Iron, Cobalt, Or Nickel Containing Patents (Class 420/550)
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Patent number: 5431751Abstract: A high strength aluminum alloy is expressed by a general formula, Al.sub.a X.sub.b Mm.sub.c, in which "X" stands for at least one element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zr, "Mm" stands for a misch metal, a content "a" of aluminum falls in a range of from 95.2 to 97.5 atomic %, and a content "b" of "X" and a content "c" of the "Mm" fall in a hatched area enclosed by points "A," "B," "C" and "D" of accompanying FIG. 1 on atomic % basis, and whose metallic phase includes microcrystalline phases or mixed phases containing amorphous phases in a volume content of less than 50% and the balance of microcrystalline phases. As a result, the amorphous phases or the microcrystalline phases are dispersed uniformly in its base microcrystalline phases appropriately, and at the same time the thus generating base microcrystalline phases are reinforced by forming solid solutions including the "Mm" and the transition metal element "X" as well.Type: GrantFiled: February 5, 1993Date of Patent: July 11, 1995Assignee: Toyota Jidosha Kabushiki KaishaInventors: Yukio Okochi, Kazuaki Sato, Tetsuya Suganuma, Akira Kato, Tsuyoshi Masumoto, Akihisa Inoue
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Patent number: 5419789Abstract: An aluminum-based alloy which consists Al and 0.1 to 25 atomic % of at least two transition metal elements and has a structure in which at least quasicrystals are homogeneously dispersed in a matrix composed of Al or a supersaturated Al solid solution. The quasicrystals are preferably composed of an I-phase alone or a mixed phase of an I-phase and a D-phase and preferably has a volume nfraction of 20% or less. Specifically, the aluminum-based alloy has the composition represented by the general formula Al.sub.bal Ni.sub.a X.sub.b or Al.sub.bal Ni.sub.a X.sub.b M.sub.c wherein X is one or two elements selected between Fe and Co; M is at least one element selected from among Cr, Mn, Nb, Mo, Ta and W; 5.ltoreq.a.ltoreq.10; 0.5.ltoreq.b.ltoreq.10; and 0.1.ltoreq.c.ltoreq.5. The alloy is excellent in hardness and strength both at room temperature and high temperature and in heat resistance and has a high specific strength. It can retain the excellent characteristics even when affected by the heat of working.Type: GrantFiled: September 3, 1993Date of Patent: May 30, 1995Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5415709Abstract: The present invention provides a high-strength, abrasion resistant aluminum alloy having a composition represented by the general formula Al.sub.a M.sub.b X.sub.c Z.sub.d Si.sub.e, wherein M is at least one element selected from the group consisting of Fe, Co, and Ni; X is at least one element selected from the group consisting of Y, La, Ce and Mm (mischmetal); Z is at least one element selected from the group consisting of Mn, Cr, V, Ti, Mo, Zr, W, Ta and Hf; and a, b, c, d and e are all expressed by atom percent and range from 50 to 89 %, 0.5 to 10 %, 0.5 to 10 %, 0 to 10 % and 10 to 49 %, respectively, with the proviso that a+b+c+d+e =100 %, the alloy containing fine Si precipitates and fine particles of intermetallic compounds dispersed in an aluminum matrix. The aluminum alloy may further contain not greater than 5 % of at least one element selected from the group consisting of Cu, Mg, Zn and Li. The alloy can be warm-worked at 300.degree.-500.degree. C.Type: GrantFiled: December 7, 1993Date of Patent: May 16, 1995Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5397403Abstract: A high strength amorphous aluminum-based alloy comprises 75 atom % (inclusive) to 90 atom % (inclusive) of Al; 3 atom % (inclusive) to 15 atom % (inclusive) of Ni; and 3 atom % (inclusive) to 12 atom % (inclusive) of at least one element selected from the group consisting of Dy, Er and Gd, and has an amorphous phase volume fraction (Vf) of at least 50%. This leads to a higher amorphous phase forming ability and a wider plastically workable temperature region so that the workability of the alloy is satisfactory to produce structural members utilizing a working process such as a hot extruding process, a hot forging process or the like.Type: GrantFiled: August 26, 1992Date of Patent: March 14, 1995Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Hiroyuki Horimura, Tadahiro Kubota, Tuyoshi Baba, Kazuya Takahashi
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Patent number: 5374295Abstract: Disclosed are heat resistant aluminum alloy powders and alloys including Ni, Si, either at least one of Fe and Zr or at least one of Zr and Ti. For instance, the alloy powders or alloys consist essentially of Ni in an amount of from 5.7 to 20% by weight, Si in an amount of from 0.2 to 25% by weight, at least one of Fe in an amount of from 0.6 to 8.0% by weight and Cu in an amount of from 0.6 to 5.0% by weight, and the balance of Al. The alloy powders or alloys are optimum for a matrix of heat and wear resistant aluminum alloy-based composite materials including at least one of nitride particles and boride particles in an amount of 0. 5 to 10% by weight with respect to the whole composite material taken as 100% by weight. The alloy powders, alloys and composite materials are satisfactory applicable to the component parts of the recent automobile engines which should produce a high output.Type: GrantFiled: March 3, 1993Date of Patent: December 20, 1994Assignees: Toyota Jidosha Kabushiki Kaisha, Toyo Aluminum Kabushiki KaishaInventors: Hirohisa Miura, Kunihiko Imahashi, Yasuhiro Yamada, Hirohumi Michioka, Jun Kusui, Akiei Tanaka
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Patent number: 5372780Abstract: Aluminium alloys are described which after suitable processing can be used to produce lithographic printing plates of improved stoving resistance. The alloys consist es",Vially of at least 99.00% by weight of aluminium, from 0.02 to 0.15% by weight in total of zirconium and/or hafnium and from 0.05 to 0.25% by weight of manganese, with the remainder being incidental impurities. Improved stoving resistance is particularly shown with 0.02 to 0.08% zirconium and from 0.05 to 0.15% manganese, especially when stoving takes place at 240.degree. C. or above.Type: GrantFiled: July 15, 1992Date of Patent: December 13, 1994Assignee: Alcan International LimitedInventors: Peter K. F. Limbach, Graeme J. Marshall, Ricky A. Ricks
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Patent number: 5344507Abstract: An aluminum-alloy, which is wear-resistant and does not wear greatly the opposed cast iron or steel, and which can be warm worked. The alloyings the following composition and structure. Composition: Al.sub.a Si.sub.b M.sub.c X.sub.d T.sub.e (where M is at least one element selected from the group consisting of Fe, Co and. Ni; X is at least one element selected from the group consisting of Y, Ce, La and Mm (misch metal); Y is at least one element selected from the group consisting of Mn, Cr, V, Ti, Mo, Zr, W, Ta and Hf; a=50-85 atomic %, b=10-49 atomic %, c=0.5-10 atomic %, d=0.5-10 atomic %, e=0-10 atomic %, and a+b+c+d+e=100 atomic %. Structure: super-saturated face-centered cubic crystals and fine Si precipitates.Type: GrantFiled: March 16, 1992Date of Patent: September 6, 1994Assignees: Tsuyoshi Masumoto, Yoshida Kogyo KK, Teikoku Piston Ring Co., Ltd.Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Kazuhiko Kita, Hitoshi Yamaguchi
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Patent number: 5336341Abstract: An infrared radiation element and a process for producing the same. An aluminum alloy material consists essentially of 0.3 to 4.3 weight % of Mn, balance Al, and impurities. The alluminum alloy material is heated for dispersing a precipitate of an Al--Mn intermetallic compound at a density of at a minimum 1.times.10.sup.5 /mm.sup.3 for a size of 0.1 .mu.m to 3 .mu.m. The heated aluminum alloy material is anodized to form an anodic oxide layer thereon.Type: GrantFiled: August 30, 1991Date of Patent: August 9, 1994Assignees: Fujikura Ltd., Sky Aluminium Co., Ltd.Inventors: Masatsugu Maejima, Koichi Saruwatari, Akihito Kurosaka, Mamoru Matsuo, Hiroyoshi Gunji, Toshiki Muramatsu
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Patent number: 5334266Abstract: High strength, heat resistant aluminum-based alloys have a composition consisting of the following general formula Al.sub.a M.sub.b X.sub.d or Al.sub.a' M.sub.b Q.sub.c X.sub.d, wherein M is at least one metal element selected from the group consisting of Co, Ni, Cu, Zn and Ag; Q is at least one metal element selected from the group consisting of V, Cr, Mn and Fe; X is at least one metal element selected from the group consisting of Li, Mg, Si, Ca, Ti and Zr; and a, a', b, c and d are, in atomic percentages; 80.ltoreq.a.ltoreq.94.5, 80.ltoreq.a'.ltoreq.94, 5.ltoreq.b.ltoreq.15, 0.5.ltoreq.c.ltoreq.3 and 0.5.ltoreq.d.ltoreq.10. In the above specified alloys, aluminum intermetallic compounds are finely dispersed throughout an aluminum matrix and, thereby, the mechanical properties, especially strength and heat resistance, are considerably improved.Type: GrantFiled: November 23, 1992Date of Patent: August 2, 1994Assignee: Yoshida Kogyo K.K.Inventors: Makoto Kawanishi, Hidenobu Nagahama
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Patent number: 5318641Abstract: Al.sub.100-a-b-c X.sub.a M.sub.b T.sub.c, in which X is Y (yttrium) and/or rare-earth element(s), M is Fe, Co, and/or Ni, and T is Mn, Mo, Cr, Zr and/or V, and, a=0.5-5 atomic %, b=5-15 atomic %, and c=0.2-3.0 atomic %, and, further, X and M fall on and within the hatched region range of the appended FIG. 1, has a complex, amorphous-crystalline structure with an amorphous matrix containing the Al, X, M and T, and minority crystalline phase consisting of aluminum-alloy particles containing super-saturated X, M and T as solutes. The alloy has a high strength due to the dispersed crystalline particles.Type: GrantFiled: June 6, 1991Date of Patent: June 7, 1994Assignees: Tsuyoshi Masumoto, Teikoku Piston Ring Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha, Yoshida Kogyo K.K.Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Kazuhiko Kita, Hitoshi Yamaguchi, Hiroyuki Horimura, Noriaki Matsumoto
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Patent number: 5302342Abstract: An aluminum alloy for heat exchangers, the alloy, comprising a base compostion selected from a group consisting of Al-Mg-Si composition containing 0.1 to 0.8 wt % of Mg, 0.2 to 1.0 wt % of Si and 0.3 to 1.5 wt % of Mn; pure-Al composition; Al-Mg composition containing 0.05 to 1.0 wt % of Mg; and a Al-Zn composition containing 0.05 to 2.0 wt % of Zn. The alloy further comprises 0.01 to 0.3 wt % of Fe and/or 0.01 to 0.3 wt % of Ni, wherein the balance are aluminum of purity of 99.9% or higher and unavoidable impurities contained therein, and content of Cu as one of the impurities is controlled to be 0.05 wt % or less.Type: GrantFiled: July 16, 1993Date of Patent: April 12, 1994Assignees: Honda Giken Kogyo Kabushiki Kaisha, Showa Aluminum Kabushiki KaishaInventors: Tsuyoshi Kawabe, Nobuaki Yamamoto, Tadayoshi Hayashi, Makoto Tanio, Ichiro Iwai, Ichizo Tsukuda, Ryotatsu Otsuka
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Patent number: 5296190Abstract: This invention is characterized by working which improves metal formability. This is contrary to the usual result of working metals, where formability decreases during working.Type: GrantFiled: October 13, 1992Date of Patent: March 22, 1994Assignee: Aluminum Company of AmericaInventor: M. K. Premkumar
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Patent number: 5284532Abstract: A rapidly solidified aluminum based alloy consists essentially of the formula Al.sub.bal Fe.sub.a M.sub.b Si.sub.c R.sub.d, wherein M is at least one element selected from the group consisting of V, Mo, Cr, Mn, Nb, Ta, and W; R is at least one element selected from the group consisting of La, Ce, Pr, Nd, Sm, Gd, Dy, Er, Yb, and Y; "a" ranges from 3.0 to 7.1 atom %; "b" ranges from 0.25 to 1.25 atom %; "c" ranges from 1.0 to 3.0 atom %; "d" ranges from 3.0 to 0.3 atom % and the balance is aluminum plus incidental impurities, with the provisos that (i) the ratio [Fe+M]:Si ranges from about 2.0:1 to 5.0:1 and (ii) the ratio Fe:M ranges from about 16:1 to 5:1. The alloy exhibits improved elevated temperature strength due to the rare earth element additions without an increase in the volume fraction of dispersed intermetallic phase precipitates therein.Type: GrantFiled: January 14, 1993Date of Patent: February 8, 1994Assignee: Allied Signal Inc.Inventor: David J. Skinner
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Patent number: 5279642Abstract: Disclosed herein is a process for producing a high strength aluminum-based alloy powder comprising mixing Al or Al alloy powder with an Al--T--X alloy powder, wherein T is at least one selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, W, Ca, Li, Mg and Si; X is at least one selected from the group consisting of Y, Nb, Hf, Ta, La, Ce, Sm, Nd, Zr and Ti or Mm; and mechanically alloying the formed powder mixture. The aluminum-based alloy powder is excellent in workability and reliability by virtue of its high strength stability in the temperature range of from room temperature to an elevated temperature, its excellent ductility in the same temperature range and its low thermal expansion coefficient in the same temperature range.Type: GrantFiled: July 7, 1992Date of Patent: January 18, 1994Assignee: Yoshida Kogyo K.K.Inventor: Katsumasa Ohtera
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Patent number: 5240517Abstract: The present invention provides high strength, heat resistant aluminum-based alloys having a composition represented by the general formula: Al.sub.a M.sub.b X.sub.c wherein:M is at least one metal element selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si;X is at least one metal element selected from the group consisting of Y, La, Ce, Sm, Nd, Hf, Nb, Ta and Mm (misch metal); anda, b and c are atomic percentages falling within the following ranges:50.ltoreq.a.ltoreq.95, 0.5.ltoreq.b.ltoreq.35 and 0.5.ltoreq.c.ltoreq.25,the aluminum-based alloy being in an amorphous state, microcrystalline state or a composite state thereof. The aluminum-based alloys possess an advantageous combination of properties of high strength, heat resistance, superior ductility and good processability which make then suitable for various applications.Type: GrantFiled: June 28, 1991Date of Patent: August 31, 1993Assignee: Yoshida Kogyo K.K.Inventors: Tsuyoshi Matsumoto, Akihisa Inoue, Katsumasa Odera, Masahiro Oguchi
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Patent number: 5217547Abstract: The present invention relates to an aluminum alloy for fins of heat exchangers such as of automobile radiators and evaporators comprising 0.3 to 1.0% by weight of silicon, 0.3 to 3.0% by weight of iron, and the balance of aluminum and unavoidable impurities, which is readily workable for a fin (or readily corrugated), and is less deformed by brazing heat, and yet has improved thermal conductivity after the brazing.Type: GrantFiled: May 17, 1991Date of Patent: June 8, 1993Assignees: Furukawa Aluminum Co., Ltd., Nippondenso Co., Ltd.Inventors: Kazunori Ishikawa, Mituo Hashiura, Yoshiharu Hasegawa
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Patent number: 5198042Abstract: An aluminum alloy powder for coating materials and a coating material containing the aluminum alloy powder. The aluminum alloy powder comprises an amorphous aluminum alloy consisting essentially of from 83 to 91% of Al, from 0.5 to 5% of Ca and from 8 to 12% of Ni, all in atom %, and comprising a leaf-shaped particle having a thickness of 0.3 to 3 .mu.m, a minor axis of from 10 to 150 .mu.m, a ratio of the minor axis to a major axis of from 1 to 3, and an aspect ratio which is the ratio of the minor axis to the thickness of from 3 to 100, wherein the aluminum alloy powder is contained in an amount of from 5 to 25 parts by weight based on 100 parts by weight of the total weight of (i) the coating material resin component and (ii) aluminum alloy powder, and the coating material resin component is selected from the group consisting of a water-based synthetic latex and a water-soluble resin. The aluminum alloy powder has a superior dispersibility in a resin in a coating material.Type: GrantFiled: November 12, 1991Date of Patent: March 30, 1993Assignees: Tsuyoshi Masumoto, Yoshida Kogyo K.K., Teikoku Piston Ring Co., Ltd.Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Kazuhiko Kita, Yoshio Harakawa, Masahiro Oguchi
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Patent number: 5185303Abstract: A self-supporting ceramic body produced by oxidation of a molten precursor metal with a vapor-phase oxidant to form an oxidation reaction product and inducing a molten flux comprising said molten precursor metal through said oxidation reaction product. A second metal is incorporated into said molten flux during the oxidation reaction. The resulting ceramic body includes sufficient second metal such that one or more properties of said ceramic body are at least partially affected by the presence and properties of said second metal in the metallic constituent.Type: GrantFiled: November 14, 1991Date of Patent: February 9, 1993Assignee: Lanxide Technology Company, LPInventors: Robert C. Kantner, Michael A. Rocazella, Jerry G. Weinstein, Danny R. White
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Patent number: 5116438Abstract: A beta phase nickel aluminide microalloyed with gallium having improved ductility. Nickel aluminide intermetallics alloyed with up to about 0.25 atomic percent gallium have significantly improved room temperature ductility over conventional unalloyed beta phase nickel aluminides or beta phase nickel aluminides alloyed with higher percentages of gallium.Type: GrantFiled: March 4, 1991Date of Patent: May 26, 1992Assignee: General Electric CompanyInventors: Ramgopal Darolia, David F. Lahrman
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Patent number: 5110371Abstract: An aluminum alloy consists of, by weight, from 0.08 to 0.50 percent silicon, from 0.15 to 0.90 percent iron, the weight ratio of iron to silicon being from 1.4 to 2.2, and the remainder aluminum, intermetallic compounds of .alpha.-type Al-Fe-Si system being contained in the alloy. A light gray oxide film is formed on the alloy by anodic treatment.Type: GrantFiled: July 9, 1991Date of Patent: May 5, 1992Assignee: Nippon Light Metal Company, Ltd.Inventors: Takeshi Moriyama, Katsuji Ogawa, Fumio Ohtake, Akito Nishizawa
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Patent number: 5104444Abstract: An aluminum alloy is prepared from an aluminum alloy powder having a composition of:lubricating componentPb: 3 to 15 Wt %;hardening componentSi: 1 to 12 Wt %;rainforcement componentone or more selected among Cu, Cr, Mg, Mn, NiZn, Fe and: 0.2 to 5.0 Wt %;and remainder of aluminum as principal material or matrix.To the aluminum alloy powder set forth above, powder state Pb in 3 to 12 Wt % is added. With the mixture of the aluminium alloy powder and Pb powder, a billet is formed. For the billet, extrustion process is performed in a extrusion ratio greater than or equal to 40. In the extruded block, Si particle dispersed in the aluminum matrix is in a grain size smaller than or equal to 12 .mu.m. Furthermore, at least of half of added Pb power particle is dispersed to have greater than or equal to 0.74 of circularity coefficient.Type: GrantFiled: August 7, 1989Date of Patent: April 14, 1992Assignees: Nissan Motor Company, Limited, NDC Co., Ltd.Inventors: Masahiko Shioda, Masashi Arita, Katsuji Tanizaki, Koue Ohdawa, Takeshi Sakai
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Patent number: 5080728Abstract: Production of a thin aluminum alloy strip containing iron, manganese and silicon by hot rolling and cold rolling with a subsequent final annealing, includes the steps of (a) producing a bar by a continuous casting process, from 0.7-1.15% by weight Fe; 0.5-2.0% by weight Mn; and less than 0.6% by weight Si; as well as impurities, none of which exceeds 0.03% by weight, the remainder of the bar being aluminum; (b) homogenizing the bar for 2 to 20 hours at a temperature from 620.degree. to 480.degree. C., after which the bar is (c) hot rolled in a usual manner to a final thickness of 4 mm; then (d) cold rolled without intermediate annealing to a final thickness of 40 to 250 microns; and (e) annealing the cold-rolled strip for 1 to 6 hours at a temperature of 250.degree. to 400.degree. C. The alloy produced has a sub-grain structure, with an average 10 grain diameter of 0.5 to 5 microns, the subgrains constituting at least 50% of the total structure.Type: GrantFiled: April 23, 1990Date of Patent: January 14, 1992Assignee: Vereinigte Aluminium-Werke AktiengellschaftInventor: Jochen Hasenclever
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Patent number: 5066618Abstract: There is disclosed a method for producing a self-supporting ceramic body by oxidation of a molten precursor metal with a vapor-phase oxidant to form an oxidation reaction product and inducing a molten flux comprising said molten precursor metal through said oxidation reaction product. A second metal is incorporated into said molten flux during the oxidation reaction. The resulting ceramic body includes sufficient second metal such that one or more properties of said ceramic body are at least partially affected by the presence and properties of said second metal in the metallic constituent.Type: GrantFiled: August 16, 1990Date of Patent: November 19, 1991Assignee: Lanxide Technology Company, LPInventors: Robert C. Kantner, Michael A. Rocazella, Jerry G. Weinstein, Danny R. White
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Patent number: 5030416Abstract: An aluminum alloy that is suitable as material for cathode foils in electrolytic capacitors comprises0.9 to 1.7% iron0.1 to 0.8% manganesemax. 0.15% siliconmax. 0.3% copper,the remainder being aluminum with further trace elements, individually <0.05%, in total <0.15%, and the total iron and manganese content amounting to at most 1.9%.Type: GrantFiled: September 19, 1989Date of Patent: July 9, 1991Assignees: Swiss Aluminium Ltd., Swiss Aluminium Ltd.Inventors: Martin Werner, Margarete Bloeck, Heinz Bichsel
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Patent number: 5023051Abstract: A hypoeutectic aluminum silicon magnesium alloy includes 4-5.5% silicon, 0.15-3.5% magnesium, 0.005 to 0.08% phosphorus and aluminum. The presence of the phosphorus causes formation of a spherical percipitates of silicon magnesium and the aluminum. The phosphorus suppresses the magnesium silicon aluminum eutectic which allows the aluminum to remain liquid for a longer period of time and consequently providing a better fill of casting during the time the alloy is solidifying in a die or a mold. This alloy which preferably includes nickel is particularly useful for marine, hydraulic and refrigeration components.Type: GrantFiled: December 4, 1989Date of Patent: June 11, 1991Assignee: Leggett & Platt IncorporatedInventor: Richard S. Lindberg
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Patent number: 4964927Abstract: Ductile, strong, and stable (crystallization temperature above 250.degree. C.) Al-X-Z metallic classes contain 90 at. % Al where X-Fe, Co, Ni, Rh; Z-rare earths, Hf, Y, Stable (crystallization temperatures reaching 500.degree. C.) Al-Y-Fe-Si glasses have superior hardness properties upon consolidation. The present alloys are at least twice as strong in tensile strength as the strongest commercial aluminum alloys.Type: GrantFiled: March 31, 1989Date of Patent: October 23, 1990Assignee: University of Virginia Alumini PatentsInventors: Gary J. Shiflet, S. Joseph Poon, Yi He
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Patent number: 4950452Abstract: The present invention provides high strength, heat resistant aluminum-based alloys having a composition represented by the general formula Al.sub.a M.sub.b Ce.sub.c, wherein M is at least one metal element selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu and Nb; and a, b and c are atomic percentages falling within the following ranges:50.ltoreq.a.ltoreq.93, 0.5.ltoreq.b.ltoreq.35 and 0.5.ltoreq.c.ltoreq.25,the aluminum alloy containing at least 50% by volume of amorphous phase. The aluminum-based alloys are especially useful as high strength, high heat resistant materials in various applications and since they exhibit superplasticity in the vicinity of their crystallization temperature, they can be easily processed into various bulk materials by extrusion, press woring or hot-forging at the temperatures within the range of the crystallization temperature .+-.100.degree. C.Type: GrantFiled: March 16, 1989Date of Patent: August 21, 1990Assignees: Yoshida Kogyo K. K., Tsuyoshi MasumotoInventors: Tsuyoshi Masumoto, Akihisa Inoue, Katsumasa Odera
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Patent number: 4948558Abstract: The invention provides an aluminum based alloy consisting essentially of the formula Al.sub.bal Fe.sub.a X.sub.b, wherein X is at least one element selected from the group consisting of Zn, Co, Ni, Cr, M, V, Zr, Ti, Y, Si and Ce, "a" ranges from about 7-15 wt %, "b" ranges from about 1.5-10 wt % and the balance is aluminium. The alloy has a predominately microeutectic microstructure.The invention provides a method and apparatus for forming rapidly solidified metal within an ambient atmosphere, the rapidly solidified metal being an aluminum based alloy. Generally stated, the apparatus includes a moving casting surface which has a quenching region for solidifying molten metal thereon. A reservoir holds the molten metal and has orifice means for depositing a stream of the molten metal onto the casting surface quenching region.Type: GrantFiled: August 9, 1988Date of Patent: August 14, 1990Assignee: Allied-Signal Inc.Inventors: David J. Skinner, Paul A. Chipko, Kenji Okazaki
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Patent number: 4939032Abstract: Composite materials having improved fracture toughness are formed by dispersing ductile inclusions in a less ductile matrix. The matrices may be formed from metals, such as high-strength aluminum alloys or ceramics. Bonding should be present between the inclusions and the matrix so that cracks in the composite material must pass through the inclusions.Type: GrantFiled: June 25, 1987Date of Patent: July 3, 1990Assignee: Aluminum Company of AmericaInventors: Jocelyn I. Petit, Philip E. Bretz, Henry G. Paris, Ralph R. Sawtell, Diana K. Denzer
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Patent number: 4909867Abstract: The present invention provides high-strength and heat resistant aluminum alloys having a composition represented by the general formula Al.sub.a M.sub.b La.sub.c (wherein M is at least one metal element selected from the group consisting of Fe, Co, Ni, Cu, Mn and Mo; and a, b and c are atomic percentages falling within the following ranges:65.ltoreq.a.ltoreq.93, 4.ltoreq.b.ltoreq.25 and 3.ltoreq.c.ltoreq.15),the aluminum alloys containing at least 50% by volume of amorphous phase. The aluminum alloys are especially useful as high strength and high heat resistant materials in various applications and, since the aluminum alloys specified above exhibit a superplasticity in the vicinity of their crystallization temperature, they can be readily worked into bulk forms by extrusion, press working or hot forging in the vicinity of the crystallization temperature.Type: GrantFiled: September 12, 1988Date of Patent: March 20, 1990Assignees: Yoshida Kogyo K. K., Tsuyoshi MasumotoInventors: Tsuyoshi Masumoto, Akihisa Inoue, Katsumasa Odera, Masahiro Oguchi
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Patent number: 4876185Abstract: A photoconductive member has a support comprising aluminum as the main component and a photoconductive layer. The photoconductive layer is provided on the support and contains an amorphous material comprising silicon atoms as a matrix. The support comprises an aluminum alloy with a Fe content of 2000 ppm by weight or less.Type: GrantFiled: July 9, 1987Date of Patent: October 24, 1989Assignee: Canon Kabushiki KaishaInventors: Yasuyuki Matsumoto, Keiichi Murai, Tadaji Fukuda, Kyosuke Ogawa
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Patent number: 4866479Abstract: A photosensitive drum adapted for use in electronic copying machines and laser beam printers, the drum made of aluminum-based alloy and supporting a photosensitive recepter thereon, the aluminum-based alloy having a composition consisting essentially of 0.5 to 8.0% of Ni, and preferably, one or more additives selected from a group of 0.05 to 1.5% of Mn, 0.05 to 1.0% of Cr, 0.05 to 0.5% of Zr, 0.5% or less of Ti, 0.1% or less of B, 0.05 to 7.0% of Cu, 0.05 to 7.0% of Mg, 0.05 to 8.0% of Zn, 0.05 to 12.0% of Si, and 0.05 to 2.0% of Fe, and the balance being substantially aluminum.Type: GrantFiled: May 24, 1988Date of Patent: September 12, 1989Assignee: Showa Aluminum Kabushiki KaishaInventors: Ichizo Tsukuda, Takashi Atsumi, Masao Yokoyama
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Patent number: 4851193Abstract: An improved alloy consisting essentially of about 6 to 10 weight percent Fe, about 2 to 10 weight percent Gd, balance Al. The alloy may also contain minor amounts of one or more refractory metals.Type: GrantFiled: February 13, 1989Date of Patent: July 25, 1989Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Yashwant R. Mahajan, Young-Won Kim, Francis H. Froes
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Patent number: 4806211Abstract: An anodized aluminum product prepared by anodizing an alloy comprising 1.20-1.60% iron and 0.25-0.55% manganese with a weight ratio of iron to manganese between 2.8 and 5, up to 0.20% silicon, up to 0.30% copper, up to 5% magnesium, up to 0.10% chromium, up to 2% zinc, up to 0.25% zirconium, up to 0.10% titanium, remainder aluminum and in total up to 0.50% of other by anodic oxidation in an electrolyte at a temperature of less than 560.degree. C. for no more than 4 hours so as to produce an oxide thickness of 5 to 30 .mu.m.Type: GrantFiled: May 12, 1987Date of Patent: February 21, 1989Assignee: Swiss Aluminum Ltd.Inventors: Jurgen Timm, Jean-Francois Paulet, Jorg Maier
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Patent number: 4765851Abstract: An aluminum alloy for the production of powders having increased high-temperature strength by rapid quenching, the said alloy containing 1.5 to 5% by weight of Li, 4 to 11% by weight of Fe and 1 to 6% by weight of at least one of the elements Mo, V or Zr, the remainder being Al, or 1.5 to 5% by weight of Li, 4 to 7% by weight of Cr and 1 to 4% by weight of at least one of the elements V or Mn, the remainder being Al. A low density and good high-temperature strength as well as good thermal stability up to 400.degree. C. coupled with Vickers hardnesses of up to 180 (HV) are achieved. Hardness-imparting dispersoids in the form of the phases Al.sub.3 Li and Al.sub.3 Zr, as well as other intermetallic compounds of Al with Mo, V or Mn, having a particle diameter of no more than 0.1 .mu.m, constitute a large volume fraction.Type: GrantFiled: June 18, 1986Date of Patent: August 23, 1988Assignee: BBC Brown, Boveri & Company, LimitedInventor: Malcolm J. Couper
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Patent number: 4715893Abstract: The invention provides an aluminum based alloy consisting essentially of the formula Al.sub.bal Fe.sub.a V.sub.b X.sub.c, wherein X is at least one element selected from the group consisting of Zn, Co, Ni, Cr, Mo, Zr, Ti, Hf, Y and Ce, "a" ranges from about 7-15 wt %, "b" ranges from about 2-10 wt %, "c" ranges from about 0-5 wt % and the balance is aluminum. The alloy has a distinctive microstructure which is at least about 50% composed of a generally spherical, intermetallic O-phase.Particles composed of the alloys of the invention can be heated in a vacuum and compacted to form a consolidated metal article have high strength and good ductility at both room temperature and at elevated temperatures of about 350.degree. C. The consolidated article is composed of an aluminum solid solution phase containing a substantially uniform distribution of dispersed intermetallic phase precipitates therein.Type: GrantFiled: April 4, 1984Date of Patent: December 29, 1987Assignee: Allied CorporationInventors: David J. Skinner, Richard L. Bye, Jr., Kenji Okazaki, Colin M. Adam
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Patent number: 4668470Abstract: A method for forming intermetallic and intermetallic-type precursor alloys for subsequent mechanical alloying applications. Elemental powders are blended in proportions approximately equal to their respective intermetallic compounds. Heating of the blend results in the formation of intermetallic compounds whereas lack of heating results in intermetallic-type powder without the intermetallic structure. The resultant powder is then blended to form a final alloy. Examples involving aluminum-titanium alloys are discussed.Type: GrantFiled: December 16, 1985Date of Patent: May 26, 1987Assignee: Inco Alloys International, Inc.Inventors: Paul S. Gilman, Arun D. Jatkar, Stephen Donachie, Winfred L. Woodard, III, Walter E. Mattson
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Patent number: 4648901Abstract: An additive is provided which enables metal additions to be made to aluminum melts with good metal recovery and speed of dissolution. The additive includes a mixture comprising:(a) an aluminum-comprising powder, for example commercially pure aluminum;(b) a powder of one or more metals or alloys comprising the metal or metals to be introduced, for example manganese, chromium, tungsten, molybdenum, titanium, vanadium, iron, cobalt, copper, niobium, tantalum, zirconium, hafnium and silver; and(c) a flux, for example one or more of potassium aluminum fluoride or potassium cryolite, potassium chloride, potassium fluoride, sodium chloride, sodium fluoride, and sodium carbonate.In a preferred form, the additive is a compacted tablet of components (a), (b) and (c), in the weight proportions of about 5%, 75% and 20%, respectively. The additive is especially useful in the method of the invention of introducing one or more metals into a melt comprising aluminum.Type: GrantFiled: July 17, 1985Date of Patent: March 10, 1987Assignee: Shieldalloy CorporationInventors: Peter Murray, David Slinn
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Patent number: 4647321Abstract: Aluminum alloy compositions and related fabrication techniques are described. Articles made of the composition by the process contain a novel dispersed strengthening phase based on iron and refractory metals. Rapid solidification techniques are used to assure a fine distribution of this phase. Articles made according to the invention have mechanical properties significantly in excess of those of conventional aluminum alloys.Type: GrantFiled: October 13, 1983Date of Patent: March 3, 1987Assignee: United Technologies CorporationInventor: Colin M. Adam
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Patent number: 4631236Abstract: A process and a device for manufacturing an extruded section of an aluminum alloy containing additions of boron or compounds thereof are intended to simplify the manufacture of aluminum alloy sections for use in nuclear science and technology. Using a boron-containing aluminum-based raw material a section is to be formed such that its design ensures adequate stability and at the same time the necessary screening properties. To this end a billet having a core of aluminum alloy with additions of boron or the like and a mantel surrounding the same is manufactured and hot formed by extrusion, such that, using the molten metal route or powder metallurgy, a blank of aluminum alloy of particular alloy groups with additions of boron or its compounds at a concentration of 0.05 to 50 wt % is taken as the starting basis.Type: GrantFiled: February 14, 1985Date of Patent: December 23, 1986Assignee: Swiss Aluminium Ltd.Inventor: Hans-Gerd Roczyn
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Patent number: 4615735Abstract: Powder metallurgy products of high tensile strength are formed in a pore-free state by a novel process which entirely avoids the use of canisters. An open-pore specimen is purged with depurative gas, backfilled with a reactive gas and, while still immersed in the reactive gas, compressed isostatically to an extent necessary to close the pores. The specimen may then be compressed to full density without the need for either high vacuum or a depurative or reactive gas atmosphere.Type: GrantFiled: September 18, 1984Date of Patent: October 7, 1986Assignee: Kaiser Aluminum & Chemical CorporationInventor: Steven W. Ping
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Patent number: 4571368Abstract: An improved aluminum base alloy which provides corrosion protection in fin stock applications includes 0.6-3.0% silicon; 0.2-1.0% by weight iron; up to 0.2% by weight copper; 0.8-2.0% by weight manganese; up to 0.2% by weight magnesium; from about 0.5% by weight zinc to 2.5% by weight zinc; up to 0.2% by weight other constituents; and the balance aluminum. The alloy is especially useful as a sacrificial alloy having improved mechanical strength.Type: GrantFiled: July 3, 1984Date of Patent: February 18, 1986Assignee: Atlantic Richfield CompanyInventors: John C. Fenoglio, David L. Wilbur, William H. Anthony
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Patent number: 4554131Abstract: Aluminum alloys suitable for use as anode structures in electrochemical cs are disclosed. These alloys include iron levels higher than previously felt possible, due to the presence of controlled amounts of manganese, with possible additions of magnesium and controlled amounts of gallium.Type: GrantFiled: September 28, 1984Date of Patent: November 19, 1985Assignee: The United States of America as represented by the Department of EnergyInventors: David S. Thompson, Darwin H. Scott
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Patent number: 4532106Abstract: A dispersion-strengthened aluminum-base alloy system is provided which is prepared by mechanical alloying and is characterized by high strength, high elastic modulus, low density and high corrosion resistance. The alloy system is comprised, by weight, of at least above 1.5% up to about 3% Li, about 0.4% up to about 1.5% O, about 0.25% up to about 1.2% C, and the balance essentially Al.Type: GrantFiled: July 31, 1980Date of Patent: July 30, 1985Assignee: Inco Alloys International, Inc.Inventor: Joseph R. Pickens
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Patent number: 4499050Abstract: This invention relates to aluminum alloy compositions that have superior corrosion and pitting resistance. These compositions include small amounts of manganese and tin, with the major constituent being aluminum. Elements such as zinc, titanium, tantalum, and/or cobalt can also be added. The manganese content ranges from 0.20 to 2 weight percent and the tin content ranges from 0.20 to 1.5 weight percent. When included, the zinc content ranges from 0.03 to 0.5 weight percent, the titanium content ranges from 0.001 to 0.5 weight percent, the tantalum content ranges from 0.03 to 0.2 weight percent and the cobalt content ranges from 0.03 to 0.2 weight percent, and the boron content ranges from 0.03 to 0.1 weight percent.Type: GrantFiled: June 6, 1983Date of Patent: February 12, 1985Assignee: Revere Copper and Brass IncorporatedInventor: Hua S. Tong
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Patent number: 4499051Abstract: This invention relates to aluminum alloy compositions that have superior pitting corrosion resistance. These compositions include small amounts of manganese, lead, and bismuth, with the major constituent being aluminum. Elements such as titanium, zinc, cobalt, zirconium, and/or boron can also be added. The manganese content ranges from 0.20 to 2 weight percent, the lead content ranges from 0.02 to 0.4 weight percent and the bismuth content ranges from 0.02 to 0.2 weight percent. When included, the zinc content can range from 0.03 to 0.5 weight percent and the titanium content can range from 0.05 to 0.5 weight percent, the cobalt content can range from 0.03 to 0.2 weight percent, the zirconium content can range from 0.03 to 0.5 weight percent, and the boron content can range from 0.03 to 0.1 weight percent.Type: GrantFiled: June 6, 1983Date of Patent: February 12, 1985Assignee: Revere Copper and Brass IncorporatedInventor: Hua S. Tong
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Patent number: 4483719Abstract: A process for the preparation of a rolled aluminum product, containing iron as the predominant alloy element, which has a grain size of less than 10 .mu.m after annealing to at least 250.degree. C., in which an alloy consisting of 0.8 to 1.5% iron, up to 0.5% by weight of each of Si and Mn, the sum of Si and Mn being between 0.2 and 0.8%, up to 0.3% by weight of any other component, the total of other components being no more than 0.8% by weight, and the remainder being aluminum, is casted at a solidification rate of 2.5 to 25 cm/min, the hot plate is cooled to less than 120.degree. C. at a rate of less than 0.5 K/sec and is then cold rolled with a thickness decrease of at least 75% without intermediate annealing, and the final annealing temperature does not exceed 380.degree. C.Type: GrantFiled: September 30, 1983Date of Patent: November 20, 1984Assignee: Swiss Aluminium Ltd.Inventors: Peter Furrer, Jurgen Timm, Frank Wehner
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Patent number: 4464199Abstract: Aluminum alloy atomized powder containing 4 to 15% iron and 1 to 12% cerium or other rare earth metal, when properly compacted and shaped into a useful article, exhibits very high strength at relatively high temperatures. The iron content exceeds the cerium or rare earth metal content, and the powder may contain refractory elements such as W, Mo and others. The powder is produced by atomizing alloyed molten aluminum, preferably in a nonoxidizing atmosphere, and is compacted to a density approaching 100% under controlled conditions including controlled temperature conditions. The alloy may be subsequently shaped by conventional forging, extruding or rolling processes.Type: GrantFiled: January 20, 1983Date of Patent: August 7, 1984Assignee: Aluminum Company of AmericaInventors: Gregory J. Hildeman, Robert E. Sanders, Jr.
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Patent number: 4389258Abstract: The present invention is for an improved aluminum alloy powder for making consolidated products with an improved combination of strength and ductility. The alloy is cast as ribbon or flake which subsequently pulverized.Type: GrantFiled: December 28, 1981Date of Patent: June 21, 1983Assignee: Allied CorporationInventors: James Dickson, Kenji Okazaki, Thomas H. Sanders
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Patent number: 4383970Abstract: A process for preparation of graphite-containing aluminum alloys includes incorporating graphite particles into an aluminum containing melt. When the graphite particles are incorporated, floating of the graphite particles to the surface of the melt is prevented by the use of certain additive metals. Before the graphite particles are incorporated into the melt, titanium, chromium, zirconium, nickel, vanadium, cobalt, manganese, niobium or phosphorus is incorporated and dispersed into the melt. The produced aluminum alloys are suitable to use as dry frictional contacts such as bearings.Type: GrantFiled: April 11, 1980Date of Patent: May 17, 1983Assignees: Hitachi, Ltd., Hitachi Chemical Company, Ltd.Inventors: Katsuhiro Komuro, Masateru Suwa, Koh Soeno, Masato Ohsawa