Plural Chemical Reaction Stages Patents (Class 422/170)
  • Publication number: 20130129575
    Abstract: A catalyst system comprising a first catalytic composition comprising a first catalytic material disposed on a metal inorganic support; wherein the metal inorganic support has pores; and at least one promoting metal. The catalyst system further comprises a second catalytic composition comprising, (i) a zeolite, or (ii) a first catalytic material disposed on a first substrate, the first catalytic material comprising an element selected from the group consisting of tungsten, titanium, and vanadium. The catalyst system may further comprise a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. A catalyst system comprising a first catalytic composition, the second catalytic composition, and the third catalytic composition is also provided. An exhaust system comprising the catalyst systems described herein is also provided.
    Type: Application
    Filed: January 11, 2013
    Publication date: May 23, 2013
    Applicant: General Electric Company
    Inventor: General Electric Company
  • Patent number: 8444729
    Abstract: An exhaust particulate filter for an engine system includes an array of filter cartridges positioned within a shell, each of the cartridges having an electrically powered heating element coupled therewith. Exhaust gases may be distributed among the cartridges according to a single distribution pattern, and the filter can be regenerated without diverting, dividing or bypassing exhaust gases from the filter. The filter cartridges may be cylindrical or wedge-shaped, or of a variety of other configurations. Regeneration may take place according to a non-axial regeneration propagation profile. Other aspects include feedback control and feedforward control of regeneration based on sensing an electrical resistance property of each of the electrically powered heating elements.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: May 21, 2013
    Assignee: Caterpillar Inc.
    Inventors: Brett M. Bailey, Clifford E. Cotton, Christopher J. Rynders, Jr., Michael J. Readey, Michael J. Pollard, Robert L. Meyer
  • Patent number: 8444741
    Abstract: A method for producing a metallic honeycomb body from metallic layers with channels through which an exhaust gas stream can flow, includes providing the honeycomb body with a coating. Such honeycomb bodies are used in exhaust gas systems of preferably mobile internal combustion engines as catalyst carrier bodies, filters, mixers and/or adsorbers. The coating is provided in a two-stage application and enables the production of exceptionally advantageous coated metallic honeycomb bodies, which are distinguished by a large coating surface and a low flow resistance. At the same time, an exceptionally large surface enlargement is provided in the honeycomb body while using a smaller amount of coating. A honeycomb body is also provided.
    Type: Grant
    Filed: October 24, 2011
    Date of Patent: May 21, 2013
    Assignee: EMITEC Gesellschaft fuer Emissionstechnologie mbH
    Inventor: Rolf Brück
  • Patent number: 8444738
    Abstract: Disclosed herein is a filter device for reducing automobile exhaust fume. The filter device includes a case, a front flange mounted inside the case, a rear flange mounted inside the case, and a filter member mounted between the front and rear flanged. The case includes an inlet port, a porous tube and an exhaust port. The filter member includes a laminated-type or rolled-up type metallic foam filter mounted between the front and rear flanges, and a jacket wrapped around the metallic foam filter. The exhaust gas that flows inside the porous tube passes through the metallic foam filter. The jacket is formed in a network form to maintain the shape of the metallic foam filter and provide durability thereto. The jacket is formed with a rectangular vent hole. The jacket holds the metallic foam filter such that the shape, construction and position of the metallic foam filter can be maintained.
    Type: Grant
    Filed: July 18, 2008
    Date of Patent: May 21, 2013
    Assignee: Alantum Corporation
    Inventor: Hyun Tae Kim
  • Patent number: 8444753
    Abstract: An exhaust gas purifying system includes an exhaust gas purifying apparatus provided with a gas inlet side connected to an inlet pipe and a gas outlet side connected to an exhaust pipe. A holding sealing material of the exhaust gas purifying apparatus has a first side face and a second side face. The first side face is positioned on the gas outlet side and has a first slanting face formed on the first side face. The first slanting face has a first inside end point and a first outside end point. The first inside end point is positioned between the gas inlet side and the first outside end point. The first slanting face extends from the first inside end point to the first outside end point and is tilted relative to an end face of an exhaust gas treating body of the exhaust gas purifying apparatus.
    Type: Grant
    Filed: April 22, 2011
    Date of Patent: May 21, 2013
    Assignee: Ibiden Co., Ltd.
    Inventor: Masashi Hagino
  • Patent number: 8444730
    Abstract: A motor-vehicle engine system comprises an envelope configured to transmit exhaust. The envelope encloses a first array of filtration cells downstream of a second array of filtration cells. The system further comprises a fuel injector configured to increase a temperature in the envelope when soot is evenly distributed between the first and second arrays in order to address thermal gradients.
    Type: Grant
    Filed: September 27, 2010
    Date of Patent: May 21, 2013
    Assignee: Ford Global Technologies, LLC
    Inventor: Xiaogang Zhang
  • Patent number: 8444737
    Abstract: A method of firing a green structure to produce a ceramic structure may comprise heating a firing environment during a first stage of firing of a green structure over a first timed temperature cycle having an average ramp rate sufficient to substantially complete burnout of organic material prior to initiation of clay dehydration proximate a core of the ceramic structure. The method may further comprise heating the firing environment during a second stage of the firing over a second timed temperature cycle having an average ramp rate that is faster than the average ramp rate of the first timed temperature cycle.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: May 21, 2013
    Assignee: Corning Incorporated
    Inventor: Sriram Rangarajan Iyer
  • Patent number: 8444739
    Abstract: A honeycomb filter including partition walls having a porous partition wall base material and a surface layer provided on only inflow side or both inflow and outflow sides of the partition wall base material, and satisfying the following conditions capable of using as a DPF. The surface layer has a peak pore diameter of from 0.3 ?m to 20 ?m (exclusive) being equal to or smaller than the average pore diameter of the base material; the porosity of from 60% to 95% (exclusive) when measured by mercury porosimetry being larger than that of the base material; and the thickness L1 of from 0.5% to 30% (exclusive) of the partition wall thickness L2; and mass per filtration area of from 0.01 mg/cm2 to 6 mg/cm2 (exclusive). The base material has an average pore diameter of from 10 ?m to 60 ?m (exclusive) and a porosity of from 40% to 65% (exclusive).
    Type: Grant
    Filed: October 21, 2009
    Date of Patent: May 21, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Yukio Mizuno, Naomi Noda, Toshio Yamada, Yukio Miyairi, Yukari Nakane, Yasushi Noguchi
  • Patent number: 8444752
    Abstract: A particulate filter may comprise an inlet end, an outlet end, and a plurality of parallel channels disposed and configured to flow fluid from the inlet end to the outlet end, the channels being defined by a plurality of porous walls configured to trap particulate matter. The particulate filter may define at least one filtration region including a first group of channels and at least one bypass region including a second group of channels, wherein at least some of the channels in the first group of channels are plugged at an end thereof, wherein the channels in the second group of channels are unplugged, and wherein greater than or equal to about 70% of the plurality of parallel channels are plugged at an end thereof.
    Type: Grant
    Filed: October 22, 2009
    Date of Patent: May 21, 2013
    Assignee: Corning Incorporated
    Inventors: Douglas Munroe Beall, Achim Karl-Erich Heibel, Pushkar Tandon
  • Publication number: 20130118351
    Abstract: SOx removal equipment for reducing sulfur oxides from flue gas from a boiler, a cooler provided on a downstream side of the SOx removal equipment, for reducing the sulfur oxides that remain in the flue gas and decrease a gas temperature, CO2 recovery equipment including an absorber for bringing CO2 in the flue gas into contact with a CO2 absorption liquid to be reduced, and a regenerator for causing the CO2 absorption liquid to emit CO2 to recover CO2 and regenerate the CO2 absorption liquid, a heat exchanger which is provided on an inlet passage side of the electric dust collector, for decreasing a temperature of the flue gas are included, and a mist generation material in the flue gas is converted from a gas state to a mist state to cause particulates in the flue gas to arrest and reduce the mist generation material in the mist state.
    Type: Application
    Filed: May 31, 2011
    Publication date: May 16, 2013
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Tatsuto Nagayasu, Takashi Kamijo, Masayuki Inui, Tsuyoshi Oishi, Hiromitsu Nagayasu, Hiroshi Tanaka, Takuya Hirata, Tatsuya Tsujiuchi, Susumu Okino, Naoyuki Kamiyama, Seiji Yoshihara
  • Publication number: 20130115144
    Abstract: The invention generally relates to three-way catalysts and catalyst formulations capable of simultaneously converting nitrogen oxides, carbon monoxide, and hydrocarbons into less toxic compounds. Such three-way catalyst formulations contain ZrO2-based mixed-metal oxide support oxides doped with an amount of lanthanide. Three-way catalyst formulations with the support oxides of the present invention demonstrate higher catalytic activity, efficiency and longevity than comparable catalysts formulated with traditional support oxides.
    Type: Application
    Filed: August 8, 2012
    Publication date: May 9, 2013
    Applicant: CLEAN DIESEL TECHNOLOGIES, INC.
    Inventors: Stephen J. Golden, Randal Hatfield, Jason D. Pless
  • Publication number: 20130115145
    Abstract: An exhaust purification system of an internal combustion engine is provided with an exhaust purification catalyst which includes an upstream side catalyst and a downstream side catalyst and removes NOX. The upstream side catalyst has an oxidation ability, while the downstream side catalyst has catalyst particles of precious metals and basic exhaust flow surface parts. The system makes the concentration of hydrocarbons which flow into the exhaust purification catalyst vibrate by within a predetermined range of amplitude and by within a predetermined range of period and reduces the NOX. The upstream side catalyst includes an upstream side substrate and an upstream side container, while the downstream side catalyst includes a downstream side substrate, a downstream side container, and a channel of exhaust between the downstream side substrate and the downstream side container.
    Type: Application
    Filed: November 9, 2011
    Publication date: May 9, 2013
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Kazuhiro Umemoto, Mikio Inoue
  • Publication number: 20130115150
    Abstract: A SCR catalyst system, comprising a first SCR catalyst (1) and a second SCR catalyst (2) which is disposed in the exhaust gas tract downstream of the first SCR catalyst (1). At least one metering device (12) for metering in a reducing agent solution is disposed in the exhaust gas tract upstream of a first SCR catalysis element (13) of said first SCR catalyst (1). The SCR catalyst system does not require a device for metering a reducing agent solution into a second SCR catalysis element (21) of the second SCR catalyst (2).
    Type: Application
    Filed: September 14, 2012
    Publication date: May 9, 2013
    Applicant: ROBERT BOSCH GMBH
    Inventors: Andreas Fritsch, Andreas Holzeder
  • Patent number: 8435320
    Abstract: A ceramic honeycomb filter comprising a honeycomb structure having a large number of flow paths partitioned by porous cell walls; and plugs formed in the flow paths alternately on the exhaust gas inlet and outlet sides; the thickness W (mm) and permeability ? (?m2) of the cell wall and the length L (mm) and cross section area A (mm2) perpendicular to the length direction of the flow path meeting the relations of 0.1?W?0.5, 8??/W?26.7, and 125?L/A0.5?360.
    Type: Grant
    Filed: August 30, 2007
    Date of Patent: May 7, 2013
    Assignee: Hitachi Metals, Ltd.
    Inventors: Toshitaka Ishizawa, Kenichiro Sekiguchi, Masakazu Konomi
  • Patent number: 8420037
    Abstract: An air pollution control system includes a desulfurization apparatus 13 that reduces sulfur oxide contained in flue gas 12 supplied from a boiler 11; and a CO2 recovery apparatus 15 including a CO2 absorber 21 that reduces CO2 contained in flue gas 12 that has been desulfurized by the desulfurization apparatus, with the aid of an amine absorbent and an absorbent regenerator 22 that regenerates the amine absorbent. Part 14a of desulfurized flue gas 14 containing SOx is supplied to treated flue gas 16, from which CO2 has been reduced and which is discharged from a top portion of the CO2 absorber 21, so that remaining mist amine accompanying the treated flue gas 16 is neutralized to amine sulfate or amine sulfite.
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: April 16, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Masaki Iijima, Tsuyoshi Oishi, Takashi Kamijo, Hiroshi Tanaka, Hiromitsu Nagayasu, Naohiko Ukawa
  • Publication number: 20130089481
    Abstract: The invention provides an exhaust gas cleaning oxidation catalyst and in particular to an oxidation catalyst for cleaning the exhaust gas discharged from internal combustion engines of compression ignition type (particularly diesel engines). The invention further relates to a catalysed substrate monolith comprising an oxidising catalyst on a substrate monolith for use in treating exhaust gas emitted from a lean-burn internal combustion engine. In particular, the invention relates to a catalysed substrate monolith comprising a first washcoat coating and a second washcoat coating, wherein the second washcoat coating is disposed in a layer above the first washcoat coating.
    Type: Application
    Filed: October 5, 2012
    Publication date: April 11, 2013
    Applicants: JOHNSON MATTHEY PUBLIC LIMITED COMPANY, JOHNSON MATTHEY JAPAN GODO KAISHA
    Inventors: JOHNSON MATTHEY JAPAN GODO KAISHA, Johnson Matthey Public Limited Company
  • Publication number: 20130089483
    Abstract: The present invention relates to a catalyst, which may be used in selective catalytic reduction (SCR), said catalyst comprising one or more zeolites of the BEA structure type, one or more zeolites of the CHA structure type, and optionally one or more zeolites of the MFI structure type, wherein at least part of the one or more zeolites of the BEA structure type contain iron (Fe), wherein at least part of the one or more zeolites of the CHA structure type contain copper (Cu), and wherein at least part of the optional one or more zeolites of the MFI structure type contain iron (Fe). Furthermore, the present invention concerns an exhaust gas treatment system comprising said catalyst as well as a process for the treatment of a gas stream comprising NO using said catalyst as well.
    Type: Application
    Filed: October 4, 2012
    Publication date: April 11, 2013
    Applicant: BASF SE
    Inventor: BASF SE
  • Patent number: 8414852
    Abstract: Plants and method of treating a combustion gas are presented in which NOx compounds are removed from the combustion gas to a predetermined level to thereby create a pre-cleaned combustion gas from which CO2 is removed in an absorber using an amine solvent. Preferably, the predetermined level of NOx compounds reduces nitro-amines, especially nitrosamine emission from the absorber to quantities of equal or less than 100 ppb.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: April 9, 2013
    Assignee: Fluor Technologies Corporation
    Inventors: Dennis W. Johnson, Satish Reddy
  • Publication number: 20130084222
    Abstract: The present invention relates to a layered diesel oxidation catalyst (DOC) comprising: a) a carrier substrate; b) a diesel oxidation catalytic material comprising b1) a first layer located on the carrier substrate, the first layer comprising palladium impregnated on a support material comprising ceria in an amount of at least 45 weight-% based on the total weight of the support material, and optionally comprising platinum; b2) a second layer located on the first layer, the second layer comprising palladium and platinum each impregnated on a support material comprising a metal oxide; wherein the platinum to palladium weight ratio of the first layer is lower than the platinum to palladium weight ratio of the second layer.
    Type: Application
    Filed: September 21, 2012
    Publication date: April 4, 2013
    Applicants: BASF Corporation, BASF SE
    Inventors: BASF SE, BASF Corporation
  • Publication number: 20130078160
    Abstract: An exhaust gas-purifying system for purifying exhaust gas discharged from a diesel engine includes a diesel oxidation catalyst through which the exhaust gas passes, a diesel particulate filter which includes a filter substrate and an active component supported by the filter substrate and exhibiting a catalytic activity for selective catalytic reduction and through which the exhaust gas having passed through the diesel oxidation catalyst penetrates, and an ammonia slip catalyst which includes a zeolite whose alkaline metal ions are partially exchanged with transition metal ions and through which the exhaust gas having penetrated the diesel particulate filter passes.
    Type: Application
    Filed: September 25, 2012
    Publication date: March 28, 2013
    Applicant: CATALER CORPORATION
    Inventor: Cataler Corporation
  • Patent number: 8404011
    Abstract: A method and to a device for the regeneration of a particle arranged in the exhaust gas train of an internal combustion engine. An exhaust gas stream to be cleaned is supplied to the at least one particle filter. At least in a regeneration mode, a predetermined amount of an exhaust gas stream to be heated is branched off from the exhaust gas stream upstream of an exhaust gas turbine of an exhaust gas turbocharger which branched-off stream, after it has been heated by a heater is mixed in the form of a heated exhaust gas stream at a point upstream of the at least one particle filter back into the residual gas stream which is coming from the exhaust gas turbine and which is at a lower temperature than that of the other stream.
    Type: Grant
    Filed: August 12, 2009
    Date of Patent: March 26, 2013
    Assignee: Man Nutzfahrzeuge AG
    Inventor: Andreas Döring
  • Publication number: 20130071311
    Abstract: An air pollution control system 10A includes a boiler 11 that burns fuel, an air heater 13 that recovers heat of flue gas 17 from the boiler 11, and a desulfurizer 15 that reduces sulfur oxides contained in the flue gas 17 after heat recovery by an absorbent, and waste-water supplying units P0 to P5 that supply desulfurized waste water 28 discharged from the desulfurizer 15 to at least one of a path for supplying fuel to the boiler 11, inside of a furnace of the boiler 11, and the inside of a flue gas duct between the boiler 11 and the air heater 13 are installed. With this configuration, an amount of desulfurized waste water to be returned into the flue gas duct per unit time can be increased as compared to conventional systems, without increasing the size of the entire air pollution control system.
    Type: Application
    Filed: November 8, 2012
    Publication date: March 21, 2013
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventor: MITSUBISHI HEAVY INDUSTRIES, LTD.
  • Publication number: 20130071308
    Abstract: The invention relates to a method for recovering sulphur from a sour gas containing hydrogen sulphide and carbon dioxide, comprising: oxidation of the sour gas, wherein a part of the hydrogen sulphide is oxidized to sulphur dioxide and water, reaction of the resulting sulphur dioxide with the residual hydrogen sulphide to elementary sulphur, and removal of elementary sulphur. According to the invention carbon dioxide and/or carbon dioxide generated by oxidation of the sour gas is compressed, and at least a part of the carbon dioxide is injected into an oil well. Furthermore, the invention relates to a plant suitable for performing the above method.
    Type: Application
    Filed: September 20, 2012
    Publication date: March 21, 2013
    Applicant: LINDE AKTIENGESELLSCHAFT
    Inventor: LINDE AKTIENGESELLSCHAFT
  • Publication number: 20130071296
    Abstract: A vertical downflow type flue gas denitrification apparatus which has a plurality of catalyst blocks, each incorporating a catalyst unit provided therein, is provided with a first ash accumulation baffle plate and a second ash accumulation baffle plate which are slidable into a gap between catalyst blocks adjacent to each other, and processes an exhaust gas emitted from a combustor and turned to a vertical downflow. The denitrification apparatus has a simple configuration where the ash accumulation baffle plates prevent ash or the like from being accumulated in the gap between the catalyst blocks. The thermal expansion of the ash accumulation baffle plate can be absorbed even under the operating conditions which produce a change in temperature, and charging and replacing the catalyst in the catalyst blocks are possible without on-site welding of the ash accumulation baffle plates.
    Type: Application
    Filed: July 5, 2011
    Publication date: March 21, 2013
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Tomokazu Harada, Satoru Shishido, Toru Ogasahara
  • Patent number: 8398736
    Abstract: Jointing cement intended in particular for fastening together a plurality of filter blocks of a filtering body of an exhaust gas particle filter of an internal combustion engine of a motor vehicle, having a silicon carbide (SiC) content of between 30% and 90%. The cement according to the invention includes at least 0.05% and less than 5% of a thermosetting resin, the percentages being percentages by weight relative to the total weight of the thermosetting resin and the mineral material, apart from the possible water.
    Type: Grant
    Filed: June 19, 2007
    Date of Patent: March 19, 2013
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Sébastien Bardon, Anthony Briot, Gaëtan Champagne, Vincent Gleize
  • Publication number: 20130058849
    Abstract: A method of using a hybrid oxidation catalyst system for remediating a lean emission from a vehicle includes the step of oxidizing the hydrocarbons and carbon monoxide in an engine emission comprising hydrocarbons, carbon monoxide, NOx including NO and NO2, and oxygen with a first catalyst. The first catalyst includes noble metal particles supported in a first ceramic layer. The method further includes oxidizing the NO with a second catalyst having base metal oxide particles supported in a second ceramic layer to form NO2. The first catalyst is disposed upstream of the second catalyst and the system is capable of converting at least 10% of the amount of NO to NO2 at a temperature ranging from 75° C. to 225° C.
    Type: Application
    Filed: November 1, 2012
    Publication date: March 7, 2013
    Applicant: FORD GLOBAL TECHNOLOGIES, LLC
    Inventor: Ford Global Technologies, LLC
  • Patent number: 8388741
    Abstract: A system comprises a particulate matter (PM) filter comprising an inlet for receiving exhaust gas. A zoned heater is arranged in the inlet and comprises a resistive heater comprising N zones, where N is an integer greater than one. Each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates others of the N zones.
    Type: Grant
    Filed: December 14, 2007
    Date of Patent: March 5, 2013
    Inventor: Eugene V. Gonze
  • Patent number: 8388719
    Abstract: The present invention relates to a ceramic filter comprising clay and a process for preparing the same. More specifically, the present invention relates to the ceramic filter, including wave-shaped ceramic paper and plate-shaped paper, having improved efficiency and performance that may optimize the process of coating and calcining inorganic binder by forming an outer wall thereon, using clay, and thus increase insulation effect and mechanical strength represented by the clay layer, and the process for preparing thereof.
    Type: Grant
    Filed: April 2, 2007
    Date of Patent: March 5, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Ju-Hyung Lee, Jong-Sik Choi, Hoon Ahn, Sun-Joo Kim, Seong-Moon Jung
  • Patent number: 8388711
    Abstract: The present disclosure provides an apparatus and method for removing particulates from a gas stream. The apparatus includes a ceramic filter, at least one electrode, and at least one conductor. The electrode is located at an end of the filter and produces an atmospheric glow discharge in order to oxidize carbon deposits trapped in the filter. The conductor extends at least partially into the filter and acts as a counter electrode. Through various arrangements of the electrodes and conductors, the present disclosure provides closer connection between the trapped carbon deposits and the electrodes. This improves the regeneration of the filter without increasing the size and/or weight of the apparatus.
    Type: Grant
    Filed: August 22, 2006
    Date of Patent: March 5, 2013
    Assignee: Perkins Engine Company Ltd.
    Inventors: Colin Peter Garner, John Ernest Harry
  • Patent number: 8388917
    Abstract: An air pollution control system 10A includes a boiler 11 that burns fuel, an air heater 13 that recovers heat of flue gas 17 from the boiler 11, and a desulfurizer 15 that reduces sulfur oxides contained in the flue gas 17 after heat recovery by an absorbent, and waste-water supplying units P0 to P5 that supply desulfurized waste water 28 discharged from the desulfurizer 15 to at least one of a path for supplying fuel to the boiler 11, inside of a furnace of the boiler 11, and the inside of a flue gas duct between the boiler 11 and the air heater 13 are installed. With this configuration, an amount of desulfurized waste water to be returned into the flue gas duct per unit time can be increased as compared to conventional systems, without increasing the size of the entire air pollution control system.
    Type: Grant
    Filed: February 25, 2010
    Date of Patent: March 5, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa
  • Patent number: 8388721
    Abstract: A ceramic honeycomb filter comprising a honeycomb structure having large numbers of flow paths partitioned by porous cell walls, and plugs alternately formed in the flow paths on the exhaust-gas-inlet and outlet sides, the area ratio of pores opening at the cell wall surfaces being 20% or more, porous, cross-linked structures being formed by heat-resistant particles introduced together with a gas into penetrating holes constituted by communicating pores in the cell walls, such that they clog the penetrating holes, and the cross-linked structures being formed more on the exhaust-gas-outlet side of the ceramic honeycomb filter than on the exhaust-gas-inlet side.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: March 5, 2013
    Assignee: Hitachi Metals, Ltd.
    Inventor: Toshitaka Ishizawa
  • Patent number: 8388720
    Abstract: Jointing cement intended in particular for fastening together a plurality of filter blocks of a filtering body for filtering exhaust gas particles of an internal combustion engine of a motor vehicle, the cement including, in percentages by weight relative to the weight of the mineral material, apart from possible water and a possible mineral resin, between 30 and 90% of silicon carbide (SiC), at least 3% of hollow spheres including, in percentages by weight and for a total of at least 99%, between 20 and 99% of silica (SiO2) and between 1 and 80% of alumina (Al2O3), at least 80% by number of the hollow spheres having a size of between 5 and 150 ?m.
    Type: Grant
    Filed: June 19, 2007
    Date of Patent: March 5, 2013
    Assignee: Saint Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Anthony Briot, Christophe Carrie, Gaëtan Champagne, Vincent Gleize
  • Publication number: 20130052111
    Abstract: The invention relates to a method for removing gas components SOX, NOx, and CO2 from a flue gas, comprising the steps of: a) contacting the flue gas with a first liquid medium which provides a first plasma containing reactive electrons or ions in an amount such that the gas molecules SOX are subject to impingement of the electrons or ions in the first plasma to enable the dissociation of the gas molecules SOX so as to remove SOx from the flue gas; b) contacting the flue gas obtained from step a) with a second liquid medium which provides a second plasma containing reactive electrons or ions in an amount such that the gas molecules CO2 are subject to impingement of the electrons or ions in the second plasma to enable the dissociation of the gas molecules CO2 so as to remove CO2 from the flue gas; and c) contacting the flue gas obtained from step b) with a third liquid medium which provides a third plasma containing reactive electrons or ions in an amount such that the gas molecules NOx are subject to impingeme
    Type: Application
    Filed: May 26, 2010
    Publication date: February 28, 2013
    Applicant: ECOSPEC GLOBAL TECHNOLOGY PTE LTD.
    Inventor: Hwee Hong Chew
  • Publication number: 20130052095
    Abstract: Disclosed is an exhaust purification system (2) for an internal combustion engine (1), which comprises: a reduction catalyst (6) that is arranged in an exhaust pipe (exhaust passage) (3) of the internal combustion engine (1); and a reducing agent spraying device (4) for spraying a reducing agent within the exhaust pipe (3) in the upstream of the reduction catalyst (6). A dispersing member (member for promoting evaporation of the reducing agent) (5) is arranged at a position, which is in the upstream of the reduction catalyst (6) within the exhaust pipe (3), and to which the reducing agent is sprayed from the reducing agent spraying device (4). The dispersing member (5) is formed of a porous member and affixed within the exhaust pipe (3) such that the dispersing member (5) is parallel to the flowing direction of the exhaust gas.
    Type: Application
    Filed: April 28, 2011
    Publication date: February 28, 2013
    Applicant: YANMAR CO, LTD.
    Inventor: Hiroshi Omote
  • Publication number: 20130052094
    Abstract: A device for treating exhaust gases from a heating system, preferably a small heating system, particularly a small heating system used in private households, comprising: a catalytic device comprising a catalytically active material, wherein the catalytically active material is a ceramic by means of which an oxidation of exhaust compounds is catalyzable; and wherein the catalytic device comprises a plurality of apertures through which the exhaust gases may flow; characterized in that the catalytic device comprises a bulk material comprising a plurality of bulky components.
    Type: Application
    Filed: February 9, 2011
    Publication date: February 28, 2013
    Inventor: Martin Pley
  • Publication number: 20130039817
    Abstract: An exhaust gas purifying apparatus has a first housing including a DOC converter and DPF, and a second housing including an SCR converter, the housings disposed in parallel on the outer side of a frame such that the exhaust upstream ends thereof are positioned on the outer side in the vehicle width direction. An outlet port of the first housing and an inlet port of the second housing are communicatively connected through a communication pipe. The first housing is dividable into a first casing accommodating the DOC converter and a second casing accommodating the DPF, the two casings separably fastened by bolts. The inlet port of the first casing housing is bent inwardly in the width direction and detachably fastened to an exhaust pipe, the distal end of which opens outwardly in the width direction, through bolts. The second casing and housing are fixed to the frame through two brackets.
    Type: Application
    Filed: October 12, 2012
    Publication date: February 14, 2013
    Inventor: Takashi FUKUDA
  • Publication number: 20130039816
    Abstract: A plasma reaction apparatus and method applied to reformation of fuel by generating and using rotating arc plasma in a furnace, the chemical treatment of a persistent gas, and the apparatus for decreasing NOx by an occlusion catalyst. A raw material for a reaction is allowed to flow into the furnace through a hole, causing it to flow within the furnace in a continuous swirl. Furthermore, an expanded plasma reaction zone is provided by a wide area chamber which is formed on an upper part of the furnace and has a greater width than that of a lower part of the furnace, and thus a plasma being generated can be expanded by the expanded plasma zone and delayed from flowing out of the furnace by corners of the wide area chamber that is spaced from a plasma inducing electrode therein.
    Type: Application
    Filed: August 6, 2012
    Publication date: February 14, 2013
    Applicant: Korea Institute of Machinery and Materials
    Inventors: Dae Hoon LEE, Kwan Tae Kim, Young Hoon Song, Min Suk Cha, Jae Ok Lee, Seok Joon Kim
  • Patent number: 8372363
    Abstract: A method for removing mercury in a combustion exhaust gas includes injecting ammonia or urea as a reducing agent into a combustion exhaust gas containing nitrogen oxides, sulfur dioxide, metallic mercury, and hydrogen halides, and then introducing the combustion exhaust gas to a denitration apparatus filled with a denitration catalyst to cause a denitration reaction and oxidize the metallic mercury to produce mercury halide; and introducing the combustion exhaust gas through an air preheater and an electric dust collector to a wet desulfurization apparatus, thereby removing sulfur dioxides and the mercury halide, wherein the ammonia concentration of the combustion exhaust gas at an exit of the denitration apparatus is maintained at 5 ppm or higher, and the mercury halide is adsorbed or precipitated onto combustion ash and collected by the electric dust collector to discharge the mercury halide out of a system.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: February 12, 2013
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Yasuyoshi Kato, Keiichiro Kai, Seiji Ikemoto
  • Publication number: 20130034485
    Abstract: According to the present invention, a mercury removing system (A) includes a reaction gas supplier (20) that supplies reaction gas to treatment target gas; de-nitration equipment (2) that reduces nitrogen oxide in the treatment target gas to be removed and oxidizes low water-soluble mercury in the treatment target gas to obtain water-soluble mercury; and desulfurization equipment (7) that removes sulfur oxide and the low water-soluble mercury in the treatment target gas. The mercury removing system further includes an oxidation gas vaporizer (124) that heats an oxidation gas generating liquid to generate oxidation gas and a gas mixer (13) that mixes the oxidation gas with reducing gas to obtain the reaction gas, outside a flue and on the upstream side of the reaction gas supplier (20).
    Type: Application
    Filed: November 2, 2010
    Publication date: February 7, 2013
    Inventor: Toshiyuki Naito
  • Publication number: 20130028818
    Abstract: The present invention relates to a method for exhaust gas after-treatment for essentially lean-burn internal combustion engines and also a corresponding advantageous exhaust gas after-treatment system. In particular, the present invention relates to reducing the proportion of the greenhouse gas N20 in the total exhaust gas from a corresponding internal combustion system using at least one NOx storage catalyst as exhaust gas purification element. The objective of the invention is to operate the N20 depletion catalyst located downstream of the NOx storage catalyst under lambda=<1 conditions when the N20 formed by the NOx storage catalyst reaches the N20 depletion catalyst.
    Type: Application
    Filed: April 5, 2011
    Publication date: January 31, 2013
    Applicant: UMICORE AG & CO. KG
    Inventors: Stephan Eckhoff, Frank Adam, Christian Lammarck
  • Publication number: 20130028795
    Abstract: An exhaust gas purification apparatus for an internal combustion engine comprises a NOx selective reduction catalyst provided in an exhaust passage of an internal combustion engine; an upstream side oxidation catalyst which is a catalyst having an oxidizing ability provided in the exhaust passage upstream from the NOx selective reduction catalyst and which includes a carrier for carrying a noble metal for oxidation, the carrier being formed of a basic carrier; and a reducing agent supply until which supplies a reducing agent to an exhaust gas allowed to flow into the NOx selective reduction catalyst. Accordingly, even when the oxidation catalyst causes the SOx poisoning in the exhaust gas purification apparatus for the internal combustion engine having the oxidation catalyst and the NOx selective reduction catalyst provided in the exhaust passage, the reduction efficiency of NOx reduced by the aid of the NOx selective reduction catalyst is favorably maintained.
    Type: Application
    Filed: April 8, 2010
    Publication date: January 31, 2013
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Yuki Bisaiji, Kohei Yoshida, Mikio Inoue
  • Publication number: 20130028807
    Abstract: Disclosed is a method of removing carbon dioxide from a process gas, the method comprising: contacting an ammoniated solution with the process gas in an absorption arrangement 101, the ammoniated solution capturing at least a part of the carbon dioxide of the process gas, wherein the molar ratio, R, of ammonia to carbon dioxide in the ammoniated solution is controlled such that substantially no precipitation of solids occurs within the absorption arrangement 101; allowing ammoniated solution including captured carbon dioxide to exit the absorption arrangement 101; cooling the ammoniated solution that has exited the absorption arrangement, wherein at least a part of the captured carbon dioxide is precipitated as solid salt; separating at least a part of the precipitated salt from the ammoniated solution; heating the ammoniated solution from which the at least a part of the precipitated salt has been separated, such that substantially no solids are present in the heated ammoniated solution; and allowing the hea
    Type: Application
    Filed: October 8, 2012
    Publication date: January 31, 2013
    Applicant: ALSTOM TECHNOLOGY LTD
    Inventor: ALSTOM TECHNOLOGY LTD
  • Publication number: 20130028806
    Abstract: An exhaust emission control device with a particulate filter 1 and a selective reduction catalyst 6 (exhaust purification catalyst) incorporated in an exhaust pipe 10 such that the former and the latter are arranged on downstream and upstream sides, respectively, has a burner 2 for generating high-temperature exhaust gas by combustion, an exhaust distribution pipe 14 capable of guiding the exhaust gas 13 from the burner 2 to entry sides of the filter 1 and the catalyst 6, respectively, and valves 15 and 16 as path switcher in the pipe 14 for selectively sorting the exhaust gas 13 from the burner 2 any one of the entry sides of the filter 1 and the catalyst 6.
    Type: Application
    Filed: April 26, 2011
    Publication date: January 31, 2013
    Applicant: HINO MOTORS, LTD.
    Inventor: Tatsuki Igarashi
  • Publication number: 20130028820
    Abstract: Disclosed are an exhaust gas treating apparatus and a treating method for a carbon dioxide capture process, in which harmful substances remaining in the exhaust gas discharged from the conventional flue-gas desulfurization process are additionally removed for efficient performance of the carbon dioxide capture process. According to the exhaust gas treating apparatus for a carbon dioxide capture process, it has the effects of minimizing the installation space of desulfurization equipment and reducing the process cost. In addition, by keeping the contaminants contained in the gas introduced in the carbon dioxide capture equipment below a proper level, absorption performance can be improved as degradation of the absorbent used in the carbon dioxide capture process is prevented. After all, it has an advantage of preventing the pollution by the exhaust gas discharged into the atmosphere.
    Type: Application
    Filed: January 27, 2012
    Publication date: January 31, 2013
    Applicant: Korea Institute of Energy Research
    Inventors: Hyung-Keun Lee, Won-Kil Choi, Hang-Dae Jo, Chang-Keun Yi, Sung-Ho Jo, Young-Cheol Park
  • Publication number: 20130022512
    Abstract: In an internal combustion engine, inside of an engine exhaust passage in order from an upstream side, a hydrocarbon feed valve, oxidation catalyst, and exhaust purification catalyst are arranged. On the exhaust purification catalyst, platinum and rhodium are carried and a basic layer is formed. Hydrocarbons are intermittently fed from the hydrocarbon feed valve while maintaining the air-fuel ratio of the exhaust gas flowing into the exhaust purification catalyst lean. At this time, the feed of hydrocarbons is controlled so as to ensure the continued presence of the reducing intermediate on the basic layer.
    Type: Application
    Filed: March 15, 2010
    Publication date: January 24, 2013
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Yuki Bisaiji, Kohei Yoshida, Mikio Inoue
  • Patent number: 8349283
    Abstract: A metal recovery apparatus recovers metal components from an exhaust gas exhausted from a processing chamber in which a thin film is formed on the surface of a target substrate by using a source gas formed of an organic metal compound serving as a source, and scrubs the exhaust gas. The metal recovery apparatus 66 includes a trap unit having an adsorption member for attaching thereon metal components included in the source gas by heating the exhaust gas and thus thermally decomposing an unreacted source gas included in the exhaust gas; and the scrubbing unit including a catalyzer for oxidizing and thus scrubbing harmful gas components included in the exhaust gas that has flowed through the trap unit.
    Type: Grant
    Filed: August 4, 2009
    Date of Patent: January 8, 2013
    Assignee: Tokyo Electron Limited
    Inventors: Masamichi Hara, Atsushi Gomi, Tatsuo Hatano
  • Publication number: 20130004392
    Abstract: An assembly and method for reducing nitrogen oxides, carbon monoxide, hydrocarbons and hydrogen gas in exhausts of internal combustion engines and simultaneously generating electrical power, wherein the exhaust is acted upon in a first stage catalytic converter and is at least in part passed through a thermoelectric generator for production of electrical power. The exhausts are thereafter directed to a second stage catalytic converter.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 3, 2013
    Inventors: Jean Roy, Robert A. Panora, Joseph B. Gehret, Ranson Roser
  • Publication number: 20120321524
    Abstract: Disclosure relates to a slip catalyst for reducing a NO2 content in an exhaust train of an internal combustion engine flowed through by an exhaust gas flow, which has an oxidizing catalyst for the formation of NO2 and a particulate filter arranged downstream for binding carbon black particles and simultaneous and/or subsequent reaction of the same with NO2 formed on the oxidizing catalyst, having a substrate that is provided with a coating, which coating reduces a proportion of NO2 in the exhaust gas flow flowing through. The coating has at least two elements from the group of rare-earth metals, which are present in the coating in the form of a salt or an oxide or in an elementary form and in a concentration of more than 300.0 g/m3.
    Type: Application
    Filed: December 21, 2010
    Publication date: December 20, 2012
    Inventor: Bernhard Kahlert
  • Patent number: 8329126
    Abstract: The present invention, in some embodiments, provides catalyst modules and/or catalytic reactors having increased effective catalyst cross-sectional areas. In some embodiments, a catalyst module comprises a fluid stream inlet side comprising a plurality of first catalyst bodies and a plurality of first ducts and a fluid stream outlet side comprising a plurality of second catalyst bodies and a plurality of second ducts, wherein the first ducts are a fluid stream inlet to the second catalyst bodies and the second ducts are a fluid stream outlet for the first catalyst bodies.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: December 11, 2012
    Assignee: Cormetech, Inc.
    Inventors: Jeremy Thomas Freeman, Eric Baker Howell
  • Patent number: 8329128
    Abstract: A gas stream containing carbon dioxide and sulfur dioxide is cleaned by removing, in a sulfur removal stage, sulfur dioxide from the gas stream. Sulfur dioxide is removed from the gas stream by bringing the gas stream into direct contact with ammonia. The used ammonia may be recycled. In a carbon dioxide removal stage, carbon dioxide is removed from the gas stream depleted in sulfur dioxide by bringing the gas stream into contact with an ammoniated liquid. Following sulfur dioxide and carbon dioxide removal, in an ammonia removal stage, ammonia from the gas stream is removed. Ammonia is removed from the gas stream by bringing the gas stream into direct contact with an acidic liquid to absorb into the acidic liquid, ammonia from the gas stream. The used acidic liquid may be recycled.
    Type: Grant
    Filed: February 1, 2011
    Date of Patent: December 11, 2012
    Assignee: ALSTOM Technology Ltd
    Inventors: Sanjay Kumar Dube, David James Muraskin