Electrical Type Patents (Class 422/199)
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Publication number: 20020094312Abstract: An electrically-heated chemical process reactor having an inlet for receiving industrial gases, an internal channel for passing the flow of gases, and an outlet for expelling the gases. An array of current-carrying screen element packets are arranged along the channel for receiving a heating current, and the internal gas channel includes passages through the array for preheating the gas prior to entering the channel.Type: ApplicationFiled: January 12, 2001Publication date: July 18, 2002Inventors: Gary J. Hanus, Stuart J. Olstad
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Publication number: 20020090327Abstract: An apparatus for carrying out a multi-step process of converting hydrocarbon fuel to a substantially pure hydrogen gas feed includes a plurality of modules each module being in fluid communication with adjacent modules. The modules may be arranged axially along a common axis of flow or alternatively the modules are arranged along a common axis so that they are nested one within the other. The multi-step process includes: providing a fuel processor having a plurality of modules; and feeding the hydrocarbon fuel successively through each of the modules in the reactor to produce the hydrogen rich gas.Type: ApplicationFiled: December 12, 2001Publication date: July 11, 2002Inventor: Vijay A. Deshpande
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Publication number: 20020090328Abstract: An apparatus for carrying out a multi-step process of converting hydrocarbon fuel to a substantially pure hydrogen gas feed includes a plurality of modules arranged in a nested manner along a common axis. The multi-step process includes: providing a fuel processor having a plurality of modules arranged so that they are nested one within the other; and feeding the hydrocarbon fuel successively through each of the modules in the reactor to produce the hydrogen rich gas.Type: ApplicationFiled: December 12, 2001Publication date: July 11, 2002Inventor: Vijay A. Deshpande
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Publication number: 20020090329Abstract: A fuel processor including a hydrogen generating apparatus, a single vessel heat-integrated multi-stage water-gas shift reactor, a multifunctional heat exchanger, a multiple heat source boiler, and a single vessel water exchanged multi-staged preferential oxidation reactor is integrated with a fuel cell stack. Hydrogen is manufactured by the fuel processing apparatus and is consumed by the fuel cell stack, thereby providing one means of integration. The portion of the hydrogen that is not utilized within the fuel cell stack is subsequently burned in the combustion chamber of the fuel processing apparatus thereby providing a second means of integration. The warm cooling water that exits from the fuel cell stack is used as a heat sink for the exothermic heat of reaction in the preferential oxidation reactor, thereby providing a third means of integration.Type: ApplicationFiled: July 31, 2001Publication date: July 11, 2002Inventor: Marten Ternan
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Publication number: 20020085966Abstract: A gas generation system for providing a gas flow to be supplied to a reformer includes an evaporator for evaporating the components contained in a gas flow, wherein the gas flow includes at least one carbon compound, such as hydrocarbon or alcohol, and water vapor. A normalizing stage is connected between the evaporator and the reformer for equalizing the temperature distribution in the gas flow to be supplied to the reformer. The temperature of the gas flow should be equalized to a temperature range below the maximum allowable reformer inlet temperature. In this way, temperature maxima caused by a load change are equalized, thereby significantly increasing the service life of the reformer catalyst.Type: ApplicationFiled: November 19, 2001Publication date: July 4, 2002Inventors: Bruno Motzet, Alois Tischler
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Publication number: 20020081253Abstract: A reformer disposed in the flow path of a reactant fluid includes: a catalyst unit capable of generating hydrogen from a reactant fluid containing an organic compound or carbon monoxide, by catalysis, and an electrically heatable heater unit. An electrically heatable catalyst unit includes: any of a sintered material, a metallic material, a composite material thereof, at least a portion of each of these materials having an electrically heatable property, and a composite material of (1) a heat-resistant material having no electrically heatable property and (2) the sintered material and/or the metallic material, and a catalyst capable of generating hydrogen from a reactant fluid containing an organic compound or carbon monoxide, by catalysis, which catalyst unit has porosity, thereby enables diffusion of a reactant fluid therethrough, and is electrically heatable. The above reformer can generate high-purity hydrogen for use in fuel cell of industrial or automotive application, in a short time.Type: ApplicationFiled: October 25, 2001Publication date: June 27, 2002Applicant: NGK INSULATORS, LTD.Inventor: Fumio Abe
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Patent number: 6409976Abstract: A reactor for the catalytic chemical reaction of a gaseous or liquid reaction starting product to a reaction end product that contains a gaseous or liquid reaction constituent which can be selectively separated by means of a membrane diffusion includes a reaction space into which the reaction starting product flows and which contains a suitable catalyst material. Porous hollow fibers are placed in the reaction space as membranes for the selective separation of the reaction constituent from the residual reaction end product.Type: GrantFiled: February 4, 1999Date of Patent: June 25, 2002Assignee: DaimlerChrysler AGInventors: Thomas Poschmann, Steffen Wieland
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Publication number: 20020073618Abstract: A hydrogen storage bed system which includes a pressure container, a hydrogen storage alloy disposed within the pressure container, and an integrated thermal management system integrally disposed within the pressure container. The integrated thermal management system includes heat generation means, cooling means adapted to use an aerosol coolant, and heat distribution means.Type: ApplicationFiled: April 25, 2001Publication date: June 20, 2002Inventors: Stanford R. Ovshinsky, Rosa T. Young, Yang Li, Vitaliy Myasnikov, Valeriy Sobolev, Farshad Bavarian
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Publication number: 20020073617Abstract: A hydrogen storage bed system which includes a pressure container, a hydrogen storage alloy disposed within the pressure container, and an integrated thermal management system integrally disposed within the pressure container. The integrated thermal management system includes heat generation means, cooling means, and heat distribution means.Type: ApplicationFiled: December 20, 2000Publication date: June 20, 2002Inventors: Stanford R. Ovshinsky, Rosa T. Young, Yang Li, Vitaliy Myasnikov, Valeriy Sobolev
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Publication number: 20020051741Abstract: A reformer is disposed in the flow path of a reactant fluid. The reformer includes an electrically heatable heater unit of honeycomb structure, in the upstream of the flow path of a reactant fluid, and a catalyst unit of honeycomb structure capable of generating hydrogen from a reactant fluid containing an organic compound or carbon monoxide, by catalysis, in the downstream of the above heater unit. The heater unit and catalyst unit satisfy the following relationship: Cell density of the heater unit≦Cell density of the catalyst unit. The reformer improve efficiency for production of hydrogen and reduce CO as the by-product.Type: ApplicationFiled: June 24, 1999Publication date: May 2, 2002Inventors: FUMIO ABE, NAOMI NODA, JUNICHI SUZUKI
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Publication number: 20020048545Abstract: A process and apparatus for producing and burning synthesis gas. Carbonaceous waste material is pyrolytically decomposed in a primary reactor in the presence of steam to produce raw product gas containing H2 and CO. The raw product gas and CO2 is then introduced into a coke containing secondary reactor under pyrolyzing conditions, so that the CO2 and coke react to produce combustible gas having an increased CO content. The combustible gas is mixed with oxygen and CO2 to produce a combustible mixture which is burned as a fuel to produce heat, CO2 and H2O. A portion of the produced CO2 is recovered and used as the source of CO2 gas in the combustible mixture and as a source of CO2 gas for the secondary reactor. Preferably filters and scrubbers are used in a closed loop system to avoid undesirable emissions into the environment.Type: ApplicationFiled: October 25, 2001Publication date: April 25, 2002Inventor: Arlin C. Lewis
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Patent number: 6375911Abstract: A process and an apparatus for treating an exhaust gas, in which a raw gas and high-boiling intermediate products contained in the exhaust gas let out from a CVD system employing a silicon-containing gas is brought into contact with a transition metal such as nickel or a silicide of such transition metals to decompose or convert them into stable halides, followed by detoxication treatment of the harmful components contained in the exhaust gas.Type: GrantFiled: August 13, 1999Date of Patent: April 23, 2002Assignee: Nippon Sanso CorporationInventors: Tadahiro Ohmi, Yoshio Ishihara, Koh Matsumoto, Tetsuya Kimijima
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Publication number: 20020034463Abstract: The present invention is directed towards a fired heater for heating a process fluid that uses U tubes provided with increased internal heat transfer surface to reduce tube metal temperatures and coking, and at the same time is not prone to plugging from coke. The fired heater comprises a radiant section enclosure with a number of U tubes in the radiant section. The U tubes are formed by connecting one or more tubular sections, and the U tubes are provided with internal generally longitudinal fins. The invention also is directed towards a process utilizing a fined heater with U tubes as disclosed for producing olefins from hydrocarbon feedstocks.Type: ApplicationFiled: June 9, 1998Publication date: March 21, 2002Inventors: ARTHUR R DI NICOLANTONIO, DAVID B SPICER, VICTOR K WEI
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Publication number: 20020028165Abstract: A reaction vessel for holding reagents is described, which vessel comprises an electrically conducting polymer capable of emitting heat when an electric current is passed through it. Suitably the reaction vessel comprises a reagent container, such as a capillary tube, slide or chip, in close contact with the electrically conducting polymer. For example, the polymer may be in the form of a film which is wrapped around the tube to form a sheath. This provides a readily controllable heating supply which may be heated and cooled to desired temperatures rapidly. An apparatus suitable for thermal cycling reactions, such as the polymerase chain reaction (PCR) and comprising one or more reaction vessels as described above, as well as methods for carrying out such reactions are also described and claimed.Type: ApplicationFiled: June 25, 1999Publication date: March 7, 2002Inventors: MARTIN A LEE, DARIO LESLIE
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Patent number: 6315969Abstract: A gas re-circulation selective catalytic reduction system. A vaporizer is provided for producing a diluted reducing agent. A reducing agent source, for storing a reducing agent, has a reducing agent pipe interconnected to the vaporizer. A re-circulation gas pipe is adapted to carry gas from a gas flow to the vaporizer. A dilution fan may be provided for propelling the gas from the gas flow to the vaporizer. An injector, connected to the vaporizer by a diluted reducing agent pipe, injects the diluted reducing agent into the gas flow. A heat trace is coupled to the diluted reducing agent pipe and the injector for maintaining a predetermined temperature of the diluted reducing agent pipe and the injector sufficient to substantially prevent the formation of ammonium bisulfate within the insides of the diluted reducing agent pipe and the injector.Type: GrantFiled: February 18, 2000Date of Patent: November 13, 2001Assignee: Mitsubishi Heavy Industries America, Inc.Inventor: Ricardo R. Yoshida
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Patent number: 6296815Abstract: An apparatus is disclosed for thermal desorption of contaminants from contaminated material, the apparatus including: a plurality of first insulated boxes, each insulated box, defining a volume effective for holding contaminated material, and each insulated box defining an opening at the top of the insulated box; at least one top effective to fit on the opening at the top of the insulated box and each top defining a pattern of heater orifices; a plurality of heaters, the heaters being insertable into the volume for holding contaminated material, through the heater orifices defined by the top; and a vapor extraction system effective to-remove vapors from within the volume for holding contaminated material.Type: GrantFiled: February 26, 1999Date of Patent: October 2, 2001Assignee: Shell Oil CompanyInventors: Stanley Lane Walker, Peter Robert Harvey
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Patent number: 6287455Abstract: The present invention provides a means of removing water, antifreeze and fuel from lubricating or hydraulic oil by evaporating these impurities and venting them out of the purifier. The oil is heated by heat of an exposed horizontal heating wand within the evaporator. The oil then passes over the upper lip of the evaporator and cascades downward over the evaporator's ridged outer surface, thereby impeding the flow of oil and increasing the rate of evaporation of the impurities. The evaporated impurities then rise upward along the interior of the domed cover and are vented out of the purifier.Type: GrantFiled: May 15, 1998Date of Patent: September 11, 2001Inventor: C. Barclay Whitmore
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Publication number: 20010012503Abstract: A silicon oxide powder can be continuously prepared by feeding a raw material powder mixture containing silicon dioxide powder into a reaction chamber (2) at a temperature of 1,100-1,600° C., to produce a silicon oxide gas, transferring the silicon oxide gas to a deposition chamber (11) through a transfer conduit (10) maintained at a temperature of from higher than 1,000° C. to 1,300° C., causing silicon oxide to deposit on a substrate (13) which is disposed and cooled in the deposition chamber, scraping the silicon oxide deposit, and recovering the deposit in a recovery chamber (18). The method and apparatus is capable of continuous and stable production of amorphous silicon oxide powder of high purity.Type: ApplicationFiled: February 2, 2001Publication date: August 9, 2001Inventors: Hirofumi Fukuoka, Susumu Ueno, Takeshi Fukuda
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Patent number: 6261524Abstract: An apparatus and method are provided for treating pollutants in a gaseous stream. The apparatus comprises tubular inlets for mixing a gas stream with other oxidative and inert gases for mixture within a reaction chamber. The reaction chamber is heated by heating elements and has orifices through which cool or heated air enters into the central reaction chamber. A process is also provided whereby additional gases are added to the gaseous stream preferably within the temperature range of 650 C.-950° C. which minimizes or alleviates the production of NOx.Type: GrantFiled: April 20, 1999Date of Patent: July 17, 2001Assignee: Advanced Technology Materials, Inc.Inventors: Timothy L. Herman, Jack Ellis, Floris Y. Tsang, Daniel O. Clark, Belynda Flippo, David Inori, Keith Kaarup, Mark Morgenlaender, Aaron Mao
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Patent number: 6197267Abstract: A reactor for corona destruction of volatile organic compounds (VOCs), a multi-surface catalyst for the reactor and a method of making the catalyst for the reactor. The reactor has a catalyst of a high dielectric material with an enhanced surface area. A catalyst layer stack is formed by depositing a high dielectric layer on a substrate and, then depositing a conductive layer on the dielectric layer. The catalyst layer stack is bombarded by low RF energy ions to form an enhanced surface area and to form a protective layer over the conductive layer. Catalyst layer stacks may be joined back to form double-sided catalyst layer stacks. The catalyst layer stack may be diced into small pieces that are used in the reactor or the whole catalyst layer stack may be used.Type: GrantFiled: July 25, 1997Date of Patent: March 6, 2001Assignee: International Business Machines CorporationInventor: Munir-ud-Din Naeem
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Patent number: 6191416Abstract: A stream of gas can be thermally decomposed in a tube along which a radiant heating wire extends to a stream of free atoms or radicals. The wire, which can be formed as a coil is connected at one end of the tube close to its outlet so that the tube provides an electrical contact for the wire and mechanically supports it.Type: GrantFiled: February 18, 1999Date of Patent: February 20, 2001Assignee: Forschungszentrum Julich GmbHInventors: Karl G. Tschersich, Johannes Fleischhauer
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Patent number: 6149881Abstract: The amount of limonene produced during pyrolysis of scrap tire carcass or polyisoprene rubber can be increased by decreasing residence time of the isoprene gas produced during the thermal degradation of polyisoprene rubber in the high temperature reactor region of an oven. This is achieved by using a novel oven design which permits rapid expansion of the isoprene gas away from the high temperature reactor region of the oven to a cooler region where the gas forms limonene and condenses. This pyrolysis method also decreases the amount of soot produced while increasing the amount of limonene produced. Furthermore, this system readily enables separation of the solid, liquid and gas phases produced during pyrolysis.Type: GrantFiled: September 3, 1999Date of Patent: November 21, 2000Inventors: Curtiss D. Hanson, Timothy Burrell, James E. Haworth, James A. Olson
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Patent number: 6130182Abstract: A reactor for corona destruction of volatile organic compounds (VOCs), a multi-surface catalyst for the reactor and a method of making the catalyst for the reactor. The reactor has a catalyst of a high dielectric material with an enhanced surface area. A catalyst layer stack is formed by depositing a high dielectric layer on a substrate and, then depositing a conductive layer on the dielectric layer. The catalyst layer stack is bombarded by low RF energy ions to form an enhanced surface area and to form a protective layer over the conductive layer. Catalyst layer stacks may be joined back to form double-sided catalyst layer stacks. The catalyst layer stack may be diced into small pieces that are used in the reactor or the whole catalyst layer stack may be used.Type: GrantFiled: July 25, 1997Date of Patent: October 10, 2000Assignee: International Business Machines CorporationInventor: Munir-ud-Din Naeem
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Patent number: 6120741Abstract: A device for carrying out large-scale chemical reactions includes a microwave generator, a microwave application vessel containing a high-capacity reactor, and a cover, in which the vessel is a cylinder having longitudinal axis X, a microwave inlet in the vessel bottom wall, and an open upper end, in which the generator provides single-mode microwaves along axis X in the vessel, the size of the vessel being made to match the wavelength of the resonant mode of the microwaves along axis X, and in which the cover seals the upper opening of the vessel, and the cover has a conduit that connects the inside of the vessel to the environment so that the vessel is under atmospheric pressure.Type: GrantFiled: February 3, 1999Date of Patent: September 19, 2000Assignee: Societe ProlaboInventors: Patrick Jacquault, Eric Koutchenkoff, Jean-Lois Di Martino
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Patent number: 6105348Abstract: A safety cut-off system prevents the running of a motor of a self-propelled lawn mower having left and right drive wheels, and forward and reverse gears. The safety cut-off system includes a first forward presence lever manipulatable, by an operator, between an ON state and an OFF state, wherein the forward presence lever is biased to the OFF state, and a reverse presence lever manipulatable, by an operator, between an ON state and an OFF state, wherein the reverse presence lever is also biased to the OFF state. A preventing element, which is responsive to the forward and reverse presence levers, is provided for preventing the motor from running, when the lawn mower is in neutral or a forward gear and neither the forward presence lever nor the reverse presence lever are in the ON state, and when the lawn mower is in a reverse gear and the reverse presence lever is not in the ON state.Type: GrantFiled: June 30, 1998Date of Patent: August 22, 2000Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Daniel J. Turk, Kevin D. King
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Patent number: 6086831Abstract: An array of reaction assemblies for heating and cooling a plurality of reaction vessels. Each reaction vessel assembly including a heat conductive reaction block having an exterior wall and a reaction vessel receiving cavity formed in the block inwardly of the exterior wall. A thermoelectric module is mounted in heat transfer engagement with the exterior wall of the heat conductive reaction block. A fluid heat exchange element is mounted in heat transfer engagement with the thermoelectric module. The thermoelectric module has its junctions to selectively remove heat from the exterior wall of the reaction block or to supply heat to this exterior wall. Each thermoelectric module has thermoelectric junctions cascaded for increased heating and cooling range and a plurality of these junctions to increase capacity.Type: GrantFiled: June 10, 1998Date of Patent: July 11, 2000Assignee: Mettler-Toledo Bohdan, Inc.Inventors: James R. Harness, Larry W. Markus, Andrew J. Grzybowski, Rudy H. Haidle, Marek Turewicz
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Patent number: 6077482Abstract: A treating apparatus for decomposing organohalogen compounds such as chlorofluorocarbons (CFC's), trichloroethylene, methylbromide, halon, and the like, effectively, with a high activity of catalyst, is provided. The apparatus includes a reactor in which organohalogen compounds are decomposed by contact at a temperature in a range of 200.degree..about.500.degree. C. with a catalyst which comprises titania and tungsten oxide by an atomic ratio of Ti and W in a range from 20 mol % to 95 mol % Ti and from 5 mol % to 80 mol % W, with at least the surface of the titania being covered with a porous layer of the tungsten oxide. In accordance with the present invention, organic compounds containing any of fluorine, chlorine and bromine will be decomposed with a high efficiency, and the activity of the catalyst can be maintained for a long time.Type: GrantFiled: January 9, 1998Date of Patent: June 20, 2000Assignee: Hitachi, Ltd.Inventors: Shuichi Kanno, Hiroshi Kawagoshi, Akira Kato, Toshiaki Arato, Hisao Yamashita, Shigeru Azuhata, Shin Tamata
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Patent number: 6045761Abstract: So that fuels can be produced efficiently from an undesirable greenhouse gas, the gas is subjected, together with a catalyst gas, preferably nitrogen or nitrous oxide, and a hydrogen-containing gas or vapour, to a silent electric discharge in a 1st reactor (4). In the process, excited or ionized atoms and/or molecules are formed which are converted, in a catalyst reactor (8) comprising a copper-containing 1st catalyst (8'), to H.sub.2 and possibly CO. Via an expansion valve (9), a liquid (13) separates from a fuel in a liquid vessel (11). Gases escaping from the liquid vessel (11) are passed over a thermal reactor (14) containing a 2nd catalyst (15) and expanded via an expansion valve (16). In a downstream liquid vessel (11') CH.sub.3 OH, for example, separates as the desired liquid fuel (13'). The 1st reactor (4) and the thermal reactor (14) may be combined in a container comprising a plurality of reaction chambers which are parallel to one another.Type: GrantFiled: October 14, 1997Date of Patent: April 4, 2000Assignee: ABB Research Ltd.Inventors: Alain Bill, Baldur Eliasson, Eric Killer, Ulrich Kogelschatz
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Patent number: 6027635Abstract: A process for the pyrolysis of hydrocarbons in a reactor with at least two rows which are parallel to each other in which at least one row is supplied with a non hydrocarbon fluid containing steam to decoke the reaction zone at least in part. At least one other row is supplied with a gaseous mixture containing at least one hydrocarbon and water, to pyrolyze said mixture.Type: GrantFiled: December 26, 1996Date of Patent: February 22, 2000Assignee: Institute Francais du PetroleInventors: Christian Busson, Henri Delhomme
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Patent number: 6007786Abstract: A device for doping silica powder with a dopant includes an arrangement for receiving silica soot particles or previously fabricated silica granules. The particles or granules contained in the receiving arrangement are heated to a temperature sufficient to allow agglomeration of the soot particles into granules followed by densification of the granules. The receiving arrangement is fed with a precursor gas of the dopant so that the granules are heated in an atmosphere containing the precursor gas, which causes the dopant to be incorporated into the granules during their densification to produce densified and doped silica grains. The receiving arrangement is mobile so that, during their movement, each of the granules that it contains is subject to movement such that substantially all of its outside surface is exposed to the atmosphere containing the precursor gas.Type: GrantFiled: May 20, 1997Date of Patent: December 28, 1999Assignee: Alcatel Fibres OptiquesInventors: Jean-Florent Campion, Bernard Jouvenel, Laurent Gasca
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Patent number: 5968456Abstract: An automobile catalytic converter that utilizes the energy of the exothermic reactions that take place in the catalysis substrate to produce electrical energy with a thermoelectric generator. On vehicle cold start, the thermoelectric generator is used as a heat pump to heat the catalyst substrate to reduce the time to catalyst light-off. In this way, the catalytic converter comes up to operating temperature more rapidly, reducing the amount of pollutant emissions at vehicle start-up.Type: GrantFiled: September 19, 1997Date of Patent: October 19, 1999Inventor: Ronald J. Parise
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Patent number: 5965097Abstract: The invention relates to a cleaning device wherein polluted effluents are passed into a cage (2) where a partitioned ring (1) of vertical axis, containing a charge (M) of a solid material exhibiting a large heat exchange surface and, against the inner wall thereof, a catalyst bed (9), rotates. An autothermal working point is reached by including in the catalyst bed heating means (resistors for example) that are temporarily connected to the power supply system, after which the cleaning operations with rotation of the ring and effluent circulation are launched. Heat control is thereafter provided by controlled injection into the effluents of either a fuel or sprayed water for example by means of injectors (15, 16). The device can be applied in the field of incineration of VOC for example in industrial effluents.Type: GrantFiled: December 5, 1997Date of Patent: October 12, 1999Assignees: Institut Francais Du Petrole, Jacques BourcierInventors: Jean Morlec, Jacques Bourcier
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Patent number: 5961932Abstract: An integrated micro-ceramic chemical plant having a unitary ceramic body formed from multiple ceramic layers in the green state which are sintered together includes a unitary ceramic body defining a reaction chamber and first passages are provided for communication with the reaction chamber so that two or more fluids may be delivered to such reaction chamber, a permeable partition wall being provided within the reaction chamber to permit the mixing of fluids during a reaction process. The integrated micro-ceramic chemical plant further includes a filtering chamber including filters disposed in such chamber for separating the solid reaction products from the fluid and for retrieving desired solid reaction products; and other passages for directing the desired solid reaction products to exit from the unitary ceramic body and other passages for directing the desired liquid reaction products to exit from the unitary ceramic body.Type: GrantFiled: June 20, 1997Date of Patent: October 5, 1999Assignee: Eastman Kodak CompanyInventors: Syamal K. Ghosh, Dilip K. Chatterjee, Edward P. Furlani
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Patent number: 5955033Abstract: A rotary kiln in which reaction is to occur between counterflowing reactants and an injector for a reactant extends into a reaction zone in the kiln. The injector is provided with means for adjusting the temperature of the injected reactant to a temperature in the desired range for that zone. Further means are provided for maintaining a temperature in the desired range throughout the zone. The arrangement be used in the production of uranium oxides from uranium hexafluoride.Type: GrantFiled: September 15, 1993Date of Patent: September 21, 1999Assignee: British Nuclear Fuels LimitedInventor: Michael Richard Hayes
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Patent number: 5948371Abstract: A catalytic converter for cleaning exhaust from combustion processes, especially exhaust from internal combustion engines, and the manufacturing method thereof, the converter including a housing and a plurality of packets provided therein. Each of the packets includes at least one corrugated foil joined at contact areas to at least one flat foil, preferably by soldering or welding. The flat and/or corrugated foil is provided at least partially with a catalytically active coating. The spaces between the corrugated foil and/or between the at least one flat foil and the at least one corrugated foil define channels running parallel to one another through which the combustion gas flows. At least one electrically heatable foil is connected on or in at least one packet with good heat conduction.Type: GrantFiled: February 7, 1997Date of Patent: September 7, 1999Assignee: Heraeus Electro-Nite International N.V.Inventor: Edelbert Hafele
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Multicomponent fluid feed apparatus with preheater and mixer for a high temperature chemical reactor
Patent number: 5935528Abstract: A multicomponent fluid feed apparatus is disclosed that independently preheats and then mixes two or more fluid streams being introduced into a high temperature chemical reactor to promote more rigorous and complete reactions using assemblies of inert tubular elements and an integral mixing orifice plate. The design allows use of ceramic and speciality alloy materials for high temperature service with particularly corrosive halide feeds such as UF.sub.6 and HF. Radiant heat transfer to the tubular elements from external means gives the necessary system high temperatures without excessive temperatures to cause material failure. Preheating of the gaseous reactants in a separate step prior to mixing and injecting the gaseous reactants into a high temperature chemical reactor was found to provide an improved thermal conversion of UF.sub.6 to uranium oxides.Type: GrantFiled: January 14, 1997Date of Patent: August 10, 1999Assignee: Molten Metal Technology, Inc.Inventors: Michael J. Stephenson, Paul A. Haas, David A. Everitt -
Patent number: 5902557Abstract: In an electrically heated catalyst support, when necessary, reinforcing layers are formed on the inner circumference and the outer circumference of a honeycomb body. On an end surface of the honeycomb body on the downstream side of exhaust gas, there are provided a plurality of insulating ceramic bars on the outer circumferential layer and/or the inner circumferential layer in such a manner that the insulating ceramic bars cross a non-reinforcing layer of the honeycomb body. End portions of the ceramic bars are held on the reinforcing layer by pins or a ring-shaped holding member joined to an external metallic cylinder. Due to the foregoing arrangement, telescoping of the honeycomb body in the direction of gas flow and damage of the metallic foil can be prevented without obstructing the generation of heat when electricity is supplied. Accordingly, durability of the catalyst support can be remarkably enhanced.Type: GrantFiled: April 15, 1997Date of Patent: May 11, 1999Assignees: Nippon Steel Corporation, Toyota Jidosha Kabushiki KaisaInventors: Kouki Yotsuya, Takuzou Kako, Shogo Konya, Yuuji Nakashima, Kouji Yoshizaki, Kazuhiro Sakurai, Masahiko Ogai
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Patent number: 5888456Abstract: A catalytic converter includes a housing, a honeycomb heater fixed to inside the housing, and a catalytic element disposed downstream of the honeycomb heater. The honeycomb heater has a first honeycomb structure made of metal having a first partition wall having a plurality of first throughholes, and at least one electrode for electrifying the first honeycomb structure. The catalytic element fixed to inside the housing and disposed downstream of the honeycomb heater has a second honeycomb structure having a second partition wall having a plurality of second throughholes, and a catalytic compound loaded on the second honeycomb structure. A horizontal cross-section of the honeycomb structure is made smaller than that of the honeycomb structure. Further, a gap between an outflow end surface of the honeycomb structure and an inflow end surface of the honeycomb structure is made large.Type: GrantFiled: December 20, 1996Date of Patent: March 30, 1999Assignee: NGK Insulators, Ltd.Inventors: Shigeharu Hashimoto, Takahisa Kaneko, Tomoharu Kondo, Yasushi Kato
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Patent number: 5866078Abstract: This invention which combines an oxygen storage system with a catalytic converter to enhance the conversion of common pollutants found in the exhaust gas stream of an internal combustion engine. The oxygen storage element is placed upstream of the catalytic converter and is designed to extract excess oxygen from the exhaust gas stream and release the extracted oxygen when the exhaust gas stream is oxygen deficient. Controlling the oxygen level in this manner allows for effectiveness of the converter to be increased.Type: GrantFiled: December 5, 1997Date of Patent: February 2, 1999Assignee: Precision Combustion, Inc.Inventors: William C. Pfefferle, Subir Roychoudbury
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Patent number: 5866077Abstract: A honeycomb support structure of an electrically-heated catalyst apparatus is disclosed, in which a support member of retainers for preventing an electrically-heated catalyst moving backward is coupled to an outer cylinder while causing the support member to follow the thermal deformation of the outer cylinder thereby to suppress the deformation of the support member due to the thermal stress. A metal foil laminate having a corrugated foil and a tabular foil superposed one on the other is spirally wound to form a cylindrical honeycomb unit, which is accommodated in a metal outer cylinder and is heated by being supplied with power. The honeycomb unit support structure includes a plurality of ceramic bars and at least a support member having a plurality of recesses for holding the ceramic bars at such a position as to traverse the end surface of the honeycomb unit downstream of the exhaust gas flow and in such a manner as to follow the deformation of the outer cylinder.Type: GrantFiled: February 5, 1997Date of Patent: February 2, 1999Assignees: Toyota Jidosha Kabushiki Kaisha, Nippon Steel Corp.Inventors: Kazuhiro Sakurai, Takuzou Kako
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Patent number: 5852274Abstract: An electrically heatable catalytic converter for internal combustion engines is provided. This catalytic converter includes a honeycomb multi-layered core member wound around an electrode. The multi-layered core member consists of a plurality of flat metal foil sheets and a plurality of corrugated metal foil sheets arranged alternately and bonded to each other for preventing the core member from telescoping in the direction of exhaust gas flow, especially, during high-load engine operation.Type: GrantFiled: September 7, 1995Date of Patent: December 22, 1998Assignee: Nippon Soken, Inc.Inventors: Kiyohiko Watanabe, Tohru Yoshinaga, Akihiro Izawa, Osamu Fujishiro
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Patent number: 5851496Abstract: Device for cleaning exhaust gases by a metallic catalyst carrier that is installed in an exhaust gas passage and is contained in a metallic outer cylinder, wherein a structure for absorbing a difference in the thermal expansion between the metallic catalyst carrier and the outer cylinder is realized without causing stress to the metallic catalyst carrier and without requiring strict tolerance in production. A cushioning material made of a heat-resistant wire gauze is arranged between the metallic catalyst carrier and the metallic outer cylinder, and the cushioning material, metallic carrier and metallic outer cylinder are conductively joined. The cushioning material is compressed between the metallic catalyst carrier and the outer cylinder, and the cushioning material is joined to the metallic catalyst carrier and to the outer cylinder. Here, the junction is accomplished locally without overlapping one upon the other in the axial direction of the outer cylinder.Type: GrantFiled: January 23, 1997Date of Patent: December 22, 1998Assignee: Toyota Jidosha Kabushiki KaishaInventor: Kazuhiro Sakurai
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Patent number: 5851495Abstract: The electrically heated catalytic converter of the present invention has a substrate, for a catalyst, which is formed as a laminated assembly of corrugated metal sheets and plain metal sheets. The corrugated metal sheet has an insulating coating made of an alumina Al.sub.2 O.sub.3, and the plain metal sheet has no insulating coating. Local conductive connections are formed between the layers of the metal sheets by soldering the metal sheets using strips of zirconium solder foils interposed between the layers of the metal sheets. The strips of solder foils are arranged in such a manner that the strips of solder foil disposed on both sides of the corrugated metal sheet defines a single electric path in the corrugated metal sheet which connects the solder foils on both sides of the corrugated metal sheet.Type: GrantFiled: October 1, 1996Date of Patent: December 22, 1998Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kouji Yoshizaki, Shogo Konya
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Patent number: 5851498Abstract: A catalytic heater includes a catalyst, for the combustion of a gaseous hydrocarbon in air, supported on a catalyst support. Fuel diffuses into the catalyst support from one (proximal) side. Air diffuses into the catalyst support from the other (distal) side. The catalytic combustion of the fuel heats the catalyst support. The resulting infrared radiation from the distal side of the catalyst support is directed at an object to be heated, for example the fluid chamber of a boiler. A modular boiler includes several catalytic heaters, with the distal sides of their catalyst supports facing a chamber wherethrough a fluid such as water is conducted and heated by the infrared radiation from the heaters.Type: GrantFiled: December 2, 1996Date of Patent: December 22, 1998Assignee: Catalytic Systems Technologies, Ltd.Inventors: Vladimir Rozenshtein, Yehuda Heimlich
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Patent number: 5846495Abstract: There is provided an improved converter body formed of thin metal core elements and a housing. The thin metal core elements have a distal end and a proximal end The distal ends are secured to the housing, and at least some, preferably all, of the proximal ends are free of attachment to any rigid member. This structure results in improved durability in severe automotive tests.Type: GrantFiled: June 26, 1997Date of Patent: December 8, 1998Assignee: Engelhard CorporationInventors: William A. Whittenberger, David Thomas Sheller
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Patent number: 5814283Abstract: An exhaust purifier of an internal combustion engine supplies secondary air into an exhaust pipe without cooling nor inactivating an electrically heated catalyst (EHC) that is active. The exhaust purifier includes the EHC 3 disposed in the exhaust pipe 2, a main catalyst 4 disposed in the exhaust pipe 2 downstream from the EHC 3, and a unit for supplying secondary air into the exhaust pipe 2. The secondary air supply unit has a main path 10 for supplying secondary air into a space defined in the exhaust pipe 2 between the EHC 3 and the main catalyst 4 when it is determined that the main catalyst 4 is active. The secondary air supply unit may additionally have a second path 9 for supplying secondary air into the exhaust pipe 2 on the upstream side of the EHC 3 when it is determined that the EHC 3 is active, so that the secondary air may pass through the EHC 3 and reach the main catalyst 4.Type: GrantFiled: November 5, 1996Date of Patent: September 29, 1998Assignee: Toyota Jidosha Kabushiki KaishaInventors: Hiroki Matuoka, Masaaki Tanaka, Shigemitu Iisaka, Michio Furuhashi, Toshinari Nagai, Tadayuki Nagai, Takashi Kawai, Kenji Harima, Yuuichi Gotou
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Patent number: 5807526Abstract: A device for removal of SO.sub.2 and NO.sub.x from flue gas by high frequency discharge has a chamber having a first inlet opening for entry of flue gas into the chamber and an outlet opening for flue gas to exit from the chamber after removal of SO.sub.2 and NO.sub.x. A generator and electrode produce a high frequency electric field of sufficient strength in the chamber to produce high energy electrons that achieve both excitation and ionization potentials of N.sub.2, O.sub.2 and H.sub.2 O, whereby to produce free radicals of OH., O.sub.2 H., N., O. and H. which react with SO.sub.2 and NO.sub.x molecules in the flue gas. A second inlet opening into the chamber adds ammonia to the SO.sub.2 and NO.sub.x for reaction with the free radicals in neutralization producing ammonium salts from the SO.sub.2 and NO.sub.x in the flue gas exiting from the chamber.Type: GrantFiled: October 14, 1994Date of Patent: September 15, 1998Inventor: Vujo Miljevic
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Patent number: 5804148Abstract: An HC adsorbent which adsorbs hydrocarbons in a predetermined low temperature region and discharges hydrocarbons in a temperature region higher than the lower temperature region is provided in an engine exhaust passage. A catalyst which oxidizes hydrocarbons in a predetermined high temperature region is provided downstream of the HC adsorbent. A heater for heating exhaust is provided upstream of the HC adsorbent. A control unit activates the heater when the exhaust temperature has risen to near the upper limit of the lower temperature region. Activation of the catalyst is thereby promoted, and the time until the catalyst starts oxidizing hydrocarbons discharged by the HC adsorbent is shortened.Type: GrantFiled: March 17, 1997Date of Patent: September 8, 1998Assignee: Nissan Motor Co., Ltd.Inventors: Hiroyuki Kanesaka, Yasuyuki Murofushi
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Patent number: 5800789Abstract: An electrically heated catalyst installed in an exhaust pipe of an internal combustion engine, featuring simple construction, without causing the flow resistance of the exhaust gases to increase, and consuming small amounts of electric power. The electrically heated catalyst has two electrodes of different polarities in a casing through which the exhaust gases flow and has at least one catalyst support that is folded plural times in a zig-zag manner in a direction intersecting the direction of flow of the exhaust gases without coming into contact with itself, the two ends of the catalyst support being connected to these two electrodes. The catalyst support is constituted by a flat foil and a corrugated foil that are joined together, and electric insulators are provided at the folding portions of the catalyst support to stretch and support the catalyst support inside the casing. Owing to the insulators, the catalyst support is held in the casing in a state of receiving tension.Type: GrantFiled: April 15, 1996Date of Patent: September 1, 1998Assignee: Toyota Jidosha Kabushiki KaishaInventor: Kouji Yoshizaki
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Patent number: 5759499Abstract: A thermal reactor to carry out a chemical reaction under precise and controlled temperature conditions. In a preferred embodiment, the reactor supplies a carbon-laden atmosphere with a predetermined carbon potential to a heat treatment furnace. The reactor has a sealed chamber, in which a chemical reaction is carried out. The chamber forms an electrical resistance element in order to produce within it the reaction temperature conditions. The chamber further being electrically isolated, having an inlet for supplying reaction products, and an outlet for the products coming from the reaction. Temperature measuring thermocouples are positioned on the chamber to determine, accurately and locally, the temperature required for the reaction. Carbon potential is measured by a probe arranged at the chamber's outlet.Type: GrantFiled: January 18, 1996Date of Patent: June 2, 1998Assignee: SerthelInventors: Guy Bourdet, Alexis Lebris