towards storage decomposition and precipitation by incorporating in the composition (c) a complexing agent such as a ketoxime.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: June 21, 1994
    Assignee: The Lubrizol Corporation
    Inventor: Kevin J. Quinn
  • Patent number: 5321067
    Abstract: Compounds prepared by the addition of the mercaptan group of 3,5-dialkyl-4-aminobenzenethiol to activated ethylenic double bonds or the sulfenyl chloride of 3,5-dialkyl-4-aminobenzenethiol to trialkyl phosphites are effective stabilizers for organic materials subject to oxidative and/or thermal degradation.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: June 14, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Stephen D. Pastor
  • Patent number: 5312852
    Abstract: 2-(2-Hydroxy-3-perfluoroalkylthiomethyl-5-alkylphenyl)-2H-benzotriazoles are prepared by reacting the Mannich base hydrohalide or quaternary salt of a 2-(2-hydroxy-5-alkylphenyl)-2H-benzotriazole with a perfluoroalkyl mercaptan. The products exhibit outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the processing of stabilized compositions at elevated temperatures.
    Type: Grant
    Filed: July 12, 1993
    Date of Patent: May 17, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Robert A. Falk, Gregory R. Coughlin
  • Patent number: 5304314
    Abstract: Sulfur-containing ester derivatives of arylamines and hindered phenols have been found to be effective antioxidant and antiwear additives for lubricants.
    Type: Grant
    Filed: December 27, 1991
    Date of Patent: April 19, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Shih-Ying Hsu, Andrew G. Horodysky
  • Patent number: 5269954
    Abstract: The present invention relates to the preparation of antioxidant additives to lubricants and to their use in lubricating compositions. The additives according to the invention have the formula:ArAr'(H)N--(R--X).sub.a --R'Ywhere--Ar and Ar' are identical or different aromatic radicals, R and R', which are identical or different, denote a C.sub.2 -C.sub.18 linear or branched alkylene radical, X denotes an oxygen or sulphur atom or an --NH group, a is an integer between 0 and 5 and Y is chosen from the group consisting of --NR.sub.1 R.sub.2, where R.sub.1 and R.sub.2, which are identical or different, denote a hydrogen atom or a C.sub.1 -C.sub.12 alkyl, alkenyl, cycloalkyl or arylalkyl radical --N.dbd.CH--Ar.sub.1 where Ar.sub.1 is an aryl radical containing at least one phenolic group --NR.sub.1 --CO--Ar.sub.1 and ##STR1## where R.sub.3 denotes a saturated or unsaturated, linear or branched alkyl radical.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: December 14, 1993
    Assignee: Elf France
    Inventors: Laurent Germanaud, Patrick Azorin, Patrick Turello