Copper Containing Patents (Class 420/89)
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Patent number: 6001194Abstract: A bias material for magnetic markers is produced by plastic working to provide a strip form, which has a metal structure consisting of the iron-base matrix and a non-magnetic copper group metal phase in an amount of not less than a solubility limit thereof in an equilibrium state at a room temperature. The non-magnetic copper group metal phase is dispersed in the matrix so as to form a microstructural rod pattern. The bias material comprises preferably 3 to 35% wt % of a copper group metal. The magnetic marker is produced by combining the bias material and a magnetostriction element.Type: GrantFiled: April 29, 1998Date of Patent: December 14, 1999Assignee: Hitachi Metals, Ltd.Inventors: Noriyuki Nakaoka, Tsutomu Inui, Akira Kawakami
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Patent number: 5961747Abstract: The invention relates to free-machining steels which do not rely on lead as a means of enhancing machinability. Instead, the steels of the invention employ concentrations of tin at ferrite grain boundaries to replicate a role of lead, which the inventors have discovered, in enhancing machinability. This role is to cause an embrittlement at the localized cutting zone temperatures by changing the fracture mode from transgranular to intergranular at those temperatures. The invention's use of concentrations of tin at the ferrite grain boundaries of the steel permits the machinability-enhancing effect to be obtained while employing bulk tin contents below the levels at which hot tearing becomes problematic. The invention improves over lead-bearing, free-machining steels in that the machinability-enhancing embrittlement produced by concentrating tin at the ferrite grain boundaries is both controllable and reversible.Type: GrantFiled: November 17, 1997Date of Patent: October 5, 1999Assignee: University of PittsburghInventors: Anthony J. DeArdo, C. Issac Garcia
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Patent number: 5951944Abstract: A lowly decarburizable spring steel comprises, on a weight basis, 0.51 to 0.70% of C, 0.15 to 2.50% of Si, 0.40 to 1.20% of Mn, 0.005 to 0.100% of Al, 0.005 to 0.050% of S, at least one of 0.05 to 0.30% of Ni and 0.05 to 1.00% of Cu and, optionally, at least one of 0.20 to 1.50% of Cr, 0.05 to 1.00% of Mo, 0.01 to 0.50% of V, 0.010 to 0.300% of Nb and 0.0005 to 0.0050% of B, and the balance consisting of Fe and unavoidable impurities. The spring steel can be remarkably lowered in decarburizability during hot working and heat treatment thereof without need of any decarburization-proofing agents and any specific heat treatment equipment. Accordingly, it has a very excellent effect in that the decarburization thereof can be remarkably decreased with a low cost when it is applied to a coil spring, a flat spring or a torsion bar.Type: GrantFiled: April 6, 1998Date of Patent: September 14, 1999Assignee: Mitsubishi Steel Mfg. Co., Ltd.Inventors: Hiroharu Motomura, Katsuyuki Uchibori
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Patent number: 5861565Abstract: A synchronizer ring performing synchronous sliding operation with and separating operation from a rotating object member, is composed of an Fe sintered alloy. The Fe sintered alloy comprises carbon of from 1.2 wt. % to 2.0 wt. %, copper of from over 15.0 wt. % to 25.0 wt. %, and the balance being iron and incidental impurities. A free Cu phase is precipitated in a matrix of the synchronizer ring. The synchronizer ring has a high scuffing resistance, an excellent friction characteristic, and sufficient abrasion resisting property and strength, and moreover, provides an easy manufacture thereof by means of a size working and is stable in quality.Type: GrantFiled: May 29, 1997Date of Patent: January 19, 1999Assignee: Nippon Piston Ring Co., Ltd.Inventors: Takao Omiya, Kunihiro Iguchi, Tetsuo Masuyama
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Patent number: 5858125Abstract: A magnetoresistive material of the present invention has a structure in which many clusters are surrounded by a crystal phase of Cu and/or Ag, where each cluster has a grain size of 20 nm or less and composed of an amorphous phase containing at least one ferromagnetic metal element T as a main component selected from Fe, Co and Ni, and at least one element M selected from Ti, Zr, Hf, V, Nb, Ta, Mo and W.Type: GrantFiled: October 15, 1996Date of Patent: January 12, 1999Assignee: Alps Electric Co., Ltd.Inventor: Naoya Hasegawa
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Patent number: 5443664Abstract: A surge current-suppressing circuit for an accelerator comprising a magnetic device inserted between a high-voltage DC power supply and an ion source for suppressing surge current generated when electric charge stored in a stray capacitance existing between the high-voltage DC power supply and the load is released at the time of short-circuiting of the load. The magnetic device comprises a magnetic core constituted by interlaminar-insulated thin ribbons of an iron-base amorphous or fine crystalline soft magnetic alloy. The iron-base fine crystalline soft magnetic alloy has the composition represented by the general formula:(Fe.sub.1-a M.sub.a).sub.100-x-y-z-.alpha. Cu.sub.x Si.sub.y.sub.B.sub.z M'.sub..alpha.wherein M is Co and/or Ni, M' is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, and a, x, y, z and .alpha. respectively satisfy 0.ltoreq.a.ltoreq.0.5, 0.1.ltoreq..times..ltoreq.3, 0.ltoreq.y.ltoreq.30, 0.ltoreq.z.ltoreq.25, 5.ltoreq.y+z.ltoreq.30 and 0.1.ltoreq..Type: GrantFiled: November 8, 1989Date of Patent: August 22, 1995Assignee: Hitachi Metals, Ltd.Inventors: Shin Nakajima, Noriyoshi Hirao, Kiyotaka Yamauchi, Osamu Shimoe
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Patent number: 5304258Abstract: A magnetic alloy film suitable for high density recording has a composition of (Fe.sub.x M.sub.y N.sub.z).sub.a L.sub.b, where L is Cu and/or Ag. The provision of Cu and/or Ag in a range from 0.5 to 5 atomic % enhances thermal stability of the soft magnet properties of the alloy.Type: GrantFiled: April 22, 1991Date of Patent: April 19, 1994Assignee: NEC CorporationInventors: Nobuyuki Ishiwata, Chizuko Wakabayashi
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Patent number: 5292383Abstract: A steel sheet for porcelain enameling having improved press formability and enameling properties comprises particular amounts of C, Mn, B, Cu, Al, O, N, and P or further Ti and Nb and the balance being Fe and inevitable impurities and is produced by hot rolling a slab of steel having a chemical composition as mentioned above as a starting material, cold rolling the resulting hot rolled sheet at a reduction of not less than 70%, and then subjecting the resulting cold rolled sheet to a continuous annealing at a heating temperature of not lower than 800.degree. C. but not higher than A.sub.c3 transformation point.Type: GrantFiled: December 17, 1991Date of Patent: March 8, 1994Assignee: Kawasaki Steel CorporationInventors: Kazunori Osawa, Susumu Satoh, Toshiyuki Kato, Hideo Abe, Keiji Nishimura
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Patent number: 5198040Abstract: In the production by the single-roll technique of a thin amorphous strip as the matrix for the manufacture of a thin Co-based amorphous alloy strip or a thin Fe-based microcrystalline alloy strip, the conditions for the production are controlled to those specified by the invention. The production conditions thus controlled concern the atmosphere and the pressure to be used for ejecting a molten metal onto a rotating cooling member, the shape of a nozzle, the distance between the nozzle and the rotary cooling member, the material for the rotary cooling member and peripheral speed of the rotary cooling member, etc. The individual numerical values of these conditions are severally important. The thin strip which has an extremely small thickness and few pinholes thus is obtained. In the thin Co-based amorphous alloy strip, the extreme decrease of thickness to below 4.8 .mu.m notably enhances the soft magnetic properties such as permeability and core loss in the high frequency range.Type: GrantFiled: December 11, 1991Date of Patent: March 30, 1993Assignee: Kabushiki Kaisha ToshibaInventors: Takao Sawa, Masaaki Yagi
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Patent number: 5192375Abstract: An Fe-based soft magnetic alloy essentially consisting of an Fe-based alloy including fine crystal grains used for such as a magnetic core. An average size of the fine crystal grains is controlled to 300.ANG. or less. Each of the fine crystal grains is composed of a body-centered cubic phase at least partially including a super lattice. This alloy has a high saturation flux density and excellent soft magnetic characteristics such as a low iron loss and a high magnetic permeability. This alloy is suitable as a core material for various kinds of choke coils.Type: GrantFiled: March 26, 1991Date of Patent: March 9, 1993Assignee: Kabushiki Kaisha ToshibaInventors: Takao Sawa, Masami Okamura, Yumiko Takahashi
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Patent number: 5180450Abstract: A high strength, low alloy, low to medium carbon structural steel is provided of the Fe/Cr/C type, said steel characterized by the presence of a small but effective amount of each of Cu and Ni sufficient to enhance the mechanical stability of retained austenite formed following quenching of said steel from its austentizing temperature. Preferably the steel also includes small but effective amounts a Al, Ti and Nb suficient to provide a fine grained microstructure.Type: GrantFiled: June 5, 1990Date of Patent: January 19, 1993Assignee: Ferrous Wheel Group Inc.Inventor: Banagaru V. N. Rao
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Patent number: 5178689Abstract: Fe-based soft magnetic alloy having excellent soft magnetic characteristics with high saturated magnetic flux density, characterized in that it has fine crystal grains dispersed in an amorphous phase and is expressed by the general formula:Fe.sub.100-a-b-c Cu.sub.a M.sub.b Y.sub.cwhere:"M" is at least one or more selected from elements of groups IVa, Va, VIa of the periodic table, Mn, Co, Ni, Al, and the Platinum group,"Y" is at least one or more selected from Si, B, P, or Cand 3<a.ltoreq.8 (atomic %)0.1<b.ltoreq.83.1.ltoreq.a+b.ltoreq.1215.ltoreq.c.ltoreq.28.Also described is a dust core made from an alloy powder having fine crystal grains dispersed in an amorphous phase and expressed by the formulaFe.sub.100-a-b-c-d-e Cu.sub.a M'.sub.b M".sub.c Si.sub.d B.sub.Type: GrantFiled: June 5, 1991Date of Patent: January 12, 1993Assignee: Kabushiki Kaisha ToshibaInventors: Masami Okamura, Takao Sawa
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Patent number: 5129966Abstract: A high strength, low alloy, low to medium carbon steel casting is provided of the Fe/Cr/C type containing by weight about 0.1 to 0.5% Si, said steel characterized by the presence of a small but effective amount of each of Cu and Ni sufficient to enhance the mechanical stability of retained austenite formed following quenching of said steel from its austenitizing temperature, the amount of Ni being at least sufficient to counteract the destabilizing effect of Si on austenite. Preferably the steel also includes small but effective amounts of Al, Ti and Nb sufficient to provide a fine grained microstructure.Type: GrantFiled: December 11, 1990Date of Patent: July 14, 1992Inventor: Bangaru V. N. Rao
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Patent number: 5069731Abstract: A low-frequency transformer including a magnetic core made of an alloy having the composition represented by the general formula:(Fe.sub.1-a M.sub.a).sub.100-x-y-z-.alpha. Cu.sub.x Si.sub.y B.sub.z M'.sub..alpha. (atomic %)wherein M is Co and/or Ni, M' is at least one element selected from the group consisting of Nb, W, Ta, Mo, Zr, Hf and Ti, and a, x, y, z and .alpha. respectively satisfy 0.ltoreq.a.ltoreq.0.3, 0.1.ltoreq.x.ltoreq.3, 0.ltoreq.y.ltoreq.17, 4.ltoreq.z.ltoreq.17, 10.ltoreq.y+z.ltoreq.28 and 0.1.ltoreq..alpha..ltoreq.5, at least 50% of the alloy structure being occupied by fine crystal grains having an average grain size of 1000 .ANG. or less when measured by their maximum diameters. The alloy may further contain at least one element selected from the group consisting of Ge, P, C, Ga, Al and N.Type: GrantFiled: March 23, 1989Date of Patent: December 3, 1991Assignee: Hitachi Metals, Ltd.Inventors: Yoshihito Yoshizawa, Kiyotaka Yamauchi
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Patent number: 5045279Abstract: A corrosion-resistant carbon sheet steel with good stamping characteristics is disclosed as relating to compositions for steel resistant to atmospheric corrosion, obtained from a basis composition containing elements such as C, Mn, P, S, Al, Si, and Cu, to which are added in various ways the elements Sb, V, Cr, and Ni which make possible obtaining properties such as high resistance to corrosion associated with the stamping characteristics.Type: GrantFiled: June 1, 1989Date of Patent: September 3, 1991Inventors: Jose A. de Queiroz Pinto, Jose G. de Souza, Takuzo Arai
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Magnetic steel plate for use as a magnetic shielding member and a method for the manufacture thereof
Patent number: 5019191Abstract: A magnetic steel plate for use as a magnetic shielding member and a method for the manufacture thereof are disclosed, and the steel composition consists essentially of, by weight %;C: not greater than 0.05%,Si: greater than 0.30%, but not greater than 1.50%,Mn: not greater than 0.50%, sol Al: less than 0.005%, with the balance being Fe and incidental impurities. The magnetic steel plate has a ferrite grain size of 0 (zero) or smaller.Type: GrantFiled: December 21, 1989Date of Patent: May 28, 1991Assignee: Sumitomo Metal Industries, Ltd.Inventors: Ryuji Ogata, Naokazu Nakano, Shuichi Suzuki -
Patent number: 5019190Abstract: An Fe-based soft magnetic alloy essentially consisting of an Fe-based alloy including fine crystal grains used for such as a magnetic core. An average size of the fine crystal grains is controlled to 300 .ANG. or less. Each of the fine crystal grains is composed of a body-centered cubic phase at least partially including a super lattice. This alloy has a high saturation flux density and excellent soft magnetic characteristics such as a low iron loss and a high magnetic permeability.Type: GrantFiled: December 20, 1989Date of Patent: May 28, 1991Assignee: Kabushiki Kaisha ToshibaInventors: Takao Sawa, Masami Okamura, Yumiko Takahashi
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Patent number: 4985088Abstract: Fe-based soft magnetic alloy having excellent soft magnetic characteristics with high saturated magnetic flux density, characterized in that it has fine crystal grains and is expressed by the general formula:(Fe.sub.1-a-b Cu.sub.a M.sub.b).sub.100-c Y.sub.cwhere "M" is at least one or more selected from rare earth elements, "Y" is at least one or more selected from Si, B, P, and C, and "a", "b" and "c" are as follows:0.005.ltoreq.a.ltoreq.0.050.005.ltoreq.b.ltoreq.0.115.ltoreq.c.ltoreq.28 (at %).Also described is a method of treating the alloy to segregate fine crystal grains which comprises heat treating the alloy for a period of from one minute to ten hours at a temperature of from 50.degree. C. below the crystallization temperature to 120.degree. C. above the crystallization temperature.Type: GrantFiled: May 17, 1989Date of Patent: January 15, 1991Assignee: Kabushiki Kaisha ToshibaInventors: Masami Okamura, Takao Sawa
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Patent number: 4985089Abstract: Fe-base soft magnetic alloy powder and dust core having the composition represented by the general formula:(Fe.sub.1-a M.sub.a).sub.100-x-y-z-.alpha.-.beta.-.gamma. Cu.sub.x Si.sub.y B.sub.z M'.sub..alpha. M".sub..beta. X.sub..gamma.wherein M is Co and/or Ni, M' is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, M" is at least one element selected from the group consisting of V, Cr, Mn, Al, elements in the platinum group, Sc, Y, rare earth elements, Au, Zn, Sn and Re, X is at least one element selected from the group consisting of C, Ge, P, Ga, Sb, In, Be and As, and a, x, y, z, .alpha., .beta. and .gamma. respectively satisfy 0.ltoreq.a.ltoreq.0.5, 0.1.ltoreq.x.ltoreq.3, 0.ltoreq.y.ltoreq.30, 0.ltoreq.z.ltoreq.25, 0.ltoreq.y+z.ltoreq.35, 0.1.ltoreq..alpha..ltoreq.30, 0.ltoreq..beta..ltoreq.10 and 0.ltoreq..gamma..ltoreq.10, at least 50% of the alloy structure being fine crystalline particles having an average particle size of 500 .ANG. or less.Type: GrantFiled: July 25, 1988Date of Patent: January 15, 1991Assignee: Hitachi Metals, Ltd.Inventors: Yoshihito Yoshizawa, Kiyotaka Yamauchi
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Patent number: 4881989Abstract: An Fe-base soft magnetic alloy having the composition represented by the general formula:(Fe.sub.1-a M.sub.a).sub.100-x-y-z-.alpha.-.beta.-.gamma. Cu.sub.x Si.sub.y B.sub.z M'.sub.60 M".sub..beta. X.sub..gamma.wherein M is Co and/or Ni, M' is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, M" is at least one element selected from the group consisting of V, Cr, Mn, Al, elements in the platinum group, Sc, Y, rare earth elements, Au, Zn, Sn and Re, X is at least one element selected from the group consisting of C, Ge, P, Ga, Sb, In, Be and As, and a, x, y, z, .alpha., .beta. and .gamma. respectively satisfy 0.ltoreq.a.ltoreq.0.5, 0.1.ltoreq.x.ltoreq.3, 0.ltoreq.y.ltoreq.30, 0.ltoreq.z.ltoreq.25, 5.ltoreq.y+z.ltoreq.30, 0.1.ltoreq..alpha..ltoreq.30, .beta..ltoreq.10 and .gamma..ltoreq.10, at least 50% of the alloy structure being fine crystalline particles having an average particle size of 1000 .ANG. or less.Type: GrantFiled: October 1, 1987Date of Patent: November 21, 1989Assignee: Hitachi Metals, Ltd.Inventors: Yoshihito Yoshizawa, Kiyotaka Yamauchi, Shigeru Oguma
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Patent number: 4863532Abstract: In a grain-oriented electromagnetic steel sheet which is produced by a process including a cold-rolling step(s), the final reduction ratio of the cold-rolling step(s) being high, a technical means for refining the secondary recrystallized grains is particularly important. One technical means is the incorporation of tin into silicon steel material. This, however, involves a problem because tin incorporated into silicon steel material deteriorates the surface coating which imparts tension to a grain-oriented electromagnetic steel sheet.The incorporation of copper into silicon steel material has been avoided since it causes secondary recrystallization to be unstable.The present invention is characterized by the combined incorporation of tin and copper into molten steel so as to simultaneously refine the secondary recrystallized grains and to form a good surface coating. The grain-oriented electromagnetic steel sheet of the present invention contains from 2.5% to less than 4.0% of silicon, from 0.03% to 0.Type: GrantFiled: April 8, 1988Date of Patent: September 5, 1989Assignee: Nippon Steel CorporationInventors: Katsuro Kuroki, Toshiya Wada, Shozaburo Nakashima
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Patent number: 4842657Abstract: Amorphous alloys containing zirconium as an amorphus forming metal and having the formula X.sub..alpha. Z.sub..gamma. wherein X is at least one of Fe, Co and Ni, .alpha. is 80 to 92 atomic %, Z is zirconium, .gamma. is 8 to 20 atomic % and the sum of .alpha. and .gamma. is 100 atomic %, cause very little variation of properties during aging and embrittlement because they contain no metalloid as the amorphous forming element, and they further have excellent strength, hardness, corrosion resistance and heat resistance and maintain superior magnetic properties which are characteristic of iron group elements.Type: GrantFiled: December 5, 1980Date of Patent: June 27, 1989Assignee: Shin-Gijutsu Kaihatsu JigyodanInventors: Tsuyoshi Masumoto, Kiyoyuki Esashi, Masateru Nose
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Patent number: 4637843Abstract: The present invention relates to the core of a noise filter.Conventionally, ferrite or iron powder is used as the core of a noise filter. Some patent publications disclose the core of a noise filter made of an amorphous magnetic alloy.An amorphous magnetic alloy which as a low pulse-noise resistance deterioration percentage is that on or within the curve X and Y of FIG. 3.Type: GrantFiled: May 3, 1985Date of Patent: January 20, 1987Assignee: TDK CorporationInventors: Suguru Takayama, Masao Shigeta
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Patent number: 4623387Abstract: Amorphous alloys containing zirconium as an amorphous forming metal and having teh formula X.sub..alpha. Z.sub..gamma. wherein X is at least one of Fe, Co and Ni, .alpha. is 80 to 92 atomic %, Z is zirconium, .gamma. is 8 to 20 atomic % and the sum of .alpha. and .gamma. is 100 atomic %, cause little variation of properties during aging and embrittlement because they contain no metalloid as the amorphous forming element, and they further have excellent strength, hardness, corrosion resistance and heat resistance and maintain superior magnetic properties which are characteristic of iron group elements.Type: GrantFiled: February 5, 1985Date of Patent: November 18, 1986Assignee: Shin-Gijutsu Kaihatsu JigyodanInventors: Tsuyoshi Masumoto, Kiyoyuki Esashi, Masateru Nose