Abstract: Disclosed is an apparatus for production of vapor-phase growth carbon fibers. The apparatus can continuously produce these carbon fibers for a long time without blocking a furnace of tubular reactor of the apparatus. Also disclosed is a process for production of carbon fibers by means of the apparatus, a device for preventing deposition of carbon fibers on an inside of a furnace of tubular reactor, and vapor-phase growth carbon fibers produced in the apparatus. The vapor-phase growth carbon fibers include carbon nanofibers and/or carbon nanotubes. The apparatus includes a furnace of tubular reactor, at an end of which a feedstock-supplying nozzle is provided, and a discharge pipe inserted in the furnace of tubular reactor, the top end of which faces the opening of the nozzle and the bottom end discharges the carbon fibers.

Abstract: A device for accessing biological fluid, sampling biological fluid constituents and determining the concentration of at least one target constituent within the accessed biological fluid is provided. The device has at least one micro-piercing member used to penetrate the skin to a selected depth and to access biological fluid, a constituent sampling means and a constituent measuring means. The constituent sampling means comprises a constituent transfer medium, such as a hydrophilic gel material, by which sampled constituents are transferred from the micro-piercing member to the measuring means. The measuring means includes an electrochemical cell having at least one porous electrode through which at least one sampled constituent is caused to enter into the electrochemical cell. Methods of sampling constituents within the skin and measuring the sampled constituents, as well as kits for practicing the invention are provided.

Abstract: The present invention is directed to inventive carbon blacks comprising the average nitrogen surface area of a conventional N500 series carbon black and at least one performance property, in a polymeric composition, equal to or better than an identical performance property of a conventional N300 series carbon black in the same polymeric composition. Additionally, the present invention is further directed to various methods and apparatuses for the manufacture of the inventive carbon blacks described herein.

Abstract: Produce a dispersion of ultra-fine titanium particles that offers a hair-repairing effect, by burning a mixture gas of oxygen and hydrogen in high-pressure water, using the combustion gas to melt titanium metal, and causing the molten titanium to collide with high-pressure water and letting the produced ultra-fine titanium particles disperse in water.

Abstract: A reactor for producing carbon black comprising, in the following order from upstream to downstream, a) a combination combustion/reaction section, wherein the combustion/reaction section comprises at least one inlet for introducing a combustion feed and at least one inlet for introducing a carbonaceous feedstock, b) a choke section, wherein the choke section comprises at least one inlet for introducing a carbonaceous feedstock and wherein the choke section converges to a downstream end, c) a quench section, wherein the cross section of the quench section is equal to or larger than the downstream end of the choke section and smaller than the cross section of the combustion/reaction section, and d) a breeching section. Also disclosed is a method for producing carbon black. Further disclosed is a simplified carbon black plant for producing tread and/or carcass type carbon black.

Abstract: Heat treatment is performed on preforms placed in an enclosure accompanied by sweeping with an inert gas under reduced pressure, and with a gaseous effluent being exhausted continuously via a first effluent outlet connected to an effluent exhaust circuit. At the end of the heat treatment, the first gaseous effluent outlet is closed so as to isolate the effluent exhaust circuit from the enclosure, sweeping of the enclosure with the inert gas is interrupted, and the heat-treated preforms are left in the enclosure and are subjected to densification by admitting a reagent gas into the enclosure via at least one reagent gas admission duct opening out into the enclosure, with gaseous effluent being exhausted via a second effluent outlet separate from the first, said second outlet being closed during the heat treatment step. Advantageously, metal, in particular sodium, contained in the gaseous effluent exhausted from the enclosure during the heat treatment step is neutralized.

Abstract: An apparatus and method for producing the nano-sized lithium-cobalt oxide using flame-spraying pyrolysis is provided. The method of producing a nano-sized lithium-cobalt oxide comprising the steps of: spraying minute droplets formed at normal temperature from a solution dissolved with a certain ratio of lithium salt and cobalt salt; atomizing the minute droplets through rapid expansion by spraying into a high temperature environment generated by the combustion of oxygen and hydrogen; decomposing the atomized minute droplets thermally at high temperature. An apparatus for producing a nano-sized lithium-cobalt oxide by utilizing a flame spraying pyrolysis comprises a minute droplet generating section (100), a combusting section (200) and a particle collecting section (300). The produced nano-sized lithium-cobalt oxide can be applied to a highly efficient lithium battery.

Abstract: Squalane, which contains fullerene useful for a complex material with high functionality including effects on improving health, is provided. Squalane in which fullerene as ultrafine particles of carbon combusting residue are floating is produced by combusting mixed gas of oxygen and hydrogen in squalane in a vacuum and heating and combusting carbon with the combustion gas obtained.

Abstract: A process for producing carbon black comprising reacting a reaction stream formed by a prior carbon black forming process with an oxidant and a carbon black yielding feedstock to produce carbon black and cooling, separating and recovering the carbon black. The process advantageously reduces the amount of fuel needed to produce carbon black. Also disclosed is an apparatus for practicing the process.

Abstract: A gasifier is disclosed combining a fixed bed gasification section where coarse fuel is gasified and an entrained flow gasification section where fine fuel is gasified. The fixed bed section includes upper and lower sections. Coarse fuel is devolatilized in the upper fixed bed section and subjected to elevated temperatures sufficient to crack and destroy tars and oils in the effluent gases. The entrained flow gasification section is disposed in a lower plenum adjacent the lower fixed bed section. A plurality of injection ports are configured to introduce oxygen, steam, or air into different sections of the gasifier to control temperature and operating conditions. Activated carbon may be formed in the upper fixed bed section and in the entrained flow section. The activated carbon may be used as a sorbent to remove pollutants from the effluent gases. The gasifier may be used with various coarse and fine fuel feedstocks.

Abstract: Components of a chemical processing system are disclosed. In particular, a chemical processing system is disclosed which includes a chemical mixing or reacting zone, an inlet to the zone, an outlet to the zone, and a vacuum or fluid flow source located downstream of the outlet. The chemical processing system further includes a device to control the amount of vacuum or fluid flow through the zone. Also disclosed is a continuous feeder system having a first loss-in-weight and a second loss-in-weight feeder and a device for measuring a lower limit of feed in each feeder. There is also a device to activate the second feeder when the lower limit is obtained in the first feeder and a device to deactivate the first feeder when the lower limit is detected in the first feeder. A sample port assembly is also disclosed for obtaining a sample of material flowing through a processing system.

Abstract: A CO2 fixation system for fixing Co2 gas existing in the atmosphere or in an exhaust gas emitted from factories and other burning sites. The system includes a fermenting tank for anaerobically fermenting organic wastes, whereby methane gas is produced. The methane gas is decomposed and hydrogen gas is produced. The hydrogen gas is reacted with the CO2 gas to produce carbon powder and water, whereby the CO2 gas is fixed to become harmless to the global warming.

Abstract: An anaerobic fermentation part generates gas containing methane and carbon dioxide by anaerobically fermenting biomass. The gas is passed to a methane.carbon dioxide separation part to be separated into methane and carbon dioxide, and part of the separated methane is fed to a methane reforming part to be decomposed into carbon and hydrogen under the presence of a catalyst. The carbon dioxide separated in the methane.carbon dioxide separation part and the hydrogen formed in the methane reforming part are fed to a carbon dioxide fixing part, which in turn reacts the carbon dioxide with the hydrogen under the presence of a catalyst for continuously forming carbon and hydrogen and fixing the carbon dioxide.

Abstract: A non-polluting liquid-phase process and a supporting system of apparatus for producing titanium dioxide from titanium ore or slag provide a more economical sulfate process for preparing anatase. The ore or slag is reacted with hot sulfuric acid. The reaction product is filtered and washed before being combined with acid water, in which the solids are partially dissolved. The resulting suspension is filtered, and the filtrate hydrolyzed to convert titanium values therein to titanium dioxide hydrate, which is calcined to produce anatase pigment.

Abstract: An improved waste rubber processing system which pyrolyzes waste rubber to produce pyrolysis oil and carbon black and then purifies and refines these end products to broaden their commercial applications and to increase their market value. The pyrolysis oil purification system of this invention produces a high quality oil which is clear and colorless and which is marketable as a plasticizer or extender oil for rubber and plastic compounding applications. The carbon black purification system mills the carbon black to a fine grade and removes oversized contaminants such as fiberglass and ferrous particles to produce a low structure furnace black. The plasticizer/extender oil is many times more valuable than the end product of conventional pyrolysis systems which is a low quality fuel oil. Similarly, the low structure furnace black is of much greater value than the low grade carbon black produced by conventional pyrolysis systems.

Abstract: A discharge system for a destructive distillation apparatus wherein the discharge solids act as plug to avoid the unwanted flow of product gas or ambient air therethrough while effectively discharging finely divided, disperse solids material from a continuously operating distillation apparatus. The use of a positive displacement two-stage auger having close clearance between the auger and auger cylinder wall, combined with an open section within the auger cylinder where a sealing material plug forms, results in improved sealing of the inventive system from unwanted transfer of gases. The hot, disperse, and finely divided solids exiting a distillation apparatus, such as carbon black formed from the distillation of automobile tire chips, is effective in the formation of a seal plug.

Abstract: Carbon black is produced by burning a mixture of air and oil to produce hot gases and then conducting the hot gases through tubes extending through a chamber of a heat exchanger. Heat exchange air is conducted through the chamber in a direction opposite the direction of gas flow, in heat-exchange relationship with the tubes, to pre-heat the air. The pre-heated air is then mixed with the oil to be burned. Prior to entering the chamber, the air is conducted within a hollow section of the wall structure of the heat exchanger to transfer heat from a hot end of the wall structure toward a cooler end thereof.

Abstract: Apparatus and method are disclosed for producing oxides of metals and of metal alloys. The metal or alloy is placed in an oxygen atmosphere in a combustion chamber and ignited. Products of the combustion include one or more oxides of the metal or alloy in powdered form. In one embodiment of the invention a feeder is provided whereby material to be oxidized by combustion can be advanced into a combustion chamber continuously. A product remover receives the powder product of the combustion.

Abstract: A combination liquid seal and spiral auger conveyor feeding system which provides both a liquid seal, effective under normal operating conditions, with a sealed spiral auger conveyor, which is effective to seal against the surge flow of distillation gases back through the feeding system. This is attained while providing for a reliable, continuous flow of solid bulk material such as rubber tire chips to a reactor or distillation unit. A bulk feeding system having a partially submerged inclined spiral auger conveyor is provided, communicating at its base with a liquid reservoir so as to form a liquid seal within the combined apparatus. Solid bulk material is introduced to the upper end of the liquid reservoir above the liquid level where it descends by the action of gravity into the liquid and sinks to the bottom of the reservoir to by picked up by the partially submerged rotating auger conveyor and elevated thereby.

Abstract: The production of fibers is carried out by allowing a gas mixture containing a gaseous hydrocarbon or an appropriate gas to pass through a substrate (generally a steel sheet) arranged facing the direction of the gas stream and situated in a furnace wherein the gas reaches a temperature of 1.000.degree. C. approximately. The schematized device is comprised of the corresponding gas reservoirs, that is to say the hydrocarbon gas and the carrying and activating gas, a mixing and preheating chamber, the furnace at the outlet of which are collected or burnt the inflammable gases and the grid from the surface of which, duly activated, the carbon fibers may grow. The gist of the invention is that the gas goes through the substrate situated facing the flow, so that said flow of gas is parallel to the direction of the fiber growth. The maximum length of the fibers is set by the distance between the substrate and a substrate or mask situated at the other extremity of the chamber.

Abstract: An apparatus for producing high surface area active carbons in a safe and commercially advantageous manner by the alkali metal hydroxide-based activation method is provided. Using pushers (9a-k), the apparatus circulates containers (C) along a container travel line (8) connecting the elements: material feeding section (1).fwdarw.inlet side gas replacement chamber (2).fwdarw.tunnel kiln (3).fwdarw.cooling zone (4).fwdarw.water injection chamber (5).fwdarw.outlet side gas replacement chamber (6).fwdarw.reaction mixture discharge port (7) to form a closed circuit. During the travel of the containers, a series of steps is performed, namely the steps of charging of the containers with raw materials (carbonaceous material and alkali metal hydroxide-water mixture), dehydration, activation of the carbonaceous material with the alkali metal hydroxide, cooling, water injection and discharge of the reaction mixture.

Abstract: An apparatus for producing carbon black comprises a reaction chamber which consists of a tapered throat and a downstream extension of the throat having the same diameter as that of the narrowest portion of the throat and provided with a plurality of ribs on its inner wall which define a plurality of flits parallel to the axis of the reaction chamber. The reaction chamber is equipped, on the upstream side of the extension, with means for introducing the feedstock oil perpendicularly to the axis of the chamber.

Abstract: A reactor and method for producing carbon black which involves arranging the combustion fuel conduits in a circumferential arrangement within the forward wall of the combustion chamber and providing an impact surface on the opposite side of the combustion chamber. The impact surface forms part of a forward wall of a constricting section which has a tapering passageway with a large opening in fluid communication with the combustion chamber and a smaller opening downstream. A throat passageway or restricting ring is provided at the downstream end of the tapering passageway and the throat passageway opens into an expansion chamber which, in turn, opens into a quenching chamber. Carbon black feedstock is injected into either the tapering passageway, the throat section, or both. The injection of the feedstock is achieved through the use of an axially extending lance and/or one or more radially extending injectors.

Abstract: A dispersion and a method therefor wherein the dispersion has composition A or B, whereinA is a nonaqueous dispersion comprising pigment particles having an average size of less than 0.1 micrometer dispersed in an organic medium, andB is an aqueous dispersion comprising certain classes of inorganic pigment particles having an average size of less than 0.1 micrometer dispersed in an aqueous medium, wherein said classes of inorganic pigment particles are selected from the group consisting of metal oxides and metal salts.

Abstract: A carbon black reactor having an extended reaction choke substantially reduces the presence of coke and refractory grit in the carbon black product and erosion of the carbon black reactor due to impingement of particles of forming carbon black within the reactor. The carbon black reactor generally comprises a reaction choke which extends into an exit chamber to an outlet opening within the exit chamber. Hot gas and particles of forming carbon black flow through the reaction choke, through the outlet opening into the exit chamber. The outlet opening of the reaction choke is located within the exit chamber sufficiently distal from the upstream end of the exit chamber to substantially eliminate impingement of the particles of forming carbon black against the upsteam end of the exit chamber.

Abstract: An apparatus for economically recovering char, oil and fuel gas from vehicle tires is disclosed, for either whole tires or physically fragmented tires. The tires may be washed to remove dirt and road film. The tires are dried and preheated with super-heat steam. The hot tires are pyrolyzed to partially devolatize a major portion of the hydrocarbons and produce a char that can be separated from the steel and fiber glass. The char may be subsequently pyrolyzed with microwaves that elevate the tire temperature and devolatize the remaining hydrocarbons from the char as gas. The hot gases are cooled and partially condensed. The uncondensed gas is used as fuel. The condensed oil is sent to storage. The solid residue from the tire pyrolysis is substantially char, fiberglass and steel. The char is mechanically separated from the glass and steel. Alternately, the char and the glass and steel are separated by dumping the hot mixture into a water quench tank. The mixture is cooled.

Abstract: In a preferred embodiment, an apparatus for forming carbon fibers in a continuous gas phase reaction is disclosed wherein a reactor defines a vertical reaction chamber with a close upper end and a lower outlet, with a vertical reactant feed tube which extends generally axially therewithin. Gaseous reactants are injected into the reactor through an opening of the feed tube. The feed tube and chamber are constructed and arranged to define a gas flow path which extends generally axially upward through the feed tube into the chamber and thereafter generally axially downward through the chamber. Preferably, the tube and reactor chamber are radially spaced and concentric. The feed tube may encompasss a capillary tube which supplies a vaporizable liquid reactant. The reactor and feed tube are each elongate and of a material which is relatively resistent to heat and corrosion and are preferably of a mullite material. The feed tube extends more than one-half of the axial length of the reactor.

Abstract: An axial flow carbon black reactor for producing carbon black particles having a relatively narrow particle size distribution. Feedstock oil is introduced into the reactor by a spray nozzle located coaxial with the longitudinal center line of the reactor. The oil spray flows either in the countercurrent or the concurrent direction relative to the flow of hot gas through the reactor and produces an oil spray pattern covering either substantially the entire frontal area of the hot gas flow or substantially less than the frontal area. Countercurrent feedstock flow increases coverage of the gas flow area by the oil spray and narrows the particle size distribution of carbon black produced by the reactor, and concurrent feedstock flow produces the opposite result.

Abstract: A non-cylindrical carbon black reactor for consistently and efficiently producing high tint carbon black. A plurality of flat sides defines the inner surface of the carbon black reactor. The flat sides provide a planar surface for the introduction of feedstock hydrocarbon into the reactor, thereby eliminating or substantially reducing impingement of the feedstock hydrocarbon on the inner surface of the reactor chamber and the consequent erosion of the inner surface. The flat sides of the inner surface of the reaction chamber also provide a hot gas flow with a cross-sectional area that substantially conforms to the spray pattern of the feedstock hydrocarbon, thereby providing a minimum flame length within the reactor and a more efficient use of hot gas.

Abstract: A vertical apparatus for continuously carbonizing and activating various types of fiber materials. The apparatus comprising a chamber having openings at upper and lower portions thereof, at least one port through which an activating gas is passed for activation of the fiber material and a heater for keeping the temperature in the chamber, a means for vertically passing the fiber material in a continuous manner for the carbonization and activation, and a means for supplying the activating gas into the chamber. A method for continuously carbonizing and activating fiber materials in an efficient manner is also described.

Abstract: A new reactor for the production of carbon black, a method for the production of carbon black, and a carbon black are disclosed. The carbon blacks are characterized by a surface area preferably in the range of 70 to 150 m.sup.2 /g and "G" values of either less than 1.20 or greater than 1.85, corresponding to very narrow or very broad aggregate size distributions, respectively. The reactor is preferably for axial flow of combustion gases and is characterized by serial arrangement of a cylindrical combustion zone, a frustoconical converging zone, a throat, an abrupt diverging zone and a cylindrical pyrolysis zone. In certain aspects of the invention, the combustion gases are formed by combusting low BTU fuel and forcing these gases through the throat at a velocity approaching Mach 1. In one method of carbon black production, the feedstock is introduced into the converging zone. In another method, it is introduced as a spray.

Abstract: Method for the treatment of fluidized carbon black with gases in a fluidized bed, wherein the carbon black and the treatment gases are conveyed for introduction in an unique operating procedure into the treating region in a countercurrent stream manner. The mass streams of the carbon black and the treating gases are held constant and the mass streams of the starting carbon black or the treated carbon black is regulated with the help of an optical electrical level sensor so that the height of the fluidized bed is held on a predetermined level. An apparatus is shown for the carrying out of the fluidized bed countercurrent process which has a novel carbon black product delivery system and is provided with a optical electrical level sensor means for controlling the level of the fluidized bed. The sensor comprises a hair pin shaped lighting circuit composed of two legs or rods separated by a gap.

Abstract: A method for producing carbon fibers in a vertical carbonizing furnace and an apparatus for producing carbon fibers using such a method are disclosed. The furnace includes a heating chamber for carbonizing fibers, the furnace including,(i) a fiber inlet at the upper end of the chamber(ii) an air tight sealed fiber outlet at the lower end of the furnace,(iii) an inert gas inlet provided on the wall of the chamber and above the fiber outlet,(iv) at least one inert gas injection portion, formed on the wall of the chamber, each capable of forming a curtain of inert gas across the heating chamber, each injection portion being provided between the gas inlet and the fiber inlet,(v) at least one outlet each being provided below each inert gas injection portion, and(vi) a heating member capable of controlling the temperature in the heating chamber in such a manner that the temperature gradually increases from the upper end toward a lower end of the heating chamber.

Abstract: In a heat exchange unit that recovers waste heat from carbon black smoke by preheating oxygen-containing gas such as air being passed to a carbon black producing reactor, a control loop is provided that automatically diverts the oxygen-containing gas being preheated through a by-pass line if the temperature of the effluent smoke being removed from the heat exchange is below a minimum temperature value in order to minimize the deposition of carbon on the heat exchange surfaces in said heat exchange zone.

Abstract: An improved carbon black burner for producing a carbon black with reduced grit content wherein feedstock oil is introduced radially into an atomizing fluid conduit through ports located proximate the discharge orifice of the burner.

Abstract: Apparatus for preparing spherical, submicronic, monodispersed, and non-agglomerated particles of metal oxides by reacing with steam a gaseous stream containing an aerosol of liquid particles of a hydrolyzable metal compound. The apparatus is characterized in that into a duct, in which an inert gas stream containing vapors of a hydrolyzable metal compound flows, there is fed through a nozzle a cold inert gas stream, the temperatures and flows of the two gaseous streams being such as to establish in the duct a temperature lower than the condensation temperature of the metal compound; the mixed gaseous streams having a turbulent flow in the duct, with a Reynolds number equal to or higher than 1800. At the duct outlet, the aerosol of metal compound liquid particles, which has formed in the duct, is caused to react with steam, wherefore solid particles of hydrated metal oxide form, which are subsequently calcined to the oxide.

Abstract: An axial flow carbon black reactor can be provided with multiple expansion steps in the reactor expansion zone, tangential air entries into the steps, tangential process air entry with straightening vanes in the converging zone to provide axial reactor flow, tangential process air entry using longitudinal baffles in the reactor expanded zone to provide axial reactor flow; multiple expansion steps with flow of fluid from the converging zone and into the steps and multiple step expansions of the reactor expansion zone with downstream sloping faces on the steps.

Abstract: A method and apparatus is disclosed for producing large particles of material from gas, or gases, containing the material (e.g., silicon from silane) in a free-space reactor comprised of a tube (20) and controlled furnace (25). A hot gas is introduced in the center of the reactant gas through a nozzle (23) to heat a quantity of the reactant gas, or gases, to produce a controlled concentration of seed particles (24) which are entrained in the flow of reactant gas, or gases. The temperature profile (FIG. 4) of the furnace is controlled for such a slow, controlled rate of reaction that virtually all of the material released condenses on seed particles and new particles are not nucleated in the furnace. A separate reactor comprised of a tube (33) and furnace (30) may be used to form a seed aerosol which, after passing through a cooling section (34) is introduced in the main reactor tube (34) which includes a mixer (36) to mix the seed aerosol in a controlled concentration with the reactant gas or gases.

Abstract: A method for producing carbon black employing a carbon black reactor which comprisesa cylindrical precombustion zone;a combustion gas introduction means adapted to tangentially introduce combustion gas into the cylindrical precombustion zone; anda cylindrical reaction zone in open communication with the cylindrical precombustion zone, wherein the axis of rotation of the cylindrical reaction zone and the axis of rotation of the cylindrical precombustion zone are substantially collinear, where the method comprises tangentially introducing a combustion gas into the cylindrical precombustion zone of the carbon black to create a spiralling flow and subjecting a portion of the spiralling flow to a counter-rotational force within the cylindrical precombustion zone; wherein the counter-rotational force is created by a helix-shaped fin positioned at least partially within the cylindrical precombustion zone; and wherein the helix-shaped fin is rotated about its axis by a motorized means thereby facilitating the creatio

Abstract: Vanes operatively attached to external sleeves are provided in a conduit to implement on the outside of the conduit change in the swirl angle of incoming fluids.

Abstract: The invention relates to improving the degree of graphitization of carbon black produced by subjecting hydrocarbons which are liquid or gaseous under normal conditions to a thermal conversion reaction in the presence of oxygen or an oxygen-containing gas and steam, if desired, at temperatures of 1200.degree. to 2000.degree. C. and pressures of 1 to 80 bars. To this end, the carbon black is conveyed downwardly in a quasi-fluid state, within 1 to 5 hours through a sojourn zone in upright position, the sojourn zone being maintained at a temperature of at least 1200.degree. C.

Abstract: Aerosols such as a carbon black containing smoke are subjected to an auto-preseparation by passing the aerosol or smoke through loose particles collected and accumulated and only thereafter passing the aerosol or smoke through a separator such as a filter bag. This changes the characteristic of the aerosol in either reducing the total content of solids or increasing the average particle size of the solids in the aerosol or achieving both of these features. Thereby the load on the downstream separator and the capacity of the separator, e.g. a carbon black filter house, is substantially reduced.

Abstract: In order to prevent burn-off of a radial feedstock nozzle in a carbon black reactor, resulting when the feedstock stopped flowing through the nozzle, a preselected minimum temperature of the feedstock tube actuates a mechanism to withdraw the feedstock from the hot zone of the reactor.

Abstract: A steam line is connected to the oil lines supplying feed to a carbon black reactor and valves are provided in each of the steam and oil lines so that either or both steam and oil can be fed to the oil tube emitting feed into the reactor. To change an oil nozzle without interrupting production, oil flow to a single nozzle is cut off and steam flow is provided while the nozzle is removed from the reactor. Steam flow is again provided as the replacement nozzle is inserted into the reactor and when it is in place, steam is cut off and oil flow resumed.

Abstract: A reactor for the production of carbon black is disclosed which is characterized by axial flow of combustion gases and sequential converging sections for sequentially accelerating the hot combustion gases used to drive the pyrolysis reaction.

Abstract: The tint residual of carbon black being produced in an oil furnace charging oxygen-enriched air falls as oxygen enrichment increases. An apparatus for conducting the process utilizing a low BTU fuel with external tangential combustors is also disclosed.

Abstract: Feed oils are injected axially into a carbon black reactor in a manner which slows buildup of deposits in the reactor. This is accomplished utilizing a nozzle configuration for injecting the feed oil into the carbon black reactor so that deposit-forming contaminants are directed away from the walls of the reactor. In one aspect, the feed oil is separated into two streams, one stream is contaminant-rich and the other is substantially contaminant-free. The contaminant-rich stream is fed into the reactor surrounded by the substantially contaminant-free stream. In another embodiment, a feed nozzle for a carbon black reactor is formed by a first feed tube surrounded coaxially by a second feed tube. The first feed tube can be utilized to inject contaminant-rich feed oil into the reactor. The second feed tube can be utilized to inject contaminant-free oil into the reactor in a manner such that it surrounds the contaminant-rich stream.

Abstract: A method and an apparatus for the production of industrial lead oxide involving mixing molten lead and air in a reactor. A particularly advantageous, having a desired particle size can be obtained with a PbO content of considerably more than 99%. The lead flow is introduced at a constant and even rate and the air flow is altered very slightly in order to maintain the pre-determined reaction temperature having fluctuations of a maximum of .+-.5.degree. C.The constant and steady infeed of the lead flow is achieved by using an apparatus according to the invention. The apparatus, which is situated above the reactor, includes a supply vessel charged with molten lead from a melt container, the supply vessel having an exchangeable nozzle which is provided with a control-operated cleaning pin. The nozzle extends into a reaction space and the supply vessel is connected to the melt container via a feed line and an overflow.

Abstract: A carbon black reactor employs the following components to produce non-uniform gas flow patterns.(a) a precombustion chamber skewed at an angle of 30-60 degrees from the reactor axis, comprising:(1) offset tangential hot gas entries(2) axial or offset multiple oil feed entries(b) an optional venturi which can be offset from the reactor axis and/or asymmetric in form.

Abstract: The tint residual of produced carbon black appears to go through a maximum value at a toluene photelometer of between about 65 and about 75. A process is disclosed for maximizing the tint residual of carbon black product at constant reactor volume and combustion gas flow by measuring the photelometer of the produced carbon black and changing the feedstock rate so that the photelometer of the carbon black being produced falls within the range of 65 to about 75.