Biaxial Or Transverse To Travel Direction Patents (Class 264/290.2)
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Patent number: 6884517Abstract: The present invention relates to a high-whiteness, biaxially oriented polyester film with at least a base layer made from polyester. The base layer of the polyester film of the invention also comprises from 2 to 60% by weight of a cycloolefin copolymer (COC), from 0.1 to 25% by weight of a white pigment, and, if desired, from 0 to 5% by weight of an optical brightener, based on the weight of the base layer. The glass transition temperature of the COC here is to be within the range from 70 to 270° C. The film is particularly suitable for packing foods or other consumable items which are sensitive to light and/or to air, or for use in industry, e.g. for producing hot-stamping foils or as a label film, or for image-recording papers, printed sheets, or magnetic recording cards, or for processing on high-speed machinery for winding, metallizing, printing or laminating.Type: GrantFiled: February 23, 2001Date of Patent: April 26, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Gottfried Hilkert, Bart Janssens
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Patent number: 6881470Abstract: Biaxially oriented, co-extruded polyester films comprising a base layer consisting of at least 90 wt. % thermoplastic polyester, preferably polyethylene terephthalate (PET), at least one sealable outer layer and a second non-sealable outer layer and, optionally, other intermediate layers, in addition to at least one flame-retardant agent, preferably organic phosphorous compounds. The inventive films are characterized by low inflammability, no embrittlement when subjected to thermal stress and a surface which is devoid of troublesome opacity, and are suitable for a multiplicity of uses both indoors and outside. The outer layers contain anti-blocking agents such as silicic acid having a particle diameter of preferably less than 50 nm and/or more than 2 ?m. Preferably, the sealable outer layer consists of a copolyester which is made of ethylene terephthalate and ethylene isophthalate units.Type: GrantFiled: January 10, 2001Date of Patent: April 19, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Andreas Stopp, Guenther Crass, Herbert Peiffer
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Patent number: 6881473Abstract: A light diffusing film including a film including crystalline polymer compound C laminated to at least one face of an internal light-diffusing film including an islands-in-a-sea structure including a sea component of thermoplastic resin A and an islands component of thermoplastic resin B, wherein thermoplastic resins A and B have different refractive indexes.Type: GrantFiled: September 6, 2001Date of Patent: April 19, 2005Assignee: Toray Industries, Inc.Inventors: Hiromitsu Takahashi, Motoyuki Suzuki
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Patent number: 6872458Abstract: A method of making a multilayer film is provided, including the steps of forming a core layer of a polypropylene film, monoaxially orienting the core layer in a first direction, and providing at least one multilayer cap layer to at least one side of the core layer to provide a multilayer film. The cap layer includes a non-crystallizable, amorphous polyester layer having a sufficient proportion of a non-crystallizable, amorphous polyester to render the amorphous polyester layer non-crystallizable and a first tie layer interposed between the polyester layer and the core layer, the first tie layer including an adhesive. The multilayer film is then oriented in a second direction transverse to the first direction.Type: GrantFiled: February 14, 2002Date of Patent: March 29, 2005Assignee: Applied Extrusion Technologies, Inc.Inventors: David Rudd, Brenda Ruf
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Patent number: 6872460Abstract: The invention relates to biaxially oriented, co-extruded polyester films. Said films comprise a base layer which consists of at least 70% by weight of a thermoplastic polyester, preferably polyethylene terephthalate (PET) with a diethylene glycol and/or polyethylene glycol content greater than 1.3% by weight and have at least one matt outer layer and optionally additional intermediate layers. The films also contain at least one UV-absorber, preferably hydroxy benzotriazoles and triazines. The films are characterized by high UV-stability, no embrittlement after exposure to temperature, a matt surface devoid of unwanted clouding and excellent thermoforming properties and are, together with the molded bodies produced therefrom, suitable for numerous interior and exterior applications.Type: GrantFiled: January 10, 2001Date of Patent: March 29, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Guenther Crass
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Patent number: 6866562Abstract: A process for finishing a metal surface comprises subjecting the surface to successive grit blasting passes including a first series of successive blasting passes using an abrasive grit of a first diameter range applied with a blasting nozzle air pressure in a first range, and a second series of successive blasting passes using an abrasive grit of a second diameter range smaller than the first diameter range, applied with a blasting nozzle air pressure in a second range lower than the first range. Thereafter a third series of successive blasting passes, using glass grit of a third diameter range smaller than the second diameter range, is applied with a blasting nozzle air pressure in a third range lower than the first range.Type: GrantFiled: August 10, 2001Date of Patent: March 15, 2005Assignee: Megara (Australia) PTY LTDInventor: Mario Girolamo
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Patent number: 6866920Abstract: The invention relates to a transparent, biaxially oriented polyester film with a base layer B which is composed of at least 80% by weight of a thermoplastic polyester, and with at least one outer layer A. Another polymeric layer made from a copolymer crosslinked using an acrylic and/or methacrylic compound, has been applied to that side of the film opposite to the outer layer A. The film has low oxygen transmission and exhibits very good adhesion between the respective layers. The coated film moveover has low coefficient of friction, excellent windability, and excellent antistatic performance. It is particularly suitable for packaging purposes, specifically for packaging foodstuffs or other consumable items. The invention further relates to a process for the production of the film.Type: GrantFiled: April 5, 2002Date of Patent: March 15, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Bart Janssens, Herbert Peiffer
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Patent number: 6863952Abstract: The invention relates to a multi-layered semi-finished product with at least one first and one second film layer. The semi-finished product has a velour-type structure on the outer surface of the first film layer facing away from the second film layer and the second layer has a filler material. The first and second film layers are permeable. A first proportion of a filler material in the first film layer is smaller than a second proportion of a filler in the second film layer.Type: GrantFiled: November 3, 2000Date of Patent: March 8, 2005Inventor: Werner Wagner
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Patent number: 6863954Abstract: Biaxially oriented, coextruded polyester films with a base layer at least 90% by weight of which is composed of a thermoplastic polyester, preferably polyethylene terephthalate (PET), and with at least one sealable outer layer and a second nonsealable outer layer and, if desired, with other intermediate layers, and comprising at least one UV absorber, preferably hydroxybenzotriazoles and triazines, have high UV resistance, do not embrittle when exposed to high temperatures, have a surface without undesirable haze and are suitable for numerous indoor and outdoor applications. The outer layers comprise antiblocking agents, such as silica with an average particle diameter preferably below 50 nm and/or above 2 ?m, and the sealable outer layer is preferably composed of a copolyester which has been built up from ethylene terephthalate units and ethylene isophthalate units.Type: GrantFiled: May 5, 2003Date of Patent: March 8, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Guenther Crass, Ulrich Kern, Ursula Murschall, Andreas Stopp
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Patent number: 6855435Abstract: A transparent film whose thickness is in the range from 1 to 500 ?m and which comprises, as principal constituent, a crystallizable thermoplastic, wherein the film comprises at least one UV stabilizer as light stabilizer and at least one optical brightener, and to the use of the film, and also to a process for its production.Type: GrantFiled: May 2, 2003Date of Patent: February 15, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Guenther Crass, Guenter Bewer, Klaus Oberlaender
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Patent number: 6855395Abstract: The invention relates to a biaxially oriented, sealable polyester film with at least one base layer (B), with a sealable outer layer (A) and with another, non-sealable outer layer (C). The sealable outer layer (A) has a minimum sealing temperature (fin) of not more than 110° C. and a seal seam strength (fin) of at least 1.3 N/15 mm of film width. The two outer layers (A) and (C) are characterized by particular features. The film of the invention is particularly suitable for use in flexible packaging, and particularly and specifically for use on systems which operate in a vacuum.Type: GrantFiled: July 1, 2003Date of Patent: February 15, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Bart Janssens, Herbert Peiffer, Gottfried Hilkert
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Patent number: 6852387Abstract: The invention relates to a one-sided mat, sealable, biaxially oriented polyester film with at least a base layer (B), a sealable cover layer (A) and an additional mat cover layer (C), where the sealable cover layer (A) has a minimum sealing temperature of 120° C. maximum and a seal-seam strength of at least 1.3 N/15 mm film width and where the topographies of the sealable cover layer (A) and the mat shimmering cover layer (C) have certain characteristics. The film according to this invention is suitable for the use as flexible packaging material, especially when used in connection with fast-running packaging machines.Type: GrantFiled: December 13, 2001Date of Patent: February 8, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Stefan Bartsch, Gottfried Hilkert
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Patent number: 6852223Abstract: The present invention relates to an asymmetric porous polytetrafluoroethylene membrane comprising a dense skin layer and a continuously foamed porous layer, (1) the dense skin layer having a surface roughness Ra of 20 to 165 nm; (2) the dense skin layer having a contact angle for water of 120 to 135°; (3) the porous layer having a maximum pore diameter of 0.03 to 1.0 ?m; and (4) the membrane having a total porosity of 20 to 70%. The asymmetric porous PTFE membrane has an ability to separate each liquid component from a liquid-liquid homogeneous mixture in addition to known properties such as water permeability resistance, gas permeability, sealing property and electric property, wherein change of these properties over time is small.Type: GrantFiled: October 28, 2002Date of Patent: February 8, 2005Assignee: Yeu Ming Tai Chemical Industrial Co., Ltd.Inventors: James Huang, William Chou, David Chou, Juin-Yih Lai, Kueir-Rarn Lee, Da-Ming Wang, Ruoh-Chyu Ruaan, Tian-Tsair Wu
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Patent number: 6852270Abstract: A drawn film production method including steps of drawing a crystalline thermoplastic resin film in the TD direction is characterized in that the orientation coefficient of the c-axis of the crystal of the thermoplastic resin in the film to the MD direction of the film is 0.8 or higher.Type: GrantFiled: March 11, 2002Date of Patent: February 8, 2005Assignee: Sumitomo Chemical Company, LimitedInventors: Atsuhiro Takata, Ryuma Kuroda, Satoshi Hanada, Takeshi Yamada
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Patent number: 6841222Abstract: The invention relates to a white, sealable, flame-retardant coextruded, biaxially oriented polyester film composed of at least one base layer B and of outer layers A and B applied to the two sides of this base layer. The film also comprises at least one flame retardant and one white pigment. The invention also includes the use of the film and a process for its production.Type: GrantFiled: February 7, 2001Date of Patent: January 11, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Klaus Oberlaender, Guenther Crass, Ulrich Kern, Herbert Peiffer
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Patent number: 6835461Abstract: The object of this invention is to provide a biaxially oriented polyester film suitable as a base film for high density magnetic recording media, small in track deviation and excellent in traveling durability and preservability, and to provide a production method thereof. The object of this invention can be achieved by a biaxially oriented polyester film, characterized in that the dimensional change rate (A) in the transverse direction of the film is in a range of −0.3 to 0% when the film is allowed to stand at 49° C. and 90% RH for 72 hours, while being loaded with 32 MPa in the machine direction.Type: GrantFiled: January 14, 2003Date of Patent: December 28, 2004Assignee: Toray Industries, Inc.Inventors: Hikaru Yamagata, Masaaki Kotoura, Hirofumi Hosokawa, Tetsuya Tsunekawa
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Publication number: 20040241407Abstract: A method of making a polyolefin film in accordance with this invention includes the steps of: blending a propylene block copolymer with a beta nucleating agent; extruding a film layer from the blend and providing a total area draw ratio in excess of 20, where at least one part of the stretching occurs at <120° C., for forming the film with a density no greater than 0.40 g/cm3 and a thickness greater than 160 gauge.Type: ApplicationFiled: April 28, 2004Publication date: December 2, 2004Applicant: Applied Extrusion Technologies, Inc.Inventors: Leo M. Landoll, Kelan Wieloch
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Patent number: 6824680Abstract: The invention is directed broadly to microporous films prepared from immiscible blends of at least two components, preferably polymers, which are produced via melt processing, a film formed therefrom, for example by extrusion and post-film-forming treatments comprising uniaxial or biaxial cold-stretching and hot-stretching. The films have a three-dimensional reticulated or interconnected network of microcracks or crazing throughout the film, extending from one surface of the film to the other, providing a stable porosity and pore size useful for a variety of filtration and other applications.Type: GrantFiled: May 7, 2001Date of Patent: November 30, 2004Assignee: New Jersey Institute of TechnologyInventors: Chaiya Chandavasu, Marino Xanthos, Kamalesh K. Sirkar, Costas Gogos
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Patent number: 6824885Abstract: Recycleable releasing polyethylene terephthalate film coated with a coating of polyethylene emulsion, polyurethane dispersion, or a mixture of the two, with an acrylic or polyester cobinder, which film is uniaxially oriented and thereafter coated with the coating and oriented in a direction transverse to the direction of the film's uniaxial orientation to generate a biaxially oriented film having a uniaxially oriented coating and a method of making the film.Type: GrantFiled: May 7, 2002Date of Patent: November 30, 2004Assignee: Toray Plastics (America), Inc.Inventors: John Fitch, Steven J. Sargeant
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Patent number: 6824878Abstract: A thermoplastic film comprising a core layer comprising a polyolefin wherein the core layer comprises the interior of the film; a first transition layer comprising a polyolefin and a silicone additive, wherein the first transition layer is exterior to the core layer; and a first skin layer comprising a polyolefin wherein the first skin layer is exterior to the first transition layer and the core layer.Type: GrantFiled: June 12, 2001Date of Patent: November 30, 2004Assignee: ExxonMobil Oil CorporationInventors: Robert A. Migliorini, Karen A. Sheppard
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Patent number: 6815048Abstract: Polymeric films including a layer of propylene polymer resin having microvoids therein, the microvoids having been formed by stretching a web containing the beta-form of polypropylene, have shown low static cling when being unwound from rolls in labelling operations and also during destacking of pre-formed labels. The invention provides labels formed from such films.Type: GrantFiled: August 6, 2002Date of Patent: November 9, 2004Assignee: Hoechst Trespaphan GmbHInventors: Paul Malcolm Mackenzie Davidson, Rebecca Karen Govier, Helen Ann Biddiscombe, Marc Fritz Manfred Ott
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Patent number: 6815079Abstract: The invention relates to an opaque biaxially oriented film made of at least one layer that contains COC. This layer contains a cycloolefin copolymer (COC) in a concentration of 0.5 to 30 wt. % with regard to this layer and contains a polymer made from aliphatic hydroxycarboxylic acid units.Type: GrantFiled: March 29, 2004Date of Patent: November 9, 2004Assignee: Treofan Germany GmbH & Co. KGInventors: Sonja Rosenbaum, Petra Hade, Detlef D. Busch, Karl-Heinz Kochem
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Patent number: 6814914Abstract: A manufacturing method of a cellulose ester film satisfying the relationships, Nx>Ny>Nz, and 0.8≦Rt/R0≦3.5, the method comprising casting a cellulose ester dope containing a solvent of a good solvent and a poor solvent on a support to form a web; peeling the web from the support; transporting the peeled web (step D0); holding the edges in the transverse direction of the web (step A); stretching the resulting web in the transverse direction while applying a tension; reducing the tension in the transverse direction of the web; and drying the stretched web, wherein the residual solvent content of the web is 5 to 90% by weight at the beginning in the step A, and the residual poor solvent content in the residual solvent content of the web is from 15 to 95% by weight at the terminal point in the Step D0.Type: GrantFiled: May 23, 2002Date of Patent: November 9, 2004Assignee: Konica CorporationInventors: Koji Tasaka, Hiroki Umeda, Noriyasu Kuzuhara, Takatoshi Yajima
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Patent number: 6797359Abstract: The invention relates to a metalized or ceramic-coated, biaxially oriented, sealable polyester film with at least one base layer (B), with a sealable outer layer (A), and with a further non-sealable outer layer (C). The sealable outer layer (A) has a minimum sealing temperature (fin) of not more than 110° C. and a seal seam strength (fin) of at least 1.3 N/15 mm of film width. The two outer layers (A) and (C) are characterized by particular features. The film of the invention is particularly suitable for use in flexible packaging, and particularly and specifically for use on systems which operate in a vacuum.Type: GrantFiled: July 1, 2003Date of Patent: September 28, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Bart Janssens, Herbert Peiffer, Stefan Bartsch
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Patent number: 6797801Abstract: An oriented polyimide film of high strength and a production process therefor. The process basically comprises stretching a gelled film and then imidating the film. The gelled film is formed by introducing a polyamic acid solution into a condensation agent solution. The gelled film is swollen with a solvent at the time of stretching.Type: GrantFiled: October 17, 2002Date of Patent: September 28, 2004Assignee: Teijin LimitedInventors: Jiro Sadanobu, Rei Nishio, Susumu Honda, Tsutomu Nakamura
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Patent number: 6797225Abstract: A process for producing a polyester sheet by dropping a molten polyester sheet extruded from an orifice-form nozzle on a cooling roll having the grooves of a large number of micro-cracks formed on the surface, closely adhering it to the cooling roll and solidifying it on the cooling roll, wherein the surface temperature (T, ° C.) of the molten polyester sheet 10 mm below the orifice-form nozzle is maintained at a temperature which satisfies the following expression (1): (Tc+20)° C.≦T≦(Tm+40)° C. (1) wherein Tc and Tm are the falling temperature crystallization temperature (° C.) and melting point (° C.) of the polyester, respectively and T is as defined hereinabove, and the surface temperature of the cooling roll when it contacts the molten polyester sheet is controlled to a range of 5 to 100° C.Type: GrantFiled: February 21, 2002Date of Patent: September 28, 2004Assignee: Teijin LimitedInventors: Norio Takagi, Shozo Nitta, Yo Goto
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Patent number: 6797358Abstract: The invention concerns a unilaterally mat, sealable, UV-stabilized and flame-resistant, sealable, co-extruded, biaxially oriented polyester film comprising at least one base layer (B) and a sealable top coating (A) applied to both sides of said base layer, in addition to a mat covering (C). The film also contains at least one UV stabilizer as a light stabilizer. The invention further concerns a method for the production of said film and the use thereof.Type: GrantFiled: July 26, 2002Date of Patent: September 28, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Herbert Peiffer, Hans Mahl
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Patent number: 6794051Abstract: Transparent, multilayer, biaxially oriented polyester films having a) a base layer B composed of at least 50% by weight of a thermoplastic polyester and from 0 to 30% by weight of a cycloolefin copolymer and b) an outer layer composed of from 20 to 100% by weight of a cycloolefin copolymer, the glass transition temperature of the cycloolefin copolymers being less than 120° C., possess very good water vapor barrier properties and effective adhesion between the layers. These films are especially suitable for packaging foods and other consumables.Type: GrantFiled: May 20, 2003Date of Patent: September 21, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Gottfried Hilkert
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Patent number: 6794021Abstract: A thermoplastic multi-layer film for forming hermetic seals on packages comprising layer A comprising polyethylene, layer B comprising polypropylene, layer C comprising a copolymer, and an adhesion promoting coating applied to layer C.Type: GrantFiled: February 20, 2002Date of Patent: September 21, 2004Assignee: Exxon Mobil Oil CorporationInventor: Michael J. Bader
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Patent number: 6794050Abstract: Transparent, biaxially oriented polyester films having a base layer composed of at least 5% by weight of a thermoplastic polyester and from 10 to 95% by weight of a cycloolefin copolymer having a glass transition temperature of less than 120° C., possess very good water vapor barrier properties and low haze at the same time. These films are especially suitable for packaging foods and other consumables.Type: GrantFiled: May 20, 2003Date of Patent: September 21, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Gottfried Hilkert
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Patent number: 6787218Abstract: The invention relates to a transparent, biaxially oriented polyester film with a base layer B, at least 80% by weight of which is composed of a thermoplastic polyester, and with at least one outer layer A. The outer layer A is composed of a copolymer or a mixture of polymers/copolymers which contains ethylene 2,6-naphthalate units in a range of from 90 to 98% by weight and up to 10% by weight of ethylene terephthalate units, and/or units derived from cycloaliphatic or aromatic diols and/or dicarboxylic acids. Its thickness is more than 0.7 &mgr;m and makes up less than 25% by weight of the total film and the Tg2 value of the polyester film is above the Tg2 value of the base layer, but below the Tg2 value of the polyester for the outer layer. The transparent film has low permeability to atmospheric oxygen and exhibits very good adhesion between the individual layers. It is particularly suitable for packaging purposes, specifically for packaging foods or other consumable items.Type: GrantFiled: July 20, 2001Date of Patent: September 7, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Gottfried Hilkert, Richard Lee Davis
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Patent number: 6787219Abstract: A transparent, biaxially oriented polyester film is disclosed, with a base layer B which comprises at least 80% by weight of thermoplastic polyester, and with at least one intermediate layer Z, and with at least one outer layer A. The outer layer A is composed of a polymer or of a mixture of polymers which contains at least 85% by weight of ethylene 2,6-naphthalate units and up to 15% by weight of ethylene terephthalate units, and/or up to 15% by weight of units derived from cycloaliphatic or aromatic diols and/or dicarboxylic acids, and the intermediate layer Z is composed of a mixture of polymers which contains at least 3% by weight of ethylene 2,6-naphthalate units and up to 97% by weight of ethylene terephthalate units, and/or up to 97% by weight of units derived from cycloaliphatic or aromatic diols and/or dicarboxylic acids. The Tg2 value of the polyester film is above the Tg2 value of the base layer B, but below the Tg2 value of the outer layer A.Type: GrantFiled: August 6, 2001Date of Patent: September 7, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Gottfried Hilkert
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Patent number: 6780371Abstract: There is disclosed a process for inline producing a biaxially oriented releasing film by consecutively orienting a non oriented film (polyethylene terephthalate or polypropylene) in the machine or transverse direction one by one which comprises coating at least one side of a film in a state prior to biaxial orientation with an addition reaction type silicone based releasing agent (e.g. solvent type), preferably incorporated with a photosensitizer; biaxially orienting the film; thereafter heat annealing the same; and subsequently performing ultraviolet ray irradiation. The process enables easy production of the releasing film which is excellent in releasability, non-migration property of silicone, and productivity, and which is well suited for use in the production of pressure sensitive adhesive labels and tapes, ceramic green sheets, synthetic leather, etc.Type: GrantFiled: July 3, 2001Date of Patent: August 24, 2004Assignee: Lintec CorporationInventors: Tomishi Shibano, Toru Nakamura
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Publication number: 20040155372Abstract: A process for making an optical film includes stretching a polyolefin film in a first direction and stretching the polyolefin film in a second direction different than the first direction forming a biaxially stretched polyolefin film. At least a portion of the stretching of the polyolefin film in the second direction occurs simultaneous with the stretching of the polyolefin film in the first direction. The biaxially stretched polyolefin film has a length and a width and substantially non-absorbing and non-scattering for at least one polarization state of visible light. The biaxially stretched polyolefin film has x, y, and z orthogonal indices of refraction where at least two of the orthogonal indices of refraction are not equal, an in-plane retardance being 100 nm or less and an out-of-plane retardance being 50 nm or greater.Type: ApplicationFiled: February 12, 2003Publication date: August 12, 2004Inventors: Richard C. Allen, Matthew B. Johnson, Fred J. Roska, Steven J. Rhyner, William W. Merrill, Joan M. Strobel, Kevin M. Hamer, John M. Klaeser, Sebastian F. Zehentmaier
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Patent number: 6770356Abstract: The present invention relates to an intermediate web comprising of high glass transition polymer fibers. The fibers are spun at low to moderate speeds and have a relative crystallinity of from 10% to 75% of the maximum achievable crystallinity. The intermediate web is a low crystallinity web that exhibits shrinkage of more than 30% and elongation to break of more than 80% at high strain rates. This web can be heat treated to reduce shrinkage to less than 15% while the web is capable of at least about 60% elongation at a strain rate of at least about 50 second−1.Type: GrantFiled: August 7, 2002Date of Patent: August 3, 2004Assignee: The Procter & Gamble CompanyInventors: Hugh Joseph O'Donnell, Eric Bryan Bond, Jody Lynn Hoying
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Patent number: 6767501Abstract: A film is extruded from plastic material by an extruder. The film is orientated after extrusion. Material is mixed into the plastic so that when the plastic film is stretched, cavitation bubbles are formed in the material particles mixed into the plastic. During the orientation, gas is arranged to the plastic film under high pressure so that the gas diffuses in the cavitation bubbles and causes overpressure in them. Thus, it is possible to make a thin foamed film with a foaming degree over 70%.Type: GrantFiled: October 4, 2000Date of Patent: July 27, 2004Assignee: Conenor OyInventor: Kari Kirjavainen
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Patent number: 6767618Abstract: A multi-layered stretched resin film comprises a base layer (A) comprising more than 90 wt % of a polyolefinic resin and less than 10 wt % of an inorganic fine powder and/or an organic filler; and an amorphous resin-containing layer (B), comprising 0 to 85 wt % of a second polyolefinic resin, which may be the same or different than the first polyolefinic resin, and 15 to 100 wt % of an amorphous resin. The amorphous resin-containing layer (B) is disposed on at least one side of the base layer (A), and has a porosity of 5% or less. Such multi-layered stretched resin films are resistant to waving or curling caused by exposure to the vehicle component of offset printing inks during offset printing, and therefore have excellent printing properties.Type: GrantFiled: February 4, 2002Date of Patent: July 27, 2004Assignee: Yupo CorporationInventors: Atsushi Ishige, Kazuhisa Kitamura
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Publication number: 20040135286Abstract: A method for producing a nonwoven web material having cross-machine direction extensibility in which a nonwoven web is conveyed through a machine which elongates the nonwoven web in a cross-machine direction (CD). The elongated nonwoven web is then necked, forming a cross-machine direction extensible nonwoven web material. The CD extensible nonwoven web material is highly stretchable and is suitable for use in personal care articles, such as diapers, incontinence garments, and feminine care products, as well as other articles, such as wipes, face masks, tissues, bandages and wound dressings.Type: ApplicationFiled: December 23, 2003Publication date: July 15, 2004Inventors: Sandy Chi-Ching Ying, Michael Tod Morman, Susan Elaine Shawver, Paul Windsor Estey, Jay Sheldon Shultz, Duane Girard Uitenbroek
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Patent number: 6761958Abstract: A directly embossable, coated polyethyleneterephthalate film including a dry, uniaxially oriented PET film, and a coating applied to the PET film, wherein the coating and the PET film have as a composite been transversely stretched, the coating resin being capable of impregnating the PET surface on drawing, rendering the film surface susceptible to embossing under pressure and the coating having low heat sealability and a method of producing a coated, directly embossable polyethyleneterephthalate film.Type: GrantFiled: July 26, 2002Date of Patent: July 13, 2004Assignee: Toray Plastics (America), Inc.Inventors: John Fitch, Jan Moritz, Gianfranco Chicarella, Jr., Yuji Shimizu, Yasuo Nishigaki, Bonnie Adams, Michael G. Fatica, Steven J. Sargeant
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Patent number: 6749785Abstract: Multilayer shaped articles, including films, preforms and containers, and method for forming the same, having at least one layer of poly(1,3-propylene 2,6-naphthalate) and at least one layer of poly(ethylene terephthalate). Poly(1,3-propylene 2,6-naphthalate) can be co-stretched with poly(ethylene terephthalate) to form oriented multilayer structures which have superior barrier properties. The poly(1,3-propylene 2,6-naphthalate) and poly(ethylene terephthalate) layers have good adhesion and do not require an adhesive tie layer.Type: GrantFiled: August 7, 2001Date of Patent: June 15, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Pallatheri M. Subramanian, Howard Chung-Ho Ng, Ross A. Lee
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Patent number: 6746633Abstract: A method for stretching an optical polymer film is described, which comprises allowing a locus L1 of the holding means from a substantial holding initiation point to a substantial holding release point on one edge of the polymer film, a locus L2 of the holding means from a substantial holding initiation point to a substantial holding release point on the other edge of the polymer film, and a distance W between the two substantial holding release points to satisfy the following equation (1), maintaining the supporting property of the polymer film, stretching the film in the presence of a state in which the volatile content is 5% or more, and then, decreasing the volatile content while shrinking the film: |L2−L1|>0.Type: GrantFiled: June 15, 2001Date of Patent: June 8, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Satoshi Sakamaki, Keiichi Taguchi
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Publication number: 20040099992Abstract: Stretched polymeric films can be used in a variety of applications, including optical applications. The stretching conditions and shape of the stretching tracks in a stretching apparatus can determine or influence film properties. Methods and stretching apparatuses can include adjustable or zone-defined stretching regions.Type: ApplicationFiled: November 27, 2002Publication date: May 27, 2004Inventors: William W. Merrill, Jeffrey N. Jackson, Andrew T. Ruff, Desiree L. Thompson, John A. Wheatley, Jeffrey D. Amundson, Curtis A. Harvey
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Publication number: 20040099993Abstract: Stretched polymeric films can be used in a variety of applications, including optical applications. The stretching conditions and shape of the stretching tracks in a stretching apparatus can determine or influence film properties. Take-away systems can be used to receive the film after stretching. The configuration of the take-away system can, in at least some instances, influence final film properties.Type: ApplicationFiled: November 27, 2002Publication date: May 27, 2004Inventors: Jeffery N. Jackson, William Ward Merrill, Andrew T. Ruff, Desiree L. Thompson
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Patent number: 6740184Abstract: Thermoplastic film, microporous film, and laminates thereof, are made at high speeds on the order of about 500 fpm to about 1200 fpm. Bond strengths of film and nonwoven laminates are effectively controlled by air cooling devices which cause the air to flow substantially parallel to the extruded web during drawdown and provide a plurality of cooling air vortices to effectively cool the web. Film gauge control is also achieved by the method.Type: GrantFiled: October 17, 2002Date of Patent: May 25, 2004Assignee: Clopay Plastic Products Company, Inc.Inventors: Robert M. Mortellite, Thomas G. Mushaben, Pai-Chuan Wu
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Publication number: 20040093831Abstract: The invention relates to a method for the plastic shaping of a biaxially-drawn film, comprising at least one base layer, containing at least one polymer (I), made from at least one hydroxycarboxylic acid and ≧0.2 wt %, based on the weight of the layer, of a thermoplastic polymer (II), different from polymer (I). Said film is plastically moulded by application of pneumatic and/or mechanical forces.Type: ApplicationFiled: September 22, 2003Publication date: May 20, 2004Inventors: Detlef Busch, Marlies Rosenbaum, Manfred Rosenbaum
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Patent number: 6737170Abstract: A directly embossable, coated polyethyleneterephthalate film including a dry, uniaxially oriented PET film, and a coating applied to the PET film, wherein the coating and the PET film have as a composite been transversely stretched, the film being coated from an aqueous solution at a thickness of about 0.1 &mgr;m-about 0.4 &mgr;m with a non-crosslinked polystyrene-acrylic emulsion and non-crosslinked polyester dispersion, the Tg of the coating resin being greater than about 20° C. and less than about 70° C.Type: GrantFiled: March 1, 2002Date of Patent: May 18, 2004Assignee: Toray Plastics (America), Inc.Inventors: John Fitch, Jan Moritz, Steven J. Sargeant, Yuji Shimizu, Yasuo Nishigaki
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Patent number: 6733719Abstract: A method of making a polypropylene product for use in making films and preferably biaxially oriented films and more preferably biaxially oriented films wherein a tenter-frame processing line is employed. The method includes the addition of low concentrations of a nucleating system in a mini-random polypropylene that allows for better processability and improved tensile properties. In one embodiment the nucleating system comprises a blend of a monocarboxylic acid nucleating agent and dicarboxylic acid nucleating agent. The nucleating system is combined with the polypropylene material and the resultant hot melt blend is further processed into biaxially oriented film. Alternately, the hot melt blend is formed into a convenient raw material for later use in a biaxial oriented film production facility. The resulting films possess superior processing and material characteristics.Type: GrantFiled: January 14, 2002Date of Patent: May 11, 2004Assignee: Sunoco Inc. (R&M)Inventors: Victor M. DiNardo, Nicholas Z. Karnavas
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Patent number: 6730406Abstract: The invention relates to a co-extruded, biaxially oriented polyester film consisting of a base layer and at least one outer layer. The film contains at least one flame-retardant agent, at least one UV-stabilizer and has a matt outer layer which contains a mixture and/or a blend of two components (I) and (II), whereby component (I) is substantially a polyethylene terephthalate homopolymer, or a polyethylene terephthalate copolymer, or a mixture of polyethylene terephthalate homopolymers or polyethylene terephthalate copolymers, and component (II) is a polymer containing at least one sulphonate group.Type: GrantFiled: July 18, 2002Date of Patent: May 4, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Gottfried Hilkert
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Publication number: 20040081928Abstract: A process for making polyester film base material comprising more than 65 mol % of 1,4-cyclohexanedimethanol (CHDM) of the total glycol component in the polyester material. The film base is prepared by sequentially carrying out the following steps: (a) casting a molten polyester resin in a machine direction onto a casting surface to form a continuous sheet, (b) drafting the sheet by stretching in the machine direction at a stretch ratio of from 2 to 4, and at a temperature ranging from 70° C. to 130° C., (c) tentering the sheet in the transverse direction by stretching at a stretch ratio of from 2 to 4, and at a temperature ranging from 70° C. to 130° C. to obtain a biaxially oriented film, (d) heat-setting the oriented film at an actual temperature of from 160° C. to 200° C., and (e) cooling the heat-set film without substantial detentering to obtain a biaxially oriented, heat-set polyester-based film having a cutting index of 1 to 1.Type: ApplicationFiled: October 24, 2002Publication date: April 29, 2004Applicant: Eastman Kodak CompanyInventors: Yuanqiao Rao, Jehuda Greener, Michael R. Brickey
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Patent number: RE38583Abstract: The invention relates to a process for the manufacture of cellulosic flat films and cellulosic membranes in the form of flat membranes whereby a solution of cellulose in an aqueous tertiary amine oxide is moulded in film form using an extrusion nozzle which has an oblong extrusion gap and is led into a precipitation bath via an air gap whereby the cellulosic flat film is formed in the precipitation bath, characterized in that the cellulosic flat film is stretched in the transverse direction after entering the precipitation bath.Type: GrantFiled: May 23, 2001Date of Patent: September 14, 2004Assignee: Lenzing AktiengesellschaftInventors: Christian Schlossnikl, Peter Gspaltl, Johann Kalleitner, Gerold Riedl, Andreas Schweigart