With Liquid Present Patents (Class 422/140)
  • Publication number: 20090022632
    Abstract: The present invention relates to a device with a rotating fluidized bed in one or a succession of cylindrical chambers, in which injectors (12), distributed around the fixed circular wall (2) of said cylindrical chamber(s), inject along this wall, in successive layers, one or more fluids (13), which entrain the solid particles (17), passing through this/these chamber(s), in a movement of rapid rotation whereof the centrifugal force concentrates these particles along this wall, thereby forming a fluidized bed rotating around a central duct or a plurality of central ducts (3), through which the fluids are removed. The present invention further relates to a method of catalytic polymerization, drying or other treatments of solid particles in suspension in a rotating fluidized bed or of catalytic conversion of fluids passing through said rotating fluidized bed using a device according to the present invention.
    Type: Application
    Filed: December 15, 2005
    Publication date: January 22, 2009
    Inventor: Axel de Broqueville
  • Publication number: 20090004068
    Abstract: A fluidized bed reactor configured for reduced backflow of fluid is provided. The fluidized bed reactor comprises a vessel configured to contain a level of fluid, a feed conduit positioned to deliver feed into the vessel from an elevation above the level of fluid and a vacuum relief valve coupled to said feed conduit to introduce gas into the feed conduit.
    Type: Application
    Filed: June 27, 2007
    Publication date: January 1, 2009
    Inventor: Samuel Frisch
  • Patent number: 7470406
    Abstract: A method and apparatus for metering catalyst in a fluid catalytic cracking catalyst injection system are provided. In one embodiment, apparatus for metering catalyst in a fluid catalytic cracking catalyst injection system includes a low pressure storage vessel coupled to a pressure vessel that defines a high pressure side of the apparatus, where the determination of the amount of catalyst transferred is made on the low pressure side of the apparatus.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: December 30, 2008
    Assignee: Intercat Equipment, Inc.
    Inventor: Martin Evans
  • Patent number: 7449155
    Abstract: A catalytic hydrocracking reactor vessel includes enhanced components for the conversion of a hydrogen gas and fossil fuel feedstream to light liquid hydrocarbons. The reactor vessel comprises one or more of a reactor cup riser with a helical cyclonic separator conduit for separating a liquid and vapor product stream to provide an essentially vapor-free liquid recycle stream; a grid plate bubble cap with wall housing having serrated edges for producing small hydrogen bubbles of increased total surface area of bubbles at lower pressure drop; a feedstream inlet pipe sparger containing rows of downward directed slots for even distribution of the feedstream across the cross-sectional area of the reactor and providing free drain of solid particles from the sparger; and optionally a liquid recycle inlet distributor containing vertically curved plates for creating a whirling motion in the liquid recycle stream for better mixing with the feedstream with minimal solids settling.
    Type: Grant
    Filed: January 27, 2005
    Date of Patent: November 11, 2008
    Assignee: Hydrocarbon Technologies Innovation Group, Inc.
    Inventors: Thomas Kao, Robert Chang
  • Publication number: 20080269432
    Abstract: Device for injecting fluid in successive layers into a rotating fluidized bed and methods for catalytic polymerization, drying or other treatments of solid particles or for catalytic conversion of fluids, in which a succession of injectors (12), distributed around the fixed circular wall (2) of a circular reaction chamber, inject along this wall, in successive layers, one or more fluids (13), which entrain the solid particles (17), passing through this chamber, in a movement of rapid rotation whereof the centrifugal force concentrates these particles along this wall, thereby forming a fluidized bed rotating around a central duct (3), through which the fluids are removed.
    Type: Application
    Filed: September 15, 2006
    Publication date: October 30, 2008
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventor: Alex de Broqueville
  • Patent number: 7438863
    Abstract: The invention is a multi-catalyst injection system. In one embodiment, the system comprises a plurality of catalyst storage regions associated with a vessel and a metering device associated with the vessel. The metering device is configured to provide a metric indicative of an amount of catalyst dispensed from a selected one of the catalyst storage regions.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: October 21, 2008
    Assignee: Intercat Equipment, Inc.
    Inventor: Martin Evans
  • Publication number: 20080251420
    Abstract: A method and apparatus for catalytic hydroconversion processing of less volatile carbonaceous material to volatile liquid products is disclosed. The process is carried out in a plug-flow reactor system using nanosize metallic catalyst particles dispersed in the reactant slurry with compressed hydrogen/hydrogen-sulfide at a temperature between about 275° C. and 525° C. at a pressure of between about 800 psi and 6000 psi and a residence time in the reactors between about 1 minute and 4 hours.
    Type: Application
    Filed: April 11, 2008
    Publication date: October 16, 2008
    Inventors: Partha S. Ganguli, Alfred G. Comolli
  • Publication number: 20080213137
    Abstract: A system is provided for separating biomass from media in a fluidized bed reactor containing an aqueous suspension of biomass and media. A lift, configured to extend within the reactor, has an inlet for receiving aqueous suspension and an outlet spaced from the inlet for delivering the aqueous suspension from the lift. A shield is disposed about the lift. The system further includes a biomass separator body, including an inner member disposed about the shield and an outer member. Three annular passageways are defined between the lift, the shield, the inner member, and the outer member, and are positioned to receive aqueous suspension from each other. A barrier extends between the inner member and the outer member at an end portion of the third annular passageway. The barrier of the biomass separator body is configured to direct biomass from the third annular passageway toward an excess biomass discharge.
    Type: Application
    Filed: April 23, 2008
    Publication date: September 4, 2008
    Applicant: Shaw Intellectual Property Holdings, Inc.
    Inventors: Samuel Frisch, Robert E. Loudon
  • Patent number: 7413713
    Abstract: A reaction apparatus comprises a first supply flow channel having a fine flow channel cross sectional area for a liquid pressurized by a pressurizing device, a gas supply flow channel having a fine flow channel cross sectional area for supplying a gas, a two-phase flow channel having a fine flow channel cross sectional area in communication with a joined portion for the first supply flow channel and the second supply flow channel for flowing a gas/liquid two-phase fluid, a gas bubble reaction flow channel in communication with the exit of the gas/liquid two-phase channel and having a flow channel cross sectional area larger than that of the gas/liquid two-phase flow channel, and a liquid discharge flow channel for discharging the liquid in the gas bubble reaction flow channel. Therefore, in the reaction apparatus, a stable mixing ratio of a gas to a liquid can be obtained and the mixing speed of the gas to the liquid is increased.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: August 19, 2008
    Assignee: Hitachi, Ltd.
    Inventors: Tadashi Sano, Ryo Miyake, Akira Koide, Norihide Saho, Akiomi Kono, Takeshi Harada
  • Patent number: 7414166
    Abstract: This invention provides feed introduction devices, and processes for using same, which minimize catalyst clogging. In particular, the invention is to a feed introduction device having a first end in fluid communication with a feed source, a second end in fluid communication with a reactor and a deviation zone between the first end and the second end to deviate the flow of feed about a deviation angle from the first end toward the second end. According to the invention, the deviation angle is greater than 90 degrees.
    Type: Grant
    Filed: October 5, 2004
    Date of Patent: August 19, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: James H. Beech, Jr., Brian A. Cunningham, Christopher G. Smalley, Rathna P. Davuluri
  • Patent number: 7399898
    Abstract: Disclosed is a simulated moving bed (SMB) adsorptive separation system in which at least one component of a fluid mixture is brought into contact with a solid adsorbent and the adsorbed component is desorbed with a desorbent, wherein the improvement comprises an inert ball layer is formed on the upper part of the solid absorbent filled in the simulated moving bed.
    Type: Grant
    Filed: April 6, 2005
    Date of Patent: July 15, 2008
    Assignee: Samsung Petrochemicals Co., Ltd.
    Inventors: Jin Suk Lee, Nam Cheol Shin
  • Patent number: 7399450
    Abstract: A fluidized-bed reactor is disclosed. The fluidized-bed reactor steadies the gas flow through the fluidized bed chamber of the reactor. The swirl chamber of the reactor consists of a conical housing in which a conical insert is also situated. This creates an annular gap between the housing and the insert, which acts as the swirl chamber and which, according to the geometry of the two components, causes a velocity of the gas flow which remains the same along the height, which increases or which decreases. Such a reactor can also be called a constant annular-gap reactor.
    Type: Grant
    Filed: March 16, 2005
    Date of Patent: July 15, 2008
    Inventor: Sebastian Zimmer
  • Publication number: 20080146683
    Abstract: Method of operating a three-phase slurry reactor includes feeding at a low level at least one gaseous reactant into a vertically extending slurry body of solid particles suspended in a suspension liquid, the slurry body being contained in at least two vertically extending shafts housed within a common reactor shell, each shaft being divided into a plurality of vertically extending channels at least some of which are in slurry flow communication and the slurry body being present in at least some of the channels. The gaseous reactant is allowed to react as it passes upwardly through the slurry body present in at least some of the channels of the shafts, thereby to form a non-gaseous and/or a gaseous product. Gaseous product, if present, and/or unreacted gaseous reactant is allowed to disengage from the slurry body in a head space above the slurry body.
    Type: Application
    Filed: March 17, 2006
    Publication date: June 19, 2008
    Inventors: Andre Peter Steynberg, Berthold Berend Breman, Derk Willem Frederik Brilman
  • Patent number: 7381320
    Abstract: Disclosed is a process for the upgrading and demetallizing of heavy oils and bitumens. A crude heavy oil and/or bitumen feed is supplied to a solvent extraction process 104 wherein DAO and asphaltenes are separated. The DAO is supplied to an FCC unit 106 having a low conversion activity catalyst for the removal of metals contained therein. The demetallized distillate fraction is supplied to a hydrotreater 110 for upgrading and collected as a synthetic crude product stream. The asphaltene fraction can be supplied to a gasifier 108 for the recovery of power, steam and hydrogen, which can be supplied to the hydrotreater 110 or otherwise within the process or exported. An optional coker 234 can be used to convert excess asphaltenes and/or decant oil to naphtha, distillate and gas oil, which can be supplied to the hydrotreater 220.
    Type: Grant
    Filed: August 30, 2004
    Date of Patent: June 3, 2008
    Assignee: Kellogg Brown & Root LLC
    Inventors: Rashid Iqbal, Anshumali, Odette Eng, Phillip Niccum
  • Patent number: 7378016
    Abstract: A device is provided for increasing the pH of an acidic aqueous stream, which may result from commercial activity in petroleum, mining, metal finishing and food processing sectors, among others. A container defines an upright reactor portion with a cross-section that increases upwardly, along with inlet and outlet conduits connected to an inlet and an outlet between which the reactor portion is located. The conical portion contains a bed of substantially water-insoluble alkaline salt particulate, such as MgSO, the bed being such that, when the pH of the inflowing aqueous stream is below 7, contact between the particulate and the aqueous stream will raise the pH of the outflowing stream to a level above that of the inflowing stream.
    Type: Grant
    Filed: November 28, 2005
    Date of Patent: May 27, 2008
    Assignee: Green Turtle Americas Ltd.
    Inventor: Joseph Gordon Monteith
  • Publication number: 20080118407
    Abstract: A reactor configuration for fluidized bed reactors in which large exposed fixed surface area per unit reactor volume is required. The configuration uses a serpentine or hairpin bend arrangement of continuously connected and communicating thin channels, with the containing surfaces of these channels being vertical. This configuration enables uniform fluidization of particles throughout the cross-sectional area of the reactor and facilitates dispersal of membrane surfaces, heat transfer surface and baffles in gas-solid fluidized bed reactors.
    Type: Application
    Filed: November 16, 2007
    Publication date: May 22, 2008
    Applicant: MEMBRANE REACTOR TECHNOLOGIES LTD.
    Inventors: John R. Grace, Choon Jim Lim, Alaa-Eldin M. Adris, Heping Cui, David Anthony Boyd
  • Publication number: 20080114083
    Abstract: A method of operating a three-phase slurry reactor includes feeding at a low level at least one gaseous reactant into a vertically extending slurry body of solid particles suspended in a suspension liquid, the slurry body being contained in a plurality of vertically extending horizontally spaced slurry channels inside a common reactor shell, the slurry channels being defined between vertically extending horizontally spaced divider walls or plates and each slurry channel having a height, width and breadth such that the height and breadth are much larger than the width. The gaseous reactant is allowed to react as it passes upwardly through the slurry body present in the slurry channels, thereby to form non-gaseous and/or gaseous product. Gaseous product and/or unreacted gaseous reactant is allowed to disengage from the slurry body in a head space above the slurry body.
    Type: Application
    Filed: March 17, 2006
    Publication date: May 15, 2008
    Inventors: Andre Peter Steynberg, Berthold Berend Breman, Derk Willem Frederick Brilman
  • Patent number: 7368090
    Abstract: An distributor arrangement introduces spent FCC catalyst more uniformly across the dense bed of the regenerator to provide more even contact with regeneration gas in order to avoid hot spots and zones of incomplete combustion. The invention forms a fluidized hopper to collect spent catalyst and a horizontally extended header with multiple horizontally extended outlet arms to place catalyst into the regenerator. The invention may use an aeration means to fluidize the header to further assist catalyst flow. Furthermore, the spent catalyst delivered to the top of the regenerator dense reduces NOx emissions in the flue gas.
    Type: Grant
    Filed: August 25, 2004
    Date of Patent: May 6, 2008
    Assignee: UOP LLC
    Inventors: Daniel N. Myers, Mikhail Tretyak, Rusty M. Pittman, Steven Niewiedzial
  • Patent number: 7332131
    Abstract: A feed nozzle assembly located near the bottom of an FCC riser reactor includes a plurality of feed nozzles, each feed nozzle including a discharge end which is angled toward the center of the riser. The angled discharged ends provide a combined discharge of hydrocarbon feed and atomization gas into the central portion of the riser thereby providing a desirable feed/catalyst contact condition while preventing impingement of the feed upon the riser walls.
    Type: Grant
    Filed: March 15, 2004
    Date of Patent: February 19, 2008
    Assignee: Shell Oil Company
    Inventors: Ye-Mon Chen, Rene Samson
  • Patent number: 7303731
    Abstract: Solvent extraction is used to remove wax and contaminants from an iron-based Fischer-Tropsch catalyst in a natural circulation continuous-flow system. The wax-free catalyst is then subjected to controlled oxidation to convert the iron to its initial oxidized state, Fe2O3. Reactivation of the oxide catalyst precursor is carried out by addition of synthesis gas.
    Type: Grant
    Filed: December 7, 2004
    Date of Patent: December 4, 2007
    Assignee: Rentech, Inc.
    Inventors: Belma Demirel, Mark S. Bohn, Charles B. Benham, James E. Siebarth, Mark D. Ibsen
  • Patent number: 7172733
    Abstract: A device suitable for atomization and injection of a hydrocarbon batch into a reaction chamber comprises an admission and mixing chamber (5) for the liquid hydrocarbon batch introduced into the device by a tube (8) and for an atomization gas introduced into the device by a cylindrical casing (9) containing tube (8). Casing (9) is extended by a Venturi tube (6) which has a convergent part connected upstream to cylindrical casing (9) and a divergent part connected downstream to a hemispheric tip (7) that leads, by a rectangular slit with an opening angle (16) between about 100 and 115 degrees, to the reaction chamber. The device can be used in processes for catalytic cracking of heavy hydrocarbons.
    Type: Grant
    Filed: May 6, 2003
    Date of Patent: February 6, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Thierry Gauthier, Patrick Leroy, Abdelhakim Koudil, Ludovic Raynal
  • Patent number: 7153478
    Abstract: A downflow catalytic cracking reactor, comprising the following components: catalyst delivery pipe (1), reactor top cover (2), feed nozzle (3), reactor vessel (6), downflow reaction pipe (9), the upper end of the outer body is close connected to top cover (2) along the direction of circumference; the bottom of the outer wall body is close connected to the outer wall of the downflow reaction pipe; the upper section of the downflow reaction pipe is located inside the reaction vessel, while the lower section extends from the bottom of the outer body; feed nozzle (3) is located on the top cover (2) and/or side wall of the reactor vessel (6) with the outlet of the feed nozzle being above the inlet of the downflow reaction pipe; catalyst delivery pipe (1) is fixedly joined to the reactor vessel and in communication with catalyst lifting zone (7) formed by the reaction vessel and the downflow reaction pipe.
    Type: Grant
    Filed: April 24, 2003
    Date of Patent: December 26, 2006
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing Sinopec
    Inventors: Kejia Xu, Shuandi Hou, Jun Long, Xiaoxiang Zhong, Jiushun Zhang, Zhanzhu Zhang, Songnian Li, Xuefeng Wu, Jun He
  • Patent number: 7094380
    Abstract: Disclosed is an apparatus for injecting a plurality of uniform jets into an extended dispersion of moving catalyst particles within a reactor vessel. The apparatus comprises a plurality of outer conduits each for carrying contacting fluid and being fixed to a respective opening in a first tube sheet. A plurality of outlet nozzles are each fixed to a respective opening in a second tube sheet which is fixed to the first tube sheet. Feed in the outer conduits are delivered to the outlet nozzles for distribution into the vessel. All of the outlet nozzles can be easily replaced by breaking the fixation between the two tube sheets and securing a new second tube sheet with outlet nozzles to the first tube sheet.
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: August 22, 2006
    Assignee: UOP LLC
    Inventors: Paolo Palmas, Lawrence A. Lacijan, Adam S. Kasle
  • Patent number: 7087097
    Abstract: A pressure-supercharged fluidized-bed gasification chamber has a pressure-tight lock for supplying the feed materials which are to be gasified. The fluidized-bed gasification chamber is connected to a filter chamber via a connecting channel, with the result that the gas produced can flow over from the fluidized-bed gasification chamber into the filter chamber, where it is directed through the filter layer. An external heat source provides the necessary heat for the allothermic gasification. A heat-pipe arrangement directs the heat from the external heat source into the gasification bed of the fluidized-bed gasification chamber, in order to provide the temperature which is necessary for the gasification.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: August 8, 2006
    Assignee: Technische Universitat Munchen Lehrstuhl fur Thermische Kraftanlagen
    Inventor: Jurgen Karl
  • Patent number: 7060228
    Abstract: Device that is integrated in a chamber that allows a separation of a mixture that comprises at least one gaseous fraction and one liquid fraction, whereby said mixture is obtained from a zone for bringing into contact a liquid phase, a gaseous phase and solid particles.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: June 13, 2006
    Assignee: Institut Francais du Petrole
    Inventors: Nathalie Brunard, Thierry Gauthier, Jean-Paul Lepage
  • Patent number: 7029633
    Abstract: Uranium trioxide is reduced to uranium dioxide using microwave radiation or radiofrequency radiation directed in such a way that the radiation encounters an interface between uranium trioxide and the uranium-containing reduction product without first having passed through that product. By this method, and also using a reducing gas, it is possible to obtain UO2 with an O:U ratio less than 2.04:1.
    Type: Grant
    Filed: March 1, 2001
    Date of Patent: April 18, 2006
    Assignee: Cameco Corporation
    Inventor: Mikhail Simonovich Ioffe
  • Patent number: 7025938
    Abstract: The partially condensed fluid recycle stream of a fluidized bed polyolefin reactor operating in the condensing mode is split into two portions by a stream splitter. In a preferred mode, the smaller stream from the splitter contains a higher ratio of liquid to gas than the larger stream. One portion of the split stream is injected below the fluidized bed and the other, preferably with enhanced liquid content, is injected into the fluidized bed at a level above the product withdrawal level. Regulation of liquid injection above the product withdrawal level, as a function of liquid in the product discharge tanks, reduces the liquid in the product discharge system, resulting in improved discharge cycle times and more efficient conservation of monomer and other materials which might otherwise be lost in the discharge process.
    Type: Grant
    Filed: October 12, 2004
    Date of Patent: April 11, 2006
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Robert Darrell Olson, Timothy Joseph Howley
  • Patent number: 7011740
    Abstract: A method and system for recovering fines from a light FCC-type effluent gas. Cracked gases from the reactor are cooled by direct contact with circulating oil in an oil quench tower. The circulating oil also washes out the catalyst fines carried with the reactor effluent gas. A flow of the oil from the quench tower bottoms is sent through one of a pair of filters to remove fines and recycled to the tower. The other filter is in backwash operation using a compressed gas to remove the fines therefrom and into a surge drum. Fuel oil or quench oil is added to the drum to form a slurry, which carries the catalyst fines to the regenerator where the oil is combusted to supply the FCC system heat requirements. Since a minimum amount of fuel oil is generated in the FCC, fuel oil is imported to inventory the quench tower.
    Type: Grant
    Filed: October 10, 2002
    Date of Patent: March 14, 2006
    Assignee: Kellogg Brown & Root, Inc.
    Inventors: Michael Tallman, Robert B. Peterson, Maureen F. Gilbert
  • Patent number: 7008460
    Abstract: Process for the production of thermally converted light products from residual feedstock and electricity from syngas obtained from thermal conversion residue as feedstock, in which process flue gas exiting from the electricity producing unit is fed through a heat recovery unit providing at least part of the heat required in the thermal conversion process.
    Type: Grant
    Filed: January 9, 2002
    Date of Patent: March 7, 2006
    Assignee: Shell Oil Company
    Inventors: Jacobus Henricus Gerardus Beurskens, Johannes Didericus De Graaf, Anthony Malcolm Rigby
  • Patent number: 6994833
    Abstract: In a shell-and-tube type reactor, the leakage between the upper and lower chambers is substantially decreased by tightly fitting the reaction tubes to the shield. The present invention provides a reactor for use in catalytic gas phase oxidation characterized by expanding reaction tubes to at least one groove formed in the reaction tube-fixing part of an intermediate tube sheet to form a shield, thereby forming plural of chambers with the intermediate tube sheet, and forming an expansion joint around the periphery of each of the chambers.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: February 7, 2006
    Assignee: Nippon Shokubai Co., LTD.
    Inventors: Takeshi Nishimura, Masakatsu Mori, Masatsugu Kitaura, Osamu Dodo, Michio Tanimoto
  • Patent number: 6949231
    Abstract: A PCB decomposition reactor includes: an injector for injecting a mixture of water and sodium hydroxide connected to the lower part of the reaction vessel; an outlet pipe for withdrawing treated fluid connected to the sidewall of the reaction vessel and a cyclone for separating sodium carbonate from the treated fluid; a discharge pipe connected to the top of the cyclone to discharge treated fluid from which precipitated sodium carbonate has been removed; a downcomer for the separated fluid connected to the bottom of the cyclone so that precipitated sodium carbonate and fluid containing it are discharged therethrough and to an injector which is connected to a feed pipe for feeding a mixture of PCB and mineral oil; and a gas supply nozzle for injecting a gas into the reaction vessel installed at the bottom of the reaction vessel.
    Type: Grant
    Filed: October 10, 2001
    Date of Patent: September 27, 2005
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Yasuhiro Yamauchi, Kan Ogata, Takashi Moribe, Masakazu Tateishi, Tadatsugu Fukuzumi, Mitsuji Iwao, Nobuyuki Ikeda, Naoki Shindo, Nobuhiro Hokao
  • Patent number: 6946105
    Abstract: A process for the recovery of metal oxides from a solution containing metallic salts by spray roasting of these solutions. The process is particularly suitable for spray roasting spent pickling acids. The process feeds the solution to a reactor for spray roasting of the droplets in at least two stages, where at least one evaporation stage follows at least one conversion stage to convert the metal salts to metal oxides. The device for implementing the process includes a spray roasting reactor having a first heating zone to evaporate the water and a second heating zone to convert the metal salts to oxides.
    Type: Grant
    Filed: April 23, 2002
    Date of Patent: September 20, 2005
    Assignee: Andritz AG
    Inventor: Albert Lebl
  • Patent number: 6936227
    Abstract: A feed-dispersion system for hydrocarbon feeds of fluid catalytic cracking units is described, which comprises: a feed-injection system made up of two concentric conduits, where the atomization fluid flows through the inner conduit, while the liquid feed flows through the annular space formed by the outer surface of the inner conduit and the inner surface of the outer conduit; an atomization unit having nozzles arranged in rows, with one row having central nozzles connected to the inner conduit for atomization fluid, and two or more rows of side nozzles, connected to the outer feed conduit, the central nozzles and side nozzles of the atomization unit being geometrically placed so that the energy of the atomization fluid is fully transferred by contact to the flow of feed, this resulting in the complete atomization of the feed; a mixing chamber formed by the edges of the central nozzles, the dimensions of which are able to prevent the coalescence of the formed oil droplets.
    Type: Grant
    Filed: October 24, 2000
    Date of Patent: August 30, 2005
    Assignee: Petroleo Brasileiro S.A.-Petrobras
    Inventors: Edson José Joaquim De Souza, Aurélio Medina Dubois, Cláudio Damiance Baptista, José Geraldo Furtado Ramos, José Loreto Moreira De Faria, Moacir José Bampi
  • Patent number: 6902711
    Abstract: An apparatus for treating wastes includes a fluidized bed reactor for partially combusting the wastes at a relatively low temperature, and a separate relatively high temperature reactor for separate gasification of gaseous material and char from the first gasification. This synthesis gas thus formed is cooled, subjected to a conversion operation in a converter to produce hydrogen.
    Type: Grant
    Filed: March 21, 2000
    Date of Patent: June 7, 2005
    Assignees: Ebara Corporation, Ube Industries, Ltd.
    Inventors: Hiroyuki Fujimura, Yoshio Hirayama, Shosaku Fujinami, Shuichi Nagato, Tetsuhisa Hirose, Takahiro Oshita, Masaaki Irie, Kazuo Takano, Toshio Fukuda
  • Patent number: 6902707
    Abstract: A process and apparatus for atomizing a fluid is disclosed herein. The fluid is mixed with an atomizing fluid in a plurality of locations and passed through a nozzle.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: June 7, 2005
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: William R Adamson, George A. Swan, III, Michael W. Bedell
  • Patent number: 6891073
    Abstract: A method for producing bisphenol includes introducing a phenol and a ketone into a fixed, supported catalytic bed reactor system in a downflow mode, reacting the phenol and the ketone to form a reaction mixture, and recovering the bisphenol isomer from the reaction mixture. The preferred bisphenol isomer is bisphenol A, or p,p?-bisphenol A, produced from the reaction of phenol and acetone. The reactor for producing the bisphenol A from the reaction of phenol and acetone includes an ion exchange resin catalyst disposed in a bed and packing randomly distributed throughout the ion exchange resin catalyst to improve heat transfer efficiency and reduce compression of the catalyst bed.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: May 10, 2005
    Assignee: General Electric Company
    Inventors: Gaylord Michael Kissinger, Allen Wai-Yee Ko, Michael D. Szillat, Brian T. Carvill
  • Patent number: 6863905
    Abstract: A mixed bed of iodine source/iodine capture resin provides high flow rates that are useful for treatment of water. The ratio of source/capture resin can be adjusted to meet the goals of the system. If insufficient iodine is being provided, the source resin amount can be increased relative to the capture resin. If excess iodine or iodide are found in the treated water, the capture resin amount can be increased relative to the source resin. The release of iodine from the source resin and its effectiveness can be significantly enhanced by using a mixed bed system in which one or both of the source and the capture ion exchange resins have had their exchange sites saturated with the anion of an organic acid such as citrate and/or isocitrate. This significantly increases the amount of iodine released into aqueous solution and enhances the disinfecting power of that iodine.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: March 8, 2005
    Assignee: Shanbrom Technologies, LLC
    Inventor: Edward Shanbrom
  • Publication number: 20040258580
    Abstract: A riser reactor system for conversion of hydrocarbon feedstock to ethylene and propylene is described. The riser reactor system prevents riser reactors with a plurality of inlet ports for feeding gases having different compositions and for controlling the residence time of a gas catalyst within the riser reactor.
    Type: Application
    Filed: June 15, 2004
    Publication date: December 23, 2004
    Inventors: Hayim Abrevaya, Joel T. Walenga, Michael A. Schultz, Anil R. Oroskar
  • Publication number: 20040258579
    Abstract: A facility for chemical conversion of a feed comprises a reactor (2) containing a slurry constituted by at least one suspension of at least one solid in a liquid, a gas supply, a circuit that is external of the reactor, for continuous movement of a slurry stream, said slurry being withdrawn from at least one point (A) and at least a portion of which is re-introduced into at least one other point (B), a section for separating at least one fluid from the slurry traversing said external circuit, said facility further comprising:
    Type: Application
    Filed: August 4, 2004
    Publication date: December 23, 2004
    Inventors: Jean-Marc Schweitzer, Eric Lenglet, Franck Gaviot-Blanc
  • Patent number: 6833078
    Abstract: Methods and apparatus for separating liquid products and catalyst fines from a slurry used in a Fischer-Tropsch reactor. A settling system continuously or intermittently removes catalyst fines from the slurry and is coupled with catalyst-liquid separation system that separates liquid products from the slurry. The preferred separation system produces a sub-particle rich stream and a catalyst-lean stream that are removed from the system. The systems of the present invention act to reduce the concentration of catalyst fines in the reactor, thereby increasing the effectiveness of a catalyst-liquid separation system.
    Type: Grant
    Filed: September 13, 2002
    Date of Patent: December 21, 2004
    Assignee: ConocoPhillips Company
    Inventors: Rafael L. Espinoza, Sergio R. Mohedas, Seyi Odueyungbo, James Dale Ortego
  • Patent number: 6827908
    Abstract: In a fluid catalytic cracking (FCC) unit, a regenerator, a stripper or a withdrawal well connecting to either of the vessels, includes a standpipe for circulating catalyst from one vessel to another, the standpipe having an inlet design which reduces gas entrainment during catalyst transport by partial de-fluidization in the standpipe inlet region. The standpipe inlet design could include multiple inlet openings through the top of the standpipe or from the side wall by slots, or both, and a horizontal disk surrounding the standpipe below the slots for blocking the upward flow of bubbles, the combination thereby forming a dense fluidization zone above the disk and surrounding the inlet, including the slots. Additionally, the disk may include a downwardly-projecting lip or edge forming an inverted void space around the standpipe and the downwardly-projecting edge may further include vent holes around its circumference which allow bubbles trapped under the disk to be vented outside the standpipe inlet region.
    Type: Grant
    Filed: July 12, 2000
    Date of Patent: December 7, 2004
    Assignee: Shell Oil Company
    Inventor: Ye-Mon Chen
  • Patent number: 6814943
    Abstract: A method and apparatus for alkylating an alkylation substrate with an alkylating agent in the presence of solid catalyst particles in a transport reactor is disclosed. Solid catalyst particles in the transport reactor effluent recirculate to the inlet of the transport reactor through one or more conduits. The rate through each conduit is regulated by fluid-controlled valves that use the alkylation substrate as the regulating fluid. This method and apparatus help ensure uniform or symmetric flow of catalyst from the effluent of the transport reactor to the bottom of the transport reactor. This method and apparatus also help ensure uniform or symmetric flow of alkylation substrate to the bottom of the transport reactor with minimal bypassing by the alkylating agent around of the transport reactor. This invention finds use in the production of motor fuels by the alkylation of liquid hydrocarbons in the presence of solid catalyst particles.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: November 9, 2004
    Assignee: UOP LLC
    Inventors: William H. Radcliffe, Wesley L. Kiel, Christopher D. Gosling, Paul A. Sechrist, Paul Anderson
  • Patent number: 6773680
    Abstract: Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: August 10, 2004
    Assignee: Mitsubishi Jukogyo Kabushiki Kaisha
    Inventors: Taku Shimizu, Kazuaki Kimura, Kiyoshi Okazoe, Atsushi Tatani, Naohiko Ukawa, Masao Hino, Susumu Okino, Takashi Haruki, Toru Takashina, Eiji Ochi
  • Publication number: 20040143939
    Abstract: In order to produce granules granulometrically polidispersed in a very little range, a fluid bed granulation process of the type comprising the steps of preparing a fluid bed of seeds (S1) of the substance to be granulated, having a free surface (P) substantially horizontal; and feeding a continuos flow (L) of a fluid comprising a growth liquid, provides in the fluid bed for a continuous vortex (V) with a substantially horizontal axis, in which an upper zone (Z1) of seeds wetting and evaporation of possible solvent contained in the flow (L) and a lower zone (Z2) of solidification/consolidation of the growth liquid are identified.
    Type: Application
    Filed: February 24, 2004
    Publication date: July 29, 2004
    Inventor: Gianfranco Bedetti
  • Patent number: 6740227
    Abstract: A baffle-style stripper for an FCC process having a complete or nearly complete coverage of stripping openings over the sloped surface of the baffle will provide improved stripping efficiency and catalyst flux through the stripper. The complete distribution of relatively small openings over the entire surface of a sloped baffle has been found to interrupt relatively dense streamers of catalyst that were previously not known to exist and which short-circuited the contact of the stripping fluid with the catalyst. Spreading out the stripping gas across the sloped area of the baffle to a much greater extent than has been practiced in the past has now been found to promote active contacting of the catalyst with the stripping fluid over the entire volume of the stripper between the baffles.
    Type: Grant
    Filed: December 21, 2000
    Date of Patent: May 25, 2004
    Assignee: UOP LLC
    Inventor: Brian W. Hedrick
  • Patent number: 6723885
    Abstract: A process for the production of 2,2-bis(4-hydroxyphenyl)propane (BPA) is disclosed. The process that entails reacting acetone with phenol in the presence of cross-linked sulfonated polystyrene resins is characterised in that BPA is separated from the reaction solution downstream of the reaction unit by means of a multi-stage vacuum distillation and a subsequent single- or multi-stage layer crystallisation. The by-product stream with accumulated by-products is returned downstream of the reaction unit.
    Type: Grant
    Filed: August 26, 2002
    Date of Patent: April 20, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Frieder Heydenreich, Michael Prein, Michael Bödiger, Rainer Neumann, Gerhard Fennhoff, Johan Vaes
  • Patent number: 6719897
    Abstract: Treatment apparatus comprising a treatment chamber (10), for receiving a process fluid, in which there are provided means for introducing gas (19, 20) at a low level within the chamber to create bubbles which drive the process fluid to circulate within the chamber as they rise, in which there are provided means associated with the gas inlet openings for collecting solid particles entrained with the process fluid which sink as a consequence of contact with the bubbles.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: April 13, 2004
    Inventor: Christopher Maltin
  • Publication number: 20040062689
    Abstract: Device for atomization and injection of a hydrocarbon batch into a reaction chamber comprising an admission and mixing chamber (5) for the liquid hydrocarbon batch introduced into the device by a tube (8) and for an atomization gas introduced into the device by a cylindrical casing (9) containing tube (8), said casing (9) being extended by a Venturi tube (6) consisting of a convergent part connected upstream to cylindrical casing (9) and a divergent part connected downstream to a hemispheric tip (7) that leads, by a rectangular slit with an opening angle (16) between about 100 and 115 degrees, to the reaction chamber. Application of this device to catalytic cracking of heavy hydrocarbons.
    Type: Application
    Filed: May 6, 2003
    Publication date: April 1, 2004
    Inventors: Thierry Gauthier, Patrick Leroy, Abdelhakim Koudil, Ludovic Raynal
  • Patent number: 6685886
    Abstract: A fluid bed processing system for particles with an agitation system includes a product chamber with an interior and a plurality of elongated structures. The elongated structures extend at least partially across the interior of the product chamber and are positioned in the product chamber where the particles are located. The fluid bed processing system also includes a system for engaging the elongated structures to agitate the particles in the product chamber.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: February 3, 2004
    Assignee: Genencor International, Inc.
    Inventors: Bruce A. Bisgrove, Ryszard Braun, Robert C. Fewkes
  • Publication number: 20040013578
    Abstract: A liquid to be treated is guided through an adsorption medium reactor (1), especially a fluidised bed reactor. The flux starts from the bottom (3) of the reactor (1) along the longitudinal axis of the reactor (1). There are provided one or more outlets (18) for the liquid to be treated inside the reactor (1) at a distance from, but near to, the bottom (3) of said reactor (1) directed mainly towards said bottom (3) of said reactor (1).
    Type: Application
    Filed: August 8, 2003
    Publication date: January 22, 2004
    Inventor: Ludwig Weibel