Halogen Containing Patents (Class 264/1.35)
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Patent number: 10201943Abstract: The present invention relates to a method for manufacturing a polarizing plate, the method comprising the sequential steps of: preparing a polarizing element comprising a polyvinyl alcohol-based polarizer dyed with any one or more of iodine and a dichroic dye; irradiating the polarizing element with light having a specific wavelength selected from a wavelength range of 200 nm to 800 nm; and moistening the polarizing element, and to a polarizing plate manufactured by the method.Type: GrantFiled: September 26, 2014Date of Patent: February 12, 2019Assignee: LG CHEM, LTD.Inventors: Byung Sun Lee, Sung Hyun Nam, Kyun Il Rah
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Patent number: 9310676Abstract: The present invention relates generally to an apparatus for embossing a flexible substrate. More specifically, the present invention relates to an apparatus for embossing a curable composition coated flexible substrate with an optically variable image transferred from an embossing foil, especially belt, or sheet of an optically transparent fluoropolymer. The optically variable image is irradiated through the embossing belt, or sheet with ultraviolet light contemporaneously with the embossing so that the transferred imprint pattern cures, hardens, and retains its shape.Type: GrantFiled: August 9, 2010Date of Patent: April 12, 2016Assignee: BASF SEInventors: Michelle Richert, David R. Boswell, Mark Robert Dicker, Alexander Stuck
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Patent number: 8889043Abstract: A method for casting a styrenic fluoropolymer film on a substrate includes preparing a polymer solution by dissolving the fluoropolymer in a solvent or solvent blend whose Hansen solubility parameters (HSPs. MPa1/2) satisfy the following relations: |SPb?SPp|<5, |SPb?SPs|<4, |SPb(H)?SPp(H)|<7, and 2<|SPb(H)?SPs(H)|<10 wherein SPb, SPp, SPs, are the total Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; SPb(H), SPp(H), and, SPs(H) are the hydrogen-bond Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; wherein the fluoropolymer comprises a moiety of: wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring.Type: GrantFiled: May 1, 2012Date of Patent: November 18, 2014Assignee: Akron Polymer Systems, Inc.Inventors: Bin Wang, Thauming Kuo, Douglas Stephens McWilliams, Frank W. Harris, Ted Calvin Germroth, Jiaokai Jing, Dong Zhang, Xiaoliang Zheng
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Publication number: 20140213727Abstract: A water soluble polyvinyl alcohol copolymer having a diad syndiotacticity of greater than about 60% and less than about 70%. In some embodiments, the water soluble polyvinyl alcohol copolymer is soluble in water at a concentration of at least 1 wt % at a temperature of less than 100° C. In other embodiments, the composition is soluble in water at a concentration of at least 5 wt % at a temperature in the range from about 90° C. to less than 100° C. The high solubility of the high syndiotactic poly vinyl alcohols disclosed herein may provide various advantages as described herein, including ease of processing and decreased use of harmful solvents.Type: ApplicationFiled: January 27, 2014Publication date: July 31, 2014Applicant: SEKISUI SPECIALTY CHEMICALS AMERICA, LLCInventors: Yohei Nishimura, Regan Pollock, Richard Vicari
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Patent number: 8741190Abstract: To obtain a water-resistant polarizing film free from deterioration in dichroic ratio caused by water-resistant treatment, it is critical that adjacent sulfonic acid groups or sulfonate groups in the organic dyes to be used for the polarizing film are spaced at moderate intervals.Type: GrantFiled: June 20, 2013Date of Patent: June 3, 2014Assignee: Nitto Denko CorporationInventors: Junzo Miyazaki, Shoichi Matsuda, Kyoko Nishiguchi
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Publication number: 20130277871Abstract: To obtain a water-resistant polarizing film free from deterioration in dichroic ratio caused by water-resistant treatment, it is critical that adjacent sulfonic acid groups or sulfonate groups in the organic dyes to be used for the polarizing film are spaced at moderate intervals.Type: ApplicationFiled: June 20, 2013Publication date: October 24, 2013Inventors: Junzo Miyazaki, Shoichi Matsuda, Kyoko Nishiguchi
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Patent number: 8491823Abstract: To obtain a water-resistant polarizing film free from deterioration in dichroic ratio caused by water-resistant treatment, it is critical that adjacent sulfonic acid groups or sulfonate groups in the organic dyes to be used for the polarizing film are spaced at moderate intervals.Type: GrantFiled: January 23, 2009Date of Patent: July 23, 2013Assignee: Nitto Denko CorporationInventors: Junzo Miyazaki, Shoichi Matsuda, Kyoko Nishiguchi
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Patent number: 8435432Abstract: Retardation expressibility of a transparent polymer film can be easily controlled by heat treatment of the film at a temperature T (unit, ° C.) satisfying a condition of the following formula (1): Tc?T<Tm0??Formula (1) wherein Tc represents the crystallization temperature (unit, ° C.) of the film before the heat treatment; and Tm0 represents the melting point (unit, ° C.) of the film before the heat treatment.Type: GrantFiled: February 21, 2007Date of Patent: May 7, 2013Assignee: FUJIFILM CorporationInventor: Yasuyuki Sasada
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Patent number: 8414803Abstract: A method for producing a transparent polymer film, comprising heat-treating a polymer film containing a polymer and a plasticizer having a number-average molecular weight of from 500 to 10000 and having a repetitive unit, at a temperature T (unit, ° C.) satisfying the following formula (1): Tc?T<Tm0??(1) wherein Tc means the crystallization temperature of the polymer film and Tm0 means the melting point of the polymer film.Type: GrantFiled: July 29, 2008Date of Patent: April 9, 2013Assignee: FUJIFILM CorporationInventors: Yasuo Mukunoki, Yasuyuki Sasada
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Publication number: 20120199994Abstract: The present invention relates generally to an apparatus for embossing a flexible substrate. More specifically, the present invention relates to an apparatus for embossing a curable composition coated flexible substrate with an optically variable image transferred from an embossing foil, especially belt, or sheet of an optically transparent fluoropolymer. The optically variable image is irradiated through the embossing belt, or sheet with ultra-violet light contemporaneously with the embossing so that the transferred imprint pattern cures, hardens, and retains its shape.Type: ApplicationFiled: August 9, 2010Publication date: August 9, 2012Applicant: BASF SEInventors: Michelle Richert, David R. Boswell, Mark Robert Dicker, Alexander Stuck
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Patent number: 8226860Abstract: A method for controlling positive birefringence in an optical compensation film (positive C-plate) having high positive birefringence throughout the wavelength range 400 nm<?<800 nm is provided. The method includes selecting polymers with optically anisotropic subunits (OASUs) that exhibit the buttressing effect, wherein the OASUs may be disks, mesogens or aromatic rings substituted with birefringence enhancing substituents. The method further includes processing the polymer by solution casting to yield a polymer film with high birefringence without the need for stretching, photopolymerization, or other processes. These optical compensation films may be used in LCDs, particularly IPS-LCDs.Type: GrantFiled: March 29, 2007Date of Patent: July 24, 2012Assignee: Akron Polymer SystemsInventors: Xiaoliang Joe Zheng, Frank W. Harris, Ted Calvin Germroth, Jiaokai Alexander Jing, Dong Zhang, Thauming Kuo, Brian Michael King
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Publication number: 20120170117Abstract: A polarizer plate includes a polarizer that includes polyvinyl alcohol and a dichroic material, the polarizer having a degree of orientation of 15 or more as represented by Equation 1: Degree of orientation=RD/RPVA×100, where RPVA represents a phase difference of the polyvinyl alcohol and RD represents a phase difference of the dichroic material.Type: ApplicationFiled: December 27, 2011Publication date: July 5, 2012Inventors: Hyeon CHO, Eun Mi Kim, Jong Gyu La, Tae Hwan Noh, Jin Sook Kim, Hae Ryong Chung, Moon Yeon Lee, Ji Heon Kim
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Patent number: 8097200Abstract: A method for producing a stretched film comprising supplying a film composed of a thermoplastic resin along a direction D1 that is different from a taking-up direction D2 of a post-stretch film, and obliquely stretching the film while transferring the film with the edges thereof being gripped by gripping devices, to produce the stretched film having an orientation angle ? being within 45±5° with respect to the taking-up direction.Type: GrantFiled: September 11, 2008Date of Patent: January 17, 2012Assignee: Zeon CorporationInventor: Takeshi Asada
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Patent number: 8052902Abstract: A method of fabricating a polarizing plate includes: providing a polarizing roll film having transmission axes; and cutting the polarizing roll film with a knife having a plurality of openings each having a rectangular shape to form a plurality of polarizing plates, the plurality of openings parallel to the transmission axes.Type: GrantFiled: November 28, 2007Date of Patent: November 8, 2011Assignee: LG Display Co., Ltd.Inventors: Jin-Kwan Jeong, Bong-Jin Choi
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Publication number: 20110249223Abstract: A method of manufacturing a polarizing plate includes fabricating a base film, dyeing the base film by using iodine, stretching the base film to form a polarizing film, firstly drying the polarizing film at a first temperature, and secondly drying the polarizing film while sequentially increasing a temperature from the first temperature to a second temperature higher than the first temperature. The polarizing plate and a liquid crystal display including the same are manufactured through the above method.Type: ApplicationFiled: August 5, 2010Publication date: October 13, 2011Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Duckjong Suh, Jeonguk Heo, Hee Wook Do, Jung-Hun Lee, Boo-Kan Ki, Min Oh Choi, Sang-Gu Lee
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Publication number: 20100314784Abstract: To obtain a water-resistant polarizing film free from deterioration in dichroic ratio caused by water-resistant treatment, it is critical that adjacent sulfonic acid groups or sulfonate groups in the organic dyes to be used for the polarizing film are spaced at moderate intervals.Type: ApplicationFiled: January 23, 2009Publication date: December 16, 2010Applicant: NITTO DENKO CORPORATIONInventors: Junzo Miyazaki, Shoichi Matsuda, Kyoko Nishiguchi
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Publication number: 20100104775Abstract: Disclosed is an ultraviolet absorbing polymer which is characterized by being derived from an ethylenically unsaturated monomer having a partial structure represented by Formula (A) below in a molecule, and a monomer represented by Formula (B) below:Type: ApplicationFiled: March 28, 2008Publication date: April 29, 2010Inventors: Takayuki Suzuki, Ryohei Iwamoto, Satomi Kawabe, Takatugu Suzuki, Issei Nakahara
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Patent number: 7651643Abstract: A polarizer of the invention comprises a polyvinyl alcohol-based film which is at least dyed with at least iodine and uniaxially stretched, having a single transmittance of 43% or more, a polarizing efficiency of 99.9% or more, and a dichroic ratio of 30 or more, wherein the dichroic ratio is calculated from a parallel transmittance (Tp) and a crossed transmittance (Tc) at a wavelength of 440 nm, and have good hue.Type: GrantFiled: April 19, 2004Date of Patent: January 26, 2010Assignee: Nitto Denko CorporationInventors: Yuuji Saiki, Hideyuki Usui, Takahisa Konishi, Takemichi Yoshida
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Patent number: 7524542Abstract: The present invention provides a negative C-plate type optical anisotropic film having negative birefringence along the thickness direction. In particular, the present invention provides a film comprising cycloolefin addition polymer, which is prepared by addition polymerizing norbornene-based monomers, a method for preparing the same, and a liquid crystal display comprising the same. The film of the present invention can be used for optical compensation films of a variety of LCD (liquid crystal display) modes because the refractive index alone the thickness direction can be controlled by the kind and amount of functional groups introduced to the cycloolefin addition polymer.Type: GrantFiled: November 19, 2003Date of Patent: April 28, 2009Assignee: LG Chem, Ltd.Inventors: Won-Kook Kim, Sung-Ho Chun, Sung-Cheol Yoon, Tae-Sun Lim, Heon Kim, Jung-Min Lee, Jeong-Su Yu
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Patent number: 7339736Abstract: A light polarizing film and method of making same includes a linear polarizer having a first surface and a second surface and having a polarization direction, an optical retarder comprising a simultaneously biaxially oriented polypropylene film disposed adjacent to the first surface of the linear polarizer and having an axis oriented at an angle with respect to the polarization direction, and an adhesive layer disposed between the first surface of the linear polarizer and the optical retarder and having a minimum adhesion strength of about 25 grams per inch.Type: GrantFiled: March 28, 2006Date of Patent: March 4, 2008Assignee: 3M Innovative Properties CompanyInventors: Giorgio B. Trapani, Pradnya V. Nagarkar
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Patent number: 7110177Abstract: The present invention provides a polarizing film or a polarizer that has an elastic modulus of at most about 3500 N/mm2 and suppresses occurrence of warping, the polarizing film is obtained by adsorbing a dichroic material in a polyvinyl alcohol-based film 20 ?m in thickness and stretching the tilin. The polarizing film has a transmittance of at least 43% and a polarization degree of at least 98%. A transparent protective layer is laminated on at least one surface of the polarizing film to form a polarizing plate.Type: GrantFiled: January 21, 2003Date of Patent: September 19, 2006Assignee: Nitto Denko CorporationInventors: Youichirou Sugino, Hisashi Mihara, Kazuhiro Higashio, Seiichi Kusumoto
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Patent number: 7088511Abstract: A light polarizing film and method of making same includes a linear polarizer having a first surface and a second surface and having a polarization direction, an optical retarder comprising a simultaneously biaxially oriented polypropylene film disposed adjacent to the first surface of the linear polarizer and having an axis oriented at an angle with respect to the polarization direction, and an adhesive layer disposed between the first surface of the linear polarizer and the optical retarder and having a minimum adhesion strength of about 25 grams per inch.Type: GrantFiled: February 12, 2003Date of Patent: August 8, 2006Assignee: 3M Innovative Properties CompanyInventors: Giorgio B. Trapani, Pradnya V. Nagarkar
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Patent number: 7045558Abstract: A radiation curable composition comprises a heterocyclic acrylate or heterocyclic methacrylate. The composition is curable to make an optical management article such as an optical management coating on a substrate. A method of making an optical management article, comprises forming a radiation curable composition comprising the heterocyclic acrylate or heterocyclic methacrylate on a substrate and curing the composition to form the optical management article.Type: GrantFiled: August 29, 2003Date of Patent: May 16, 2006Assignee: General Electric CompanyInventors: Bret Ja Chisholm, James Edward Pickett
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Patent number: 6888676Abstract: A method of producing an antireflection structure for use on a display or a window surface or both in an electronic device, such as a mobile phone. The display can be an LCD with a top polarizer and a bottom polarizer. The antireflection structure is imparted on the top polarizer by a roller embossing process. In particular, the embossing is carried out in the same manufacturing process when the polarizer is produced. The antireflection structure has a plurality of sub-wavelength periodic grooves. The antireflection structure on the window surface can be imparted using an embossing process or an injection molding process.Type: GrantFiled: March 20, 2003Date of Patent: May 3, 2005Assignee: Nokia CorporationInventors: Marko Parikka, Kaj Saarinen
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Patent number: 6833090Abstract: The present invention provides a polarizing film having a high polarization degree and high transmittance, a process for producing the polarizing film, and a polarizing plate using the polarizing film, and an optical member. In the process for producing the polarizing film, a polyvinyl alcohol-based film is dry-stretched uniaxially, relaxed in an aqueous solution containing iodine or a dichroic dyestuff, and further stretched in an aqueous solution containing a PVA crosslinking agent. It is preferable that the polyvinyl alcohol-based film has a dry-stretch ratio of at least 2, the film after relaxation has a stretch ratio of at least 1.02, and the total stretch ratio is at most 6.5. It is also preferable that the relaxation rate is at most 10% of the dry-stretch ratio.Type: GrantFiled: April 22, 2002Date of Patent: December 21, 2004Assignee: Nitto Denko CorporationInventors: Kazuki Tsuchimoto, Seiji Kondou, Akihiro Nishida
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Patent number: 6757102Abstract: A polarizer comprising a polyvinyl alcohol based film being dyed by iodine and treated with potassium iodide, wherein an element content ratio (K/I) of iodine (I) and potassium (K) is 0.05 through 0.24, show an effect controlling coloring and satisfying high durability under conditions of high temperature.Type: GrantFiled: January 31, 2003Date of Patent: June 29, 2004Assignee: Nitto Denko CorporationInventors: Akihiro Nishida, Kazuki Tsuchimoto, Seiji Kondo
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Publication number: 20030197939Abstract: The present invention provides a polarizing film having a high polarization degree and high transmittance, a process for producing the polarizing film, and a polarizing plate using the polarizing film, and an optical member. In the process for producing the polarizing film, a polyvinyl alcohol-based film is dry-stretched uniaxially, relaxed in an aqueous solution containing iodine or a dichroic dyestuff, and further stretched in an aqueous solution containing a PVA crossling agent. It is preferable that the polyvinyl alcohol-based film has a dry-stretch ratio of at least 2, the film after relaxation has a stretch ratio of at least 1.02, and the total stretch ratio is at most 6.5. It is also preferable that the relaxation rate is at most 10% of the dry-stretch ratio.Type: ApplicationFiled: April 22, 2002Publication date: October 23, 2003Inventors: Kazuki Tsuchimoto, Seiji Kondou, Akihiro Nishida
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Patent number: 6606136Abstract: A polarizing plate comprising a uniaxial stretched polyvinyl alcohol resin film with iodine adsorbed thereto in an oriented state and a protection film bonded to at least one surface of the resin film. The polarizing plate has a single transmittance of about 42.5% or more, a degree of polarization of about 99% or more, and a neutral coefficient Np of 0 to about 4 which is calculated from expression (I), and the polarizing plate also satisfies the relationship represented by expression (II); Np=|{square root over ((Pa*)2+(Pb*)2)}−{square root over ((Qa*)2+(Qb*)2)}| (I) wherein Pa*, Pb*, Qb*, and Qa* respectively denote a* and b* in a parallel hue and a* and b* in a perpendicular hue in L*a*b* color system; {square root over ((Pa*)2+(Pb*)2)}<4.5 (II). The resultant polarizing plate enables neutral white in the case of white display and neutral black in the case of black display, bright white display, and high-contrast display.Type: GrantFiled: September 12, 2001Date of Patent: August 12, 2003Assignee: Sumitomo Chemical Company, LimitedInventors: Koji Matsumoto, Narutoshi Hayashi
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Patent number: 6337369Abstract: The present invention provides a polarizing film having a dichroic ratio of at least 20 and comprising a polyvinyl alcohol derivative with a polyvinylene structure as obtained from a polyvinyl alcohol material having a degree of polymerization of at least 2000. The polarizing film of the present invention has excellent polarizing properties in the range of the visible ray spectrum, and exhibits excellent durability when left in high-temperature and high-humidity surroundings for a long period of time. The polarizing film of the present invention is useful for a polarizing sheet laminated with a protective film for on-vehicle LCD that is placed in heavy temperature and humidity fluctuations, such as LCD navigation systems, LCD TV, etc.Type: GrantFiled: October 26, 1998Date of Patent: January 8, 2002Assignee: Kuraray Co., Ltd.Inventor: Takanori Isozaki
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Patent number: RE44315Abstract: The present invention provides a polarizing film or a polarizer that has an elastic modulus of at most about 3500 N/mm2 and suppresses occurrence of warping, the polarizing film is obtained by adsorbing a dichroic material in a polyvinyl alcohol-based film 20 ?m in thickness and stretching the film. The polarizing film has a transmittance of at least 43% and a polarization degree of at least 98%. A transparent protective layer is laminated on at least one surface of the polarizing film to form a polarizing plate.Type: GrantFiled: July 25, 2012Date of Patent: June 25, 2013Assignee: Nitto Denko CorporationInventors: Youichirou Sugino, Hisashi Mihara, Kazuhiro Higashio, Seiichi Kusumoto