Silver Containing Patents (Class 420/539)
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Patent number: 8845827Abstract: The present application discloses wrought 2xxx Al—Li alloy products that are work insensitive. The wrought aluminum alloy products generally include from about 2.75 wt. % to about 5.0 wt. % Cu, from about 0.2 wt. % to about 0.8 wt. % Mg, where the ratio of copper-to-magnesium ratio (Cu/Mg) in the aluminum alloy is in the range of from about 6.1 to about 17, from about 0.1 wt. % to 1.10 wt. % Li, from about 0.3 wt. % to about 2.0 wt. % Ag, from 0.50 wt. % to about 1.5 wt. % Zn, up to about 1.0 wt. % Mn, the balance being aluminum, optional incidental elements, and impurities. The wrought aluminum alloy products may realize a low strength differential and in a short aging time due to their work insensitive nature.Type: GrantFiled: April 11, 2011Date of Patent: September 30, 2014Assignee: Alcoa Inc.Inventors: Cagatay Yanar, Roberto J. Rioja, Jen C. Lin, Ralph R. Sawtell
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Patent number: 8771441Abstract: An aluminum alloy comprising 2.1 to 2.8 wt. % Cu, 1.1 to 1.7 wt. % Li, 0.1 to 0.8 wt. % Ag, 0.2 to 0.6 wt. % Mg, 0.2 to 0.6 wt. % Mn, a content of Fe and Si less or equal to 0.1 wt. % each, and a content of unavoidable impurities less than or equal to 0.05 wt. % each and 0.15 wt. % total, and the alloy being substantially zirconium free.Type: GrantFiled: December 18, 2006Date of Patent: July 8, 2014Inventors: Bernard Bes, Herve Ribes, Christophe Sigli, Timothy Warner
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Patent number: 8444777Abstract: An object of the present invention is to provide an Al—Zn—Mg—Cu 7000-series Al alloy having high ductility as well as having high strength. For attaining this purpose, an Al alloy having a structure in which an inclusion is not included is produced by reducing an amount of oxygen contained in an Al alloy that is obtained by solidifying a preform resulting from rapid solidification by preferably spray forming a molten metal of an Al—Zn—Mg—Cu 7000-series Al alloy with an inert gas. This Al alloy has, as mechanical properties at an ordinary temperature, a tensile strength of 600 MPa or more, and an elongation of 15% or more when the tensile strength is from 600 MPa or more and less than 800 MPa or an elongation of 10% or more when the tensile strength is 800 MPa or more, and is excellent in cold workability such as rollability.Type: GrantFiled: February 20, 2008Date of Patent: May 21, 2013Assignee: Kobe Steel, Ltd.Inventors: Hideo Hata, Katsura Kajihara, Shigenobu Namba, Hiroyuki Takeda, Mamoru Nagao
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Patent number: 8366839Abstract: The present invention relates to extruded, rolled and/or forged products. Also provided are methods of making such products based on aluminum alloy wherein a liquid metal bath is prepared comprising 2.0 to 3.5% by weight of Cu, 1.4 to 1.8% by weight of Li, 0.1 to 0.5% by weight of Ag, 0.1 to 1.0% by weight of Mg, 0.05 to 0.18% by weight of Zr, 0.2 to 0.6% by weight of Mn and at least one element selected from Cr, Sc, Hf and Ti, the quantity of said element, if it is selected, being 0.05 to 0.3% by weight for Cr and for Sc, 0.05 to 0.5% by weight for Hf and 0.01 to 0.15% by weight for Ti, the remainder being aluminum and inevitable impurities. The products and methods of the present invention offer a particularly advantageous compromise between static mechanical strength and damage tolerance and are particularly useful in the field of aeronautical design.Type: GrantFiled: November 13, 2009Date of Patent: February 5, 2013Assignee: Constellium FranceInventors: Fabrice Heymes, Frank Eberl, Gaëlle Pouget
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Patent number: 8118950Abstract: Improved aluminum-copper-lithium alloys are disclosed. The alloys may include 3.4-4.2 wt. % Cu, 0.9-1.4 wt. % Li, 0.3-0.7 wt. % Ag, 0.1-0.6 wt. % Mg, 0.2-0.8 wt. % Zn, 0.1-0.6 wt. % Mn, and 0.01-0.6 wt. % of at least one grain structure control element, the balance being aluminum and incidental elements and impurities. The alloys achieve an improved combination of properties over prior art alloys.Type: GrantFiled: December 4, 2008Date of Patent: February 21, 2012Assignee: Alcoa Inc.Inventors: Edward L. Colvin, Roberto J. Rioja, Les A. Yocum, Diana K. Denzer, Todd K. Cogswell, Gary H. Bray, Ralph R. Sawtell, Andre L. Wilson
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Patent number: 8043445Abstract: The invention relates to an aluminium alloy wrought product with high strength and fracture toughness and high fatigue resistance and low fatigue crack growth rate, and having a composition for the alloy comprising, in weight %, about 0.3 to 1.0% magnesium (Mg), about 4.4 to 5.5% copper (Cu), about 0 to 0.20% iron (Fe), about 0 to 0.20% silicon (Si), about 0 to 0.40% zinc (Zn), and Mn in a range 0.15 to 0.8 as a dispersoids forming element in combination with one or more of dispersoids forming elements selected from the group consisting of: (Zr, Sc, Cr, Hf, Ag, Ti, V), in ranges of: about 0 to 0.5% zirconium (Zr), about 0 to 0.7% scandium (Sc), about 0 to 0.4% chromium (Cr), about 0 to 0.3% hafnium (Hf), about 0 to 0.4% titanium (Ti), about 0 to 1.0% silver (Ag), the balance being aluminium (Al) and other incidental elements, and whereby there is a limitation of the Cu—Mg content such that ?1.1[Mg]+5.38?[Cu]?5.5. The invention further relates to a method of manufacturing such a product.Type: GrantFiled: May 28, 2004Date of Patent: October 25, 2011Assignee: Aleris Aluminum Koblenz GmbHInventors: Rinze Benedictus, Christian Joachim Keidel, Alfred Ludwig Heinz, Hinrich Johannes Wilhelm Hargarter
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Patent number: 7972631Abstract: The present invention provides novel compositions and methods for pharmaceutical or nutraceutical use in an animal, preferably in a human. In one aspect, compositions and methods are provided for promoting cell growth, tissue repair and organ regeneration, preferably in vivo and in situ. The composition comprises a sterol compound dissolved in oil at a concentration at least 0.5% by weight. The compositions may be used in the treatment of various conditions caused by injury, diseases and aging. As shown clinically, the methodology disclosed in the present invention was used successfully to regenerate or clone a new organ through cultivation of regenerative stem cells in vivo and in situ.Type: GrantFiled: December 15, 2005Date of Patent: July 5, 2011Inventor: Rongxiang Xu
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Patent number: 7744704Abstract: A low density aluminum based alloy useful in aircraft structure for fuselage sheet or light-gauge plate applications which has high strength, high fracture toughness and high corrosion resistance, comprising 2.7 to 3.4 weight percent Cu, 0.8 to 1.4 weight percent Li, 0.1 to 0.8 weight percent Ag, 0.2 to 0.6 weight percent Mg and a grain refiner such as Zr, Mn, Cr, Sc, Hf, Ti or a combination thereof, the amount of which being 0.05 to 0.13 wt. % for Zr, 0.1 to 0.8 wt. % for Mn, 0.05 to 0.3 wt. % for Cr and Sc, 0.05 to 0.5 wt. % for Hf and 0.05 to 0.15 wt. % for Ti. The amount of Cu and Li preferably corresponds to the formula Cu(wt. %)+5/3 Li(wt. %)<5.2.Type: GrantFiled: June 5, 2006Date of Patent: June 29, 2010Assignee: Alcan RhenaluInventors: Bernard Bés, Hervé Ribes, Christophe Sigli, Timothy Warner
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Patent number: 7704333Abstract: An aluminum alloy having improved strength and ductility, comprising: Cu 3.5-5.8 wt. %, Mg 0.2-1.5 wt. % Mn 0.2-0.5 wt. % Ag 0.2-0.8 wt. % Ti 0.02-0.12 wt. % and optionally one or more selected from the group consisting of Cr 0.1-0.8 wt. %, Hf 0.1-1.0 wt. %, Sc 0.03-0.6 wt. %, and V 0.05-0.15 wt. %, balance aluminum and incidental elements and impurities, and wherein the alloy is substantially zirconium-free.Type: GrantFiled: January 19, 2007Date of Patent: April 27, 2010Assignees: Alean Rolled Products Ravenswood LLC, Alean RhenaluInventors: Alex Cho, Vic Dangerfield, Bernard Bès, Timothy Warner
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Patent number: 7572521Abstract: The invention relates to an aluminium alloy used as a coating for surfaces subjected to extreme friction stress, with an aluminium matrix incorporating at least a soft phase and a hard phase, as well as a process for producing the coating. The soft phase and/or the hard phase is essentially finely distributed in the aluminium matrix (20) and at least 80%, preferably at least 90%, of the soft phase or soft phase particles (18) have a mean diameter of a maximum of 3 ?m. The aluminium alloy is produced by depositing it on the base (11) by a process of deposition from a gas phase.Type: GrantFiled: August 3, 2005Date of Patent: August 11, 2009Assignee: Miba Gleitlager GmbHInventors: Robert Mergen, Walter Gärtner
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Patent number: 7547366Abstract: The invention provides a 2000 series aluminum alloy having enhanced damage tolerance, the alloy consisting essentially of about 3.0-4.0 wt % copper; about 0.4-1.1 wt % magnesium; up to about 0.8 wt % silver; up to about 1.0 wt % Zn; up to about 0.25 wt % Zr; up to about 0.9 wt % Mn; up to about 0.5 wt % Fe; and up to about 0.5 wt % Si, the balance substantially aluminum, incidental impurities and elements, said copper and magnesium present in a ratio of about 3.6-5 parts copper to about 1 part magnesium. The alloy is suitable for use in wrought or cast products including those used in aerospace applications, particularly sheet or plate structural members, extrusions and forgings, and provides an improved combination of strength and damage tolerance.Type: GrantFiled: July 15, 2004Date of Patent: June 16, 2009Assignee: Alcoa Inc.Inventors: Jen C. Lin, John M. Newman, Paul E. Magnusen, Gary H. Bray
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Patent number: 7449073Abstract: The invention provides a 2000 series aluminum alloy having enhanced damage tolerance, the alloy consisting essentially of about 3.0-4.0 wt % copper; about 0.4-1.1 wt % magnesium; up to about 0.8 wt % silver; up to about 1.0 wt % Zn; up to about 0.25 wt % Zr; up to about 0.9 wt % Mn; up to about 0.5 wt % Fe; and up to about 0.5 wt % Si, the balance substantially aluminum, incidental impurities and elements, said copper and magnesium present in a ratio of about 3.6-5 parts copper to about 1 part magnesium. The alloy is suitable for use in wrought or cast products including those used in aerospace applications, particularly sheet or plate structural members, extrusions and forgings, and provides an improved combination of strength and damage tolerance.Type: GrantFiled: September 7, 2005Date of Patent: November 11, 2008Assignee: Alcoa Inc.Inventors: Jen C. Lin, John M. Newman, Paul E. Magnusen, Gary H. Bray
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Patent number: 7438772Abstract: An aluminum-copper-magnesium alloy having ancillary additions of lithium. The alloy composition includes from about 3 to about 5 weight percent Cu, from about 0.5 to about 2 weight percent Mg, and from about 0.01 to about 0.9 weight percent Li. The combined amount of Cu and Mg is maintained below a solubility limit of the aluminum alloy. The alloys possess improved combinations of fracture toughness and strength, and also exhibit good fatigue crack growth resistance.Type: GrantFiled: October 3, 2003Date of Patent: October 21, 2008Assignee: Alcoa Inc.Inventors: Roberto J. Rioja, Gary H. Bray, Paul E. Magnusen
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Patent number: 7229509Abstract: An improved aluminum lithium alloy comprising 0.1 to 2.5 wt. % Li, 2.5 to 5.5 wt. % Cu, 0.2 to 1.0 wt. % Mg, 0.2 to 0.8 wt. % Ag, 0.2 to 0.8 wt. % Mn, up to 0.4 wt. % Zr or other grain refiner such as chromium, titanium, hafnium, scandium or vanadium, the balance aluminum. The present alloy exhibits an improved combination of strength and fracture toughness, over any thickness range. The present invention is further directed to methods for preparing and using Al—Li alloys as well as to products comprising the same.Type: GrantFiled: May 26, 2004Date of Patent: June 12, 2007Assignee: Alcan Rolled Products Ravenswood, LLCInventor: Alex Cho
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Patent number: 7229508Abstract: An aluminum alloy having improved strength and ductility, comprising: Cu 3.5–5.8 wt. %, Mg 0.1–1.8 wt. % Mn 0.1–0.8 wt. % Ag 0.2–0.8 wt. % Ti 0.02–0.12 wt. % and optionally one or more selected from the group consisting of Cr 0.1–0.8 wt. %, Hf 0.1–1.0 wt. %, Sc 0.03–0.6 wt. %, and V 0.05–0.15 wt. %. balance aluminum and incidental elements and impurities, and wherein the alloy is substantially zirconium-free.Type: GrantFiled: May 26, 2004Date of Patent: June 12, 2007Assignees: Alcan Rolled Products-Ravenswood, LLC, Alcan RhenaluInventors: Alex Cho, Vic Dangerfield, Bernard Bès, Timothy Warner
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Patent number: 7214279Abstract: An Al/Cu/Mg/Mn alloy for the production of semi-finished products with high static and dynamic strength properties has the following composition: 0.3–0.7 wt % silicon (Si), max. 0.15 wt. % iron (Fe), 3.5–4.5 wt % copper (Cu), 0.1–0.5 wt. % manganese (Mn), 0.3–0.8 wt. % magnesium (Mg), 0.5–0.15 wt % titanium (Ti), 0.1–0.25 wt % zirconium (Zr), 0.3–0.7 wt. % silver (Ag), max. 0.05 wt. % others individually, max 0.15 wt. % others globally, the remaining wt. % aluminum (Al). The invention further relates to a semi-finished product made for such an alloy and a method of production of a semi-finished product made for such an alloy.Type: GrantFiled: June 29, 2002Date of Patent: May 8, 2007Assignee: Otto Fuchs KGInventors: Gernot Fischer, Dieter Sauer, Gregor Terlinde
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Patent number: 6126898Abstract: An aluminum-copper alloy comprising substantially insoluble particles which occupy the interdendritic regions of the alloy.Type: GrantFiled: March 4, 1999Date of Patent: October 3, 2000Assignee: Aeromet International PLCInventor: Simon Andrew Butler
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Patent number: 5879475Abstract: There is claimed a forged structural member suitable for aerospace applications and having improved combinations of strength and toughness. The member is made from a substantially vanadium-free, lithium-free aluminum-based alloy consisting essentially of: about 4.85-5.3 wt. % copper, about 0.5-1.0 wt. % magnesium, about 0.4-0.8 wt. % manganese, about 0.2-0.8 wt. % silver, about 0.05-0.25 wt. % zirconium, up to about 0.1 wt. % silicon, and up to about 0.1 wt. % iron, the balance aluminum, incidental elements and impurities, the Cu:Mg ratio of said alloy being between about 5 and 9, and more preferably between about 6.0 and 7.5. The invention exhibits a typical longitudinal tensile yield strength of about 71 ksi or higher at room temperature and can be forged into aircraft wheels or various brake and other product forms.Type: GrantFiled: April 8, 1997Date of Patent: March 9, 1999Assignee: Aluminum Company of AmericaInventor: Lynette M. Karabin
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Patent number: 5738735Abstract: A high creep resistance aluminum alloy containing, in percent by weight:Cu: 2.0-3.0;Mg: 1.5-2.1;Mn: 0.3-0.7;Fe<0.3;Ni<0.3;Zr<0.15;Ti<0.15;Ag<1.0;Si<0.6;with Si and Ag in amounts such that 0.3<Si+0.4Ag<0.6; other elements <0.05 each and <0.15 total; and balance Al. The alloy has in its wrought state after being treated by natural aging, quenching and aging, a creep strain after 1,000 h at 150.degree. C. under a stress of 250 MPA of less than 0.3% and a fracture time of at least 2,500 h, and can be used for structural parts for aircraft or spacecraft, rotating machine parts, or plastic processing molds.Type: GrantFiled: July 25, 1996Date of Patent: April 14, 1998Assignee: Pechiney RhenaluInventor: Denis Bechet
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Patent number: 5667600Abstract: Disclosed is a practical aluminum-based alloy containing 1 to 99 weight percent beryllium and improved methods for the investment casting of net shape aluminum-beryllium alloy parts.Type: GrantFiled: March 31, 1994Date of Patent: September 16, 1997Assignee: Brush Wellman, Inc.Inventors: Fritz C. Grensing, James M. Marder, Jere H. Brophy
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Patent number: 5630889Abstract: An extruded structural member suitable for aerospace applications and having improved combinations of strength and toughness. The member is made from a substantially vanadium-free aluminum-based alloy consisting essentially of: about 4.85-5.3 wt. % copper, about 0.5-1.0 wt. % magnesium, about 0.4-0.8 wt. % manganese, about 0.2-0.8 wt. % silver, about 0.05-0.25 wt. % zirconium, up to about 0.1 wt. % silicon, and up to about 0.1 wt. % iron, the balance aluminum, incidental elements and impurities, the Cu:Mg ratio of said alloy being between about 5 and 9, and more preferably between about 6.0 and 7.5. The invention exhibits a typical tensile yield strength of about 77 ksi or higher at room temperature and can be forged into aircraft wheels or extruded into various other product forms for use as high speed aircraft wing members, e.g. stringers or the like.Type: GrantFiled: March 22, 1995Date of Patent: May 20, 1997Assignee: Aluminum Company of AmericaInventor: Lynette M. Karabin
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Patent number: 5593516Abstract: An aluminum-based alloy composition having improved combinations of strength and fracture toughness consists essentially of 2.5-5.5 percent copper, 0.10-2.30 percent magnesium, with minor amounts of grain refining elements, dispersoid additions and impurities and the balance aluminum. The amounts of copper and magnesium are controlled such that the solid solubility limit for these elements in aluminum is not exceeded. The inventive alloy composition may also include 0.10-1.00 percent silver for improved mechanical properties. The alloys are useful as high strength, high fracture toughness components for aircraft and aerospace structural parts.Type: GrantFiled: June 7, 1995Date of Patent: January 14, 1997Assignee: Reynolds Metals CompanyInventor: William A. Cassada, III
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Patent number: 5512241Abstract: Weld filler alloys comprising aluminum, copper, lithium and, optionally, silver are disclosed which possess significantly improved fabricability and weldability. The weld filler alloys are free of magnesium and can be easily drawn into weld wire that is useful for welding aluminum-base alloys. Weldments made with the filler alloys exhibit highly improved mechanical, physical and corrosion resistance properties. The weld filler alloys may be used to weld cryogenic containers for space launch vehicles and the like.Type: GrantFiled: April 13, 1994Date of Patent: April 30, 1996Assignee: Martin Marietta CorporationInventors: Lawrence S. Kramer, Joseph R. Pickens, Carl E. Cross
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Patent number: 5512112Abstract: A process for producing an aluminum-based alloy composition having improved combinations of strength and fracture toughness. The process includes casting an ingot consisting essentially of 2.5-5.5 percent copper, 0.10-2.30 percent magnesium, with minor amounts of grain refining elements, dispersoid additions and impurities and the balance aluminum. The amounts of copper and magnesium are controlled such that the solid solubility limit for these elements in aluminum is not exceeded. The alloy composition also includes 0.10-1.00 percent silver for improved mechanical properties. The ingot, in accordance with the inventive process, is homogenized and worked to produce a product. The product is solution heat treated to obtain a saturated solid solution and then aged to develop an improved combination of high strength and fracture toughness.Type: GrantFiled: June 27, 1994Date of Patent: April 30, 1996Assignee: Reynolds Metals CompanyInventor: William A. Cassada, III
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Patent number: 5455003Abstract: A method is disclosed for the production of aluminum-copper-lithium alloys that exhibit improved strength and fracture toughness at cryogenic temperatures. Improved cryogenic properties are achieved by controlling the composition of the alloy, along with processing parameters such as the amount of cold-work and artificial aging. The ability to attain substantially equal or greater strength and fracture toughness at cryogenic temperature in comparison to room temperature allows for use of the alloys in cryogenic tanks for space launch vehicles and the like.Type: GrantFiled: August 10, 1993Date of Patent: October 3, 1995Assignee: Martin Marietta CorporationInventors: Joseph R. Pickens, William T. Tack
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Patent number: 5211910Abstract: Aluminum-base alloys containing Cu, Li, Zn, Mg and Ag are disclosed which possess highly desirable properties, such as relatively low density, high modulus, high strength/ductility combinations, strong natural aging response with and without prior cold work, and high artificially aged strength with and without prior cold work. In addition, the alloys possess good weldability, corrosion resistance, cryogenic properties, and elevated temperature properties. The alloys may comprise from about 1 to about 7 weight percent Cu, from about 0.1 to about 4 weight percent Li, from about 0.01 to about 4 weight percent Zn, from about 0.05 to about 3 weight percent Mg, from about 0.01 to about 2 weight percent Ag, from about 0.01 to about 2 weight percent grain refiner selected from Zr, Cr, Mn, Ti, Hf, V, Nb, B and TiB.sub.2, and the balance Al along with incidental impurities. Preferred alloys comprise from about 3.0-6.5 weight percent Cu, from about 0.5-2.6 weight percent Li, from about 0.Type: GrantFiled: January 26, 1990Date of Patent: May 18, 1993Assignee: Martin Marietta CorporationInventors: Joseph R. Pickens, Timothy J. Langan, Frank H. Heubaum, Lawrence S. Kramer, Alex Cho
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Patent number: 5169462Abstract: An aluminum-lithium based alloy which comprises 10-20 wt. % silicon, 1.5-5.0 wt. % copper, 1.0-4.0 wt. % lithium, 0.45-1.5 wt. % magnesium, 0.01-1.3 wt. % iron, 0.01-0.5 wt. % manganese, 0.01-1.5 wt. % nickel, 0.01-1.5 wt. % zinc, 0.01-0.5 wt. % silver, 0.01-0.25 wt. % titanium and the balance aluminum. The alloy is utilized to cast high temperature assemblies including pistons which have a reduction in density and similar mechanical properties including tensile strengths to alloys presently used.Type: GrantFiled: December 9, 1991Date of Patent: December 8, 1992Assignee: Reynolds Metals CompanyInventors: Richard A. Morley, William H. Overbagh
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Patent number: 5135713Abstract: An aluminum base alloy suitable for forming into a wrought product having improved combinations of strength and fracture toughness is disclosed. The product is comprised of 0.2 to 3.0 wt. % Li, 0.1 to 3 wt. % Mg, 0.2 to 3 wt. % Cu, 5.1 to 12 wt. % Zn, 0.5 wt. % max. Fe, 0.5 wt. % max. Si, at least one of the elements selected from the group Cr, V, Hf, Mn, Ti, Ag, In and Zr, with Cr, V, Ti and Zr in the range of 0.01 to 0.2 wt. %; Hf and Mn up to 0.6 wt. % each, Ag in the range of 0.05 to 1 wt. % and in the range of 0.01 to 0.5 wt. %, the balance aluminum and incidental impurities.Type: GrantFiled: September 26, 1990Date of Patent: August 4, 1992Assignee: Aluminum Company of AmericaInventors: Roberto J. Rioja, James T. Staley
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Patent number: 5032359Abstract: A family of alloys based upon aluminum-copper-magnesium-silver alloys to which lithium has been added, within specified ranges, exhibits superior ambient- and elevated-temperature strength, superior ductility at ambient and elevated temperatures, extrudability, forgeability, weldability, and an unexpected natural aging response.Type: GrantFiled: March 23, 1989Date of Patent: July 16, 1991Assignee: Martin Marietta CorporationInventors: Joseph R. Pickens, Frank H. Heubaum, Lawrence S. Kramer, K. Sharvan Kumar
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Patent number: 4623513Abstract: Titanium-silver alloys containing specified amounts of silver and titanium and controlled amounts of copper, aluminum and mixtures thereof are suitable for brazing ceramics, other non-metallic and metallic materials. These alloys also may contain controlled amounts of tin, palladium, indium and mixtures thereof.Type: GrantFiled: September 20, 1984Date of Patent: November 18, 1986Assignee: GTE Products CorporationInventor: Howard Mizuhara