Halogen Containing Patents (Class 264/1.35)
  • Patent number: 10201943
    Abstract: The present invention relates to a method for manufacturing a polarizing plate, the method comprising the sequential steps of: preparing a polarizing element comprising a polyvinyl alcohol-based polarizer dyed with any one or more of iodine and a dichroic dye; irradiating the polarizing element with light having a specific wavelength selected from a wavelength range of 200 nm to 800 nm; and moistening the polarizing element, and to a polarizing plate manufactured by the method.
    Type: Grant
    Filed: September 26, 2014
    Date of Patent: February 12, 2019
    Assignee: LG CHEM, LTD.
    Inventors: Byung Sun Lee, Sung Hyun Nam, Kyun Il Rah
  • Patent number: 9310676
    Abstract: The present invention relates generally to an apparatus for embossing a flexible substrate. More specifically, the present invention relates to an apparatus for embossing a curable composition coated flexible substrate with an optically variable image transferred from an embossing foil, especially belt, or sheet of an optically transparent fluoropolymer. The optically variable image is irradiated through the embossing belt, or sheet with ultraviolet light contemporaneously with the embossing so that the transferred imprint pattern cures, hardens, and retains its shape.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: April 12, 2016
    Assignee: BASF SE
    Inventors: Michelle Richert, David R. Boswell, Mark Robert Dicker, Alexander Stuck
  • Patent number: 8889043
    Abstract: A method for casting a styrenic fluoropolymer film on a substrate includes preparing a polymer solution by dissolving the fluoropolymer in a solvent or solvent blend whose Hansen solubility parameters (HSPs. MPa1/2) satisfy the following relations: |SPb?SPp|<5, |SPb?SPs|<4, |SPb(H)?SPp(H)|<7, and 2<|SPb(H)?SPs(H)|<10 wherein SPb, SPp, SPs, are the total Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; SPb(H), SPp(H), and, SPs(H) are the hydrogen-bond Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; wherein the fluoropolymer comprises a moiety of: wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring.
    Type: Grant
    Filed: May 1, 2012
    Date of Patent: November 18, 2014
    Assignee: Akron Polymer Systems, Inc.
    Inventors: Bin Wang, Thauming Kuo, Douglas Stephens McWilliams, Frank W. Harris, Ted Calvin Germroth, Jiaokai Jing, Dong Zhang, Xiaoliang Zheng
  • Publication number: 20140213727
    Abstract: A water soluble polyvinyl alcohol copolymer having a diad syndiotacticity of greater than about 60% and less than about 70%. In some embodiments, the water soluble polyvinyl alcohol copolymer is soluble in water at a concentration of at least 1 wt % at a temperature of less than 100° C. In other embodiments, the composition is soluble in water at a concentration of at least 5 wt % at a temperature in the range from about 90° C. to less than 100° C. The high solubility of the high syndiotactic poly vinyl alcohols disclosed herein may provide various advantages as described herein, including ease of processing and decreased use of harmful solvents.
    Type: Application
    Filed: January 27, 2014
    Publication date: July 31, 2014
    Applicant: SEKISUI SPECIALTY CHEMICALS AMERICA, LLC
    Inventors: Yohei Nishimura, Regan Pollock, Richard Vicari
  • Patent number: 8741190
    Abstract: To obtain a water-resistant polarizing film free from deterioration in dichroic ratio caused by water-resistant treatment, it is critical that adjacent sulfonic acid groups or sulfonate groups in the organic dyes to be used for the polarizing film are spaced at moderate intervals.
    Type: Grant
    Filed: June 20, 2013
    Date of Patent: June 3, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Junzo Miyazaki, Shoichi Matsuda, Kyoko Nishiguchi
  • Publication number: 20130277871
    Abstract: To obtain a water-resistant polarizing film free from deterioration in dichroic ratio caused by water-resistant treatment, it is critical that adjacent sulfonic acid groups or sulfonate groups in the organic dyes to be used for the polarizing film are spaced at moderate intervals.
    Type: Application
    Filed: June 20, 2013
    Publication date: October 24, 2013
    Inventors: Junzo Miyazaki, Shoichi Matsuda, Kyoko Nishiguchi
  • Patent number: 8491823
    Abstract: To obtain a water-resistant polarizing film free from deterioration in dichroic ratio caused by water-resistant treatment, it is critical that adjacent sulfonic acid groups or sulfonate groups in the organic dyes to be used for the polarizing film are spaced at moderate intervals.
    Type: Grant
    Filed: January 23, 2009
    Date of Patent: July 23, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Junzo Miyazaki, Shoichi Matsuda, Kyoko Nishiguchi
  • Patent number: 8435432
    Abstract: Retardation expressibility of a transparent polymer film can be easily controlled by heat treatment of the film at a temperature T (unit, ° C.) satisfying a condition of the following formula (1): Tc?T<Tm0??Formula (1) wherein Tc represents the crystallization temperature (unit, ° C.) of the film before the heat treatment; and Tm0 represents the melting point (unit, ° C.) of the film before the heat treatment.
    Type: Grant
    Filed: February 21, 2007
    Date of Patent: May 7, 2013
    Assignee: FUJIFILM Corporation
    Inventor: Yasuyuki Sasada
  • Patent number: 8414803
    Abstract: A method for producing a transparent polymer film, comprising heat-treating a polymer film containing a polymer and a plasticizer having a number-average molecular weight of from 500 to 10000 and having a repetitive unit, at a temperature T (unit, ° C.) satisfying the following formula (1): Tc?T<Tm0??(1) wherein Tc means the crystallization temperature of the polymer film and Tm0 means the melting point of the polymer film.
    Type: Grant
    Filed: July 29, 2008
    Date of Patent: April 9, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Yasuo Mukunoki, Yasuyuki Sasada
  • Publication number: 20120199994
    Abstract: The present invention relates generally to an apparatus for embossing a flexible substrate. More specifically, the present invention relates to an apparatus for embossing a curable composition coated flexible substrate with an optically variable image transferred from an embossing foil, especially belt, or sheet of an optically transparent fluoropolymer. The optically variable image is irradiated through the embossing belt, or sheet with ultra-violet light contemporaneously with the embossing so that the transferred imprint pattern cures, hardens, and retains its shape.
    Type: Application
    Filed: August 9, 2010
    Publication date: August 9, 2012
    Applicant: BASF SE
    Inventors: Michelle Richert, David R. Boswell, Mark Robert Dicker, Alexander Stuck
  • Patent number: 8226860
    Abstract: A method for controlling positive birefringence in an optical compensation film (positive C-plate) having high positive birefringence throughout the wavelength range 400 nm<?<800 nm is provided. The method includes selecting polymers with optically anisotropic subunits (OASUs) that exhibit the buttressing effect, wherein the OASUs may be disks, mesogens or aromatic rings substituted with birefringence enhancing substituents. The method further includes processing the polymer by solution casting to yield a polymer film with high birefringence without the need for stretching, photopolymerization, or other processes. These optical compensation films may be used in LCDs, particularly IPS-LCDs.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: July 24, 2012
    Assignee: Akron Polymer Systems
    Inventors: Xiaoliang Joe Zheng, Frank W. Harris, Ted Calvin Germroth, Jiaokai Alexander Jing, Dong Zhang, Thauming Kuo, Brian Michael King
  • Publication number: 20120170117
    Abstract: A polarizer plate includes a polarizer that includes polyvinyl alcohol and a dichroic material, the polarizer having a degree of orientation of 15 or more as represented by Equation 1: Degree of orientation=RD/RPVA×100, where RPVA represents a phase difference of the polyvinyl alcohol and RD represents a phase difference of the dichroic material.
    Type: Application
    Filed: December 27, 2011
    Publication date: July 5, 2012
    Inventors: Hyeon CHO, Eun Mi Kim, Jong Gyu La, Tae Hwan Noh, Jin Sook Kim, Hae Ryong Chung, Moon Yeon Lee, Ji Heon Kim
  • Patent number: 8097200
    Abstract: A method for producing a stretched film comprising supplying a film composed of a thermoplastic resin along a direction D1 that is different from a taking-up direction D2 of a post-stretch film, and obliquely stretching the film while transferring the film with the edges thereof being gripped by gripping devices, to produce the stretched film having an orientation angle ? being within 45±5° with respect to the taking-up direction.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: January 17, 2012
    Assignee: Zeon Corporation
    Inventor: Takeshi Asada
  • Patent number: 8052902
    Abstract: A method of fabricating a polarizing plate includes: providing a polarizing roll film having transmission axes; and cutting the polarizing roll film with a knife having a plurality of openings each having a rectangular shape to form a plurality of polarizing plates, the plurality of openings parallel to the transmission axes.
    Type: Grant
    Filed: November 28, 2007
    Date of Patent: November 8, 2011
    Assignee: LG Display Co., Ltd.
    Inventors: Jin-Kwan Jeong, Bong-Jin Choi
  • Publication number: 20110249223
    Abstract: A method of manufacturing a polarizing plate includes fabricating a base film, dyeing the base film by using iodine, stretching the base film to form a polarizing film, firstly drying the polarizing film at a first temperature, and secondly drying the polarizing film while sequentially increasing a temperature from the first temperature to a second temperature higher than the first temperature. The polarizing plate and a liquid crystal display including the same are manufactured through the above method.
    Type: Application
    Filed: August 5, 2010
    Publication date: October 13, 2011
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Duckjong Suh, Jeonguk Heo, Hee Wook Do, Jung-Hun Lee, Boo-Kan Ki, Min Oh Choi, Sang-Gu Lee
  • Publication number: 20100314784
    Abstract: To obtain a water-resistant polarizing film free from deterioration in dichroic ratio caused by water-resistant treatment, it is critical that adjacent sulfonic acid groups or sulfonate groups in the organic dyes to be used for the polarizing film are spaced at moderate intervals.
    Type: Application
    Filed: January 23, 2009
    Publication date: December 16, 2010
    Applicant: NITTO DENKO CORPORATION
    Inventors: Junzo Miyazaki, Shoichi Matsuda, Kyoko Nishiguchi
  • Publication number: 20100104775
    Abstract: Disclosed is an ultraviolet absorbing polymer which is characterized by being derived from an ethylenically unsaturated monomer having a partial structure represented by Formula (A) below in a molecule, and a monomer represented by Formula (B) below:
    Type: Application
    Filed: March 28, 2008
    Publication date: April 29, 2010
    Inventors: Takayuki Suzuki, Ryohei Iwamoto, Satomi Kawabe, Takatugu Suzuki, Issei Nakahara
  • Patent number: 7651643
    Abstract: A polarizer of the invention comprises a polyvinyl alcohol-based film which is at least dyed with at least iodine and uniaxially stretched, having a single transmittance of 43% or more, a polarizing efficiency of 99.9% or more, and a dichroic ratio of 30 or more, wherein the dichroic ratio is calculated from a parallel transmittance (Tp) and a crossed transmittance (Tc) at a wavelength of 440 nm, and have good hue.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: January 26, 2010
    Assignee: Nitto Denko Corporation
    Inventors: Yuuji Saiki, Hideyuki Usui, Takahisa Konishi, Takemichi Yoshida
  • Patent number: 7524542
    Abstract: The present invention provides a negative C-plate type optical anisotropic film having negative birefringence along the thickness direction. In particular, the present invention provides a film comprising cycloolefin addition polymer, which is prepared by addition polymerizing norbornene-based monomers, a method for preparing the same, and a liquid crystal display comprising the same. The film of the present invention can be used for optical compensation films of a variety of LCD (liquid crystal display) modes because the refractive index alone the thickness direction can be controlled by the kind and amount of functional groups introduced to the cycloolefin addition polymer.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: April 28, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Won-Kook Kim, Sung-Ho Chun, Sung-Cheol Yoon, Tae-Sun Lim, Heon Kim, Jung-Min Lee, Jeong-Su Yu
  • Patent number: 7339736
    Abstract: A light polarizing film and method of making same includes a linear polarizer having a first surface and a second surface and having a polarization direction, an optical retarder comprising a simultaneously biaxially oriented polypropylene film disposed adjacent to the first surface of the linear polarizer and having an axis oriented at an angle with respect to the polarization direction, and an adhesive layer disposed between the first surface of the linear polarizer and the optical retarder and having a minimum adhesion strength of about 25 grams per inch.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: March 4, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Giorgio B. Trapani, Pradnya V. Nagarkar
  • Patent number: 7110177
    Abstract: The present invention provides a polarizing film or a polarizer that has an elastic modulus of at most about 3500 N/mm2 and suppresses occurrence of warping, the polarizing film is obtained by adsorbing a dichroic material in a polyvinyl alcohol-based film 20 ?m in thickness and stretching the tilin. The polarizing film has a transmittance of at least 43% and a polarization degree of at least 98%. A transparent protective layer is laminated on at least one surface of the polarizing film to form a polarizing plate.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: September 19, 2006
    Assignee: Nitto Denko Corporation
    Inventors: Youichirou Sugino, Hisashi Mihara, Kazuhiro Higashio, Seiichi Kusumoto
  • Patent number: 7088511
    Abstract: A light polarizing film and method of making same includes a linear polarizer having a first surface and a second surface and having a polarization direction, an optical retarder comprising a simultaneously biaxially oriented polypropylene film disposed adjacent to the first surface of the linear polarizer and having an axis oriented at an angle with respect to the polarization direction, and an adhesive layer disposed between the first surface of the linear polarizer and the optical retarder and having a minimum adhesion strength of about 25 grams per inch.
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: August 8, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Giorgio B. Trapani, Pradnya V. Nagarkar
  • Patent number: 7045558
    Abstract: A radiation curable composition comprises a heterocyclic acrylate or heterocyclic methacrylate. The composition is curable to make an optical management article such as an optical management coating on a substrate. A method of making an optical management article, comprises forming a radiation curable composition comprising the heterocyclic acrylate or heterocyclic methacrylate on a substrate and curing the composition to form the optical management article.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: May 16, 2006
    Assignee: General Electric Company
    Inventors: Bret Ja Chisholm, James Edward Pickett
  • Patent number: 6888676
    Abstract: A method of producing an antireflection structure for use on a display or a window surface or both in an electronic device, such as a mobile phone. The display can be an LCD with a top polarizer and a bottom polarizer. The antireflection structure is imparted on the top polarizer by a roller embossing process. In particular, the embossing is carried out in the same manufacturing process when the polarizer is produced. The antireflection structure has a plurality of sub-wavelength periodic grooves. The antireflection structure on the window surface can be imparted using an embossing process or an injection molding process.
    Type: Grant
    Filed: March 20, 2003
    Date of Patent: May 3, 2005
    Assignee: Nokia Corporation
    Inventors: Marko Parikka, Kaj Saarinen
  • Patent number: 6833090
    Abstract: The present invention provides a polarizing film having a high polarization degree and high transmittance, a process for producing the polarizing film, and a polarizing plate using the polarizing film, and an optical member. In the process for producing the polarizing film, a polyvinyl alcohol-based film is dry-stretched uniaxially, relaxed in an aqueous solution containing iodine or a dichroic dyestuff, and further stretched in an aqueous solution containing a PVA crosslinking agent. It is preferable that the polyvinyl alcohol-based film has a dry-stretch ratio of at least 2, the film after relaxation has a stretch ratio of at least 1.02, and the total stretch ratio is at most 6.5. It is also preferable that the relaxation rate is at most 10% of the dry-stretch ratio.
    Type: Grant
    Filed: April 22, 2002
    Date of Patent: December 21, 2004
    Assignee: Nitto Denko Corporation
    Inventors: Kazuki Tsuchimoto, Seiji Kondou, Akihiro Nishida
  • Patent number: 6757102
    Abstract: A polarizer comprising a polyvinyl alcohol based film being dyed by iodine and treated with potassium iodide, wherein an element content ratio (K/I) of iodine (I) and potassium (K) is 0.05 through 0.24, show an effect controlling coloring and satisfying high durability under conditions of high temperature.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: June 29, 2004
    Assignee: Nitto Denko Corporation
    Inventors: Akihiro Nishida, Kazuki Tsuchimoto, Seiji Kondo
  • Publication number: 20030197939
    Abstract: The present invention provides a polarizing film having a high polarization degree and high transmittance, a process for producing the polarizing film, and a polarizing plate using the polarizing film, and an optical member. In the process for producing the polarizing film, a polyvinyl alcohol-based film is dry-stretched uniaxially, relaxed in an aqueous solution containing iodine or a dichroic dyestuff, and further stretched in an aqueous solution containing a PVA crossling agent. It is preferable that the polyvinyl alcohol-based film has a dry-stretch ratio of at least 2, the film after relaxation has a stretch ratio of at least 1.02, and the total stretch ratio is at most 6.5. It is also preferable that the relaxation rate is at most 10% of the dry-stretch ratio.
    Type: Application
    Filed: April 22, 2002
    Publication date: October 23, 2003
    Inventors: Kazuki Tsuchimoto, Seiji Kondou, Akihiro Nishida
  • Patent number: 6606136
    Abstract: A polarizing plate comprising a uniaxial stretched polyvinyl alcohol resin film with iodine adsorbed thereto in an oriented state and a protection film bonded to at least one surface of the resin film. The polarizing plate has a single transmittance of about 42.5% or more, a degree of polarization of about 99% or more, and a neutral coefficient Np of 0 to about 4 which is calculated from expression (I), and the polarizing plate also satisfies the relationship represented by expression (II); Np=|{square root over ((Pa*)2+(Pb*)2)}−{square root over ((Qa*)2+(Qb*)2)}|  (I) wherein Pa*, Pb*, Qb*, and Qa* respectively denote a* and b* in a parallel hue and a* and b* in a perpendicular hue in L*a*b* color system; {square root over ((Pa*)2+(Pb*)2)}<4.5  (II). The resultant polarizing plate enables neutral white in the case of white display and neutral black in the case of black display, bright white display, and high-contrast display.
    Type: Grant
    Filed: September 12, 2001
    Date of Patent: August 12, 2003
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Koji Matsumoto, Narutoshi Hayashi
  • Patent number: 6337369
    Abstract: The present invention provides a polarizing film having a dichroic ratio of at least 20 and comprising a polyvinyl alcohol derivative with a polyvinylene structure as obtained from a polyvinyl alcohol material having a degree of polymerization of at least 2000. The polarizing film of the present invention has excellent polarizing properties in the range of the visible ray spectrum, and exhibits excellent durability when left in high-temperature and high-humidity surroundings for a long period of time. The polarizing film of the present invention is useful for a polarizing sheet laminated with a protective film for on-vehicle LCD that is placed in heavy temperature and humidity fluctuations, such as LCD navigation systems, LCD TV, etc.
    Type: Grant
    Filed: October 26, 1998
    Date of Patent: January 8, 2002
    Assignee: Kuraray Co., Ltd.
    Inventor: Takanori Isozaki
  • Patent number: RE44315
    Abstract: The present invention provides a polarizing film or a polarizer that has an elastic modulus of at most about 3500 N/mm2 and suppresses occurrence of warping, the polarizing film is obtained by adsorbing a dichroic material in a polyvinyl alcohol-based film 20 ?m in thickness and stretching the film. The polarizing film has a transmittance of at least 43% and a polarization degree of at least 98%. A transparent protective layer is laminated on at least one surface of the polarizing film to form a polarizing plate.
    Type: Grant
    Filed: July 25, 2012
    Date of Patent: June 25, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Youichirou Sugino, Hisashi Mihara, Kazuhiro Higashio, Seiichi Kusumoto