Over 1.5 Percent Silicon Containing Patents (Class 420/50)
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Patent number: 9694435Abstract: Disclosed is a method for producing a permanently joined plate heat exchanger comprising a plurality of metal heat exchanger plates having a solidus temperature above 1100° C., provided beside each other and forming a plate package with first plate interspaces for a first medium and second plate interspaces for a second medium, wherein the first and second plate interspaces are provided in an alternating order in the plate package. Each heat exchanger plate comprises a heat transfer area and an edge area which extend around the heat transfer area. The heat transfer area comprises a corrugation of elevations and depressions, wherein said corrugation of the plates are provided by pressing the plates. Also disclosed is a plate heat exchanger produced by the method.Type: GrantFiled: March 28, 2013Date of Patent: July 4, 2017Assignee: ALFA LAVAL CORPORATE ABInventors: Per Sjödin, Kristian Walter
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Patent number: 9694434Abstract: Disclosed is a method for producing a permanently joined plate heat exchanger comprising a plurality of metal heat exchanger plates having a solidus temperature above 1100° C., provided beside each other and forming a plate package with first plate interspaces for a first medium and second plate interspaces for a second medium, wherein the first and second plate interspaces are provided in an alternating order in the plate package, wherein each heat exchanger plate comprises a heat transfer area and an edge area comprising bent edges which extend around the heat transfer area, wherein a first surface of the plates forms a convex shape and a second surface of the plates forms a concave shape, wherein the heat transfer area comprises a corrugation of elevations and depressions, wherein said corrugation of the plates and the bent edges are provided by pressing the plates. Also disclosed is a plate heat exchanger produced by the method.Type: GrantFiled: March 27, 2013Date of Patent: July 4, 2017Assignee: ALFA LAVAL CORPORATE ABInventors: Per Sjödin, Kristian Walter
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Publication number: 20140131338Abstract: Various embodiments of a metal cored wires, hardband alloys, and methods are disclosed. In one embodiment of the present invention, a hardbanding wire comprises from about from about 16% to about 30% by weight chromium; from about 4% to about 10% by weight nickel; from about 0.05% to about 0.8% by weight nitrogen; from about 1% to about 4% by weight manganese; from about 1% to about 4% by weight carbon from about 0.5% to about 5% by weight molybdenum; from about 0.25% to about 2% by weight silicon; and the remainder is iron including trace elements. The hardband alloy produced by the metal cored wire meets API magnetic permeability specifications and has improved metal to metal, adhesive wear resistance compared to conventional hardband alloys.Type: ApplicationFiled: November 12, 2013Publication date: May 15, 2014Applicant: Postle Industries, Inc.Inventor: Christopher J. Postle
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Patent number: 8647448Abstract: A steel piston ring and a steel cylinder liner are described which comprise as the main body a steel composition which has good nitridability. The steel composition consists of the following elements: 0-0.5 weight % B, 0.5-1.2 weight % C, 4.0-20.0 weight % Cr, 0-2.0 weight % Cu, 45.30-91.25 weight % Fe, 0.1-3.0 weight % Mn, 0.1-3.0 weight % Mo, 0-0.05 weight % Nb, 2.0-12.0 weight % Ni, 0-0.1 weight % P, 0-0.05 weight % Pb, 0-0.05 weight % S, 2.0-10.0 weight % Si, 0-0.05 weight % Sn, 0.05-2.0 weight % V, 0-0.2 weight % Ti and 0-0.5 weight % W. The steel piston ring and the steel cylinder liner can be manufactured in a casting process using the machinery and technology employed for the manufacture of cast iron parts.Type: GrantFiled: March 25, 2010Date of Patent: February 11, 2014Assignee: Federal-Mogul Burscheid GmbHInventor: Laszlo Pelsoeczy
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Patent number: 8486204Abstract: The hinge is made with a metal injection molding process from an alloy having at least: from 4 to 32 wt % Mn, from 16 to 37 wt % Cr, and from Fe that fills up the rest of the percentage.Type: GrantFiled: November 17, 2010Date of Patent: July 16, 2013Assignee: Shin Zu Shing Co., Ltd.Inventors: Yu-Chi Lu, Yu-Chan Hsieh, Shun-Tian Lin
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Publication number: 20130047786Abstract: A corrosion resistant, neutron absorbing, austenitic alloy powder is disclosed having the following composition in weight percent. C 0.08 max. Mn up to 3 Si up to 2 P 0.05 max. S 0.03 max. Cr 17-27 Ni 11-20 Mo + (W/1.92) ??up to 5.2 BEq 0.78-13.0 O ?0.1 max. N ??up to 0.2 Y less than 0.005 The alloy contains at least about 0.25% B, at least about 0.05% Gd, and the balance of the alloy composition is iron and usual impurities. BEq is defined as % B+4.35×(% Gd). An article of manufacture made from consolidated alloy powder is also disclosed which is characterized by a plurality of boride and gadolinide particles dispersed within a matrix. The boride and gadolinide particles are predominantly M2B, M3B2, M3X, and M5X in form, where X is gadolinium or a combination of gadolinium and boron and M is one or more of the elements silicon, chromium, nickel, molybdenum, iron.Type: ApplicationFiled: August 25, 2011Publication date: February 28, 2013Inventors: Michael L. Schmidt, Gregory J. Del Corso, Patrick C. Ray, Ning Ma
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Publication number: 20120301347Abstract: An austenitic stainless steel alloy consisting essentially of, in terms of weight percent ranges 0.15-0.5C; 8-37Ni; 10-25Cr; 2.5-5Al; greater than 0.6, up to 2.5 total of at least one element selected from the group consisting of Nb and Ta; up to 3Mo; up to 3Co; up to 1W; up to 3Cu; up to 15Mn; up to 2Si; up to 0.15B; up to 0.05P; up to 1 total of at least one element selected from the group consisting of Y, La, Ce, Hf, and Zr; <0.3Ti+V; <0.03N; and, balance Fe, where the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale comprising alumina, and a stable essentially single phase FCC austenitic matrix microstructure, the austenitic matrix being essentially delta-ferrite free and essentially BCC-phase-free. A method of making austenitic stainless steel alloys is also disclosed.Type: ApplicationFiled: May 24, 2011Publication date: November 29, 2012Applicant: UT-Battelle, LLCInventors: Govindarajan MURALIDHARAN, Yukinori Yamamoto, Michael P. Brady
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Patent number: 8287805Abstract: The present invention relates an iron based brazing material comprising an alloy consisting essentially of: 15 to 30 wt % chromium (Cr); 0 to 5.0 wt % manganese (Mn); 15 to 30 wt % nickel (Ni); 1.0 to 12 wt % molybdenum (Mo); 0 to 4.0 wt % copper (Cu); 0 to 1.0 wt % nitrogen (N); 0 to 20 wt % silicone (Si); 0 to 2.0 wt % boron (B); 0 to 16 wt % phosphorus (P); optionally 0.0 to 2.5 wt % of each of one or more of elements selected from the group consisting of carbon (C), vanadium (V), titanium (Ti), tungsten (W), aluminum (Al), niobium (Nb), hafnium (Hf), and tantalum (Ta); the alloy being balanced with Fe, and small inevitable amounts of contaminating elements; and wherein Si, B and P are in amounts effective to lower melting temperature, and Si, B, and P are contained in amounts according to the following formula: Index=wt % P+1.1×wt % Si+3×wt % B, and the value of the Index is within the range of from about 5 wt % to about 20.Type: GrantFiled: November 14, 2007Date of Patent: October 16, 2012Assignee: Alfa Laval Corporate ABInventor: Per Sjödin
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Publication number: 20120190321Abstract: A nonmagnetic stainless steel which has a higher electrical resistivity than existing nonmagnetic alloys, a production process for producing the stainless steel, and a radio wave receiver. The receiver has a main case and rear cover constituted of a nonmagnetic stainless steel having an electrical resistivity as high as more than 100 ??·cm and consisting of C: not more than 0.1%, Si: 4.0-7.5%, Mn: not more than 2.0%, Ni: 25.5-30.0%, Cr: 15.0-20.0%, Mo: 0.1-3.0%, Cu: 0-2.0%, in mass % and the balance Fe and impurities. Even if some variable magnetic flux generated by a coil of an antenna runs through the main case and the rear cover, the receiving efficiency of the antenna can be prevented from being reduced by eddy current loss and a sufficient radio receiving sensitivity can be obtained. This nonmagnetic stainless steel is produced by hot and/or cold plastic working and subsequent solution treating conducted at 1,000-1,180° C.Type: ApplicationFiled: July 29, 2010Publication date: July 26, 2012Applicants: HITACHI METALS, LTD., CASIO COMPUTER CO., LTD.Inventors: Junichi Sato, Toshihiro Uehara, Kenji Yokoyama
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Publication number: 20110300016Abstract: In order to provide a material of low cost that is suitable to produce parts or coatings having a high wear and also high chemical resistance, an alloy is proposed comprising 13 to 16 percent by weight nickel (Ni), 13.5 to 16.5 percent by weight of chromium (Cr), 0.5 to 3 percent by weight of molybdenum (Mo), 3.5 to 4.5 percent by weight of silicon (Si), 3.5 to 4 percent by weight of boron (B) and 1.5 to 2.1 percent by weight of carbon (C), balance iron (Fe).Type: ApplicationFiled: February 17, 2010Publication date: December 8, 2011Applicant: MEC Holding GmbHInventor: Gary Robert Heath
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Publication number: 20110226459Abstract: The invention relates to an iron-based brazing material comprising a brazing alloy, which alloy comprises: from about 9 wt % to about 30 wt % Cr, from about 5 wt % to about 25 wt % Ni, from about 0 wt % to about 9 wt % Mo, from about 0 wt % to about 5 wt % Mn, from about 0 wt % to about 1 wt % N, from about 6 wt % to about 20 wt % Si. Within the alloy is at least one of the B and the P are present as a melting point lowering supplement to Si, and wherein B is from about 0.1 wt % to about 1.5 wt %, or wherein P is from about 0.1 to about 15 wt % P. The brazing alloy may comprise contaminating elements as at least one of C, O, and S, and optionally the brazing alloy also comprises at least one micro-alloying element as V, Ti, W, Nb, or Ta, and the micro-alloying element is less than 1.5 wt % in the brazing alloy. All values are stated in weight percent, and wherein Si, B and P lower the liquidus temperature, that is the temperature when the brazing material is completely melted.Type: ApplicationFiled: March 22, 2011Publication date: September 22, 2011Inventor: Per Erik Sjodin
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Publication number: 20110192127Abstract: A filter comprising a porous sintered stainless steel is provided. The filter includes 10-30% chromium, 5-25% nickel, 0.5-3% manganese; 1-4% silicon, and 0-3% molybdenum with the remainder being iron and inevitable impurities. The sintered steel has a density less than 80% of full density. The use of a stainless steel powder for the preparation of a filter having improved permeability at high temperatures also is described.Type: ApplicationFiled: April 20, 2011Publication date: August 11, 2011Applicant: HÖGANÄS ABInventors: Owe Mårs, Ingrid Hauer
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Publication number: 20110020166Abstract: The object of the present invention is to provide at a low cost iron-base heat- and corrosion-resistant brazing material which make it possible to braze parts made of a base metal selected from among various stainless steels, particularly ferritic stainless steels, at a practical temperature (of 1120° C. or lower) and are excellent in the wetting property against the base metal and which can attain excellent resistance to corrosion by sulfuric acid or nitric acid and high strength without coarsening the structure of the base metal. The iron-base heat- and corrosion-resistant brazing material is characterized by comprising 30 to 75 wt % of Fe, 35 wt % or less of Ni and 5 to 20 wt % of Cr in a total amount of Ni and Cr of 15 to 50 wt %, and 7 wt % or less of Si and 4 to 10 wt % of P in a total amount of Si and P of 9 to 13 wt %. The iron-base heat- and corrosion-resistant brazing material further comprising 0.5 to 5 wt % of Mo and/or 0.Type: ApplicationFiled: August 28, 2008Publication date: January 27, 2011Inventors: Katsunori Otobe, Shozo Nagai
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Publication number: 20100055495Abstract: The present invention relates to a brazing material comprising an alloy containing essentially of: 15 to 30 wt % chromium (Cr); 0.1 to 5.0 wt % manganese (Mn); 9 to 20 wt % nickel (Ni); 0 to 4.0 wt % molybdenum (Mo); 0 to 1.0 wt % nitrogen (N); 1.0 to 7.0 wt % silicone (Si); 0 to 0.2 wt % boron (B); 1.0 to 7.0 wt % phosphorus (P); optionally 0.0 to 2.5 wt % of each of one or more of elements selected from the group consisting of vanadium (V), titanium (Ti), tungsten (W), aluminum (Al), niobium (Nb), hafnium (Hf) and tantalum (Ta); the alloy being balanced with Fe, and small inevitable amounts of contaminating elements; and wherein Si and P are in amounts effective to lower melting temperature. The present invention relates further to a method of brazing, a product brazed with the brazing material.Type: ApplicationFiled: November 14, 2007Publication date: March 4, 2010Applicant: ALFA LAVAL CORPORATE ABInventor: Per Sjödin
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Publication number: 20090038280Abstract: A filter comprising a porous sintered stainless steel is provided. The filter includes 10-30% chromium, 5-25% nickel, 0.5-3% manganese; 1-4% silicon, and 0-3% molybdenum with the remainder being iron and inevitable impurities. The sintered steel has a density less than 80% of full density. The use of a stainless steel powder for the preparation of a filter having improved permeability at high temperatures also is described.Type: ApplicationFiled: May 24, 2006Publication date: February 12, 2009Applicant: Hoganas ABInventors: Owe Mars, Ingrid Hauer
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Patent number: 7455811Abstract: An iron based brazing material for joining objects by brazing represents an alloy, which apart from iron contains approximately 9-30% Cr, approximately 0-8% Mn, approximately 0-25% Ni, 0-1% N, a maximum of 7% Mo, less than about 6% Si, approximately 0-2% B and/or about 0-15% P, all stated in weight percent, which addition of Si, P, and B in combination or separately lowers the liquidus temperature, that is the temperature at which the brazing material is completely melted. A brazed product is manufactured by brazing of iron based objects with an iron based brazing material which is alloyed with a liquidus lowering element as Si, P and B.Type: GrantFiled: June 3, 2002Date of Patent: November 25, 2008Assignee: Alfa Laval Corporate ABInventor: Per Erik Sjodin
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Patent number: 7101446Abstract: An austenitic stainless steel with minimized deformation by heating and cooling treatment after cold working, which consists of, % by mass, C: 0.03% or less, Si: 2 to 4%, Mn: 0.1 to 2%, P: 0.03% or less, S: 0.03% or less, Ni: 9 to 15%, Cr: 15 to 20%, N: 0.02 to 0.2%, Nb: 0.03% or less, each of Mo and Cu or a total of Mo and Cu: 0.2 to 4%, and the balance Fe and impurities, and satisfies the following formulas (1) and (2). This steel can also have good weldability when the following formula (3) is also satisfied in addition to the formulas (1) and (2); 16.9+6.9Ni+12.5Cu?1.3Cr+3.2Mn+9.3Mo?205C?38.5N?6.5Si?120Nb?40??(1) 450?440(C+N)?12.2Si?9.5Mn?13.5Cr?20(Cu+Ni)?18.5Mo??90??(2) 8.2+30(C+N)+0.5Mn+Ni?1.1(1.5Si+Cr+Mo)+2.5Nb??0.8??(3) wherein each element symbol in the formulas (1), (2) and (3) represents the content, % by mass, of each element included in the steel.Type: GrantFiled: June 3, 2005Date of Patent: September 5, 2006Assignee: Sumitomo Metal Industries, Ltd.Inventors: Kiyoko Takeda, Haruhiko Kajimura, Mitsuo Miyahara
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Patent number: 6883701Abstract: A plurality of parts are brazed using an iron/chromium filler metal. The parts are preferably composed of stainless steel. The brazed assembly forms a heat exchanger characterized by good corrosion resistance and low rates of leaching of Ni, which are further improved by a post-brazing conditioning step in an oxygen-containing atmosphere at a temperature of about 150° to 600° C. The preferred brazing filler metal consists essentially of a composition having the formula FeaCrbCocNidMoeWfBgSih wherein the subscripts are in atom percent and total 100%, “b” is about 5 to 20, “c” ranges from 0 to about 30, “d” is 0 to about 20, “e” is 0 to about 5, “f” is 0 to about 5, “g” is about 8 to 15, “h” is about 8 to 15, the balance being incidental impurities of up to about 1 percent by weight of the total composition.Type: GrantFiled: December 2, 2003Date of Patent: April 26, 2005Assignee: Metglas, Inc.Inventors: Anatol Rabinkin, Nicholas J. DeCristofaro
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Publication number: 20040184945Abstract: An iron based brazing material for joining objects by brazing represents an alloy, which apart from iron contains 0-40% Cr, preferably 9-30% Cr, 0-16% Mn, preferably 0-8% Mn, and even more preferably 0-5% Mn, 0-25% Ni, 0-1% N and maximally 7% Mo, below 6% Si and/or 0-2% B, preferably 0-1.5% B and/or 0-15% P, all stated in weight percent, which addition of B, P, Si in combination or separately lowers the liquidus temperature, that is the temperature at which the brazing material is completely melted. A brazed product is manufactured by brazing of iron based objects with an iron based brazing material which is alloyed with a liquidus lowering element as B and/or P and/or Si.Type: ApplicationFiled: April 27, 2004Publication date: September 23, 2004Inventor: Per Erik Sjodin
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Patent number: 6773660Abstract: A hot workable ferric stainless steel alloy resistant to thermal cyclic stress and oxidation at elevated temperatures having improved mechanical properties rendering it especially suitable as a substrate for exhaust gas purifying applications, such as catalytic converters or heating applications, has a composition including (in weight-%): C ≦0.05%; Cr 16.0-24.0%; Ni more than 1.0-15.0%; Al 4.5-12.0%; Mo + W ≦4.0%; Mn ≦1.0%; Si ≦2.0%; Zr + Hf ≦0.1%; REM ≦0.1%; N ≦0.05%; and balance Fe and normally occurring steelmaking impurities and additions.Type: GrantFiled: October 2, 2002Date of Patent: August 10, 2004Assignee: Sandvik ABInventors: Magnus Cedergren, Kenneth Göransson
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Patent number: 6355212Abstract: The invention is directed to anti-corrosive alloys and relates in particular to an alloy containing cobalt, chromium, aluminum, yttrium, silicon, a metal from the second main group, together with the corresponding oxide, in the following proportions: chromium (Cr) 26.0-30%; aluminum (Al) 5.5-13.0%; yttrium (Y) 0.3-1.5%; silicon (Si) 1.5-4.5%; metal from the second main group (magnesium, calcium, barium, strontium) 0.1-2.0%; oxide of the corresponding metal from the second main group 0.1-2.0%; cobalt (Co) remaining percentage. Preferably, tantalum (Ta) is also added in a proportion of 0.5-4.0%, and the remaining percentage of cobalt is replaced by a remaining percentage of Me, Me being understood to mean a metal which may be nickel (Ni) or iron (Fe) or cobalt (Co) or a composition comprising Ni—Fe—Co, Ni—Fe, Ni—Co, Co—Fe.Type: GrantFiled: January 5, 2000Date of Patent: March 12, 2002Assignee: Turbocoating SpAInventor: Nelso Antolotti
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Patent number: 6060180Abstract: The present invention provides a highly corrosion-resistant alloy used as a boiler tube in equipment the energy source of which is obtained by burning fossil fuel or waste, a steel tube for which the alloy is used, and a process for producing the steel tube. The alloy comprises up to 0.05% of C, 1.0 to 2.6% of Si, 0.02 to 1.0% of Mn, 20.0 to 28.0% of Cr, 18.0 to 30.0% of Ni, up to 4.0% of Mo, up to 0.05% of Al, 0.05 to 0.30% of N and the balance Fe and unavoidable impurities. Furthermore, the present invention also provides a multilayer steel tube having the alloy as a liner material and a standardized boiler tube as a base layer material, and a process for producing the multilayer steel tube.Type: GrantFiled: November 2, 1997Date of Patent: May 9, 2000Assignee: Nippon Steel CorporationInventors: Tetsuo Ishitsuka, Koichi Nose
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Patent number: 6036917Abstract: An alloy having a composition, by weight, of about 0.025% or less carbon, about 0.5 to about 4.1% manganese, about 5.5 to about 6.2% silicon, about 11 to about 15% chromium, about 9.0 to about 15.5% nickel, about 0.8 to about 1.2% molybdenum and about 0.8 to about 2% copper and the remainder being essentially iron with incidental impurities. This composition results in lean alloy content in a high silicon austenitic stainless steel for concentrated sulfuric acid service while maintaining a corrosion rate similar to and competitive with existing alloys for such service. Acceptable characteristics were found when hot working was carried out in the range of about 2100.degree. F. to about 2200.degree. F. Annealing in the range of about 1925.degree. F. to about 2025.degree. F. is preferred, as is rapid water quenching after annealing.Type: GrantFiled: December 17, 1998Date of Patent: March 14, 2000Assignee: Allegheny Ludlum CorporationInventors: Dominic A. Sorace, John F. Grubb
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Patent number: 5944917Abstract: A stainless steel having excellent corrosion resistance to ozone added water, such as ozone added ultrapure water used in semiconductor manufacturing processes and the like, as well as a manufacturing method. The stainless steel comprises a base metal and an oxide film formed on the surface of the base metal, the base metal being a stainless steel which contains 12 to 30% of Cr, 0 to 35% of Ni, and 1 to 6% of Al and Si while the contents of the other alloying elements are limited to as low a level as possible, the oxide film mainly comprising Al oxide or a Si oxide or both. The oxide film may be formed on the base metal surface through the dry oxidation process or the wet oxidation process. In the stainless steel, metallic ions are rarely dissolved from the base metal into the ozone added water.Type: GrantFiled: May 29, 1997Date of Patent: August 31, 1999Assignee: Sumitomo Metal Industries, Ltd.Inventors: Kiyoko Takeda, Shigeki Azuma, Yoshio Tarutani, Yoshitaka Nishiyama, Yasushi Matsuda
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Patent number: 5749939Abstract: A multiple stage process for obtaining Ni units from Ni laterite ores and sulfur-bearing Ni concentrates during production of nickel-alloyed iron, nickel-alloyed steel or nickel-alloyed stainless steel in a reactor equipped with top- and bottom-blowing means. Dried Ni laterite ore is charged into an iron/slag bath mixture containing dissolved carbon and a metalloid reductant such as aluminum or silicon. The laterite ore is melted while heat is generated by oxidation of the metalloid and carbon in the reactor. After the laterite ore is melted, top-blowing of pure oxygen and bottom-blowing of an oxygen-containing gas are ceased. Bottom injection of an inert stirring gas is begun. A sulfur-bearing Ni concentrate and aluminum are added to the bath.Type: GrantFiled: December 4, 1996Date of Patent: May 12, 1998Assignee: Armco Inc.Inventor: David M. Kundrat
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Patent number: 5693155Abstract: For diminishing coking in a petrochemical process, coking-resistant steel containing by weight:about 0.05% to 0.06% of carbon;about 2.5% to 5% of silicon;10% to 20% of chromium;10% to 15% of nickel0.5% to 1.5% of manganese;0-0.5% of titanium;at most 0.8% of aluminium;the complement to 100% being essentially iron,can be used to manufacture tubes and plates for producing reactors or elements thereof, as well as for coatings of the internal walls of furnaces, reactors or tubings where coking can occur.Type: GrantFiled: December 20, 1995Date of Patent: December 2, 1997Assignee: Institut Francais du PetroleInventors: Valerie Mousseaux, Fran.cedilla.ois Ropital, Andre Sugier
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Stainless steel member for semiconductor fabrication equipment and surface treatment method therefor
Patent number: 5569334Abstract: Stainless steel member for semiconductor fabrication equipment having a passive state coating on the surface of the stainless steel comprising, in weight percent, 0.1% or less of C, 2.0% or less of Si, 3.0% or less of Mn, 10% or more of Ni, 15 to 25% of Cr, 1.5 to 4.5% of Mo, 0.5% or less of one or more rare earth element and Fe for substantially the whole remainder. Said passive state coating has a pitting potential of at least 900 mV (when the current density of the anode polarization curve determined with a potentiostat in 3.5% aqueous sodium chloride solution is 10 .mu.A/cm.sup.2) and has a thickness of 0.5 to 20 nm. The invention also includes a surface treatment method for the stainless steel.Type: GrantFiled: December 7, 1993Date of Patent: October 29, 1996Assignee: Hitachi Metals, Ltd.Inventors: Tsunehiro Kawata, Katsuhiko Kojo, Youichiro Kazama, Takayuki Fukaya, Toshihiko Tsujimura -
Patent number: 5565167Abstract: A stainless steel excellent in fused-salt corrosion resistance having a composition specified in weight per cent including not more than 0.1% of C, not more than 2.0% of Mn, not less than 7.5% and less than 15.0% of Ni, 14.0-20.0% of Cr, more than 0.2% and not more than 4.0% of Si, and 1.0-4.0% of Al, and in some cases also including one or more of not more than 3.0% of Cu, not more than 3.0% of Mo, not more than 1.0% of Ti, not more than 1.0% of Zr, not more than 0.5% Y, and not more than 0.5% of REM, and satisfying the relationship Si%/Al%.ltoreq.1.0, the balance being Fe and unavoidable impurities.Type: GrantFiled: July 10, 1995Date of Patent: October 15, 1996Assignee: Nisshin Steel Co., Ltd.Inventors: Nobukazu Fujimoto, Naoto Hiramatsu, Yoshihiro Uematsu
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Patent number: 5340413Abstract: Fe-Ni based soft magnetic alloys having nanocrystalline particles substantially uniformly distributed throughout an amorphous matrix are disclosed. The soft magnetic alloys of the present invention may be represented by the general formula:(Fe.sub.1-x Ni.sub.x).sub.a M.sub.b (B.sub.1-y Si.sub.y).sub.cwhere M is a metal chosen from the group consisting of Mo, Cr, Hf, Nb, Ta, Ti, V, W, Zr. The quantity "x" is between about 0.2 and about 0.9; a is between about 60 and 90; b is between about 0.1 and 10; y is between 0 and 0.5; and c is between about 0.1 and about 30, with the stipulation that all the elements, plus impurities, add up to 100. Also described is a process for making the nanocrystalline alloys and for optimizing certain magnetic properties of said alloys via a two step anneal.Type: GrantFiled: June 2, 1992Date of Patent: August 23, 1994Assignee: AlliedSignal Inc.Inventor: Ronald Martis
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Patent number: 5340534Abstract: An austenitic, stainless steel alloy having a good combination of galling resistance and corrosion resistance is disclosed containing in weight percent about:______________________________________ Broad Intermediate Preferred ______________________________________ C 0.25 max. 0.02-0.15 0.05-0.12 Mn 3-10 4-8 5-7 Si 2.25-5 2.5-4.5 3-4 Cr 15-23 16.5-21 17.5-19 Ni 2-12 4-10 6-9 Mo 0.5-4.0 0.5-2.5 0.75-1.5 N 0.35 max. 0.05-0.25 0.10-0.20 ______________________________________and the balance of the alloy is essentially iron. This alloy also has good resistance to formation of deformation-induced martensite as indicated by the alloy's low work-hardening rate and low magnetic permeability when cold-rolled to a 50% reduction in cross-sectional area.Type: GrantFiled: August 24, 1992Date of Patent: August 23, 1994Assignee: CRS Holdings, Inc.Inventor: John H. Magee
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Patent number: 5338616Abstract: A far-infrared emitter of high corrosion resistance is prepared by an oxidizing heat treatment of a body made from a stainless steel of 20-35% by weight of chromium, 0.5-5.0% by weight of molybdenum, up to 3.0% by weight of manganese and up to 3.0% by weight of silicon at 900.degree.-1200.degree. C. to form an oxidized surface film having a thickness of at least 0.2 mg/cm.sup.2. Further, a far-infrared emitter of a high emissivity approximating a black body is prepared by subjecting a body made from a stainless steel of 10-35% by weight of chromium, 1.0-4.0% by weight of silicon and up to 3.0% by weight of manganese to a blasting treatment to roughen the surface followed by an oxidizing heat treatment at 900.degree.-1200.degree. C. to form an oxide film on the surface in the form of protrusions having a length of at least 5 .mu.m.Type: GrantFiled: April 8, 1993Date of Patent: August 16, 1994Assignees: Kawasaki Steel Corporation, Osaka Gas Co., Ltd.Inventors: Kazuhide Ishii, Tatsuo Kawasaki, Noriyuki Kuriyama, Shoji Dohi, Akio Nakashiba, Souhei Miyazaki
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Patent number: 5320801Abstract: Air-meltable, castable, machinable, hardenable alloys that are resistant to highly corrosive and abrasive slurries, especially those employed in the handling of wet-process phosphoric acid reactor fluids or hot concentrated sulfuric acid. The alloys consist of, by weight, about 11% to about 40% nickel (plus cobalt), about 27% to about 42% chromium, about 1% to about 4% copper, about 3% to about 4.5% silicon, about 0.7% to about 2% carbon, about 0.3% to about 3% manganese, up to about 4.5% molybdenum, and the balance essentially iron plus the usual minor impurities.Type: GrantFiled: April 26, 1993Date of Patent: June 14, 1994Assignee: Carondelet Foundry CompanyInventor: John H. Culling
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Patent number: 5316721Abstract: A heat-resistant alloy having a high creep rupture strength under high-temperature low-stress conditions and excellent resistance to carburization even when used at a high temperature exceeding 1100.degree. C. The alloy comprises, in % by weight, more than 0.1% to less than 1.5% of C, more than 2% to less than 3% of Si, more than 0% to less than 2% of Mn, more than 20% to less than 30% of Cr, more than 25% to less than 40% of Ni, more than 0.6% to less than 2% of Al, and the balance Fe and inevitable impurities. When required, the alloy contains at least one component selected from the group consisting of 0.01 to 0.5% of Zr, up to 0.2% of N, 0.2 to 2.0% of Nb, 0.2 to 2.0% of W and 0.01 to 03% of Ti.Type: GrantFiled: December 30, 1991Date of Patent: May 31, 1994Assignee: Kubota CorporationInventors: Junichi Sugitani, Masahiro Inui, Koji Tsuchida, Teruo Yoshimoto
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Patent number: 5306464Abstract: Air-meltable, castable, machinable, tough, silicon containing, chromium-nickel-iron alloys that are resistant to hot concentrated sulfuric acid and to abrasive or erosive action of grit or vapor bubbles in the acid. The alloys consist of, by weight, about 15% to about 25% nickel, from about 15% to about 26% chromium, from about 4.5% to about 8% silicon, from about 1% to about 4% copper, from about 0.3% to about 3% molybdenum, from about 0.5% to about 1.7% carbon, up to about 1.5% manganese, and the balance substantially iron plus the usual impurities and incidental tramp elements.Type: GrantFiled: April 5, 1993Date of Patent: April 26, 1994Assignee: Carondelet Foundry CompanyInventor: John H. Culling
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Patent number: 5296054Abstract: The invention relates to a high-silicon-content corrosion-resistant austenitic steel, characterized by alloying contents (in % by weight) of______________________________________ max. 0.2% C 10 to 25% Ni 8 to 13% Cr 6.5 to 8% Si 0 to 10% Mn and/or Co max. 0.010% S max. 0.025% P ______________________________________residue iron and the usual admixtures and impurities due to manufacture.The steel is suitable as a material for the production of corrosion-resistant articles for the handling of highly concentrated hot sulphuric acid, highly concentrated hot nitric acid and other strongly oxidizing media, such as chromic acid, in the form of rolled plates, strips, pipes, rods, wires and other forms of product.Type: GrantFiled: June 4, 1992Date of Patent: March 22, 1994Assignees: I.P. Bardin Central Research Institute of Iron & Steel, Krupp-VDM GmbHInventors: Levin F. Lvovich, Goronkova A. Dmitrievna, Kzasnykh V. Ivanovich, Rolf Kirchheiner, Michael Kohler, Ulrich Heubner
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Patent number: 5252148Abstract: A soft magnetic alloy having a composition of general formula:(Fe.sub.1-a Ni.sub.a).sub.100-x-y-z-p-q Cu.sub.x Si.sub.y B.sub.z Cr.sub.p M.sup.1.sub.q (I)wherein M.sup.1 is V or Mn or a mixture of V and Mn, 0.ltoreq.a.ltoreq.0.5, 0.1.ltoreq.x.ltoreq.5, 6.ltoreq.y.ltoreq.20, 6.ltoreq.z.ltoreq.20, 15.ltoreq.y+z.ltoreq.30, 0.5.ltoreq.p.ltoreq.10, and 0.5.ltoreq.q.ltoreq.10 and possessing a fine crystalline phase is suitable as a core, especially a wound core and a compressed powder core.Type: GrantFiled: August 10, 1992Date of Patent: October 12, 1993Assignee: TDK CorporationInventors: Masao Shigeta, Asako Kajita, Ippo Hirai, Tsutomu Choh
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Patent number: 5244513Abstract: Ferrous group shape memory alloys consisting essentially of Cr: 16.0-21.0 wt %, Si: 3.0-7.0 wt % and Ni: 11.0-21.0 wt % and satisfying Ni wt %.gtoreq.[0.67.times.{Cr+1.2.times.(Si+Ti+Zr+Hf+V+Nb+Ta)}-] wt % and (Cr+Si) wt %.gtoreq.20 wt %, these ferrous-group shape-memory alloys having a corrosion resistance, a shape-memorizing properties, an intergranular corrosion resistance and a stress corrosion cracking resistance in nitric acid for nuclear fuel reprocessing plants and high-temperature, high-pressure water for light-water reactors.Type: GrantFiled: March 27, 1992Date of Patent: September 14, 1993Assignees: Mitsubishi Jukogyo Kabushiki Kaisha, NKK CorporationInventors: Yoshikuni Kadoya, Toshio Yonezawa, Naotake Ito, Toru Inazumi, Yutaka Moriya, Haruo Suzuki, Katsumi Masamura, Takemi Yamada
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Patent number: 5151248Abstract: An austenitic stainless steel for use for high temperature concentrated sulfuric acid which comprises, on weight basis, 0.04% or less of C, 5-7% of Si, 2% or less of Mn, 15-25% of Cr, 4-24% of Ni, 0.01-1.07% of Pd and the rest consisting of Fe and unavoidable contaminant materials. By the incorporation of small amount of palladium in a basal austenitic stainless steel containing the essential three elements of Cr, Ni and Si, a superior corrosion resistance against highly concentrated high temperature sulfuric acid is attained.Type: GrantFiled: December 13, 1991Date of Patent: September 29, 1992Assignee: Mitsubishi Jukogyo Kabushiki KaishaInventors: Ryuichiro Ebara, Hideo Nakamoto, Naohiko Ukawa, Tamotsu Yamada, Yasuo Nishimura
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Patent number: 5147475Abstract: The invention relates to a high silicon containing stainless steel alloy in which the amounts of the alloy elements have been balanced such that the austenite phase remains stable without being deformed into martensite even under large amounts of working. The steel alloy comprises 0.04-0.25% C, 2.0-5.0% Si, 3.5-7.5% Mn, 16-21% Cr, 8-11% Ni, 0.10-0.45% N, the remainder being iron and normal impurities.Type: GrantFiled: February 26, 1991Date of Patent: September 15, 1992Assignee: Sandvik ABInventor: Hakan Holmberg
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Patent number: 5120496Abstract: In the processing of hot concentrated sulfuric acid or oleum in steel apparatus, the improvement wherein said apparatus is formed of an alloyed material comprising an iron-chrome-nickel-silicon alloy containing 13 to 32% by weight Cr, 5 to 25% by weight nickel and 4 to 9% by weight Si and having a structure containing more than 10% delta-ferrite.Type: GrantFiled: September 14, 1990Date of Patent: June 9, 1992Assignee: Bayer AktiengesellschaftInventors: Elmar-Manfred Horn, Stylianos Savakis
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Patent number: 5051233Abstract: In the processing of hot concentrated sulfuric acid or oleum in steel apparatus, the improvement wherein said apparatus is formed of an alloyed material comprising an iron-chrome-nickel-silicon alloy containing 13 to 32% by weight Cr, 5 to 25% by weight nickel and 4 to 9% by weight Si and having a structure containing more than 10% delta-ferrite.Type: GrantFiled: January 11, 1990Date of Patent: September 24, 1991Assignee: Bayer AktiengesellschaftInventors: Elmar-Manfred Horn, Stylianos Savakis
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Patent number: 5028396Abstract: Apparatus for the manufacture of sulphuric acid comprising at least one gas-concentrated sulphuric acid contacting unit and a sulphuric acid heat exchanger. The contacting unit and/or the heat exchanger is formed of high silicon content austenitic steel.Type: GrantFiled: July 25, 1990Date of Patent: July 2, 1991Assignee: Chemetics International Company, Ltd.Inventors: Frederick W. S. Jones, Frank Smith
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Patent number: 4999158Abstract: This invention relates to iron-base alloy compositions, nickel containing austenitic ferrous alloy compositions (especially low nickel compositions) and dopants added to low nickel austenitic alloys as a means of improving the elevated temperature oxidation resistance of the resultant material.Type: GrantFiled: November 2, 1988Date of Patent: March 12, 1991Assignee: Chrysler CorporationInventor: John M. Corwin
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Patent number: 4999159Abstract: A heat-resistant austenitic stainless steel is disclosed. This steel essentially consists of: not more than 0.06% C, 1-4% Si, 0.5-4% mn, not more than 0.035% P, not more than 0.005% S, 10-17% Ni, 14-20% Cr, 1-4% Mo, 0.01-0.5% Al, not more than 0.035% N, and balance essentially Fe, and may further contain small amounts of any of Cu, REM and B and the composition thereof is adjusted so that a limited amount of .delta.-ferrite appears in solidification. The steel has excellent hot salt corrosion resistance, weldability, salt errosion resistance of the weld and hot-workability.Type: GrantFiled: February 13, 1990Date of Patent: March 12, 1991Assignee: Nisshin Steel Company, Ltd.Inventors: Yoshihiro Uematsu, Isami Shimizu, Naoto Hiramatsu
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Patent number: 4933143Abstract: An austenitic stainless steel having excellent corrosion resistance in hot aqueous medium is disclosed. The steel essentially consists by weight ofC: not more than 0.08%Si: 2.5-4.0%Mn: not more than 0.8%P: not more than 0.045%S: not more than 0.005%Cr: 16-25%Ni: 6-20%Cu: 1.5-4.0%N: not more than 0.05%and the balance Fe and unavoidable incidental impurities.Type: GrantFiled: August 29, 1988Date of Patent: June 12, 1990Assignee: Nisshin Steel Company, Ltd.Inventors: Toshiro Adachi, Atsushi Fujii, Isamu Yoshimura, Tsuguyasu Yoshii
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Patent number: 4933027Abstract: An iron-based shape-memory alloy excellent in a shape-memory property, a corrosion resistance and a high-temperature oxidation resistance, consisting essentially of:chromium: from 5.0 to 20.0 wt. %,silicon: from 2.0 to 8.0 wt. %,at least one element selected from the group consisting of:manganese: from 0.1 to 14.8 wt. %,nickel: from 0.1 to 20.0 wt. %,cobalt: from 0.1 to 30.0 wt. %,copper: from 0.1 to 3.0 wt. %, andnitrogen: from 0.001 to 0.400 wt. %,whereNi+0.5 Mn+0.4 Co+0.06 Cu+0.002 N.gtoreq.0.67 (Cr+1.2 Si)-3,and the balance being iron and incidental impurities.Type: GrantFiled: February 23, 1989Date of Patent: June 12, 1990Assignee: NKK CorporationInventors: Yutaka Moriya, Tetsuya Sanpei, Hisatoshi Tagawa
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Patent number: 4929289Abstract: An iron-based shape-memory alloy excellent in a shape-memory property and a corrosion resistance, consisting essentially of:______________________________________ chromium: from 0.1 to 5.0 wt. %, silicon: from 2.0 to 8.0 wt. %, manganese: from 1.0 to 14.8 wt. %, at least one element selected from the group consisting of: nickel: from 0.1 to 20.0 wt. %, cobalt: from 0.1 to 30.0 wt. %, copper: from 0.1 to 3.0 wt. %, and nitrogen: from 0.001 to 0.400 wt. %, where, Ni + 0.5 Mn + 0.4 Co + 0.06 Cu + 0.002 N .gtoreq. 0.67 (Cr + 1.2 Si), and the balance being iron and incidental impurities.Type: GrantFiled: February 23, 1989Date of Patent: May 29, 1990Assignee: NKK CorporationInventors: Yutaka Moriya, Tetsuya Sanpei, Hisatoshi Tagawa
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Patent number: 4917860Abstract: Alloys are provided which consist essentially of between about 4% and 18.5% by weight nickel, from about 24% to about 30% by weight chromium, from about 0.35 to about 1% by weight molybdenum, from about 2.7% to about 4.5% by weight copper, from about 2.7% to about 4.5% by weight silicon, up to about 1.5% by weight manganese, up to about 0.25% by weight nitrogen, up to about 0.8% by weight columbium (niobium), up to about 1.0% by weight tantalum, up to about 0.007% by weight boron, up to about 0.35% by weight vanadium, up to about 0.8% by weight tungsten, up to about 0.08% by weight carbon, up to about 0.6% by weight titanium and the balance essentially iron. Small amounts of cobalt as naturally occur in some ores may be present but are considered a part of the nickel content.Type: GrantFiled: January 10, 1989Date of Patent: April 17, 1990Assignee: Carondelet Foundry CompanyInventor: John H. Culling
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Patent number: 4826655Abstract: A new cast high silicon heat resistant alloy is provided having the broad composition of about 0.16 to 0.30% carbon, about 3.2 to 4.5% silicon, about 0.8 to 1.5% aluminum, about 17 to 20% chromium, about 12 to 16% nickel, up to about 2% manganese, 0 to 0.07% rare earth alloys and the balance iron with residual impurities in ordinary amounts. The alloy is an austenitic chromium and nickel containing alloy having high strength and corrosion resistance.Type: GrantFiled: November 25, 1987Date of Patent: May 2, 1989Assignee: Rolled Alloys, Inc.Inventor: Gene Rundell
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Patent number: 4802894Abstract: A structural member to be subjected to a hot gas atmosphere produced through reaction between coal and a gasifier such as oxygen, air, steam or hydrogen, in a gasification furnace for example. The structural member is made of an anti-sulfur attack Cr-Ni-Al-Si alloy steel which has a composition essentially consisting of, by weight, 0.03 to 0.3% of C, 1 to 10% of Si, not greater than 2.0% of Mn, 8 to 14% of Ni, 16 to 20% of Cr, 0.5 to 10% of Al and the balance not less than 50% of Fe.Type: GrantFiled: January 12, 1987Date of Patent: February 7, 1989Assignee: Hitachi, Ltd.Inventors: Kenichi Usami, Seishin Kirihara, Tadaoki Morimoto, Hiroyuki Doi, Michiya Okada