Abstract: The present invention provides an electrochemical capacitor, which includes: a cell electrode unit which includes cathodes, anodes, and separators interposed between the cathodes and the anodes which are alternately stacked in multiple layers; cathode terminals which are extended to one side of each of the cathodes and are stacked one above another; anode terminals which are extended to one side of each of the anodes and are stacked one above another with a separation space from the cathode terminals; a housing for receiving the cell electrode unit, the cathode terminals, and the anode terminals; and an output terminal unit which is insert-molded to penetrate from the inside to the outside of the housing, electrically connected to at least one of each of the stacked cathode and anode terminals, and immobilizes the cell electrode unit into the housing.

Abstract: An extremely high-performance polyaniline electrode was prepared by potentiostatic deposition of aniline on hierarchically porous carbon monolith (HPCM), which was carbonized from mesophase pitch. A capacitance value of 2200 F g?1 of polyaniline was obtained at a power density of 0.47 kW kg?1 and an energy density of 300 Wh kg?1. This active material deposited on HPCM also has an advantageous high stability. These superior advantages can be attributed to the backbone role of HPCM. This method also has the advantages of not introducing any binder, thus contributing to the increase of ionic conductivity and power density. High specific capacitance, high power and energy density, high stability, and low cost of active material make it very promising for supercapacitors.

Abstract: An additive of the formula (1) for use in electrolytic solutions wherein A is —CH(X)— or —C?C(X)—, X being hydrogen, halogen, alkyl having 1 to 4 carbon atoms, alkoxycarbonyl having 2 to 5 carbon atoms, benzoyl or alkoxycarbonylalkyl having 3 to 9 carbon atoms, Q1 and Q2 are the same or different and are each alkyl having 1 to 6 carbon atoms, alkoxyl having 1 to 4 carbon atoms, alkoxycarbonylalkyl having 3 to 9 carbon atoms or amino having as a substituent alkyl having 1 to 4 carbon atoms, and A, Q1 and Q2 may form a ring structure.

Abstract: This invention discloses a load system for loading an Mcap energy storage module to an apparatus, comprising: a storage unit and a load unit. The storage unit further comprises: a first housing part and a seal for sealing the first housing part. The first housing part includes four side walls, a bottom wall and a first opening. A plurality of Mcap cell are disposed in the first housing part through the first opening. A first electrode formed in a side wall. A second electrode formed in another side wall facing the first side wall. The load unit comprises a second housing part and a seal for sealing the second housing part. The storage unit is loaded into the second housing part through the second opening.

Abstract: Disclosed is a coin type lithium ion capacitor which includes a positive electrode made of an activated carbon based positive active material and a negative electrode opposite to the positive electrode with a first separator interposed therebetween. The negative electrode includes a graphite electrode including a first current collector and a graphite based negative active material coated onto the first current collector; and a lithium metal member opposite to the graphite electrode with a second separator interposed therebetween and including a second current collector and lithium metal coated on the second current collector, in which lithium ions of the lithium metal move from the lithium metal to the positive electrode through the graphite electrode during discharge and are carried in the graphite electrode from the positive electrode during charge.

Abstract: An electrical energy storage device includes a first electrode; a second electrode; a separator; and an electrolyte; where the separator is an electronic insulator; the separator is positioned between the first and second electrodes; the separator includes a first surface proximal to the first electrode and a second surface proximal to the second electrode; the separator is configured to support an electric double layer at the first surface, the second surface, or at both the first surface and the second surface; and the device is an electrical energy storage device.

Abstract: The present invention provides electrolytes for use in electronic devices which contain imidazolium salts in combination with high boiling aprotic solvents having lower flammability and lower toxicity than acetonitrile electrolytes.

Abstract: Disclosed herein is an energy storage device. The energy storage device according to an exemplary embodiment of the present invention includes a case providing an internal space with a first space and a second space; an electrolyte solution filled in the internal space of the case; a positive electrode structure disposed on an interface between the first space and the second space and having a cathode active material layer including metal oxide composite; a first negative electrode disposed in the first space and having a first anode active material layer including graphite; and a second negative electrode disposed in the second space and having a second anode active material layer including activated carbon.

Abstract: A coated electrode includes a current collector of an etched aluminum foil having a thickness of 20 to 45 ?m, an apparent density of 2.00 to 2.54 g/cm3, an air permeability of 20 to 120 s and a number of through-holes penetrating therethrough from the front surface to the back surface, and an electrode layer formed by applying a coating material including, as an active material, a substance capable of reversibly carrying lithium ions and anions on to the current collector. The coated electrode is industrially producible, high in conductivity and strength, and excellent in evenness. A capacitor, for example, can make use of the electrode.

Abstract: The present invention discloses an improved electrode for a supercapacitor and a method of preparation thereof. The inventive electrode comprises a collector, a carbon substrate disposed on the collector comprising ultrafine carbon fibers having a specific surface area of at least 200 m2/g (BET) and a d002 value of 0.36 nm or less, and a metal oxide thin layer formed on the carbon substrate. The electrode of the subject invention retains a high specific capacitance during high-speed charging and discharging cycles.

Abstract: The disclosure relates to asymmetric supercapacitors containing: a positive electrode comprising a current collector and a first active material selected from a layered double hydroxide of formula [M2+1?xMx3+(OH)2]An?x/n·mH2O where M2+ is at least one divalent metal, M3+ is at least one trivalent metal and A is an anion of charge n?, where x is greater than zero and less than 1, n is 1, 2, 3 or 4 and m is 0 to 10; LiCoO2; LiCoxNiyO2 where x and y are greater than zero and less than 1; LiCoxNiyMn(1?x?y)O2 where x and y are greater than zero and less than 1; CoSx where x is from 1 to 1.5; MoS; Zn; activated carbon and graphite; a negative electrode containing a material selected from a carbonaceous active material, MoO3 and Li1xMoO6?x/2; an aqueous electrolyte solution or a non-aqueous ionic conducting electrolyte solution containing a salt and a salt and a non-aqueous solution; and a separator plate. Alternatively, the electrolyte can be a solid electrolyte.

Abstract: A supercapacitor and a manufacturing method thereof are disclosed. With manufacturing method of Supercapacitor including: arranging a plurality of filters to be spaced at a designated interval apart, forming a first plating layer connecting one end of the filter, forming a second plating layer lengthened along the filter from the first plating layer, polymerizing to form a conductive polymer layer between the second plating layer, and removing the filter, capacitance (C), power (kw) and energy (E) can be increased as the space for absorbing electrons is widened, by making the surface area of an electrode wider than the a general film.

Abstract: A capacitor includes a plurality of electrode substrates, with each of the plurality of electrode substrates having a coated portion and an uncoated portion. The coated portion is coated with a coating material that includes a high surface area activated carbon material, a water soluble binder selected from the group consisting of: poly vinyl alcohol, poly acrylic acid, polymethacrylic acid, polyethylene oxide, polyacrylamide, poly-N-isopropylearylamide, poly-N,N-dimethylacrylamide, polyethyleneimine, polyoxyethylene, polyvinylsulfonic acid, poly(2-methoxyethoxyethoxyethylene), butadiene-acrylonitrile, and combinations thereof, and a water soluble thickener. A separator is inserted between adjacent substrates of the plurality of electrode substrates. The capacitor further includes an electrolyte. A method of manufacturing the capacitor is also provided.

Abstract: The present invention is an electrochemical double layer capacitor (EDLC) series stack formed into a single electrolyte cell structure. The concatenated multiple electrode assembly stack has electrode assemblies electrically connected in series. The electrode assemblies have a double-sided activated carbon electrode formed on a current collector. Power tabs are connected to the end electrode assemblies. An electrolyte is also provided. A poly bag contains the electrolyte and the electrode assemblies. The electrode assemblies form a double-sided activated-carbon electrode on a current collector. The EDLC stack has a number of segments and mass free zones separating them. The segments are folded so that mass free zones are disposed at the apex of each fold.

Abstract: A double layer capacitor (DLC) containing at least one double layer capacitor cell is provided. Each double layer capacitor cell contains two current collectors, each containing a metallized carrier film with upper and lower planar surfaces, two thin electrode layers in direct contact with the lower and upper planar surfaces of the metallized carrier films of the first and second current collectors, and a polymer electrolyte layer in direct contact with the first and the second thin electrode layers. The polymer electrolyte is applied as a liquid which impregnates and encases the electrode layers and then solidified to form the electrolyte layer. The resulting DLC is preferably no thicker than about 20 microns, and may be as thin as 5 microns. Methods of producing a DLC and for forming a cross-linked electrolyte are also provided.

Abstract: In one aspect of the present invention, a method for increasing the dielectric breakdown strength of a polymer is described. The method comprises providing the polymer and contacting a surface of the polymer in a reaction chamber with a gas plasma, under specified plasma conditions. The polymer is selected from the group consisting of a polymer having a glass transition temperature of at least about 150° C., and a polymer composite comprising at least one inorganic constituent. The contact with the gas plasma is carried out for a period of time sufficient to incorporate additional chemical functionality into a surface region of the polymer film, to provide a treated polymer. Also provided are an article and method of manufacture.

Abstract: A supercapacitor having a main energy storage form that is based on the electrode reaction of electrochemical active materials in a thin liquid layer near the inner and outer surfaces of porous electrodes.

Abstract: There are provided a microporous film for an electric storage device separator, which can increase energy density and power density when used in an electric storage device, and which is excellent in handling properties in a processing step to the electric storage device, as well as an electric storage device separator and an electric storage device, using the microporous film. Specifically, provided is a microporous film for an electric storage device separator, characterized by including a porosity of 70% or more, a strength of 40 MPa or more in a longitudinal direction, an average pore size of from 40 to 400 nm, anuclear pores, and exhibiting biaxial orientation.

Abstract: Provided is an electrical energy storage device including an electrode winding body, which includes a positive electrode generating electrons by oxidation and reduction, a negative electrode for absorbing the generated electrons, and separation layers for physically separating the negative electrode from the positive electrode, which are sequentially wound around a winding core, and an electrolyte provided between the positive electrode and the negative electrode, the electrical energy storage device including: a terminal plate for externally connecting the electrode winding body to an external electrode connecting member such as an external resistor; a cylindrical can for accommodating the electrode winding body connected to the terminal plate; and a conductive interconnecting member for connection between the terminal plate and polarity-leads on one side of the electrode winding body by a method selected from the group consisting of plasma-spraying, welding, soldering and adhesion using a conductive adhesiv

Abstract: Provided is an electrical energy storage device including an electrode winding body, which includes a positive electrode generating electrons by oxidation and reduction, a negative electrode for absorbing the generated electrons, and separation layers for physically separating the negative electrode from the positive electrode, which are sequentially wound around a winding core, and an electrolyte provided between the positive electrode and the negative electrode, the electrical energy storage device including: a terminal plate for connecting the electrode winding body to an external electrode interconnecting member such as an external resistor; a cylindrical can for accommodating the electrode winding body connected to the terminal plate; and a ring-shaped sealing member for closing an opening formed in the can; wherein the sealing member includes a vent part having a vent hole and integrally formed in the center of at least one side of the sealing member.

Abstract: A solution or dispersion of an ion-permeable compound, a carbon fine particle a, and a solvent is coated on a conductive sheet such as an aluminum foil, the coat is dried to form a film a, which allows to obtain a collector for an electric double layer capacitor. A solution or dispersion of a binder, a carbon fine particle b, an activated carbon b, and a solvent is coated on the film a, the coat is dried to form a film b, which results in obtaining an electrode for an electric double layer capacitor. The electrode is piled on a separator, and immersed in an electrolytic solution to obtain an electric double layer capacitor.

Abstract: An electrical storage device includes high surface area fibers (e.g., shaped fibers and/or microfibers) coated with carbon (graphite, expanded graphite, activated carbon, carbon black, carbon nanofibers, CNT, or graphite coated CNT), electrolyte, and/or electrode active material (e.g., lead oxide) in electrodes. The electrodes are used to form electrical storage devices such as electrochemical batteries, electrochemical double layer capacitors, and asymmetrical capacitors.

Abstract: An inexpensive and reliable dry process based capacitor and method for making a self-supporting dry electrode film for use therein is disclosed. Also disclosed is an exemplary process for manufacturing an electrode for use in an energy storage device product, the process comprising: supplying dry carbon particles; supplying dry binder; dry mixing the dry carbon particles and dry binder; and dry fibrillizing the dry binder to create a matrix within which to support the dry carbon particles as dry material.

Abstract: This invention relates to a capacitor electrode which includes porous layers made of a fiber and/or a whisker containing crystal tungsten oxides. The tungsten oxide fiber and/or whisker contain W18O49 as a main ingredient. The tungsten oxide fiber and/or whisker are made on a substrate. When manufacturing the capacitor electrode the substrate or its precursor is heated in vacuo or in an inactive containing a minute amount of oxygen, thereby completing the fiber and/or whisker.

Abstract: A composite suitable as a charge-storing material for electrochemical capacitors contains carbon nanotubes and a carbonaceous materiel. The carbonaceous material is the carbonization residue of a biopolymer or seaweed rich in heteroatoms. Wherein the carbonization residue of the biopolymer or seaweed is electrically conductive and has a heteroatom content as detected by XPS of at least 6%.

Abstract: This disclosure relates to an electrolyte for an aluminum electrolytic capacitor. An electrolyte according to one embodiment includes a protic fluid and a high dielectric co-solvent or a dipolar aprotic. According to various embodiments, the electrolyte is pH buffered to less than approximately 6.8 pH. The protic fluid includes ethylene glycol and the high dielectric co-solvent includes N-methylformamide, in various embodiments. The disclosure further relates to methods for manufacturing an electrolyte, and capacitors and implantable devices including a supporting electrolyte selected for optimal cation size and charge and anion solubility.

Abstract: A method for producing an ultracapacitor includes the steps of: providing a negative porous electrode in contact with a negative conducting plate; providing a positive porous electrode in contact with a positive conducting plate; providing an ultracapacitor separator being a microporous material that separates the negative porous electrode from the positive porous electrode; providing an electrolytic solution that impregnates the negative porous electrode, the positive porous electrode, and the ultracapacitor separator; and curing the ultracapacitor at a temperature of at least 200° C.

Abstract: Ion storage electrodes formed by coating an underlying substrate with a nanofibrillar film of structured conjugate polymer nanofibers and methods of forming such electrodes are described herein. The electrical properties of the electrodes may be customized by modifying the structure of the polymer nanofibers, the thickness of the nanofiber film, and the pore size of the nanofiber films.

Abstract: A hybrid energy storage device includes at least one cell comprising at least one positive electrode, at least one negative electrode, a separator placed between said at least one positive and said at least one negative electrode, and an electrolyte. The at least one positive electrode comprises an active material comprising lead and a tab extending from a side of the at least one positive electrode. The at least one negative electrode comprises an activated carbon material, a tab extending from a side of the at least one negative electrode, and a lead lug encapsulating said tab. A first cast-on lead strap is on the tab extending from said at least one positive electrode. A second cast-on lead strap is on the lead lug of the at least one negative electrode.

Abstract: Provided is an electrolyte containing tetrafluoroaluminate ions, which is advantageous in that the electrolyte can be prevented from leaking from both the cathode and the anode in an electrolytic capacitor.

Abstract: A capacitor includes a plurality of nanochannels formed in a dielectric material. A conductive film is formed over interior surfaces of the nanochannels, and a charge barrier is formed over the conductive film. An electrolytic solution is disposed in the nanochannels. An electrode is coupled to the electrolytic solution in the nanochannels to form the capacitor.

Abstract: In a method of manufacturing a porous coke suitable as a charge-storing material in electrochemical capacitors, one manufactures or provides a non-calcined isotropic coke with spherical or onion-shaped morphology and low graphitizability as a starting material. The starting material is comingled with a caustic alkali to obtain a homogenous mixture. The homogenous mixture is heat treated at a temperature in a range between 650 and 950° C. to obtain the porous coke. The porous coke is washed and neutralized.

Abstract: A flexible, asymmetric electrochemical cell comprising: (A) A sheet of graphene paper as first electrode comprising nano graphene platelets having a platelet thickness less than 1 nm, wherein the first electrode has electrolyte-accessible pores; (B) A thin-film or paper-like first separator and electrolyte; and (C) A thin-film or paper-like second electrode which is different in composition than the first electrode; wherein the separator is sandwiched between the first and second electrode to form a flexible laminate configuration. The asymmetric supercapacitor cells with different NGP-based electrodes exhibit an exceptionally high capacitance, specific energy, and stable and long cycle life.

Abstract: A composite electrode is created by forming a thin conformal coating of mixed metal oxides on a highly porous carbon structure. The highly porous carbon structure performs a role in the synthesis of the mixed oxide coating and in providing a three-dimensional, electronically conductive substrate supporting the thin coating of mixed metal oxides. The metal oxide mixture shall include two or more metal oxides. The composite electrode, a process for producing said composite electrode, an electrochemical capacitor and an electrochemical secondary (rechargeable) battery using said composite electrode are disclosed.

Abstract: An electrochemical device having an operational voltage up to 4.5 V in combination with a high concentration of an electrolyte salt consisting of a tetrafluoroborate salt and a eutectic of two solvents in which ethylene carbonate is one and an improved carbon electrode a preferred electrochemical device is a capacitor.

Abstract: Disclosed is an all-solid-state electric double layer capacitor comprising a solid electrolyte and a current collector, wherein the solid electrolyte is an inorganic solid electrolyte. Such a capacitor has high capacity and is free from any fear of leakage of an electrolytic solution, and also ensures high heat resistance and enables a low process cost.

Abstract: A method for manufacturing an electrode of a supercapacitor is provided. First, a poly(acrylonitrile) (PAN) fabric is provided. The PAN fabric includes a plurality of PAN fibers each having a diameter of about 50-500 nm. Then, the PAN fabric undergoes a heat treatment so that the PAN fibers are carbonized to form a carbon fiber textile. The carbon fiber fabric includes a plurality of carbon fibers each having a diameter of about 50-500 nm. The surface of each carbon fiber is nano-porous having a plurality of nano pores of about 1-50 nm in diameter. The total surface area of the nano pores account for about 85-95% of the total surface area of the carbon fibers. The carbon fiber fabric is then cut to acquire the electrode of the supercapacitor.

Abstract: This document provides an apparatus including a sintered electrode, a second electrode and a separator material arranged in a capacitive stack. A conductive interconnect couples the sintered electrode and the second electrode. Embodiments include a clip interconnect. In some embodiments, the interconnect includes a comb-shaped connector. In some embodiments, the interconnect includes a wire snaked between adjacent sintered substrates.

Abstract: Disclosed are supercapacitor materials comprising compositions having pores that are optimally sized to maximize capacitance. Also disclosed are related methods for fabricating such supercapacitors.

Abstract: The present invention provides an electrode material for an electric double layer capacitor which can provide an electric double layer capacitor having a low internal resistance and a large capacitance, a process for producing the same, and an electrode for an electric double layer capacitor and an electric double layer capacitor using the same. The electrode material of the present invention is characterized by comprising a carbonaceous material and an activated carbon, the carbonaceous material obtained by thermal-treating or activating a fullerene-containing soot or an extracted residue obtained by substantially extracting at least a part of fullerene from a fullerene-containing soot using a solvent. The electrode for an electric double layer capacitor and the electric double layer capacitor of the present invention is characterized by using the electrode material.

Abstract: An electrolytic capacitor (1) includes a first electrode (2) and a second electrode (3) each including carbon and an aqueous electrolyte (4) situated at the interface of the two electrodes. The carbon surface of the first electrode (2) has an atomic degree of functionalization which is at least twice that of the carbon surface of the second electrode (3).

Abstract: A flexible super capacitor including a pair of flexible electrodes and a separator film is disclosed. Each flexible electrode includes a carbon fiber layer and a collector formed on a surface of the carbon fiber layer. The pair of flexible electrodes has two outer surfaces, and the collector layers are formed on the outer surfaces of the pair of the flexible electrodes. The separator film is disposed between the flexible electrodes. The collector layer would be formed on the carbon fiber layer with surface metalizing the carbon fiber layer. A method for fabricating the flexible electrode of the flexible super capacitor is also disclosed.

Abstract: Composite carbon electrodes for use in, for example, Capacitive Deionization (CDI) of a fluid stream or, for example, an electric double layer capacitor (EDLC) are described. Methods of making the composite carbon electrodes are also described. The composite carbon electrode comprises an electrically conductive porous matrix comprising carbon; and an electric double layer capacitor, comprising an activated carbonized material, dispersed throughout the pore volume of the electrically conductive porous matrix.

Abstract: Carbon electrodes for a capacitor having conditioned carbon elements in combination with a high concentration of an electrolyte tetrafluoroborate salt and a non-aqueous aprotic solvent to provide an operational voltage up to 4.5V and capacitors used with the carbon electrodes.

Abstract: Films of active electrode material, such as films made from carbon and fibrillized polymer, are attached to a porous separator. Outer surfaces of the films (i.e., surfaces opposite those adjoining the separator) are then covered with current collectors. The 5 resulting stack is usable in fabrication of electrical energy storage devices. The stack can be shaped as needed, connected to terminals, and immersed in an electrolytic solution to provide a double layer capacitor.

Abstract: An electrode for a supercapacitor includes a block copolymer and active material particles. The block copolymer is used both to bind the particles together and to act as an electrolyte. The electrode does not have a porous structure, but rather it is pressed or rolled to achieve zero porosity and to ensure good contact between the particles and the block copolymer electrolyte. Thus, the entire surface of the active particles can be accessed for charge storage. Furthermore, the volume of such an electrode is smaller than typical electrodes with the same capacity, as none of the volume is wasted with additional, non-active binder material, offering a higher effective active material loading per unit volume. Electrodes made in this way, with block copolymer electrolyte and active materials, can also form free-standing films that are easy to handle during manufacture of supercapacitors.

Abstract: A capacitor having stable characteristics and an improved energy density while sufficiently ensuring a bonding strength between the polarizable electrode layer and the current collector is provided. A buffer layer including a ratio of 60 wt % to 90 wt %, preferably 70 wt % to 80 wt %, of carbon nanofiber or carbon nanotube, is formed over the current collector. Then, by forming a polarizable electrode layer over the aforesaid buffer layer, a pair of electrodes are obtained in which, the buffer layer and the polarizable electrode layer are stacked in this order over the current collector. Additionally, a capacitor is formed with the above-mentioned pair of electrodes by opposing the polarizable electrode layers to each other so as to be facing one another with a separator sandwiched therebetween in an electrolyte solution.

Abstract: A coin-type electrochemical element enables the external lead terminal portions to be accurately and reliably attached to a first lid portion and to a second lid portion of the coin-type electrochemical element, and a method of its production. A coin-type electric double layer capacitor includes a first lid portion and a second lid portion. External lead terminal portions, each having a nearly triangular shape, are separately connected to the outer surfaces of the lid portions. Upon providing the external lead terminal portions having the triangular shape, a welded portion is allowed to have an increased area enabling the coin-type electrochemical element of even a small size to be accurately and reliably welded and making it possible to provide the coin-type electrochemical element having excellent reliability.

Abstract: An energy storage cell pack cradle assembly for holding multiple rows of energy storage cells oriented along a dominant axis of vibration includes a first cradle member including a plurality of energy storage cell body supporting structures including respective holes; a second cradle member including a plurality of energy storage cell body supporting structures including respective holes; and one or more fasteners connecting the first cradle member and the second cradle member together. The energy storage cell body supporting structures are configured to structurally support the energy storage cells, with the energy storage cells oriented along a dominant axis of vibration, by energy storage cell bodies of the energy storage cells with respective electrically conductive terminals extending through the respective holes without structural support of the electrically conductive terminals by the cradle members.

Abstract: An electric energy storage component having coil windings and at least one connector. A plate of the connector is in contact with the coil windings. The plate of the connector has a surface which is provided with a terminal wherein the shape thereof is essentially that of a revolution. The plate also forms a series of bosses extending in a raised manner along a surface of the plate opposite to that containing the terminal. The terminal has at least one inner recess and at least one boss which penetrates into the recess.