Cobalt Containing Patents (Class 420/585)
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Patent number: 5516485Abstract: Air meltable, weldable cast alloys of high hot strength and hot gas corrosion resistance especially in the service temperature range of about 1800.degree. F. to 2100.degree. F. which consist essentially of:______________________________________ Nickel 41-54% by weight Chromium 24-29% Iron 8-18% Cobalt 3-8% Tungsten 4.5-6.5% Molybdenum 4-6.5% Niobium 0.8-2% Manganese 0.1-1.5% Silicon 0.1-1.5% Carbon 0.2-0.4% ______________________________________provided, that the nickel plus cobalt content is at least about 45%.Type: GrantFiled: March 17, 1994Date of Patent: May 14, 1996Assignee: Carondelet Foundry CompanyInventor: John H. Culling
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Patent number: 5514328Abstract: A cavitation erosion resistant alloy comprising about 10 to 40 percent by weight of one or more carbide formers including some chromium, 5 to 15 percent by weight cobalt, 5 to 15 percent by weight manganese, 3.5 to 7.0 percent by weight silicon, 1.8 to 4.8 percent by weight nickel, 0.15 to 3.5 percent by weight carbon plus boron, up to 0.3 percent weight nitrogen and the balance being iron plus impurities.Type: GrantFiled: May 12, 1995Date of Patent: May 7, 1996Assignee: Stoody Deloro Stellite, Inc.Inventors: Ravi Menon, William C. Mosier, James B. C. Wu
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Patent number: 5439640Abstract: The invention provides a controlled coefficient of thermal expansion alloy having in weight percent about 26-50% cobalt, about 20-40% nickel, about 20-35% iron, about 4-10% aluminum, about 0.5-5% niobium plus 1/2 of tantalum weight percent and about 1.5-10% chromium. Additionally the alloy may contain about 0-1% titanium, about 0-0.2% carbon, about 0-1% copper, about 0-2% manganese, about 0-2% silicon, about 0-8% molybdenum, about 0-8% tungsten, about 0-0.3% boron, about 0-2% rhenium, about 0-2% hafnium, about 0-0.3% zirconium, about 0-0.5% nitrogen, about 0-1% yttrium, about 0-1% lanthanum, about 0-1% total rare earths other than lanthanum, about 0-1% cerium, about 0-1% magnesium, about 0-1% calcium, about 0-4% oxidic dispersoid and incidental impurities. The alloy may be further optimized with respect to crack growth resistance by annealing at temperature below about 1010.degree. C. or temperatures between 1066.degree. C. or 1110.degree. C.Type: GrantFiled: September 3, 1993Date of Patent: August 8, 1995Assignee: Inco Alloys International, Inc.Inventors: Karl A. Heck, Melissa A. Moore, Darrell F. Smith, Jr., Larry I. Stein, John S. Smith
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Patent number: 5425822Abstract: A hard facing chromium-base alloy consisting essentially of 30.0 to 48.0% by weight of nickel. 1.5 to 15.0% by weight of tungsten and/or 1.0 to 6.5% by weight of molybdenum, the balance being more than 40.0% by weight of chromium, and the maximum sum of tungsten and molybdenum being 15.0% by weight. The alloy may also contain one or more of iron, cobalt, carbon, boron, aluminum, silicon, niobium and titanium. When the alloy is used in powder form as a material for hard facing by welding, the alloy may further contain 0.01 to 0.12% by weight of aluminum, yttrium, misch metal, titanium, zirconium and hafnium. 0.01 to 0.1% by weight of oxygen may also be added to the alloy. The alloy has a high degree of toughness wear resistance and corrosion resistance. The alloy can be used as a hard facing material to be applied to various objects, such as automobile engine valves.Type: GrantFiled: November 30, 1993Date of Patent: June 20, 1995Assignee: Fukuda Metal Foil & Powder Co., Ltd.Inventors: Kensuke Hidaka, Kanichi Tanaka, Yoshio Kohira, Hideshi Yamaguchi, Yoshinao Suzuki, Masahiro Nakagawa, Yoshio Fuwa, Kazuhiko Mori, Yoshihiko Ito, Atsushi Taguchi
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Patent number: 5422072Abstract: A Co-based alloy exhibits superior high-temperature strength and resistance properties. In one embodiment, the Co-based alloy contains, in weight percent, from about 0.1 to about 1.2 of C; from about 0.01 to about 2 of at least one of Si and Mn; from about 22 to about 37 of Cr; from about 5 to about 15 of Ni; from about 0.1 to about 3.5 of Re; with a balance being Co and incidental impurities. Co and C, Si, Mn, Cr, Ni, Re, B, Zr, W, Mo, Ta, and Nb impart high-temperature wear resistance to the alloy to withstand repeated temperature cycling in a glass spinnaret. In one embodiment of the present invention, Hf is added to improve molten glass corrosion resistance, while Y and other rare earth elements are added in alternate embodiments to improve high-temperature oxidation resistance. Percentages by weight are disclosed for enhanced high-temperature oxidation resistance, increased fluid wear resistance and enhanced molten glass corrosion resistance.Type: GrantFiled: December 20, 1993Date of Patent: June 6, 1995Assignee: Mitsubishi Materials Corp.Inventors: Akira Mitsuhashi, Kensho Sahira, Saburo Wakita
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Patent number: 5350560Abstract: Disclosed are iron based, austenitic alloys of substantially reduced cobalt content compared to current cobalt based alloys, such as Stellite 1 and 6, which are substantially less expensive than current cobalt based alloys, which are machinable using standard machine processes and procedures, which can be deposited as a hard surface with a tight crack pattern or a smooth surface, which does not stress crack upon cooling, which provides substantially reduced radiation exposure by plant maintenance workers in nuclear power plants, and which has a superior hardness, lower friction coefficiency, metal to metal wear loss and erosion loss than cobalt based alloys, such as Stellite 1 and Stellite 6. The alloying content comprises from about 38.0 to 62.0 percent by weight, and has a cobalt content of from about 3.00 to 9.00 percent by weight.Type: GrantFiled: July 12, 1993Date of Patent: September 27, 1994Assignee: Triten CorporationInventor: John M. Kasiske
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Patent number: 5320801Abstract: Air-meltable, castable, machinable, hardenable alloys that are resistant to highly corrosive and abrasive slurries, especially those employed in the handling of wet-process phosphoric acid reactor fluids or hot concentrated sulfuric acid. The alloys consist of, by weight, about 11% to about 40% nickel (plus cobalt), about 27% to about 42% chromium, about 1% to about 4% copper, about 3% to about 4.5% silicon, about 0.7% to about 2% carbon, about 0.3% to about 3% manganese, up to about 4.5% molybdenum, and the balance essentially iron plus the usual minor impurities.Type: GrantFiled: April 26, 1993Date of Patent: June 14, 1994Assignee: Carondelet Foundry CompanyInventor: John H. Culling
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Patent number: 5314659Abstract: A hard facing chromium-base alloy consisting essentially of 30.0 to 48.0% by weight of nickel, 1.5 to 15.0% by weight of tungsten and/or 1.0 to 6.5% by weight of molybdenum, the balance being more than 40.0% by weight of chromium, and the maximum sum of tungsten and molybdenum being 15.0% by weight. The alloy may also contain one or more of iron, cobalt, carbon, boron, aluminum, silicon, niobium and titanium. When the alloy is used in powder form as a material for hard facing by welding, the alloy may further contain 0.01 to 0.12% by weight of aluminum, yttrium, misch metal, titanium, zirconium and hafnium. 0.01 to 0.1% by weight of oxygen may also be added to the alloy. The alloy has a high degree of toughness, wear resistance and corrosion resistance. The alloy can be used as a hard facing material to be applied to various objects, such as automobile engine valves.Type: GrantFiled: May 15, 1992Date of Patent: May 24, 1994Assignee: Fukuda Metal Foil & Powder Co., Ltd.Inventors: Kensuke Hidaka, Kanichi Tanaka, Yoshio Kohira, Hideshi Yamaguchi, Yoshinao Suzuki, Masahiro Nakagawa, Yoshio Fuwa, Kazuhiko Mori, Yoshihiko Ito, Atsushi Taguchi
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Patent number: 5310522Abstract: Alloys are provided which consist essentially by weight percentages of from about 30% to about 35% Ni, from about 22% to about 25% Cr, from about 4% to about 6.5% Mo, from about 0.2% to about 1.5% W, from about 0.2% to about 0.6% Nb, from about 0.1% to about 0.6% Ti, from about 0.35% to about 1.75% Co, from about 0.05% to about 0.3% C, from about 0.2% to about 1.3% Si, from about 0.2% to about 1.5% Mn, and the balance essentially iron and the usual impurities.Type: GrantFiled: December 7, 1992Date of Patent: May 10, 1994Assignee: Carondelet Foundry CompanyInventor: John H. Culling
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Patent number: 5226980Abstract: A novel oxide-dispersion strengthened type heat-resistant alloy is provided for use of preparing furnace members such as a skid rail. The alloy consists essentially of up to about 0.2% C+N, up to about 2.0% Si, up to about 2.0% Mn, about 15 to 35% Ni and about 0.2 to 4% Ta, and the balance of Fe, and contains about 0.1-2% of fine particles of high melting point metal oxide such as Y.sub.2 O.sub.3 dispersed in the austenite matrix.The alloy exhibits excellent properties of anti-hot deformation, oxidation resistance, abrasion resistance and thermal shock resistance.Type: GrantFiled: April 8, 1992Date of Patent: July 13, 1993Assignees: Diado Tokushuko Kabushiki Kaisha, Inco Alloys International, Inc.Inventors: Kenji Tsukuta, Tomohito Iikubo
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Patent number: 5194222Abstract: An alloy exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises, in weight percent, not more than 0.05% C, 0.02-0.5% Si, 0.02-0.5% Mn, 15-35% Cr, 0.5-4% Mo, 10-40% Co, 5-15% Fe, 0.5-5% W, 0.0003-0.005% Ca and the remainder of Ni at a content of not less than 4% and unavoidable impurities, provided that Cr (%)+0.5Ni (%)+3Mo (%).gtoreq.30 (%) and Ni (%)+0.5Co (%).gtoreq.Cr (%)+Mo (%)+W (%). A composite steel tube exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises an inner tube constituted of Cr-containing boiler tube and an outer tube constituted of the alloy.Type: GrantFiled: December 20, 1991Date of Patent: March 16, 1993Assignee: Nippon Steel CorporationInventors: Hiroyuki Ogawa, Tetsuo Ishitsuka, Kozo Denpo, Akihiro Miyasaka, Michihisa Ito, Mizuo Sakakibara
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Patent number: 5190832Abstract: An alloy exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises, in weight percent, not more than 0.05% C, 0.02-0.5% Si, 0.02-0.5% Mn, 15-35% Cr, 0.5-4% Mo, more than 40% but not more than 60% Co, 5-15% Fe, 0.5-5% W, 0.0003-0.005% Ca and the remainder of Ni at a content of not less than 4% and unavoidable impurities, provided that Cr (%)+0.5Ni (%)+3Mo (%).gtoreq.30 (%). A composite steel tube exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises an inner tube constituted of Cr-containing boiler tube and an outer tube constituted of the alloy.Type: GrantFiled: December 20, 1991Date of Patent: March 2, 1993Assignee: Nippon Steel CorporationInventors: Hiroyuki Ogawa, Tetsuo Ishitsuka, Kozo Denpo, Akihiro Miyasaka, Koichi Takeda, Satoshi Araki
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Patent number: 5154885Abstract: A protective coating for metal components formed of nickel or cobalt-based superalloys essentially consists of the following constituents (in percentages by weight):1 to 20% rhenium,22 to 50% chromium,0 to 15% aluminum, the share of chromium and aluminum taken together being at least 25% and at most 53%,0.3 to 2% in total of at least one reactive element from the group consisting of the rare earths, and0 to 3% silicon,impurities, as well as the following elective components:0 to 5% hafnium,0 to 12% tungsten,0 to 10% manganese,0 to 15% tantalum,0 to 5% titanium,0 to 4% niobium, and0 to 2% zirconium,the total share of the elective components being from 0 to a maximum of 15%, and a remainder primarily being at least one of the elements iron, nickel, and cobalt.Type: GrantFiled: August 10, 1990Date of Patent: October 13, 1992Assignee: Siemens AktiengesellschaftInventors: Norbert Czech, Friedhelm Schmitz
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Patent number: 5114503Abstract: A magnetic core comprised of an amorphous alloy ribbon wound into a toroidal shape, wherein the said amorphous alloy has a composition of the formula:(Co.sub.1-x-y-z Fe.sub.x Ni.sub.y Mn.sub.z).sub.100-a-b-c M.sub.a Si.sub.b B.sub.cwherein M is at least one element selected from the group consisting of Nb, Cr and Mo, and x, y, z, a, b and c are numbers which satisfy relations of 0<a.ltoreq.6, 13.ltoreq.b.ltoreq.16, 7.ltoreq.b.ltoreq.10, 0<x.ltoreq.0.1, 0.ltoreq.y.ltoreq.0.2 and 0.ltoreq.x.ltoreq.0.13 respectively, said amorphous alloy after heat treatment having a rectangular ratio Br/Bs of at least 80%, a Bs value in a range of 5 KG to 8 KG and a stress relief ratio of at least 75%.Type: GrantFiled: March 24, 1987Date of Patent: May 19, 1992Assignee: Hitachi Metals, Inc.Inventors: Yoshihito Yoshizawa, Kiyotaka Yamauchi
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Patent number: 5064731Abstract: A dental prosthesis comprises an inner layer portion and an outer layer portion. The outer layer portion is a dental porcelain material, while the inner layer portion is a sintered product which, after sintering, is composed of:(i) 40 to 95% by weight of one or (two or) more electric conductive ceramic materials selected from the group consisting of nitride ceramics, boride ceramics and carbide ceramics, all having a specific electric resistance of 10.sup.-1 .OMEGA..multidot.cm or below, and(ii) 5 to 60% by weight of the following (A) and/or (B):(A) a dental porcelain material, and(B) one or (two or) more metals selected from the group consisting of Ti, Zr, Au, Pt, Pd, Ag, In and Sn.Type: GrantFiled: March 21, 1990Date of Patent: November 12, 1991Assignee: G-C Dental Industrial Corp.Inventors: Takashi Miyazaki, Takashi Inamochi, Masaaki Kitamura, Shohei Hayashi
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Patent number: 5064610Abstract: A heat resistant steel for use as a material of engine valves, having a composition containing, not less than 0.01% and below 0.20% of carbon, from 0.05% to 1.0% of silicon, from 7.5% to 15.0% of manganese, from 2.0% to 20.0% in total of at least one of nickel and cobalt, from 15.0% to 25.0% of chromium, not more than 3.0% of molybdenum, above 2.0% and not more than 10.0% of tungsten, not less than 0.01% and below 0.50% of niobium, from 0.30% to 0.65% of nitrogen, not more than 0.02% of boron, and the balance incidental inclusions and iron. Cobalt content is determined to meet the condition of % Co=(Ni.+-.5)%. The heat resistant steel meets the conditions of: oxidation weight loss when held at 1000.degree. C. for 100 hours being not greater than 0.15 mg/cm.sup.2 /hour in atmosphere; tensile strength being not less than 20 kgf/mm.sup.2 at 900.degree. C. after a solution treatment at 1030.degree. to 1070.degree. C. and a subsequent aging treatment; and creep rupture life at 900.degree. C.Type: GrantFiled: July 30, 1990Date of Patent: November 12, 1991Assignee: Hitachi Metals, Ltd.Inventors: Koji Sato, Rikizo Watanabe
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Patent number: 5019459Abstract: A high temperture, bimetallic cylinder of either ASTM 193B-16 carbon steel or duplex stainless steel having a wear and corrosion resistant inlay or liner of a nickel-based alloy containing 1.5 to 4.5% carbon, 1.5 to 3.5% silicon, 1.0 to 3.0% boron, up to 7.0% chromium, up to 15% iron, 1.0 to 6.0% cobalt and 30 to 60% tungsten. The inlay is centrifugally cast within the cylinder which is thermally compatible with the inlay such that it retains a high yield strength after casting.Type: GrantFiled: April 5, 1990Date of Patent: May 28, 1991Assignee: Xaloy IncorporatedInventors: Schiao F. Chou, Willie Roberson
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Patent number: 5002731Abstract: Disclosed is a cobalt-base alloy that has a valuable combination of both corrosion- and wear-resistant properties. The alloy nominally contains, in percent by weight, 25.5 chromium, 8.5 nickel, 3.0 iron, 5 molybdenum, 2 tungsten, 0.40 silicon, 0.75 manganese, 0.06 carbon, 0.08 nitrogen and the balance cobalt plus normal impurities normally found in alloys of this class. The alloy may also contain copper and certain "carbide formers" (i.e., columbium, tantalum, titanium, vanadium and the like) to tie up excess carbon and/or nitrogen that may be present.Type: GrantFiled: April 17, 1989Date of Patent: March 26, 1991Assignee: Haynes International, Inc.Inventors: Paul Crook, Aziz I. Asphahani, Steven J. Matthews
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Patent number: 4931255Abstract: This invention relates to a nickel-cobalt alloy comprising the following elements in percent by weight:______________________________________ Carbon about 0-0.05 Molybdenum about 6-11 Iron about 0-1 Titanium about 0-6 Chromium about 15-23 Boron about 0.005-0.020 Columbium about 1.1-10 Aluminum about 0.4-4.0 Cobalt about 30-60 Nickel balance ______________________________________the alloy having an electron vacancy number, N.sub.v, defined by N.sub.v =0.61 Ni+1.71 Co+2.66 Fe+4.66 Cr+5.66 Mo wherein the respective chemical symbols represent the effective atomic fractions of the respective elements present in the alloy, the value not exceeding the value N.sub.v =2.82-0.017 W.sub.Fe, wherein W.sub.Fe is the percent by weight of iron in the alloy.In one aspect, the alloy of the present invention is preferably finally cold worked at ambient temperature to a reduction in cross-section of at least 5% and up to about 40%, although higher levels of cold work may be used with some loss of thermomechanical properties.Type: GrantFiled: December 2, 1988Date of Patent: June 5, 1990Assignee: SPS Technologies, Inc.Inventors: Roger D. Doherty, Rishi P. Singh, John S. Slaney
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Patent number: 4822567Abstract: Antibiotic alloys adapted for making sanitary articles, such as orthodontic fittings and component parts of water purifying apparatus, the alloy containing cobalt to impart an antibiotic ability hereto, and iron and nickel to enhance the workability thereof so that the alloy can be easily worked into intricate shapes.Type: GrantFiled: October 29, 1987Date of Patent: April 18, 1989Assignee: Sankin Kogyo Kabushiki KaishaInventors: Isamu Kato, Sadayuki Yuhda, Naoki Oda, Masahiro Suganuma
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Patent number: 4818483Abstract: An air-meltable, workable, castable, weldable, machinable, nonmagnetic alloy resistant to seawater and corrosive process fluids of the type that may be circulated in seawater-cooled heat exchangers. The alloy consists essentially of between about 3% and about 8% by weight manganese, between about 12% and about 28% by weight nickel, between about 17.3% and about 19% by weight chromium, between about 0.68% and about 3.51% by weight copper, between about 0.07% and about 0.25% by weight nitrogen, between about 5.9% and about 8% by weight molybdenum, up to about 0.08% by weight carbon, up to about 1.5% by weight silicon, up to about 0.66% by weight niobium, up to about 1.32% by weight tantalum, up to about 1% by weight vanadium, up to about 1% by weight titanium, up to about 0.6% by weight of a rare earth component selected from the group consisting of cerium, lanthanum, and misch metal, up to about 5% by weight cobalt, and between about 30% and about 56% by weight iron.Type: GrantFiled: December 29, 1986Date of Patent: April 4, 1989Assignee: Carondelet Foundry CompanyInventor: John H. Culling
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Patent number: 4765957Abstract: The alloys of this invention are of low strategic element content, nonmagnetic, resistant to damage by chloride- or other halide-containing solutions as well as to a wide variety of other chemical agents, airmeltable, castable, of improved fabricability and weldability and of higher chromium level but lower molybdenum contents than other alloys intended for chloride resistance. The alloys consist by weight percentages of from about 13.5% to about 29% Ni, from about 23 to about 26% Cr, from about 3.75 to about 6% Mo, from about 2.95 to about 4.5% Mn, from about 3 to about 6.39% Cu, from about 0.3 to about 2.07% Cb (Nb), from about 0 to about 1.5% Si, from about 0 to about 0.09% C, from about 0.10% to about 0.45% N, up to about 1% V, up to about 1% Ti, up to about 5% Co, as a partial substitute for Ni, up to about 0.3% Ce, La or Misch metal, and the balance essentially iron. The sum of the Ni and Co content is between about 18.5% and about 29% by weight.Type: GrantFiled: December 29, 1986Date of Patent: August 23, 1988Assignee: Carondelet Foundry CompanyInventor: John H. Culling
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Patent number: 4765956Abstract: Nickel-chromium alloys consisting essentially of from 30-75 nickel, 12-30% chromium, up to 10% molybdenum, up to 8% tungsten, up to 15% cobalt, up to 5% of niobium and/or tantalum, titanium plus aluminum up to 5%, and carbon nitrogen and silicon in correlated percentages to thereby improve low cycle and thermal fatigue strength, the balance being from 0 to 50% iron.Type: GrantFiled: August 18, 1986Date of Patent: August 23, 1988Assignee: Inco Alloys International, Inc.Inventors: Gaylord D. Smith, Jack M. Wheeler, Stephen C. Tassen
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Patent number: 4743318Abstract: An iron-nickel-chromium-aluminum alloy containing about 30 to 40% nickel, about 15 to less than 19% chromium, about 2 to 4% aluminum, carbon in an amount of at least 0.05% and up to 0.2%, about 0.2 to 0.8% titanium, from 1.5 to 4% molybdenum, up to 0.1% boron, up to 0.5% zirconium, up to about 5% cobalt and the balance iron.Alloy is characterized by (i) carburization resistance and (ii) stress-rupture strength which is desirable for ethylene pyrolysis tubing, (iii) highly oxidation resistant, (iv) cold workable such that mill product forms can be readily produced without deleterious cracking, (vi) ductile, (vii) structurally stable, i.e., will resist forming detrimental quantities of undesirable phases such as sigma, and (viii) weldable.Type: GrantFiled: September 24, 1986Date of Patent: May 10, 1988Assignee: Inco Alloys International, Inc.Inventors: John J. Fischer, Gaylord D. Smith
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Patent number: 4735772Abstract: The invention relates to magnetic Pd-Co alloys for use in dental prostheses, in particular in root caps. The alloys contain, by weight, 40-60% Pd, 20-59% Co, 0-40% Ni, 0.1-5% Cr, 0.05-0.2% Re, 0.01-0.5% Fe, 0.5-3% Ga, 0-0.1% B, 0-5% Pt or Au, and the gallium may be replaced, in full or in part, by Sn, In, Zn or Mn.Type: GrantFiled: November 25, 1986Date of Patent: April 5, 1988Assignee: Elephant Edelmetaal B.V.Inventor: Joseph M. van der Zel
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Patent number: 4727740Abstract: This invention relates to the thermal and wear resistant, tough alloy at elevated temperatures. The alloy consists essentially of carbon, chromium, iron, titanium, aluminum, tungsten, molybdenum, silicon, manganese, cobalt and balance nickel, further the alloy includes optionally at least one selected from the group consisting of nitrogen, niobium and tantalum, further the alloy includes optionally at least one selected from the group consisting of nitrogen, niobium and tantalum, further the alloy includes optionally at least one selected from the group consisting of boron and zirconium. The alloy according to this invention are widely utilized to serve as the alloy for build-up weld and for guide shoe used in the hot rolling apparatus for fabricating seamless steel pipe.Type: GrantFiled: April 24, 1986Date of Patent: March 1, 1988Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Ritsue Yabuki, Junya Ohe, Takumi Kawamura
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Patent number: 4724012Abstract: In-tube component material for an electronic tube such as a color cathode ray tube, of low thermal expansion coefficient and grain size 2,000-40,000 grains/mm.sup.2, containing Fe as the main constituent and 25-45 wt % Ni, 0.3-10 wt % Cr, and 0-10 wt % Co, and a method of manufacturing it.Type: GrantFiled: September 6, 1985Date of Patent: February 9, 1988Assignee: Kabushiki Kaisha ToshibaInventors: Michihiko Inaba, Tetsuo Fujiwara, Masaharu Kanto, Yasuhisa Ohtake
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Patent number: 4711763Abstract: Disclosed is a sulfidation-resistant alloy. The alloy preferably may contain about 27% each cobalt and chromium, 8% iron, 2.7% silicon and the balance nickel plus normal impurities found in alloys of this class.The alloy is eminently suitable for applications in high temperature, hostile environments generated by many industrial processes, such as refinery, chemical processing and power generations.Type: GrantFiled: December 16, 1986Date of Patent: December 8, 1987Assignee: Cabot CorporationInventor: George Y. Lai
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Patent number: 4711826Abstract: The present invention relates to iron-nickel alloys having improved glass sealing properties. Alloys of the present invention contain from about 30% to about 60% nickel, from about 0.5% to about 3% silicon, from about 0.5% to about 3.5% aluminum and the balance essentially iron. Preferably, the alloys have a total aluminum plus silicon content of less than about 4%. The alloys of the present invention have particular utility in electronic and electrical applications. For example, they may be used as a lead frame or a similar component in a semiconductor package.Type: GrantFiled: January 27, 1986Date of Patent: December 8, 1987Assignee: Olin CorporationInventors: Eugene Shapiro, Michael L. Santella
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Patent number: 4708848Abstract: A nickel/chrome-base alloy, particularly suitable for high temperature molten glass handling and forming apparatus, resistant to oxidation and possessing high rupture strength.Type: GrantFiled: February 18, 1986Date of Patent: November 24, 1987Assignee: Glass Incorporated InternationalInventor: Albert Lewis
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Patent number: 4643767Abstract: Disclosed is an iron-base alloy eminently suited for use as components in nuclear energy installations. The alloy normally contains, in percent by weight, about 20% chromium, about 10% nickel, about 5.5% silicon, about 1.5% carbon, about 8% niobium plus vanadium, about 0.05% nitrogen, less than 1% cobalt as an impurity and the balance iron plus normal impurities found in alloys of this class.Type: GrantFiled: November 19, 1984Date of Patent: February 17, 1987Assignee: Cabot CorporationInventors: Paul Crook, Richard D. Zordan
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Patent number: 4618474Abstract: A Co-base heat resistant alloy consisting essentially of:from 0.05 to 1% by weight of C,from 0.05 to 2% by weight of one or both of Si and Mn,from 31 to 40% by weight of Cr,from 5 to 15% by weight of Ni,from 2 to 12% by weight of one or both of W and Mo andfrom 0.1 to 5% by weight of Hf, and optionally further containing:from 0.01 to 1% by weight of one or both of Al and Y,from 0.5 to 3% by weight of one or both of Ta and Nb andfrom 0.005 to 0.1% by weight of one or both of B and Zr,the rest being Co and unavoidable impurities.Type: GrantFiled: January 25, 1985Date of Patent: October 21, 1986Assignees: Asahi Fiber Glass Company, Limited, Asahi Glass Company, Limited, Mitsubishi Kinzoku Kabushiki KaishaInventors: Junya Ohe, Saburo Wakita, Kiichi Yamatsuta, Shoji Goto, Yukinori Kutsukake, Masuo Sugizaki
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Patent number: 4615658Abstract: This invention relates to an improvement on material of a shroud for gas turbines. The material comprises 0.25-0.7 wt % C, 20-35 wt % Cr, 20-40 wt % Ni and balance Fe, and has an austenitic structure. The amount of the .sigma.-phase in this invention is less than 5% and Nv value (Electron Vacancy Number) is less than 2.8.Type: GrantFiled: July 11, 1985Date of Patent: October 7, 1986Assignee: Hitachi, Ltd.Inventors: Hiromi Kagohara, Yutaka Fukui, Masahiko Sakamoto, Nobuyuki Iizuka
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Patent number: 4560408Abstract: As a construction material in sulphurous environments at high temperatures it has according to the invention been found advantageous to use an austenitic chromium-nickel-manganese alloy having a relatively high content of manganese such as 3-12% and preferably 3-8%.Type: GrantFiled: June 1, 1984Date of Patent: December 24, 1985Assignee: Santrade LimitedInventor: Per H. Wilhelmsson
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Patent number: 4512965Abstract: Quaternary hyperstoichiometric alloys of the formula: ZrCrFeT.sub.x and their hydrides are provided, characterized as having MgZn.sub.2 hexagonal crystal structure wherein T is selected from Mn, Fe, Co, Ni and Cu, and X is a number from 0.1 to 1.0. These alloys readily form hydrides at low hydrogen pressure and are suitable for use as hydrogen storage materials.Type: GrantFiled: November 21, 1983Date of Patent: April 23, 1985Assignee: Koppers Company, Inc.Inventors: William E. Wallace, Faiz Pourarian
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Patent number: 4489040Abstract: Disclosed is an alloy eminently suited for use as a tubular product in deep, sour gas operations. The alloy has an optimum combination of corrosion resistance, high strength in the cold worked condition and resistance to sulfide stress cracking and stress corrosion cracking. A typical alloy contains, in weight percent, 0.03 carbon, 22 chromium, 36 iron, 3 molybdenum, 1 manganese, 36 nickel, 0.60 silicon, 0.15 nitrogen, up to 3 tungsten and incidental impurities including copper, cobalt, columbium, tantalum and titanium.Type: GrantFiled: April 2, 1982Date of Patent: December 18, 1984Assignee: Cabot CorporationInventors: Aziz I. Asphahani, Eugene W. Kelley, Juri Kolts
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Patent number: 4487630Abstract: A high chromium stainless steel especially suited for use as wear (galling) resisting components, for example, valve parts. A typical alloy generally contains chromium, nickel, silicon, carbon, an effective cobalt content and the balance iron plus normal impurities. The alloy may be produced in the form of castings, P/M products, hardfacing and welding materials and wrought mill products.Type: GrantFiled: October 25, 1982Date of Patent: December 11, 1984Assignee: Cabot CorporationInventors: Paul Crook, Richard D. Zordan
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Patent number: 4476091Abstract: Disclosed is an oxidation resilient nickel alloy containing chromium, tungsten and molybdenum in a critical relationship that provides a combination of engineering properties including a high degree of dynamic oxidation resistance and superior strength.The alloy is especially suited for service under severe conditions, for example, as components of gas turbine engines.Type: GrantFiled: March 1, 1982Date of Patent: October 9, 1984Assignee: Cabot CorporationInventor: Dwaine L. Klarstrom
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Patent number: 4443406Abstract: A heat-resistant and corrosion-resistant weld metal alloy consisting essentially of, by weight, less than 0.08% of C, 0.1 to 1.0% of Si, 2 to 3% of Mn, 32 to 42% of Ni, 21 to 25% of Cr, 0.8 to 1.7% of Mo, 0.1 to 1.0% of Nb, up to 0.5% of Ti, up to 2% of Co, up to 2% of Cu, up to 1% of W, up to 0.2% of N, up to 1.0% of V, up to 1.0% of Zr, up to 1.0% of Ta and the balance Fe, wherein the following conditions are met: Ti+Zr.ltoreq.1.0%, Ni+Co.ltoreq.42%, W+V.ltoreq.1.0%, Nb+Ta.ltoreq.1.0%, and 4.ltoreq.Nb/C.ltoreq.15; and an austenitic welded structure composed of an austenitic structural alloy and of a weld metal of the above-mentioned kind are provided by the invention.Type: GrantFiled: May 24, 1982Date of Patent: April 17, 1984Assignees: Hitachi, Ltd., Babcock-Hitachi Kabushiki KaishaInventors: Masayuki Sukekawa, Yoshimitsu Tobita, Seishin Kirihara, Hisashi Morimoto, Kenichi Usami, Katsumi Iijima
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Patent number: 4439236Abstract: Boron-containing transition metal alloys based on one or more of iron, cobalt and nickel, and containing at least two metal components, are characterized by being composed of ultrafine grains of a primary solid-solution phase randomly interspersed with particles of complex borides which are predominantly located at the junctions of at least three grains of the primary solid-solution phase. These alloys are obtained by devitrification of the solid, amorphous state under specific heat-treatment conditions. These alloys can be consolidated into three-dimensional bodies.Type: GrantFiled: April 26, 1982Date of Patent: March 27, 1984Assignee: Allied CorporationInventor: Ranjan Ray
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Patent number: 4425300Abstract: Hard facing nickel-base alloy comprising 10 to 25% by weight of chromium, 3 to 15% by weight of molybdenum, 3 to 7% by weight of silicon, 1 to 2.5% by weight of carbon and 1 to 30% by weight of iron, the balance being substantially nickel. The alloy may also contain up to 0.4% by weight of boron, up to 15% by weight of cobalt, up to 4% by weight of tungsten, up to 3% by weight of tantalum or up to 2% by weight of tin, or two or more of these elements, if necessary. No porosity is likely to be produced in the hard facing layer of the alloy formed on a relatively small piece of base metal.Type: GrantFiled: April 30, 1981Date of Patent: January 10, 1984Assignee: Fukuda Metal Foil & Powder Co., Ltd.Inventors: Takao Teramoto, Kensuke Hidaka
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Patent number: 4416709Abstract: The present invention relates to an amorphous magnetic alloy material suited for use as a core material of a magnetic head.When the magnetic head is subjected to a slide contact with a magnetic tape over a long period of time, a film of oxide and the like is formed on the surface of an amorphous magnetic alloy material due to chemically corrosive media frequently contained in the magnetic coating layer of the magnetic tape or due to carbon dioxide, water and the like contained in the air.The amorphous magnetic alloy material of the present invention is highly corrosion resistant due to the combination of chromium and platinum family element(s), and, the inconveniences in a magnetic head, due to chemical wear, can be prevented even where the magnetic head is operated or stored in a considerably severe condition.Type: GrantFiled: September 10, 1981Date of Patent: November 22, 1983Assignee: TDK Electronics Co., Ltd.Inventors: Kazuo Ohya, Hiroki Fujishima, Norio Ishijima, Hiroyoshi Itoga, Yasuhiko Kominami
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Patent number: 4415532Abstract: Disclosed is a cobalt-base superalloy containing about 32% cobalt, 8% nickel, 26.5% chromium, 2.5% tungsten, 5% niobium, about 1% each manganese and silicon, about 0.4% carbon, and the balance about 23% iron plus incidental impurities and modifiers normally found in alloys of this class. The alloy is readily processed in the form of wrought products, castings, metal powder and all forms of welding and hardfacing materials. The outstanding characteristics of the new alloy include the resistance to cavitation erosion and galling, low cost and minimal use of strategic metals.Type: GrantFiled: March 5, 1981Date of Patent: November 15, 1983Assignee: Cabot CorporationInventor: Paul Crook
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Patent number: 4400209Abstract: An alloy useful for manufacturing high strength deep well casing, tubing and drill pipes for use in oil-well operations is disclosed. The alloy exhibits improved resistance to stress corrosion cracking in the H.sub.2 S--CO.sub.2 --Cl.sup.- environment, which comprises the following alloy composition:______________________________________ C: .ltoreq. 0.1% Si: .ltoreq. 1.0% Mn: .ltoreq. 2.0% P: .ltoreq. 0.030% S: .ltoreq. 0.005% N: 0-0.30% Ni: 25-60% Cr: 22.5-40% Mo: 0-3.5% (excl.) W: 0-7% (excl.) Cr (%) + 10Mo (%) + 5W (%) .gtoreq. 50%, 1.0% .ltoreq. Mo (%) + 1/2W (%) < 3.5% Cu: 0-2.0% Co: 0-2.0% Rare earths: 0-0.10% Y: 0-0.20% Mg: 0-0.10% Ca: 0-0.10% one or more of Nb, Ti, Ta, Zr and V in the total amount of 0.5-4.0, if necessary, Fe and incidental impurities: balance.Type: GrantFiled: June 1, 1982Date of Patent: August 23, 1983Assignee: Sumitomo Metal Industries, Ltd.Inventors: Takeo Kudo, Yasutaka Okada, Taishi Moroishi, Akio Ikeda, Hiroo Ohtani, Kunihiko Yoshikawa
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Patent number: 4400211Abstract: An alloy useful for manufacturing high strength deep well casing, tubing and drill pipes for use in oil-well operations is disclosed. The alloy exhibits improved resistance to stress corrosion cracking in the H.sub.2 S-CO.sub.2 -Cl.sup.- environment, which comprises the following alloy composition:______________________________________ C: .ltoreq.0.1% Si: .ltoreq.1.0% Mn: .ltoreq.2.0% P: .ltoreq.0.030% S: .ltoreq.0.005% N: 0-0.30% Ni: 30-60% Cr: 15-35% Mo: 0-12% W: 0-24% Cr(%) + 10Mo(%) + 5W(%) .gtoreq. 110% 7.5% .ltoreq. Mo(%) + 1/2W(%) .ltoreq. 12% Cu: 0-2.0% Co: 0-2.0% rare earths: 0-0.10% Y: 0-0.20% Mg: 0-0.10% Ca: 0-0.10% one or more of Nb, Ti, Ta, Zr and V in the total amount of 0.5-4.0%, if necessary Fe and incidental impurities: balance.Type: GrantFiled: June 1, 1982Date of Patent: August 23, 1983Assignee: Sumitomo Metal Industries, Ltd.Inventors: Takeo Kudo, Yasutaka Okada, Taishi Moroishi, Akio Ikeda, Hiroo Ohtani, Kunihiko Yoshikawa
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Patent number: 4400349Abstract: An alloy useful for manufacturing high strength oil-well casing, tubing and drill pipes for use in oil-well operations is disclosed. The alloy exhibits improved resistance to stress corrosion cracking in the H.sub.2 S--CO.sub.2 --Cl.sup.- environment, which comprises the following alloy composition:______________________________________ C: .ltoreq. 0.1% Si: .ltoreq. 1.0% Mn: 3-20% P: .ltoreq. 0.030% S: .ltoreq. 0.005% N: 0-0.30% sol. Al .ltoreq. 0.5% Ni: 20-60% Cr: 15-35% Mo: 0-12% W: 0-24% Cr(%) + 10 Mo(%) + 5 W(%) .gtoreq. 50% 1/2 Mn(%) + Ni(%) .gtoreq. 25% 1.5% .ltoreq. Mo(%) + 1/2 W(%) .ltoreq. 12% Cu: 0-2.0% Co: 0-2.0% Rare Earths: 0-0.10% Y: 0-0.20% Mg: 0-0.10% Ti: 0-0.5% Ca: 0-0.10% Fe and incidental impurities: balance.Type: GrantFiled: June 17, 1982Date of Patent: August 23, 1983Assignee: Sumitomo Metal Industries, Ltd.Inventors: Takeo Kudo, Yasutaka Okada, Taishi Moroishi, Akio Ikeda, Hiroo Ohtani, Kunihiko Yoshikawa
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Patent number: 4400210Abstract: An alloy useful for manufacturing high strength deep well casing, tubing and drill pipes for use in oil-well operations is disclosed. The alloy exhibits improved resistance to stress corrosion cracking in the H.sub.2 S--CO.sub.2 --Cl.sup.- -environment, which comprises the following alloy composition:______________________________________ C: .ltoreq.0.1% Si: .ltoreq.1.0% Mn: .ltoreq.2.0% P: .ltoreq.0.030% S: .ltoreq.0.005% N: 0-0.30% Ni: 25-60% Cr: 22.5-35% Mo: 0-7.5% (excl.) W: 0-15% (excl.) Cr (%) + 10Mo (%) + 5W (%) .gtoreq. 70% 3.5% .ltoreq. Mo (%) + 1/2W (%) < 7.5% Cu: 0-2.0% Co: 0-2.0% Rare earths: 0-0.10% Y: 0-0.20% Mg: 0-0.10% Ca: 0-0.10% ______________________________________one or more of Nb, Ti, Ta, Zr and V in the total amount of 0.5-4.0%, if necessary,Fe and incidental impurities: balance.Type: GrantFiled: June 1, 1982Date of Patent: August 23, 1983Assignee: Sumitomo Metal Industries, Ltd.Inventors: Takeo Kudo, Yasutaka Okada, Taishi Moroishi, Akio Ikeda, Hiroo Ohtani, Kunihiko Yoshikawa
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Patent number: 4370163Abstract: A hydrogen storage Ti-Fe alloy of the general formula, Ti.sub.1-x A.sub.x Fe.sub.y-z B.sub.z, in which A is Zr, Hf or a mixture thereof, B is a member selected from Cr, Cu, Co, Mo, V, Ni, Nb, Mn and a mixture thereof, and x, y and z are values of certain ranges, respectively. The alloy is predominantly comprised of an effective alloy phase of CsCl type body-centered cubic crystals. The alloy of the formula where z=O is within the scope of the invention. A process for making an alloy of this type is also disclosed.Type: GrantFiled: September 4, 1980Date of Patent: January 25, 1983Assignee: Matsushita Electric Industrial Company, LimitedInventors: Yoshio Moriwaki, Takaharu Gamou, Nobuyuki Yanagihara, Toshio Yamashita, Tsutomu Iwaki
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Patent number: 4363660Abstract: An iron-base alloy having high erosion resistance to molten zinc attack which essentially consists of (by weight):0.01 to 2% of carbon;0.01 to 2% of silicon;0.01 to 2% of manganese;totally 1 to 6% of at least one element selected from the group consisting of niobium and tantalum;totally 1 to 10% of at least one element selected from the group consisting of molybdenum and tungsten;10 to 30% of nickel;10 to 30% of cobalt;10 to 25% of chromium; anda balance which is iron and inevitable impurities.Type: GrantFiled: November 26, 1980Date of Patent: December 14, 1982Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Saburo Wakita, Akihiko Sakonooka