Antimony, Or Bismuth Containing Patents (Class 420/561)
  • Publication number: 20100233018
    Abstract: Provided is an SnCu lead-free solder alloy which eliminates a drawback that an intermetallic compound excessively precipitates and the precipitate serves as nuclei to form dross to thereby cause soldering defects including a needle-like protrusion to occur, thus to satisfy all of the properties required for practical use. A lead-free solder alloy contains 0.1 to 1.5% by weight of Cu, not less than 0.01 and less than 0.05% by weight of Co, 0.05 to 0.5% by weight of Ag and 0.01 to 0.1% by weight of Sb, the remainder being Sn, or further contains 0.001 to 0.008% by weight of Ge, whereby the formation of dross is prevented, and thus the drawback that soldering defects including a needle-like protrusion occur is eliminated.
    Type: Application
    Filed: July 20, 2007
    Publication date: September 16, 2010
    Applicants: TOPY KOGYO KABUSHIKI KAISHA,, KABUSHIKI KAISHA NIPPON FILLER METALS,
    Inventors: Seiji Yamada, Kenichiro Sugimori
  • Patent number: 7749340
    Abstract: A technique for technique for increasing the compliance of lead-free solders containing silver is disclosed. In one particular exemplary embodiment, the technique may be realized as a Sn—Ag—Al alloy composition comprising (0.01-20)% Ag, (0.01-2)% Al, balanced with Sn. In another particular exemplary embodiment, the technique may be realized as a Sn—Ag—Cu—Al alloy composition comprising (0.01-20)% Ag, (0.01-1)% Cu, (0.01-2)% Al, balanced with Sn. In still another particular exemplary embodiment, the technique may be realized as a Sn—Ag—Al—Ni composition comprising (0.01-20)% Ag, (0.01-2)% Al, (0.01-4)% Ni, balanced with Sn. In yet another particular exemplary embodiment, the technique may be realized as a Sn—Ag—Cu—Al—Ni alloy composition comprising (0.01-20)% Ag, (0.01-1)% Cu, (0.01-2)% Al, (0.01-4)% Ni, balanced with Sn.
    Type: Grant
    Filed: October 18, 2006
    Date of Patent: July 6, 2010
    Assignee: Indium Corporation of America
    Inventors: Benlih Huang, Hong-Sik Hwang, Ning-Cheng Lee
  • Patent number: 7749336
    Abstract: A technique for increasing the compliance of tin-indium solders is disclosed. In one particular exemplary embodiment, the technique may be realized as a lead free solder alloy comprising from about 58.0% to about 99.998% by weight tin, from about 0.001% to about 40.0% by weight indium, and from about 0.001% to about 2.0% by weight at least one rare earth element.
    Type: Grant
    Filed: February 24, 2006
    Date of Patent: July 6, 2010
    Assignee: Indium Corporation of America
    Inventors: Benlih Huang, Hong-Sik Hwang, Ning-Cheng Lee
  • Patent number: 7682468
    Abstract: A lead-free solder alloy suitable for use in flow soldering of electronic components to printed wiring boards comprises 0.1-3 wt % of Cu, 0.001-0.1 wt % of P, optionally 0.001-0.1 wt % of Ge, and a balance of Sn. The solder alloy may further contain at least one element of Ag and Sb in a total amount of at most 4 wt %, and/or at least one element of Ni, Co, Fe, Mn, Cr, and Mo in a total amount of at most 0.5 wt % in order to strengthen the alloy, and/or at least one element of Bi, In, and Zn in a total amount of at most 5 wt % in order to lower the melting point of the alloy.
    Type: Grant
    Filed: August 10, 2007
    Date of Patent: March 23, 2010
    Assignee: Senju Metal Industry Co., Ltd.
    Inventors: Osamu Munekata, Yoshitaka Toyoda, Tsukasa Ohnishi, Minoru Ueshima
  • Publication number: 20100059576
    Abstract: A lead-free and solder alloy composition for electronic assembly applications having reduced toxicity. The alloy composition comprises, by weight, about 0.2% to about 1% copper; about 0.001% to about 0.039% nickel; about 0.001% to about 0.039% cobalt; and the balance of tin. The alloy composition has a melting temperature of about 227° C., with superior wetting and mechanical strength making the alloy composition wells suited for electronic circuit board manufacture and lead less component bumping or column arrays, and replacement of conventional tin-lead solders.
    Type: Application
    Filed: September 5, 2008
    Publication date: March 11, 2010
    Applicant: American Iron & Metal Company, Inc.
    Inventor: Karl F. Seelig
  • Publication number: 20090304545
    Abstract: A lead-free solder alloy exhibiting good performance in impact resistance and vibration resistance. Also provided are a solder ball using such a lead-free solder alloy, and an electronic member having a solder bump using such a lead-free alloy. Specifically, the lead-free solder alloy consists of 1.0 to 2.0% by mass of Ag, 0.3 to 1.0% by mass of Cu, 0.005 to 0.1% by mass of Ni and the balance including Sn and unavoidable impurities. In an Sn—Ag—Cu based solder joint portion on a Cu electrode, a Cu3Sn intermetallic compound layer is formed directly on the Cu electrode, and then a Cu6Sn5 intermetallic compound layer is formed thereon. A Cu atomic site in the Cu6Sn5 intermetallic compound layer is replaced by Ni having a smaller atomic radius than Cu to thereby reduce strain in the Cu6Sn5 intermetallic compound layer, thus enabling impact resistance and vibration resistance to be improved therein.
    Type: Application
    Filed: March 8, 2007
    Publication date: December 10, 2009
    Applicants: NIPPON STEEL MATERIALS CO., LTD, NIPPON MICROMETAL CORPORATION
    Inventors: Masamoto Tanaka, Tsutomu Sasaki, Takayuki Kobayashi, Kazuto Kawakami, Masayoshi Fujishima
  • Publication number: 20090232696
    Abstract: A lead-free solder alloy is provided which has improved impact resistance to dropping even after thermal aging and which is excellent with respect to solderability, occurrence of voids, and yellowing. A solder alloy according to the present invention consists essentially of, in mass percent, (1) Ag: 0.8-2.0%, (2) Cu: 0.05-0.3%, (3) at least one element selected from In: at least 0.01% and less than 0.1%, Ni; 0.01-0.04%, Co: 0.01-0.05%, and Pt: 0.01-0.1%, optionally (4) at least one element selected from Sb, Bi, Fe, Al, Zn, and P in a total amount of up to 0.1%, and a remainder of Sn and impurities.
    Type: Application
    Filed: May 31, 2006
    Publication date: September 17, 2009
    Inventors: Tsukasa Ohnishi, Tokuro Yamaki, Daisuke Soma
  • Patent number: 7488445
    Abstract: A lead-free solder includes at least one selected from 0.01 to 1% by weight of Co, 0.01 to 0.2% by weight of Fe, 0.01 to 0.2% by weight of Mn, 0.01 to 0.2% by weight of Cr, and 0.01 to 2% by weight of Pd; 0.5 to 2% by weight of Cu; and 90.5% by weight or more of Sn. This solder exhibits a satisfactory solderability in solder joints and shows a high resistance to electrode leaching upon soldering or when the resulting soldered article is left at high temperatures.
    Type: Grant
    Filed: November 8, 2007
    Date of Patent: February 10, 2009
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Hidekiyo Takaoka, Kiyotaka Maegawa
  • Publication number: 20080292492
    Abstract: An alloy suitable for use in a wave solder process, reflow soldering process, hot air levelling process or a ball grid array, the alloy comprising from 0.08-3 wt. % bismuth, from 0.15-1.5 wt. % copper, from 0.1-1.5 wt. % silver, from 0-0.1 wt. % phosphorus, from 0-0.1 wt. % germanium, from 0-0.1 wt. % gallium, from 0-0.3 wt. % one or more rare earth elements, from 0-0.3 wt. % indium, from 0-0.3 wt. % magnesium, from 0-0.3 wt. % calcium, from 0-0.3 wt. % silicon, from 0-0.3 wt. % aluminium, from 0-0.3 wt. % zinc, and at least one of the following elements from 0.02-0.3 wt % nickel, from 0.008-0.2 wt % manganese, from 0.01-0.3 wt % cobalt, from 0.01-0.3 wt % chromium, from 0.02-0.3 wt % iron, and from 0.008-0.1 wt % zirconium, and the balance tin, together with unavoidable impurities.
    Type: Application
    Filed: December 1, 2005
    Publication date: November 27, 2008
    Applicant: ALPHA FRY LIMITED
    Inventors: Anthony E. Ingham, Gerard Campbell, Brian G. Lewis, Bawa Singh, John P. Laughlin, Ranjit Pandher
  • Publication number: 20080292493
    Abstract: Provided is a quaternary Pb-free solder composition incorporating Sn—Ag—Cu—In, which can prevent a cost increase and sufficiently ensure proccessability and mechanical property as a solder material. To this end, indium (In) with appropriate amount is added into the Pb-free solder composition, and the addition amount of Ag is optimized, thus preventing a decrease in wettability caused by a decrease in the amount of Ag and improving resistance to a thermal cycling and a mechanical impact. The quaternary Pb-free solder composition includes silver (Ag) of about 0.3 wt. % or more, and less than about 2.5 wt. %, copper (Cu) of about 0.2 wt. % or more, and less than about 2.0 wt. %, indium (In) of about 0.2 wt. % or more, and less than about 1.0 wt. % or less, and a balance of tin (Sn).
    Type: Application
    Filed: April 11, 2008
    Publication date: November 27, 2008
    Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY
    Inventors: Jong-Hyun Lee, Chang-Woo Lee, Jeong-Han Kim
  • Patent number: 7422721
    Abstract: A lead-free solder includes at least one selected from 0.01 to 1% by weight of Co, 0.01 to 0.2% by weight of Fe, 0.01 to 0.2% by weight of Mn, 0.01 to 0.2% by weight of Cr, and 0.01 to 2% by weight of Pd; 0.5 to 2% by weight of Cu; and 90.5% by weight or more of Sn. This solder exhibits a satisfactory solderability in solder joints and shows a high resistance to electrode leaching upon soldering or when the resulting soldered article is left at high temperatures.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: September 9, 2008
    Assignee: Murata Manufacturing Co., Ltd
    Inventors: Hidekiyo Takaoka, Kiyotaka Maegawa
  • Publication number: 20080175748
    Abstract: A solder composition having a mixture of elements including tin, indium, silver, and bismuth, and can include about 30% to 85% tin and about 15% to 65% indium.
    Type: Application
    Filed: March 10, 2008
    Publication date: July 24, 2008
    Inventor: John Pereira
  • Publication number: 20080159903
    Abstract: An alloy suitable for use in a ball grid array or chip scale package comprising from 0.05-1.5 wt. % copper, from 0.1-2 wt. % silver, from 0.005-0.3 wt % nickel, from 0.003-0.3 wt % chromium, from 0-0.1 wt. % phosphorus, from 0-0.1 wt. % germanium, from 0-0.1 wt. % gallium, from 0-0.3 wt. % of one or more rare earth elements, from 0-0.3 wt. % indium, from 0-0.3 wt. % magnesium, from 0-0.3 wt. % calcium, from 0-0.3 wt. % silicon, from 0-0.3 wt. % aluminium, from 0-0.3 wt. % zinc, from 0-2 wt. % bismuth, from 0-1 wt. % antimony, from 0-0.2 wt % manganese, from 0-0.3 wt % cobalt, from 0-0.3 wt % iron, and from 0-0.1 wt % zirconium, and the balance tin, together with unavoidable impurities.
    Type: Application
    Filed: February 25, 2008
    Publication date: July 3, 2008
    Applicant: FRY'S METALS, INC.
    Inventors: Brian G. Lewis, Bawa Singh, John Laughlin, Ranjit Pandher
  • Publication number: 20080159904
    Abstract: An alloy suitable for use in a ball grid array or chip scale package, the alloy comprising from 0.05-1.5 wt. % copper; from 2.5-5 wt. % silver; one or both of from 0.005-0.3 wt % nickel and/or from 0.003-0.3 wt % chromium; from 0-0.1 wt. % phosphorus; from 0-0.1 wt. % germanium; from 0-0.1 wt. % gallium; from 0-0.3 wt. % of one or more rare earth elements; from 0-0.3 wt. % indium; from 0-0.3 wt. % magnesium; from 0-0.3 wt. % calcium; from 0-0.3 wt. % silicon; from 0-0.3 wt. % aluminium; from 0-0.3 wt. % zinc; from 0-2 wt. % bismuth; from 0-1 wt. % antimony; from 0-0.2 wt % manganese; from 0-0.3 wt % cobalt; from 0-0.3 wt % iron; and from 0-0.1 wt % zirconium; and the balance tin, together with unavoidable impurities.
    Type: Application
    Filed: February 25, 2008
    Publication date: July 3, 2008
    Applicant: FRY'S METALS, INC.
    Inventors: Brian G. Lewis, Bawa Singh, John Laughlin, Ranjit Pandher
  • Publication number: 20080152996
    Abstract: This invention relates to intermetallic negative electrode compounds for non-aqueous, electrochemical lithium cells and batteries. More specifically, the invention relates to one or more electrode components or compositions, one of which contains the basic structural unit of a MM?3 intermetallic compound, in which M and M? are comprised of one or more metals. The MM?3 intermetallic electrode compounds can be mixed, blended or integrated with one or more other intermetallic compounds, such as isostructural M3M? compounds. The electrodes are of particular use in rechargeable lithium-ion cells and batteries in numerous applications such as portable electronic devices, medical devices, space, aeronautical and defense-related devices and in transportation applications such as electric and hybrid-electric vehicles.
    Type: Application
    Filed: December 19, 2007
    Publication date: June 26, 2008
    Applicant: UChicago Argonne, LLC
    Inventors: Michael M. Thackeray, John T. Vaughey
  • Patent number: 7338567
    Abstract: A lead-free solder alloy suitable for use in flow soldering of electronic components to printed wiring boards comprises 0.1-3 wt % of Cu, 0.001-0.1 wt % of P, optionally 0.001-0.1 wt % of Ge, and a balance of Sn. The solder alloy may further contain at least one element of Ag and Sb in a total amount of at most 4 wt %, and/or at least one element of Ni, Co, Fe, Mn, Cr, and Mo in a total amount of at most 0.5 wt % in order to strengthen the alloy, and/or at least one element of Bi, In, and Zn in a total amount of at most 5 wt % in order to lower the melting point of the alloy.
    Type: Grant
    Filed: September 22, 2003
    Date of Patent: March 4, 2008
    Assignee: Senju Metal Industry Co., Ltd.
    Inventors: Osamu Munekata, Yoshitaka Toyoda, Tsukasa Ohnishi, Minoru Ueshima
  • Patent number: 7335269
    Abstract: A Pb-free solder alloy based on Sn as matrix is provided, which is a metal that has no toxicity and is environmental friendly. The Pb-free solder comprises a tetra-nary composition consisting essentially of about 99.0 weight % Sn, 0.3 to 0.4 weight % Ag, and 0.6 to 0.7 weight % Cu, with off-eutectic melting temperature of 217 to 227 degree Celsius. The fourth component is a non-metallic phosphorus (P), and 0.01 to 1.0 weight % of phosphorus is added into said composition to improve better micro-structural stability and hence reduce the formation of dross when hand soldering, wave soldering and reflow soldering during the electronic assembly installation process.
    Type: Grant
    Filed: February 23, 2006
    Date of Patent: February 26, 2008
    Assignee: Aoki Laboratories Ltd.
    Inventor: Wai Yin David Leung
  • Publication number: 20070295528
    Abstract: A Pb-free Sn-based material part of a wiring conductor is provided at least at a part of a surface the wiring conductor, and the Sn-based material part includes a base metal doped with a transformation retardant element and an oxidation control element. The transformation retardant element is at least one element selected from a group consisted of Sb, Bi, Cd, In, Ag, Au, Ni, Ti, Zr, and Hf. The oxidation control element is at least one element selected from a group consisted of Ge, P, Zn, Kr, Cr, Mn, Na, V, Si, Al, Li, Mg and Ca. The wiring conductor is reflow processed, such that at least one of the Sn, the transformation retardant element and the oxidation control element is diffused to form an alloy.
    Type: Application
    Filed: June 4, 2007
    Publication date: December 27, 2007
    Applicant: HITACHI CABLE, LTD.
    Inventors: Hajime Nishi, Takayuki Tsuji, Hiroshi Yamanobe, Hiroshi Okikawa
  • Patent number: 7250135
    Abstract: Provided is a Pb-free solder alloy used for mounting electronic parts on a printed circuit board. The Pb-free solder alloy is highly resistant to oxidation and impact. The Pb-free solder alloy includes Ag of 2.8 wt % to 4.2 wt %, Cu of 0.3 wt % to 0.8 wt %, Ge of 0.0001 wt % to 0.01 wt %, In of 0.001 wt % to 0.2 wt %, and the balance of Sn. The Pb-free solder alloy having this composition also has a high shear strength and low brittleness factor after bonding. Thus, the Pb-free solder alloy has high quality mechanical properties, to form a high quality joint.
    Type: Grant
    Filed: October 18, 2005
    Date of Patent: July 31, 2007
    Assignee: MK Electron Co., Ltd.
    Inventors: Suk Joon Lim, Sang Wan Cho
  • Patent number: 7179417
    Abstract: An Sn—Zn lead-free solder alloy according to the present invention is constructed in a manner such that it is an Sn-based solder alloy indispensably containing 6 to 10 wt % zinc at least, and further containing 0.0015 to 0.1 wt % magnesium, said magnesium content being effective quantity for forming a protective magnesium oxide film on the solder surface and also for destroying said oxide film during soldering. When solder paste is preserved, the inside of solder particle is protected by the protective magnesium oxide film formed on the surface of solder particle, and a reaction between zinc and an activator is suppressed, so that preservation stability is improved, and at elevated temperature during soldering, a state where said protective oxide film is easily destroyed is obtained, so that good wettability is held.
    Type: Grant
    Filed: May 17, 2006
    Date of Patent: February 20, 2007
    Assignee: Nippon Metal Industry Co., Ltd.
    Inventors: Masaaki Yoshikawa, Haruo Aoyama, Hirotaka Tanaka
  • Patent number: 7175805
    Abstract: An Sn—Zn lead-free solder alloy according to the present invention is constructed in a manner such that it is an Sn-based solder alloy indispensably containing 6 to 10 wt % zinc at least, and further containing 0.0015 to 0.1 wt % magnesium, said magnesium content being effective quantity for forming a protective magnesium oxide film on the solder surface and also for destroying said oxide film during soldering. When solder paste is preserved, the inside of solder particle is protected by the protective magnesium oxide film formed on the surface of solder particle, and a reaction between zinc and an activator is suppressed, so that preservation stability is improved, and at elevated temperature during soldering, a state where said protective oxide film is easily destroyed is obtained, so that good wettability is held.
    Type: Grant
    Filed: November 18, 2002
    Date of Patent: February 13, 2007
    Assignee: Nippon Metal Industry Co., Ltd.
    Inventors: Masaaki Yoshikawa, Haruo Aoyama, Hirotaka Tanaka
  • Patent number: 7172726
    Abstract: A lead-free solder which is significantly less susceptible to copper leaching when used in a molten state in which coil ends of copper wire are dipped comprises 1.5–8 mass % of Cu, 0.01–2 mass % of Co, optionally 0.01–1 mass % of Ni, and a remainder of Sn and has a liquidus temperature of 420° C. or below. The solder may further comprise at least one oxidation-inhibiting element selected from the group consisting of P, Ge, and Ga in a total amount of 0.001–0.5 mass %, and/or Ag in an amount of 0.05–2 mass % as a wettability-improving element.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: February 6, 2007
    Assignee: Senju Metal Industry Co., Ltd.
    Inventor: Tsukasa Ohnishi
  • Patent number: 7148426
    Abstract: In a lead-free solder comprising an alloy composition composed mainly of tin, the alloy composition further contains 0.002 to 0.015% by mass of phosphorus. This lead-free solder can be used as a plating in a connection lead comprising: a copper strip or other strip conductor; and the plating provided on at least one side of the strip constructor, the plating having a shape such that the plating in the widthwise direction of the strip conductor has a bulge as viewed in section with the apex being located at a proper position in the widthwise direction of the strip conductor. By virtue of this constitution, the lead-free solder on its surface is less likely to be oxidized, and the connection lead has excellent bond strength owing to the property of the lead-free solder and, in addition, has the function of breaking the formed oxide layer and the function of removing included gas bubbles and can eliminate the need to form the plating in very large thickness.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: December 12, 2006
    Assignee: Hitachi Cable, Ltd.
    Inventors: Seigi Aoyama, Takaaki Ichikawa, Hiromitsu Kuroda, Takashi Nemoto, Atsushi Ohtake, Hiroyoshi Hiruta
  • Patent number: 7138086
    Abstract: There is disclosed a soldering alloy which prevents an iron tip of a soldering iron from being deteriorated. The soldering alloy comprises: 0.3 to 3% by weight of Cu; 0.01 to 0.1% by weight of Fe; 0.001 to 0.004% by weight of Ga; and a remainder including Sn and unavoidable impurities.
    Type: Grant
    Filed: December 14, 2004
    Date of Patent: November 21, 2006
    Assignee: Nihom Almit Co., Ltd.
    Inventors: Tadashi Sawamura, Takeo Igarashi, Yasuhito Azuma
  • Patent number: 7029542
    Abstract: A lead-free solder alloy comprises 1.0–5.0 wt % Ag, 0.01–0.5 wt % Ni, one or both of (a) 0.001–0.05 wt % Co and (b) at least one of P, Ge, and Ga in a total amount of 0.001–0.05 wt %, and a remainder of Sn. The solder can form solder bumps which have a high bonding strength and which do not undergo yellowing after soldering.
    Type: Grant
    Filed: July 8, 2003
    Date of Patent: April 18, 2006
    Assignee: Senju Metal Industry Co., Ltd.
    Inventors: Masazumi Amagai, Masako Watanabe, Kensho Murata, Osamu Munekata, Yoshitaka Toyoda, Minoru Ueshima, Tsukasa Ohnishi, Hiroshi Okada
  • Patent number: 7022282
    Abstract: A lead-free solder includes at least one selected from 0.01 to 1% by weight of Co, 0.01 to 0.2% by weight of Fe, 0.01 to 0.2% by weight of Mn, 0.01 to 0.2% by weight of Cr, and 0.01 to 2% by weight of Pd; 0.5 to 2% by weight of Cu; and 90.5% by weight or more of Sn. This solder exhibits a satisfactory solderability in solder joints and shows a high resistance to electrode leaching upon soldering or when the resulting soldered article is left at high temperatures.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: April 4, 2006
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Hidekiyo Takaoka, Kiyotaka Maegawa
  • Patent number: 7005106
    Abstract: Prevented is disconnection, and generation of the bridging effect which causes short circuits between terminals, when electric wire having an insulating coating and terminals are soldered together, in electronic components which are constituted using electric wire having an insulating coating, the core wire thereof being copper or a copper alloy, and in which electronic components distances between neighboring terminals are narrow. Electric wire having an insulating coating, the base metal of which is copper, and terminal portions (connection portions) are soldered together by means of a lead-free solder alloy, which contains 3.0 to 5.5 wt % copper (Cu); 0.1 to 0.5 wt % nickel (Ni); and 0.001 to 0.1 wt % germanium (Ge), the remainder of the solder alloy consisting of tin (Sn).
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: February 28, 2006
    Assignees: Sumida Corporation, Nihon Genma Mfg. Co., Ltd.
    Inventors: Koichi Izumida, Yuki Takano, Hitoshi Abe, Toshiyuki Moribayashi, Koichi Hagio, Junichi Takenaka
  • Patent number: 6936219
    Abstract: Lead-free Tin-Zinc alloy contains Manganese in the amount of about 0.001-0.9 wt. %. The alloy is suitable for use as a solder with commercially available fluxes. Various types of solders can be prepared from the alloy, like wire, cored wire, atomized powder, solder paste, thin sheet, ribbon foil, perform etc. The alloy has improved mechanical and electrical properties in comparison with conventional Tin-Lead alloys Sn9Zn and 63Sn37Pb.
    Type: Grant
    Filed: July 7, 2002
    Date of Patent: August 30, 2005
    Assignee: IKA Industrial Consulting Ltd.
    Inventors: Baruch Kopeliovich, Alberto Kaufman, Yaron Man
  • Patent number: 6884389
    Abstract: Disclosed is a lead-free solder alloy containing 43 to 47% by weight of bismuth, 0.5 to 2.5% by weight of silver, 0.25 to 0.75% by weight of copper, 0.25 to 0.75% by weight of indium, 0.02 to 0.09% by weight of nickel and the balance of tin.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: April 26, 2005
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Kuniaki Takahashi
  • Patent number: 6843862
    Abstract: A substantially lead-free solder with enhanced properties comprises from 88.5% to 93.5% tin; from 3.5% to 4.5% silver; from 2.0% to 6.0% indium; and from 0.3% to 1.0% copper. The solder may also comprise up to 0.5% of an anti-oxidant or anti-skinning additive. A solder embodying the invention finds particular utility in wave-soldering processes where it may be used as a direct replacement for conventional tin/lead solder.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: January 18, 2005
    Assignees: Quantum Chemical Technologies (Singapore) Pte Ltd, Singapore Asahi Chemical and Solder Industries Pte Ltd
    Inventors: Kai Hwa Chew, Wei Chih Pan
  • Patent number: 6837947
    Abstract: This invention discloses a lead-free Sn—Zn—Al—Ag solder alloy, which is composed of 7-10 wt % of Zn, up to 0.5 wt % of Al, up to 4.0 wt % of Ag, and the balance of Sn; and a lead-free Sn—Zn—Al—Ag—Ga solder alloy, which is composed of 7-10 wt % of Zn, up to 0.5 wt % of Al, up to 4.0 wt % of Ag, up to 4.0 wt % of Ga; and the balance of Sn. The lead-free solder alloys of the present invention have better tensile strength and elongation than the conventional Sn—Pb solder alloys. In addition, the lead-free solder alloys of the present invention have a melting point lower than 200° C., which is close to the 183.5° C. of an eutectic Sn—Pb alloy.
    Type: Grant
    Filed: January 15, 2002
    Date of Patent: January 4, 2005
    Assignee: National Cheng-Kung University
    Inventors: Kwang-Lung Lin, Kang-I Chen, Shou-Chang Cheng, Jia-Wei Huang
  • Publication number: 20040241039
    Abstract: Disclosed is a high temperature, high performance lead-free solder alloy comprising effective amounts of tin, copper, silver, bismuth, and antimony and having a liquidus temperature above 215° C. More particularly, several lead-free solder alloys are disclosed that comprise about (i) at least about 90% Sn, 0.2 to 5.0% Cu, 0.05 to 5.0% Bi; or (ii) at least about 75% Sn, 0.5 to 7.0% Cu, 0.05 to 18% Sb; or (iii) at least about 67% Sn, 3 to 15% Ag, 0.01 to 18% Sb; (iv) at least about 78% Sn, 0.8 to 7.0% Cu, 4 to 15% Ag; (v) at least about 96% Sn, and at least one of 0.01 to 2.0% Ni, and 0.01 to 2.0% Co; (vi) at least about 90% Sn, 0.05 to 5.0% Bi, and 0 to 5.0% Sb; and (vii) at least about 90% Sn, 0.2 to 0.9% Cu, and 0.1 to 5.0% Bi.
    Type: Application
    Filed: June 22, 2004
    Publication date: December 2, 2004
    Applicant: H-Technologies Group
    Inventor: Jennie S. Hwang
  • Patent number: 6805974
    Abstract: A solder composition and associated method of formation. The solder composition comprises a substantially lead-free alloy that includes tin (Sn), silver (Ag), and copper. The tin has a weight percent concentration in the alloy of at least about 90%. The silver has a weight percent concentration X in the alloy. X is sufficiently small that formation of Ag3Sn plates is substantially suppressed when the alloy in a liquefied state is being solidified by being cooled to a lower temperature at which the solid Sn phase is nucleated. This lower temperature corresponds to an undercooling &dgr;T relative to the eutectic melting temperature of the alloy. Alternatively, X may be about 4.0% or less, wherein the liquefied alloy is cooled at a cooling rate that is high enough to substantially suppress Ag3Sn plate formation in the alloy. The copper has a weight percent concentration in the alloy not exceeding about 1.5%.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: October 19, 2004
    Assignee: International Business Machines Corporation
    Inventors: Won K. Choi, Charles C. Goldsmith, Timothy A. Gosselin, Donald W. Henderson, Sung K. Kang, Karl J. Puttlitz, Sr., Da-Yuan Shih
  • Patent number: 6774490
    Abstract: An electronic equipment is capable of improving falling down shock resistance or impact resistance in an electronic equipment and of improving reliability of a solder joint in a semiconductor device die-bonded Si chip or the like to which thermal shock causing large deformation may act, bump mounting of BGA, CSP, WPP, flip-chip and so forth, a power module acting large stress and so forth. The electronic equipment has a circuit board and an electronic parts to be electrically connected to an electrode of the circuit board. The electrode of the circuit board and an electrode of the electronic part are connected by soldering using a lead free solder consisted of Cu: 0-2.0 mass %, In: 0.1-10 mass %, and Sn: remaining amount.
    Type: Grant
    Filed: March 25, 2003
    Date of Patent: August 10, 2004
    Assignee: Hitachi, Ltd.
    Inventors: Tasao Soga, Hanae Shimokawa, Tetsuya Nakatsuka, Masato Nakamura, Yuji Fujita, Toshiharu Ishida, Masahide Okamoto, Koji Serizawa, Toshihiro Hachiya, Hideki Mukuno
  • Publication number: 20040151616
    Abstract: Lead-free alloys comprising tin, copper, antimony, silver and a lanthanide metal are disclosed. Also disclosed are methods of preparing the lead-free alloys and their use for soldering and babbitting. The lead-free solder alloys exhibit improved tensile and shear strength, and they exhibit flow characteristics similar to those of 50:50 tin:lead alloys.
    Type: Application
    Filed: February 4, 2003
    Publication date: August 5, 2004
    Inventors: Daniel M. Sabarese, Harold Stuhler, Mark A. Sabarese
  • Patent number: 6726780
    Abstract: There is provided a lead-free solder which makes it possible to reliably and accurately perform the inspection of various kinds of defective soldering in the inspection using an image inspection apparatus after the reflow soldering. According to this lead-free solder, the delustering of the metallic luster of fillet is realized in order to minimize the probability of generating a dark portion at the area where no defective soldering is existed and instead to increase the area of whitish portion which can be generated through the irregular reflection of beam. Specifically, this invention provides a lead-free solder comprising an Sn—Ag—Cu-based lead-free solder containing a small quantity of Bi and Sb as an element which is capable of generating a delustering component for minimizing metallic luster of the fillet.
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: April 27, 2004
    Assignee: Tamura Kaken Corporation
    Inventors: Takao Ono, Mitsuru Iwabuchi, Kenji Fujimori, Hiroaki Koyahara
  • Publication number: 20040076541
    Abstract: A friction-resistant alloy being a tin matrix containing copper, antimony, and between about 0.10% and about 2% by weight bismuth; and an industrial bearing component having this alloy on a wear surface.
    Type: Application
    Filed: October 22, 2002
    Publication date: April 22, 2004
    Inventors: John P. Laughlin, David V. Kyaw
  • Patent number: 6692691
    Abstract: A Pb-free soldering alloy that does not include any Pb is provided. The soldering alloy prevents Cu present in a printed-circuit board from combining with Ni in the soldering alloy at the soldered part, prevents Cu from precipitating and diffusing in the soldering alloy, suppresses the generation of fine cracks at the soldered part and increases the mechanical strength of the soldered part. The Pb-free soldering alloy contains 3.5 to 6.0 wt. % Ag, 0.001 to 1.0 wt. % Ni and Sn for the balance.
    Type: Grant
    Filed: June 29, 2001
    Date of Patent: February 17, 2004
    Assignees: Nihon Alimit Co., Ltd., Matsushita Electric Industrial Co., Ltd.
    Inventors: Tadashi Sawamura, Hisashi Komiya, Tsuguo Inazawa, Fujio Nakagawa
  • Publication number: 20030230361
    Abstract: Disclosed is a lead-free solder alloy containing 43 to 47% by weight of bismuth, 0.5 to 2.5% by weight of silver, 0.25 to 0.75% by weight of copper, 0.25 to 0.75% by weight of indium, 0.02 to 0.09% by weight of nickel and the balance of tin.
    Type: Application
    Filed: June 16, 2003
    Publication date: December 18, 2003
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventor: Kuniaki Takahashi
  • Patent number: 6649127
    Abstract: New and improved substantially lead-free solder compositions are provided exhibiting excellent wettability and mechanical properties. In an embodiment, an improved solder material is a substantially silver-free material including from about 0.5 to about 10% by weight of Zn, from about 0.5 to about 8% by weight of Bi, from about 0.005 to about 0.5% by weight of Ge, from about 0.3 to about 3% by weight of Cu and the balance to make 100% by weight of Sn. In another embodiment, an improved solder material includes from about 0.5 to 8% by weight of Bi, from about 0.5 to about 3% by weight of Ag, from about 0.01 to about 0.1% by weight of Ge, from about 0.3 to about 1% by weight of Cu, and the balance to make 100% by weight of Sn. In a further embodiment, an improved solder material includes from about 3 to about 15% by weight of Zn, from about 3 to about 10% by weight of In, from about 0.01 to about 0.3% by weight of Ge, from about 0.3 to about 3% by weight of Ag and the balance to make 100% by weight of Sn.
    Type: Grant
    Filed: March 21, 2001
    Date of Patent: November 18, 2003
    Inventors: Kazutaka Habu, Naoko Takeda
  • Patent number: 6648210
    Abstract: Tombstoning susceptibility and reflow peak temperature reduction of solder alloys, in particularly lead-free solder alloys, has been found to be achieved effectively by mixing the solder alloy in the form of an alloy paste with a low melting alloy utilised in powder form, in particular a Bi-containing alloy.
    Type: Grant
    Filed: February 9, 2001
    Date of Patent: November 18, 2003
    Assignee: Multicore Solders Limited
    Inventor: Hector Andrew Hamilton Steen
  • Publication number: 20030178101
    Abstract: There is provided a lead-free solder which makes it possible to reliably and accurately perform the inspection of various kinds of defective soldering in the inspection using an image inspection apparatus after the reflow soldering. According to this lead-free solder, the delustering of the metallic luster of fillet is realized in order to minimize the probability of generating a dark portion at the area where no defective soldering is existed and instead to increase the area of whitish portion which can be generated through the irregular reflection of beam. Specifically, this invention provides a lead-free solder comprising an Sn—Ag—Cu-based lead-free solder containing a small quantity of Bi and Sb as an element which is capable of generating a delustering component for minimizing metallic luster of the fillet.
    Type: Application
    Filed: March 10, 2003
    Publication date: September 25, 2003
    Inventors: Takao Ono, Mitsuru Iwabuchi, Kenji Fujimori, Hiroaki Koyahara
  • Patent number: 6555052
    Abstract: An electronic equipment is capable of improving falling down shock resistance or impact resistance in an electronic equipment and of improving reliability of a solder joint in a semiconductor device die-bonded Si chip or the like to which thermal shock causing large deformation may act, bump mounting of BGA, CSP, WPP, flip-chip and so forth, a power module acting large stress and so forth. The electronic equipment has a circuit board and an electronic parts to be electrically connected to an electrode of the circuit board. The electrode of the circuit board and an electrode of the electronic part are connected by soldering using a lead free solder consisted of Cu: 0˜2.0 mass %, In: 0.1˜10 mass %, and Sn: remaining amount.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: April 29, 2003
    Assignee: Hitachi, Ltd.
    Inventors: Tasao Soga, Hanae Shimokawa, Tetsuya Nakatsuka, Masato Nakamura, Yuji Fujita, Toshiharu Ishida, Masahide Okamoto, Koji Serizawa, Toshihiro Hachiya, Hideki Mukuno
  • Patent number: 6488888
    Abstract: A lead-free solder alloy having a relatively low melting temperature and suitable for use to solder electronic devices consists essentially of: from 7 to 10 wt % of Zn; at least one of from 0.01 to 1 wt % of Ni, from 0.1 to 3.5 wt % of Ag, and from 0.1 to 3 wt % of Cu; optionally at least one of from 0.2 to 6 wt % of Bi, from 0.5 to 3 wt % of In, and from 0.001 to 1 wt % of P; and a balance of Sn. Another such lead-free solder alloy consists essentially of: from 2 to 10 wt % of Zn; from 10 to 30 wt % of Bi; from 0.05 to 2 wt % of Ag; optionally from 0.001 to 1 wt % of P, and a balance of Sn. These solder alloys have a tensile strength of at least 5 kgf/mm2 and at least 10% elongation.
    Type: Grant
    Filed: April 9, 2001
    Date of Patent: December 3, 2002
    Assignees: Matsushita Electric Industrial Co., Ltd., Senju Metal Industry Co., Ltd.
    Inventors: Toshikazu Murata, Hiroji Noguchi, Sadao Kishida, Toshihiko Taguchi, Shozo Asano, Ryo Oishi, Takashi Hori
  • Publication number: 20020155024
    Abstract: Disclosed is a high temperature, high performance lead-free solder alloy comprising effective amounts of tin, copper, silver, bismuth, and antimony and having a liquidus temperature above 215° C. More particularly, several lead-free solder alloys are disclosed that comprise about (i) at least about 90% Sn, 0.2 to 5.0% Cu, 0.05 to 5.0% Bi; or (ii) at least about 75% Sn, 0.5 to 7.0% Cu, 0.05 to 18% Sb; or (iii) at least about 67% Sn, 3 to 15% Ag, 0.01 to 18% Sb; (iv) at least about 78% Sn, 0.8 to 7.0% Cu, 4 to 15% Ag; (v) at least about 96% Sn, and at least one of 0.01 to 2.0% Ni, and 0.01 to 2.0% Co; (vi) at least about 90% Sn, 0.05 to 5.0% Bi, and 0 to 5.0% Sb; and (vii) at least about 90% Sn, 0.2 to 0.9% Cu, and 0.1 to 5.0% Bi.
    Type: Application
    Filed: October 29, 2001
    Publication date: October 24, 2002
    Applicant: H-Technologies Group, Inc.
    Inventor: Jennie S. Hwang
  • Publication number: 20020106302
    Abstract: A solder material optimum in the melting temperature as a solder material, superior in mechanical properties and in wettability and capable of assuring excellent soldering performance. For a Sn—Zn—Bi based solder material, germanium and cooper is added, while germanium and further copper are added for a Sn—Bi—Ag based solder material and germanium and silver are added for a Sn—Zn—In based solder material.
    Type: Application
    Filed: February 8, 2002
    Publication date: August 8, 2002
    Inventors: Kazutaka Habu, Naoko Takeda
  • Patent number: 6428745
    Abstract: Disclosed are a solder and a solder paste used for soldering an electronic part to a circuit board. This solder comprises 2.0 to 3.5 wt % of Ag, 5 to 18 wt % of Bi and Sn for the rest. Alternatively, it further contains at least one element selected from the group consisting of 0.1 to 1.5 wt % of In, 0.1 to 0.7 wt % of Cu and 0.1 to 10 wt % of Zn.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: August 6, 2002
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Atsushi Yamaguchi, Tetsuo Fukushima, Kenichiro Suetsugu, Akio Furusawa
  • Patent number: 6416883
    Abstract: A lead-free solder composition comprising: 20 to 30 wt. % bismuth, 1.0 to 3.0 wt. % silver, 0.01 to 2.0 wt. % copper, 0.01 to 4.0 wt. % antimony and incidental impurities, the balance being tin.
    Type: Grant
    Filed: January 3, 2000
    Date of Patent: July 9, 2002
    Assignee: Ecosolder International Pty Ltd
    Inventor: Ian Noel Walton
  • Patent number: 6365097
    Abstract: A novel lead-free Sn—Bi based alloy having an improved wettability in comparison to conventional Sn—Bi based alloys, a melting point lower than 221° C., the eutectic point of an Sn—Ag alloy, and proper bonding and heat-resistant properties is provided. This alloy is an Sn—Bi based alloy containing tin as a major component, and 21 wt.% or less bismuth, 4 wt.% or less silver, 2 wt.% or less copper (inclusive of zero), and 0.2 wt.% or less nickel.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: April 2, 2002
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Mitsuo Yamashita, Shinji Tada, Kunio Shiokawa
  • Publication number: 20020015660
    Abstract: A lead-free solder alloy having a relatively low melting temperature and suitable for use to solder electronic devices consists essentially of: from 7 to 10 wt % of Zn; at least one of from 0.01 to 1 wt % of Ni, from 0.1 to 3.5 wt % of Ag, and from 0.1 to 3 wt % of Cu; optionally at least one of from 0.2 to 6 wt % of Bi, from 0.5 to 3 wt % of In, and from 0.001 to 1 wt % of P; and a balance of Sn. Another such lead-free solder alloy consists essentially of: from 2 to 10 wt % of Zn; from 10 to 30 wt % of Bi; from 0.05 to 2 wt % of Ag; optionally from 0.001 to 1 wt % of P, and a balance of Sn. These solder alloys have a tensile strength of at least 5 kgf/mm2 and at least 10% elongation.
    Type: Application
    Filed: April 9, 2001
    Publication date: February 7, 2002
    Inventors: Toshikazu Murata, Hiroji Noguchi, Sadao Kishida, Toshihiko Taguchi, Shozo Asano, Ryo Oishi, Takashi Hori